A SEM-EDX Study on the Structure of Phenyl Phosphinic Hybrids Containing Boron and Zirconium
Abstract
:1. Introduction
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- The condensation reaction of a phosphonic acid with a metal alkoxide under anhydrous conditions.
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2. Results and Discussion
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- Hybrids S1–S3 were obtained from phenyl phosphinic acid and ZrOCl2·6H2O, in water.
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- Hybrids S4 and S5 were synthesized from phenyl phosphinic acid, ZrOCl2·6H2O and triethyl borate at different molar ratios, also in aqueous solution.
3. Conclusions
4. Materials and Methods
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Bridge | S1 | S2 | S3 | S4 | S5 |
---|---|---|---|---|---|
P-O-Zr | Expected | Expected | Expected | Expected | Expected |
Zr-O-Zr | Expected | Expected | Expected | Expected | Expected |
P-O-P | Not possible | Not possible | Not possible | Not possible | Not possible |
Zr-O-B | - | - | - | Expected | Expected |
P-O-B | - | - | - | Not possible | Not possible |
P-P | Not possible | Not possible | Not possible | Not possible | Not possible |
Zr-Zr | Not possible | Not possible | Not possible | Not possible | Not possible |
B-B | Not possible | Not possible | Not possible | Not possible | Not possible |
P-Zr | Not possible | Not possible | Not possible | Not possible | Not possible |
P-B | Not possible | Not possible | Not possible | Not possible | Not possible |
Zr-B | Not possible | Not possible | Not possible | Not possible | Not possible |
Organic–Inorganic Hybrid | C% | Zr% |
---|---|---|
S1 | 52.07 | 17.26 |
S2 | 60.55 | 15.25 |
S3 | 53.74 | 12.9 |
S4 | 62.25 | 11 |
S5 | 58.59 | 11.72 |
Organic–Inorganic Hybrid | Phenyl Phosphinic Acid:ZrOCl2:B(OEt)3 |
---|---|
S1 | 1:1:0 |
S2 | 2:1:0 |
S3 | 1:2:0 |
S4 | 1:1:1 |
S5 | 1:2:1 |
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Merghes, P.; Varan, N.; Ilia, G.; Hulka, I.; Simulescu, V. A SEM-EDX Study on the Structure of Phenyl Phosphinic Hybrids Containing Boron and Zirconium. Gels 2023, 9, 706. https://doi.org/10.3390/gels9090706
Merghes P, Varan N, Ilia G, Hulka I, Simulescu V. A SEM-EDX Study on the Structure of Phenyl Phosphinic Hybrids Containing Boron and Zirconium. Gels. 2023; 9(9):706. https://doi.org/10.3390/gels9090706
Chicago/Turabian StyleMerghes, Petru, Narcis Varan, Gheorghe Ilia, Iosif Hulka, and Vasile Simulescu. 2023. "A SEM-EDX Study on the Structure of Phenyl Phosphinic Hybrids Containing Boron and Zirconium" Gels 9, no. 9: 706. https://doi.org/10.3390/gels9090706