Next Article in Journal
Chemical Sensors – from Molecules, Complex Mixtures to Cells – Supramolecular Imprinting Strategies
Previous Article in Journal
A Novel Hydrogen Peroxide Sensor via the Direct Electrochemistry of Horseradish Peroxidase Immobilized on Colloidal Gold Modified Screen-printed Electrode
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Flow injection amperometric determination of persulfate in cosmetic products using a Prussian Blue film-modified electrode

Departameno de Quimica Analitica, Universidade Estadual Paulista, 14800-900, PO Box 355, Araraquara-SP, Brasil
*
Author to whom correspondence should be addressed.
Sensors 2003, 3(9), 371-380; https://doi.org/10.3390/s30900371
Submission received: 2 June 2003 / Accepted: 28 July 2003 / Published: 11 September 2003

Abstract

:
A flow-injection system with a glassy carbon disk electrode modified with Prussian Blue film is proposed for the determination of persulfate in commercial samples of hair bleaching boosters by amperometry. The detection was obtained by chronoamperometric technique and the sample is injected into the electrochemical cell in a wall jet configuration.
Potassium chloride at concentration of 0.1 mol L-1 acted as sample carrier at a flow rate of 4.0 mL min-1 and supporting-electrolyte.
For 0.025 V (vs. Ag/AgCl) applied voltage, the proposed system handles ca. 160 samples per hour (1.0 10-4 -1.0 10-3 mol L-1 of persulfate), consuming about 200 µL sample and 11 mg KCl per determination. Typical linear correlations between electrocatalytic current and persulfate concentration was ca. 0.9998. The detection limit is 9.0 10-5 mol L-1 and the calculated amperometric sensibility 3.6 103 µA L mol-1. Relative standard deviation (n =12) of a 1.0 10-4 mol L-1 sample is about 2.2%. The method was applied to persulfate determination in commercial hair-bleaching samples and results are in agreement with those obtained by titrimetry at 95% confidence level and good recoveries (95 -112%) of spiked samples were found.

Introduction

Chemical deposition of electroative species in inert solid electrodes has been used to produce electrochemical sensors for different types of samples and analytes [1,2]. Modified electrodes are widely used sensors due to simplicity, high selectivity and sensitivity and relative low cost [3]. When electrochemical catalysis is present, a significant reduction in activation overpotential occurs and a less prone of surface contamination and oxide formation in comparison to inert electrodes [4]. Several methods have been described for electrode modification such as addition of redox polymers [5], ion-exchange polymers [6], clays [7], metal cyanometallates [8] and metal oxides [9].
Figure 1. Flow diagram of the system for persulfate determination. IC: injector-commutator; S: sample or analytical solution (2.5 ml min-1); C: sample carrier stream (4 ml min-1); L: sampling loop (200 µl); W: waste; B: coiled reactor (100 cm); WE: working electrode (PB-modified glassy carbon); RE: reference electrode (Ag/AgCl); AE: auxiliary electrode (platinum tube).
Figure 1. Flow diagram of the system for persulfate determination. IC: injector-commutator; S: sample or analytical solution (2.5 ml min-1); C: sample carrier stream (4 ml min-1); L: sampling loop (200 µl); W: waste; B: coiled reactor (100 cm); WE: working electrode (PB-modified glassy carbon); RE: reference electrode (Ag/AgCl); AE: auxiliary electrode (platinum tube).
Sensors 03 00371 g001
Prussian Blue (PB) [iron(III) hexacyanoferrate(II)] modified electrodes have been used for the determination of several organic and inorganic compounds [10,11,12,13,14,15,16,17,18,19] due to its high stability, operation under highly reproducible conditions, user friendly, simple preparation and applicability to different workable samples.
Electrocatalytic effect in the reduction of persulfate (peroxodissulfate) anions on PB modified carbon paste electrodes has been presented by Weissenbacher and co-workers [20]. By using direct current voltammetric measurements, the reduction reaction of persulfate is supposed to yield the corresponding PB complex of Fe(III) and the sulfate anions:
S2O82- + 2 [FeIIFeII(CN)6]2- → 2 SO42- + 2 [FeIIIFeII(CN)6]2-
This catalytic property has allowed the application of PB as a modifier substrate for different electrodes for persulfate determination. An example of PB carbon paste-modified electrode can be obtained by mechanical mix of graphite powder and substrate for persulfate analysis [20]. Afterwards, a PB film-modified electrode was obtained by electrochemical deposition of this film in platinum disk electrode [21], exhibiting a better mechanical stability in relation to carbon paste and easiness of preparation. These sensors were used for voltammetric determinations of persulfate anions in commercial samples, using conventional electrochemical cells and exhibiting good agreement with titrimetry.
Flow-injection analysis (FIA) is attractive for procedures involving electrochemical detection due to their operation under highly reproducible conditions [22,23].
A manual procedure has been proposed for persulfate determination using PB modified electrode [21], but its applicability to routine analysis in large scale is seriously limited by the time and reagent consumption. Little attention has been given for the use of electrode modified by PB film and wall jet configuration electrochemical cell for automated determination of persulfate.
This study reports on a flow injection amperometric procedure for the determination of persulfate in real samples by using glassy carbon disk electrode modified by PB film and an wall jet configuration electrochemical cell. The performance of the proposed procedure was checked after analyzing commercial hair bleach booster samples.

