Journal Description
Materials
Materials
is an international peer-reviewed, open access journal on materials science and engineering published semimonthly online by MDPI. The Portuguese Materials Society (SPM), Spanish Materials Society (SOCIEMAT) and Manufacturing Engineering Society (MES) are affiliated with Materials and their members receive discounts on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, SCIE (Web of Science), PubMed, PMC, Ei Compendex, CaPlus / SciFinder, Inspec, Astrophysics Data System, and other databases.
- Journal Rank: JCR - Q2 (Metallurgy & Metallurgical Engineering) / CiteScore - Q2 (Condensed Matter Physics)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 13.9 days after submission; acceptance to publication is undertaken in 2.7 days (median values for papers published in this journal in the second half of 2023).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in any MDPI journal, in appreciation of the work done.
- Testimonials: See what our editors and authors say about Materials.
- Companion journals for Materials include: Electronic Materials and Construction Materials.
Impact Factor:
3.4 (2022);
5-Year Impact Factor:
3.8 (2022)
Latest Articles
On the Determination of Elastic Properties of Single-Walled Nitride Nanotubes Using Numerical Simulation
Materials 2024, 17(10), 2444; https://doi.org/10.3390/ma17102444 (registering DOI) - 18 May 2024
Abstract
In recent years, tubular nanostructures have been related to immense advances in various fields of science and technology. Considerable research efforts have been centred on the theoretical prediction and manufacturing of non-carbon nanotubes (NTs), which meet modern requirements for the development of novel
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In recent years, tubular nanostructures have been related to immense advances in various fields of science and technology. Considerable research efforts have been centred on the theoretical prediction and manufacturing of non-carbon nanotubes (NTs), which meet modern requirements for the development of novel devices and systems. In this context, diatomic inorganic nanotubes formed by atoms of elements from the 13th group of the periodic table (B, Al, Ga, In, Tl) and nitrogen (N) have received much research attention. In this study, the elastic properties of single-walled boron nitride, aluminium nitride, gallium nitride, indium nitride, and thallium nitride nanotubes were assessed numerically using the nanoscale continuum modelling approach (also called molecular structural mechanics). The elastic properties (rigidities, surface Young’s and shear moduli, and Poisson’s ratio) of nitride nanotubes are discussed with respect to the bond length of the corresponding diatomic hexagonal lattice. The results obtained contribute to a better understanding of the mechanical response of nitride compound-based nanotubes, covering a broad range, from the well-studied boron nitride NTs to the hypothetical thallium nitride NTs.
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(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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Open AccessArticle
Viscoelastic Analysis of Asphalt Concrete with a Digitally Reconstructed Microstructure
by
Marek Klimczak
Materials 2024, 17(10), 2443; https://doi.org/10.3390/ma17102443 (registering DOI) - 18 May 2024
Abstract
In the finite element analysis of asphalt concrete (AC), it is nowadays common to incorporate the information from the underlying scales to study the overall response of this material. Heterogeneity observed at the asphalt mixture scale is analyzed in this paper. Reliable finite
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In the finite element analysis of asphalt concrete (AC), it is nowadays common to incorporate the information from the underlying scales to study the overall response of this material. Heterogeneity observed at the asphalt mixture scale is analyzed in this paper. Reliable finite element analysis (FEA) of asphalt concrete comprises a set of complex issues. The two main aspects of the asphalt concrete FEA discussed in this study are: (1) digital reconstruction of the asphalt pavement microstructure using processing of the high-quality images; and (2) FEA of the asphalt concrete idealized samples accounting for the viscoelastic material model. Reconstruction of the asphalt concrete microstructure is performed using a sequence of image processing operations (binarization, removing holes, filtering, segmentation and boundaries detection). Geometry of the inclusions (aggregate) are additionally simplified in a controlled mode to reduce the numerical cost of the analysis. As is demonstrated in the study, the introduced geometry simplifications are justified. Computational cost reduction exceeds of several orders of magnitude additional modeling error occurring due to the applied simplification technique. Viscoelastic finite element analysis of the AC identified microstructure is performed using the Burgers material model. The analysis algorithm is briefly described with a particular focus on the computational efficiency aspects. In order to illustrate the proposed approach, a set of 2D problems is solved. Numerical results confirm both the effectiveness of the self-developed code and the applicability of the Burgers model to the analyzed class of AC analysis problems. Further research directions are also described to highlight the potential benefits of the developed approach to numerical modeling of asphalt concrete.
