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Article

The Cu II Spectrum

National Institute of Standards and Technology, Gaithersburg, MD 20899, USA
*
Author to whom correspondence should be addressed.
Submission received: 16 December 2016 / Revised: 7 February 2017 / Accepted: 8 February 2017 / Published: 24 February 2017
(This article belongs to the Special Issue Spectra of Ionized Atoms: From Laboratory to Space)

Abstract

:
New wavelength measurements in the vacuum ultraviolet (VUV), ultraviolet and visible spectral regions have been combined with available literature data to refine and extend the description of the spectrum of singly ionized copper (Cu II). In the VUV region, we measured 401 lines using a concave grating spectrograph and photographic plates. In the UV and visible regions, we measured 276 lines using a Fourier-transform spectrometer. These new measurements were combined with previously unpublished data from the thesis of Ross, with accurate VUV grating measurements of Kaufman and Ward, and with less accurate older measurements of Shenstone to construct a comprehensive list of ≈2440 observed lines, from which we derived a revised set of 379 optimized energy levels, complemented with 89 additional levels obtained using series formulas. Among the 379 experimental levels, 29 are new. Intensities of all lines observed in different experiments have been reduced to the same uniform scale by using newly calculated transition probabilities (A-values). We combined our calculations with published measured and calculated A-values to provide a set of 555 critically evaluated transition probabilities with estimated uncertainties, 162 of which are less than 20%.

1. Introduction

The spectrum of singly ionized copper, belonging to the Ni isoelectronic sequence, has a long history of research. The most significant contributions to the analysis were made by Shenstone [1] in 1936 and by Ross [2] in 1969. Interest in this spectrum was mainly due to the fact that it has a large number of sharp distinct lines in the vacuum ultraviolet (VUV) region, as well as an equally large number of lines in the ultraviolet (UV), visible, and infrared (IR) regions, from which accurate wavelengths of the VUV lines can be established using the Ritz combination principle, thus providing a large set of lines usable as secondary VUV wavelength standards. This spectrum is also of considerable interest for astrophysics. Lines of Cu II were observed in the spectra of nebulae by Thackeray [3], Aller et al. [4], McKenna et al. [5], and by Wallerstein et al. [6], and also in interstellar H I clouds, as well as in Ap, Be, and Bp stars (Jaschek, and Jaschek [7], Danezis and Theodossiou [8]) and in the Sun (Samain [9]). Cu+ was successfully used as an active lasing medium in various hollow cathodes. Continuous-wave or pulsed lasing has been reported for 28 lines of Cu II in a wide range from UV to IR (McNeil et al. [10,11], Jain [12], Zinchenko and Ivanov [13]). Since copper is an important impurity in tokamaks, the Cu II spectrum has potential applications in fusion research, where its lines can be used for diagnostic purposes.
For several decades after the original analysis by Shenstone [1] the VUV wavelengths of Cu II calculated from the energy levels (i.e., Ritz wavelengths) were widely used as auxiliary wavelength standards. After the refinements of the measured UV wavelengths by Reader et al. [14] and by Kaufman and Ward [15], and after improved and greatly extended measurements by Ross [2] in the UV and visible ranges, the quality of the VUV Ritz wavelengths of Cu II seemed to be so good that no further investigations of this spectrum were needed. The only inconvenience stemmed from the fact that Ross’s thesis [2] was never published, although a large part of it was released with small modifications as a report of the Los Alamos National Laboratory, see Ross [16]. Energy levels and a few strongest lines from Ross [2] were included in the compilations by Sugar and Musgrove [17] and by Sansonetti and Martin [18], but the bulk of the wavelength and line intensity data remains nearly inaccessible. Thus, the initial goal of the present work was simply to digitize Ross’s line lists and include them in the Atomic Spectra Database (ASD; see Kramida et al. [19]) of the National Institute of Standards and Technology (NIST) with consistent energy-level identifications. However, a close examination revealed several problems with Ross’s data.
The first problem is with internal consistency of Ross’s data. An important aspect of ASD is that it requires the observed wavelengths for an atom to be consistent with the energy levels tabulated for that atom. That is, the wavelengths derived from the energy levels (Ritz wavelengths) must agree with the observed wavelengths to within the stated uncertainties. However, in attempting to incorporate the data of Ross into ASD, we found that for a large number of lines the differences between observed and Ritz wavelengths were much greater than the uncertainties. We decided that, because of the importance of Ritz wavelengths for Cu II, this had to be investigated.
The second problem with Ross’s data is the possible presence of systematic shifts in his wavelengths. Nave and Sansonetti [20] showed that Ritz wavelengths below 2400 Å (41667 cm−1) derived from Ross’s Cu II energy levels are systematically too low, the mean relative deviation being about 4 × 10−7. This error is significantly greater than the average relative uncertainty of Ritz wavenumbers given by Ross, 1.2 × 10−7. Near 2000 Å (50000 cm−1), it corresponds to an error of 0.02 cm−1, compared to the mean stated uncertainty of 0.006 cm−1. This puts the usability of Ross’s Ritz wavenumbers in the VUV into question.
The third problem is the absence of a consistent description of line intensities throughout the entire range of observed wavelengths. While Ross’s own measurements cover the large range above 1980 Å, most of the observed intensities in the VUV region are furnished by old measurements of Shenstone [1], which were made with seven different instruments and with two different light sources. Additional measurements for some selections of strongest lines were made by Reader et al. [14] and by Kaufman and Ward [15], each with their own intensity scale.
Finally, Ross’s theoretical interpretation of the energy levels, adopted by Sugar and Musgrove [17] and by Sansonetti and Martin [18], is inadequate. Ross used the LS coupling scheme in his analysis, as well as in his final level list. However, the observed fine-structure intervals indicate that the level structure of most configurations is best described by the J1l (a.k.a. JK) coupling scheme, similar to the isoelectronic Ni I spectrum interpreted by Litzén et al. [21].
Another problem that needs to be addressed is the scarcity of available critically evaluated data on radiative transition probabilities (A-values). At present, the NIST ASD [19] includes only seven A-values of Cu II from the compilation of Wiese and Martin [22]. All of them have large estimated uncertainties (≤40% for six transitions and ≤50% for one transition).
The main purpose of the present work is to solve the above-mentioned problems and construct a self-consistent set of recommended energy levels and wavelengths of Cu II supplemented with a uniform description of line intensities. Re-interpretation of the energy levels, as well as the search for possible classifications of previously unidentified lines, required new calculations, which necessarily produce radiative transition probabilities (A-values). Thus, we also critically evaluate all available data on A-values and extend them with our calculated ones found to be of sufficiently good accuracy.
The usability of the Cu II wavelengths as standards is limited by substantial hyperfine structure (HFS) splitting and presence of two stable isotopes, 63Cu (69.15%) and 65Cu (30.85%) in natural copper (Coursey et al. [23]). HFS and isotope shifts (IS) of a few tens of Cu II lines between 2218 Å and 8096 Å were first observed and roughly estimated by Shenstone [1] and then more accurately investigated by Elbel et al. [24,25]. The measured IS was in the range (0.001 to 0.101) cm−1. For singly-excited 3d9nl configurations the IS is smaller than 0.05 cm−1, while for the doubly-excited 4d84s2 configuration it is about 0.1 cm−1. The HFS constants Ahfs for several [3d9]4s, 4p, 4d, 5s, 5p, 5d, 6s and [3d8]4s2 and 4s5p levels were found to range from 0.022 cm−1 to 0.075 cm−1 except for one level, 3d94s 3D1, having a very small Ahfs = −0.004 cm−1. The nuclear spin I of both 63Cu and 65Cu is I = 3/2 [18]. Thus, depending on the total angular momentum J of the levels, the width of the HFS varies between 0.016 cm−1 and 0.5 cm−1. The ionization energy of Cu+ is 163669.2 cm−1 (20.292 39 eV) (Ross [2]). Thus, excitation of this spectrum requires temperatures in excess of 6000 K (0.5 eV). Such temperatures lead to Doppler broadening ΔσDop/σ > 4 × 10−6, resulting in line widths >0.4 cm−1 at wavelengths near 1000 Å, 0.2 cm−1 near 2000 Å, and 0.1 cm−1 near 4000 Å. As a result, most observed lines possess unresolved or partially resolved HFS and IS. The smallness of HFS and IS explains the scarcity of studies of these effects in Cu II. However, these effects should be relatively easy to observe in the infrared region. Such observations would be very valuable.
All wavelength measurements described in the present paper were made with natural copper samples. As we know, there is no such physical entity as an atom of natural copper. Thus, the energy levels and Ritz wavelengths derived from these measurements do not pertain to a real atom, but rather are empirical values that best describe the spectrum as normally observed.

2. Wavelength Measurements

The unfortunate consequence of the thorough analysis made by Ross [2,16] is that, in the 46 years after his thesis, there were no studies devoted specifically to Cu II. Instead, his Cu II Ritz wavelengths were widely used as secondary standards for investigation of other species. In particular, the archive of the NIST Atomic Spectroscopy Group has several tens of photographic plates with VUV spectra obtained with the 10.7 m normal incidence vacuum spectrograph with a 1200 lines/mm concave grating. These plates were recorded for studies of Y, Zr, Ge, La, and other elements. For calibration purposes, separate tracks were exposed on these plates with spectra of copper hollow cathodes. The latter, in addition to copper lines, contain lines of carrier gases (helium, neon, and argon), as well as hydrogen, carbon, oxygen, nitrogen, silicon, and germanium that were present as intrinsic or deliberately introduced impurities. These spectra were obtained in different years from 1969 to 1974. In addition to that, we have several high-resolution spectra recorded with two NIST vacuum Fourier transform spectrometers (FTS) in years 2002 to 2008 using Cu/Ge/Pt/Fe/Ne and Cu/Re/Ar/He hollow cathodes. The “new” measurements described in the Abstract were all made with these old recordings. However, we carried out new reductions of the wavelengths and re-analyzed the uncertainties, so it is in this sense that the measurements can be considered as new. To obtain a consistent and comprehensive description of the Cu II spectrum, we combined these new measurements with the old published data from Shenstone [1], Kaufman and Ward [15], and Ross [2,16], which we re-analyzed to evaluate the wavelength calibration, measurement uncertainties, and observed line intensities. Since this re-analysis depends on our new measurements, we describe them first.
Table 1 lists the exposures used in the present analysis. Since exposures used in grating measurements were taken over a period of several years, several different lamp designs were employed. The design of these lamps was similar to the one described in detail by Reader and Davis [26], except that a special fitting was made to attach them to the NIST vacuum spectrograph. The cathode was solid copper with a cylindrical hole of about 7 mm in diameter. Following Kaufman and Ward [15], small pieces of Ge and Si were placed in the cathode to obtain good reference lines in regions that were not covered well by Cu II. The carrier gas was a combination of flowing helium at a pressure of about 0.5 kPa (4 Torr) and neon or argon at about 70 Pa (0.5 Torr). The entrance slit of the spectrometer separated the lamp from the spectrometer chamber, which was maintained at a residual pressure of about 7 × 10−3 Pa (5 × 10−5 Torr). The demountable high-current lamp made at the University of Hannover, used several tens of years later in the FTS measurements, had a similar design described by Danzmann et al. [27]. Ar at a pressure of 200 Pa (1.5 Torr) with an addition of He at 70 Pa (0.5 Torr) was used as a carrier gas in spectrum 14, while Ne at a pressure of 270 Pa (2 Torr) was used in spectra 12 and 13. Pieces of Ge, Pt, Fe, or Re were placed inside the cathode. The grating spectrograms covered the region (636 to 2682) Å, while the FTS spectrograms covered the region (1792 to 11733) Å.
The grating spectra were photographed on Kodak SWR plates and measured with a Grant semiautomatic comparator. (Commercial products are identified in this paper for adequate specification of the experimental procedure. This identification does not imply recommendation or endorsement by NIST.) Repeated measurements of the same plates were made, from which the measurement uncertainty of line positions was estimated to be 1.6 μm for isolated well-resolved lines, corresponding to statistical wavelengths uncertainties of 0.0012 Å. Most of the lines were measured on two to six different tracks. Thirty-eight Cu II lines were measured in the second order of diffraction, and one (861.9932 Å) in the third order, while the rest of them were measured in the first order. Below 1980 Å, most of the tracks had a sufficient number of impurity lines (H, He, C, N, O, Ne, Si, Ar, Ge), which were used as standards. Cu II lines accurately measured by Kaufman and Ward [15] were also used as standards in the region (860 to 1663) Å. In the region above 1980 Å, we used Ross’s [2] interferometric and grating measurements as standards. Although later we found that Ross’s wavelengths are systematically too long (see below), the average error in the wavelengths we used as standards in the grating spectra was only (−0.0004 ± 0.0008) Å, well below our total measurement uncertainties. Therefore, we did not remove the systematic errors from Ross’s wavelengths used at this stage. The systematic uncertainty of each measured wavelength on our plates was estimated as a combination in quadrature of the standard deviation of the fitted polynomial (given in Table 1) and a mean uncertainty of standard wavelengths in the vicinity of the measured line. These systematic uncertainties were combined in quadrature with the statistical uncertainty (0.0012 Å for sharp isolated lines and up to 0.005 Å for blended or overexposed lines). Multiple measurements of the same line on different tracks were averaged with weights inversely proportional to squares of total uncertainties. The uncertainty of the mean was calculated as a combination in quadrature of the reduced statistical uncertainty and the straight average systematic uncertainty. In total, we have measured 1217 unique spectral lines in the grating spectra between 636 Å and 2682 Å, of which 938 were either identified as Cu II lines or did not have any identification, and the rest were identified as belonging to impurities noted above. The wavelengths determined in the present work have uncertainties ranging from 0.0008 Å to 0.010 Å. A number of lines reported by Kaufman and Ward [15] were overexposed on our plates, which led to significant systematic shifts in determining their positions. Such overexposed lines were not used in the current wavelength measurements.
Our FTS measurements were calibrated assuming a common calibration factor for all wavenumbers in each spectrogram. The value of the calibration factor was determined as a weighted mean of the ratio σ/σstd, where σ is the measured wavenumber, and σstd is the tabulated wavenumber of the reference line. For the Ar II and Ge I-II lines used as standards in the FTS spectra, we used the Ritz values from ASD as σstd. We used reciprocal squared uncertainties of σstd, combined in quadrature with our measurement uncertainties (see below), as weights in this averaging. Uncertainties of thus obtained calibration factors (given in Table 1) represent the systematic uncertainties in our FTS measurements. Positions of the line centers σ, line widths W, signal-to-noise ratios S/N, and total integrated intensities were evaluated using the XGREMLIN code by Nave et al. [28] either automatically, assuming a Lorentzian profile for isolated symmetrical lines, Gaussian profile for nearly symmetrical but visibly perturbed lines, or manually with a Gaussian profile with a line width fixed at a visually estimated value.
For well-resolved symmetrical lines, statistical uncertainties of FTS measurements can be approximated by Equation (1) of Brault [29]:
δ σ stat = k N w · W S / N ,
where σ is the wavenumber, W is the full width at half maximum of the line, Nw is the number of statistically-independent points in the line width, and k is a constant depending on the line shape and the algorithm used for fitting the line. For Gaussian profiles, k = 0.693. For an optimally sampled spectrum, the interferogram is recorded to a path difference such that Nw is between 3 and 4 for the majority of the spectral lines. This gives the commonly-used approximation of
δ σ stat = W 2 · S / N
Using Nw = W/r, where r is the resolution of the spectrum in cm−1, Equation (1) can be re-written as:
δ σ stat =   k S / N r W
Our spectra were taken with r = 0.015 cm−1 for the Cu/Re/Ar/He spectrum and r = 0.13 cm−1 for the Cu/Ge/Pt/Fe/Ne spectra. Typical line widths of symmetrical lines in our spectra range from 0.04 cm−1 around 10000 cm−1 to 0.25 cm−1 around 30000 cm−1, giving values of Nw between 2.5 and 3. The instrumental line shape of the FTS comes from the finite length of the interferogram and is a sinc function of width r. When this is convolved with the Gaussian lines in our spectra, the increase in the width is negligible for a line with Nw = 3 and only 0.2% for a line with Nw = 2 and can thus be ignored in the calculation of the statistical uncertainty.
Many of the Cu lines are affected by HFS and cannot be adequately fitted using Gaussian profiles. For example, Figure 1 shows the profile of the Cu II line at 12852 cm−1.
The position of such lines was estimated using the center of gravity. For strong isolated lines (S/N > 150), where it is easy to estimate the range for calculation of the center of gravity, Equation (3) can be used to estimate the uncertainty using k = 1 [29]. However, this uncertainty increases for weaker lines where it is not as easy to estimate the range of calculation for the center of gravity. The measurements are further complicated by the asymmetric HFS. Its precise shape and width is not studied so far for the Cu II spectrum. In our high-resolution Cu/Re/Ar/He spectrogram, HFS patterns are partially resolved in 230 out of total 352 Cu II lines. The average width of the HFS of those lines is Wave = 0.14 cm−1. Since the shapes of the HFS are unknown, an additional uncertainty in the measured centers of gravity arises from the possible omission (or erroneous inclusion) of a weak HFS component at the far wing of the line profile. The possible error caused by this effect of noise is easy to estimate by calculating the shift of the center of gravity of the structure:
δσhfs = 0.5WhfsInoise/(Itot + Inoise),
where Itot is the measured integrated intensity, Whfs is the maximum of Wave (see above) and the fitted width of the structure, and Inoise is the estimated possible integrated intensity of a hypothetical missed or erroneously included HFS component, equal to the root of mean square of the noise amplitude in the vicinity of the structure multiplied by the average width of sharp Cu II lines (equal to 5 × 10−6 times wavenumber for this spectrum).
The calibration of exposures 12 and 13, measured with a Cu/Ge/Pt/Ne hollow cathode, was made using 37 Ge I and II lines interferometrically measured by Kaufman and Andrew [30]. The reference wavenumbers from the latter paper have been decreased by 1.4 parts in 108 to put them on the scale of a recent measurement of 198Hg by Sansonetti and Veza [31], as described in Nave and Sansonetti [32]. Exposure 14, made with a Cu/Re/Ar/He hollow cathode, was calibrated using 68 Ar II standards from Whaling et al. [33]. Uncertainties of the calibration factors were determined as the sum in quadrature of the statistical uncertainty (coming from the different values of the calibration factor derived from different standard lines) and the mean uncertainty of the standard lines.
The total uncertainty of Cu II measurements was determined as the sum in quadrature of statistical and systematic uncertainties. The former was taken as the sum in quadrature of Equations (3) and (4), and the latter is the uncertainty in the calibration factor (given in Table 1) times the wavenumber. Total uncertainties of our Cu II wavelengths measured by FTS range from 0.000025 Å to 0.023 Å.
Kaufman and Ward [15] photographed the VUV spectrum of a water-cooled hollow cathode discharge containing germanium and silicon in the first, second, and third orders of diffraction of the same 10.7 m Eagle-mounting vacuum grating spectrograph as used in the present work (designated as NIVS in Table 1). They reported 141 measured wavelengths of Cu II in the range (861 to 1663) Å. As wavelength standards, they used lines of Cu II, Ge I, and Si I that were either calculated (Ritz) or interferometrically measured. The reciprocal linear dispersion was 0.78 Å/mm in the first order of diffraction. Many of the reported lines were measured on several (up to 11) spectrograms. We estimated their measurement uncertainties by comparing the measured wavelengths with the Ritz values (using Ross’s [2] energy levels) separately for lines measured only in the first order (0.003 Å for a single measurement), measured several times in the 1st order, but only once in the 2nd and/or 3rd order (0.0010 Å), and for lines measured on several spectrograms in several orders of diffraction (varying from 0.0004 Å to 0.0018 Å). These estimates agree well with those given explicitly by Kaufman and Ward for a few lines. Careful work was required to reconstruct the list of observed wavelengths, since some of the values given in Table III of Kaufman and Ward [15] are Ritz wavelengths, but many of them are also given in their Table I including the value of the residual λRitzλobs. Since there is no information regarding the wavelength standards actually used in various wavelength regions, all wavelengths reported by Kaufman and Ward [15] were adopted without corrections.
Ross [2,16] investigated the Cu II spectrum photographically from 1979 Å to 11217 Å using plane and concave grating spectrographs and Fabry-Perot interferometers. The light source was a water-cooled hollow cathode discharge with helium or neon as a buffer gas. Ross [2] noted that intensity of most Cu II lines was greatly enhanced when He at a pressure of about 0.9 kPa (7 Torr) was used as the carrier gas, while if Ne is used, only lines below 3000 Å arising from relatively low levels are excited. The standards for the Fabry-Perot interferograms were the lines of 198Hg emitted by a water-cooled sealed electrodeless-discharge lamp containing argon carrier gas at a pressure of 33 Pa (0.25 Torr), with vacuum wavelengths 5462.27055 Å and 2537.2687 Å referred to Kaufman [34]. For grating measurements, a 9.2 m concave grating spectrograph with Paschen-Runge mounting was used. The grating had 600 lines/mm, was blazed at 10000 Å, and provided a reciprocal dispersion of ≈1.7 Å/mm. For calibration, interferometrically measured Cu II lines were used as standards.
As noted in the Introduction, subsequent studies reported some systematic errors in Ross’s short-wavelength measurements. This can be explained by the fact that below 2200 Å, Ross encountered severe technical difficulties in his interferometric measurements, caused by strong absorption in the crystalline quartz of the plates and windows. He partially solved the problem by removing the windows, which exposed the interferometer to spectroscopically non-standard air and did not permit thorough temperature control. In addition, Kaufman’s values for the 198Hg lines Ross used as standards, 5462.27046 Å and 2537.26877 Å [34], have since been re-evaluated. Their currently recommended vacuum wavelengths are 5462.27062(3) Å and 2537.268755(17) Å [35]. Additional errors could have been due to a possibly imperfect match between filling the interferometer’s aperture with light from the hollow cathode and from the mercury lamp. To verify the calibration of Ross’s wavelengths, we compared his reported wavelengths with those measured in our FTS spectra. Similar to FTS measurements, interferometric measurements of Ross can be corrected by a multiplicative factor [20]:
σc = (1 + keff)σu,
where σc is the corrected wave number, σu is the uncorrected wave number, and the correction factor keff is determined from one or more internal standard lines in the spectrum, in this case from our wavenumbers measured by FTS. Dependence of thus derived keff on wavenumber is plotted in Figure 2.
It should be noted that Figure 2 includes all Ross’s lines that were also measured in our FTS spectra. Many of those lines were weak in our FTS spectra, resulting in large error bars in Figure 2. However, there was a sufficiently large number of strong lines with small error bars, which explain the very small uncertainties of the fitted curve in Figure 2.
Unlike FTS measurements, where keff is a constant over the entire range of measured lines, the calibration correction of Ross’s measurements depends on wavenumber. This dependence is rather weak, and the value of keff is small (<10−7) in the interval (17000 to 38000) cm−1 (6000 Å to 2700 Å), but keff notably increases (up to 3.5 × 10−7) for infrared lines, and varies rapidly for the far-UV lines below 2700 Å. The accuracy of the fitted keff values varies from 3 × 10−8 to 3.5 × 10−7, depending on the measurement uncertainties in Ross [2] and in our FTS data. It determines the systematic uncertainties in the Ross’s wavenumbers as now re-calibrated.
This re-calibration and increased uncertainty associated with it allowed us to explain only a small part of numerous lines strongly deviating from Ritz wavelengths in Ross’s list, noted in the Introduction. To explain the remaining problematic lines, additional factors contributing to uncertainties, not accounted for by Ross, must be considered. One such factor can be pressure shifts caused by relatively high pressure of He in his discharge, 0.9 kPa (7 Torr). Such shifts could cause quasi-random deviations of measured wavelengths in both directions from unperturbed values. Another contributing factor could be partially resolved HFS. The Doppler width reported by Ross for the sharp line at 2473 Å (40419 cm−1) was about 0.1 cm−1, which is of the same order of magnitude as most of the known HFS widths. He noted that partially-resolved HFS was indeed a problem in his wavelength measurements, and that his tabulated results are centers of gravity of observed HFS structures. However, he did not give any details about the method with which these centers of gravity were determined. Such determination depends on the measurement accuracy of the relative intensities of the HFS components, which might have been distorted by non-linearity of response of photographic plates used by Ross. The shift in the measured center-of-gravity wavenumber caused by errors in intensity measurements would be some fraction of the HFS width. We accounted for both types of such possible shifts (caused by pressure and HFS) by adding in quadrature a constant quantity to the wavenumber-measurement uncertainties of Ross [2]. The value of this constant was found empirically to be 0.007 cm−1. These increased uncertainties are statistically consistent with residuals σobsσRitz of the level-optimization procedure (see Section 3).
Shenstone [1] made the most comprehensive study of the Cu II spectrum prior to Ross [2]. He photographed spectra of a copper hollow cathode (Schuler tube) filled with helium or neon using several spectrographs: 6.4 m and 3 m normal incidence grating spectrographs and two Hilger prism spectrographs for the UV and visible regions, a 2 m normal incidence vacuum grating spectrograph for the VUV region, and another concave grating spectrograph (in NBS) for the infrared region. Since Ross could not observe lines shorter than 1979 Å, Shenstone’s line list remained the only source of information about observed Cu II lines and their intensities in the VUV. We have re-measured many of VUV lines listed by Shenstone with much greater accuracy. Most of his lines in the UV, visible, and infrared regions were re-measured by Ross [2]. However, 94 lines from Shenstone [1] ranging from 836 Å to 6870 Å were not observed in our and Ross’s spectra. For 15 of them, Shenstone did not give a measured wavelength (apparently, because low resolution did not permit accurate measurement), but gave the observed intensity. Wavelength calibration and uncertainties of Shenstone’s measurements were investigated by comparing them with Ritz wavelengths calculated from Ross’s [2] energy levels. Because of the relatively low resolution of Shenstone’s measurements, the small differences of Ross’s Ritz wavelengths from more accurate ones obtained from our final level optimization (see Section 3) did not have any effect on this analysis. Since most of Shenstone’s lines used in the final line list were measured with the vacuum grating spectrograph, we compare his measurements made on this instrument with Ritz wavelength in Figure 3.
Although Figure 3 includes all wavelengths reported by Shenstone (excluding a few lines with extremely large deviations), assessment of uncertainties was made separately for “good” wavelengths given with three figures after the decimal point (in Å) and having no indication of blending or other perturbations, for wavelengths given with two decimal figures (apparently, deemed less accurate by Shenstone), and for lines indicated as blended or perturbed, or having multiple classifications. The trend indicated in Figure 3 by a solid line was derived from accurately measured lines only. It resulted in a correction to Shenstone’s VUV wavelength varying from +0.003 Å for the shortest wavelengths near 700 Å to +0.010 Å near 1980 Å. After this correction, the uncertainty for each category of lines was estimated as a root-mean-square (rms) of the residuals. These uncertainties were found to vary from 0.006 Å for the best measurements to 0.07 Å for the worst. A similar analysis was made separately for each spectrograph used by Shenstone.
For completeness, we included in our line list one line observed by Wagatsuma and Hirokawa [36] at 4485.3 Å, which was not reported by other observers. Since wavelengths reported by Wagatsuma and Hirokawa are the Ritz ones (owing to low precision of their measurements), we also give only the Ritz wavelength for this line.
In all the laboratory studies described above, only electric-dipole allowed (E1) lines could be observed, since densities in the discharge light sources are high enough to collisionally depopulate metastable levels, from which forbidden lines could emerge. However, four forbidden lines of Cu II were observed in other studies. The first observation known to us is that of Thackeray [3] who identified the line of Cu II at 3806.3 Å as the electric-quadrupole (E2) 3d10 1S0–3d94s 1D2 transition in emission spectra of two nebulae, η Carinae and RR Telescopii. Another E2 transition, 3d10 1S0–3d94s 3D2 at 4375.8 Å, as well as the hyperfine-induced 3d10 1S0–3d94s 3D3 transition at 4558.7 Å, were observed but not identified in emission of RR Telescopii by Aller et al. [4]. The above-mentioned E2 transition at 3806.3 Å, as well as the magnetic-dipole (M1) 3d10 1S0–3d94s 3D1 transition at 4165.7 Å, were observed and identified by McKenna et al. [5] in emission of the same nebula, RR Telescopii. In the laboratory, the two E2 transitions at 3806.3 Å and 4375.8 Å were observed (with an accuracy inferior to astrophysical observations) and their radiative decay rates were measured by Prior [37] in an electrostatic ion trap.
All observed and identified spectral lines of Cu II are collected in Appendix A, Table A1. In addition to observed lines, this table includes several predicted transitions, in particular, six M1 and E2 transitions between the levels of the first excited configuration, 3d94s. This table lists 2557 transitions corresponding to 2494 unique measured spectral lines, 677 of which were measured in this work, and includes 50 additional lines that are either predicted (not observed), observed but not measured, or were masked by stronger neighboring lines in observed spectra. In addition to observed wavelengths, Table A1 gives for each transition the Ritz wavelength with standard uncertainty obtained in the level optimization procedure (see Section 3), energy-level classification, intensity on a unified scale (see Section 5), and a reference to the source of the observed wavelength. For 555 transitions, we also give a critically evaluated transition probability (A-value) with its uncertainty estimate and a reference. Lines on which laser action was reported in the literature are marked with “L” in the Notes column.
In Table A1, wavelengths between 2000 Å and 20000 Å are given in standard air; outside of this region, they are in vacuum. Conversion from air to vacuum was made using the five-parameter formula from Peck and Reeder [38]. Ritz wavelengths and their uncertainties were obtained using the LOPT (level optimization) code [39] as described below in Section 3. Transition probabilities are either calculated in the present work or critically compiled from references [40,41,42,43,44,45,46,47,48,49,50,51] as described in Section 6.

