Synergetic Photocatalytic Peroxymonosulfate Oxidation of Benzotriazole by Copper Ferrite Spinel: Factors and Mechanism Analysis
Abstract
:1. Introduction
2. Experimental Section
2.1. Chemicals
2.2. Preparation of Catalyst
2.3. Material Characterization
2.4. Degradation Experiments and Sample Analyses
2.5. Response Surface Method Experimental Design and Data Analysis
3. Results and Discussion
3.1. CuFe2O4 Spinel Morphology and Microstructure Analysis
3.2. Textural and Surface Area, Magnetic and Optical Properties
3.3. Performance Evaluation towards BTA Oxidation
3.4. Influence of Operating Parameters on BTA Degradation
3.4.1. CCD Analysis
0.51x1x2 + 2.23x1x3 + 1.83x1x4 + 2.76x2x3 + 0.42x2x4 −
1.34x3x4 + 2.37x12 + 0.95x22 + 0.09x32 + 1.61x42
3.4.2. Interaction Analysis of Influential Factors
3.5. Recyclability Performance of the CuFe2O4/UV/PMS System
3.6. Feasibility of the Process (Effect of Inorganic Anions)
3.7. Radical Scavenging Experiments
3.8. Mechanistic Discussion
3.9. Reaction Pathway of BTA Degradation
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Independent Factors | Unit | Symbols | Ranges and Levels | ||||
---|---|---|---|---|---|---|---|
−α | Low (−1) | Middle (0) | High (+1) | +α | |||
Catalyst loading | g L−1 | x1 | 0.1 | 0.2 | 0.3 | 0.4 | 0.5 |
PMS dosage | mM | x2 | 0.5 | 1 | 1.5 | 2 | 2.5 |
Initial BTA concentration | mg L−1 | x3 | 10 | 20 | 30 | 40 | 50 |
Irradiation time | min | x4 | 10 | 30 | 50 | 70 | 90 |
No. | SE Equation | SE Value |
---|---|---|
1 | 1.68 | |
2 | 1.38 | |
3 | 1.51 | |
4 | 1.50 | |
5 | 1.15 | |
6 | 1.04 |
System | Pollutant (mg/L) | Catalyst (g/L) | Oxidant (mM) | Removal Efficiency (%) | Mineralization Rate (%) | Metal Ion Leaching (mg/L) | Ref. |
---|---|---|---|---|---|---|---|
CuFe@NG/PMS | Sulfamethoxazole (10) | 0.3 | 0.4 | 93.15 in 60 min | 31.96 | [Cu] = 0.25, [Fe] = - | [39] |
CuFe2O4@GO/PMS | Methylene blue (20) | 0.2 | 0.8 | 93.3 in 30 min | - | [Cu] = 0.3, [Fe] = 0.3 | [32] |
OVs-CFEp/Vis/PMS | Sulfamethazine (10) | 1 | 0.3 | 95 in 90 min | 56 | [Cu] < 0.1, [Fe] < 0.1 | [9] |
CuFe2O4 3DPs/Vis/PMS | Tetracycline hydrochloride (20) | 0.25 | 0.2 | 93 in 30 min | [Cu] = 0.2, [Fe] = 0.2 | [22] | |
CuFe2O4-CoFe2O4/PMS | BPA (20) | 0.2 | 1 | 98.7 in 110 min | 72.5 | [21] | |
CuFe2O4/kaolinite/PMS | BPA (50) | 0.5 | 0.5 | 97 in 60 min | 55 | [Cu] = 0.27, [Fe] = 0.01 | [17] |
CuFe2O4/Biochar/Ag3PO4/Vis | Phenol (20) | 0.15 | - | 100 in 18 min | [40] | ||
CN/BVO/CFO/Vis/PMS | Levofloxacin (10) | 0.2 | 1 | 96.2 in 60 min | 67 | [Cu] = 0.08, [Fe] = 0.02 | [13] |
CuFe2O4/MnO2/Vis/PMS | Phenol (100) | 0.5 | 0.5 | 100 in 30 min | 62.2 | [Cu] = 0.026, [Fe] = 0.012 | [37] |
CuFe2O4/UV/PMS | BTA (20) | 0.4 | 2 | 82.3 in 70 min | 53.2 | [Cu] = 0.33, [Fe] 0.18 | This study |
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Golshan, M.; Tian, N.; Mamba, G.; Kakavandi, B. Synergetic Photocatalytic Peroxymonosulfate Oxidation of Benzotriazole by Copper Ferrite Spinel: Factors and Mechanism Analysis. Toxics 2023, 11, 429. https://doi.org/10.3390/toxics11050429
Golshan M, Tian N, Mamba G, Kakavandi B. Synergetic Photocatalytic Peroxymonosulfate Oxidation of Benzotriazole by Copper Ferrite Spinel: Factors and Mechanism Analysis. Toxics. 2023; 11(5):429. https://doi.org/10.3390/toxics11050429
Chicago/Turabian StyleGolshan, Masoumeh, Na Tian, Gcina Mamba, and Babak Kakavandi. 2023. "Synergetic Photocatalytic Peroxymonosulfate Oxidation of Benzotriazole by Copper Ferrite Spinel: Factors and Mechanism Analysis" Toxics 11, no. 5: 429. https://doi.org/10.3390/toxics11050429