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Short Note

Dibutyldichloro(1,10-phenanthroline-N1,N10)tin

by
Chun Hu
1,*,
Rihong Tan
2,
Jianping Wang
1,
Yu Ji
1 and
Shengfu Wang
1
1
Shenyang Pharmaceutical University, Shenyang 110015, P. R. China
2
Teachers' College of Shenyang University, Shenyang 110015, P. R. China
*
Author to whom correspondence should be addressed.
Molecules 2001, 6(3), M209; https://doi.org/10.3390/M209
Submission received: 5 May 2000 / Accepted: 21 February 2001 / Published: 25 March 2001
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
Versions Notes
Diorganotin dihalide complexes with bidentate nitrogen ligands exhibit some pharmaceutical activities such as antitumour activity, antiviral activity and anti-microbiological activity[1,2,3], we have synthesized some diorganotin dihalide complexes with bidentate nitrogen ligands, one of which is dibutyldichloro(1,10-phenanthroline-N1,N10)tin.
Molecules 06 m209 i001
A solution of dibutyltin dichloride (1.22 g, 4 mmol) in benzene (20 ml) was added to a solution of 1,10-phenanthroline (0.72 g, 4 mmol) in benzene (20 ml). The mixture was refluxed for 4 h, the solid that appeared upon cooling was filtered and recrystallized from absolute ethanol to give the title compound as white crystal (1.82 g, 94%).
M.p. 190-193°C.
IR(KBr): 1620 (C=N), 1574, 1514 (C=C), 850 (C-H), 624, 594 (Sn-C).
1H-NMR(CDCl3, 250 MHz): 9.82 (dd, 2H, H-2 in aromatic ring), 8.71 (dd, 2H, H-4), 8.14 (s, 2H, H-5), 8.03 (dd, 2H, H-3), 1.60 (m, 4H, 2CH2), 1.38 (m, 4H, 2CH2), 1.06 (m, 4H, 2CH2), 0.62 (t, 6H, 2CH3).
Anal. cacl. for C20H26Cl2N2Sn (394.81): C 49.63, H 5.41, N 5.79; found: C 49.45, H 5.70, N 5.84.

Supplementary materials

Supplementary File 1Supplementary File 2

References

  1. Crowe, A.J.; Smith, P.J.; Atassi, G. Chem. Biol. Interact. 1980, 32, 171–178. [PubMed]
  2. Ward, S.G.; Taylor, R.C.; Crowe, A.J.; Balzarini, J.; De Clercq, E. Appl. Organomet. Chem. 1989, 3, 431–436.
  3. Hu, C.; Wang, S.; Tan, R. J. Shenyang Pharm. Univ. 1990, 7, 111–114.
  • Sample Availability: available from authors and MDPI, MDPI Reg. No.1204.

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MDPI and ACS Style

Hu, C.; Tan, R.; Wang, J.; Ji, Y.; Wang, S. Dibutyldichloro(1,10-phenanthroline-N1,N10)tin. Molecules 2001, 6, M209. https://doi.org/10.3390/M209

AMA Style

Hu C, Tan R, Wang J, Ji Y, Wang S. Dibutyldichloro(1,10-phenanthroline-N1,N10)tin. Molecules. 2001; 6(3):M209. https://doi.org/10.3390/M209

Chicago/Turabian Style

Hu, Chun, Rihong Tan, Jianping Wang, Yu Ji, and Shengfu Wang. 2001. "Dibutyldichloro(1,10-phenanthroline-N1,N10)tin" Molecules 6, no. 3: M209. https://doi.org/10.3390/M209

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