3. Energy Levels

The precise positions of energy levels, as well as the Ritz wavelengths and their uncertainties, were derived from the identified lines listed in Table A1 using the least-squares level optimization code LOPT [39]. The resulting energy levels are listed in Table A2.
Of all 2557 transitions in Table A1, 113 were excluded from the level optimization procedure. Among those, there are 61 transitions that were either predicted (e.g., far-IR forbidden transitions), had poorly measured wavelengths (e.g., astrophysically observed forbidden lines), were severely blended, or were masked by much stronger nearby lines. The remaining 52 lines were excluded because their observed wavelengths deviated too much from the Ritz values. In total, we used 2443 observed transitions in our level-optimization procedure. For comparison, Ross [2,16] used 1691 observed transitions in his level optimization.
If one compares the presently found energy levels with those given by Ross [2,16], the average agreement is good. The mean difference (ETWERoss) is only 0.007 cm−1 with a standard deviation of 0.016 cm−1 (the subscript “TW” means “this work”). However, a more detailed comparison shows that, of the 347 levels correctly identified by Ross, 156 deviate from those given in Table A2 by more than two (up to 11) combined uncertainties. Uncertainties of our level values are on average greater than those of Ross by a factor of 1.4, owing to our increased estimate of Ross’s wavelength uncertainties. For only 32 levels our uncertainties are smaller than those of Ross (by up to a factor of eight). This improvement is due to our FTS measurements. Similar conclusions can be made for the Ritz wavelengths. Among about 500 Ritz VUV wavelengths listed by Ross, only a few are incorrect because of erroneous identifications described below. If these are excluded, the mean difference (σTWσRoss) is 0.012 cm−1 with a standard deviation of 0.019 cm−1. However, for 273 VUV lines (more than half of all given by Ross), Ross’s Ritz wavelengths deviate from ours by more than twice the combined uncertainty. Our Table A1 includes 632 Ritz wavelengths for VUV lines below 2000 Å. Most of the new lines were observed and measured in this work.
The analysis that led to Table A1 and Table A2 was made in an iterative manner. In the first step, after an initial list of all observed lines was constructed, it contained more than 600 unclassified lines, 143 of which were listed by Ross [2,16], 54 by Shenstone [1], one by Kaufman and Ward [15], and the rest were observed in our VUV grating spectra. Twenty-four of these lines (18 in Ross [2,16] and 6 in Shenstone [1]) were found to be due to previously identified transitions in Cu I. To find possible identifications for the remaining unknown lines and to find proper designations for the energy levels, we made a parametric analysis of the Cu II spectrum using Cowan’s suite of atomic codes RCN/RCN2/RCG/RCE [52] (A version of the codes adapted by A. Kramida for Windows-based personal computers is available online: http://das101.isan.troitsk.ru/COWAN). In this analysis, we included the following sets of configurations: 3d10, [3d9](ns, nd) (n = 4–10), ng (n = 5–10), [3d8](4s2, 4p2, 4s4d, 4s5s, 4d2, 4s5d) in the even parity, and [3d9](np, nf) (n = 4–8), nh (n = 6–8), [3d8](4s4p, 4s4f, 4p4d, 4s5p, 4s5f) in the odd parity, 25 configurations in total. All known energy levels from Sugar and Musgrove [17] were included in the least-squares parametric fitting (LSF) with the RCE code. The calculations were made in the relativistic mode (HFR), including Breit corrections and correlation term (explained in the RCN manual). The fitted parameters were substituted as input for the RCG code to obtain a list of predicted lines with calculated A-values. The calculated A-values and energy levels, as well as known experimental levels, were used in the input files for the visual line-identification code IDEN1 originally designed by Azarov [53] and later programmed for Windows-based computers by one of the present authors (AK). Using this tool, we identified 117 previously unclassified lines with transitions between known energy levels, revised four levels and found 28 new energy levels. The revised and newly found energy levels explained 79 previously unclassified lines and involved revised classifications of 24 lines previously identified by Ross [2] and Shenstone [1].
At this stage of the analysis, it was also found that two levels listed by Ross [2] and included in the compilation of Sugar and Musgrove [17] had to be rejected. One of them, an undesignated odd-parity level with J = 1 at 144240.6 cm−1, was retained by Ross from Shenstone’s level list. It was identified by one line measured by Shenstone at 823.802 Å, which we re-measured to be at 823.8361(18) Å and identified with a transition between other previously known levels, 3d94s 1D2–3d9(2D5/2)7p 2[5/2]°2. It was also found that there are no possible unknown odd-parity levels with J = 1 sufficiently close to the value given by Ross to explain this level. Another rejected level is also of odd parity, designated by Ross as 3d96p 30 (at 141154.164 cm−1). It was based by Ross on two lines, one observed by Shenstone at 853.56 Å and identified by Ross as a transition from this level to 3d94s 3D1, and another observed by Ross at 3217.641 Å, which he interpreted as a transition from this level to 3d9(2D3/2)5s 2[3/2]1 (to be consistent with our tables, we use our new JK designations). Both these transitions were predicted to be extremely weak, certainly much weaker than other possible transitions from this level. We re-measured the first line to be at 853.544(2) Å and re-classified both lines as transitions from other levels. In addition, the energy given by Ross deviates too much from that predicted by our parametric fitting.
Two levels listed by Ross as 3d96p 32 and 31 at 141244.576 cm−1 and 141734.167 cm−1, respectively, were each based by Ross on several transitions to lower-lying even levels with J = 1 or 2. Most of the corresponding lines were previously observed and similarly identified by Shenstone. However, we found that observed line intensities agree much better with those predicted if assignments of these two levels are interchanged. Further proof for this revision was provided by our identification of two transitions from the lower of these two levels down to levels with J = 3. One of the corresponding lines was newly observed in our VUV spectrum, and another one was present among Ross’s unclassified lines.
Following Shenstone [1], Ross interpreted the level at 137212.765 cm−1 as 3d84s4p 11. Sugar and Musgrove [17] gave a more specific designation, 3d8(3P)4s4p(3P°) 11 based on a parametric calculation made by Roth [54]. We found three transitions connecting this level with even J = 3 levels. Since other combining levels have J = 1 and 2, the only possible J value for this level is 2. We labeled this strongly mixed level as 3d8(1G)4s4p(3P°) 32, although it represents only 36% of the percentage composition; an equal contribution is from 3d8(3F)4s4p(1P°) 32, followed by 14% of 3d8(3P)4s4p(3P°) 12.
Ross found the level at 147491.888 cm−1, which he designated as 3d97p 33 based on three weak lines at 3360.9941 Å, 9310.353 Å, and 9569.11 Å, identified as transitions from this level down to 3d94d 3G3, 3d95d 3P2, and 3d95d 3F4. Although these three lines indeed perfectly satisfy the Ritz combination principle, our calculations indicate that their intensities should be negligibly small, while much stronger transitions to other even-parity levels should occur, but were not observed by Ross. The strongest predicted transitions from this level are in the VUV region inaccessible to Ross. We have found three lines in our VUV exposures at 824.663 Å, 1609.342 Å, and 1924.548 Å, which have wavelengths and intensities consistent with this level, placing it at our new revised position, 147525.93 cm−1. All other odd-parity levels with J = 3 predicted to occur within ±2000 cm−1 from this energy are experimentally known, which leads us to conclude that the combination of three lines observed by Ross is spurious. We note that the density of observed lines in the UV, visible, and IR regions is sufficiently high to produce several tens of spurious combinations of two, and a few of three lines, which we observed in the combined line list. We could not find alternate identifications for the three lines assigned previously by Ross to this revised level.
Three other levels in Ross’s list were found to be questionable, either because they were based on only one or two weak lines, or because the energy strongly disagrees with our parametric calculation. These levels are at 154838.963 cm−1, 155244.833 cm−1, and 156958.096 cm−1, designated by Ross as 3d98d 3P1, 3P0, and 3F2, respectively.
After the new identifications were made, the new experimental energies were incorporated in the LSF procedure, and the questionable levels removed. We also inserted in the LSF several tens of levels belonging to the [3d9]9d, 10d, 8g, 9g, 10g, 7f, 8f, 6h, 7h, and 8h levels whose positions were accurately extrapolated by Ritz-type quantum defect or polarization formulas (see Section 4). These levels were found to be sufficiently pure, unperturbed by interactions with other configurations, and thus the series formulas provided dependable results.
In this final LSF, 218 known even-parity levels were fitted with 38 free parameters with a standard deviation of 40 cm−1, and 241 known odd-parity levels were fitted with 35 free parameters with a standard deviation of 72 cm−1. The fitted (LSF) and ab initio Hartree-Fock (HF) values of parameters are given in Table A3. In both parities, the ζ3d parameters of the 3dn core were linked together in one group for all configurations, so that their LSF/HF ratio was the same for all members of the group, but was allowed to vary in the fitting. Other parameters, similar in different configurations, such as the effective parameter α3d, electrostatic parameter F2(3d,3d) of the 3d8 core, and configuration-interaction parameters, were also linked in similar groups, which decreased the number of free parameters and made the fitting more stable.
Using the transformation procedures implemented in Cowan’s RCE code, eigenvector compositions were calculated in several coupling schemes. Similar to the spectrum of neutral nickel analyzed by Litzén et al. [21], most of the 3d9nl configurations were found to be best described in the J1l (otherwise known as JK or JcK) coupling scheme, in which the total angular momentum of the core (3d9 in this case) is combined with the orbital momentum of the valence electron to produce the K quantum number, which is then combined with the spin of the valence electron to obtain the final total angular momentum J. In Ni I, Litzén et al. [21] found the lowest [3d9]nl configurations, 4s, 4p, and 5p, to be better described in the LS coupling scheme, which is also the best for the 3d84s2 and other 3d8nlnl′ configurations. In Cu II, our findings are similar, except that the 3d95p configuration is better described by J1l coupling. The J1l purity of the 3d9nl configurations increases from 65% for 3d96p to 100% for 3d9ns, nh (n ≥ 6), and ng (n ≥ 6), and generally increases with increasing n and l. This general trend is disrupted in 3d96p. This configuration strongly interacts with 3d84s4p, unlike 3d95p, for which this interaction is somewhat weaker, resulting in the average J1l purity of 75%. For the 3d84s4p configuration, in agreement with the previous analysis by Roth [54], we found that the best description is obtained by first combining the quantum numbers of the 4s and 4p electrons with each other to produce an intermediate LSJ term (3P° or 1P°) of the 4s4p valence shell, and then combine it with LSJ of the 3d8 core. Although the average purity of 3d84s4p in this coupling scheme is rather high, 73%, many of its levels are strongly mixed with other configurations, rendering assignment of single-configuration labels arbitrary. Several levels attributed to this configuration have a leading percentage of the composition smaller than 30%. In a few cases, such as the levels at 139331.149 cm−1 (J = 3) and 139710.491 cm−1 (J = 2), we assigned labels corresponding to the second leading term in the composition, in order to preserve uniqueness of the labels within the J manifolds. The labels assigned to the levels do not fully describe their physical nature; percentage compositions given in Table A2 are somewhat better in this regard.
The high J1l purity of the 3d9ng configurations and very small values of parameters describing interactions between 3d9 and ng shells allows for accurate prediction of the levels that were missing in Ross’s levels list. This permitted us to find some of these levels from the lines left unclassified in his analysis.
For each level, Table A2 gives a number of observed lines on which this level is based. Most of the levels are based on more than two observed lines. However, 71 of them are derived from only one or two observed lines. Most of them are firmly identified, because the observed lines are the strongest predicted ones, and the level positions are confirmed by trends along series. Five of such levels are marked as questionable, because the corresponding series are strongly perturbed, or because the observed lines are not the strongest predicted to occur from these levels. The absence of predicted stronger lines could be explained by different registration sensitivity in exposures used in different spectral regions.
We identified the previously missing 3d84s2 1S0 level based on one line observed at 1807.8535 Å in two exposures in our VUV spectra and at 1807.84 Å by Shenstone [1]. We assigned this line to the strongest predicted transition from this level, terminating at 3d94p 11. Although this line is observed to be about 20 times stronger than predicted, this was the only unidentified line within the interval of ±3000 cm−1, and it places the 3d84s2 1S0 level within 25 cm−1 of its predicted position. Therefore, we believe that this identification is correct.
Five odd-parity levels are given in Table A2 with revised designations. The level with J = 3 at 121524.8509 cm−1 was previously labeled by Sugar and Musgrove [17] as 3d95p 3D° with a 53% contribution of this term in the composition, as given by Roth [54]. Although our calculation yields the same leading term in the composition of this level, the total contribution from the 3d84s4p configuration is calculated to be greater than from 3d95p. Therefore, we designated this level by the second largest component, 3d8(3F)4s4p(3P°) 1F°. A marginally larger contribution of the 3d95p 3D° term was found in the J = 3 level at 121079.1501 cm−1, which we attributed to this configuration. The J1l-coupling designation gives a better description of this level, the leading term being 54% of 3d9(2D5/2)5p 2[5/2]°. In effect, the identifications of these two J = 3 levels at 121079.1501 cm−1 and 121524.8509 cm−1 have been interchanged. This revision is supported by better agreement of observed and calculated line intensities.
The J = 4 level at 134742.863 cm−1 was labeled by Sugar and Musgrove [17] as 3d96p 3F°, and its composition was given as 49% of this term and 39% of 3d8(1G)4s4p(3P°) 3F°. We found the leading term to be 50% of 3d8(3F)4s4p(1P°), which we use as a revised label. We note that Sugar and Musgrove gave the same configuration and term label to another J = 4 level at 139395.786 cm−1 with almost the same percentage composition. We found for the latter level 59% contribution from 3d96p 3F°, but designated it in J1l-coupling as 3d9(2D5/2)6p 2[7/2]°.
Another J = 4 level at 137938.904 cm−1 was designated by Sugar and Musgrove [17] as 3d8(3F)4s4p(1P°) 3F° with 53% of this term in the composition. We found the leading terms to be 49% of 3d8(1G)4s4p(3P°) 3F°, 39% of 3d96p 3F°, and only 5% of the term given as label by Sugar and Musgrove. We changed the label to the leading term indicated by our calculation.
The J = 3 level at 139331.149 cm−1 was designated by Sugar and Musgrove [17] as 3d96p 3D° with 56% of this term in the composition. In our calculation, the leading LS term is found to be 46% of 3d96p 1F°. However, in J1l-coupling adopted for the 3d96p configuration, the leading term is 32% of 3d9(2D5/2)6p 2[7/2]°, which is used to label another level having 62% of this term. Thus, we labeled the level at 139331.149 cm−1 by the second leading LS term of its composition, 3d8(1G)4s4p(3P°) 3F°.

4. Ionization Energy

Ross [2] derived the value for the ionization limit by extrapolation of quantum defects along 12 series of the type 3d9nl (two ns, nine nd, and one nf, with n ranging from 4 to 10 for the ns J = 3 series, 4 to 9 for the ns J = 1 series, and 4 to 8 for the rest). Although Ross used LS designations for all the levels involved, the series he chose are almost pure in J1l coupling, resulting in smooth behavior of quantum defects along the series. Using the RITZPL computer code by Sansonetti [55], we repeated Ross’s derivation with our more accurate level values and obtained slightly different values for the series limits. In the derivation of the limit, we added two more 5-member 3d9nd series, in which we found some new identifications. The weighted average of the limits obtained closely agrees with the average value adopted by Ross. In addition, series limits obtained from six three-member series with an exact fit of the polarization formula (Sansonetti [56]) produced values in close agreement with this average. Thus, we adopted the value for the ionization limit given by Ross [2], 163669.2(5) cm−1 or 20.292 39(6) eV, which is now confirmed.
Table A2 includes predicted energies for 89 [3d9]nd, nf, ng, and nh levels for which no reliable identification could be found in the observed spectra. These levels are not necessarily those that produce the strongest predicted lines. Rather, they are those that are easier to accurately predict, because the corresponding series have relatively small perturbations. In this derivation, we used predicted positions for centers of gravity of groups of closely located levels along series, using the RITZPL (quantum-defect formula) and POLAR (polarization-formula) extrapolation codes by Sansonetti [55,56], which we combined with fine-structure intervals predicted by the LSF (described in Section 3). Uncertainties assigned to these levels in Table A2 are weighted means of the “observed-calculated” residuals of the LSF, calculated separately for known levels with J1l purities of ≥99%, (97 to 98) %, and (92 to 96) %. Some of the remaining unclassified lines observed by Ross [2,16], Shenstone [1], and by us may be due to these levels. However, we could not reliably identify them because of lack of observed Ritz combinations.

5. Line Intensities

Procedures used in the present work to adjust observed line intensities to a common scale were described in detail by Kramida [57,58]. In this derivation, line intensities observed in each experiment are roughly modeled as described by Boltzmann level populations with certain effective excitation temperature Teff. This temperature is found from a Boltzmann plot built using calculated transition probabilities. The ratios of predicted Boltzmann-population intensities are plotted against wavelengths to derive the response function of the registration equipment, which is then removed from the observed intensities to obtain an improved fit for Teff from the Boltzmann plot. For photographic registration, an additional correction of non-linearity of intensity registration with exposure is deduced from a plot of ratios of calculated and observed intensities versus observed intensity. This procedure is repeated iteratively until convergence is achieved. Then it is easy to scale the reduced intensities observed in experiments with different Teff and different sensitivity to a common value of Teff. In this way, we combined intensities observed in our 22 VUV and 3 FTS spectrograms listed in Table 1 with those reported by Shenstone [1], Kaufman and Ward [15], and Ross [2,16] and reduced them to the scale derived from Ross’s observed intensities to produce the average values given in Table A1. This scale corresponds to Teff = 1.5 eV, which is about average for all experiments included in the analysis. For different experiments, the fitted value of Teff varied between 0.6 eV in some of our VUV exposures to 11 eV in observations of Kaufman and Ward [15]. It should be noted that in most experiments analyzed here populations of highly excited levels were enhanced by resonant transfer from excited levels of helium or other rare gases used in the discharges. This population transfer is the mechanism leading to population inversion and producing laser action observed in hollow-cathode discharges. Thus, it should be expected and is indeed observed that level populations deviate from the Boltzmann distribution by a factor of three on average and strongly vary depending on discharge conditions. Line intensities are given in Table A1 in terms of total energy flux under the line contour.
As noted in Section 2, only E1-allowed lines were observed in laboratory discharges. Thus, the intensity scale adopted for E1-forbidden lines is different from the allowed lines. It is based on relative intensities observed in nebulae spectra by Thackeray [3], Aller et al. [4], and McKenna et al. [5], modified in such a way that the relative intensities of lines from a common upper level are consistent for different observations.

6. Transition Probabilities

Transition probabilities of Cu II were reported in 42 papers, the full list of which can be found in the NIST Atomic Probability Bibliographic Database (Kramida and Fuhr [59]). In addition, we have calculated them using Cowan’s codes [52] using our LSF parameters described in Section 3. To assess the uncertainties of all available data sets, we used evaluation procedures described by Kramida [57].
The initial reference data set was constructed of 41 A-values determined by Ortiz et al. [50] from branching fractions measured using laser-induced breakdown spectroscopy and lifetimes calculated using the Cowan suite of codes [52], modified by inclusion of core-polarization effects. The high accuracy of theoretical lifetimes used in that work was confirmed by excellent agreement with accurate measurements made by Pinnington et al. [51] and Cederquist et al. [43], as well as with other advanced calculations.
This initial selection was expanded by inclusion of theoretical A-values from Dong and Fritzsche [45] obtained in a large-scale multiconfiguration Dirac-Fock calculation accounting for relaxation effects in the orbitals. Uncertainties of these theoretical data were estimated by comparing the results obtained by those authors in the Babushkin (length) and Coulomb (velocity) gauges. This comparison indicated that the stronger lines with line strength S > 10−6 a.u. were calculated with uncertainties in A-values of about 12% on average, while for weaker lines the average uncertainty was much larger, 60%. These conclusions are supported by good agreement (less than 10%) of calculated lifetimes with measurements. For 18 transitions the A-values reported by Dong and Fritzsche [45] were normalized to lifetimes of the upper levels measured by Pinnington et al. [51] and by Cederquist et al. [43].
For three transitions representing the sole allowed decay channels of their upper levels, the lifetimes measured by Pinnington et al. [51] and by Cederquist et al. [43] were directly converted into A-values and also added to the reference data set. Further expansion of the reference data set was provided by results of Crespo López-Urrutia et al. [44] obtained by combining their own measurements of emission branching fractions with radiative lifetimes measured in other studies. From this work, the results obtained using the lifetimes reliably measured by Cederquist et al. [43] and by Kono and Hattori [48] were used without adjustments. However, for several transitions we re-normalized their results to lifetimes more accurately measured by Pinnington et al. [51]. Uncertainties of Crespo López-Urrutia et al. [44] were estimated by combining in quadrature systematic contributions from the uncertainties of the lifetimes and statistical uncertainties, which we estimated to vary from less than 5% for the strongest lines to 90% for the weakest lines, which we assumed to have a signal-to-noise ratio about 1.
Kono and Hattori [48] measured radiative lifetimes of some of the 3d94p and 3d95s levels by a delayed coincidence technique and combined them with branching fractions, some of which were measured in a specially designed discharge tube, and some of which were obtained in a single-configuration LSF-adjusted intermediate-coupling calculation. These authors did not report separately their measured branching fractions, which impedes assessment of their results. Instead, they used all of their data, both experimental and theoretical, together, and adjusted the resulting A-values to satisfy the J-file sum rule. We renormalized several of their reported A-values to radiative lifetimes measured more accurately by Brown et al. [42], Pinnington et al. [51], and Cederquist et al. [43] and estimated the uncertainties by a method similar to the one described above in evaluation of results of Crespo López-Urrutia et al. [44].
Assessment of measurements made by Neger and Jäger [49] and by Hefferlin et al. [47] (hereafter referred to as N88 and H71) presented the greatest difficulties, since they grossly disagree with each other. N88 reported relative transition probabilities (A-values) of seven Cu II lines measured by using an axial discharge type of an exploding copper wire. The rather vague description of these measurements does not include the temperature value used in the data reduction. However, Neger and Jäger compare their results with those reported by Lux [60], obtained with similar equipment, and note that Lux determined the plasma temperature to be 26500(3500) K (2.3(3) eV) from a Boltzmann plot using several Cu I lines with known transition probabilities. The relative A-values reported by N88 (using the line at 4555.92 Å as reference) have uncertainties ranging from 18% to 25% and perfectly agree with those of Lux [60]. Thus, we assumed that they used Lux’s temperature value in their data reduction and restored the observed line intensities from the reported line ratios and this temperature. Two of the lines reported in N88 are in common with more accurate measurements of Ortiz et al. [50].
Hefferlin et al. [47] (H71) determined relative intensities of 11 Cu II lines from photoelectric radiance measurements on the Burnout V experimental magnetic-confinement fusion reactor at the Oak Ridge National Laboratory. To derive the relative log(gf) values from these measurements, they assumed the electron temperature to be 67 eV (±50%). Neger and Jäger [49] blamed this large uncertainty in the temperature value for the discrepancy of the H71 results with theirs. We note that Cu+ should be completely ionized at this high temperature. Thus, an obvious path would be to dismiss the results of H71 as erroneous. However, their reported relative log(gf) values appear to be internally consistent and agree well with other independent estimates. Thus, we restored the observed line intensities from them, using the 67 eV temperature as reported in H71, and attempted to reconcile the two sets of relative intensities (from H71 and N88) by using the following procedure.
As a first step, to determine initial estimates of the excitation temperatures in H71 and N88, we used Boltzmann plots with reference A-values for the lines at 4043.48 Å and 4227.94 Å from Ortiz et al. [50], and for the line at 4909.73 Å from Cederquist et al. [43], while for all other lines we used our Cowan-code calculations. As a second step, using the temperatures derived from these Boltzmann plots, we determined the adjusted A-values from the H71 and N88 observed line intensities. Then we replaced the Cowan-code A-values in the reference set with logarithmic means of thus obtained H71 and N88 adjusted A-values and found adjusted temperature values from the Boltzmann plots. The second step was repeated iteratively until reasonable convergence, i.e., until the change in the temperature values between iterations decreased below 0.001 eV. The final Boltzmann plots for H71 and N88 are shown in Figure 4a,b, respectively.
The excitation temperatures determined for the H71 and N88 data sets are 0.662(5) eV and 1.4(5) eV, respectively. The latter is somewhat lower than the Lux [60] value used in N88, 2.3(3) eV. The final adjusted A-values deduced from the H71 and N88 data are compared with the adopted A-values in Figure 5. In this plot, the reference A-values used for the two leftmost lines (4043.48 Å and 4227.94 Å) and for the rightmost line at 4909.73 Å are from Ortiz et al. [50] and Cederquist et al. [43], while the rest of the lines use the mean of H71 and N88. The error bars are combined uncertainties of the measured line ratios and reference A-values. This plot shows that the adjusted A-values from H71 and N88 are consistent with each other, as well as with the adopted reference A-values.
With the reference data set constructed from data described above, assessment of uncertainties in the theoretical study by Biémont et al. [41] was relatively easy to do by plotting the ratio of the calculated values to the reference ones against line strength S and calculating standard deviations for different ranges of S. This procedure resulted in estimated uncertainties of 9% for S ≥ 8.5 atomic units (a.u.), 22% for S = (0.2 to 8.5) a.u., and 120% for S < 0.2 a.u.
Assessment procedures described above resulted in 210 reference A-values with uncertainties less than 25% covering a wide range of line strengths from 0.06 a.u. to 155 a.u., after which it became possible to evaluate the uncertainties of our LSF calculations. Comparison of our calculated A-values with the reference ones is illustrated in Figure 6.
This plot displays a typical behavior of theoretical transition probabilities. Namely, the strongest lines exhibit the smallest discrepancies from the reference values, while for weaker lines the magnitude of discrepancies grows. A similar comparison was made between A-values produced in our two LSFs (the final and preliminary ones, described in Section 3). From these comparisons, we estimated the uncertainties of our A-values to be ≤10% for S > 200 a.u., ≤15% for S = (50 to 200) a.u., ≤30% for S = (4.3 to 50) a.u., and ≥50% for smaller S. We included 79 of our best calculated A-values in Table A1.
Studies of E1-forbidden transition probabilities of Cu II are very scarce. Garstang [46] calculated A-values for several M1 and E2 transitions from the first excited configuration, 3d94s, down to lower-lying levels of the same configuration and to the ground state, 3d10 1S0. He used the pseudo-relativistic Hartree-Fock method with superposition of configurations and LSF-adjusted Slater parameters, similar to the one implemented in Cowan’s codes [52] used in the present work, but limited by inclusion of only three low-lying configurations of even parity. Beck [61] made an ab initio restricted non-relativistic multiconfiguration Hartree-Fock calculation for the 3d10 1S0–3d94s 1,3D2 E2 transition and obtained A = 2.33 s−1, somewhat larger than the sum of Garstang’s values for transitions from 1D2, 1.7 s−1, and 3D2, 0.12 s−1. Prior [37] measured the A-value for the 3d10 1S0–3d94s 1D2 transition at 3806.3 Å to be 1.60(24) s−1, in excellent agreement with Garstang’s semiempirical value. The most recent multiconfiguration Dirac-Hartree-Fock calculation of Andersson et al. [40] gave A = 1.937 s−1 for this transition. However, their calculated wavelength is 3724.7 Å, significantly shorter than experimental. Adjustment to the experimental wavelength yields Aadj = 1.74 s−1, in good agreement with Prior [37] and Garstang [46]. A similar adjustment of the value of Andersson et al. [40] for the 3d10 1S0–3d94s 3D2 transition at 4375.8 Å (which Andersson et al. [40] calculated to be at 4275.8 Å) gives Aadj = 0.093 s−1, about 30% lower than Garstang’s result. For these two E2 transitions, our A-values calculated with Cowan’s codes are too high by a factor of about 1.7. We assume that our A-value for the predicted 3d94s 3D33D1 E2 transition at 48318 Å, 9 × 10−8 s−1, has a similar low accuracy. The 3d10 1S0–3d94s 1D2 transition at 3806.3 Å was observed by Thackeray [3] and by McKenna et al. [5] in emission spectra of nebulae.
It should be noted that, in addition to the two E2 transitions mentioned above, Andersson et al. [40] give calculated A-values for the magnetic-octupole (M3) and hyperfine-induced 3d10 1S0–3d94s 3D3 transitions at 4559 Å. The latter are different for various HFS components of the two isotopes (63Cu and 65Cu) and are typically on the order of a few times 10−9 s−1, three orders of magnitude greater than for the M3 transition. This transition, as well as the 3d10 1S0–3d94s 3D2 E2 transition at 4375.8 Å, was observed by Aller et al. [4] in the spectrum of the RR Telescopii nebula.
A-values for M1 transitions are relatively easier to calculate than E1 and E2 transitions, since their calculation does not involve radial integrals, but only amplitudes of eigenvector components. We compared our calculated A-values for M1 transitions with those of Garstang [46] and found that all of them agree to better than 15%. We included in Table A1 our A-value for the 3d10 1S0–3d94s 3D1 M1 transition at 4165.7 Å, which was not given by Garstang [46]. It turned out to be extremely small, 2.1 × 10−12 s−1. Our calculation indicates that there is no E2 contribution to the total decay rate of the 3d94s 3D1 level. This makes the identification of the line observed at this wavelength by McKenna et al. [5] with this transition questionable. Possible explanations for this observation could be (1) our calculated M1 A-value is greatly underestimated; (2) there is a considerable contribution of E2 transition to this line, which for unknown reason is computed as negligibly small by Cowan’s codes; (3) hyperfine-induced transition significantly increases the total radiative rate; (4) the population of the 3d94s 3D1 level in RR Telescopii is many orders of magnitude greater than that of 3D2 and 1D2; or (5) the identification is incorrect, and the observed line is possibly due to some other species. As explained above, the first explanation is rather unlikely. To confirm or disprove the second and third explanations, more extensive atomic calculations are needed, while checking the fourth one requires population-kinetics modeling.

7. Conclusions

The present work provides a comprehensive list of all observed, classified, and predicted spectral lines of Cu II, which includes 2557 transitions with wavelengths from 675 Å to 10.9 μm. Over 600 of them were measured in this work using grating and Fourier-transform spectrometers. Experimental wavelengths of 2443 transitions were used in a least-squares level optimization procedure to produce optimized values for 379 energy levels, of which 29 are newly identified, and nine are revised. The previous analysis of Ross [2,16] is largely confirmed. However, our extended base for the levels optimization results in more dependable level values and Ritz wavelengths that can be used as secondary standards in the vacuum ultraviolet region. An improved theoretical interpretation of the energy levels was made by a parametric least-squares fitting with Cowan’s atomic codes, which included all experimental levels. The fitted Slater parameters were used to calculate radiative transition probabilities for electric-dipole, magnetic-dipole, and electric-quadrupole transitions, which were critically evaluated together with other published data to construct a list of recommended A-values for 555 transitions.

Acknowledgments

This work was partially supported by the National Aeronautics and Space Administration (NASA) under interagency agreement NNH10AN38I.

Author Contributions

All authors contributed equally to this work.

Conflicts of Interest

The authors declare no conflict of interest.