Experimental

Reagents, analytical solutions and samples

All solutions were prepared with high-purity chemicals and distilled-deionized water.
Potassium chloride stock standard solution (0.1 mol L-1) was prepared by dissolving appropriate amount of KCl in water. This solution was used as supporting-electrolite for voltammetric measurements and also used as sample carrier stream (C, Fig. 1).
Iron(III) stock standard solution (FeCl3 0.01 mol L-1) and hexacyanoferrate(III) stock standard solution (K3[Fe(CN6)] 0.01 mol L-1) were prepared by dissolving respective salts in appropriate amounts of the previously prepared KCl standard solution (0.1 mol L-1) in order to prevent dilution effect of the supporting-electrolite.
Persulfate working standards (1.00 10-4 -10.0 10-4 mol L-1 K2S2O8) were prepared by appropriate dilution of the stock solution in previously deaerated 0.1 mol L-1 KCl.
Hair bleach booster samples were purchased at a local super market. A mass of 250 mg of each sample was dissolved in about 200 mL 0.1 mol L-1 KCl solution and acidified with 1.0 mol L-1 HCl until pH 7 in order to eliminate alkaline substances as carbonates. Thereafter the volume was completed to 1000 mL with KCl solution. The final solution should be deaired for 15 minutes before injection in the FIA system. Further dilutions can be necessary for some sample lots to match the analyte concentration to those of calibration curve.

The flow injection system

The system comprised a IPC-8 Ismatec peristaltic pump furnished with Tygon® pumping tubes, an injector-commutators (IC), a 173 Princeton Applied Research potentiostat interfaced through a 273 Princeton Applied Research electrochemical software, polyethylene tubing (i.d. 0.7 mm), coiled reactors and accessories. A conventional three-electrode cell was employed with a glassy carbon disk electrode (0.25 cm2) as working electrode, an Ag/AgCl reference electrode and a platinum plate as auxiliary electrode.
The flow diagram of the system is shown in Fig. 1. In the position specified of the figure, a sample (S) volume of 200 µL is selected by the sampling loop L. After loop-based injection, the established sample zone passes through the electrochemical cell in where persulfate is reduced to sulfate. A transient current is recorded as a peak with height proportional to the persulfate content in the sample. After peak maximum measurement, the injector-commutator is switched back and another cycle can be started.
Concentration of persulfate, sample volume, flow-rate and applied potencial were investigated in order to optimize the system stability, sensitivity and sampling rate.

