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Molecules 2002, 7(2), 189-199; doi:10.3390/70200189

Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors

College of Chemistry, Isfahan University of Technology, Isfahan, I.R. Iran
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Received: 12 November 2001 / Revised: 5 February 2002 / Accepted: 5 February 2002 / Published: 28 February 2002
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Abstract

The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N3, (Ar = p-NO2-C6H4-, p-Br-C6H4-, p-Cl-C6H4-, p-C6H5-, p-CH3-C6H4-, 2,4-dimethyl-C6H3-, 2,4,6-trimethyl-C6H2-, p-CH3O-C6H4- and Z = p-CH3-C6H4-SO2-, 2,4,6-trimethyl-C6H2-SO2-,CN) in the solid phase and in anisole has been studied in detail. The sensitivity of nitrenes and nitrene precursors (imidoyl azides) towards substitution changes in the aryloxy (ArO) and Z moieties is examined. View Full-Text
Keywords: Imidoyl azides; Imidoylnitrenes; Reactivity; Selectivity Imidoyl azides; Imidoylnitrenes; Reactivity; Selectivity
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Dabbagh, H.A.; Karimzadeh, R. Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors. Molecules 2002, 7, 189-199.

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