Appendix A

Table A1. Spectral lines of Cu II.
Table A1. Spectral lines of Cu II.
λobs a (Å)σobs b (cm−1)λRitz c (Å)Δλobs-Ritz (Å)Iobs d (arb. u.)Char eLower LevelUpper LevelA (s−1)Acc fLine Ref. gTP Ref. gNotes h
675.5994(20)148016.7(4)675.60192(8)−0.002573000 d101S05f(3/2)2[3/2]°1 TW
677.675(3)147563.3(6)677.67816(8)−0.00329000 d101S07p(5/2)2[3/2]°1 TW
685.1377(20)145956.1(4)685.14058(8)−0.0029240000 d101S05f(5/2)2[3/2]°1 TW
685.3922(20)145901.9(4)685.39671(8)−0.004545000 d101S05f(5/2)2[1/2]°1 TW
709.3098(20)140982.1(4)709.31287(9)−0.0031250000 d101S06p(3/2)2[1/2]°1 TW
718.1766(20)139241.5(4)718.17860(9)−0.0020310000 d101S06p(5/2)2[3/2]°1 TW
724.4881(20)138028.5(4)724.48867(9)−0.0006490000 d101S04f(3/2)2[3/2]°1 TW
735.5215(11)135957.95(20)735.52023(9)0.0013780000 d101S04f(5/2)2[3/2]°1 TW
736.0331(8)135863.46(16)736.03185(9)0.0012870000 d101S04f(5/2)2[1/2]°1 TW
763.2658(20)131016.0(3)763.2692(3)−0.0034140000 4s3D3sp(3P)132 TWn
768.4821(20)130126.6(3)768.48565(19)−0.0035150000 4s3D38p(5/2)2[3/2]°2 TWn
776.484(3)128785.6(5)776.4877(3)−0.00458000 4s3D1sp(3P)130 TWn
777.739(3)128577.8(5)777.74333(3)−0.00456000 4s3D28p(5/2)2[3/2]°1 TW
779.2932(20)128321.4(3)779.29473(5)−0.0015590000 4s3D3sp(1D)112 TW
779.328(3)128315.6(5)779.33660(4)−0.008480000 4s3D26f(5/2)2[1/2]°1 TWn
784.9098(20)127403.2(3)784.91229(5)−0.002569000 4s3D2sp(1D)112 TW
786.392(3)127163.1(5)786.39222(4)−0.00021000*4s3D16f(5/2)2[1/2]°1 TWn
786.392(3)127163.1(5)786.39795(4)−0.00621000*4s1D26f(3/2)2[3/2]°2 TW
787.907(3)126918.5(5)787.9056(3)0.00133000 4s3D27p(3/2)2[3/2]°1 TWn
788.012(3)126901.6(5)788.01778(20)−0.00645000 4s1D2sp(1D)111 TWn
789.3937(20)126679.5(3)789.3933(3)0.0004100000*4s1D2sp(3P)132 TWn
789.3937(20)126679.5(3)789.3977(3)−0.0040100000*4s3D27p(3/2)2[5/2]°2 TWn
789.6575(20)126637.2(3)789.65867(5)−0.001159000 4s3D27p(3/2)2[1/2]°1 TWn
794.9719(20)125790.6(3)794.97430(20)−0.002456000 4s1D28p(5/2)2[3/2]°2 TWn
797.4530(20)125399.2(3)797.45499(4)−0.0020560000 4s3D37p(5/2)2[3/2]°2 TW
797.6193(20)125373.1(3)797.6218(5)−0.002535000 4s3D17p(3/2)2[1/2]°0 TWn
798.977(3)125160.0(5)798.97928(3)−0.00223000 4s1D28p(5/2)2[3/2]°1 TW
800.6592(20)124897.1(3)800.66084(5)−0.001726000 4s1D26f(5/2)2[1/2]°1 TWn
801.8229(20)124715.8(3)801.82460(4)−0.001784000 4s3D27p(5/2)2[3/2]°1 TW
803.3370(20)124480.8(3)803.33841(4)−0.001477000 4s3D27p(5/2)2[3/2]°2 TW
806.5454(20)123985.6(3)806.54699(5)−0.0016180000 4s1D2sp(1D)112 TW
809.2942(20)123564.5(3)809.29524(4)−0.001117000 4s3D17p(5/2)2[3/2]°1 TW
809.706(3)123501.6(5)809.7079(3)−0.00212000 4s1D27p(3/2)2[3/2]°1 TWn
809.9630(20)123462.4(3)809.9649(3)−0.001945000 4s1D27p(3/2)2[3/2]°2 TWn
810.9987(20)123304.8(3)810.99829(11)0.0004520000 d101S05p(3/2)2[3/2]°1 TW
810.6365(20)123359.8(3)810.6361(3)0.000586000 4s1D27p(3/2)2[5/2]°3 TWn
811.2843(20)123261.4(3)811.2839(4)0.0004110000 4s1D27p(3/2)2[5/2]°2 TWn
811.5559(20)123220.1(3)811.55946(5)−0.003613000 4s1D27p(3/2)2[1/2]°1 TWn
813.882(3)122867.9(4)813.88328(11)−0.001760000 d101S05p(3/2)2[1/2]°1 TW
823.059(3)121497.9(4)823.05584(4)0.0042000 4s1D27p(5/2)2[5/2]°3 TW
823.8361(18)121383.4(3)823.83758(6)−0.001590000 4s1D27p(5/2)2[5/2]°2 TW
824.4127(20)121298.5(3)824.41507(4)−0.00246100 4s1D27p(5/2)2[3/2]°1 TW
824.6630(19)121261.7(3)824.6649(4)−0.001990000 4s1D27p(5/2)2[7/2]°3 TWn
826.014(3)121063.3(5)826.01546(5)−0.0014400 4s1D27p(5/2)2[3/2]°2 TW
826.9946(22)120919.8(3)826.99598(12)−0.00141100000 d101S05p(5/2)2[3/2]°1 TW
829.360(5)120575.0(8)829.35106(14)0.0087400 4s3D2sp(1G)333 TWn
836.042(20)119611(3)836.02765(3)0.01427000 4s3D36p(3/2)2[3/2]°2 S36c
841.136(3)118886.8(4)841.13445(3)0.00230000 4s3D26p(3/2)2[3/2]°1 TW
842.4973(24)118694.7(3)842.49630(3)0.001066000 4s3D26p(3/2)2[3/2]°2 TW
844.6125(21)118397.5(3)844.61287(4)−0.000388000 4s3D26p(3/2)2[5/2]°2 TW
844.9124(21)118355.5(3)844.91208(4)0.0003410000 4s3D26p(3/2)2[5/2]°3 TW
848.8062(20)117812.5(3)848.80734(3)−0.0011920000 4s3D36p(5/2)2[5/2]°3 TW
849.3599(19)117735.7(3)849.35931(3)0.0006240000 4s3D16p(3/2)2[3/2]°1 TW
850.7481(19)117543.6(3)850.74794(3)0.0001140000 4s3D16p(3/2)2[3/2]°2 TW
851.3012(16)117467.24(23)851.30253(3)−0.00131100000 4s3D36p(5/2)2[7/2]°4 TW
851.776(3)117401.8(4)851.77122(3)0.00421000 4s3D3sp(1G)333 TW
852.9074(21)117246.0(3)852.90622(4)0.0012370000 4s3D16p(3/2)2[5/2]°2 TW
853.5444(24)117158.5(3)853.54260(15)0.001845000 4s1D2sp(1G)333 TWn
855.4770(19)116893.9(3)855.476052(24)0.0009270000 4s3D26p(5/2)2[5/2]°3 TW
855.6994(21)116863.5(3)855.70010(3)−0.0007720000 4s3D2sp(3F)132 TW
858.4844(20)116484.4(3)858.486771(24)−0.0024990000 4s3D2sp(1G)333 TW
858.5639(20)116473.6(3)858.566433(20)−0.0025890000 4s3D36p(5/2)2[7/2]°3 TW
859.1522(24)116393.8(3)859.15072(3)0.001414000 4s3D26p(5/2)2[3/2]°1 TW
860.7214(24)116181.6(3)860.72158(4)−0.000122000 4s3D26p(5/2)2[5/2]°2 TW
861.9932(11)116010.19(14)861.99338(6)−0.00021900000 4s3D3sp(1G)334 TW
862.8221(20)115898.7(3)862.82245(4)−0.000378000 4s3D26p(5/2)2[3/2]°2 TW
864.163(4)115718.9(5)864.15435(3)0.009130000 4s3D3sp(3P)312 TW
864.214(3)115712.0(4)864.21371(3)0.001670000 4s3D1sp(3F)132 TW
865.3907(8)115554.74(11)865.389986(23)0.00071600000 4s3D26p(5/2)2[7/2]°3 K66
866.4430(20)115414.4(3)866.442524(13)0.000564000 4s3D24f(3/2)2[7/2]°3 TW
867.7321(21)115242.9(3)867.73348(3)−0.0014320000 4s3D16p(5/2)2[3/2]°1 TW
869.0634(18)115066.40(24)869.06394(3)−0.0005250000 4s3D2sp(3F)131 TW
869.3338(24)115030.6(3)869.33592(4)−0.00211200000 4s3D16p(5/2)2[5/2]°2 TW
870.5390(18)114871.37(24)870.538673(24)0.0003240000 4s3D3sp(3F)132 TW
871.0674(18)114801.68(24)871.06737(3)0.0000130000 4s3D2sp(3P)312 TW
873.2629(21)114513.0(3)873.262654(21)0.0003310000 4s3D3sp(3F)133 TW
876.7226(20)114061.2(3)876.722436(13)0.0002830000 4s3D34f(5/2)2[7/2]°3 TW
876.973(5)114028.6(7)876.962109(24)0.011420000 4s3D14f(3/2)2[3/2]°1 TW
877.0107(24)114023.7(3)877.01184(4)−0.0012890000 4s3D3sp(3P)352 TW
877.5531(20)113953.2(3)877.554632(23)−0.0015820000 4s3D2sp(3F)132 TW
877.8469(21)113915.1(3)877.84692(3)0.0000610000 4s3D1sp(3F)131 TW
878.6984(8)113804.69(10)878.69833(3)0.00011500000 4s3D3sp(3F)133 K66
879.8897(24)113650.6(3)879.89110(3)−0.001421000 4s3D1sp(3P)312 TW
880.3225(24)113594.7(3)880.322766(20)−0.000338000 4s3D2sp(3F)133 TW
881.473(3)113446.4(4)881.47711(3)−0.0043100 4s1D2sp(3F)132 TW
883.2800(20)113214.4(3)883.27981(3)0.000241000 4s3D1sp(1G)332 TW,S36r
883.8404(20)113142.6(3)883.838830(10)0.001655000 4s3D24f(5/2)2[7/2]°3 TW
884.1340(21)113105.0(3)884.13295(4)0.0011290000 4s3D2sp(3P)352 TW
884.4346(18)113066.58(23)884.43449(3)0.0001420000 4s1D2sp(1G)333 TW
884.8262(20)113016.5(3)884.826019(13)0.000234000 4s3D24f(5/2)2[1/2]°1 TW
885.8463(20)112886.4(3)885.846966(24)−0.0006770000 4s3D2sp(3F)133 TW
886.4163(24)112813.8(3)886.413782(20)0.002525000 4s3D3sp(3F)134 TW
886.5113(20)112801.7(3)886.510950(24)0.0004280000 4s3D1sp(3F)132 TW
886.9435(8)112746.75(10)886.94322(3)0.00031300000 4s3D3sp(3P)332 K66
890.5677(6)112287.93(8)890.56671(3)0.00101300000 4s3D2sp(3P)331 K66
891.7636(24)112137.3(3)891.76309(3)0.000523000 4s1D26p(5/2)2[7/2]°3 TW
892.4154(6)112055.44(8)892.41418(3)0.00121100000 4s3D3sp(3P)333 K66
893.634(5)111902.7(7)893.624985(19)0.0091100000 4s3D14f(5/2)2[1/2]°0 TW
893.6787(6)111897.04(8)893.67746(3)0.0012940000 4s3D3sp(3P)332 K66
894.2260(20)111828.56(25)894.227192(24)−0.0012860000 4s3D2sp(3P)332 TW
896.7583(15)111512.77(19)896.758608(23)−0.00031000000 4s3D2sp(3P)331 TW
896.9741(20)111485.94(25)896.97600(3)−0.0019870000 4s3D1sp(3P)330 TW
897.7927(18)111384.29(22)897.79300(3)−0.0003410000 4s1D2sp(3P)312 TW
899.7904(18)111136.99(22)899.78867(3)0.0018910000*4s3D2sp(3P)333 TW
899.7904(18)111136.99(22)899.79200(3)−0.0016910000*4s3D1sp(3P)331 TW
901.0757(16)110978.47(20)901.07654(7)−0.0009660000*4s1D2sp(3P)311 TW,S36r
901.0757(16)110978.47(20)901.07292(3)0.0027660000*4s3D2sp(3P)332 TW
901.322(3)110948.2(4)901.32128(3)0.00025000 4s1D2sp(1G)332 TWn
903.522(6)110678.0(7)903.52887(3)−0.00716000 4s3D1sp(3P)332 S36c
906.1130(20)110361.52(24)906.11330(3)−0.0003670000 4s3D1sp(3P)331 TW
910.5183(21)109827.56(25)910.51831(3)−0.0000240000 4s3D1sp(3P)332 TW
911.630109693.6911.629867(16) 15000:4s1D24f(5/2)2[3/2]°1 S36c
911.679109687.7911.67901(4) 15000:4s1D2sp(3P)352 S36c
912.025109646.2912.024525(12) 7400:4s1D24f(5/2)2[3/2]°2 S36c
912.4142(24)109599.3(3)912.415956(16)−0.001815000 4s1D24f(5/2)2[1/2]°1 TW
913.47(4)109472(5)913.50160(3)−0.037300 4s1D2sp(3F)133 S36c
914.2128(6)109383.72(7)914.21305(11)−0.0003830000 4s3D3sp(3P)354 K66
917.3051(20)109014.98(23)917.30556(8)−0.0004380000 4s3D3sp(3P)352 TW
922.0188(8)108457.66(9)922.01869(14)0.0001520000 4s3D3sp(1D)332 K66
922.4141(16)108411.18(19)922.41586(3)−0.0018350000 4s1D2sp(3P)332 TW
924.2381(8)108197.23(9)924.23840(7)−0.0003550000 4s3D2sp(3P)353 K66
925.119(10)108094.2(12)925.09896(8)0.020510000*4s3D2sp(3P)352 TW
925.119(10)108094.2(12)925.10963(3)0.009510000*4s1D2sp(3P)331 TW
925.119(10)108094.2(12)925.12612(7)−0.007510000*4s3D2sp(3P)351 TW
929.702(3)107561.4(3)929.70175(3)0.00018000 4s1D2sp(3P)332 TW
929.8940(20)107539.14(23)929.89272(14)0.001318000 4s3D2sp(1D)332 TW
932.9398(8)107188.05(9)932.93989(10)−0.0001590000 4s3D3sp(1D)3331.7e+08CK66B00
934.9761(18)106954.61(21)934.97102(14)0.0050280000?4s3D1sp(3P)350 TWn
935.0564(14)106945.42(17)935.05755(8)−0.0012380000 4s3D1sp(3P)352 TW
935.08529(7) m4s3D1sp(3P)351 S36c
935.2307(22)106925.49(25)935.23232(7)−0.0016450000 4s3D3sp(1D)332 TW
935.3408(18)106912.90(20)935.34317(5)−0.0023360000 4s3D2sp(1D)331 TW
935.892(3)106849.9(3)935.89753(15)−0.006620000 4s3D3sp(1D)3341.12e+08CTWB00
937.815(6)106630.8(7)937.81726(7)−0.00248000 4s3D3sp(1D)333 S36c
939.5218(15)106437.12(16)939.52288(6)−0.0010190000 4s3D3sp(1D)332 TW
943.3333(18)106007.07(20)943.33466(7)−0.0014580000 4s3D2sp(1D)3321.4e+08CTWB00
945.5223(17)105761.65(19)945.52474(6)−0.0025510000 4s3D1sp(1D)331 TW
945.8771(21)105721.98(24)945.87663(7)0.0005400000 4s3D2sp(1D)331 TW
945.9614(21)105712.56(24)945.96464(7)−0.0033460000 4s3D2sp(1D)3331.1e+08CTWB00
947.6989(17)105518.74(19)947.70005(6)−0.001114000 4s3D2sp(1D)332 TW
951.4068(15)105107.51(16)951.40774(8)−0.001024000 4s3D1sp(1D)330 TW
954.3815(15)104779.91(16)954.38279(7)−0.0013270000 4s1D2sp(3P)353 TW
955.306(5)104678.5(6)955.30043(8)0.0059900 4s1D2sp(3P)352 TW
955.320(5)104677.0(6)955.32939(7)−0.0099900 4s1D2sp(3P)351 TW
956.2871(17)104571.11(19)956.29010(7)−0.0030300000 4s3D1sp(1D)3311.8e+08CTWB00
958.1503(17)104367.76(19)958.15393(6)−0.0037380000 4s3D1sp(1D)3321.6e+08CTWB00
960.4115(17)104122.04(19)960.41317(15)−0.0017270000 4s1D2sp(1D)332 TW
966.2283(21)103495.21(23)966.22839(6)−0.000111000 4s1D2sp(1D)331 TW
967.8711(21)103319.54(23)967.87255(7)−0.00154800 4s3D3sp(3P)352 TW
968.0392(17)103301.60(18)968.04176(16)−0.0025250000 4s3D3sp(3P)353 TW
972.2703(19)102852.06(20)972.26872(10)0.001624000 4s1D2sp(1D)333 TW
973.509(10)102721.2(11)973.49928(20)0.01018000 4s3D2sp(3P)351 S36c
974.7581(15)102589.56(15)974.75876(8)−0.0007200000 4s1D2sp(1D)332 TW
976.5524(15)102401.06(15)976.55293(7)−0.0005110000 4s3D2sp(3P)352 TW
976.7238(17)102383.09(18)976.72519(17)−0.001435000 4s3D2sp(3P)353 TW
977.5662(13)102294.86(14)977.56714(7)−0.0009190000 4s1D2sp(1D)333 TW
979.4200(15)102101.25(16)979.42055(6)−0.000612000 4s1D2sp(1D)332 TW
984.02(4)101624(4)983.979887(19)0.049100 4s3D35p(3/2)2[3/2]°2 S36c
984.5331(15)101570.98(15)984.53339(21)−0.000388000 4s3D1sp(3P)351 TW
987.6568(12)101249.75(12)987.65677(8)−0.000061000 4s3D1sp(3P)352 TW
989.2364(12)101088.07(12)989.236270(17)0.000230000 4s3D35p(3/2)2[5/2]°3 TW
992.9530(13)100709.70(13)992.952929(16)0.0001210000 4s3D25p(3/2)2[3/2]°2 TW
998.3067(14)100169.62(14)998.305876(14)0.000840000 4s3D25p(3/2)2[5/2]°3 TW
999.797(3)100020.3(3)999.793812(15)0.0037600 4s3D25p(3/2)2[1/2]°1 TW
1001.0129(19)99898.81(19)1001.012710(14)0.000222000 4s3D25p(3/2)2[5/2]°2 TW
1004.0540(17)99596.24(17)1004.055195(18)−0.0012330000 4s3D3sp(3F)313 TW
1006.980(6)99306.8(6)1006.983925(18)−0.00413000 4s3D15p(3/2)2[3/2]°1 S36c
1008.5674(17)99150.54(16)1008.568623(17)−0.0012290000 4s3D35p(5/2)2[5/2]°3 TW
1008.7274(17)99134.81(16)1008.728151(15)−0.0008310000 4s3D2sp(3F)312 TW
1010.2680(17)98983.64(16)1010.26867(8)−0.0007320000 4s1D2sp(3P)352 TW
1010.4520(18)98965.61(18)1010.45303(18)−0.001148000 4s1D2sp(3P)353 TW
1010.640(3)98947.2(3)1010.639186(19)0.00118000 4s3D35p(5/2)2[5/2]°2 TW
1011.43698869.41011.435606(17) 29000:4s3D15p(3/2)2[1/2]°1 S36c
1012.5956(18)98756.11(18)1012.596906(18)−0.0013290000 4s3D35p(5/2)2[7/2]°3 TW
1012.6813(18)98747.75(18)1012.683073(16)−0.001750000 4s3D15p(3/2)2[5/2]°2 TW
1013.382(20)98679.5(19)1013.399849(15)−0.01815000 4s3D2sp(3F)313 S36c
1017.9976(18)98232.06(18)1017.997872(13)−0.000270000 4s3D25p(5/2)2[5/2]°3 TW
1018.0628(19)98225.77(18)1018.064039(22)−0.0013180000 4s3D15p(3/2)2[1/2]°0 TW
1018.7031(24)98164.03(23)1018.707024(17)−0.0039550000 4s3D35p(5/2)2[3/2]°2 TW
1019.6525(18)98072.62(17)1019.654307(13)−0.0018240000 4s3D25p(5/2)2[3/2]°1 TW
1020.1070(18)98028.93(18)1020.107372(16)−0.0004280000 4s3D25p(5/2)2[5/2]°2 TW
1022.10297837.61022.101982(13) 91000:4s3D25p(5/2)2[7/2]°3 S36c
1027.825(3)97292.8(3)1027.830823(19)−0.0061800000 4s1D25p(3/2)2[3/2]°21.7e+08CTWB00
1028.3251(18)97245.51(17)1028.327701(13)−0.0026670000 4s3D25p(5/2)2[3/2]°2 TW
1029.7493(18)97111.01(17)1029.750492(24)−0.0012290000 4s3D3sp(3F)332 TW
1030.2612(18)97062.76(17)1030.26297(7)−0.0017500000 4s3D3sp(3F)314 TW
1031.7650(18)96921.30(17)1031.766015(15)−0.0010240000 4s3D15p(5/2)2[3/2]°1 TW
1033.5668(18)96752.33(17)1033.567510(18)−0.0007200000 4s1D25p(3/2)2[5/2]°3 TW
1035.161(3)96603.3(3)1035.162498(19)−0.00185000 4s1D25p(3/2)2[1/2]°1 TW
1036.465(3)96481.8(3)1036.469217(18)−0.0041800000 4s1D25p(3/2)2[5/2]°21.01e+08CTWB00
1039.341(3)96214.8(3)1039.34743(3)−0.0062100000 4s3D3sp(3F)3332.0e+08CTWB00
1039.579(3)96192.8(3)1039.581895(21)−0.0031900000 4s3D2sp(3F)3322.0e+08CTWB00
1044.5185(8)95737.89(7)1044.51849(6)0.00002300000 4s3D3sp(3F)3342.3e+08CK66B00
1044.7437(8)95717.26(7)1044.743170(19)0.00052200000 4s1D2sp(3F)3124.8e+08CK66B00
1049.3642(18)95295.80(17)1049.363833(22)0.0004770000 4s3D2sp(3F)3331.11e+08CTWB00
1049.7551(6)95260.31(5)1049.755242(19)−0.00012100000 4s1D2sp(3F)3131.04e+08CK66B00
1050.1523(18)95224.28(17)1050.15339(3)−0.0010530000 4s3D2sp(3F)3311.4e+08CTWB00
1050.4013(18)95201.71(17)1050.40243(3)−0.0012520000 4s3D3sp(3F)3328.2e+07CTWB00
1052.1742(18)95041.30(16)1052.174562(23)−0.00041000000 4s3D1sp(3F)3327.3e+07CTWB00
1054.6907(6)94814.53(5)1054.689891(17)0.00082800000 4s1D25p(5/2)2[5/2]°32.1e+08CK66B00
1055.792(3)94715.6(3)1055.79644(4)−0.0052500000 4s3D3sp(3F)3332.1e+08CTWB00
1056.9549(6)94611.42(5)1056.954368(20)0.00052300000 4s1D25p(5/2)2[5/2]°24.0e+08CK66B00
1058.798(3)94446.7(3)1058.79854(4)−0.0001800000 4s3D3sp(3F)3331.9e+08CTWB00
1059.0963(8)94420.12(7)1059.095825(18)0.00051400000 4s1D25p(5/2)2[7/2]°3 K66
1060.631(3)94283.5(3)1060.63409(3)−0.0031700000 4s3D2sp(3F)3323.0e+08CTWB00
1063.0027(18)94073.14(16)1063.00505(3)−0.00241400000 4s3D1sp(3F)3314.2e+08CTWB00
1065.7837(18)93827.67(16)1065.781839(17)0.0019560000 4s1D25p(5/2)2[3/2]°2 TW
1066.1356(18)93796.70(16)1066.13397(4)0.0017590000 4s3D2sp(3F)333 TW
1069.1944(18)93528.36(16)1069.19523(4)−0.00081000000 4s3D2sp(3F)3331.03e+08CTWB00
1070.3134(18)93430.58(16)1070.31087(6)0.0025380000 4s3D3sp(3F)334 TW
1073.7444(18)93132.04(16)1073.74516(3)−0.0008720000 4s3D1sp(3F)3321.5e+08CTWB00
1077.889(20)92773.9(17)1077.87559(3)0.01320000 4s1D2sp(3F)332 S36c
1086.1134(18)92071.42(15)1086.10984(8)0.003672000 4s3D3sp(3F)353 TW
1088.405(5)91877.6(4)1088.39510(3)0.010270000 4s1D2sp(3F)333 TW
1089.237(6)91807.4(5)1089.24451(3)−0.00739000 4s1D2sp(3F)331 S36c
1091.293(3)91634.43(24)1091.29136(8)0.00140000 4s3D2sp(3F)352 TW
1094.399(3)91374.35(24)1094.40214(8)−0.003440000 4s3D3sp(3F)354 TW
1097.0512(18)91153.45(15)1097.05257(8)−0.0014320000 4s3D2sp(3F)353 TW
1100.523(3)90865.86(24)1100.52419(3)−0.00125000 4s1D2sp(3F)332 TW
1101.836(6)90757.6(5)1101.83633(13)−0.0008200 4s3D1sp(3F)351 S36c
1105.1751(18)90483.40(15)1105.17629(8)−0.001260000 4s3D1sp(3F)352 TW
1106.44790379.41106.44670(4) 23000:4s1D2sp(3F)333 S36c
1109.74490110.91109.74420(4) 7200:4s1D2sp(3F)333 S36c
1111.753(6)89948.0(5)1111.75742(11)−0.0043000 4s3D3sp(3F)353 S36c
1119.9480(18)89289.86(15)1119.94659(11)0.001498000 4s3D3sp(3F)354 TW
1123.2265(18)89029.24(14)1123.22580(11)0.000721000 4s3D2sp(3F)353 TW
1127.2516(18)88711.34(14) 18000 4p3210s(3/2)2[3/2]1 TWn
1130.888(12)88426.1(9)1130.8852(3)0.0034500*4s3D1sp(3F)352 S36c
1130.888(12)88426.1(9)1130.89779(11)−0.0104500*4p319s(3/2)2[3/2]2 S36c
1130.96216(16) m4p328d(5/2)2[3/2]1 S36cn
1135.3657(18)88077.35(14)1135.34826(20)0.01748200?4p3310s(5/2)2[5/2]2 TW X
1142.6393(18)87516.68(14)1142.64027(10)−0.000973000 4s3D2sp(3F)352 TW
1144.853(3)87347.48(22)1144.85531(8)−0.003120000 4s3D3sp(3F)353 TW
1147.7628(18)87126.02(14) 25000 4s3D1sp(3F)351 TW
1157.0194(18)86428.97(14)1157.02043(8)−0.001015000 4s3D2sp(3F)353 TW
1157.8714(18)86365.38(14)1157.87172(10)−0.000419000 4s3D1sp(3F)352 TW
1157.88056(11) m4p319s(5/2)2[5/2]2 TW
1162.5991(18)86014.17(13)1162.60059(14)−0.00156300 4s3D3sp(3F)354 TW
1185.89984324.21185.89903(5) 19000:4p328s(5/2)2[5/2]3 S36c
1201.627(6)83220.5(4)1201.62566(8)0.00118000 4p337d(5/2)2[9/2]4 S36c
1204.643(20)83012.1(14)1204.61568(7)0.0279100*4p347d(5/2)2[7/2]4 S36c
1204.643(20)83012.1(14)1204.63538(5)0.0089100*4p347d(5/2)2[7/2]3 S36c
1204.643(20)83012.1(14)1204.65288(9)−0.0109100*4s1D2sp(3F)353 S36c
1205.180(12)82975.2(8)1205.14656(6)0.0344800*4p347d(5/2)2[5/2]3 S36c
1205.180(12)82975.2(8)1205.19424(8)−0.0144800*4p137d(3/2)2[5/2]3 S36c
1205.180(12)82975.2(8)1205.2024(3)−0.0224800*4p329s(3/2)2[3/2]1 S36c
1205.180(12)82975.2(8)1205.21874(7)−0.0394800*4p328s(3/2)2[3/2]2 S36cn
1205.901(6)82925.5(4)1205.90271(8)−0.00218000 4p347d(5/2)2[9/2]5 S36c
1206.771(6)82865.8(4)1206.76906(5)0.0024400 4p318s(5/2)2[5/2]2 S36c
1214.54082335.71214.53971(8) 9600:4p339s(5/2)2[5/2]3 S36c
1214.55482334.71214.55446(5) 8600:4p338s(5/2)2[5/2]2 S36c
1219.33482012.01219.33363(5) 8500:4p348s(5/2)2[5/2]3 S36c
1235.93(5)80911(3)1235.87291(5)0.064000 4p328s(5/2)2[5/2]2 S36c
1240.026(6)80643.5(4)1240.02707(5)−0.0017400 4p316d(3/2)2[3/2]2 S36c
1241.96480517.61241.96398(3) 14000:4p327s(3/2)2[3/2]2 S36c
1243.03(5)80448(3)1243.08557(6)−0.057300 4p316d(3/2)2[1/2]1 S36c
1248.796(3)80077.12(17)1248.79156(5)0.00526000 4p326d(5/2)2[5/2]3 TW
1250.058(4)79996.30(22)1250.04822(6)0.01069000 4p326d(5/2)2[3/2]2 TW
1253.185(3)79796.67(17)1253.18074(7)0.00425000 4p326d(5/2)2[1/2]1 TW
1255.163(6)79670.9(4)1255.15693(6)0.0066800 4p306d(3/2)2[3/2]1 S36c
1257.675(6)79511.8(4)1257.68320(7)−0.0086700 4p306d(3/2)2[1/2]1 S36c
1261.214(6)79288.7(4)1261.21537(5)−0.0013500 4p128s(5/2)2[5/2]2 S36c
1262.929(6)79181.0(4)1262.92481(9)0.00419000 4p316d(5/2)2[1/2]0 S36c
1265.510(3)79019.53(17)1265.50624(3)0.00472000 4p317s(3/2)2[3/2]2 TW
1266.313(3)78969.42(17)1266.30992(4)0.00327000 4p317s(3/2)2[3/2]1 TW
1268.71(5)78820(3)1268.66846(5)0.043300 4p338s(5/2)2[5/2]3 S36c
1269.446(6)78774.5(4)1269.44626(6)0.0006200 4p326d(3/2)2[5/2]2 S36c
1271.327(6)78658.0(4)1271.31771(4)0.01012000 4p316d(5/2)2[5/2]2 S36c
1272.043(3)78613.69(17)1272.04165(6)0.00131000 4p326d(3/2)2[7/2]3 TW
1273.705(6)78511.1(4)1273.70053(5)0.00511000 4p316d(5/2)2[3/2]1 S36c
1274.07178488.61274.07065(3) 17000:4p337s(3/2)2[3/2]2 S36c
1274.46578464.31274.46493(3) 16000:4p327s(5/2)2[5/2]2 S36c
1275.5713(15)78396.24(9)1275.57159(3)−0.000375000 4p327s(5/2)2[5/2]3 TW
1279.948(20)78128.2(12)1279.96123(5)−0.0132700 4p336d(5/2)2[5/2]2 S36c
1280.271(3)78108.48(17)1280.26800(4)0.00330000 4p336d(5/2)2[7/2]3 TW,S36r
1281.094(3)78058.29(17)1281.09394(9)−0.00010000 s23F47p(5/2)2[5/2]°3 TW
1281.228(20)78050.1(12)1281.25682(6)−0.02916000 4p336d(5/2)2[5/2]3 S36c
1281.462(3)78035.88(17)1281.46142(4)0.00044000 4p307s(3/2)2[3/2]1 TW
1282.455(3)77975.44(17)1282.45466(5)0.00072000 4p336d(5/2)2[9/2]4 TW
1283.824(6)77892.3(4)1283.82966(10)−0.0055300 s23F47p(5/2)2[7/2]°4 S36c
1284.872(3)77828.74(16)1284.87116(5)0.00136000 4p346d(5/2)2[7/2]4 TW
1285.521(6)77789.5(4)1285.51841(5)0.0035400 4p136d(3/2)2[5/2]3 S36c
1285.901(20)77766.5(12)1285.92203(6)−0.0215100 4p346d(5/2)2[5/2]3 S36c
1287.43101(6) m4p136d(3/2)2[7/2]4 TW
1287.4690(8)77671.77(5)1287.46810(6)0.000953000 4p346d(5/2)2[9/2]5 K66
1297.550(4)77068.31(21)1297.54980(3)0.0004900 4p327s(3/2)2[3/2]2 TW
1297.979(20)77042.8(12)1297.9922(9)−0.0134900 s23F27p(3/2)2[3/2]°1 S36cn
1298.3952(8)77018.15(5)1298.39471(4)0.000560000 4p327s(3/2)2[3/2]1 K66
1298.917(12)76987.2(7)1298.90527(6)0.0124700 4p126d(3/2)2[7/2]3 S36c
1299.2684(8)76966.39(5)1299.26777(3)0.000644000 4p317s(5/2)2[5/2]2 K66
1303.661(4)76707.04(21)1303.66001(5)0.0012900 4p326d(5/2)2[5/2]2 TW
1303.978(3)76688.38(16)1303.97824(4)0.0006400 4p326d(5/2)2[7/2]3 TW
1305.562(3)76595.40(16)1305.56082(6)0.00119000 4p336d(3/2)2[7/2]4 TW
1308.2982(6)76435.17(4)1308.29687(3)0.001399000 4p337s(5/2)2[5/2]2 K66
1309.464(3)76367.12(16)1309.46310(3)0.00152000 4p337s(5/2)2[5/2]3 TW
1311.76(4)76233.5(23)1311.79458(10)−0.043900 s23F37p(5/2)2[5/2]°3 S36c
1314.1498(8)76094.83(5)1314.14936(4)0.000450000 4p137s(3/2)2[3/2]2 K66
1314.3371(6)76083.98(3)1314.33637(3)0.0007150000 4p347s(5/2)2[5/2]3 K66
1320.687(3)75718.15(16)1320.68581(5)0.00230000 4p136d(5/2)2[7/2]4 TW
1321.798(3)75654.53(16)1321.79611(6)0.00211000 4p136d(5/2)2[5/2]3 TW
1322.628(6)75607.0(3)1322.63248(13)−0.00421000 4p116d(3/2)2[1/2]0 S36c
1323.188(20)75575.0(11)1323.20408(6)−0.0169700 4p136d(5/2)2[3/2]2 S36c
1323.812(20)75539.4(11)1323.79410(6)0.01821000 4p316d(3/2)2[5/2]2 S36c
1325.272(20)75456.2(11)1325.24199(5)0.0303300 4p316d(3/2)2[3/2]2 S36c
1325.515(3)75442.39(15)1325.51345(3)0.0018300 4p127s(3/2)2[3/2]2 TW
1326.396(3)75392.26(15)1326.39519(4)0.00128000 4p127s(3/2)2[3/2]1 TW
1328.415(3)75277.66(15)1328.41289(5)0.00212000 4p326d(3/2)2[5/2]3 TW
1329.656(20)75207.4(11)1329.66943(6)−0.0143100 4p326d(3/2)2[3/2]2 S36c
1331.892(3)75081.17(15)1331.89052(5)0.00114000 4p126d(5/2)2[5/2]2 TW
1332.224(3)75062.46(15)1332.22268(4)0.00117000 4p126d(5/2)2[7/2]3 TW
1333.0457(8)75016.18(5)1333.04501(3)0.000758000 4p337s(3/2)2[3/2]2 K66
1333.06670(3) m4p327s(5/2)2[5/2]2 TW
1334.56(4)74931.2(22)1334.50604(5)0.055500p4p126d(5/2)2[3/2]1 S36c X
1334.650(4)74926.02(20)1334.65445(7)−0.0055800 4p116d(3/2)2[3/2]1 TW
1334.686(6)74924.0(3)1334.68792(17)−0.0021500 s23F27p(5/2)2[5/2]°2 TW