Procedure

Glassy carbon disk electrode (0.25 cm2) was polished to a mirror finish with alumina (0.03 μm), then rinsed thoroughly with water, cleaned in an ultrasonic bath with water and finally rinsed with water before using. The formation of Prussian Blue film on the glassy carbon disk surface (0.25 cm2) was obtained by immerging the electrode in an oxygen-free solution containing 0.1 mol L-1 KCl plus 1 mmol L-1 FeCl3 plus 1mmol L-1 K3Fe(CN)63- and by repetitive potential cycling within - 0.2 and + 0.6 V vs. Ag/AgCl, at a scan rate of 0.010 V s-1. After film formation, the electrode was rinsed with deionised water. The resulting modified electrode was cycled in 0.1 mol L-1 KCl within the - 0.1 and + 0.5 V range (vs. Ag/AgCl) at a scan rate of 100 mV s-1 in order to verify the film stability for use in further experiments. A steady current-voltage profile was attained after at least 10 cycles.
Cyclic voltammograms at 0.100 V s-1 in different medium were carried out in order to verify the electrochemical catalysis of persulfate reduction: PB film; 0.1 mol L-1 KCl solution; 0.1 mol L-1 KCl plus 1.0 10-3 mol L-1 persulfate solution; 0.1 mol L-1 KCl plus 1.0 10-3 mol L-1 persulfate solution at PB modified electrode.
The optimum potential for amperommetric measurements at he PB film was obtained by means of hydrodynamic voltammograms. The voltage was varied from 0 to 0.150 V vs. Ag/AgCl and the sample carrier was a 0.1 mol L-1 KCl solution (C, Fig. 1) flowing at 4.0 ml min-1. The concentration and volume of persulfate solution were 2.0 10-4 mol L-1 and 200 μL, respectively.
The influence of the sample carrier stream on signal and sampling rate was investigated by varying the rotation speed of the peristaltic pump in order to obtain different flow rates (0.5 - 5.0 mL min-1) for the channel C. The influence of sample volume was studied in the range of 40 – 400 μL by varying the length of loop L from 10 to 100 cm, respectively.
The electrocatalytic determination of persulfate at the Prussian Blue modified electrode was obtained by chronoamperometry, being measured the current variation according to addition of standard solutions by the commutator trough the flow cell. Calibration curves were drown in order to verify the linear response interval for persulfate determination. All measurements were done in triplicate, and precision was evaluated after twelve sucessive injections of an analytical solution (1.0 10-4 mol L-1) in the flow system. The concentration of analyte was determined by interpolation of current values in the calibration curve.

Results and discussion

Prussian blue film formation

The electrodeposition of Prussian Blue at the glassy carbon surface is reported at Figure 2, where the 5 first cycles are shown. After complete film formation (10 cycles) the surface coverage was calculated in 1.3x10-8 mol.cm-2 by integratting the curve current vs. time. The initial reduction process of brown-yellow soluble complex (PX) [(iron(III) hexacyanoferrate(III)] in the insoluble Prussian Blue (PB) forms consist in one electron transfer process:
Sensors 03 00371 i001
Subsequently, the reduction of PB yields to the Prussian White (PW) form [3] in an also one electron process, whose this latter redox process was applied in this work:
Sensors 03 00371 i002
Stability study for PB-modified in supporting-electrolite was carried out for 20 cycles of potential to the PB/PW redox couple, with no loss of charge observed.
Figure 2. Prussian Blue film formation. Supporting-electrolyte: 0.1 mol L-1 KCl solution; area of the glassy carbon disk electrode: 0.25 cm2; number of cycles: first 5; scan rate: 100 mV s-1.
Figure 2. Prussian Blue film formation. Supporting-electrolyte: 0.1 mol L-1 KCl solution; area of the glassy carbon disk electrode: 0.25 cm2; number of cycles: first 5; scan rate: 100 mV s-1.
Sensors 03 00371 g002

Electrocatalysis of persulfate reduction

Shown in Fig. 3 are voltammograms for supporting-electrolite (curve a), persulfate reduction at glassy carbon (curve b), Prussian Blue modified electrode (curve c) and persulfate reduction at the modified electrode (curve d). A shift of 700 mV to more positive potential in the persulfate reduction is observed, being decreased the overpotential in relation of solid electrodes. Additionally, an increasing of 10 times at the reduction peak current is obtained for persulfate at modified Prussian Blue electrode, showing up catalysis effect. The increase in cathodic peak current is linear and proportional to the concentration of added persulfate, corresponding to the reduction of Fe(CN)63- to Fe(CN)64- of the Prussian Blue film (curve d).
Figure 3. Cyclic voltammograms of the PB fil-modified electrode. Curves correspond to measurements in 0.1 mol L-1 KCl (a), 1.0 10-3 mol L-1 persulfate in 0.1 mol L-1 KCl at glassy carbon electrode (b), Prussian Blue film at supporting-electrolyte (c) and 5.0 10-4 mol L-1 persulfate plus 0.1 mol L-1 KCl at Prussian Blue-modified electrode (d). The scan rate was 100 mV s-1.
Figure 3. Cyclic voltammograms of the PB fil-modified electrode. Curves correspond to measurements in 0.1 mol L-1 KCl (a), 1.0 10-3 mol L-1 persulfate in 0.1 mol L-1 KCl at glassy carbon electrode (b), Prussian Blue film at supporting-electrolyte (c) and 5.0 10-4 mol L-1 persulfate plus 0.1 mol L-1 KCl at Prussian Blue-modified electrode (d). The scan rate was 100 mV s-1.
Sensors 03 00371 g003