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(This article belongs to the Special Issue Experimental Tests and Numerical Analysis of Construction Materials)
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Influence of Carboxymethyl Cellulose as a Thickening Agent for Glauber’s Salt-Based Low Temperature PCM
by
Jay Thakkar, Sai Bhargav Annavajjala, Margaret J. Sobkowicz and Jan Kosny
Materials 2024, 17(10), 2442; https://doi.org/10.3390/ma17102442 (registering DOI) - 18 May 2024
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This work is focused on a novel, promising low temperature phase change material (PCM), based on the eutectic Glauber’s salt composition. To allow phase transition within the refrigeration range of temperatures of +5 °C to +12 °C, combined with a high repeatability of
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This work is focused on a novel, promising low temperature phase change material (PCM), based on the eutectic Glauber’s salt composition. To allow phase transition within the refrigeration range of temperatures of +5 °C to +12 °C, combined with a high repeatability of melting–freezing processes, and minimized subcooling, the application of three variants of sodium carboxymethyl cellulose (Na-CMC) with distinct molecular weights (700,000, 250,000, and 90,000) is considered. The primary objective is to optimize the stabilization of this eutectic PCM formulation, while maintaining the desired enthalpy level. Preparation methods are refined to ensure repeatability in mixing components, thereby optimizing performance and stability. Additionally, the influence of Na-CMC molecular weight on stabilization is examined through differential scanning calorimetry (DSC), T-history, and rheology tests. The PCM formulation of interest builds upon prior research in which borax, ammonium chloride, and potassium chloride were used as additives to sodium sulfate decahydrate (Glauber’s salt), prioritizing environmentally responsible materials. The results reveal that CMC with molecular weights of 250 kg/mol and 90 kg/mol effectively stabilize the PCM without phase separation issues, slowing crystallization kinetics. Conversely, CMC of 700 kg/mol proved ineffective due to the disruption of gel formation at its low gel point, hindering higher concentrations. Calculations of ionic concentration indicate higher Na ion content in PCM stabilized with 90 kg/mol CMC, suggesting increased ionic interactions and gel strength. A tradeoff is discovered between the faster crystallization in lower molecular weight CMC and the higher concentration required, which increases the amount of inert material that does not participate in the phase transition. After thermal cycling, the best formulation had a latent heat of 130 J/g with no supercooling, demonstrating excellent performance. This work advances PCM’s reliability as a thermal energy storage solution for diverse applications and highlights the complex relationship between Na-CMC molecular weight and PCM stabilization.
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Open AccessArticle
Influence of Fibre Orientation on the Slotting Quality of CFRP Composites Using the Multi-Tooth Mill
by
Ying Zhai, Shuwei Lv, Defeng Yan, Shuaishuai Wang, Junyi Lin, Chunyu Mao, Qihao Xu and Jiyu Liu
Materials 2024, 17(10), 2441; https://doi.org/10.3390/ma17102441 (registering DOI) - 18 May 2024
Abstract
Carbon fibre-reinforced plastic (CFRP) composites, prized for their exceptional properties, often encounter surface quality issues during slotting due to their inherent heterogeneity. This paper tackles CFRP slotting challenges by employing multi-tooth mills in experiments with various fibre orientations and tool feed rates. In-plane
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Carbon fibre-reinforced plastic (CFRP) composites, prized for their exceptional properties, often encounter surface quality issues during slotting due to their inherent heterogeneity. This paper tackles CFRP slotting challenges by employing multi-tooth mills in experiments with various fibre orientations and tool feed rates. In-plane scratching tests are performed under linearly varying loads; then, slotting experiments are conducted at different parameters. The scratching test results indicate that the fibre orientation and cutting angles have significant influences on forces and fracture process. The slotting experiments demonstrate that cutting forces and surface roughness Sa of the bottom slotting surface are notably affected by the fibre orientation, with disparities between up-milling and down-milling sides. Reorganising Sa data by local fibre cutting angle θ highlights consistent Sa variations between up-milling and down-milling sides for 0° ≤ θ ≤ 90°, with lower Sa on the up-milling side. However, for 90° < θ ≤ 150°, Sa variations diverge, with lower Sa on the down-milling side. Unexpectedly, Sa on the down-milling side decreases with increasing θ in this range. Additionally, the tool feed rate exerts a more pronounced influence on Sa on the up-milling side.
