The selective separation of CO
2 from gas mixtures representative of flue gas generated in waste incineration systems is studied on two activated carbons obtained from pine sawdust and compared to a commercial activated carbon. Dynamic adsorption experiments were conducted in a fixed-bed
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The selective separation of CO
2 from gas mixtures representative of flue gas generated in waste incineration systems is studied on two activated carbons obtained from pine sawdust and compared to a commercial activated carbon. Dynamic adsorption experiments were conducted in a fixed-bed adsorption column using a binary mixture (N
2/CO
2) with a composition representative of incineration streams at temperatures from 30 to 70 °C. The adsorption behavior of humid mixtures (N
2/CO
2/H
2O) was also evaluated in order to assess the influence of water vapor in CO
2 adsorption at different relative humidity in the feed gas: 22% and 60%. Moreover, CO
2 adsorption was studied in less favorable conditions, i.e., departing from a bed initially saturated with H
2O. In addition, the effect of CO
2 on H
2O adsorption was examined.
Experimental results showed that the CO
2 adsorption capacity can be reduced significantly by the adsorption of H
2O (up to 60% at high relative humidity conditions). On the other hand, the breakthrough tests over the adsorbent initially saturated with water vapor indicated that H
2O is little affected by CO
2 adsorption. The experimental results pointed out the biomass based carbons as best candidates for CO
2 separation under incineration flue gas conditions.
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