1337.55(4)74763.8(22)1337.51122(8)0.031400 4p116d(3/2)2[1/2]1 S36c
1339.46(4)74656.7(22)1339.49492(5)−0.031300 4p336d(5/2)2[5/2]2 S36c
1339.7734(23)74639.49(13)1339.77126(5)0.002214000 4p336d(5/2)2[7/2]4 TW
1340.9161(23)74575.88(13)1340.91390(6)0.00226700 4p336d(5/2)2[5/2]3 TW
1350.5963(20)74041.37(11)1350.59358(4)0.002729000 4p137s(5/2)2[5/2]2 TW
1351.8384(8)73973.34(4)1351.83646(3)0.001953000 4p137s(5/2)2[5/2]3 K66
1355.3066(8)73784.04(4)1355.30507(4)0.001536000 4p317s(3/2)2[3/2]1 K66
1358.7736(6)73595.78(3)1358.7729(3)0.000715000000 d101S04p113.3e+08C+K66B09
1359.0107(8)73582.94(4)1359.00914(3)0.001638000 4p327s(3/2)2[3/2]2 K66
1359.9394(20)73532.69(11)1359.93602(4)0.003411000 4p327s(3/2)2[3/2]1 TW
1362.6004(6)73389.09(3)1362.59959(3)0.000849000 4p127s(5/2)2[5/2]2 K66
1363.506(2)73340.36(13)1363.50304(4)0.00312000 4p117s(3/2)2[3/2]2 TW
1367.9508(6)73102.04(3)1367.9509(3)−0.00015800000 d101S04p318.3e+07C+K66D05
1370.257(6)72979.0(3)1370.25181(6)0.0052700 4p116d(5/2)2[5/2]2 S36c
1370.561(3)72962.83(18)1370.55975(3)0.0011800 4p337s(5/2)2[5/2]2 TW
1371.8400(6)72894.80(3)1371.83967(3)0.000343000 4p337s(5/2)2[5/2]3 K66
1375.522(20)72699.7(11)1375.50173(4)0.0206900 4p325d(3/2)2[5/2]3 S36c
1393.129(2)71780.88(13)1393.12738(3)0.00118000 4p317s(5/2)2[5/2]2 TW
1398.6428(16)71497.88(8)1398.64196(11)0.000940000 s23F46p(3/2)2[5/2]°3 TW
1399.3532(17)71461.59(9)1399.35262(3)0.000515000 4p327s(5/2)2[5/2]3 TW
1402.7785(8)71287.09(4)1402.77693(4)0.001698000 4p117s(5/2)2[5/2]2 K66
1403.985(3)71225.85(16)1403.99171(5)−0.0074900 4p315d(3/2)2[5/2]2 TW
1407.1688(16)71064.68(8)1407.16862(5)0.000160000 4p315d(3/2)2[3/2]2 TW
1408.8131(23)70981.74(12)1408.81230(5)0.00084900 4p315d(3/2)2[3/2]1 TW
1414.4390(19)70699.41(10)1414.4371(4)0.001926000 s23F2sp(1G)333 TWn
1414.8980(15)70676.47(8)1414.89768(6)0.000349000 4p315d(3/2)2[1/2]1 TW
1418.4250(14)70500.73(7)1418.42631(3)−0.0014140000 4p325d(5/2)2[5/2]3 TW
1419.7465(20)70435.11(10)1419.74554(4)0.00107500 4p335d(3/2)2[7/2]4 TW
1421.3746(13)70354.43(7)1421.37346(5)0.001135000 4p325d(5/2)2[3/2]1 TW
1421.7587(6)70335.42(3)1421.75866(4)0.0000200000 4p325d(5/2)2[3/2]2 K66
1427.5920(12)70048.03(6)1427.59106(6)0.000958000 4p305d(3/2)2[3/2]1 TW
1427.8283(8)70036.43(4)1427.82905(7)−0.0007180000 s23F46p(5/2)2[5/2]°3 K66
1428.3572(8)70010.50(4)1428.35801(11)−0.0008190000 s23F36p(3/2)2[3/2]°2 K66
1430.2425(8)69918.21(4)1430.24252(5)−0.0000240000 4p325d(5/2)2[1/2]1 K66
1433.8415(12)69742.72(6)1433.84011(7)0.001453000 4p305d(3/2)2[1/2]1 TW
1434.452(3)69713.01(13)1434.45240(14)−0.0003600 s23F36p(3/2)2[5/2]°2 TWn
1434.7712(12)69697.52(6)1434.76999(8)0.001376000 4p315d(5/2)2[1/2]0 TW
1434.9035(6)69691.10(3)1434.90377(9)−0.0003270000 s23F46p(5/2)2[7/2]°4 K66
1435.3153(13)69671.10(6)1435.31565(13)−0.0004110000 s23F36p(3/2)2[5/2]°3 TW
1436.2352(12)69626.48(6)1436.23585(7)−0.0007130000 s23F4sp(1G)333 TW
1442.1398(12)69341.40(6)1442.13845(4)0.001466000 4p326s(3/2)2[3/2]2 TW
1443.5423(12)69274.04(6)1443.54170(6)0.000673000 4p325d(3/2)2[5/2]2 TW
1444.1295(22)69245.87(10)1444.13017(4)−0.00077700 4p326s(3/2)2[3/2]1 TW
1445.9841(12)69157.05(6)1445.98335(4)0.000797000 4p315d(5/2)2[5/2]2 TW
1446.9008(22)69113.24(10)1446.90033(6)0.00054600 4p325d(3/2)2[3/2]2 TW
1448.6390(19)69030.31(9)1448.63819(6)0.00086100 4p325d(3/2)2[3/2]1 TW
1449.0578(8)69010.36(4)1449.05784(12)−0.0000180000 s23F26p(3/2)2[3/2]°1 K66
1450.3032(12)68951.10(6)1450.30363(4)−0.0004170000 4p325d(3/2)2[7/2]3 TW
1452.2950(12)68856.53(6)1452.29331(5)0.001797000 4p315d(5/2)2[3/2]1 TW
1452.670(20)68838.7(9)1452.69545(4)−0.0253600 4p315d(5/2)2[3/2]2 S36c
1455.6643(13)68697.16(6)1455.66225(7)0.002122000 s23F46p(5/2)2[7/2]°3 TW
1457.1778(12)68625.81(6)1457.17554(5)0.002355000 4p335d(5/2)2[5/2]2 TW
1458.0022(6)68587.00(3)1458.00133(5)0.0009150000 4p335d(5/2)2[7/2]3 K66
1459.4131(6)68520.70(3)1459.41216(15)0.0009220000 s23F26p(3/2)2[5/2]°2 K66
1460.3076(13)68478.72(6)1460.30573(14)0.001814000 s23F26p(3/2)2[5/2]°3 TW
1460.4620(13)68471.48(6)1460.45917(4)0.002817000 4p335d(5/2)2[5/2]3 TW
1461.5557(11)68420.25(5)1461.55369(5)0.002060000 4p315d(5/2)2[1/2]1 TW
1462.8534(18)68359.55(9)1462.85242(6)0.00105100 s23F44f(3/2)2[9/2]°5 TW
1463.7512(6)68317.62(3)1463.75130(4)−0.0001350000 4p335d(5/2)2[9/2]4 K66
1463.8367(6)68313.63(3)1463.83785(5)−0.0012200000 4p345d(5/2)2[7/2]4 K66
1463.9947(12)68306.26(6)1463.99219(5)0.002520000 4p335d(5/2)2[3/2]2 TW
1464.1173(22)68300.54(10)1464.11637(6)0.00094600 4p135d(3/2)2[5/2]2 TW
1464.6035(11)68277.86(5)1464.60141(5)0.002169000 4p135d(3/2)2[5/2]3 TW
1465.0339(18)68257.81(9)1465.03633(14)−0.00244300 s23F26p(3/2)2[1/2]°1 TW
1465.5404(6)68234.22(3)1465.54069(16)−0.0003170000 s23F4sp(1G)334 K66
1466.0705(6)68209.54(3)1466.07026(9)0.0002280000 s23F36p(5/2)2[5/2]°3 K66
1466.5247(10)68188.42(5)1466.52373(4)0.001079000 4p345d(5/2)2[5/2]3 K66
1466.7305(12)68178.85(6)1466.72839(10)0.002242000 s23F3sp(3F)132 TW
1467.574(5)68139.68(24)1467.57153(6)0.0021400 4p135d(3/2)2[3/2]2 TW
1469.6935(6)68041.40(3)1469.69291(5)0.0006150000 4p135d(3/2)2[7/2]4 K66
1469.8457(12)68034.35(5)1469.84329(5)0.002449000 4p345d(5/2)2[9/2]4 TW
1470.6970(6)67994.97(3)1470.69711(4)−0.0001500000 4p345d(5/2)2[9/2]5 K66
1471.072(5)67977.65(24)1471.07289(5)−0.0012700 4p135d(3/2)2[7/2]3 TW
1472.3946(6)67916.58(3)1472.3950(4)−0.00046800000 d101S04p318.e+06EK66D05se
1473.5295(8)67864.27(4)1473.53001(10)−0.0005100000 s23F36p(5/2)2[7/2]°4 K66
1473.9786(6)67843.59(3)1473.97844(4)0.0002190000 4p316s(3/2)2[3/2]2 K66
1474.9348(6)67799.61(3)1474.93480(9)−0.0000230000 s23F3sp(1G)333 K66
1475.4361(22)67776.57(10)1475.4383(9)−0.002323000 s21D2sp(1D)111 TWn
1476.0596(6)67747.94(3)1476.05914(4)0.0005150000 4p316s(3/2)2[3/2]1 K66
1478.2385(13)67648.08(6)1478.23606(6)0.002423000 4p125d(3/2)2[5/2]2 TW
1481.5438(6)67497.16(3)1481.54375(12)0.0000130000 s23F36p(5/2)2[5/2]°2 K66
1484.178(5)67377.37(24)1484.17557(13)0.0021200 s23F4sp(1G)335 TW
1485.3282(8)67325.19(4)1485.32773(4)0.0005110000 4p125d(3/2)2[7/2]3 K66
1485.6143(13)67312.22(6)1485.60994(4)0.004353000 4p336s(3/2)2[3/2]2 TW
1485.6788(8)67309.30(4)1485.67761(4)0.0012110000 4p326s(5/2)2[5/2]2 K66
1487.612(5)67221.81(24)1487.60927(6)0.0031400 4p335d(3/2)2[5/2]2 TW
1487.7805(12)67214.22(5)1487.77920(12)0.001368000 s23F36p(5/2)2[3/2]°2 TW
1487.9719(12)67205.57(5)1487.96988(5)0.002070000 4p325d(5/2)2[5/2]2 TW
1488.1123(12)67199.23(5)1488.11000(4)0.002353000 4p335d(3/2)2[5/2]3 TW
1488.2853(13)67191.42(6)1488.2853(12)−0.000034000 s21D28p(5/2)2[5/2]°2 TWn
1488.6366(6)67175.56(3)1488.63692(4)−0.00031100000 4p326s(5/2)2[5/2]3 K66
1488.8319(12)67166.75(6)1488.83094(5)0.0009120000 4p325d(5/2)2[7/2]3 TW
1491.178(5)67061.07(24)1491.17634(6)0.0021400 4p335d(3/2)2[3/2]2 TW
1491.384(6)67051.8(3)1491.39392(4)−0.0101200 4p325d(5/2)2[5/2]3 TW
1492.1535(10)67017.23(4)1492.15247(11)0.001095000 s23F26p(5/2)2[5/2]°3 K66
1492.6819(10)66993.51(4)1492.68146(13)0.0004100000 4p115d(3/2)2[1/2]0 K66
1492.8346(6)66986.66(3)1492.83423(11)0.0004330000 s23F2sp(3F)1325.5e+08D+K66TW
1493.3675(6)66962.75(3)1493.36656(4)0.0009180000 4p335d(3/2)2[7/2]4 K66
1494.661(6)66904.8(3)1494.65244(5)0.00849000 4p325d(5/2)2[3/2]1 S36c
1494.7930(19)66898.89(8)1494.79138(4)0.00166700 4p335d(3/2)2[7/2]3 TW
1495.4296(6)66870.42(3)1495.42965(9)−0.0001200000 s23F36p(5/2)2[7/2]°3 K66
1496.6862(6)66814.27(3)1496.68654(4)−0.0003260000 4p306s(3/2)2[3/2]1 K66
1498.5779(14)66729.93(6)1498.57545(7)0.002418000 s23F34f(3/2)2[7/2]°3 TW
1499.5135(10)66688.30(4)1499.51299(7)0.000579000 s23F34f(3/2)2[7/2]°4 K66
1500.016(3)66665.97(13)1500.0148(7)0.00114000 s21D28p(5/2)2[3/2]°2 TWn
1501.3359(12)66607.35(5)1501.33622(11)−0.0003110000 s23F2sp(1G)333 TW
1502.811(3)66541.96(13)1502.80934(8)0.0022600 s23F34f(3/2)2[9/2]°4 TW
1503.3675(6)66517.34(3)1503.36800(13)−0.0005150000 s23F26p(5/2)2[3/2]°1 K66
1504.7561(6)66455.95(3)1504.75691(4)−0.0008220000 s23F44f(5/2)2[9/2]°5 K66
1505.3866(6)66428.12(3)1505.38756(4)−0.0010160000 s23F44f(5/2)2[7/2]°4 K66
1505.8576(12)66407.34(5)1505.85714(18)0.000560000 s23F3sp(1G)334 TW
1507.4705(22)66336.29(10)1507.4706(5)−0.00009700 s23P27f(5/2)2[5/2]°2 TWn
1507.6008(22)66330.56(10)1507.59910(4)0.00173200 s23F44f(5/2)2[5/2]°3 TW
1508.1835(6)66304.93(3)1508.18443(13)−0.0009170000 s23F26p(5/2)2[5/2]°2 K66
1508.4845(22)66291.70(10)1508.4829(15)0.00166400 s23P27f(5/2)2[3/2]°1 TWn
1508.6313(6)66285.25(3)1508.63203(5)−0.0007150000 s23F44f(5/2)2[7/2]°3 K66
1510.5051(6)66203.02(3)1510.50562(5)−0.0005210000 4p135d(5/2)2[7/2]4 K66
1510.724(3)66193.41(13)1510.72666(5)−0.0028900 4p135d(5/2)2[7/2]3 TW
1512.1738(12)66129.96(5)1512.17367(6)0.000298000 s23F4sp(3F)134 TW
1512.4640(8)66117.28(3)1512.46442(11)−0.000497000 s23F3sp(3P)312 K66
1512.5393(19)66113.98(8)1512.5391(6)0.000318000 s23P18p(3/2)2[1/2]°1 TWn
1513.0157(22)66093.17(9)1513.0151(5)0.00059800 s23P17f(5/2)2[5/2]°2 TWn
1513.3651(6)66077.91(3)1513.36565(4)−0.0005140000 4p135d(5/2)2[5/2]3 K66
1513.9340(13)66053.08(6)1513.93287(14)0.001146000 s21D26f(5/2)2[7/2]°3 TW
1514.2339(8)66040.00(3)1514.23361(6)0.000380000 4p315d(3/2)2[5/2]2 K66
1514.3380(12)66035.46(5)1514.33770(11)0.0003110000 s21D28p(5/2)2[3/2]°1 TW
1514.4921(6)66028.74(3)1514.49222(8)−0.0001700000 s23F4sp(3F)1334.8e+08D+K66TW
1514.6461(13)66022.02(6)1514.64663(14)−0.000548000 s23F26p(5/2)2[3/2]°2 TW
1514.805(5)66015.12(23)1514.80334(10)0.00113000 s21D26f(5/2)2[5/2]°2 TW
1515.456(3)65986.75(12)1515.46044(10)−0.0058600 s21D26f(5/2)2[3/2]°2 TW
1515.491(5)65985.22(23)1515.49438(15)−0.0044300 s21D26f(5/2)2[3/2]°1 TW
1516.9018(13)65923.84(6)1516.90090(5)0.000943000 4p135d(5/2)2[9/2]4 TW
1517.1600(12)65912.63(5)1517.15960(5)0.000481000 4p135d(5/2)2[3/2]2 TW
1517.6309(8)65892.17(3)1517.63100(4)−0.0001130000 4p326s(3/2)2[3/2]2 K66
1517.9297(8)65879.20(3)1517.92967(6)0.000087000 4p315d(3/2)2[3/2]2 K66
1519.4914(6)65811.49(3)1519.49170(4)−0.0003410000 4p316s(5/2)2[5/2]2 K66
1519.8366(6)65796.55(3)1519.83686(4)−0.0003540000 4p326s(3/2)2[3/2]1 K66
1519.84246(6) m4p315d(3/2)2[3/2]1 K66
1519.923(3)65792.81(13)1519.9165(7)0.00711000*s23P08p(3/2)2[1/2]°1 TWn
1519.923(3)65792.81(13)1519.9261(7)−0.00311000*s23F2sp(3P)331 TWn
1520.0166(12)65788.75(5)1520.01664(6)−0.000053000 4p325d(3/2)2[5/2]2 TW
1520.3899(12)65772.60(5)1520.38979(17)0.0001150000 s21D26f(5/2)2[1/2]°1 TWn
1520.5397(6)65766.12(3)1520.53944(5)0.0003150000 4p325d(3/2)2[5/2]3 K66
1521.4252(22)65727.84(9)1521.4270(16)−0.00188000 s23P07f(5/2)2[3/2]°1 TWn
1522.5070(19)65681.14(8)1522.50482(12)0.00228900 s23F3sp(1G)332 TWn
1522.5767(6)65678.14(3)1522.57664(11)0.000197000 s23F26p(5/2)2[7/2]°3 K66
1523.7415(8)65627.93(3)1523.74102(6)0.000576000 4p325d(3/2)2[3/2]2 K66
1523.9231(15)65620.11(6)1523.9230(10)0.000131000 s23P18p(3/2)2[3/2]°1 TWn
1524.8604(8)65579.77(3)1524.85998(5)0.0004130000 4p125d(5/2)2[5/2]2 K66
1525.656(20)65545.6(9)1525.63103(13)0.02592000 s23F3sp(3F)133 S36c
1525.6433(13)65546.12(5)1525.64065(7)0.002673000 4p115d(3/2)2[5/2]2 TW
1525.656(20)65545.6(9)1525.66850(6)−0.01397000 4p325d(3/2)2[3/2]1 S36c
1525.7649(6)65540.90(3)1525.76429(5)0.0006150000 4p125d(5/2)2[7/2]3 K66
1525.8388(8)65537.72(3)1525.83781(9)0.001092000 s23F24f(3/2)2[7/2]°3 K66
1526.932(5)65490.79(21)1526.92724(7)0.00532000 4p315d(3/2)2[1/2]1 TW
1526.9944(7)65488.12(3)1526.9931(5)0.0013130000 s23P2sp33 K66n
1527.8127(13)65453.05(6)1527.81239(9)0.000342000 s23F24f(3/2)2[5/2]°2 TW
1528.4583(22)65425.40(9)1528.45612(3)0.00224700 4p125d(5/2)2[5/2]3 TW
1528.785(20)65411.4(9)1528.89495(9)−0.11019000?s23F24f(3/2)2[5/2]°3 S36c X
1529.3927(22)65385.43(9)1529.39267(7)0.00004900 4p115d(3/2)2[3/2]2 TW
1531.2874(14)65304.53(6)1531.28647(11)0.001070000 s23F24f(3/2)2[3/2]°1 TW
1531.3338(14)65302.55(6)1531.33448(7)−0.000741000 4p115d(3/2)2[3/2]1 TW
1531.4120(14)65299.21(6)1531.4121(10)−0.000260000 s23P08p(3/2)2[3/2]°1 TWn
1531.8555(6)65280.31(3)1531.85562(4)−0.0001700000 4p336s(5/2)2[5/2]2 K66
1531.87878(5) m4p125d(5/2)2[3/2]1 TW
1532.128(3)65268.70(13)1532.13042(10)−0.003390000 s23F3sp(3F)1321.0e+09D+TWTW
1532.8083(15)65239.73(6)1532.80783(7)0.000417000 4p325d(3/2)2[1/2]1 TW
1533.9867(6)65189.61(3)1533.98624(12)0.0005170000 s23F2sp(3F)131 K66
1534.6282(13)65162.37(6)1534.62719(10)0.001043000 s23F3sp(1G)334 TW
1535.0023(6)65146.48(3)1535.00194(4)0.0004350000 4p336s(5/2)2[5/2]3 K66
1535.5242(6)65124.34(3)1535.52352(4)0.0007130000 4p335d(5/2)2[7/2]4 K66
1536.193(5)65096.00(21)1536.19869(21)−0.0068200 s23P26f(3/2)2[3/2]°1 TW
1536.9317(16)65064.70(7)1536.93333(14)−0.001624000 s23P26f(3/2)2[3/2]°2 TW
1537.3218(12)65048.19(5)1537.32130(14)0.0005120000 s23P26f(3/2)2[5/2]°3 TW
1537.5581(6)65038.19(3)1537.55884(8)−0.0007860000 s23F4sp(3F)1341.4e+09D+K66TW
1538.4795(6)64999.24(3)1538.47917(3)0.000396000 4p335d(5/2)2[5/2]3 K66
1538.522(5)64997.45(21)1538.52706(8)−0.00540000 4p115d(3/2)2[1/2]1 TW
1540.2392(6)64924.98(3)1540.23914(12)0.0001120000 s23F2sp(3P)312 K66
1540.3886(6)64918.68(3)1540.38850(4)0.0001290000 4p136s(3/2)2[3/2]2 K66
1540.5879(6)64910.29(3)1540.58814(9)−0.0002600000 s23F3sp(3F)1339.e+08D+K66TW
1541.246(5)64882.59(22)1541.24593(13)−0.0005200 s23P16f(3/2)2[5/2]°2 TW
1541.7007(22)64863.43(9)1541.70280(5)−0.0021860000 4p346s(5/2)2[5/2]3 K66
1541.7542(18)64861.18(8)1541.75580(18)−0.0016260000 s21D2sp(1D)1121.4e+09D+K66TW
1541.9565(22)64852.67(9)1541.95701(21)−0.000511000 s23P16f(3/2)2[3/2]°1 TW
1542.4007(13)64834.00(6)1542.40025(4)0.000455000 4p335d(5/2)2[3/2]2 TW
1542.6989(22)64821.46(9)1542.69717(14)0.001710000 s23P16f(3/2)2[3/2]°2 TW
1543.1328(13)64803.24(5)1543.1327(9)0.000164000 s23P2sp(1D)111 TWn
1544.6764(6)64738.48(3)1544.67690(8)−0.0005430000 s23F34f(5/2)2[9/2]°4 K66
1547.9581(8)64601.23(3)1547.95800(7)0.000159000 s23F34f(5/2)2[7/2]°4 K66
1548.4169(12)64582.09(5)1548.4165(12)0.0004200000 s23P2sp(3P)1321.0e+09D+TWnTW
1548.942(3)64560.22(12)1548.9433(10)−0.00215000 s23P1sp(1D)111 TWn
1549.56(7)64534(3)1549.62492(22)−0.0624000 s23P06f(3/2)2[3/2]°1 S36nc
1550.0971(17)64512.09(7)1550.09682(9)0.000310000 4p315d(5/2)2[1/2]0 TW
1550.2978(13)64503.73(5)1550.29648(7)0.001429000 s23F34f(5/2)2[5/2]°3 TW
1550.6528(6)64488.969(25)1550.65296(13)−0.0002180000 s23F2sp(1G)3327.3e+08D+K66nTW
1551.3886(6)64458.383(25)1551.38877(7)−0.0002250000 s23F34f(5/2)2[7/2]°3 K66
1552.297(5)64420.66(22)1552.29519(14)0.0021100 s23F3sp(3P)352 TW
1552.6450(6)64406.223(25)1552.64631(10)−0.0013720000 s23F4sp(3F)1351.9e+09D+K66TW
1553.3473(13)64377.11(5)1553.3472(13)0.000196000 s21D27p(3/2)2[3/2]°1 TWn
1553.8961(6)64354.367(25)1553.89596(14)0.0001210000 s23F2sp(3F)1331.4e+09D+K66TW
1554.2933(12)64337.92(5)1554.2934(11)−0.0001120000 s21D27p(3/2)2[3/2]°2 TWn
1555.1336(6)64303.157(25)1555.13425(8)−0.0007810000 s23F3sp(3F)1341.3e+09D+K66TW
1555.7018(6)64279.671(25)1555.70295(9)−0.0012880000 s23F4sp(3P)3336.8e+08D+K66TW
1556.0269(8)64266.24(3)1556.02548(4)0.001440000 4p126s(3/2)2[3/2]2 K66
1556.6836(21)64239.13(9)1556.6810(10)0.002719000 s23P0sp(1D)111 TWn
1556.7668(12)64235.70(5)1556.7668(12)0.0001180000 s21D27p(3/2)2[5/2]°3 TWn
1557.5867(6)64201.884(25)1557.58652(10)0.0002110000 s23F3sp(3F)133 K66
1558.1590(13)64178.30(6)1558.1587(13)0.000362000 s23P1sp(3P)130 TWn
1558.3446(6)64170.659(25)1558.34444(4)0.0002180000 4p126s(3/2)2[3/2]1 K66
1559.1587(14)64137.15(6)1559.1576(13)0.0011210000 s21D27p(3/2)2[5/2]°2 TWn
1563.108(3)63975.10(12)1563.1083(13)−0.0009400 s23P18p(5/2)2[5/2]°2 TWn
1563.1959(13)63971.51(5)1563.19353(5)0.002422000 4p315d(5/2)2[5/2]2 TW
1565.9244(6)63860.043(24)1565.92414(4)0.0003190000 4p326s(5/2)2[5/2]2 K66
1566.4148(4)63840.051(16)1566.41460(4)0.0002220000 4p336s(3/2)2[3/2]2 K66
1569.2124(8)63726.24(3)1569.21212(4)0.000340000 4p326s(5/2)2[5/2]3 K66
1569.4154(11)63717.99(4)1569.41524(11)0.000142000 s23F2sp(3F)133 TW
1570.0365(11)63692.79(4)1570.0367(8)−0.000294000 s23P28p(5/2)2[3/2]°2 TW,S36r
1570.5722(12)63671.06(5)1570.57051(5)0.001717000 4p315d(5/2)2[3/2]1 TW
1573.1666(22)63566.06(9)1573.16667(4)−0.00014000 4p325d(5/2)2[5/2]3 TW
1575.3547(12)63477.77(5)1575.35310(6)0.001634000 4p115d(5/2)2[5/2]2 TW
1576.0523(12)63449.67(5)1576.0520(8)0.000347000 s23P18p(5/2)2[3/2]°2 TWn
1577.2693(22)63400.71(9)1577.26680(5)0.00254500 4p325d(5/2)2[3/2]2 TW
1579.4926(8)63311.47(3)1579.49148(9)0.001164000 s23F24f(5/2)2[5/2]°3 K66
1580.0260(11)63290.10(4)1580.02469(9)0.001343000 s23F24f(5/2)2[5/2]°2 TW
1580.6258(6)63266.081(24)1580.62531(9)0.000571000 s23F24f(5/2)2[7/2]°3 K66
1581.4029(14)63234.99(6)1581.40630(5)−0.00345300 4p315d(5/2)2[1/2]1 TW
1581.420(12)63234.3(5)1581.41834(10)0.0012300 s23F24f(5/2)2[3/2]°1 S36c
1581.9962(6)63211.277(24)1581.99510(10)0.001182000 s23F3sp(3F)134 K66
1582.6074(20)63186.86(8)1582.60633(9)0.00116600 s23F24f(5/2)2[3/2]°2 TW
1582.8471(11)63177.30(4)1582.84558(6)0.001535000 4p115d(5/2)2[3/2]1 TW
1583.6831(4)63143.946(16)1583.68224(10)0.0009160000 s23F3sp(3P)332 K66
1586.276(5)63040.74(21)1586.27882(10)−0.0034100 s23P26f(5/2)2[5/2]°3 TW
1587.0607(22)63009.56(9)1587.05935(12)0.00146100 s23F2sp(3F)133 TW
1587.716(3)62983.56(11)1587.71486(5)0.0012600 4p325d(5/2)2[1/2]1 TW
1590.1649(4)62886.560(16)1590.16460(4)0.0003110000 4p136s(5/2)2[5/2]2 K66
1593.5559(4)62752.741(16)1593.55527(4)0.0006190000 4p136s(5/2)2[5/2]3 K66
1596.749(6)62627.26(24)1596.74558(10)0.0035100 s21D25f(3/2)2[3/2]°1 S36c
1598.4025(4)62562.465(16)1598.40212(4)0.0004140000 4p316s(3/2)2[3/2]1 K66
1601.211(3)62452.75(12)1601.20967(12)0.0012800 s23F3sp(3P)333 TW
1602.2739(8)62411.30(3)1602.27264(12)0.001328000 s23F2sp(3P)331 K66
1602.3887(4)62406.831(16)1602.38797(4)0.0007130000 4p326s(3/2)2[3/2]2 K66
1603.2280(23)62374.16(9)1603.22651(14)0.001413000 s21D27p(5/2)2[5/2]°3 TW
1604.8475(4)62311.216(16)1604.84729(4)0.000256000 4p326s(3/2)2[3/2]1 K66
1605.2810(4)62294.390(16)1605.28112(12)−0.0001150000 s23F3sp(3P)332 K66
1606.1963(17)62258.89(6)1606.19537(24)0.000976000 s21D27p(5/2)2[5/2]°2 TW
1606.8338(4)62234.190(15)1606.83396(4)−0.0002170000 4p126s(5/2)2[5/2]2 K66
1608.3931(17)62173.85(6)1608.39195(15)0.001287000 s21D27p(5/2)2[3/2]°1 TW
1608.6395(4)62164.332(15)1608.63928(6)0.000272000 4p116s(3/2)2[3/2]2 K66
1609.3421(23)62137.19(9)1609.3430(15)−0.000910000 s21D27p(5/2)2[7/2]°3 TWn
1610.2967(8)62100.36(3)1610.29617(4)0.000521000 4p126s(5/2)2[5/2]3 K66
1611.1185(20)62068.68(8)1611.11784(6)0.000612000 4p116s(3/2)2[3/2]1 TW
1614.159(5)61951.76(21)1614.16058(12)−0.0012100 s23F2sp(3P)332 TW
1614.4945(18)61938.89(7)1614.49462(18)−0.000275000 s21D27p(5/2)2[3/2]°2 TW
1617.9152(8)61807.94(3)1617.91504(4)0.000224000 4p336s(5/2)2[5/2]2 K66
1621.4262(4)61674.099(15)1621.42522(4)0.001084000 4p336s(5/2)2[5/2]3 K66
1622.4281(4)61636.013(15)1622.42766(12)0.000480000 s23F2sp(3P)331 K66
1623.1726(6)61607.743(23)1623.1731(3)−0.000536000 s23F4sp(3P)354 K66
1629.603(3)61364.65(12)1629.6017(12)0.0019500 s23P27p(3/2)2[3/2]°2 TWn
1630.2669(18)61339.65(7)1630.26799(21)−0.001132000 s23F4sp(3P)353 TW
1636.0706(23)61122.06(9)1636.06917(21)0.001419000 s23P27p(3/2)2[1/2]°1 TWn
1636.6049(20)61102.10(7)1636.60469(14)0.000211000 s23F2sp(3P)332 TW
1645.6583(23)60765.95(8)1645.6575(22)0.000812000 s23P17p(3/2)2[1/2]°0 TWn
1649.4570(14)60626.01(5)1649.45739(4)−0.000426000 4p316s(5/2)2[5/2]2 K66
1656.32260374.741656.32175(4) 27000:4p326s(5/2)2[5/2]2 S36c
1660.0022(14)60240.88(5)1660.00075(4)0.001418000 4p326s(5/2)2[5/2]3 K66
1663.0029(14)60132.19(5)1663.00184(5)0.001131000 4p116s(5/2)2[5/2]2 K66
1672.7773(23)59780.82(8)1672.7755(4)0.00188600 s23F3sp(3P)354 TW
1680.27(4)59514.1(14)1680.31169(23)−0.04980 s23F3sp(3P)353 S36c
1683.152(5)59412.32(18)1683.1596(3)−0.00734000*s23F4sp(1D)3331.1e+08CTWB00
1683.152(5)59412.32(18)1683.1583(3)−0.00634000*s23F3sp(3P)352 TW
1695.9031(23)58965.63(8)1695.90238(20)0.000712000 s23P27p(5/2)2[3/2]°2 TW
1699.0958(20)58854.83(7)1699.0950(5)0.000822000*s23F3sp(1D)332 TW
1699.0958(20)58854.83(7)1699.10217(23)−0.006422000*s23F4sp(1D)333 TW
1702.9236(23)58722.54(8)1702.92295(21)0.00068600 s23P17p(5/2)2[3/2]°2 TW
1714.655(20)58320.8(7)1714.6631(3)−0.008460 s23F2sp(3P)353 S36c
1717.7188(22)58216.75(7)1717.7210(3)−0.002311000 s23F2sp(3P)351 TW
1734.2254(23)57662.63(8)1734.2267(5)−0.00134200 s23F2sp(1D)332 TW
1736.5531(22)57585.34(7)1736.5563(3)−0.00328900 s23F3sp(1D)333 TW
1744.506(20)57322.8(7)1744.5159(3)−0.01022000 s23F3sp(1D)3325.9e+07CS36cB00
1753.2791(21)57035.99(7)1753.28069(22)−0.001621000 s23F2sp(1D)331 TW
1759.5030(21)56834.23(7)1759.50415(22)−0.00123400 s23F3sp(1D)332 TW
1781.573(3)56130.16(10)1781.5715(3)0.0024400 s23F2sp(1D)332 TW
1790.6606(21)55845.31(7)1790.6599(3)0.000733000 s23F2sp(1D)3314.5e+07CTWB00
1800.9806(24)55525.31(7)1800.9789(6)0.001811000 s23F4sp(3P)353 TW
1807.8535(21)55314.22(7) 160000 4p11s21S0 TW,S36r
1856.937(20)53852.1(6)1856.92890(17)0.00914000 s21D26p(5/2)2[3/2]°1 S36c
1861.57(4)53718.2(12)1861.6226(3)−0.0610000 s23F3sp(3P)352 S36c
1874.166(5)53357.06(14)1874.16676(18)−0.00114000 s21D26p(5/2)2[3/2]°2 TW
1875.74638(18)53312.112(5)1875.74622(7)0.0001620000 s23F45p(3/2)2[5/2]°3 F
1882.253(3)53127.82(8)1882.2566(10)−0.00317000 s21D2sp(3P)331 TWn
1903.858(5)52524.93(15)1903.86698(15)−0.009410 s21D2sp(3F)131 TW
1920.6709(8)52065.141(22)1920.67133(7)−0.000443000 4p324d(3/2)2[5/2]31.5e+07CFB00
1922.14229(17)52025.285(5)1922.14231(11)−0.0000394000 s23F35p(3/2)2[3/2]°2 F
1924.548(3)51960.26(9)1924.5458(22)0.0025200 s21G47p(5/2)2[7/2]°3 TWn
1928.46(4)51854.9(11)1928.4863(3)−0.0346000 s21D2sp(3P)311 S36cn
1929.60764(17) ms21D2sp(1G)332 S36cn
1929.75131(6)51820.1488(16)1929.75129(5)0.00002340000 s23F4sp(3F)3132.1e+07CFB00
1942.3030(7)51485.272(19)1942.30290(12)0.000131000 s23F35p(3/2)2[5/2]°3 F
1944.59596(14)51424.564(4)1944.59601(6)−0.000056000000 4s3D34p321.99e+07C+FD05se
1946.4928(3)51374.451(7)1946.49291(7)−0.0001130000 s23F45p(5/2)2[5/2]°3 F
1952.5792(18)51214.31(5)1952.57557(12)0.003797000 s23F35p(3/2)2[5/2]°2 F
1957.5176(3)51085.108(8)1957.51767(7)−0.0000190000 s23F45p(5/2)2[7/2]°4 F
1968.008(3)50812.79(8)1968.01129(8)−0.0039700 4p324d(3/2)2[1/2]11.8e+07CTWO07
1970.4936(6)50748.707(15)1970.49395(7)−0.0004760000 4s3D24p115.3e+06C+FK82cor
1974.467(3)50646.57(8)1974.46773(8)−0.0002800 s21D24f(5/2)2[5/2]°3 TW
1977.0266(3)50581.009(6)1977.02671(15)−0.000180000 s23F25p(3/2)2[3/2]°1 F
1979.95578(4)50506.1785(10)1979.95579(3)−0.0000218000000 4s3D24p329.6e+07C+FD05se
1982.1503(20)50450.26(5)1982.14827(12)0.002116000 s23F3sp(3F)312 F
1984.763(3)50383.85(8)1984.76431(19)−0.00114000 s23P26p(5/2)2[3/2]°2 TW
