Metal Processing for Sustainability

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Extractive Metallurgy".

Deadline for manuscript submissions: 10 July 2024 | Viewed by 744

Special Issue Editor


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Guest Editor
Department of Mechanical & Materials Engineering, Worcester Polytechnic Institute, Worcester, MA, USA
Interests: high-temperature metal processing for sustainability; clean production; recycling of metals and for energy storage

Special Issue Information

Dear Colleagues,

I am pleased to invite you to contribute to a special issue of the journal Metals on metal processing for sustainability. As many of you know, open source and open access have been important to me throughout my career, so when invited I welcomed the opportunity to create a special issue in Metals which is completely open access.

This is a broad topic, covering areas from clean production of high-volume commodity metals such as steel, Al, Cr, Cu, Zn, Mn, Mg, etc; to scaling clean production of metals for new energy systems including silicon, rare earth, and battery materials; to energy storage inspired by metal processing such as liquid metal batteries.

This topic is inspired in part by the Reactive Metals Workshop (RMW), and I have met many of you through RMW. Whether you’re connected to the workshop or not, I look forward to seeing many of you in March at the first RMW in three years.

Dr. Adam C. Powell
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Metals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • metal processing
  • climate mitigation
  • greenhouse gases
  • primary production
  • metal recycling

Published Papers (1 paper)

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Research

21 pages, 14427 KiB  
Article
Aluminothermic Reduction Kinetics of Calcium Silicate Slag for Silicon Alloy Production
by Harald G. R. Philipson, Maria Wallin and Kristian Etienne Einarsrud
Metals 2024, 14(6), 604; https://doi.org/10.3390/met14060604 - 21 May 2024
Viewed by 362
Abstract
We investigated the reaction kinetics and initial chemical conditions in the production of silicon alloys, employing aluminum as the reductant for calcium silicate slag, to enhance process economics and scalability to industrial levels. The apparent kinetics and transient chemical conditions were studied by [...] Read more.
We investigated the reaction kinetics and initial chemical conditions in the production of silicon alloys, employing aluminum as the reductant for calcium silicate slag, to enhance process economics and scalability to industrial levels. The apparent kinetics and transient chemical conditions were studied by immersing solid aluminum into molten slag, allowing the reaction to proceed for varying durations without external agitation, before quenching the reaction for chemical and microscopic analyses of the resulting silicon alloy and slag. The majority of the conversion was observed within the first 15 s at 1650 °C, driven by significant chemical interactions and interfacial turbulence introduced upon aluminum immersion. For Al-SiO2 stoichiometries ranging from 0.5 to 1.2, the slag phase reaction conformed to first-order kinetics during the initial two minutes, when it approached equilibrium. The mass transfer coefficients for Al2O3 were estimated at 1–2 × 10−4 m/s, comparable to those for SiO2 and CaO. A constant mass transfer coefficient could not be established for stoichiometries of 1.6 and 2, as these deviated from the standard slag mass transfer relationship and did not adhere to established relationships. Despite near-complete reactions, alloy–slag mixing was extensive, decreasing with lower stoichiometry values. Full article
(This article belongs to the Special Issue Metal Processing for Sustainability)
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