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(This article belongs to the Special Issue Precision Machining and Micro-/Nano Manufacturing)
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Open AccessArticle
Influence of Solute Drag Effect and Interphase Precipitation of Nb on Ferrite Transformation
by
Yiming Cai, Ran Wei, Duoduo Jin, Honghong Wang, Xiangliang Wan, Chengyang Hu and Kaiming Wu
Materials 2024, 17(10), 2440; https://doi.org/10.3390/ma17102440 (registering DOI) - 18 May 2024
Abstract
The significant impact of Nb on ferrite transformation, both in terms of solute drag effect (SDE) and interphase precipitation, was investigated quantitatively. Ferrite transformation kinetics were characterized using thermal expansion experiments and theoretical calculations. The microstructures were characterized using high−temperature confocal laser scanning
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The significant impact of Nb on ferrite transformation, both in terms of solute drag effect (SDE) and interphase precipitation, was investigated quantitatively. Ferrite transformation kinetics were characterized using thermal expansion experiments and theoretical calculations. The microstructures were characterized using high−temperature confocal laser scanning microscopy (CLSM), a field−emission scanning electron microscope (FESEM), and a transmission electron microscope (TEM). Under a higher driving force, interphase precipitations were observed in the sample with a higher Nb content. A three−dimensional (3D) reconstruction method was used to convert the two−dimensional (2D) image of interphase precipitation into a three−dimensional model for a more typical view. The SDE and interphase precipitation had opposite effects on the kinetics of ferrite transformation. A lower Nb content showed a strong contribution to the SDE, which delayed ferrite transformation. A higher concentration of Nb was expected to enhance the SDE, but the inhibition effect was eliminated by the interphase precipitation of NbC during interfacial migration. Both the experimental results and theoretical calculations confirmed this phenomenon.
Full article
(This article belongs to the Special Issue Plastic Deformation, Strengthening and Toughening of Advanced Metallic Materials (2nd Edition))
Open AccessReview
Exploring the Progress of Hyaluronic Acid Hydrogels: Synthesis, Characteristics, and Wide-Ranging Applications
by
Iman Gholamali, Trung Thang Vu, Sung-Han Jo, Sang-Hyug Park and Kwon Taek Lim
Materials 2024, 17(10), 2439; https://doi.org/10.3390/ma17102439 (registering DOI) - 18 May 2024
Abstract
This comprehensive review delves into the world of hyaluronic acid (HA) hydrogels, exploring their creation, characteristics, research methodologies, and uses. HA hydrogels stand out among natural polysaccharides due to their distinct features. Their exceptional biocompatibility makes them a top choice for diverse biomedical
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This comprehensive review delves into the world of hyaluronic acid (HA) hydrogels, exploring their creation, characteristics, research methodologies, and uses. HA hydrogels stand out among natural polysaccharides due to their distinct features. Their exceptional biocompatibility makes them a top choice for diverse biomedical purposes, with a great ability to coexist harmoniously with living cells and tissues. Furthermore, their biodegradability permits their gradual breakdown by bodily enzymes, enabling the creation of temporary frameworks for tissue engineering endeavors. Additionally, since HA is a vital component of the extracellular matrix (ECM) in numerous tissues, HA hydrogels can replicate the ECM’s structure and functions. This mimicry is pivotal in tissue engineering applications by providing an ideal setting for cellular growth and maturation. Various cross-linking techniques like chemical, physical, enzymatic, and hybrid methods impact the mechanical strength, swelling capacity, and degradation speed of the hydrogels. Assessment tools such as rheological analysis, electron microscopy, spectroscopy, swelling tests, and degradation studies are employed to examine their attributes. HA-based hydrogels feature prominently in tissue engineering, drug distribution, wound recovery, ophthalmology, and cartilage mending. Crafting HA hydrogels enables the production of biomaterials with sought-after qualities, offering avenues for advancements in the realm of biomedicine.
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(This article belongs to the Special Issue Synthesis and Characterization of Hydrogels)
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Combustion Synthesis of Functionalized Carbonated Boron Nitride Nanoparticles and Their Potential Application in Boron Neutron Capture Therapy
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Stanisław Cudziło, Bożena Szermer-Olearnik, Sławomir Dyjak, Mateusz Gratzke, Kamil Sobczak, Anna Wróblewska, Agnieszka Szczygieł, Jagoda Mierzejewska, Katarzyna Węgierek-Ciura, Andrzej Rapak, Paulina Żeliszewska, Dawid Kozień, Zbigniew Pędzich and Elżbieta Pajtasz-Piasecka
Materials 2024, 17(10), 2438; https://doi.org/10.3390/ma17102438 (registering DOI) - 18 May 2024
Abstract
In this research, we developed boron-rich nanoparticles that can be used for boron neutron capture therapy as potential carriers for boron delivery to cancerous tissues. Functionalized carbonated boron nitride nanostructures (CBNs) were successfully synthesized in self-propagating combustion waves in mixtures of high-nitrogen explosives
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In this research, we developed boron-rich nanoparticles that can be used for boron neutron capture therapy as potential carriers for boron delivery to cancerous tissues. Functionalized carbonated boron nitride nanostructures (CBNs) were successfully synthesized in self-propagating combustion waves in mixtures of high-nitrogen explosives and boron compounds. The products’ composition, morphology, and structural features were investigated using Fourier transform infrared spectroscopy, powder X-ray diffraction, low-temperature nitrogen sorption analysis, thermogravimetric analysis, high-resolution scanning electron microscopy, and high-resolution transmission electron microscopy. The extreme conditions prevailing in combustion waves favor the formation of nanosized CBN hollow grains with highly disordered structures that are properly functionalized on the surface and inside the particles. Therefore, they are characterized by high porosity and good dispersibility in water, which are necessary for medical applications. During biological tests, a concentration-dependent effect of the obtained boron nitride preparations on the viability of normal and neoplastic cells was demonstrated. Moreover, the assessment of the degree of binding of fluorescently labeled nanoparticles to selected cells confirmed the relationships between the cell types and the concentration of the preparation at different incubation time points.