1986.307(3)50344.68(8)1986.30794(14)−0.0018100 s21D2sp(3F)133 TW
1989.85478(3)50254.9236(9)1989.85480(3)−0.000017400000 4s3D24p319.8e+07C+FD05
1990.18000(19)50246.711(5)1990.18009(7)−0.00009670000 4p314d(3/2)2[3/2]21.3e+08CFB00
1993.8395(21)50154.49(5)1993.8395(12)−0.000034000 s23P2sp(3P)331 TWn
1994.257(3)50143.98(8)1994.25958(15)−0.00217000 s23F25p(3/2)2[1/2]°1 TW
1998.5575(16)50036.09(4)1998.55790(7)−0.000434000 4p334d(3/2)2[5/2]3 F
1999.5327(18)50011.69(5)1999.53361(8)−0.0009140000 4p314d(3/2)2[3/2]15.8e+07CTWB00
1999.69752(6)49991.3640(16)1999.69754(5)−0.0000220000000 4s3D34p332.13e+08BFC94c
2002.9033(20)49911.36(5)2002.9020(12)0.001373000 s23P1sp(3P)331 TWn
2009.32(15)49752(4)2009.28239(8)0.046800 4p344d(3/2)2[5/2]3 S36c
2012.98037(14)49661.540(4)2012.98041(6)−0.000041800000 4p324d(5/2)2[5/2]32.5e+08CFB00
2015.5822(4)49597.442(10)2015.58222(8)0.00001400000 4s3D14p112.1e+07C+FK82cor
2015.8660(24)49590.46(6)2015.8649(12)0.001139000 s23P0sp(3P)331 TWn
2016.8964(6)49565.129(14)2016.89673(6)−0.00031700000 4s3D34p128.1e+06C+FD05se
2017.6096(16)49547.61(4)2017.60977(12)−0.0002160000 s23F35p(5/2)2[5/2]°3 F
2022.1913(16)49435.37(4)2022.19147(7)−0.0002170000 4p334d(3/2)2[7/2]41.14e+07C+FO07
2025.48773(12)49354.924(3)2025.48775(5)−0.000018100000 4s3D14p326.8e+07C+FD05se
2025.919(3)49344.43(8)2025.91683(13)0.00225000 s23F35p(5/2)2[5/2]°2 TW
2027.1336(6)49314.858(15)2027.13416(9)−0.0005610000 4p314d(3/2)2[1/2]11.3e+08CFO07se
2029.471(3)49258.06(8)2029.47227(16)−0.00137000 s23F2sp(3F)312 TW
2029.9491(7)49246.469(17)2029.94908(6)0.0000560000 4p324d(5/2)2[3/2]18.0e+07BFO07
2031.03579(16)49220.123(4)2031.03598(6)−0.000202700000 4p324d(5/2)2[3/2]24.5e+08BFO07
2033.844(3)49152.18(8)2033.84242(8)0.00162000 4p344d(3/2)2[7/2]48.9e+06C+TWO07
2035.85321(6)49103.6704(15)2035.85327(4)−0.0000619000000 4s3D14p313.7e+08C+FD05
2036.9201(3)49077.954(8)2036.92001(9)0.0001730000 4p304d(3/2)2[3/2]11.9e+08CFB00
2037.12672(4)49072.9776(9)2037.12668(3)0.0000413000000 4s3D24p331.36e+08BFC94c
2043.8019(5)48912.725(11)2043.80148(7)0.000421000000 4s3D34p131.42e+08C+R1cD05se
2047.67825(16)48820.143(4)2047.67825(11)−0.000001300000 4p114d(3/2)2[1/2]05.32e+08B+FB09
2054.25259(21)48663.922(5)2054.25263(8)−0.00003810000 4p324d(3/2)2[5/2]21.4e+08CFB00
2054.4171(3)48660.025(7)2054.41739(8)−0.0003960000 4p314d(5/2)2[1/2]06.7e+08CFB00
2054.97836(4)48646.7370(10)2054.97836(3)0.0000118000000 4s3D24p121.65e+08C+FD05se
2058.611(3)48560.91(8)2058.61377(13)−0.00349000 s23F35p(5/2)2[3/2]°2 TW
2062.4201(4)48471.230(8)2062.42011(6)−0.00001500000 4p314d(5/2)2[5/2]21.7e+08CFB00
2066.2609(5)48381.143(12)2066.26109(10)−0.0002960000 4p304d(3/2)2[1/2]12.00e+08B+FO07
2067.368(3)48355.23(7)2067.36392(16)0.00435000 s23F25p(5/2)2[5/2]°3 TW
2069.9356(13)48295.27(3)2069.93487(7)0.0007240000 4p324d(3/2)2[3/2]23.7e+07CFB00
2074.213(3)48195.68(8)2074.20995(16)0.00339000 s23F25p(5/2)2[3/2]°1 TW
2074.24066(15) ms23P1sp(3F)132 TW
2078.66147(9)48092.5549(21)2078.66153(6)−0.000056700000 4p324d(5/2)2[1/2]16.3e+08B+FO07
2080.0593(13)48060.24(3)2080.05953(9)−0.0002210000 4p324d(3/2)2[3/2]14.9e+07CR1cB00
2082.920(20)47994.2(5)2082.91535(6)0.00556000 4s3D24p131.0e+06ES36cD05se
2084.3229(20)47961.94(5)2084.32369(22)−0.0008170000 s23F4sp(3F)334 TW
2085.2735(9)47940.081(21)2085.27476(6)−0.0012860000 4p334d(5/2)2[5/2]26.7e+07CR1cB00
2085.297(4)47939.55(9)2085.30956(7)−0.0132500000 4s3D34p324.1e+06C+TWD05cor
2087.91812(11)47879.3666(25)2087.91817(7)−0.000053400000 4p324d(3/2)2[7/2]34.2e+08BFB00
2087.96979(24)47878.182(5)2087.96987(6)−0.000083700000 4p334d(5/2)2[7/2]32.6e+08CFB00
2093.6366(5)47748.606(11)2093.63705(6)−0.00042400000 4p314d(5/2)2[3/2]12.20e+08BR1cO07
2094.7925(9)47722.261(21)2094.79321(6)−0.0007290000 4p314d(5/2)2[3/2]22.21e+07C+R1cO07
2096.1891(14)47690.47(3)2096.19052(9)−0.0014120000 4p134d(3/2)2[5/2]21.6e+07CR1cB00
2098.3067(3)47642.348(7)2098.30677(8)−0.00011200000 4p134d(3/2)2[5/2]31.01e+08CFB00
2098.3971(2)47640.295(6)2098.39724(8)−0.00015000000 4p344d(5/2)2[7/2]42.09e+08BFO07
2098.7405(9)47632.502(21)2098.74108(6)−0.0006300000 4p334d(5/2)2[5/2]32.0e+07CR1cB00
2100.397(3)47594.94(7)2100.39318(8)0.00453000 4p344d(5/2)2[7/2]3 TW
2104.79587(5)47495.4827(11)2104.79586(4)0.0000262000000 4s3D14p127.7e+07C+FD05se
2106.3816(11)47459.73(3)2106.3791(3)0.0025240000 s23F3sp(3F)314 F
2110.308(3)47371.45(7)2110.30833(15)−0.00190000 s23P2sp(3F)133 TW
2111.2934(4)47349.333(10)2111.29323(8)0.0001860000 4p344d(5/2)2[5/2]36.6e+07CR1cB00
2112.09930(19)47331.268(4)2112.09946(9)−0.0001655000000 4s1D24p113.5e+08C+FD05se
2112.5245(14)47321.74(3)2112.52195(8)0.0026110000 4p134d(3/2)2[3/2]21.2e+07CR1cB00
2117.30881(9)47214.8259(20)2117.30874(7)0.0000612000000 4p334d(5/2)2[9/2]47.2e+08BFO07
2118.3748(20)47191.07(5)2118.37484(7)−0.0001260000 4p334d(5/2)2[3/2]22.7e+07BTWO07
2122.97861(13)47088.745(3)2122.97858(6)0.0000371000000 4s1D24p322.2e+08C+FD05se
2125.10512(12)47041.631(3)2125.10507(7)0.000043800000 4p134d(3/2)2[7/2]42.28e+08B+FO07
2125.2670(5)47038.048(12)2125.26686(8)0.0001610000 4p124d(3/2)2[5/2]26.6e+07CFB00
2126.04361(6)47020.8676(14)2126.04362(5)−0.0000174000000 4s3D24p321.41e+08BFC94c
2130.0848(5)46931.669(10)2130.08459(9)0.00021000000 4p344d(5/2)2[9/2]44.4e+07B+R1cO07
2131.2548(6)46905.908(13)2131.25595(8)−0.0011190000 4p134d(3/2)2[7/2]31.3e+07CR1cB00
2134.3400(4)46838.113(9)2134.34030(8)−0.00039500000 4p344d(5/2)2[9/2]57.7e+08BR1cB00
2135.39946814.892135.39887(8) :4p304d(5/2)2[3/2]14.e+07E O07se
2135.98008(7)46802.1541(16)2135.98004(6)0.00004140000000 4s3D34p344.59e+08A+FP97
2144.706(10)46611.76(22)2144.70358(8)0.002160000*4p334d(3/2)2[5/2]21.5e+07CR1cB00
2144.706(10)46611.76(22)2144.72206(16)−0.016160000*s23F3sp(3F)333 R1c
2145.4920(4)46594.683(9)2145.49206(7)−0.00011200000 4p314d(5/2)2[1/2]11.14e+08BR1cO07
2146.9187(4)46563.722(8)2146.91894(7)−0.00021100000 4p334d(3/2)2[5/2]31.04e+08CFB00
2148.94587(6) m4p324d(5/2)2[5/2]21.12e+08CS36cB00
2148.9830(6)46518.999(13)2148.98283(8)0.000259000000 4s3D34p338.8e+07BR1cC94c
2151.8083(4)46457.927(9)2151.80815(7)0.00014200000 4p324d(5/2)2[7/2]32.59e+08BR1cB00
2152.910(20)46434.2(4)2152.90029(9)0.01023000 4p124d(3/2)2[3/2]1 S36c
2158.4108(10)46315.829(21)2158.41130(19)−0.000560000 s23F2sp(3F)332 R1c
2161.31978(23)46253.498(5)2161.31990(7)−0.000124200000 4p124d(3/2)2[7/2]33.1e+08BFB00
2161.7998(10)46243.228(21)2161.80255(7)−0.002758000 4p334d(3/2)2[3/2]2 R1c
2166.850(20)46135.5(4)2166.8678(3)−0.01821000 s23F3sp(3F)334 S36c
2174.98119(9)45963.0038(18)2174.98126(6)−0.000077500000 4p334d(3/2)2[7/2]44.9e+08BFO07
2179.41026(22)45869.606(5)2179.40994(6)0.0003372000000 4s3D14p322.15e+08BFC94c
2180.7508(5)45841.413(11) 680000 s23F4sp(3F)335 R1c
2181.4243(4)45827.261(9)2181.42461(7)−0.0003290000 4p334d(3/2)2[7/2]32.4e+07CR1cB00
2182.8585(5)45797.154(11)2182.85780(7)0.0007560000 4p324d(5/2)2[3/2]18.0e+07C+R1cO07
2189.3693(10)45660.976(21)2189.36930(8)0.0000240000 4p304d(5/2)2[1/2]11.3e+07CR1cO07se
2189.62967(9)45655.5468(18)2189.62971(6)−0.0000447000000 4s1D24p331.04e+08BF,R1cC94c
2190.500(20)45637.4(4)2190.5192(3)−0.01957000 s21G46p(3/2)2[5/2]°3 S36c
2192.26759(8)45600.6159(16)2192.26753(6)0.0000773000000 4s3D24p332.8e+08BFC94c
2195.68180(17)45529.716(4)2195.68192(7)−0.000124200000 4p134d(5/2)2[7/2]44.2e+08BFO07
2197.8688(15)45484.42(3)2197.86726(7)0.001671000 4p134d(5/2)2[7/2]3 R1c
2200.300(20)45434.2(4)2200.31543(20)−0.01547000 s23P0sp(3P)331 S36c
2200.5078(3)45429.874(6)2200.50822(8)−0.00041600000 4p314d(3/2)2[5/2]22.1e+08CFB00
2201.000(20)45419.7(4)2201.02822(20)−0.02833000 s23F2sp(3F)333 S36c
2209.8049(4)45238.760(8)2209.80507(7)−0.00021900000 4p134d(5/2)2[5/2]32.1e+08CR1cB00
2210.26692(11)45229.3048(22)2210.26693(6)−0.0000156000000 4s1D24p121.53e+08C+FD05se
2212.7470(6)45178.617(12)2212.74730(8)−0.00031100000 4p324d(3/2)2[5/2]21.4e+08CFB00
2215.1054(3)45130.521(5)2215.10550(8)−0.00013800000 4p324d(3/2)2[5/2]34.9e+08BFB00
2218.10770(6)45069.4401(12)2218.10772(5)−0.0000266000000 4s3D24p313.5e+08C+FD05se
2218.5123(4)45061.222(9)2218.51209(8)0.00021900000 4p314d(3/2)2[3/2]22.6e+08CR1cB00
2221.649(3)44997.60(6)2221.6477(8)0.00199000 s21D2sp(1D)332 R1c
2224.6906(5)44936.092(10)2224.69062(11)−0.00001300000 4p114d(3/2)2[5/2]21.3e+08CR1cB00
2226.7798(4)44893.936(8)2226.77999(6)−0.00022200000 4p124d(5/2)2[5/2]22.9e+08CR1cB00
2228.86748(6)44851.8904(11)2228.86745(6)0.0000335000000 4s3D14p303.88e+08B+FP97
2229.8529(4)44832.072(8)2229.85346(6)−0.00061800000 4p124d(5/2)2[7/2]32.1e+08CR1cB00
2230.1439(7)44826.223(15)2230.14604(9)−0.00221900000 4p314d(3/2)2[3/2]11.9e+08CR1cB00
2230.3979(7)44821.118(13)2230.39901(9)−0.0011440000 4p134d(5/2)2[9/2]42.0e+07CR1cO07se
2230.9512(6)44810.003(12)2230.95279(8)−0.00161600000 4p324d(3/2)2[3/2]22.2e+08CR1cB00
2231.5817(4)44797.343(8)2231.58204(7)−0.00031100000 4p134d(5/2)2[3/2]21.14e+08BR1cO07
2242.1424(11)44586.363(21)2242.14217(6)0.0003240000 4p124d(5/2)2[5/2]31.07e+07CR1cB00
2242.61775(10)44576.9146(20)2242.61764(7)0.0001154000000 4s1D24p132.5e+08C+FD05se
2242.718(3)44574.93(5)2242.71791(9)−0.000100000 4p324d(3/2)2[3/2]15.8e+07CTWB00
2243.0938(7)44567.454(14)2243.09395(10)−0.0001230000 4p114d(3/2)2[3/2]24.0e+07CR1cB00
2247.0017(5)44489.953(11)2247.00170(9)−0.000066000000 4s3D34p323.3e+08BR1cC94c
2248.9666(4)44451.086(8)2248.96667(6)−0.00011800000 4p334d(5/2)2[7/2]49.1e+07BR1cO07
2251.8564(5)44394.047(9)2251.85601(8)0.000472000 4p324d(3/2)2[7/2]35.8e+06CR1cB00
2253.0326(16)44370.87(3)2253.0273(3)0.005351000 s21D2sp(1D)331 R1c
2254.9880(4)44332.402(8)2254.98778(11)0.0002620000 4p114d(3/2)2[3/2]11.9e+08CR1cB00
2263.2130(4)44171.302(8)2263.21318(6)−0.0002580000 4p124d(5/2)2[3/2]11.54e+08B+R1cO07
2263.7857(4)44160.128(8)2263.78578(6)−0.00001700000 4p334d(5/2)2[5/2]31.8e+08CR1cB00
2264.5671(16)44144.89(3)2264.56423(6)0.002950000 4p124d(5/2)2[3/2]21.4e+06ER1cO07se
2265.3643(4)44129.358(8)2265.36424(10)0.0001190000 4p314d(3/2)2[1/2]11.25e+08BR1cO07
2274.7407(6)43947.476(11)2274.74107(8)−0.0004150000 4p325s(3/2)2[3/2]24.e+06ER1cC94
2276.2577(4)43918.191(8)2276.25797(7)−0.000316000000 4s3D14p316.3e+07C+R1cD05se
2278.3378(5)43878.098(10)2278.33737(10)0.0004220000 4p324d(3/2)2[1/2]11.32e+08B+R1cO07
2280.9423(4)43827.999(8)2280.9428(3)−0.0005260000 s23F3sp(3F)334 R1c
2284.202(4)43765.46(7)2284.19835(22)0.00417000 s21G4sp(1G)333 R1c
2286.6447(4)43718.712(8)2286.64494(6)−0.0002810000 4p334d(5/2)2[3/2]21.52e+08B+R1cO07
2289.4160(4)43665.797(8)2289.41619(8)−0.0002170000 4p325s(3/2)2[3/2]17.e+06DR1cC94
2290.1606(7)43651.600(14)2290.16119(24)−0.000649000 s23F2sp(3F)333 R1c
2291.0018(4)43635.575(8)2291.00110(12)0.0007550000 4p114d(3/2)2[1/2]11.76e+08B+R1cO07
2292.6896(6)43603.454(11)2292.69060(8)−0.001019000 4s1D24p324.e+05ER1cD05cor
2292.9699(6)43598.124(11)2292.9700(3)−0.000220000 s23F4sp(3F)354 R1c
2294.3674(4)43571.571(8)2294.36758(7)−0.000215000000 4s3D24p323.4e+07C+R1cC94c
2299.4885(5)43474.542(9)2299.48891(10)−0.0004140000 4p314d(5/2)2[1/2]01.07e+08CR1cB00
2309.5189(4)43285.747(8)2309.51890(6)−0.0000200000 4p314d(5/2)2[5/2]21.02e+07CR1cB00
2315.681(5)43170.57(10)2315.6826(4)−0.00217000 s21D2sp(1D)333 R1c
2323.0039(5)43034.495(9)2323.00409(6)−0.0002200000 4p324d(5/2)2[5/2]2 R1c
2323.9280(6)43017.383(11)2323.92802(7)0.000086000 4p124d(5/2)2[1/2]1 R1c
2325.9100(17)42980.73(3)2325.90832(12)0.001725000 4p114d(5/2)2[1/2]0 R1c
2327.5669(6)42950.137(11)2327.5672(4)−0.000312000 s23F3sp(3F)352 R1c
2333.743(3)42836.49(6)2333.75088(22)−0.00823000 s21G46p(5/2)2[7/2]°3 R1c
2336.1707(4)42791.971(8)2336.17057(10)0.0001230000 4p114d(5/2)2[5/2]24.9e+07CR1cB00
2339.7275(5)42726.924(10)2339.72732(6)0.000268000 4p324d(5/2)2[5/2]3 R1c
2341.3713(12)42696.930(21) 17000 s23F4sp(3F)355 R1c
2342.1723(17)42682.33(3)2342.1734(4)−0.001155000 s23P2sp(3P)353 R1c
2347.890(20)42578.4(4)2347.8850(4)0.0059000*s23P2sp(3P)351 S36c
2347.890(20)42578.4(4)2347.914(3)−0.0249000*5s(3/2)2[3/2]2sp(3P)132 S36cn
2348.7330(4)42563.115(8)2348.73311(7)−0.0001120000 4p314d(5/2)2[3/2]12.8e+07BR1cO07
2350.1902(8)42536.727(15)2350.18820(6)0.002014000 4p314d(5/2)2[3/2]2 R1c
2352.2911(12)42498.740(21)2352.29447(19)−0.003430000 s21G44f(3/2)2[9/2]°5 R1c
2353.9437(5)42468.905(9)2353.9434(4)0.000327000 s23F3sp(3F)353 R1c
2355.0143(6)42449.600(11)2355.01447(8)−0.0001610000 4p315s(3/2)2[3/2]22.5e+07C+R1cK82
2356.6402(5)42420.316(9)2356.64033(9)−0.00011400000 4s3D14p323.0e+06C+R1cC94c
2360.6389(9)42348.465(16)2360.6391(9)−0.00029200 s23P1sp(3P)350 R2nc
2361.1901(12)42338.579(21)2361.1910(5)−0.000837000 s23P1sp(3P)352 R1c
2362.6809(9)42311.867(16)2362.68143(7)−0.000526000 4p324d(5/2)2[3/2]16.3e+06C+R1cO07
2364.1538(6)42285.508(10)2364.15386(7)−0.000057000 4p324d(5/2)2[3/2]23.4e+06BR1cO07
2366.980(3)42235.03(5)2366.9785(4)0.0018700 5s(5/2)2[5/2]3sp(1D)112 R1c
2369.8893(5)42183.179(9)2369.88902(9)0.000312000000 4s1D24p335.3e+07BR1cC94c
2370.7464(5)42167.930(8)2370.74698(8)−0.0006490000 4p315s(3/2)2[3/2]12.4e+07C+R1cK82
2376.3030(4)42069.335(8)2376.30277(10)0.0003330000 4p114d(5/2)2[3/2]11.61e+08C+R1cO07se
2377.7920(6)42042.994(10)2377.79223(10)−0.000312000 4p114d(5/2)2[3/2]23.5e+06D+R1cO07
2378.4047(7)42032.163(13)2378.4063(6)−0.001519000 s23F2sp(3F)351 R1c
2378.8442(12)42024.399(21)2378.8439(9)0.0002220000 s23P2sp(1D)332 R1c
2379.4048(12)42014.499(21)2379.4055(5)−0.000753000 s23P0sp(3P)351 R1c
2384.80(6)41919.5(11)2384.85893(9)−0.0649000 4p335s(3/2)2[3/2]26.e+05ES36cK82cal
2384.9439(4)41916.926(8)2384.94408(9)−0.0002100000 4p325s(5/2)2[5/2]27.e+06ER1cK82cal
2385.0951(18)41914.27(3)2385.0945(4)0.00067400 5s(5/2)2[5/2]2sp(1D)112 R1c
2392.6852(18)41781.32(3)2392.6858(9)−0.00066900 s23P1sp(1D)332 R1c
2393.2599(5)41771.287(9)2393.2602(4)−0.000323000 s23F3sp(3F)354 R1c
2394.0296(5)41757.858(9)2394.0296(4)−0.000020000 s23F2sp(3F)352 R1c
2400.1140(7)41652.008(12)2400.11404(9)−0.00013700000 4s1D24p316.9e+06C+R1cD05se
2403.3373(5)41596.149(8)2403.33713(9)0.00022200000 4p325s(5/2)2[5/2]31.06e+08C+FC94
2414.1881(5)41409.205(9)2414.18856(8)−0.000436000 4p314d(5/2)2[1/2]12.e+06ER1cO07cal
2414.8568(5)41397.740(9)2414.8563(4)0.000537000 s23P2sp(1D)331 R1c
2421.9424(6)41276.637(11)2421.9425(4)−0.00016700 s23F2sp(3F)353 R1c
2424.4338(3)41234.223(5)2424.43430(9)−0.00051100000 4p305s(3/2)2[3/2]15.0e+07C+FC94
2426.558(5)41198.13(8)2426.5614(9)−0.00310000 4d(5/2)2[9/2]58f(5/2)2[11/2]°6 R1c
2426.996(9)41190.69(15)2427.016(3)−0.0195000 5s(5/2)2[5/2]27p(3/2)2[5/2]°2 R2nc
2428.9274(5)41157.944(8)2428.92746(8)−0.000038000 4p324d(5/2)2[1/2]11.93e+07C+R1cO07
2430.6772(13)41128.318(21)2430.67651(24)0.00075600 s21G4sp(1G)334 R1c
2432.420(3)41098.86(5)2432.4183(5)0.0014800 4d(5/2)2[9/2]48f(5/2)2[11/2]°5 R1c
2442.6646(5)40926.494(9) 90000 s23F4sp(3F)355 R1c
2443.3256(5)40915.423(8)2443.32555(11)0.000144000 4p114d(5/2)2[1/2]12.00e+07BR1cO07
2448.2143(13)40833.727(21)2448.2131(4)0.001246000 s23P0sp(1D)331 R1c
2452.951(6)40754.88(10)2452.9576(7)−0.0063900 s23P2sp(1D)333 R1c
2456.008(4)40704.16(7)2455.99461(18)0.0137600 s21G44f(5/2)2[9/2]°4 R1c
2462.6140(19)40594.98(3)2462.61266(17)0.001411000 s21G44f(5/2)2[9/2]°5 R1c
2464.307(5)40567.10(8)2464.30282(17)0.0043500 s21G44f(5/2)2[7/2]°4 R1c
2468.3475(8)40500.690(13)2468.3480(6)−0.000533000 s23P1sp(1D)330 R1c
2468.5000(5)40498.187(8)2468.50111(9)−0.0011170000 4p325s(3/2)2[3/2]21.30e+07C+R1cK82
2473.3333(4)40419.053(7)2473.33345(9)−0.0002570000 4p315s(5/2)2[5/2]25.9e+07C+R1cC94
2476.4439(7)40368.287(11)2476.44459(19)−0.000715000 s21G44f(5/2)2[11/2]°5 R1c
2483.784(5)40249.00(8)2483.7876(5)−0.0032900 s23P1sp(1D)332 R1c
2485.7919(5)40216.489(8)2485.79176(9)0.00021000000 4p325s(3/2)2[3/2]11.42e+08C+R1cC94L
2489.6523(6)40154.136(10)2489.65236(11)−0.0001660000 4s1D24p321.0e+06D+R1cC94c
2499.001(8)40003.94(12)2499.0132(4)−0.0134900 s23P2sp(1D)332 R1c
2501.4933(13)39964.076(21)2501.4947(5)−0.00144800 s23P1sp(1D)331 R1c
2506.2727(3)39887.871(5)2506.27258(10)0.00011000000 4p335s(5/2)2[5/2]22.0e+08C+FC94L
2514.2919(10)39760.659(16)2514.2931(4)−0.00124200 s23P1sp(1D)332 R1c
2515.0822(7)39748.166(11)2515.0831(3)−0.00088400 5s(5/2)2[5/2]37p(5/2)2[5/2]°3 R1c
2518.9484(5)39687.164(8)2518.9484(5)−0.000134000 s23F3sp(3F)354 R1c
2526.3277(14)39571.246(21)2526.3234(4)0.00431900 s23F4sp(3F)353 R1c
2526.5923(5)39567.103(7)2526.59232(10)−0.0000500000 4p335s(5/2)2[5/2]32.7e+07C+R1cK82
2529.30395(21)39524.686(3)2529.30385(10)0.00010940000 4p135s(3/2)2[3/2]21.06e+08C+FC94
2542.9345(8)39312.840(12)2542.9357(4)−0.00123200 5s(5/2)2[5/2]37p(5/2)2[3/2]°2 R1c
2544.80509(20)39283.945(3)2544.80482(11)0.000271200000 4p345s(5/2)2[5/2]31.94e+08BFB00
2553.3430(5)39152.595(8)2553.3430(5)−0.000014000 s23F2sp(3F)353 R1c
2556.3698(9)39106.241(13)2556.3691(3)0.00072800 4d(5/2)2[9/2]57f(5/2)2[9/2]°5 R1c
2558.2130(5)39078.067(8)2558.2134(4)−0.00045400 4d(5/2)2[9/2]57f(5/2)2[11/2]°6 R1c
2559.4301(14)39059.485(21)2559.4301(13)−0.00002700 4d(5/2)2[3/2]27f(5/2)2[5/2]°2 R2nc
2559.7925(20)39053.96(3)2559.7938(18)−0.00121300 4d(5/2)2[3/2]18p(3/2)2[1/2]°1 R2nc
2564.7257(6)38978.841(9)2564.7264(4)−0.00075100 4d(5/2)2[9/2]47f(5/2)2[11/2]°5 R1c
2565.0459(7)38973.975(10)2565.0471(5)−0.00112500 4d(3/2)2[7/2]37f(3/2)2[9/2]°4 R1c
2568.9061(20)38915.41(3)2568.9075(4)−0.00142400 4d(5/2)2[1/2]16f(3/2)2[3/2]°2 R1c
2571.7551(6)38872.306(9)2571.75556(8)−0.0004220000 4p125s(3/2)2[3/2]21.10e+07C+R1cK82
2574.4124(7)38832.185(11)2574.4125(5)−0.00012100 s23F3sp(3F)352 R1c
2574.6371(7)38828.796(11)2574.6371(5)−0.00004600 4d(3/2)2[7/2]47f(3/2)2[9/2]°5 R1c
2590.4012(9)38592.515(14)2590.3994(4)0.0019990 4d(5/2)2[5/2]37f(5/2)2[7/2]°4 R1c
2590.52825(17)38590.6226(25)2590.52826(8)−0.00001440000 4p125s(3/2)2[3/2]16.0e+07C+FC94L
2598.8126(6)38467.613(9)2598.81194(10)0.0006400000 4p325s(5/2)2[5/2]24.2e+07C+R1cK82L
2600.26992(14)38446.0554(20)2600.26973(8)0.00018500000 4p335s(3/2)2[3/2]21.01e+08C+FC94
2604.5253(21)38383.24(3)2604.5089(11)0.0164870?sp(3F)33310s(5/2)2[5/2]2 R1c X
2606.5804(14)38352.984(21)2606.5819(5)−0.00151700 4d(5/2)2[7/2]37f(5/2)2[7/2]°3 R1c
2606.8761(8)38348.634(12)2606.8759(4)0.00013400 4d(5/2)2[7/2]37f(5/2)2[9/2]°4 R1c
2606.9973(10)38346.850(15)2606.9973(4)0.00012500 4d(5/2)2[7/2]37f(5/2)2[7/2]°4 R1c
2607.04138346.212607.0410(4) :4d(5/2)2[7/2]37f(5/2)2[5/2]°3
2609.9088(6)38304.075(9)2609.9094(3)−0.00068400 4d(5/2)2[7/2]47f(5/2)2[9/2]°5 R1c
2610.7937(14)38291.094(21)2610.7940(5)−0.00031600 4d(5/2)2[5/2]27f(5/2)2[7/2]°3 R1c
2611.2544(8)38284.338(11)2611.2546(4)−0.0002810 4d(5/2)2[5/2]27f(5/2)2[5/2]°3 R1c
2614.4127(7)38238.092(11)2614.4126(7)0.000115000 s23F4sp(3F)354 R1c
2619.2104(5)38168.054(8)2619.21044(15)−0.00008000 s21D25p(3/2)2[3/2]°2 R1c
2620.6656(5)38146.862(7)2620.66627(10)−0.000756000 4p325s(5/2)2[5/2]31.3e+06ER1cK82cal
2636.6187(6)37916.065(8)2636.61965(16)−0.00102200 s21D25p(3/2)2[3/2]°1 R1c
2648.6056(7)37744.477(9)2648.6059(4)−0.00033000 s23F3sp(3F)353 R1c
2655.9644(7)37639.906(9)2655.9642(5)0.0002840 s23F2sp(3F)352 R1c
2666.2906(5)37494.140(8)2666.29047(11)0.0001230000 4p135s(5/2)2[5/2]22.0e+07C+R1cK82
2667.4229(15)37478.224(21)2667.4250(4)−0.0021990 5s(3/2)2[3/2]17p(5/2)2[3/2]°1 R1c
2676.0660(6)37357.184(8)2676.06654(15)−0.00053100 s21D25p(3/2)2[5/2]°2 R1c
2681.4966(15)37281.533(21)2681.4957(7)0.00082100 5s(3/2)2[3/2]27p(5/2)2[5/2]°2 R1c
2682.7484(8)37264.137(11)2682.75015(9)−0.0017440 4p315s(3/2)2[3/2]29.e+05ER1cK82cal
2689.2993(5)37173.370(7)2689.29932(11)0.0000410000 4p135s(5/2)2[5/2]35.9e+07C+R1cC94
2692.4978(15)37129.213(21)2692.4942(4)0.00363200 4d(5/2)2[7/2]36f(3/2)2[9/2]°4 R1c
2700.96242(17)37012.8599(24)2700.96252(9)−0.00011520000 4p325s(3/2)2[3/2]21.02e+08C+FC94
2703.18424(13)36982.4398(18)2703.18448(8)−0.00024540000 4p315s(3/2)2[3/2]11.17e+08C+FC94
2704.5194(23)36964.18(3)2704.5157(16)0.00371100 s23P1sp(3P)351 R1c
2708.2695(8)36913.003(11)2708.2695(3)−0.00007200 4d(5/2)2[1/2]18p(5/2)2[3/2]°1 R1c
2709.7592(6)36892.711(8)2709.7597(3)−0.00061600 4d(5/2)2[1/2]16f(5/2)2[5/2]°2 R1c
2710.2454(16)36886.093(21)2710.2434(6)0.00202700 s23P2sp(3P)352 R1c
2710.6069(16)36881.173(21)2710.6071(7)−0.0001700 4d(5/2)2[1/2]06f(3/2)2[3/2]°1 R1c
2711.5767(23)36867.98(3)2711.5711(13)0.0057350 s23P2sp(3P)353 R2nc
2711.8649(6)36864.066(8)2711.8639(3)0.001018000 4d(5/2)2[1/2]16f(5/2)2[3/2]°2 R1c
2713.5078(5)36841.748(7)2713.50740(10)0.0004400000 4p125s(5/2)2[5/2]28.9e+07C+R1cC94
2715.4038(6)36816.024(8)2715.4039(6)−0.000010000 4d(5/2)2[1/2]16f(5/2)2[1/2]°0 R1c
2718.7770(3)36770.349(4)2718.77770(14)−0.0007440000 4p115s(3/2)2[3/2]28.0e+07C+FC94
2721.6764(2)36731.179(3)2721.67628(9)0.0002300000 4p325s(3/2)2[3/2]13.9e+07C+FK82L
2727.6947(6)36650.142(8)2727.6948(5)−0.0001620 4d(5/2)2[1/2]16f(5/2)2[1/2]°1 R2nc
2728.204(7)36643.30(10)2728.2019(16)0.002310 s23P0sp(3P)351 R1c
2731.9477(6)36593.089(7)2731.94820(16)−0.00056300 s21D2sp(3F)312 R1c
2737.3415(6)36520.989(7)2737.34194(10)−0.000548000 4p125s(5/2)2[5/2]31.9e+06DR1cC94
2739.7662(6)36488.669(8)2739.76664(14)−0.000486000 4p115s(3/2)2[3/2]14.0e+06DR1cC94
2745.2710(6)36415.506(7)2745.27056(10)0.0005140000 4p335s(5/2)2[5/2]21.40e+07C+R1cC94
2757.3283(7)36256.276(9)2757.3290(4)−0.0007770 4d(3/2)2[1/2]16f(3/2)2[5/2]°2 R1c
2759.6070(8)36226.340(11)2759.6065(7)0.0005760 4d(3/2)2[1/2]16f(3/2)2[3/2]°1 R1c
2762.481(20)36188.6(3)2762.4581(4)0.0231000*4d(3/2)2[5/2]37f(5/2)2[7/2]°4 R1c
2762.481(20)36188.6(3)2762.5072(5)−0.0261000*4d(3/2)2[5/2]37f(5/2)2[5/2]°3 R1c
2769.6690(6)36094.738(7)2769.66882(9)0.0002310000 4p335s(5/2)2[5/2]36.7e+07C+R1cC94
2788.2614(7)35854.067(9)2788.2619(3)−0.00055700 4d(5/2)2[9/2]56f(5/2)2[9/2]°5 R1c
2789.2226(17)35841.712(21)2789.2218(12)0.0009210 5p(5/2)2[7/2]°310s(5/2)2[5/2]2 R1c
2791.7945(6)35808.695(8)2791.7947(4)−0.000254000 4d(5/2)2[9/2]56f(5/2)2[11/2]°6 R1c
2792.224(11)35803.19(14)2792.2125(3)0.012420*4d(5/2)2[9/2]56f(5/2)2[11/2]°5 R1c
2792.224(11)35803.19(14)2792.2312(4)−0.007420*4d(5/2)2[3/2]26f(5/2)2[7/2]°3 R1c
2793.6079(7)35785.452(9)2793.6091(3)−0.0012620 4d(5/2)2[3/2]28p(5/2)2[3/2]°1 R1c
2795.2979(6)35763.818(8)2795.2980(3)−0.00018000 4d(5/2)2[3/2]26f(5/2)2[5/2]°3 R1c
2795.6571(7)35759.223(9)2795.6567(3)0.00044600 4d(5/2)2[9/2]46f(5/2)2[9/2]°4 R1c
2795.8729(11)35756.463(14)2795.8732(3)−0.0003610 4d(5/2)2[9/2]46f(5/2)2[7/2]°4 R1c
2796.2625(7)35751.482(9)2796.2624(5)0.0001820 4d(3/2)2[7/2]36f(3/2)2[7/2]°3 R1c
2797.2549(6)35738.798(8)2797.2557(3)−0.00087500 4d(5/2)2[3/2]16f(5/2)2[5/2]°2 R1c
2797.4336(6)35736.516(8)2797.4337(3)−0.00018300 4d(5/2)2[3/2]26f(5/2)2[3/2]°2 R1c
