Table of Contents
Crystals, Volume 8, Issue 6 (June 2018)
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Cover Story (view full-size image) Multinary transition metal nitrides and nitridometalates constitute a fairly unexplored family that [...] Read more. Multinary transition metal nitrides and nitridometalates constitute a fairly unexplored family that offers rich structural and chemical versatility. The crystal structure of the novel barium nitridomanganate Ba4[Mn3N6] bears corrugated chains of edge-shared [MnN4] tetrahedra. The Mn atoms along the chains develop a charge order with the unusual coexistence of Mn2+ and Mn4+. A combination of strong intrachain exchange interactions between the Mn centers and weak interchain coupling makes this material a quasi-one-dimensional magnet. View this paper