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(This article belongs to the Special Issue Advances in Nanomaterials for Medical Application, Drug Delivery and Bone Tissue Engineering)
Open AccessArticle
Development of Low-Weight and High-Strength AA6005A Extrudates Intended for Modern Architecture and Design of Innovative Die for Extrusion Process
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Jacek Madura, Sandra Puchlerska, Maciej Balcerzak, Piotr Noga, Marek Bogusz, Józef Zasadziński, Dariusz Leśniak, Krzysztof Żaba and Henryk Jurczak
Materials 2024, 17(10), 2437; https://doi.org/10.3390/ma17102437 (registering DOI) - 18 May 2024
Abstract
In the realm of modern architecture, the demand for materials that combine strength, durability, and aesthetic flexibility is ever-growing. Addressing this need, this paper presents a study on the innovative use of aluminum extrudates in construction. Focusing on the AA6005 alloy, which is
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In the realm of modern architecture, the demand for materials that combine strength, durability, and aesthetic flexibility is ever-growing. Addressing this need, this paper presents a study on the innovative use of aluminum extrudates in construction. Focusing on the AA6005 alloy, which is known for its excellent balance of strength, corrosion resistance, and weldability, this research delves into the development of an extrusion process that yields thin-walled, lightweight, yet high-strength structural components. Using FEM simulations, a new extrudate of the AA6005A was developed. It is compatible with standard façade systems, with high-strength properties and a weight reduced by 20% compared to that of conventional extrudates made of the AA6063 alloy. Using CAD engineering and FEM simulations of aluminum extrusion process, an innovative die was designed for the extrusion process, ensuring uniform flow of metal from the bearing and minimizing the elastic deflection of the die. This resulted in an increase in the extrusion velocity of thin-walled extrudate from AA6005A by 24% compared to conventional profiles extruded from AA6063. As part of the research, a trial test was carried out in production conditions and the quality of the extrudates was tested by 3D optical scanning, mechanical and structural properties tests, and microstructure observation.
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(This article belongs to the Section Metals and Alloys)
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Reversible Multi-Mode Optical Modification in Inverse-Opal-Structured WO3: Yb3+, Er3+ Photonic Crystal
by
Bokun Zhu, Keliang Ruan, Cherkasova Tatiana and Yangke Cun
Materials 2024, 17(10), 2436; https://doi.org/10.3390/ma17102436 (registering DOI) - 18 May 2024
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Reversible optical regulation has potential applications in optical anti-counterfeiting, storage, and catalysis. Compared to common power materials, the reverse opal structure has a larger specific surface area and an increased contact area for optical regulation, which is expected to achieve higher regulation rates.
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Reversible optical regulation has potential applications in optical anti-counterfeiting, storage, and catalysis. Compared to common power materials, the reverse opal structure has a larger specific surface area and an increased contact area for optical regulation, which is expected to achieve higher regulation rates. However, it is difficult to achieve reversible and repeatable regulation of the luminescent properties of photonic crystals, especially with the current research on the structural collapse of photonic crystals. In this work, WO3: Yb3+, Er3+ inverse photonic crystals were prepared by the template approach, and reversible multi-mode optical modification was investigated. Upon heat treatment in a reducing atmosphere or air, the color of the photonic crystals can reversibly change from light yellow to dark green, accompanied by changes in absorption and upconversion of luminescence intensity. The stability and fatigue resistance of this reversible optical modification ability were explored through cyclic experiments, providing potential practical applications for photocatalysis, optical information storage, and electrochromism.