Flow-injection amperometric detection of persulfate

Electrocatalytic reduction current for persulfate at modified electrode was applied in FIA system. To determine the optimum potential for amperommetric measurements with the Prussian Blue film, hydrodynamic voltammograms were obtained. Figure 4 shows a plot of current vs. applied potential for the reduction of 2.0 10-4 mol L-1 persulfate solution at the modified electrode, where a maximum amperommetric response was obtained for a potential value of 0.025 V vs. Ag/AgCl. The current decrease at potentials higher than 0.025 V can be attributed to the irreversible passivation of the electrocatalyst at potentials high enough to reduce persulfate anions. Consequently, in subsequent experiments with this electrochemical detector, a value of 0.025 V was selected for the detection potential of persulfate at Prussian Blue film.
Figure 4. Hydrodynamic voltammogram for the reduction of persulfate. Curve correspond to 2.0 10-4 mol L-1 persulfate solution at Prussian Blue modified electrode; carrier C: 0.1 mol L-1 KCl (4.0 mL min-1); sampling loop L: 200 μL.
Figure 4. Hydrodynamic voltammogram for the reduction of persulfate. Curve correspond to 2.0 10-4 mol L-1 persulfate solution at Prussian Blue modified electrode; carrier C: 0.1 mol L-1 KCl (4.0 mL min-1); sampling loop L: 200 μL.
Sensors 03 00371 g004
The influence of flow rate of carrier C on peak profile and sampling rate was investigated within the 0.5 - 5.0 mL min-1 interval. For flow rates < 1.6 mL min-1, peaks for 2.0 10-4 mol L-1 persulfate were broadened, the sampling rate was low and the sensitivity unsatisfactory. When the flow rates increased from to 1.6 to 4 ml min-1, the signal profile improved and peak heights increased linearly. Flow rates > 4.0 ml min-1 resulted in solution leakage at the inlet of the electrochemical cell. As a compromise between system stability, sensitivity and sampling rate, 4.0 ml min-1 was selected.
In the study of the injected volume on transient signals in the 40 - 400 µL volume range, peak heights increased linearly with the volume of the sample injected into the FIA system from 40 to 200 µL. For higher injected volume samples the transient signal reached a constant value. The best sensitivity was attained with 200 µL {I= 4.1 10-9 + 2.5 10-5[persulfate]}, the volume selected for subsequent experiments.
After all parameters had been chosen, analytical solutions within the 0.1 - 1.0 10-3 mol L-1 persulfate concentration range were injected in triplicate and calibration curves with good linearity were consistently obtained (R= 0.9998), with an amperommetric sensibility of 3.6x103 µA.L.mol-1. The detection limit of this method was 9.0 10-5 mol L-1. The transient peaks of a typical calibration curve are depicted in Fig. 5. Accuracy was assessed by analyzing two commercial samples of hair bleaching boosters (Table 1). The results obtained with the proposed procedure were not statistically
Table 1. Comparative results. Results (n = 3) for persulfate [as mg/g] in cosmetic samples as determined by the proposed FIA system and by titrimetry [25]. For experimental conditions, see Fig. 5
Table 1. Comparative results. Results (n = 3) for persulfate [as mg/g] in cosmetic samples as determined by the proposed FIA system and by titrimetry [25]. For experimental conditions, see Fig. 5
Sample*FIATitrimetry
280274 ± 9267 ± 12
280275 ± 8269 ± 13
* labeled by manufacturer and expressed as mg/g
Figure 5:. Recorded peaks for persulfate determination. From left to right, each set of triplicate corresponds sample #1, sample #2, and five working standard solutions (0.1 mmol L-1, 0.2 mmol L-1, 0.5 mmol L-1, 0.8 mmol L-1 and 1.0 mmol L-1, respectively. L: 200 mL; C: 0.1 mol L-1 KCl at 4.0 mL min-1; applied potential: 0.025 V (vs. Ag/AgCl).
Figure 5:. Recorded peaks for persulfate determination. From left to right, each set of triplicate corresponds sample #1, sample #2, and five working standard solutions (0.1 mmol L-1, 0.2 mmol L-1, 0.5 mmol L-1, 0.8 mmol L-1 and 1.0 mmol L-1, respectively. L: 200 mL; C: 0.1 mol L-1 KCl at 4.0 mL min-1; applied potential: 0.025 V (vs. Ag/AgCl).
Sensors 03 00371 g005
different from those obtained by titrimetry and from those labeled values by the manufacturer at 95% confidence level (t-test). The system handles up to 160 samples to be examined per hour, requires about 11 mg KCl and 200 µL sample consumed per determination. The relative standard deviation was estimated as ≤ 3.4% for 0.5 mmol L-1 persulfate solution after twelve successive injections.