2797.5493(12)35735.038(16)2797.5494(5)−0.0001410 4d(5/2)2[3/2]26f(5/2)2[3/2]°1 R1c
2798.8296(17)35718.692(21) 200 5p(5/2)2[7/2]°410s(5/2)2[5/2]3 R1c
2799.5280(6)35709.781(8)2799.5291(3)−0.001035000 4d(5/2)2[9/2]46f(5/2)2[11/2]°5 R1c
2799.6805(6)35707.837(8)2799.6812(4)−0.000710000 4d(3/2)2[7/2]36f(3/2)2[9/2]°4 R1c
2801.0500(6)35690.379(8)2801.05008(16)−0.00011000 s21D25p(5/2)2[5/2]°3 R1c
2801.3182(24)35686.96(3)2801.3220(17)−0.0038400 4d(3/2)2[3/2]2sp33 R2nc
2803.2711(17)35662.102(21)2803.2706(6)0.0005390 4d(5/2)2[3/2]16f(5/2)2[1/2]°0 R1c
2804.1888(17)35650.432(21)2804.1896(12)−0.0008200 5p(5/2)2[5/2]°210s(5/2)2[5/2]2 R1c
2807.1550(8)35612.763(10)2807.1556(5)−0.0006770 4d(3/2)2[7/2]46f(3/2)2[7/2]°4 R1c
2810.3655(17)35572.082(21)2810.3657(4)−0.0002190 4d(3/2)2[7/2]46f(3/2)2[9/2]°4 R1c
2810.8038(6)35566.536(7)2810.8039(4)−0.000114000 4d(3/2)2[7/2]46f(3/2)2[9/2]°5 R1c
2813.6315(7)35530.793(9)2813.63100(16)0.00052900 s21D25p(5/2)2[3/2]°1 R1c
2816.1978(9)35498.417(11)2816.1982(5)−0.00043700 4d(3/2)2[3/2]16f(3/2)2[3/2]°2 R1c
2817.0843(7)35487.247(9)2817.08465(18)−0.0004370 s21D25p(5/2)2[5/2]°2 R1c
2828.6968(7)35341.570(9)2828.6970(3)−0.00023500 4d(5/2)2[5/2]36f(5/2)2[9/2]°4 R1c
2828.9184(12)35338.802(15)2828.9187(3)−0.00033500 4d(5/2)2[5/2]36f(5/2)2[7/2]°4 R1c
2830.2314(8)35322.408(10)2830.2323(3)−0.00086100 4d(5/2)2[5/2]36f(5/2)2[5/2]°3 R1c
2832.4214(7)35295.099(9)2832.4217(3)−0.00043400 4d(5/2)2[5/2]36f(5/2)2[3/2]°2 R1c
2833.053(2)35287.23(3)2833.0250(5)0.028170?sp(3F)3337d(5/2)2[3/2]2 R1c X
2834.9699(17)35263.372(21)2834.9704(5)−0.0005510 4d(3/2)2[3/2]26f(3/2)2[3/2]°2 R1c
2836.2898(8)35246.962(10)2836.2911(5)−0.00134600 4d(3/2)2[3/2]26f(3/2)2[5/2]°3 R1c
2836.6971(17)35241.902(21)2836.7201(6)−0.0230840?sp(3F)3329s(5/2)2[5/2]2 R1c X
2837.3682(6)35233.566(7)2837.36814(10)0.0001150000 4p315s(5/2)2[5/2]22.3e+07C+R1cC94
2840.4918(6)35194.823(8)2840.49162(17)0.00025800 s23P25p(3/2)2[3/2]°2 R1c
2846.8683(7)35115.996(8)2846.8693(5)−0.00094300 4d(5/2)2[7/2]36f(5/2)2[7/2]°3 R1c
2848.4999(6)35095.883(8)2848.5005(3)−0.000511000 4d(5/2)2[7/2]36f(5/2)2[9/2]°4 R1c
2848.7252(6)35093.108(8)2848.7252(3)−0.00009100 4d(5/2)2[7/2]36f(5/2)2[7/2]°4 R1c
2849.9526(10)35077.995(12)2849.9500(3)0.0026160 4d(5/2)2[7/2]36f(5/2)2[5/2]°2 R1c
2851.8949(8)35054.106(10)2851.8944(5)0.00054700 4d(5/2)2[5/2]26f(5/2)2[7/2]°3 R1c
2852.0764(7)35051.875(8)2852.0764(3)0.000112000 4d(5/2)2[7/2]46f(5/2)2[9/2]°5 R1c
2852.1785(11)35050.621(13)2852.1793(3)−0.00086300 4d(5/2)2[7/2]46f(5/2)2[9/2]°4 R1c
2852.4042(6)35047.847(8)2852.4046(3)−0.00043900 4d(5/2)2[7/2]46f(5/2)2[7/2]°4 R1c
2853.7403(7)35031.439(8)2853.7401(3)0.0002630 4d(5/2)2[7/2]46f(5/2)2[5/2]°3 R1c
2854.9858(7)35016.157(9)2854.9860(3)−0.00022100 4d(5/2)2[5/2]26f(5/2)2[5/2]°2 R1c
2855.0785(5) m4d(3/2)2[5/2]36f(3/2)2[7/2]°3 R1nc
2855.0930(17)35014.842(21)2855.0937(3)−0.0007310 4d(5/2)2[5/2]26f(5/2)2[5/2]°3 R1c
2855.3206(7)35012.052(8)2855.3215(5)−0.00094700 4d(3/2)2[5/2]36f(3/2)2[7/2]°4 R1c
2856.2109(7)35001.138(8)2856.2100(4)0.0010310 4d(5/2)2[7/2]46f(5/2)2[11/2]°5 R1c
2857.4418(17)34986.062(21)2857.4425(5)−0.0007310 4d(5/2)2[5/2]26f(5/2)2[3/2]°1 R1c
2857.7484(6)34982.309(8)2857.74808(11)0.000319000 4p325s(5/2)2[5/2]25.e+05ER1cK82cal
2859.0051(7)34966.932(8)2859.0054(5)−0.00035300 4d(3/2)2[5/2]26f(3/2)2[7/2]°3 R1c
2859.9192(7)34955.757(9)2859.9187(4)0.00052300 4d(3/2)2[5/2]26f(3/2)2[5/2]°2 R1c
2860.2493(9)34951.723(11)2860.24866(19)0.00061100 s23P15p(3/2)2[3/2]°2 R1c
2862.3233(7)34926.399(8)2862.3233(5)−0.00003000 4d(3/2)2[5/2]36f(3/2)2[5/2]°3 R1c
2866.2706(17)34878.302(21)2866.2702(5)0.0004740 4d(3/2)2[5/2]26f(3/2)2[5/2]°3 R1c
2868.7914(8)34847.656(9)2868.7906(4)0.0008440 4d(5/2)2[1/2]08p(5/2)2[3/2]°1 R1c
2872.9461(7)34797.263(8)2872.9460(5)0.0001580 4d(5/2)2[1/2]06f(5/2)2[3/2]°1 R1c
2875.3341(7)34768.365(9)2875.3346(5)−0.0005570 5p(5/2)2[3/2]°28d(5/2)2[5/2]3 R1c
2877.6996(6)34739.786(7)2877.69898(16)0.0007170000 4p115s(5/2)2[5/2]22.3e+07C+R1cC94
2880.7003(7)34703.600(9)2880.69947(17)0.00092000 s21D25p(5/2)2[3/2]°2 R1c
2881.0216(8)34699.730(9)2881.02191(20)−0.00031000 s23P15p(3/2)2[3/2]°1 R1c
2883.1886(18)34673.651(21) 2800 5p(5/2)2[3/2]°28d(5/2)2[1/2]1 R1c
2884.1954(6)34661.548(8)2884.19598(11)−0.000641000 4p325s(5/2)2[5/2]31.20e+07C+R1cC94
2884.7560(7)34654.812(9)2884.75571(16)0.0003280 s23P25p(3/2)2[5/2]°3 R1c
2897.2206(7)34505.726(8)2897.21944(17)0.00111200 s23P25p(3/2)2[1/2]°1 R1c
2907.9162(8)34378.816(10)2907.9158(3)0.00041300 s23P05p(3/2)2[3/2]°1 R1c
2908.863(3)34367.63(3)2908.8746(4)−0.012130 sp(3F)3338s(5/2)2[5/2]3 R1c X
2912.4526(18)34325.271(21) 250 5p(5/2)2[3/2]°18d(5/2)2[1/2]0 R1c
2917.7762(9)34262.646(11)2917.77629(20)−0.0001620 s23P15p(3/2)2[1/2]°1 R1c
2923.2569(18)34198.411(21)2923.2586(8)−0.0017240 5p(5/2)2[7/2]°38d(5/2)2[7/2]3 R1c
2926.2499(7)34163.434(8)2926.2501(4)−0.0002240 5p(5/2)2[3/2]°29s(5/2)2[5/2]3 R1c
2927.2539(7)34151.717(9)2927.2535(5)0.00032900 5p(5/2)2[7/2]°38d(5/2)2[9/2]4 R1c
2928.1916(18)34140.781(21)2928.18542(19)0.0062240 s23P15p(3/2)2[5/2]°2 R1c
2931.789(3)34098.89(4)2931.7851(4)0.004230 sp(3F)3338s(5/2)2[5/2]3 R1c
2932.2253(7)34093.818(9)2932.2254(6)−0.00021200 5p(5/2)2[7/2]°48d(5/2)2[7/2]4 R1c
2933.565(6)34078.25(7)2933.5614(6)0.003230 sp(3F)3347d(5/2)2[7/2]4 R1c
2936.9553(7)34038.912(8)2936.9555(7)−0.00022900 5p(5/2)2[7/2]°48d(5/2)2[9/2]5 R1c
2939.7041(9)34007.084(10)2939.7036(8)0.00051100 5p(5/2)2[5/2]°28d(5/2)2[7/2]3 R1c
2941.2137(18)33989.631(21)2941.2085(6)0.00521100 sp(3F)3347d(5/2)2[9/2]5 R1c
2942.623(5)33973.35(6)2942.6237(18)−0.001230 5p(5/2)2[3/2]°18d(5/2)2[5/2]2 R1c
2945.370(8)33941.66(9)2945.3640(3)0.0076100 s23P05p(3/2)2[1/2]°1 S36c
2947.3037(11)33919.401(12)2947.3037(11)0.0000670 5p(5/2)2[3/2]°18d(5/2)2[3/2]1 R1c
2949.3463(18)33895.911(21)2949.3453(10)0.0010550 5p(3/2)2[5/2]°39d(5/2)2[9/2]4 R1c
2957.3211(19)33804.511(21)2957.3242(6)−0.00321100 5p(5/2)2[5/2]°38d(5/2)2[7/2]4 R1c
2959.3285(19)33781.581(21)2959.3276(5)0.0009740 5p(5/2)2[5/2]°38d(5/2)2[5/2]3 R1c
2968.744(3)33674.44(3)2968.7445(4)−0.000200 4d(3/2)2[7/2]36f(5/2)2[9/2]°4 R1c
2973.6495(7)33618.897(8)2973.64712(23)0.00241300 s23P15p(3/2)2[1/2]°0 R1c
2975.271(5)33600.57(6)2975.2681(3)0.003300 sp(3F)3337d(5/2)2[7/2]3 R1c
2975.6294(8)33596.529(9)2975.6286(7)0.00081200 5p(5/2)2[7/2]°39s(5/2)2[5/2]2 R1c
2977.0081(19)33580.971(21)2977.0087(16)−0.00061100 5p(3/2)2[5/2]°29s(3/2)2[3/2]1 R1c
2981.7867(12)33527.156(14)2981.7860(4)0.00071000 5s(5/2)2[5/2]36p(3/2)2[3/2]°2 R1c
2981.945(3)33525.38(3)2981.9449(5)−0.0001400 sp(3F)3337d(5/2)2[9/2]4 R1c
2983.7677(10)33504.898(11)2983.7658(3)0.00181100 4d(5/2)2[1/2]15f(3/2)2[3/2]°1 R1c
2986.3345(8)33476.101(9)2986.3327(3)0.00175700 4d(5/2)2[1/2]15f(3/2)2[3/2]°2 R1c
2987.2351(7)33466.009(8)2987.2353(5)−0.00021400 5p(5/2)2[7/2]°49s(5/2)2[5/2]3 R1c
2992.6695(19)33405.241(21)2992.6698(7)−0.0003460 5p(5/2)2[5/2]°29s(5/2)2[5/2]2 R1c
2993.024(5)33401.28(5) 460 5p(3/2)2[3/2]°28d(3/2)2[5/2]2 R1c
2993.2667(8)33398.576(9)2993.2675(4)−0.0008920 5s(5/2)2[5/2]26p(3/2)2[3/2]°1 R1c
2996.8412(19)33358.741(21)2996.8382(6)0.0030720 sp(3F)3138d(5/2)2[7/2]4 R1c
2998.893(5)33335.92(6)2998.8956(6)−0.003180 sp(3F)3138d(5/2)2[5/2]3 R1c
2999.8710(19)33325.051(21)2999.8701(8)0.0009530 5p(3/2)2[5/2]°39s(3/2)2[3/2]2 R1c
3004.058(5)33278.60(6)3004.0555(5)0.003260 4d(3/2)2[3/2]26f(5/2)2[7/2]°3 R1c
3010.5921(19)33206.381(21)3010.5910(4)0.00111700 5s(5/2)2[5/2]26p(3/2)2[3/2]°2 R1c
3012.2768(19)33187.811(21)3012.2786(5)−0.0018170 5s(5/2)2[5/2]36p(3/2)2[5/2]°3 R1c
3013.2896(11)33176.656(12)3013.2888(5)0.0008170 5p(5/2)2[5/2]°39s(5/2)2[5/2]3 R1c
3014.5445(8)33162.846(9)3014.54413(18)0.00046200 s23P2sp(3F)313 R1c
3024.1816(19)33057.171(21)3024.1822(19)−0.0005230 5s(3/2)2[3/2]2sp(1G)333 R2nc
3027.388(6)33022.16(6)3027.3945(17)−0.00676 5p(3/2)2[3/2]°19s(3/2)2[3/2]1 R1c
3037.6082(20)32911.061(21)3037.6081(19)0.0001140 sp(3F)3128d(5/2)2[5/2]2 R1c
3037.801(3)32908.97(3)3037.8031(6)−0.002710 5s(5/2)2[5/2]26p(3/2)2[5/2]°2 R1c
3041.6787(8)32867.019(9)3041.6786(5)0.00024500 5s(5/2)2[5/2]26p(3/2)2[5/2]°3 R1c
3042.8556(8)32854.308(9)3042.8551(5)0.0005340 5p(5/2)2[3/2]°17d(3/2)2[3/2]2 R1c
3049.2831(10)32785.058(11)3049.2836(8)−0.0005130 5p(3/2)2[3/2]°29s(3/2)2[3/2]2 R1c
3051.9472(20)32756.441(21)3051.9509(7)−0.0038130 sp(3F)3139s(5/2)2[5/2]2 R1c
3052.1596(20)32754.161(21)3052.15798(24)0.0016130 s21D2sp(3F)333 R1c
3053.5737(15)32738.993(16)3053.5735(6)0.0003190 5p(5/2)2[3/2]°17d(3/2)2[1/2]1 R1c
3055.6134(8)32717.140(9)3055.61251(18)0.0009500 s23P25p(5/2)2[5/2]°3 R1c
3056.8491(9)32703.914(9)3056.8484(3)0.0007310 sp(3F)3327d(5/2)2[7/2]3 R1c
3059.8637(9)32671.695(10)3059.8632(5)0.0005420 5p(5/2)2[5/2]°37d(3/2)2[7/2]4 R1c
3062.2814(8)32645.902(8)3062.2814(5)−0.0000590 5s(5/2)2[5/2]26p(3/2)2[1/2]°1 R1c
3066.6018(12)32599.910(13)3066.5985(3)0.0033400 sp(3F)3338s(5/2)2[5/2]3 R1c
3080.3202(20)32454.730(21)3080.3284(6)−0.0082400 sp(3F)3527s(3/2)2[3/2]2 R1c
3081.4480(14)32442.852(15)3081.4527(3)−0.0046150 4d(5/2)2[9/2]45f(3/2)2[7/2]°4 R1c
3082.935(3)32427.21(3)3082.9348(3)−0.00097 4d(5/2)2[3/2]25f(3/2)2[5/2]°2 R1c
3083.3677(8)32422.654(8)3083.3669(3)0.0009970 4d(5/2)2[3/2]25f(3/2)2[5/2]°3 R1c
3085.4342(20)32400.940(21)3085.4421(3)−0.007995 4d(5/2)2[3/2]15f(3/2)2[5/2]°2 R1c
3085.5818(20)32399.390(21)3085.6280(3)−0.046294?4d(5/2)2[9/2]45f(3/2)2[5/2]°3 R1c X
3088.7489(7)32366.170(8)3088.74858(24)0.0003550 4d(5/2)2[9/2]45f(3/2)2[9/2]°5 R1c
3097.8651(13)32270.929(13)3097.86615(23)−0.0011410 s23P15p(5/2)2[5/2]°2 R1c
3110.4745(10)32140.112(10)3110.4732(4)0.001370 sp(3F)3336d(3/2)2[7/2]4 R1c
3121.3959(8)32027.662(8)3121.3961(5)−0.0002150 4d(5/2)2[9/2]57p(5/2)2[7/2]°4 R1c
3121.6428(7)32025.129(7)3121.6415(3)0.0013240 4d(5/2)2[5/2]35f(3/2)2[7/2]°4 R1c
3121.8708(21)32022.790(21)3121.8736(3)−0.002790 4d(5/2)2[5/2]35f(3/2)2[7/2]°3 R1c
3124.7229(8)31993.563(8)3124.7222(3)0.0006440 s23P05p(5/2)2[3/2]°1 R1c
3139.7885(9)31840.054(9)3139.7857(6)0.0028610blsp(3F)3127d(3/2)2[5/2]2 R1c
3140.4073(9)31833.781(9)3140.4064(6)0.0008230 sp(3F)3127d(3/2)2[5/2]3 R1c
3146.0122(8)31777.068(8)3146.0119(3)0.0003480 4d(5/2)2[7/2]35f(3/2)2[7/2]°3 R1c
3148.7869(8)31749.067(8)3148.7856(5)0.0013170 sp(3F)3127d(3/2)2[7/2]3 R1c
3149.6815(21)31740.050(21)3149.6769(3)0.0046260bl4d(5/2)2[7/2]35f(3/2)2[5/2]°2 R1c
3150.2634(9)31734.187(9)3150.2636(3)−0.000288 4d(5/2)2[7/2]45f(3/2)2[7/2]°4 R1c
3150.540(8)31731.40(8)3150.4999(3)0.0404600?4d(5/2)2[7/2]45f(3/2)2[7/2]°3 S36c X
3150.6422(9)31730.372(9)3150.64124(19)0.00103000 s23P25p(5/2)2[3/2]°2 R1c
3151.0505(7)31726.261(7)3151.0506(3)−0.000110000 5s(5/2)2[5/2]36p(5/2)2[5/2]°3 R1c
3152.9000(7)31707.651(7)3152.8992(3)0.00083500 4d(5/2)2[7/2]35f(3/2)2[9/2]°4 R1c
3154.0935(8)31695.653(8)3154.0934(4)0.0001550 5s(5/2)2[5/2]3sp(3F)132 R1c
3155.3760(9)31682.771(9)3155.3765(5)−0.0005380 4d(5/2)2[5/2]37p(5/2)2[5/2]°3 R1c
3155.8323(21)31678.190(21)3155.8290(3)0.0033190 4d(5/2)2[5/2]25f(3/2)2[5/2]°2 R1c
3156.2820(7)31673.677(7)3156.2817(3)0.00031900 4d(5/2)2[5/2]25f(3/2)2[5/2]°3 R1c
3157.8901(8)31657.548(8)3157.88937(23)0.00071900 4d(5/2)2[7/2]45f(3/2)2[9/2]°5 R1c
3158.6729(8)31649.703(8)3158.6734(5)−0.00053700 5s(3/2)2[3/2]16p(3/2)2[3/2]°1 R1c
3162.0434(7)31615.968(7)3162.0438(4)−0.00042300 5p(5/2)2[3/2]°27d(5/2)2[5/2]3 R1c
3163.6838(11)31599.575(11)3163.6842(4)−0.0003610 4d(5/2)2[5/2]25f(3/2)2[3/2]°2 R1c
3166.5879(7)31570.596(7)3166.5873(5)0.00063500 5p(5/2)2[3/2]°27d(5/2)2[3/2]2 R1c
3170.6936(8)31529.717(8)3170.6935(7)0.0001540 5p(3/2)2[1/2]°07d(3/2)2[3/2]1 R1c
3173.6092(9)31500.752(9)3173.6088(3)0.0004330 sp(3F)3326d(3/2)2[5/2]3 R1c
3174.9680(12)31487.271(11)3174.96642(22)0.0016840 s23P15p(5/2)2[3/2]°2 R1c
3176.3094(16)31473.974(16)3176.3108(3)−0.0014230 4d(5/2)2[1/2]15f(5/2)2[5/2]°2 R1c
3177.7392(8)31459.813(8)3177.7397(7)−0.00051700 5p(5/2)2[3/2]°27d(5/2)2[1/2]1 R1c
3177.9692(8)31457.536(8)3177.9705(5)−0.00122700 5s(3/2)2[3/2]16p(3/2)2[3/2]°2 R1c
3179.3173(17)31444.198(17)3179.3163(4)0.0010230 4d(5/2)2[1/2]15f(5/2)2[3/2]°1 R1c
3179.7846(8)31439.577(8)3179.7842(4)0.00046400 4d(5/2)2[1/2]05f(3/2)2[3/2]°1 R1c
3180.2932(9)31434.550(9)3180.2935(6)−0.0003470 5p(3/2)2[1/2]°07d(3/2)2[1/2]1 R1c
3180.7930(21)31429.610(21)3180.7922(4)0.0008230 sp(3F)3326d(3/2)2[3/2]2 R1c
3182.1717(7)31415.994(7)3182.1718(3)−0.000211000 4d(5/2)2[1/2]15f(5/2)2[3/2]°2 R1c
3184.6224(12)31391.819(12)3184.6233(5)−0.0010480 4d(5/2)2[7/2]47p(5/2)2[5/2]°3 R1c
3184.8404(8)31389.670(8)3184.8409(3)−0.000515000 4d(5/2)2[1/2]15f(5/2)2[1/2]°1 R1c
3185.7249(7)31380.955(7)3185.7256(4)−0.00064000 5s(5/2)2[5/2]36p(5/2)2[7/2]°4 R1c
3186.0148(7)31378.100(7)3186.0153(4)−0.00056400 4d(5/2)2[1/2]15f(5/2)2[1/2]°0 R1c
3186.3411(8)31374.887(8)3186.3415(4)−0.00043000 5s(5/2)2[5/2]2sp(3F)132 R1c
3187.0427(13)31367.980(13)3187.0386(5)0.00411200 5s(3/2)2[3/2]26p(3/2)2[3/2]°1 R1c
3188.7231(22)31351.450(21)3188.7259(4)−0.0028490 sp(3F)3326d(3/2)2[7/2]3 R1c
3192.3023(22)31316.300(21)3192.3011(3)0.0012250 5s(5/2)2[5/2]3sp(1G)333 R1c
3198.1052(10)31259.480(9)3198.1052(8)−0.00011000 5p(5/2)2[3/2]°17d(5/2)2[1/2]0 R1c
3204.5231(16)31196.877(16)3204.5259(6)−0.0029640 sp(3F)3346d(5/2)2[7/2]3 R1c
3206.6848(13)31175.847(12)3206.6848(5)−0.00001800 5s(3/2)2[3/2]26p(3/2)2[3/2]°2 R1c
3208.3026(16)31160.127(16)3208.3076(6)−0.00501500 5s(3/2)2[3/2]16p(3/2)2[5/2]°2 R1c
3216.9896(14)31075.987(14)3216.9895(6)0.0001520 5p(3/2)2[5/2]°27d(3/2)2[5/2]2 R1c
3217.3123(22)31072.870(21)3217.3104(4)0.0019650 5p(5/2)2[7/2]°37d(5/2)2[5/2]2 R1c
3217.6410(17)31069.696(17)3217.6411(6)−0.0001390 5p(3/2)2[5/2]°27d(3/2)2[5/2]3 R1rc
3218.2664(15)31063.658(15)3218.2653(6)0.0011260 sp(3F)3346d(5/2)2[9/2]4 R1c
3218.6278(16)31060.170(16)3218.6244(5)0.0034390 5p(5/2)2[7/2]°37d(5/2)2[7/2]4 R1c
3218.7642(8)31058.854(8)3218.7651(4)−0.00092000 5p(5/2)2[7/2]°37d(5/2)2[7/2]3 R1c
3221.9702(22)31027.950(21)3221.9718(6)−0.0016260 5p(3/2)2[5/2]°27d(3/2)2[3/2]2 R1c
3225.3388(8)30995.545(8)3225.3392(3)−0.00042100 5s(5/2)2[5/2]2sp(1G)333 R1c
3226.3290(16)30986.033(16)3226.3301(12)−0.0011260 5p(3/2)2[1/2]°17d(3/2)2[1/2]0 R1c
3226.4395(9)30984.972(9)3226.4380(5)0.0015640 5p(3/2)2[5/2]°27d(3/2)2[7/2]3 R1c
3226.5812(10)30983.611(9)3226.5808(5)0.00045200 5p(5/2)2[7/2]°37d(5/2)2[9/2]4 R1c
3229.5526(8)30955.105(8)3229.5524(5)0.0003970 5p(5/2)2[7/2]°47d(5/2)2[7/2]4 R1c
3233.3754(13)30918.508(12)3233.3722(4)0.00321000 5p(5/2)2[7/2]°47d(5/2)2[5/2]3 R1c
3234.6710(14)30906.125(13)3234.6691(6)0.0019510 5p(3/2)2[1/2]°17d(3/2)2[3/2]2 R1c
3234.7336(10)30905.527(9)3234.7341(5)−0.0005930 5s(5/2)2[5/2]26p(5/2)2[3/2]°1 R1c
3237.1430(16)30882.525(15)3237.1420(7)0.0009250 sp(3F)3537s(5/2)2[5/2]2 R1c
3237.2417(11)30881.583(11)3237.2413(5)0.00041100 5p(5/2)2[5/2]°27d(5/2)2[5/2]2 R1c
3237.5629(5) m5p(5/2)2[7/2]°47d(5/2)2[9/2]4 R1nc
3237.5736(12)30878.417(11)3237.5752(6)−0.00161300 5s(3/2)2[3/2]26p(3/2)2[5/2]°2 R1c
3238.7160(10)30867.526(10)3238.7141(4)0.00191900 5p(5/2)2[5/2]°27d(5/2)2[7/2]3 R1c
3238.8232(8)30866.504(7)3238.8228(6)0.00055500 5p(5/2)2[7/2]°47d(5/2)2[9/2]5 R1c
3239.6499(13)30858.628(12)3239.6507(5)−0.0008250 sp(3F)3128s(3/2)2[3/2]2 R1c
3241.8139(12)30838.030(11)3241.8139(5)−0.0000860 5p(5/2)2[3/2]°17d(5/2)2[5/2]2 R1c
3242.425(10)30832.21(10)3242.4129(5)0.012250*5p(5/2)2[5/2]°27d(5/2)2[5/2]3 R1nc
3242.425(10)30832.21(10)3242.4292(7)−0.004250*sp(3F)3128s(3/2)2[3/2]1 R1c
3245.9402(14)30798.829(13)3245.9405(6)−0.00031500 5p(3/2)2[5/2]°37d(3/2)2[5/2]3 R1c
3246.7898(22)30790.770(21)3246.7839(7)0.0059620 5p(3/2)2[1/2]°17d(3/2)2[1/2]1 R1c
3250.4652(8)30755.955(8)3250.4650(4)0.000311000 4d(3/2)2[1/2]15f(3/2)2[3/2]°2 R1c
3250.8739(13)30752.089(12)3250.8733(7)0.00061200 5p(5/2)2[3/2]°17d(5/2)2[3/2]1 R1c
3251.76(3)30743.7(3)3251.7620(6)0.00240*sp(3F)3345g(5/2)2[11/2]5 R1c
3251.76(3)30743.7(3)3251.7913(5)−0.03240*5p(5/2)2[3/2]°17d(5/2)2[3/2]2 R1c
3252.7830(8)30734.041(8)3252.7838(6)−0.00082400 5p(3/2)2[5/2]°37d(3/2)2[7/2]4 R1c
3253.1078(12)30730.972(11)3253.1070(5)0.00081200 5s(5/2)2[5/2]36p(5/2)2[3/2]°2 R1c
3257.1234(16)30693.086(15)3257.1222(5)0.0012240 5s(5/2)2[5/2]26p(5/2)2[5/2]°2 R1c
3260.0249(11)30665.770(11)3260.0253(5)−0.00042400 5p(5/2)2[5/2]°37d(5/2)2[7/2]4 R1c
3260.1697(17)30664.408(16)3260.1697(4)0.0000240 5p(5/2)2[5/2]°37d(5/2)2[7/2]3 R1c
3261.6469(8)30650.520(8)3261.6476(3)−0.00071800 5p(5/2)2[3/2]°28s(5/2)2[5/2]3 R1c
3263.5546(14)30632.604(13)3263.5530(7)0.0017350 5p(5/2)2[3/2]°17d(5/2)2[1/2]1 R1c
3263.9177(11)30629.197(10)3263.9177(4)0.00003500 5p(5/2)2[5/2]°37d(5/2)2[5/2]3 R1c
3265.3948(14)30615.342(13)3265.3933(6)0.00151100 5s(3/2)2[3/2]26p(3/2)2[1/2]°1 R1c
3268.0990(16)30590.010(15)3268.0988(7)0.0002230 5p(3/2)2[1/2]°08s(3/2)2[3/2]1 R1c
3268.1895(14)30589.163(13)3268.1879(5)0.0016450 5p(5/2)2[5/2]°37d(5/2)2[9/2]4 R1c
3268.7591(13)30583.833(12)3268.7589(5)0.00021400 5p(5/2)2[5/2]°37d(5/2)2[3/2]2 R1c
3270.1104(16)30571.195(15)3270.1113(4)−0.00081000 sp(3F)3316d(3/2)2[5/2]2 R1c
3275.9027(13)30517.143(12)3275.9057(6)−0.00312200 5p(3/2)2[3/2]°17d(3/2)2[5/2]2 R1c
3278.9653(23)30488.640(21)3278.9636(4)0.0017210 sp(3F)3316d(3/2)2[3/2]2 R1c
3281.0757(23)30469.030(21)3281.0724(6)0.0034210 5p(3/2)2[3/2]°17d(3/2)2[3/2]2 R1c
3281.6964(8)30463.268(8)3281.69629(23)0.00019700 4d(5/2)2[9/2]55f(5/2)2[9/2]°5 R1c
3282.0106(9)30460.351(8)3282.01019(24)0.00051100 4d(5/2)2[9/2]55f(5/2)2[9/2]°4 R1c
3282.6022(11)30454.862(10)3282.6016(3)0.0006530 4d(5/2)2[9/2]55f(5/2)2[7/2]°4 R1c
3283.0958(16)30450.283(15)3283.0969(4)−0.0011210 sp(3F)3316d(3/2)2[3/2]1 R1c
3283.2431(13)30448.917(12)3283.2433(7)−0.0002940 5p(3/2)2[3/2]°17d(3/2)2[3/2]1 R1c
3290.4174(4)30382.530(4)3290.41683(16)0.000538000 4d(5/2)2[9/2]55f(5/2)2[11/2]°65.9e+07D+F_ReTW
3291.0597(8)30376.600(7)3291.05952(22)0.00021100 4d(5/2)2[9/2]55f(5/2)2[11/2]°5 R1c
3291.8090(16)30369.686(15)3291.8073(3)0.00172000 4d(5/2)2[9/2]45f(5/2)2[9/2]°5 R1c
3292.1232(8)30366.788(7)3292.1232(3)−0.00007700 4d(5/2)2[9/2]45f(5/2)2[9/2]°4 R1c
3292.7189(10)30361.294(9)3292.7183(3)0.00073500 4d(5/2)2[9/2]45f(5/2)2[7/2]°4 R1c
3292.9965(13)30358.735(12)3292.9984(3)−0.00201500 4d(5/2)2[9/2]45f(5/2)2[7/2]°3 R1c
3293.3326(9)30355.637(8)3293.3327(4)−0.00012800 4d(3/2)2[7/2]35f(3/2)2[7/2]°3 R1c
3294.3354(8)30346.397(7)3294.3355(3)−0.00023800 4d(5/2)2[3/2]25f(5/2)2[5/2]°2 R1c
3295.1019(8)30339.338(7)3295.1018(3)0.000111000 4d(5/2)2[3/2]25f(5/2)2[5/2]°3 R1c
3297.1983(8)30320.048(7)3297.1986(3)−0.00039300 4d(5/2)2[3/2]15f(5/2)2[5/2]°2 R1c
3297.3461(12)30318.689(11)3297.3492(4)−0.00311200 4d(3/2)2[7/2]35f(3/2)2[5/2]°2 R1c
3297.5688(10)30316.642(9)3297.5686(4)0.00021400 4d(5/2)2[3/2]25f(5/2)2[3/2]°1 R1c
3300.2124(14)30292.358(13)3300.2124(4)0.0000380 sp(3F)3337s(3/2)2[3/2]2 R1c
3300.4370(9)30290.296(9)3300.4373(4)−0.00036100 4d(5/2)2[3/2]15f(5/2)2[3/2]°1 R1c
3300.6409(9)30288.425(9)3300.6406(3)0.00039100 4d(5/2)2[3/2]25f(5/2)2[3/2]°2 R1c
3300.8815(9)30286.218(8)3300.8808(3)0.000613000 4d(3/2)2[7/2]35f(3/2)2[9/2]°45.4e+07D+R1cTW
3301.2286(7)30283.034(6)3301.22844(23)0.000125000 4d(5/2)2[9/2]45f(5/2)2[11/2]°55.6e+07D+F_ReTW
3303.1817(12)30265.128(11)3303.1836(6)−0.00181400 5p(3/2)2[3/2]°27d(3/2)2[5/2]2 R1c
3303.5132(21)30262.091(20)3303.5122(4)0.00105800*4d(5/2)2[3/2]25f(5/2)2[1/2]°1 R1c
3303.5132(21)30262.091(20)3303.5147(3)−0.00155800*4d(5/2)2[3/2]15f(5/2)2[3/2]°2 R1c
3303.8698(10)30258.825(9)3303.8706(6)−0.00082300 5p(3/2)2[3/2]°27d(3/2)2[5/2]3 R1c
3306.3890(15)30235.771(14)3306.3913(4)−0.0023180 4d(5/2)2[3/2]15f(5/2)2[1/2]°1 R1c
3307.6576(11)30224.175(10)3307.6570(4)0.00061200 4d(5/2)2[3/2]15f(5/2)2[1/2]°0 R1c
3307.8727(13)30222.210(12)3307.8664(4)0.00631200 4d(3/2)2[7/2]45f(3/2)2[7/2]°4 R1c X
3308.1052(14)30220.086(13)3308.1074(5)−0.00231100 sp(3F)3137d(5/2)2[7/2]4 R1c
3308.2526(15)30218.739(14)3308.2561(4)−0.0035180 sp(3F)3137d(5/2)2[7/2]3 R1c
3308.4337(13)30217.085(12)3308.4367(6)−0.0029360 5p(3/2)2[3/2]°27d(3/2)2[3/2]2 R1c
3310.338(3)30199.70(3)3310.3389(4)−0.00189 sp(3F)3336d(5/2)2[5/2]2 R1c
3312.0278(13)30184.296(11)3312.0276(4)0.0001550 sp(3F)3336d(5/2)2[7/2]4 R1c
3312.1151(14)30183.500(13)3312.1155(5)−0.0004970 sp(3F)3137d(5/2)2[5/2]3 R1c
3312.6771(10)30178.380(9)3312.6783(3)−0.0012610 4d(3/2)2[7/2]45f(3/2)2[5/2]°3 R1c
3315.7440(8)30150.467(7)3315.7431(3)0.00101300 4d(3/2)2[7/2]45f(3/2)2[9/2]°4 R1c
3316.2756(8)30145.634(7)3316.2752(3)0.000416000 4d(3/2)2[7/2]45f(3/2)2[9/2]°55.6e+07D+R1cTW
3316.5116(16)30143.489(15)3316.5129(6)−0.0013260 sp(3F)3137d(5/2)2[9/2]4 R1c
3317.1383(8)30137.794(7)3317.1386(4)−0.00035500 4d(3/2)2[3/2]15f(3/2)2[5/2]°2 R1c
3318.3147(23)30127.110(21)3318.3232(12)−0.008584 sp(3F)3517s(5/2)2[5/2]2 R1c
3319.0203(11)30120.706(10)3319.0216(5)−0.0013840 sp(3F)3336d(5/2)2[5/2]3 R1c
3321.1137(23)30101.720(21)3321.1114(7)0.0023500 5p(3/2)2[3/2]°27d(3/2)2[1/2]1 R1c
3321.5526(8)30097.743(8)3321.5528(3)−0.00021400 5p(5/2)2[7/2]°38s(5/2)2[5/2]2 R1c
3321.7168(14)30096.255(13)3321.7165(8)0.0003410 4d(3/2)2[1/2]17p(5/2)2[3/2]°2 R1c
3322.6363(10)30087.927(9)3322.6351(4)0.00122000 4d(3/2)2[3/2]15f(3/2)2[3/2]°1 R1c
3324.8295(9)30068.080(8)3324.8292(7)0.00031200 5p(3/2)2[5/2]°28s(3/2)2[3/2]1 R1c
3325.0235(13)30066.326(11)3325.0210(4)0.0025720 5s(5/2)2[5/2]26p(5/2)2[7/2]°3 R1c
3325.8187(14)30059.137(12)3325.8184(4)0.00033000 4d(3/2)2[3/2]15f(3/2)2[3/2]°2 R1c
3325.9236(13)30058.189(11)3325.9242(4)−0.0006400 5p(5/2)2[7/2]°38s(5/2)2[5/2]3 R1c
3327.9129(16)30040.222(15)3327.9161(5)−0.0032160 sp(3F)3336d(5/2)2[3/2]2 R1c
3335.4075(14)29972.725(12)3335.4064(5)0.0011520 5p(3/2)2[1/2]°18s(3/2)2[3/2]2 R1c
3337.5951(12)29953.080(11)3337.5942(4)0.00083000 5p(5/2)2[7/2]°48s(5/2)2[5/2]3 R1c
3338.0369(14)29949.116(12)3338.03567(24)0.00129200 4d(5/2)2[5/2]35f(5/2)2[9/2]°4 R1c
3338.6475(9)29943.638(8)3338.6475(3)0.00019900 4d(5/2)2[5/2]35f(5/2)2[7/2]°42.7e+07D+R1cTW
3338.9360(9)29941.051(8)3338.9355(3)0.00053600 4d(5/2)2[5/2]35f(5/2)2[7/2]°3 R1c
3339.0850(9)29939.715(8)3339.0845(4)0.00063600 4d(3/2)2[3/2]25f(3/2)2[7/2]°3 R1c
3340.8308(13)29924.070(11)3340.8312(8)−0.0003720 5s(5/2)2[5/2]3sp(1G)334 R1c
3341.7610(13)29915.741(11)3341.7607(5)0.0003570 sp(3F)3336d(5/2)2[7/2]4 R1c
3342.8004(10)29906.439(9)3342.8003(4)0.0001710 5p(5/2)2[5/2]°28s(5/2)2[5/2]2 R1c
3342.9641(9)29904.975(8)3342.9640(3)0.00011800 4d(5/2)2[5/2]35f(5/2)2[5/2]°2 R1c
3343.2140(24)29902.740(21)3343.2134(4)0.0006280 4d(3/2)2[3/2]25f(3/2)2[5/2]°2 R1c
3343.7214(9)29898.202(8)3343.7215(3)−0.000114000 4d(3/2)2[3/2]25f(3/2)2[5/2]°3 R1c
3343.7515(9)29897.933(8)3343.7531(3)−0.001614000 4d(5/2)2[5/2]35f(5/2)2[5/2]°3 R1c