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Open AccessArticle
Keratin/Copper Complex Electrospun Nanofibers for Antibacterial Treatments: Property Investigation and In Vitro Response
by
Maria Laura Tummino, Iriczalli Cruz-Maya, Alessio Varesano, Claudia Vineis and Vincenzo Guarino
Materials 2024, 17(10), 2435; https://doi.org/10.3390/ma17102435 (registering DOI) - 18 May 2024
Abstract
The frontiers of antibacterial materials in the biomedical field are constantly evolving since infectious diseases are a continuous threat to human health. In this work, waste-wool-derived keratin electrospun nanofibers were blended with copper by an optimized impregnation procedure to fabricate antibacterial membranes with
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The frontiers of antibacterial materials in the biomedical field are constantly evolving since infectious diseases are a continuous threat to human health. In this work, waste-wool-derived keratin electrospun nanofibers were blended with copper by an optimized impregnation procedure to fabricate antibacterial membranes with intrinsic biological activity, excellent degradability and good cytocompatibility. The keratin/copper complex electrospun nanofibers were multi-analytically characterized and the main differences in their physical–chemical features were related to the crosslinking effect caused by Cu2+. Indeed, copper ions modified the thermal profiles, improving the thermal stability (evaluated by differential scanning calorimetry and thermogravimetry), and changed the infrared vibrational features (determined by infrared spectroscopy) and the chemical composition (studied by an X-ray energy-dispersive spectroscopy probe and optical emission spectrometry). The copper impregnation process also affected the morphology, leading to partial nanofiber swelling, as evidenced by scanning electron microscopy analyses. Then, the membranes were successfully tested as antibacterial materials against gram-negative bacteria, Escherichia coli. Regarding cytocompatibility, in vitro assays performed with L929 cells showed good levels of cell adhesion and proliferation (XTT assay), and no significant cytotoxic effect, in comparison to bare keratin nanofibers. Given these results, the material described in this work can be suitable for use as antibiotic-free fibers for skin wound dressing or membranes for guided tissue regeneration.
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(This article belongs to the Special Issue Nanoarchitectonics in Materials Science)
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Effect of the Axial Profile of a Ceramic Grinding Wheel on Selected Roughness Parameters of Shaped Surfaces Obtained in the Grinding Process with a Dual-Tool Grinding Head
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Piotr Jaskólski, Marzena Sutowska, Wojciech Zawadka, Winfried Malorny, Krzysztof Rokosz and Krzysztof Nadolny
Materials 2024, 17(10), 2434; https://doi.org/10.3390/ma17102434 (registering DOI) - 18 May 2024
Abstract
The use of CNC equipment that integrates several machining operations eliminates downtime due to changes in setup and clamping of workpieces in more than one machining device. A review of CNC equipment and tools known from the literature and from manufacturers’ offerings indicates
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The use of CNC equipment that integrates several machining operations eliminates downtime due to changes in setup and clamping of workpieces in more than one machining device. A review of CNC equipment and tools known from the literature and from manufacturers’ offerings indicates that new technical solutions are being developed to integrate two or more technological operations. However, these examples have numerous limitations and are mostly not suitable for machining surfaces with complex shapes. An example of such solutions is the use of a dual-tool grinding head, which integrates the process of rough grinding with a ceramic grinding wheel and finish grinding with a flexible grinding wheel. Unfortunately, it has the disadvantage of being limited by the angular shape of the ceramic grinding wheel, making it unable to adapt to the complex geometries of the shaped surfaces being ground. The need to overcome this limitation became the motivation for the research work described in this article. By means of experimental research, it was verified what effect the radial outline on the periphery of a ceramic grinding wheel realized by rough grinding would have on the surface roughness parameters obtained in the process of grinding shaped surfaces. For this purpose, grinding processes using a ceramic wheel with a conical and radial outline were compared. The result of the study was a summary of the surface roughness parameters Sa, St, Sq, Spk, Str, and Sds obtained after two-stage machining (rough and finish grinding). The obtained analysis results showed that changing the axial outline of the ceramic grinding wheel makes it possible to significantly expand the range of applications of the dual-tool head without negatively affecting the quality of the machined surface. Thus, such an improvement will make it possible to increase the applicability of the head by grinding shaped surfaces with a radial profile of curvature.
Full article
(This article belongs to the Special Issue Obtaining and Characterization of New Materials, Volume V)
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Open AccessArticle
Investigation of Fiber–Matrix Interface Strength via Single-Fiber Pull-Out Test in 3D-Printed Thermoset Composites: A Simplified Methodology
by
Kaan Nuhoglu, Neyton M. Baltodano, Jr. and Emrah Celik
Materials 2024, 17(10), 2433; https://doi.org/10.3390/ma17102433 (registering DOI) - 18 May 2024
Abstract
The emergence of additive manufacturing technologies for fiber-reinforced thermoset composites has greatly bolstered their utilization, particularly within the aerospace industry. However, the ability to precisely measure the interface strength between the fiber and thermoset matrix in additively manufactured composites has been constrained by
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The emergence of additive manufacturing technologies for fiber-reinforced thermoset composites has greatly bolstered their utilization, particularly within the aerospace industry. However, the ability to precisely measure the interface strength between the fiber and thermoset matrix in additively manufactured composites has been constrained by the cumbersome nature of single-fiber pull-out experiments and the need for costly instrumentation. This study aims to introduce a novel methodology for conducting single-fiber pull-out tests aimed at quantifying interface shear strength in additively manufactured thermoset composites. Our findings substantiate the viability of this approach, showcasing successful fiber embedding within composite test specimens and precise characterization of fiber pull-out strength using a conventional mechanical testing system. The test outcome revealed an average interfacial strength value of 2.4 MPa between carbon fiber and the thermoset epoxy matrix, aligning with similar studies in the existing literature. The outcome of this study offers an affordable and versatile test methodology to revolutionize composite material fabrication for superior mechanical performance.