Conclusions

Modified electrodes by Prussian Blue films function as amperommetric sensors for persulfate ions as much as they present electrocatalytical activity, with an increase on the anodic current of the film, which occurs in a potential value lower than the overpotential of reduction of this ion without the film, in the same experimental conditions. The modified electrode can be applied in FIA systems as an amperommetric sensor for persulfate ions in a concentration range from 1.0 10-4 to 1.0 10-3 mol.L-1, exhibiting a linear peak current variation, with a linear correlation coefficient of 0.9998 and a detection limit of 9.0 10-5 mol.L-1. Due to its electrocathalytical property, high analytical frequency and good accuracy, this methodology allows the employment of Prussian Blue-glassy carbon modified electrodes in flow injection systems for analysis of persulfate concentration in hair bleaching commercial products in large scale.

Acknowledgments

The authors thank the FAPESP, CAPES and CNPq for financial support.

References

  1. Wing, S.A.; Hart, J.P. Chemically modified, carbon-based electrodes and their application as electrochemical sensors for the analysis of biologically important compounds – a review. Analyst 1992, 117, 1215–1229. [Google Scholar]
  2. Gilmartin, M.A.T.; Hart, J.P. Sensing with chemically and biologically modified carbon electrodes. Analyst 1995, 120, 1029–1045. [Google Scholar] [CrossRef]
  3. Mortimer, R.J.; Rosseinsky, D.R. Electrochemical polychromicity in iron hexacyanoferrate films, and a new film form of ferric ferricyanide. J. Electroanal. Chem. 1983, 151, 133–147. [Google Scholar] [CrossRef]
  4. Pan, K.C.; Chuang, C.S.; Cheng, S.H.; Su, Y.O. Electrocatalytic reactions of nitric oxide on Prussian blue film modified electrodes. J. Electroanal. Chem., 2001, 501, 160–165. [Google Scholar] [CrossRef]
  5. Lu, W.; Wallace, G.G.; Karayakin, A.A. Use of Prussian Blue conducting polymer modified electrodes for the detection of cytochrome c. Electroanalysis 1998, 10, 472–476. [Google Scholar] [CrossRef]
  6. Komplin, G.C.; Pietro, W.J. Redox coenzyme functionalization of electrochemically grown Prussian Blue films. Sensors and Actuators B-Chem. 1996, 30, 173–178. [Google Scholar] [CrossRef]
  7. Scharf, U.; Grabner, E.W. Electrocatalytic oxidation of hydrazine at a Prussian Blue-modified glassy carbon electrode. Electrochim. Acta 1996, 41, 233–239. [Google Scholar] [CrossRef]
  8. Chi, Q.J.; Dong, S.J. Amperometric biosensors based on the immobilization of oxidases in a Prussian Blue film by electrochemical codeposition. Anal. Chim. Acta 1995, 310, 429–436. [Google Scholar] [CrossRef]
  9. Hou, W.Y.; Wang, E. Flow-injection amperometric detection of hydrazine by electrocatalytic oxidation at a Prussian Blue film-modified electrode. Anal. Chim. Acta 1992, 257, 275–280. [Google Scholar] [CrossRef]
  10. Dong, S.J.; Che, G.L. Electrocatalytic oxidation of ascorbic-acid at a Prussian Blue film modified microdisk electrode. J. Electroanal. Chem. 1991, 315, 191–199. [Google Scholar] [CrossRef]
  11. Karyakin, A.A.; Karyakina, E.E.; Gorton, L. The electrocatalytic activity of Prussian Blue in hydrogen peroxide reduction studied using a wall-jet electrode with continuous flow. J. Electroanal. Chem., 1998, 456, 97–104. [Google Scholar] [CrossRef]