3347.2268(18)29866.892(16)3347.2279(4)−0.0011140 5p(5/2)2[5/2]°28s(5/2)2[5/2]3 R1c
3347.6754(9)29862.890(8)3347.6762(3)−0.0008550 5p(5/2)2[3/2]°18s(5/2)2[5/2]2 R1c
3348.7955(14)29852.902(12)3348.7967(4)−0.0012540 4d(3/2)2[3/2]25f(3/2)2[3/2]°1 R1c
3348.8824(14)29852.127(12)3348.8809(5)0.0015620 sp(3F)3336d(5/2)2[5/2]3 R1c
3349.4567(8)29847.009(7)3349.4569(3)−0.00024200 4d(5/2)2[5/2]35f(5/2)2[3/2]°2 R1c
3352.0324(12)29824.075(11)3352.0304(4)0.00206400 4d(3/2)2[3/2]25f(3/2)2[3/2]°2 R1c
3352.07929823.663352.0793(6) :5p(3/2)2[5/2]°38s(3/2)2[3/2]2
3354.0672(12)29805.983(11)3354.0677(3)−0.0005330 sp(3F)3327s(3/2)2[3/2]2 R1c
3355.3107(13)29794.937(11)3355.31179(19)−0.0011130 5s(5/2)2[5/2]24f(3/2)2[5/2]°3 R1c
3356.8877(17)29780.940(15)3356.8867(3)0.001064 s23P2sp(3F)333 R1c
3357.4722(10)29775.756(9)3357.4732(5)−0.0010640 sp(3F)3127d(5/2)2[5/2]2 R1c
3357.9368(14)29771.636(12)3357.9364(5)0.0004510 sp(3F)3336d(5/2)2[3/2]2 R1c
3359.0587(9)29761.693(8)3359.0575(4)0.0012950 sp(3F)3127d(5/2)2[7/2]3 R1c
3359.7217(9)29755.820(8)3359.7209(3)0.0008670 sp(3F)3327s(3/2)2[3/2]1 R1c
3363.8287(17)29719.491(15)3363.8300(10)−0.0013310 4d(3/2)2[3/2]17p(5/2)2[5/2]°2 R1c
3365.4414(17)29705.250(15)3365.4436(7)−0.0021610 sp(3F)3535d(3/2)2[3/2]2 R1c
3365.6475(8)29703.431(7)3365.6470(3)0.000511000 4d(5/2)2[7/2]35f(5/2)2[9/2]°42.9e+07D+R1cTW
3366.2696(10)29697.942(9)3366.2690(3)0.000610000 4d(5/2)2[7/2]35f(5/2)2[7/2]°4 R1c
3366.5619(8)29695.364(7)3366.5618(3)0.00016100 4d(5/2)2[7/2]35f(5/2)2[7/2]°3 R1c
3366.8560(24)29692.770(21)3366.8553(4)0.0007120 5s(5/2)2[5/2]24f(3/2)2[3/2]°1 R1c
3370.1508(11)29663.742(10)3370.1503(4)0.0005610 5p(5/2)2[5/2]°38s(5/2)2[5/2]3 R1c
3370.4529(7)29661.083(6)3370.45289(23)−0.000022000 4d(5/2)2[7/2]45f(5/2)2[9/2]°54.3e+07D+F_ReTW
3370.6573(11)29659.285(10)3370.6573(3)−0.00011100 4d(5/2)2[7/2]35f(5/2)2[5/2]°2 R1c
3370.7846(8)29658.165(7)3370.7840(3)0.00065900 4d(5/2)2[7/2]45f(5/2)2[9/2]°4 R1c
3371.4075(9)29652.685(8)3371.4079(3)−0.00046200 4d(5/2)2[7/2]45f(5/2)2[7/2]°4 R1c
3371.7016(9)29650.099(8)3371.7016(3)−0.0000870 4d(5/2)2[7/2]45f(5/2)2[7/2]°3 R1c
3373.5914(8)29633.490(7)3373.5912(3)0.00029700 4d(5/2)2[5/2]25f(5/2)2[7/2]°3 R1c
3374.4423(13)29626.018(11)3374.4427(4)−0.0005170 5s(3/2)2[3/2]1sp(3F)132 R1c
3374.9515(8)29621.548(7)3374.9510(4)0.000512000 4d(3/2)2[5/2]35f(3/2)2[7/2]°44.6e+07D+R1cTW
3375.2221(12)29619.173(11)3375.2222(4)−0.00001400 4d(3/2)2[5/2]35f(3/2)2[7/2]°3 R1c
3376.6139(8)29606.965(7)3376.6143(3)−0.00041300 4d(5/2)2[7/2]45f(5/2)2[5/2]°3 R1c
3377.0834(17)29602.849(15)3377.0829(4)0.0006170 sp(3F)3326d(3/2)2[5/2]2 R1c
3377.2601(14)29601.300(12)3377.2583(3)0.0019110 4d(5/2)2[7/2]35f(5/2)2[3/2]°2 R1c
3377.7037(8)29597.412(7)3377.7038(3)−0.00015300 4d(5/2)2[5/2]25f(5/2)2[5/2]°2 R1c
3378.3846(15)29591.448(13)3378.3831(4)0.0015170 sp(3F)3326d(3/2)2[5/2]3 R1c
3378.5094(8)29590.354(7)3378.5094(3)0.00013500 4d(5/2)2[5/2]25f(5/2)2[5/2]°3 R1c
3379.4421(9)29582.188(8)3379.4410(4)0.0011500 4d(3/2)2[5/2]35f(3/2)2[5/2]°2 R1c
3379.9595(9)29577.660(8)3379.9602(3)−0.00073800 4d(3/2)2[5/2]35f(3/2)2[5/2]°3 R1c
3380.3311(8)29574.409(7)3380.33017(22)0.00091100 4d(5/2)2[7/2]45f(5/2)2[11/2]°5 R1c
3380.7117(8)29571.079(7)3380.7116(4)0.00027600 4d(3/2)2[5/2]25f(3/2)2[7/2]°33.4e+07D+R1cTW
3381.1021(11)29567.665(10)3381.1027(4)−0.00061400 4d(5/2)2[5/2]25f(5/2)2[3/2]°1 R1c
3384.3322(8)29539.446(7)3384.3324(3)−0.00021300 4d(5/2)2[5/2]25f(5/2)2[3/2]°2 R1c
3384.7698(14)29535.627(12)3384.7669(6)0.0029160 5p(3/2)2[3/2]°18s(3/2)2[3/2]2 R1c
3384.9450(9)29534.098(8)3384.9442(4)0.00093600 4d(3/2)2[5/2]25f(3/2)2[5/2]°2 R1c
3385.4657(9)29529.556(8)3385.4650(3)0.00062100 4d(3/2)2[5/2]25f(3/2)2[5/2]°3 R1c
3387.3535(17)29513.099(15)3387.3515(4)0.0021100 4d(5/2)2[5/2]25f(5/2)2[1/2]°1 R1c
3387.7986(17)29509.222(15)3387.8000(8)−0.0015210 5p(3/2)2[3/2]°18s(3/2)2[3/2]1 R1c
3388.4491(14)29503.557(12)3388.4504(4)−0.0013420 4d(3/2)2[5/2]35f(3/2)2[3/2]°2 R1c
3390.6470(10) m4d(3/2)2[3/2]27p(5/2)2[5/2]°2 R1c
3390.664(20)29484.29(17)3390.6678(4)−0.004260 4d(3/2)2[5/2]25f(3/2)2[3/2]°1 R1c
3390.9325(24)29481.950(21)3390.9337(4)−0.0012100 sp(3F)3326d(3/2)2[3/2]1 R1c
3392.7462(24)29466.190(21)3392.7444(4)0.0019130 s23P1sp(3F)331 R1c
3393.9761(18)29455.513(16)3393.9803(13)−0.0042150*sp(3P)3527g(5/2)2[7/2]3 R1c X
3393.9761(18)29455.513(16)3393.9829(4)−0.0069150*4d(3/2)2[5/2]25f(3/2)2[3/2]°2 R1c X
3393.9909(15)29455.384(13)3393.9914(6)−0.0004150 sp(3F)3347s(5/2)2[5/2]3 R1c
3395.2150(9)29444.765(8)3395.2154(4)−0.00042000 sp(3F)3326d(5/2)2[5/2]2 R1c
3395.5206(10)29442.115(9)3395.5191(4)0.0015450 sp(3F)3326d(3/2)2[7/2]3 R1c
3397.3752(9)29426.043(8)3397.3754(3)−0.0002740 sp(3F)3326d(5/2)2[7/2]3 R1c
3400.4535(9)29399.406(8)3400.4535(6)0.000096 4d(3/2)2[3/2]27p(5/2)2[3/2]°1 R1c
3402.8301(9)29378.873(7)3402.8303(4)−0.00021500 4d(5/2)2[1/2]05f(5/2)2[3/2]°1 R1c
3406.835(2)29344.340(21)3406.8351(4)−0.000140 5s(3/2)2[3/2]2sp(3F)132 R1c
3409.1599(8)29324.327(7)3409.1597(4)0.00011400 4d(5/2)2[1/2]05f(5/2)2[1/2]°1 R1c
3410.4564(17)29313.180(15)3410.4549(5)0.001590 5s(5/2)2[5/2]2sp(3P)312 R1c
3410.6738(13)29311.311(11)3410.6739(9)−0.000090 5p(3/2)2[1/2]°17d(5/2)2[1/2]0 R1c
3412.2696(10)29297.604(9)3412.2691(4)0.0005130 sp(3F)3326d(5/2)2[3/2]1 R1c
3413.7074(14)29285.265(12)3413.7080(5)−0.0007180 sp(3F)3326d(5/2)2[3/2]2 R1c
3413.8952(9)29283.654(8)3413.8957(6)−0.0006220 5p(3/2)2[3/2]°28s(3/2)2[3/2]2 R1c
3416.9362(12)29257.593(11)3416.9349(4)0.0012170 sp(3F)3138s(5/2)2[5/2]2 R1c
3421.5612(10)29218.046(8)3421.5612(4)−0.0001850 sp(3F)3138s(5/2)2[5/2]3 R1c
3428.7658(10)29156.654(8)3428.7659(5)−0.0001330 5s(3/2)2[3/2]16p(5/2)2[3/2]°1 R1c
3430.1011(12)29145.304(10)3430.1015(4)−0.000481 s23P0sp(3F)331 R1c
3433.9380(9)29112.740(8)3433.9259(7)0.0120120?4d(3/2)2[5/2]37p(5/2)2[7/2]°4 R1c X
3437.1829(19)29085.256(16)3437.1784(5)0.004578 sp(3F)3326d(5/2)2[1/2]1 R1c
3444.1360(17)29026.540(14)3444.1368(7)−0.000875 sp(3F)3316d(5/2)2[1/2]0 R1c
3445.9053(16)29011.637(13)3445.9035(5)0.001837 5p(3/2)2[5/2]°27d(5/2)2[5/2]2 R1c
3451.4534(9)28965.003(8)3451.4543(4)−0.0009360 5s(3/2)2[3/2]2sp(1G)333 R1c
3453.9306(10)28944.230(9)3453.9308(6)−0.0002540 5s(3/2)2[3/2]16p(5/2)2[5/2]°2 R1c
3460.045(3)28893.080(21)3460.0456(7)−0.000350 sp(3F)3346d(5/2)2[7/2]4 R1c
3460.4304(14)28889.865(11)3460.4309(5)−0.000569 5p(3/2)2[1/2]°17d(5/2)2[5/2]2 R1c
3461.9510(15)28877.176(12)3461.9515(5)−0.0005100 5s(5/2)2[5/2]2sp(1G)332 R1nc
3463.4085(10)28865.024(9)3463.4094(3)−0.0009140 sp(3F)3317s(3/2)2[3/2]2 R1c
3467.679(3)28829.480(21)3467.6793(7)−0.001200 sp(3F)3346d(5/2)2[5/2]3 R1c
3469.4366(10)28814.873(9)3469.4375(4)−0.00091000 sp(3F)3317s(3/2)2[3/2]1 R1c
3470.7569(14)28803.912(11)3470.7552(8)0.0017130 5p(3/2)2[1/2]°17d(5/2)2[3/2]1 R1c
3471.1558(10)28800.602(8)3471.1560(4)−0.0003260 sp(3F)3128s(5/2)2[5/2]2 R1c
3472.0275(10)28793.371(9)3472.0278(3)−0.0003130 sp(3F)3337s(3/2)2[3/2]2 R1c
3473.0008(10)28785.302(8)3473.0010(4)−0.0002330 5s(5/2)2[5/2]3sp(3F)132 R1c
3476.4708(17)28756.571(14)3476.4703(7)0.000597 sp(3F)3346d(5/2)2[9/2]4 R1c
3478.950(3)28736.080(21)3478.9487(7)0.001640 sp(3F)3346d(5/2)2[9/2]5 R1c
3483.8304(9)28695.825(8)3483.8297(4)0.0006310 4d(3/2)2[1/2]15f(5/2)2[3/2]°2 R1c
3487.0291(9)28669.502(7)3487.0290(4)0.0001470 4d(3/2)2[1/2]15f(5/2)2[1/2]°1 R1c
3488.0212(16)28661.348(13)3488.0222(6)−0.001031 5s(3/2)2[3/2]16p(5/2)2[3/2]°2 R1c
3488.4370(9)28657.932(7)3488.4369(5)0.0001150 4d(3/2)2[1/2]15f(5/2)2[1/2]°0 R1c
3501.612(3)28550.110(21)3501.6122(4)−0.00059 5p(5/2)2[3/2]°26d(3/2)2[5/2]2 R1c
3503.0098(9)28538.716(8)3503.0101(3)−0.0003150 5p(5/2)2[3/2]°26d(3/2)2[5/2]3 R1c
3504.6643(15)28525.244(12)3504.6642(4)0.000159 s23P1sp(3F)332 R1c
3506.8362(11)28507.578(9)3506.8359(4)0.0003330 sp(3F)3337s(5/2)2[5/2]2 R1c
3507.3014(10)28503.797(8)3507.3011(4)0.000358 sp(3F)3316d(5/2)2[5/2]2 R1c
3515.2292(11)28439.515(9)3515.2302(4)−0.0011850 sp(3F)3337s(5/2)2[5/2]3 R1c
3516.1395(14)28432.152(11)3516.1396(4)−0.0001110 sp(3F)3336d(5/2)2[5/2]2 R1c
3516.7786(9)28426.985(8)3516.7792(3)−0.0006280 5s(5/2)2[5/2]3sp(3F)133 R1c
3518.0440(10)28416.761(8)3518.0449(4)−0.0009230 sp(3F)3336d(5/2)2[7/2]4 R1c
3518.4565(9)28413.429(7)3518.4562(3)0.0003420 sp(3F)3336d(5/2)2[7/2]3 R1c
3522.643(3)28379.660(21)3522.6429(6)0.00084 5s(3/2)2[3/2]26p(5/2)2[3/2]°2 R1c
3525.5026(16)28356.644(13)3525.5023(5)0.000355 sp(3F)3316d(5/2)2[3/2]1 R1c
3525.9383(15)28353.140(12)3525.9370(4)0.0013140 sp(3F)3336d(5/2)2[5/2]3 R1c
3534.6784(20)28283.034(16)3534.6781(9)0.000227 5p(5/2)2[3/2]°16d(3/2)2[1/2]0 R1c
3534.809(5)28281.99(4)3534.8076(3)0.002410*4d(3/2)2[7/2]35f(5/2)2[9/2]°4 R1c
3534.809(5)28281.99(4)3534.8127(5)−0.004410*s23P2sp(3F)333 R1c
3535.0258(14)28280.254(11)3535.0262(4)−0.00031100 sp(3F)3336d(5/2)2[9/2]4 R1c
3535.4942(10)28276.508(8)3535.4937(3)0.0005220 4d(3/2)2[7/2]35f(5/2)2[7/2]°4 R1c
3535.8163(12)28273.932(9)3535.8167(3)−0.0004190 4d(3/2)2[7/2]35f(5/2)2[7/2]°3 R1c
3535.9757(10)28272.657(8)3535.9767(5)−0.0009140 sp(3F)3336d(5/2)2[3/2]2 R1c
3540.1850(15)28239.042(12)3540.1870(5)−0.0020110 sp(3F)3337s(5/2)2[5/2]2 R1c
3540.3356(19)28237.841(15)3540.3346(4)0.0010110 4d(3/2)2[7/2]35f(5/2)2[5/2]°2 R1c
3541.2200(20)28230.789(16)3541.2196(4)0.000427 4d(3/2)2[7/2]35f(5/2)2[5/2]°3 R1c
3546.7568(21)28186.719(17)3546.7551(5)0.001727 5p(3/2)2[3/2]°27d(5/2)2[7/2]3 R1c
3548.7423(11)28170.949(9)3548.7419(4)0.00041400 sp(3F)3337s(5/2)2[5/2]3 R1c
3551.4887(13)28149.165(10)3551.4887(3)0.0001530 4d(3/2)2[7/2]45f(5/2)2[9/2]°5 R1c
3551.8563(10)28146.252(8)3551.8563(3)−0.0000210 4d(3/2)2[7/2]45f(5/2)2[9/2]°4 R1c
3552.5495(12)28140.760(9)3552.5490(3)0.0005110 4d(3/2)2[7/2]45f(5/2)2[7/2]°4 R1c
3552.8735(15)28138.194(12)3552.8751(3)−0.001653 4d(3/2)2[7/2]45f(5/2)2[7/2]°3 R1c
3555.4287(21)28117.972(17)3555.43262(15)−0.003953 5s(5/2)2[5/2]34f(5/2)2[7/2]°4 R1c
3556.915(5)28106.22(4)3556.9167(3)−0.00179*5s(5/2)2[5/2]2sp(3F)133 R1c
3556.915(5)28106.22(4)3556.9231(7)−0.00879*5p(3/2)2[3/2]°27d(5/2)2[3/2]2 R1nc
3558.332(4)28095.03(3)3558.3303(4)0.00252 4d(3/2)2[7/2]45f(5/2)2[5/2]°3 R1c
3562.4574(10)28062.497(8)3562.4572(3)0.0002100 4d(3/2)2[7/2]45f(5/2)2[11/2]°5 R1c
3563.1578(10)28056.981(8)3563.1580(4)−0.000278 4d(3/2)2[3/2]15f(5/2)2[5/2]°2 R1c
3565.7620(21)28036.491(17)3565.7601(4)0.001852 5p(3/2)2[5/2]°28s(5/2)2[5/2]2 R1c
3565.8472(10)28035.821(8)3565.8496(4)−0.0024210 5s(3/2)2[3/2]26p(5/2)2[7/2]°3 R1c
3566.9405(11)28027.228(9)3566.9405(5)−0.000052 4d(3/2)2[3/2]15f(5/2)2[3/2]°1 R1c
3567.801(3)28020.470(21)3567.79746(15)0.00373 5s(5/2)2[5/2]34f(5/2)2[5/2]°3 R1c
3568.7006(18)28013.405(14)3568.7005(4)0.000178 s23P2sp(3F)333 R1c
3573.5908(14)27975.072(11)3573.58964(18)0.0011520 5s(5/2)2[5/2]34f(5/2)2[7/2]°3 R1c
3575.373(4)27961.13(3)3575.3666(24)0.00626*sp(1D)3329s(3/2)2[3/2]1 R1nc
3575.373(4)27961.13(3)3575.3746(5)−0.00226*4d(3/2)2[3/2]15f(5/2)2[1/2]°0 R1c
3577.5874(19)27943.821(15)3577.5764(4)0.011051?5s(3/2)2[3/2]14f(3/2)2[3/2]°1 R1c X
3578.4051(17)27937.436(13)3578.4043(6)0.0008130 5s(5/2)2[5/2]3sp(3P)352 R1c
3581.3166(13)27914.724(10)3581.3179(4)−0.001326 5p(3/2)2[1/2]°18s(5/2)2[5/2]2 R1c
3583.6322(15)27896.687(11)3583.6328(3)−0.000577 sp(3F)3327s(3/2)2[3/2]2 R1c
3588.6079(9)27858.009(7)3588.6074(3)0.0005200 4d(3/2)2[3/2]25f(5/2)2[7/2]°3 R1c
3590.0862(10)27846.538(8)3590.0870(3)−0.0008650 sp(3F)3327s(3/2)2[3/2]1 R1c
3592.1150(19)27830.811(15)3592.1139(5)0.001151 5p(5/2)2[7/2]°36d(3/2)2[7/2]4 R1c
3592.3528(10)27828.969(8)3592.3522(5)0.0005770 5s(3/2)2[3/2]1sp(3F)131 R1c
3593.2610(10)27821.935(8)3593.2613(4)−0.0002100 4d(3/2)2[3/2]25f(5/2)2[5/2]°2 R1c
3594.1722(18)27814.882(14)3594.1729(4)−0.0008130 4d(3/2)2[3/2]25f(5/2)2[5/2]°3 R1c
3597.100(3)27792.240(21)3597.1080(5)−0.00851 4d(3/2)2[3/2]25f(5/2)2[3/2]°1 R1c
3600.4380(11)27766.477(8)3600.4382(4)−0.000276 5p(5/2)2[5/2]°26d(3/2)2[5/2]2 R1c
3600.7635(10)27763.967(7)3600.7638(4)−0.0002130 4d(3/2)2[3/2]25f(5/2)2[3/2]°2 R1c
3601.9187(19)27755.063(15)3601.9162(4)0.0025200 5p(5/2)2[5/2]°26d(3/2)2[5/2]3 R1c
3602.2331(11)27752.641(8)3602.2324(3)0.00071200 sp(3F)3327s(5/2)2[5/2]2 R1c
3606.6576(11)27718.596(8)3606.6576(4)0.00001900 5s(5/2)2[5/2]3sp(3F)133 R1c
3611.0901(10)27684.573(7)3611.0902(3)−0.0001370 sp(3F)3327s(5/2)2[5/2]3 R1c
3611.17227683.943611.1721(4) :5p(5/2)2[5/2]°26d(3/2)2[3/2]2
3615.0429(20)27654.303(16)3615.04192(19)0.001025 5s(5/2)2[5/2]24f(5/2)2[7/2]°3 R1c
3616.8636(10)27640.382(7)3616.8630(4)0.0007890 5p(5/2)2[3/2]°16d(3/2)2[3/2]2 R1c
3621.4008(19)27605.753(15)3621.4013(5)−0.000526 5p(5/2)2[5/2]°26d(3/2)2[7/2]3 R1c
3621.8942(11)27601.992(8)3621.8927(4)0.001677 5p(5/2)2[3/2]°16d(3/2)2[3/2]1 R1c
3626.350(3)27568.080(21)3626.3111(9)0.03977?sp(3F)3146d(5/2)2[7/2]4 R1c X
3626.973(3)27563.340(21)3626.9734(4)−0.00051 5p(5/2)2[5/2]°36d(3/2)2[5/2]2 R1c
3628.4741(10)27551.940(8)3628.4733(4)0.0008130 5p(5/2)2[5/2]°36d(3/2)2[5/2]3 R1c
3629.0907(16)27547.259(12)3629.0858(5)0.004951 5s(3/2)2[3/2]2sp(3F)131 R1c
3629.3186(19)27545.529(15)3629.3176(3)0.001126 4d(3/2)2[5/2]35f(5/2)2[9/2]°4 R1c
3630.0412(11)27540.046(8)3630.0408(3)0.0004100 4d(3/2)2[5/2]35f(5/2)2[7/2]°4 R1c
3630.6454(10)27535.463(7)3630.6450(4)0.0004380 sp(3F)3326d(5/2)2[5/2]2 R1c
3631.6198(22)27528.075(17)3631.61939(23)0.000451 5s(5/2)2[5/2]24f(5/2)2[1/2]°1 R1c
3633.1159(10)27516.740(8)3633.1151(4)0.0008520 sp(3F)3326d(5/2)2[7/2]3 R1c
3635.1554(17)27501.302(13)3635.1443(4)0.0111210bl4d(3/2)2[5/2]35f(5/2)2[5/2]°2 R1c X
3636.0783(17)27494.322(13)3636.0773(4)0.000977 4d(3/2)2[5/2]35f(5/2)2[5/2]°3 R1c
3637.867(3)27480.800(21)3637.8663(4)0.00126 5p(5/2)2[5/2]°36d(3/2)2[3/2]2 R1c
3641.0912(20)27456.470(15)3641.0918(5)−0.000752 sp(3F)3326d(5/2)2[5/2]3 R1c
3641.7928(11)27451.180(8)3641.7903(4)0.00251000 s21G45p(3/2)2[5/2]°3 R1c
3642.4505(14)27446.224(11)3642.4488(4)0.001777 4d(3/2)2[5/2]25f(5/2)2[5/2]°3 R1c
3642.8238(22)27443.411(17)3642.8229(4)0.000926 4d(3/2)2[5/2]35f(5/2)2[3/2]°2 R1c
3643.0146(11)27441.974(8)3643.0150(5)−0.0004770 5p(5/2)2[3/2]°16d(3/2)2[1/2]1 R1c
3643.7566(10)27436.386(7)3643.7571(5)−0.00051300 5p(5/2)2[5/2]°36d(3/2)2[7/2]4 R1c
3647.081(4)27411.38(3)3647.0800(10)0.001160 sp(3F)3146d(5/2)2[9/2]5 R1c
3648.2463(20)27402.622(15)3648.2475(5)−0.001152 5p(5/2)2[5/2]°36d(3/2)2[7/2]3 R1c
3648.8875(15)27397.807(11)3648.8850(4)0.0025390 5s(5/2)2[5/2]2sp(3F)133 R1c
3649.2205(22)27395.307(17)3649.2180(4)0.002552 4d(3/2)2[5/2]25f(5/2)2[3/2]°2 R1c
3651.800(3)27375.960(21)3651.7990(5)0.001100 sp(3F)3326d(5/2)2[3/2]2 R1c
3664.2913(10)27282.636(8)3664.2900(5)0.0014130 5s(3/2)2[3/2]2sp(3P)312 R1c
3678.6688(20)27176.009(15)3678.6702(6)−0.001480 sp(3F)3326d(5/2)2[1/2]1 R1c
3682.4238(14)27148.298(11)3682.4254(7)−0.00163900 sp(3F)3347s(5/2)2[5/2]3 R1c
3686.5552(10)27117.875(8)3686.5539(4)0.001316000 4p33s21G49.7e+05C+R1cO07
3693.3279(12)27068.148(9)3693.3271(10)0.000981 4d(3/2)2[1/2]07p(3/2)2[1/2]°1 R2nc
3703.9305(11)26990.667(8)3703.9285(5)0.0020680 sp(3F)3136d(3/2)2[7/2]4 R1c
3724.1764(11)26843.940(8)3724.1770(3)−0.0006390 5p(5/2)2[3/2]°27s(3/2)2[3/2]2 R1c
3725.4537(17)26834.737(12)3725.4544(4)−0.0007110 4p34s21G4 R1c
3728.6574(10)26811.681(7)3728.6569(4)0.0005280 sp(3F)3317s(5/2)2[5/2]2 R1c
3730.3433(10)26799.564(7)3730.3437(5)−0.0005250 5s(5/2)2[5/2]2sp(3P)331 R1c
3731.1462(13)26793.797(9)3731.1479(3)−0.0018170 5p(5/2)2[3/2]°27s(3/2)2[3/2]1 R1c
3738.6488(10)26740.029(7)3738.6478(3)0.00101700 sp(3F)3337s(5/2)2[5/2]2 R1c
3740.3281(11)26728.024(8)3740.3278(4)0.0003280 5s(5/2)2[5/2]3sp(3F)134 R1c
3742.0597(10)26715.656(7)3742.0592(4)0.0006430 5s(3/2)2[3/2]1sp(3F)132 R1c
3748.1909(10)26671.956(7)3748.1901(3)0.00081800 sp(3F)3337s(5/2)2[5/2]3 R1c
3749.782(10)26660.64(7)3749.7756(4)0.006400*5s(5/2)2[5/2]3sp(3P)332 R1c
3749.782(10)26660.64(7)3749.7826(5)−0.001400*sp(3F)3126d(3/2)2[5/2]2 R1c
3751.3859(10)26649.241(7)3751.3858(4)0.0001310 sp(3F)3126d(3/2)2[5/2]3 R1c
3761.4270(14)26578.103(10)3761.4269(5)0.0001150 sp(3F)3126d(3/2)2[3/2]2 R1c
3766.8662(14)26539.726(10)3766.8669(5)−0.0007230 sp(3F)3126d(3/2)2[3/2]1 R1c
3772.5256(10)26499.913(7)3772.5262(5)−0.0006480 sp(3F)3126d(3/2)2[7/2]3 R1c
3774.9743(20)26482.724(14)3774.9751(4)−0.000859 5p(5/2)2[3/2]°26d(5/2)2[5/2]2 R1c
3777.6444(10)26464.006(7)3777.6455(3)−0.0011150 5p(5/2)2[3/2]°26d(5/2)2[7/2]3 R1c
3781.9355(12)26433.980(9)3781.9350(4)0.0005290 5s(3/2)2[3/2]2sp(3F)132 R1c
3786.2696(10)26403.721(7)3786.2702(5)−0.00063200 5p(5/2)2[3/2]°26d(5/2)2[5/2]3 R1c
3795.4413(11)26339.919(8)3795.4419(4)−0.0006450 5s(5/2)2[5/2]2sp(3P)332 R1c
3796.0675(12)26335.574(8)3796.0687(4)−0.0012580 5p(5/2)2[3/2]°26d(5/2)2[3/2]1 R1c
3796.1694(12)26334.867(9)3796.1694(11)−0.0000820 5p(3/2)2[1/2]°16d(3/2)2[1/2]0 R1c
3797.8489(10)26323.221(7)3797.8496(5)−0.00074200 5p(5/2)2[3/2]°26d(5/2)2[3/2]2 R1c
3801.5563(10)26297.551(7)3801.5556(5)0.0007670 5p(3/2)2[1/2]°06d(3/2)2[3/2]1 R1c
3806.27(5)26265.0(3)3806.333(3)−0.067400 d101S04s1D21.58e+00C+T53,M97,P84P84X,E2
3818.8787(11)26178.268(7)3818.8793(8)−0.00062000 5p(5/2)2[3/2]°16d(5/2)2[1/2]0 R1c
3824.8323(11)26137.521(8)3824.8321(6)0.00021000 5p(3/2)2[1/2]°06d(3/2)2[1/2]1 R1c
3826.9209(10)26123.256(7)3826.9216(6)−0.00073000 5p(5/2)2[3/2]°26d(5/2)2[1/2]1 R1c
3836.1646(11)26060.310(7)3836.1655(3)−0.00101800 5p(5/2)2[5/2]°27s(3/2)2[3/2]2 R1c
3841.4818(11)26024.240(7)3841.4819(4)−0.0001590 5s(5/2)2[5/2]2sp(3P)331 R1c
3842.5889(12)26016.742(8)3842.5882(3)0.00072000 5p(5/2)2[3/2]°17s(3/2)2[3/2]2 R1c
3843.5628(13)26010.150(9)3843.5624(3)0.0004150 5p(5/2)2[5/2]°27s(3/2)2[3/2]1 R1c
3849.5824(13)25969.479(9)3849.5810(5)0.00141700 5s(5/2)2[5/2]3sp(3P)333 R1c
3850.0092(15)25966.600(10)3850.0099(3)−0.00071600 5p(5/2)2[3/2]°17s(3/2)2[3/2]1 R1c
3851.1050(11)25959.212(7)3851.1020(4)0.0030890 s21G4sp(3F)313 R1c
3859.41(6)25903.4(4)3859.4330(7)−0.02180 4d(5/2)2[3/2]26p(3/2)2[3/2]°2 S36c
3861.3421(11)25890.391(8)3861.3424(4)−0.00041300 5p(5/2)2[7/2]°36d(5/2)2[5/2]2 R1c
3862.1245(11)25885.146(8)3862.1243(4)0.00021200 5p(3/2)2[5/2]°26d(3/2)2[5/2]3 R1c
3863.6403(11)25874.991(8)3863.6404(4)−0.00011200 5p(5/2)2[7/2]°36d(5/2)2[7/2]4 R1c
3864.1370(11)25871.665(7)3864.1365(4)0.00053200 5p(5/2)2[7/2]°36d(5/2)2[7/2]3 R1c
3866.3047(11)25857.160(7)3866.3035(3)0.00131200 5p(5/2)2[5/2]°37s(3/2)2[3/2]2 R1c
3868.3711(11)25843.348(7)3868.3707(3)0.00041100 sp(3F)3327s(5/2)2[5/2]2 R1c
3871.334(3)25823.570(21)3871.3321(10)0.002210 sp(3F)3147s(5/2)2[5/2]3 R1c
3872.7645(15)25814.031(10)3872.7678(5)−0.0033550 5p(3/2)2[5/2]°26d(3/2)2[3/2]2 R1c
3873.2075(11)25811.078(7)3873.2058(6)0.0017940 5s(5/2)2[5/2]3sp(3P)332 R1c
3878.5873(12)25775.278(8)3878.5875(3)−0.0002860 sp(3F)3327s(5/2)2[5/2]3 R1c
3878.66725774.753878.6670(5) :5p(3/2)2[1/2]°16d(3/2)2[5/2]2
3879.3966(11)25769.901(7)3879.3976(4)−0.00103800 5p(5/2)2[7/2]°46d(5/2)2[7/2]4 R1c
3879.8973(21)25766.576(14)3879.8977(4)−0.0005140 5p(5/2)2[7/2]°46d(5/2)2[7/2]3 R1c
3884.1312(9)25738.489(6)3884.1313(5)−0.00018100 5p(5/2)2[7/2]°36d(5/2)2[9/2]43.1e+07D+F_ReTW
3884.5339(11)25735.821(7)3884.5350(5)−0.00103800 5p(3/2)2[5/2]°26d(3/2)2[7/2]33.1e+07D+R1cTW
3885.2865(17)25730.836(11)3885.2789(5)0.007685bl5p(5/2)2[7/2]°36d(5/2)2[3/2]2 R1c X
3890.0864(14)25699.088(9)3890.0865(4)−0.00012200 5p(5/2)2[5/2]°26d(5/2)2[5/2]2 R1c
3891.1277(12)25692.211(8)3891.1267(5)0.00101500 5p(3/2)2[1/2]°16d(3/2)2[3/2]2 R1c
3892.9237(11)25680.358(7)3892.9223(4)0.00143000 5p(5/2)2[5/2]°26d(5/2)2[7/2]3 R1c
3894.6198(21)25669.175(14)3894.61915(19)0.0006280 5s(3/2)2[3/2]24f(5/2)2[5/2]°3 R1c
3896.6915(11)25655.527(7)3896.6912(4)0.00031900 5p(5/2)2[3/2]°16d(5/2)2[5/2]2 R1c
3896.9491(20)25653.832(13)3896.9487(5)0.0004280 5p(3/2)2[1/2]°16d(3/2)2[3/2]1 R1c
3897.7292(20)25648.698(13)3897.7262(5)0.00302500 5s(5/2)2[5/2]2sp(3P)333 R1c
3900.0557(11)25633.397(7)3900.0565(5)−0.00081100 5p(5/2)2[7/2]°46d(5/2)2[9/2]4 R1c
3901.2315(12)25625.672(8)3901.2316(5)−0.0000280 5p(3/2)2[5/2]°36d(3/2)2[5/2]2 R1c
3902.0837(24)25620.076(16)3902.0821(5)0.0016140 5p(5/2)2[5/2]°26d(5/2)2[5/2]3 R1c
3902.9667(12)25614.280(8)3902.9668(4)−0.00022500 5p(3/2)2[5/2]°36d(3/2)2[5/2]3 R1c
3903.1761(7)25612.905(5)3903.1759(5)0.00028200 5p(5/2)2[7/2]°46d(5/2)2[9/2]53.5e+07D+F_ReTW
3905.1121(14)25600.208(9)3905.1133(6)−0.0012830 4d(3/2)2[1/2]05f(3/2)2[3/2]°1 R1c
3907.2743(24)25586.042(16)3907.2616(8)0.012782?5s(3/2)2[3/2]2sp(3P)352 R1c X
3912.4911(12)25551.927(8)3912.4900(5)0.0011690 5p(5/2)2[5/2]°26d(5/2)2[3/2]1 R1c
3913.8355(14)25543.150(9)3913.8369(5)−0.0014160 5p(3/2)2[5/2]°36d(3/2)2[3/2]2 R1c
3914.311(3)25540.050(21)3914.3081(9)0.002110bl4d(5/2)2[9/2]46p(3/2)2[5/2]°3 R1c
3918.3817(12)25513.515(8)3918.3792(4)0.0025400 s21G45p(5/2)2[5/2]°3 R1c
3919.1725(11)25508.366(7)3919.1710(4)0.00161000 5p(5/2)2[3/2]°16d(5/2)2[3/2]1 R1c
3920.6546(11)25498.724(7)3920.6561(5)−0.00154000 5p(3/2)2[5/2]°36d(3/2)2[7/2]43.3e+07D+R1cTW
3921.071(10)25496.02(7)3921.0693(5)0.002130*5p(5/2)2[3/2]°16d(5/2)2[3/2]2 R1c
3921.071(10)25496.02(7)3921.0811(4)−0.010130*5p(5/2)2[5/2]°36d(5/2)2[5/2]2 R1c
3921.4136(15)25493.789(10)3921.4117(6)0.0019450 5p(3/2)2[1/2]°16d(3/2)2[1/2]1 R1c
3923.4504(11)25480.555(7)3923.4506(5)−0.00032100 5p(5/2)2[5/2]°36d(5/2)2[7/2]4 R1c
3923.9630(12)25477.226(8)3923.9622(4)0.0008400 5p(5/2)2[5/2]°36d(5/2)2[7/2]3 R1c
3925.8560(11)25464.942(7)3925.8554(5)0.0006390 5p(3/2)2[5/2]°36d(3/2)2[7/2]3 R1c
3933.2684(11)25416.953(7)3933.2688(5)−0.00042000 5p(5/2)2[5/2]°36d(5/2)2[5/2]3 R1c
3934.1202(11)25411.450(7)3934.1175(3)0.0027470 sp(3F)3137s(3/2)2[3/2]2 R1c
3935.9626(14)25399.555(9)3935.9560(6)0.0067380bl5s(3/2)2[3/2]1sp(3P)330 R1c X
3940.9702(12)25367.282(8)3940.9707(5)−0.0004300 5s(3/2)2[3/2]2sp(3F)133 R1c
3944.5822(12)25344.054(8)3944.5826(5)−0.0004490 5p(5/2)2[5/2]°36d(5/2)2[9/2]4 R1c
3945.5770(12)25337.664(8)3945.5767(5)0.00042300 5p(3/2)2[3/2]°16d(3/2)2[5/2]2 R1c
3945.7664(13)25336.448(9)3945.7662(5)0.00021500 5p(5/2)2[5/2]°36d(5/2)2[3/2]2 R1c
3952.0661(11)25296.062(7)3952.0660(6)0.0001980 5p(5/2)2[3/2]°16d(5/2)2[1/2]1 R1c
3958.4734(13)25255.118(8)3958.4707(5)0.0027840 5p(3/2)2[3/2]°16d(3/2)2[3/2]2 R1c
3974.3504(22)25154.229(14)3974.3528(7)−0.002491 4d(5/2)2[5/2]26p(3/2)2[3/2]°2 R1c
3975.5387(13)25146.711(8)3975.5380(9)0.000790 4d(3/2)2[1/2]07p(5/2)2[3/2]°1 R1c
3985.2145(11)25085.657(7)3985.2136(5)0.0009700 5p(3/2)2[3/2]°26d(3/2)2[5/2]2 R1c
3987.0237(11)25074.274(7)3987.0244(5)−0.00072300 5p(3/2)2[3/2]°26d(3/2)2[5/2]3 R1c
3990.7807(13)25050.670(8)3990.7773(5)0.0033960 5s(3/2)2[3/2]1sp(3P)331 R1c
3993.3023(12)25034.852(8)3993.3022(5)0.00012600 sp(3F)3136d(5/2)2[7/2]4 R1c
3998.3675(12)25003.138(8)3998.3684(5)−0.0009860 5p(3/2)2[3/2]°26d(3/2)2[3/2]2 R1c