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(This article belongs to the Special Issue Carbon Fiber Reinforced Polymers (2nd Edition))
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Freeze-Casting of Alumina and Permeability Analysis Based on a 3D Microstructure Reconstructed Using Generative Adversarial Networks
by
Xianhang Li, Li Duan, Shihao Zhou, Xuhao Liu, Zhaoyue Yao and Zilin Yan
Materials 2024, 17(10), 2432; https://doi.org/10.3390/ma17102432 (registering DOI) - 18 May 2024
Abstract
In this study, alumina ceramics with hierarchical pores were successfully fabricated using freeze casting. Experimental studies show that both the solid loading of the slurry and the thermal insulation layer at the interface of the slurry and cooling plate can influence the pore
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In this study, alumina ceramics with hierarchical pores were successfully fabricated using freeze casting. Experimental studies show that both the solid loading of the slurry and the thermal insulation layer at the interface of the slurry and cooling plate can influence the pore characteristics of cast samples. In order to examine the pore characteristics and evaluate the permeability of the freeze-cast samples fabricated under different conditions, a generative adversarial network (GAN) method was employed to reconstruct the three-dimensional (3D) microstructure from two-dimensional (2D) scanning electron microscopy (SEM) images of the samples. Furthermore, GAN 3D reconstruction was validated against X-ray tomography 3D reconstruction results. Based on the GAN reconstructed microstructures, the permeability and pore distribution of the various samples were analyzed. The sample cast with 35 wt.% solid loading shows an optimal permeability.
Full article
(This article belongs to the Special Issue Porous Ceramics, Glasses and Composites, Volume II)
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Open AccessArticle
Study of the Long-Term High-Temperature Structural Stability of RuAl Electrodes for Microelectronic Devices
by
Marietta Seifert, Barbara Leszczynska and Thomas Gemming
Materials 2024, 17(10), 2431; https://doi.org/10.3390/ma17102431 (registering DOI) - 18 May 2024
Abstract
The high-temperature stability of RuAl-based electrodes for application in microelectronic devices is analyzed for long-term duration. The electrodes are prepared on Ca3TaGa3Si2O14 (CTGS) substrates using SiO2 and Al-N-O cover and barrier layers as oxidation protection.
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The high-temperature stability of RuAl-based electrodes for application in microelectronic devices is analyzed for long-term duration. The electrodes are prepared on Ca3TaGa3Si2O14 (CTGS) substrates using SiO2 and Al-N-O cover and barrier layers as oxidation protection. The samples are annealed at 600, 700, or 800 °C in air for 192 h. Minor degradation is observed after thermal loading at 700 °C. The annealing at 800 °C for 192 h leads to a partial oxidation of the Al in the extended contact pad and to a complete oxidation of the Al within the structured interconnect electrodes. The different degradation of the interconnect electrodes and the contact pads is caused by their different lateral dimensions. In summary, long-term high-temperature stability is demonstrated up to at least 700 °C in air. Less oxidizing atmospheres should allow the application at higher temperatures and for a significantly longer duration.
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(This article belongs to the Section Electronic Materials)
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Evaluation of the Surface Topography of Microfinishing Abrasive Films in Relation to Their Machining Capability of Nimonic 80A Superalloy
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Katarzyna Tandecka, Wojciech Kacalak, Filip Szafraniec, Michał Wieczorowski and Thomas G. Mathia
Materials 2024, 17(10), 2430; https://doi.org/10.3390/ma17102430 (registering DOI) - 18 May 2024
Abstract
This study investigates the surface topography of microfinishing abrasive films and their machining capability on the Nimonic 80A superalloy, a high-performance nickel-based alloy commonly used in aerospace and gas turbine engine applications. Surface analysis was conducted on three abrasive films with nominal grain
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This study investigates the surface topography of microfinishing abrasive films and their machining capability on the Nimonic 80A superalloy, a high-performance nickel-based alloy commonly used in aerospace and gas turbine engine applications. Surface analysis was conducted on three abrasive films with nominal grain sizes of 30, 15, and 9 μm, exploring wear patterns, contact frequency, and distribution. To assess the distribution of grain apexes, Voronoi cells were employed. Results revealed distinct wear mechanisms, including torn abrasive grains and cracked bond surfaces, highlighting the importance of efficient chip removal mechanisms in microfinishing processes. Larger grain sizes exhibited fewer contacts with the workpiece but provided more storage space for machining products, while smaller grain sizes facilitated smoother surface finishes. The research demonstrated the effectiveness of microfinishing abrasive films in reducing surface irregularities. Additionally, surface analysis of worn abrasive tools provided insights into wear mechanisms and chip formation, with the segmentation of microchips contributing to efficient chip removal. These findings underscore the significance of selecting appropriate abrasive films and implementing effective chip removal mechanisms to optimize microfinishing processes and improve surface finishing quality in advanced material machining applications. It is worth emphasizing that no prior research has investigated the microfinishing of components crafted from Nimonic 80A utilizing abrasive films, rendering this study truly unique in its contribution to the field.