  12. Karyakin, A.A.; Karyakina, E.E. Prussian Blue-based 'artificial peroxidase' as a transducer for hydrogen peroxide detection. Application to biosensors. Sensors and Actuators B-Chem. 1999, 57, 268–273. [Google Scholar] [CrossRef]
  13. Sotomayor, M.D.; Kubota, L.T. Enzymeless biosensors: A novel area for the development of amperometric sensors. Quim. Nova 2002, 25, 123–128. [Google Scholar]
  14. Wu, X.Q.; Guo, X.M.; Wang, R.; Zhang, Z.R. Cholesterol biosensor based on platinium electrode modified by Prussian blue. Chinese J. Anal. Chem. 2001, 29, 1273–1275. [Google Scholar]
  15. Kulesza, P.J.; Miecznikowski, K.; Malik, M.A.; Galkowski, M.; Chojak, M.; Caban, K.; Wieckowski, A. Electrochemical preparation and characterization of hybrid films composed of Prussian blue type metal hexacyanoferrate and conducting polymer. Electrochim. Acta 2001, 46, 4065–4073. [Google Scholar] [CrossRef]
  16. Lenarczuk, T.; Wencel, D.; Glab, S.; Glab, S.; Koncki, R. Prussian blue-based optical glucose biosensor in flow-injection analysis. Anal. Chim. Acta 2001, 447, 23–32. [Google Scholar] [CrossRef]
  17. Thompson, D.F.; Church, C.O. Prussian blue for treatment of radiocesium poisoning. Pharmacotherapy 2001, 21, 1364–1367. [Google Scholar] [CrossRef]
  18. Liu, J.F.; Jiang, G.B. Spectrophotometric flow injection determination of total reducing sugars in tobacco based on oxidation by ferricyanide and formation of Prussian blue. Anal. Lett. 2001, 34, 1923–1934. [Google Scholar]
  19. O'Halloran, M.P.; Pravda, M.; Guilbault, G.G. Prussian Blue bulk modified screen-printed electrodes for H2O2 detection and for biosensors. Talanta 2001, 55, 605–611. [Google Scholar] [CrossRef]
  20. Weissenbacher, M.; Kalcher, K.; Greschonig, H.; Ng, W.; Chan, W.H.; Vougaropoulos, A. Electrochemical behaviour of persulfate on carbon paste electrodes modified with Prussian Blue and analogous compounds. Fres. J. Anal. Chem. 1992, 344, 87–92. [Google Scholar]
  21. Oliveira, M.F.; Mortimer, R.J.; Stradiotto, N.R. Voltammetric determination of persulfate anions using an electrode modified with a Prussian blue film. Microchem. J. 2000, 64, 155–159. [Google Scholar] [CrossRef]
  22. Ruzicka, J.; Hansen, E.H. Flow Injection Analysis. Wiley: New York, 1988; pp. 498–507. [Google Scholar]
  23. Castro, S.S.L.; Balbo, V.R.; Barbeira, P.J.S.; Stradiotto, N.R. Flow injection amperometric detection of ascorbic acid using a Prussian Blue film-modified electrode. Talanta 2001, 55, 249–254. [Google Scholar] [CrossRef]
  • Sample Availability: Available from the authors.

Share and Cite

MDPI and ACS Style

Oliveira, M.F.D.; Saczk, A.A.; Neto, J.A.G.; Roldan, P.S.; Stradiotto, N.R. Flow injection amperometric determination of persulfate in cosmetic products using a Prussian Blue film-modified electrode. Sensors 2003, 3, 371-380. https://doi.org/10.3390/s30900371

AMA Style

Oliveira MFD, Saczk AA, Neto JAG, Roldan PS, Stradiotto NR. Flow injection amperometric determination of persulfate in cosmetic products using a Prussian Blue film-modified electrode. Sensors. 2003; 3(9):371-380. https://doi.org/10.3390/s30900371

Chicago/Turabian Style

Oliveira, Marcelo F. De, Adelir A. Saczk, Jose A. Gomes Neto, Paulo S. Roldan, and Nelson R. Stradiotto. 2003. "Flow injection amperometric determination of persulfate in cosmetic products using a Prussian Blue film-modified electrode" Sensors 3, no. 9: 371-380. https://doi.org/10.3390/s30900371

Article Metrics

Back to TopTop