Full article
(This article belongs to the Special Issue Precision and Ultra-Precision Subtractive and Additive Manufacturing Processes of Alloys and Steels, 2nd Edition)
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Open AccessArticle
First-Principles Study of Discharge Products and Their Stability for Lithium-Nitrogen Batteries
by
Guoxiong Qu, Xudong Zhao, Chengdong Wei, Hongyi Zhang, Yutong Yang, Hongtao Xue and Fuling Tang
Materials 2024, 17(10), 2429; https://doi.org/10.3390/ma17102429 (registering DOI) - 18 May 2024
Abstract
Li-N2 batteries present a relatively novel approach to N2 immobilization, and an advanced N2/Li3N cycling method is introduced in this study. The low operating overpotential of metal–air batteries is quite favorable to their stable cycling performance, providing
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Li-N2 batteries present a relatively novel approach to N2 immobilization, and an advanced N2/Li3N cycling method is introduced in this study. The low operating overpotential of metal–air batteries is quite favorable to their stable cycling performance, providing a prospect for the development of a new type of battery with extreme voltage. The battery system of Li-N2 uses N2 as the positive electrode, lithium metal as the negative electrode, and a conductive medium containing soluble lithium salts as the electrolyte. In accordance with its voltage-distribution trend, a variety of lithium-nitrogen molecule intermediates are produced during the discharge process. There is a lack of theoretical description of material changes at the microscopic level during the discharge process. In this paper, the first-principles approach is used to simulate and analyze possible material changes during the discharge process of Li-N2 batteries. The discharge process is simulated on a 4N-graphene anode substrate model, and simulations of its electrostatic potential, Density of States (DOS), HOMO (Highest Occupied Molecular Orbital) and LUMO (Lowest Unoccupied Molecular Orbital) aspects confirm that the experimentally found Li3N becomes the final stabilized product of the Li-N2 battery. It can also be seen in the density of states that graphene with adsorption of 4N transforms from semiconducting to metallic properties. In addition, the differential charge also indicates that the Li-N2 material has a strong adsorption effect on the substrate, which can play the dual role of electricity storage and nitrogen fixation.
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(This article belongs to the Special Issue Advanced Electrode Materials for Batteries)
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Effect of Pseudomonas aeruginosa on Corrosion Behavior of X65 Carbon Steel
by
Zixuan Shao, Ruiqi Guo, Jianhua Tang and Xin Zhang
Materials 2024, 17(10), 2428; https://doi.org/10.3390/ma17102428 - 17 May 2024
Abstract
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X65 pipeline steel is widely used in the field of offshore oil and gas exploitation due to its excellent performance. However, due to the complex environment in the ocean, X65 pipeline steel is faced with a great risk of microbial corrosion failure. Therefore,
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X65 pipeline steel is widely used in the field of offshore oil and gas exploitation due to its excellent performance. However, due to the complex environment in the ocean, X65 pipeline steel is faced with a great risk of microbial corrosion failure. Therefore, it is of great significance to study the corrosion mechanism of X65 pipeline steel by microorganisms. In this paper, the corrosion effect of Pseudomonas aeruginosa (P. aeruginosa) secreting phenazine compounds on X65 pipeline steel was studied by the weight loss method, biofilm scanning electron microscopy analysis, surface corrosion morphology observation, electrochemical testing and medium pH test corrosion products. The results showed that the inoculation of P. aeruginosa accelerated the corrosion of X65 steel. After knocking out the phzM and phzS genes that regulate the synthesis of PYO, P. aeruginosa can still produce biofilms on the surface of X65 steel consistent with the morphology of wild-type P. aeruginosa, but the corrosion of X65 steel is significantly reduced. It is proved that PYO plays an important role in the corrosion process of P. aeruginosa on steel.
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Open AccessArticle
An Experiment on the Dwell Time Effect of Rubber Seal O-Rings: Friction Force in Intermittent Reciprocating Motion
by
Shaoxian Bai, Tao Wang and Jing Yang
Materials 2024, 17(10), 2427; https://doi.org/10.3390/ma17102427 - 17 May 2024
Abstract
The adhesive force between two contact surfaces often leads to an increase in the friction force of the rubber seal O-ring after a certain dwell time, forming dwell time effects and affecting the reliability of sealing. The dwell time effect may result in
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The adhesive force between two contact surfaces often leads to an increase in the friction force of the rubber seal O-ring after a certain dwell time, forming dwell time effects and affecting the reliability of sealing. The dwell time effect may result in substantial instability with respect to the frictional behavior of rubber O-rings, which needs to be carefully taken into account in the design of rubber seals. Therefore, in this paper, the dwell time effect of the friction force was studied experimentally for intermittent reciprocating rubber seal O-rings coupled with stainless steel 316L and a sealing air medium. The friction force of three kinds of rubber materials, including fluorine rubber (FPM), silicone rubber (SI), and nitrile rubber (NBR), was measured under different dwell times, compression ratios, and seal pressure. The results showed that there was a rolling frictional force, and the second peak value of the frictional force caused by the O-ring's rolling under shear action and after the maximum static frictional force was observed at the starting stage of reciprocating motion. For FPM O-rings, the rolling friction force was much greater than the maximum static frictional force at about four times the value of the compression ratio at 9% and seal pressure at 0; moreover, the force was much greater at greater compression ratios. The dwell time effect was significant in the friction forces of rubber O-rings. The friction force increases with an increase in dwell time. The increase in maximum static friction force exceeded 50% after 5 dwell days. The increase in seal pressure led to the disappearance of the rolling friction feature and the rapid increase in friction during the starting stage. Under gas seal pressure conditions, the dwell time effect still led to a significant increase in friction force. The obtained results might provide guidance for the material selection of sealing designs.
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Open AccessArticle
Study on the Flow Field Distribution in Microfluidic Cells for Surface Plasmon Resonance Array Detection
by
Wanwan Chen, Jing Li, Peng Wang, Shuai Ma and Bin Li
Materials 2024, 17(10), 2426; https://doi.org/10.3390/ma17102426 - 17 May 2024
Abstract
This research is dedicated to optimizing the design of microfluidic cells to minimize mass transfer effects and ensure a uniform flow field distribution, which is essential for accurate SPR array detection. Employing finite element simulations, this study methodically explored the internal flow dynamics
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This research is dedicated to optimizing the design of microfluidic cells to minimize mass transfer effects and ensure a uniform flow field distribution, which is essential for accurate SPR array detection. Employing finite element simulations, this study methodically explored the internal flow dynamics within various microfluidic cell designs to assess the impact of different contact angles on flow uniformity. The cells, constructed from Polydimethylsiloxane (PDMS), were subjected to micro-particle image velocimetry to measure flow velocities in targeted sections. The results demonstrate that a contact angle of 135° achieves the most uniform flow distribution, significantly enhancing the capability for high-throughput array detection. While the experimental results generally corroborated the simulations, minor deviations were observed, likely due to fabrication inaccuracies. The microfluidic cells, evaluated using a custom-built SPR system, showed consistent repeatability.
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(This article belongs to the Section Materials Physics)
Open AccessArticle
Artificial Neuron Based on the Bloch-Point Domain Wall in Ferromagnetic Nanowires
by
Carlos Sánchez, Diego Caso and Farkhad G. Aliev
Materials 2024, 17(10), 2425; https://doi.org/10.3390/ma17102425 - 17 May 2024
Abstract
Nanomagnetism and spintronics are currently active areas of research, with one of the main goals being the creation of low-energy-consuming magnetic memories based on nanomagnet switching. These types of devices could also be implemented in neuromorphic computing by crafting artificial neurons (ANs) that
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Nanomagnetism and spintronics are currently active areas of research, with one of the main goals being the creation of low-energy-consuming magnetic memories based on nanomagnet switching. These types of devices could also be implemented in neuromorphic computing by crafting artificial neurons (ANs) that emulate the characteristics of biological neurons through the implementation of neuron models such as the widely used leaky integrate-and-fire (LIF) with a refractory period. In this study, we have carried out numerical simulations of a 120 nm diameter, 250 nm length ferromagnetic nanowire (NW) with the aim of exploring the design of an artificial neuron based on the creation and destruction of a Bloch-point domain wall. To replicate signal integration, we applied pulsed trains of spin currents to the opposite faces of the ferromagnetic NW. These pulsed currents (previously studied only in the continuous form) are responsible for inducing transitions between the stable single vortex (SV) state and the metastable Bloch point domain wall (BP-DW) state. To ensure the system exhibits leak and refractory properties, the NW was placed in a homogeneous magnetic field of the order of mT in the axial direction. The suggested configuration fulfills the requirements and characteristics of a biological neuron, potentially leading to the future creation of artificial neural networks (ANNs) based on reversible changes in the topology of magnetic NWs.
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(This article belongs to the Special Issue Nanowires: Growth and Applications)
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