4003.4759(12)24971.235(8)4003.4736(5)0.00231600 sp(3F)3136d(5/2)2[5/2]3 R1c
4004.5155(14)24964.752(9)4004.5160(6)−0.0004400 5p(3/2)2[3/2]°26d(3/2)2[3/2]1 R1c
4006.1651(12)24954.473(7)4006.1666(3)−0.00151500 sp(3F)3127s(3/2)2[3/2]2 R1c
4014.2360(12)24904.301(7)4014.2342(4)0.0018870 sp(3F)3127s(3/2)2[3/2]1 R1c
4015.1963(12)24898.345(8)4015.1954(5)0.0009860 sp(3F)3136d(5/2)2[9/2]4 R1c
4016.4254(14)24890.726(9)4016.4218(6)0.00361500 sp(3F)3136d(5/2)2[3/2]2 R1c
4030.3508(21)24804.727(13)4030.3525(7)−0.0018330 5p(3/2)2[3/2]°26d(3/2)2[1/2]1 R1c
4032.6469(12)24790.604(7)4032.6470(3)−0.00011500 5p(5/2)2[3/2]°27s(5/2)2[5/2]2 R1c
4042.549(3)24729.880(21)4042.5473(7)0.00267 4d(5/2)2[1/2]16p(5/2)2[3/2]°1 R1c
4043.4879(9)24724.139(6)4043.4858(5)0.002127000 4p13s21G41.14e+06C+F_ReO07
4043.7515(4)24722.527(3)4043.75122(21)0.000317000 5p(5/2)2[3/2]°27s(5/2)2[5/2]3 F_Re
4053.6529(21)24662.142(13)4053.6521(4)0.00083100 5p(3/2)2[1/2]°07s(3/2)2[3/2]1 R1c
4065.0094(12)24593.244(7)4065.0090(4)0.00041600 sp(3F)3126d(5/2)2[5/2]2 R1c
4065.3723(22)24591.049(13)4065.3730(5)−0.0007230 5s(3/2)2[3/2]1sp(3P)332 R1c
4068.1058(12)24574.526(7)4068.1056(4)0.00012000 sp(3F)3126d(5/2)2[7/2]3 R1c
4089.4787(13)24446.094(8)4089.4788(5)−0.0001480 sp(3F)3126d(5/2)2[3/2]1 R1c
4112.4816(13)24309.359(8)4112.4801(5)0.0015820 5s(3/2)2[3/2]2sp(3P)332 R1c
4118.2403(24)24275.367(14)4118.2398(5)0.000557 5s(3/2)2[3/2]1sp(3P)331 R1c
4125.171(4)24234.580(21)4125.1717(8)−0.00011 4d(5/2)2[1/2]16p(5/2)2[3/2]°2 R1c
4125.9352(17)24230.094(10)4125.9352(9)0.000165 5p(3/2)2[1/2]°16d(5/2)2[1/2]0 R1c
4131.3610(4)24198.2729(25)4131.3610(3)0.000016000 5p(5/2)2[7/2]°37s(5/2)2[5/2]2 F_Re
4132.7116(21)24190.365(12)4132.7109(3)0.00071000 5p(3/2)2[5/2]°27s(3/2)2[3/2]2 R1c
4141.2965(5)24140.219(3)4141.2968(4)−0.00039700 5p(3/2)2[5/2]°27s(3/2)2[3/2]1 F_Re
4143.0170(13)24130.195(7)4143.01624(20)0.00072100 5p(5/2)2[7/2]°37s(5/2)2[5/2]3 R1c
4147.8136(20)24102.291(11)4147.8131(6)0.0004190 4d(5/2)2[3/2]26p(5/2)2[5/2]°3 R1c
4151.904(3)24078.544(15)4151.9059(6)−0.00247 4d(5/2)2[9/2]46p(5/2)2[5/2]°3 R1c
4153.6234(13)24068.579(7)4153.6236(3)−0.00033600 5p(3/2)2[1/2]°17s(3/2)2[3/2]2 R1c
4154.642(4)24062.680(21)4154.642(4)−0.0009 s23P2sp(3F)352 R1c
4161.13984(15)24025.1034(9)4161.13989(14)−0.0000517000 5p(5/2)2[7/2]°47s(5/2)2[5/2]3 F_Re
4162.2967(14)24018.426(8)4162.2967(4)0.00003000 5p(3/2)2[1/2]°17s(3/2)2[3/2]1 R1c
4164.2826(10)24006.972(6)4164.2827(3)−0.00018700 5p(5/2)2[5/2]°27s(5/2)2[5/2]2 F_Re
4165.67(15)23999.0(9)4165.775(3)−0.103 d101S04s3D12.1e−12C+M97TWX,M1
4166.5884(23)23993.687(13)4166.5874(5)0.0010350 5s(3/2)2[3/2]2sp(3P)331 R1c
4171.8513(5)23963.419(3)4171.8521(3)−0.000710000 5p(5/2)2[3/2]°17s(5/2)2[5/2]2 F_Re
4176.1248(12)23938.897(7)4176.1247(3)0.00011400 5p(5/2)2[5/2]°27s(5/2)2[5/2]3 R1c
4179.5117(4)23919.4987(21)4179.5113(3)0.000312000 5p(3/2)2[5/2]°37s(3/2)2[3/2]2 F_Re
4185.149(4)23887.280(21)4185.1555(11)−0.0068 s21D2sp(3F)353 R1c
4195.3590(16)23829.148(9)4195.3583(5)0.0007210 5p(3/2)2[5/2]°26d(5/2)2[5/2]2 R1c
4195.7735(13)23826.794(8)4195.7740(7)−0.0005340 4d(5/2)2[9/2]56p(5/2)2[7/2]°4 R1c
4198.6561(13)23810.436(8)4198.6568(4)−0.0007240 5p(3/2)2[5/2]°26d(5/2)2[7/2]3 R1c
4199.435(4)23806.020(21)4199.4464(9)−0.011110 4d(3/2)2[3/2]16p(3/2)2[3/2]°1 R1c
4201.735(3)23792.990(17)4201.7309(10)0.00415 5p(3/2)2[3/2]°16d(5/2)2[1/2]0 R1c
4201.888(4)23792.120(21)4201.8877(16)0.00122 sp(3P)3538d(5/2)2[9/2]4 R1c
4207.672(3)23759.417(16)4207.5870(9)0.08515?sp(3F)3345d(3/2)2[5/2]3 R1c X
4209.321(4)23750.110(21)4209.3213(10)−0.00029 4d(3/2)2[1/2]16p(3/2)2[1/2]°1 R1c
4211.8649(8)23735.766(5)4211.86561(23)−0.000711000 5p(5/2)2[5/2]°37s(5/2)2[5/2]3 F_Re
4212.315(3)23733.232(16)4212.3160(7)−0.00114 4d(5/2)2[9/2]46p(5/2)2[7/2]°4 R1c
4216.9124(13)23707.356(7)4216.9115(5)0.0008640 5p(3/2)2[1/2]°16d(5/2)2[5/2]2 R1c
4219.38(20)23693.5(11)4219.5840(6)−0.20340 4d(5/2)2[3/2]2sp(1G)333 S36c
4221.427(2)23682.000(14)4221.4276(5)−0.00069 5p(3/2)2[5/2]°26d(5/2)2[3/2]1 R1c
4223.8195(14)23668.588(8)4223.8197(6)−0.0002100 4d(5/2)2[9/2]4sp(1G)333 R1c
4224.344(4)23665.650(21)4224.3455(3)−0.00214 4d(5/2)2[1/2]14f(3/2)2[5/2]°2 R1c
4225.1956(14)23660.880(8)4225.1967(6)−0.0012140 4d(5/2)2[5/2]36p(5/2)2[5/2]°3 R1c
4227.9422(14)23645.509(8)4227.9397(5)0.00257900 4p33s21G45.1e+05BR1cO07
4230.4486(14)23631.500(8)4230.4495(4)−0.00094000 5p(3/2)2[3/2]°17s(3/2)2[3/2]2 R1c
4232.8346(15)23618.180(8)4232.8362(6)−0.0016130 5s(3/2)2[3/2]2sp(3P)333 R1c
4239.4445(20)23581.356(11)4239.4468(4)−0.00237000 5p(3/2)2[3/2]°17s(3/2)2[3/2]1 F_Re
4240.410(3)23575.985(14)4240.4120(8)−0.00264 4d(5/2)2[3/2]16p(5/2)2[3/2]°1 R1c
4241.31(4)23570.97(22)4241.271(3)0.0448*sp(3P)3548d(5/2)2[7/2]4 R1nc
4241.31(4)23570.97(22)4241.3236(9)−0.0148*4d(3/2)2[3/2]26p(3/2)2[3/2]°1 R1c
4243.2516(15)23560.199(8)4243.2501(5)0.0015320 5p(3/2)2[1/2]°16d(5/2)2[3/2]1 R1c
4246.9860(20)23539.483(11)4246.9715(4)0.0145390*5p(3/2)2[5/2]°36d(5/2)2[7/2]3 R1nc X
4246.9860(20)23539.483(11)4246.9847(7)0.0013390*4d(3/2)2[1/2]05f(5/2)2[3/2]°1 R1c
4251.0194(15)23517.149(8)4251.0200(6)−0.0006300 4d(5/2)2[1/2]14f(3/2)2[3/2]°1 R1c
4254.630(4)23497.190(21)4254.6275(11)0.00312 4d(3/2)2[7/2]36p(3/2)2[5/2]°2 R2nc
4255.6348(14)23491.644(8)4255.6343(4)0.00061100 4d(5/2)2[1/2]14f(3/2)2[3/2]°2 R1c
4256.846(4)23484.960(21)4256.8484(7)−0.00230 4d(3/2)2[1/2]05f(5/2)2[1/2]°1 R1c
4267.611(4)23425.720(21)4267.6128(13)−0.002120 s21G4sp(3F)314 R1c
4268.103(4)23423.020(21)4268.1012(12)0.00218 sp(3F)3545d(5/2)2[9/2]5 R1c
4276.0484(9)23379.499(5)4276.0496(4)−0.00128700 5p(3/2)2[3/2]°27s(3/2)2[3/2]2 F_Re
4277.805(4)23369.900(21)4277.8016(6)0.003150 4d(5/2)2[7/2]46p(5/2)2[5/2]°3 R1c
4279.9621(15)23358.120(8)4279.9594(3)0.00285100 sp(3F)3137s(5/2)2[5/2]2 R1c
4280.845(4)23353.300(21)4280.8437(6)0.0026 4d(5/2)2[5/2]26p(5/2)2[5/2]°3 R1c
4281.838(3)23347.889(15)4281.8368(8)0.00129 5p(3/2)2[1/2]°16d(5/2)2[1/2]1 R1c
4285.2433(13)23329.334(7)4285.2420(4)0.00122000 5p(3/2)2[3/2]°27s(3/2)2[3/2]1 R1c
4286.465(3)23322.683(16)4286.4615(7)0.00411 4d(5/2)2[5/2]2sp(3F)132 R1c
4287.13(6)23319.1(3)4287.0450(10)0.08180 4d(3/2)2[7/2]46p(3/2)2[5/2]°3 S36c
4287.779(3)23315.537(17)4287.7744(7)0.00511 4d(5/2)2[5/2]36p(5/2)2[7/2]°4 R1c
4291.084(3)23297.580(16)4291.0824(24)0.002640 5s(5/2)2[5/2]3sp(3P)354 R1c
4292.4705(14)23290.055(8)4292.4694(3)0.00119000 sp(3F)3137s(5/2)2[5/2]3 R1c
4296.123(3)23270.256(14)4296.1187(5)0.00417 5p(3/2)2[3/2]°16d(5/2)2[5/2]2 R1c
4299.696(3)23250.920(16)4299.6946(6)0.00111 4d(5/2)2[5/2]3sp(1G)333 R1c
4308.710(3)23202.274(16)4308.7114(9)−0.00128 4d(3/2)2[5/2]26p(3/2)2[3/2]°1 R1c
4320.7611(19)23137.564(10)4320.7616(7)−0.0005270 4d(5/2)2[1/2]1sp(3P)312 R1c
4335.639(3)23058.167(16)4335.6353(9)0.00417 4d(3/2)2[5/2]36p(3/2)2[3/2]°2 R1c
4341.039(3)23029.484(15)4341.0414(14)−0.00217 5s(5/2)2[5/2]3sp(3P)353 R1c
4343.152(4)23018.280(21)4343.1532(5)−0.00111 5p(3/2)2[3/2]°26d(5/2)2[5/2]2 R1c
4344.700(4)23010.080(21)4344.6972(9)0.0036 4d(3/2)2[5/2]26p(3/2)2[3/2]°2 R1c
4346.687(4)22999.560(21)4346.6883(5)−0.001240 5p(3/2)2[3/2]°26d(5/2)2[7/2]3 R1c
4357.339(4)22943.340(21)4357.3345(6)0.0046 4d(5/2)2[5/2]2sp(1G)333 R1c
4360.102(3)22928.797(14)4360.0973(17)0.00547 5s(5/2)2[5/2]3sp(3P)352 R1c
4365.3705(14)22901.127(7)4365.3697(3)0.00087300 sp(3F)3127s(5/2)2[5/2]2 R1c
4373.460(3)22858.770(15)4373.4591(7)0.00118 5p(3/2)2[3/2]°26d(5/2)2[3/2]2 R1c
4375.8(5)22847(3)4375.690(3)0.12000 d101S04s3D29.e−02D+A73,P84A08adjX,E2
4378.3840(14)22833.061(7)4378.3848(3)−0.00071500 sp(3F)3127s(5/2)2[5/2]3 R1c
4396.423(3)22739.375(15)4396.4196(6)0.00413 4d(5/2)2[9/2]46p(5/2)2[7/2]°3 R1c
4402.363(3)22708.694(16)4402.3616(15)0.00233 5s(5/2)2[5/2]2sp(3P)353 R1c
4410.941(3)22664.535(17)4410.9371(9)0.0047 4d(5/2)2[1/2]06p(5/2)2[3/2]°1 R1c
4419.088(4)22622.750(21)4419.0825(3)0.0067 4d(5/2)2[3/2]24f(3/2)2[7/2]°3 R1c
4422.583(3)22604.871(16)4422.5816(15)0.00215 5s(5/2)2[5/2]2sp(3P)351 R1c
4435.693(3)22538.066(15)4435.6906(4)0.00280 4d(5/2)2[3/2]24f(3/2)2[5/2]°2 R1c
4440.8836(15)22511.721(8)4440.8827(4)0.0009520 4d(5/2)2[3/2]14f(3/2)2[5/2]°2 R1c
4441.709(14)22507.54(7)4441.7193(7)−0.011180 sp(3F)3335d(3/2)2[7/2]4 R1c
4444.8314(14)22491.727(7)4444.8307(3)0.00071200 4d(5/2)2[3/2]24f(3/2)2[5/2]°3 R1c
4462.6902(16)22401.721(8)4462.6875(5)0.00271600 4d(5/2)2[9/2]44f(3/2)2[9/2]°5 R1c
4485.28022288.904485.2800(6) :4d(5/2)2[1/2]1sp(3F)132 W93
4495.356(3)22238.942(15)4495.3577(8)−0.00238 sp(3F)3335d(3/2)2[7/2]4 R1c
4505.9982(8)22186.418(4)4505.9996(4)−0.001311000 4p32s23P16.3e+05CF_ReH71,N88L
4515.5194(15)22139.637(7)4515.5195(3)−0.0001960 4d(5/2)2[5/2]34f(3/2)2[7/2]°4 R1c
4516.0492(15)22137.040(7)4516.0499(4)−0.00072700 5p(3/2)2[5/2]°27s(5/2)2[5/2]2 R1c
4529.983(3)22068.951(15)4529.9803(3)0.00270 5p(3/2)2[5/2]°27s(5/2)2[5/2]3 R1c
4533.814(4)22050.300(21)4533.8122(3)0.00254 4d(5/2)2[5/2]34f(3/2)2[5/2]°3 R1c
4541.0325(15)22015.251(7)4541.0337(4)−0.00136900 5p(3/2)2[1/2]°17s(5/2)2[5/2]2 R1c
4542.15(4)22009.82(19)4542.1167(8)0.04390*4d(5/2)2[3/2]2sp(3P)312 R1c
4542.15(4)22009.82(19)4542.1719(10)−0.02390*4d(3/2)2[1/2]16p(5/2)2[3/2]°1 R1c
4546.433(3)21989.099(12)4546.4353(6)−0.002410 sp(3F)3325d(3/2)2[5/2]3 R1c
4551.807(3)21963.141(13)4551.8069(8)−0.000260 4d(3/2)2[7/2]3sp(3F)132 R1c
4555.9211(5)21943.307(3)4555.9193(4)0.001818000 4p32s23P27.1e+05CF_ReH71,N88L
4557.5077(15)21935.668(7)4557.5079(4)−0.00021100 4d(5/2)2[7/2]34f(3/2)2[7/2]°3 R1c
4558.7(5)21929.9(24)4558.949(4)−0.23000 d101S04s3D3 A73 X,HF
4575.180(7)21850.94(3)4575.1748(4)0.005550*4d(5/2)2[7/2]34f(3/2)2[5/2]°2 R1c
4575.185(3) msp(3P)33210s(5/2)2[5/2]2 R1c
4575.180(7)21850.94(3)4575.1871(7)−0.007550*sp(3F)3325d(3/2)2[3/2]2 R1c
4575.6529(15)21848.681(7)4575.6532(3)−0.0003850 4d(5/2)2[7/2]44f(3/2)2[7/2]°4 R1c
4584.899(3)21804.623(12)4584.8994(3)−0.00160 4d(5/2)2[7/2]34f(3/2)2[5/2]°3 R1c
4586.274(3)21798.084(13)4586.2719(3)0.002300 5p(3/2)2[5/2]°37s(5/2)2[5/2]3 R1c
4588.1661(15)21789.095(7)4588.1667(4)−0.0006620 4d(5/2)2[5/2]24f(3/2)2[5/2]°2 R1c
4589.601(3)21782.285(12)4589.6035(8)−0.003220 4d(3/2)2[3/2]1sp(3F)132 R1c
4594.330(3)21759.863(13)4594.3638(14)−0.034200?sp(3F)3536s(3/2)2[3/2]2 R1c X
4594.436(3)21759.358(15)4594.4374(3)−0.001130 4d(5/2)2[7/2]44f(3/2)2[5/2]°3 R1c
4596.9056(15)21747.671(7)4596.9063(5)−0.00074800 4d(5/2)2[7/2]34f(3/2)2[9/2]°4 R1c
4597.9473(15)21742.744(7)4597.9466(3)0.00073200 4d(5/2)2[5/2]24f(3/2)2[5/2]°3 R1c
4606.5041(21)21702.356(10)4606.4944(5)0.0097730bl4d(5/2)2[7/2]44f(3/2)2[9/2]°4 R1c X
4608.4661(16)21693.117(7)4608.4662(5)−0.00013100 4d(5/2)2[7/2]44f(3/2)2[9/2]°5 R1c
4609.416(3)21688.646(14)4609.3996(6)0.016560 sp(3F)3325d(3/2)2[7/2]3 R1c X
4619.659(3)21640.559(15)4619.6507(6)0.00882 4d(5/2)2[5/2]24f(3/2)2[3/2]°1 R1c
4625.097(3)21615.114(13)4625.1004(5)−0.0032100 4d(5/2)2[5/2]24f(3/2)2[3/2]°2 R1c
4631.801(3)21583.829(16)4631.8076(7)−0.00790 4d(3/2)2[7/2]3sp(1G)333 R1c
4635.260(3)21567.722(12)4635.2599(16)0.000230 4d(5/2)2[7/2]4sp(1G)334 R1c
4639.5854(16)21547.616(8)4639.5835(9)0.00191100 4d(5/2)2[3/2]1sp(1G)332 R1nc
4647.012(5)21513.180(21)4647.0121(12)−0.000950 4d(5/2)2[9/2]5sp(1G)335 R1c
4649.2705(16)21502.730(7)4649.27084(23)−0.00036700 4d(5/2)2[1/2]14f(5/2)2[5/2]°2 R1c
4660.3044(17)21451.820(8)4660.3070(7)−0.00265600 4d(5/2)2[1/2]04f(3/2)2[3/2]°1 R1c
4661.3627(16)21446.950(7)4661.3620(3)0.00077100 4d(5/2)2[1/2]14f(5/2)2[3/2]°1 R1c
4662.654(3)21441.010(12)4662.6475(11)0.00713000 4d(5/2)2[1/2]1sp(3P)352 R1c
4667.315(2)21419.599(11)4667.3119(12)0.00311000 4d(5/2)2[9/2]4sp(1G)335 R1c
4671.7016(2)21399.4867(11)4671.70176(20)−0.000229000 4d(5/2)2[1/2]14f(5/2)2[3/2]°25.6e+07D+F_ReTW
4673.5772(5)21390.8989(25)4673.5774(5)−0.000220000 4d(5/2)2[1/2]14f(5/2)2[1/2]°01.6e+08D+F_ReTWL
4681.9938(5)21352.4459(22)4681.9935(3)0.000336000 4d(5/2)2[1/2]14f(5/2)2[1/2]°11.1e+08D+F_ReTWL
4687.7662(18)21326.153(8)4687.7648(4)0.00143000 5p(3/2)2[3/2]°27s(5/2)2[5/2]2 R1c
4702.125(3)21261.032(13)4702.1291(9)−0.004550 4d(5/2)2[5/2]2sp(3P)312 R1c
4737.909(4)21100.456(16)4737.9023(11)0.006170 4d(3/2)2[3/2]16p(5/2)2[5/2]°2 R1c
4744.588(3)21070.751(11)4744.5892(8)−0.001520 sp(3F)3315d(3/2)2[5/2]2 R1c
4753.4684(16)21031.389(7)4753.4691(7)−0.00072100 4d(5/2)2[9/2]4sp(1G)334 R1c
4758.4334(9)21009.445(4)4758.4334(7)0.000015000 4p31s23P01.3e+06CF_ReH71,N88
4765.913(3)20976.472(14)4765.9115(6)0.00262 sp(3F)3335d(3/2)2[5/2]3 R1c
4766.7392(16)20972.837(7)4766.7394(9)−0.00024500 4d(5/2)2[1/2]1sp(3P)330 R1c
4772.9651(17)20945.481(7)4772.9656(5)−0.0005590 4d(3/2)2[1/2]14f(3/2)2[5/2]°2 R1c
4781.0855(17)20909.907(8)4781.0769(8)0.0086670 sp(3F)3315d(3/2)2[3/2]2 R1c X
4792.709(3)20859.194(14)4792.7117(21)−0.002430 5s(3/2)2[3/2]1sp(3P)352 R1c
4797.306(3)20839.208(14)4797.3080(18)−0.002150 5s(5/2)2[5/2]3sp(1D)332 R1c
4800.112(3)20827.027(11)4800.1106(8)0.001590 sp(3F)3315d(3/2)2[3/2]1 R1c
4800.584(3)20824.980(14)4800.5808(9)0.003370 4d(5/2)2[5/2]2sp(1G)332 R1nc
4805.6557(19)20803.001(8)4805.6527(6)0.00303600 4d(5/2)2[3/2]2sp(3F)133 R1c
4807.0463(17)20796.983(7)4807.0463(8)0.00007000 4d(3/2)2[1/2]14f(3/2)2[3/2]°1 R1c
4811.1487(21)20779.250(9)4811.1475(6)0.00121000 4d(5/2)2[9/2]4sp(3F)133 R1c
4812.9476(5)20771.4831(22)4812.9474(4)0.000336000 4d(3/2)2[1/2]14f(3/2)2[3/2]°21.3e+08D+F_ReTW
4814.868(4)20763.199(16)4814.868(4)0.000310 5s(5/2)2[5/2]3sp(1D)334 R1c
4820.269(3)20739.934(15)4820.2672(6)0.002160 sp(3F)3335d(3/2)2[7/2]4 R1c
4829.3349(17)20701.001(7)4829.3340(3)0.00091100 4d(5/2)2[9/2]54f(5/2)2[9/2]°4 R1c
4832.2454(17)20688.533(7)4832.2439(5)0.001414000 4p31s23P12.5e+05CR1cH71,N88
4833.761(3)20682.046(12)4833.7603(9)0.0011000 4d(3/2)2[1/2]1sp(3F)131 R1c
4834.673(3)20678.146(12)4834.6703(18)0.002440 5s(3/2)2[3/2]2sp(3P)353 R1c
4836.799(2)20669.054(11)4836.7982(8)0.001790 sp(3F)3335d(5/2)2[7/2]4 R1c
4837.434(3)20666.341(15)4837.4350(20)−0.001360 4d(5/2)2[1/2]0sp(3P)311 R2nc
4840.1833(17)20654.604(7)4840.1829(8)0.00051100 4d(3/2)2[7/2]36p(5/2)2[7/2]°3 R1c
4841.832(3)20647.573(15)4841.8320(24)−0.00091?4f(5/2)2[9/2]°58g(5/2)2[11/2]6 R2nc
4847.3822(17)20623.930(7)4847.3823(8)−0.00001500 4d(5/2)2[1/2]1sp(3P)331 R1c
4851.2625(11)20607.434(5)4851.2617(4)0.000812000 4d(5/2)2[9/2]44f(5/2)2[9/2]°42.9e+07D+F_ReTW
4854.98733(18)20591.6237(7)4854.98743(17)−0.0001134000 4d(5/2)2[9/2]54f(5/2)2[9/2]°53.5e+07D+F_ReTWL
4859.068(7)20574.33(3)4859.0673(19)0.00197 5s(3/2)2[3/2]2sp(3P)351 R1c
4861.5612(18)20563.780(8)4861.56049(20)0.00083600 4d(5/2)2[9/2]54f(5/2)2[7/2]°4 R1c
4866.254(3)20543.951(12)4866.2550(8)−0.001700 sp(3F)3335d(5/2)2[5/2]3 R1c
4873.3056(17)20514.223(7)4873.3035(5)0.00219900 4d(3/2)2[7/2]34f(3/2)2[7/2]°32.4e+07D+F_ReTW
4877.151(3)20498.050(13)4877.1492(3)0.002100 4d(5/2)2[9/2]44f(5/2)2[9/2]°5 R1c
4883.2352(17)20472.510(7)4883.2351(4)0.00012900 4d(3/2)2[7/2]34f(3/2)2[7/2]°4 R1c
4883.7832(17)20470.213(7)4883.7825(3)0.00072900 4d(5/2)2[9/2]44f(5/2)2[7/2]°4 R1c
4889.7005(17)20445.441(7)4889.6998(5)0.000812000 4p31s23P21.9e+05CR1cH71,N88
4893.506(3)20429.543(11)4893.5089(5)−0.003770 4d(3/2)2[7/2]34f(3/2)2[5/2]°2 R1c
4896.414(3)20417.408(14)4896.4163(10)−0.0021900 4d(3/2)2[1/2]1sp(3P)312 R1c
4900.472(3)20400.501(11)4900.4712(9)0.001920 sp(3F)3335d(5/2)2[7/2]4 R1c
4901.42635(21)20396.5291(9)4901.42634(15)0.0000226000 4d(5/2)2[3/2]24f(5/2)2[5/2]°36.2e+07D+F_ReTW
4904.534(4)20383.605(16)4904.5146(21)0.020110?4f(5/2)2[3/2]°19s(3/2)2[3/2]2 R1c X
4905.768(3)20378.478(11)4905.7667(5)0.001580 4d(3/2)2[7/2]44f(3/2)2[7/2]°3 R1c
4906.5663(3)20375.1629(11)4906.56612(16)0.000121000 4d(5/2)2[3/2]24f(5/2)2[5/2]°24.4e+07D+F_ReTW
4907.1427(24)20372.770(10)4907.1424(4)0.00021000 4d(5/2)2[9/2]44f(5/2)2[5/2]°3 R1c
4908.2819(24)20368.041(10)4908.2838(8)−0.0019970 4d(5/2)2[7/2]3sp(1G)334 F_Re
4909.0397(13)20364.897(5)4909.0390(5)0.00076100 4d(5/2)2[9/2]54f(5/2)2[11/2]°5 F_Re
4909.73351(2)20362.01913(10)4909.733510(20)0.00000160000 4d(5/2)2[9/2]54f(5/2)2[11/2]°62.04e+08B+F_ReC84L
4912.3645(5)20351.1138(21)4912.3644(3)0.000117000 4d(5/2)2[3/2]24f(5/2)2[7/2]°3 F_Re
4912.91989(16)20348.8131(7)4912.91987(14)0.0000229000 4d(5/2)2[3/2]14f(5/2)2[5/2]°26.0e+07D+F_ReTW
4915.8321(17)20336.758(7)4915.8312(4)0.000911000 4d(3/2)2[7/2]44f(3/2)2[7/2]°42.5e+07D+F_ReTW
4918.1079(21)20327.348(9)4918.1061(4)0.00192400 4d(5/2)2[9/2]44f(5/2)2[7/2]°3 R1c
4918.3779(5)20326.2320(20)4918.3778(4)0.000054000 4d(3/2)2[7/2]34f(3/2)2[9/2]°42.9e+08CF_ReH71
4920.0348(12)20319.387(5)4920.0345(4)0.00036800 4d(5/2)2[3/2]24f(5/2)2[3/2]°1 F_Re
4921.4627(21)20313.492(9)4921.4666(12)−0.00395900 4d(5/2)2[3/2]2sp(3P)352 F_Re
4926.4228(5)20293.0397(22)4926.4232(3)−0.000426000 4d(5/2)2[3/2]14f(5/2)2[3/2]°19.e+07D+F_ReTW
4926.811(4)20291.440(17)4926.8186(15)−0.007740 sp(3F)3546s(5/2)2[5/2]3 R1c
4927.860(3)20287.121(14)4927.8590(12)0.001830 4d(5/2)2[3/2]1sp(3P)352 R1c
4930.713(3)20275.383(11)4930.7110(8)0.002620 sp(3F)3335d(5/2)2[5/2]3 R1c
4931.55496(20)20271.9213(8)4931.55505(16)−0.0000928000 4d(5/2)2[3/2]24f(5/2)2[3/2]°27.1e+07D+F_ReTW
4931.6982(5)20271.3325(20)4931.6981(4)0.0001140000 4d(5/2)2[9/2]44f(5/2)2[11/2]°51.9e+08CF_ReH71L
4933.0777(24)20265.664(10)4933.0745(5)0.00321100 4d(5/2)2[9/2]5sp(3F)134 R1c
4937.22029(23)20248.6601(9)4937.22031(22)−0.0000226000 4d(3/2)2[3/2]14f(3/2)2[5/2]°21.1e+08D+F_ReTW
4937.516(3)20247.449(11)4937.5188(4)−0.0031100 4d(3/2)2[7/2]44f(3/2)2[5/2]°3 R1c
4937.9740(4)20245.5693(16)4937.97372(21)0.000316000 4d(5/2)2[3/2]14f(5/2)2[3/2]°22.8e+07D+F_ReTW
4939.648(3)20238.709(11)4939.6526(8)−0.0051200 4d(3/2)2[3/2]26p(5/2)2[7/2]°3 R1c
4940.0695(17)20236.982(7)4940.0693(6)0.00024700 4d(5/2)2[3/2]14f(5/2)2[1/2]°0 R1c
4940.912(8)20233.53(3)4940.9093(20)0.003130 5s(5/2)2[5/2]2sp(1D)331 R1c
4943.0240(7)20224.886(3)4943.0250(4)−0.001020000 4d(5/2)2[3/2]24f(5/2)2[1/2]°14.0e+07D+F_ReTW
4949.4750(18)20198.526(7)4949.4735(4)0.00153700 4d(5/2)2[3/2]14f(5/2)2[1/2]°1 R1c
4951.4463(18)20190.484(7)4951.4464(6)−0.00004200 4d(3/2)2[7/2]44f(3/2)2[9/2]°4 F_Re
4951.6184(14)20189.783(6)4951.6201(3)−0.001612000 4d(5/2)2[5/2]34f(5/2)2[9/2]°4 F_Re
4953.7244(5)20181.1995(20)4953.7246(4)−0.000282000 4d(3/2)2[7/2]44f(3/2)2[9/2]°53.1e+08CF_ReH71
4955.9564(18)20172.111(7)4955.9566(5)−0.00026300 4d(5/2)2[9/2]4sp(3F)134 R1c
4969.8062(18)20115.896(7)4969.8046(6)0.00164400 4d(5/2)2[7/2]3sp(3F)1331.1e+07D+R1cTW
4971.222(4)20110.167(15)4971.2261(9)−0.004280 sp(3F)3335d(5/2)2[3/2]2 R1c
4973.136(3)20102.429(12)4973.1394(7)−0.004280 sp(3F)3325d(3/2)2[5/2]2 R1c
4973.6975(19)20100.158(8)4973.6959(8)0.00169000 4d(3/2)2[3/2]14f(3/2)2[3/2]°13.6e+07D+F_ReTW
4974.1542(15)20098.313(6)4974.1533(5)0.00089700 4d(3/2)2[3/2]24f(3/2)2[7/2]°33.0e+07D+F_ReTW
4975.064(3)20094.637(12)4975.0659(8)−0.002560 4d(5/2)2[3/2]2sp(3F)133 R1c
4980.0153(19)20074.659(8)4980.0135(6)0.001811000 4d(3/2)2[3/2]14f(3/2)2[3/2]°2 R1c
4981.0125(23)20070.640(9)4981.0133(6)−0.0008670 4d(5/2)2[7/2]4sp(3F)133 R1c
4985.1421(23)20054.014(9)4985.1381(6)0.00405100 4d(5/2)2[5/2]2sp(3F)1332.1e+07D+R1cTW
4985.50499(7)20052.5541(3)4985.50498(7)0.0000170000 4d(5/2)2[5/2]34f(5/2)2[7/2]°49.7e+07C+F_ReTW
4988.327(4)20041.212(15)4988.326(4)0.000430 5d(5/2)2[9/2]58f(5/2)2[11/2]°65.7e+06D+R1cTW
4995.2054(22)20013.614(9)4995.2055(5)−0.0001800 4d(3/2)2[3/2]24f(3/2)2[5/2]°2 R1c
4999.584(3)19996.088(12)4999.5826(20)0.001440 5d(5/2)2[9/2]48f(5/2)2[11/2]°5 R1c
5002.294(3)19985.255(12)5002.2998(10)−0.006440 4d(3/2)2[3/2]1sp(3F)131 R1c
5006.79983(15)19967.2680(6)5006.79978(15)0.0000546000 4d(3/2)2[3/2]24f(3/2)2[5/2]°31.20e+08C+F_ReTW
5009.8505(3)19955.1095(10)5009.85058(17)−0.000135000 4d(5/2)2[5/2]34f(5/2)2[5/2]°35.4e+07D+F_ReTW
5012.6197(3)19944.0855(12)5012.6199(3)−0.000237000 4d(5/2)2[7/2]34f(5/2)2[9/2]°49.6e+07C+F_ReTWL
5015.2190(8)19933.749(3)5015.22038(21)−0.001411000 4d(5/2)2[5/2]34f(5/2)2[5/2]°2 F_Re
5020.126(3)19914.266(10)5020.1256(5)0.0002000 4p33s23P2 R1c
5021.2785(4)19909.6939(15)5021.27849(23)0.000032000 4d(5/2)2[5/2]34f(5/2)2[7/2]°33.2e+07EF_ReTWL
5022.599(3)19904.459(11)5022.6044(7)−0.005760 sp(3F)3325d(5/2)2[7/2]3 R1c
5024.0251(16)19898.810(6)5024.0227(3)0.00248700 4d(5/2)2[7/2]44f(5/2)2[9/2]°4 F_Re
5030.789(3)19872.057(11)5030.7892(12)−0.0001400 4d(5/2)2[5/2]3sp(3P)352 R1c
5031.299(3)19870.040(10)5031.2968(8)0.0031400 4d(3/2)2[5/2]26p(5/2)2[7/2]°3 R1c
5032.544(3)19865.125(11)5032.5461(8)−0.0021100 4d(3/2)2[3/2]24f(3/2)2[3/2]°1 R1c
5034.171(3)19858.705(13)5034.1729(8)−0.002460 sp(3F)3325d(3/2)2[3/2]1 R1c
5036.7302(21)19848.616(8)5036.7320(7)−0.0019540 4d(5/2)2[1/2]1sp(3P)331 R1c
5039.0109(13)19839.632(5)5039.0141(6)−0.003217000 4d(3/2)2[3/2]24f(3/2)2[3/2]°23.9e+07D+F_ReTW
5041.3310(9)19830.502(4)5041.33123(23)−0.000314000 4d(5/2)2[5/2]34f(5/2)2[3/2]°21.6e+07D+F_ReTW
5042.093(3)19827.505(11)5042.0348(18)0.058310?sp(3F)3145d(3/2)2[7/2]3 R1c X
5044.2776(21)19818.918(8)5044.2768(10)0.0008940 4d(5/2)2[3/2]1sp(3P)330 R1c
5047.34772(23)19806.8629(9)5047.34770(18)0.0000227000 4d(5/2)2[7/2]34f(5/2)2[7/2]°4 F_Re
5051.79210(4)19789.43784(14)5051.79209(4)0.00000120000 4d(5/2)2[7/2]44f(5/2)2[9/2]°51.55e+08C+F_ReTWL
5054.344(3)19779.447(10)5054.3487(6)−0.005950 sp(3F)3325d(3/2)2[7/2]3 R1c
5054.7758(20)19777.757(8)5054.7728(5)0.00301300 4d(3/2)2[5/2]34f(3/2)2[7/2]°3 R1c
5058.90906(16)19761.5981(6)5058.90923(14)−0.0001748000 4d(5/2)2[7/2]44f(5/2)2[7/2]°44.8e+07D+F_ReTW
5059.418(5)19759.611(21)5059.4131(13)0.005160 6s(5/2)2[5/2]26f(3/2)2[5/2]°2 R1c
5060.6437(9)19754.825(4)5060.6415(5)0.002216000 4p30s23P14.1e+05CF_ReH71L
5065.45858(8)19736.0471(3)5065.45861(8)−0.0000270000 4d(3/2)2[5/2]34f(3/2)2[7/2]°41.61e+08C+F_ReTW
5067.09416(17)19729.6767(7)5067.09423(17)−0.0000846000 4d(3/2)2[5/2]24f(3/2)2[7/2]°31.23e+08C+F_ReTW
5069.431(3)19720.584(11)5069.4315(10)−0.0011600 4d(3/2)2[3/2]1sp(3P)312 R1c
5072.3034(6)19709.4147(23)5072.30253(22)0.000832000 4d(5/2)2[7/2]34f(5/2)2[5/2]°3 F_Re
5076.5136(20)19693.069(8)5076.5143(5)−0.0007830 4d(3/2)2[5/2]34f(3/2)2[5/2]°2 R1c
5077.8070(18)19688.053(7)5077.8071(3)−0.00016300 4d(5/2)2[7/2]34f(5/2)2[5/2]°2 R1c
5081.099(4)19675.296(14)5081.1053(16)−0.006330 5s(3/2)2[3/2]1sp(1D)331 R1c
5082.525(4)19669.778(14)5082.5262(15)−0.001160 5p(5/2)2[3/2]°15d(3/2)2[1/2]0 R1c
5083.9795(12)19664.150(5)5083.97879(22)0.000721000 4d(5/2)2[7/2]44f(5/2)2[5/2]°3 F_Re
5084.0173(5)19664.0034(18)5084.0175(3)−0.000214000 4d(5/2)2[7/2]34f(5/2)2[7/2]°3 F_Re,R1r
5088.27603(10)19647.5455(4)5088.27603(9)0.0000057000 4d(5/2)2[5/2]24f(5/2)2[5/2]°3 F_Re
5088.4882(8)19646.726(3)5088.4896(4)−0.001325000 4d(3/2)2[5/2]34f(3/2)2[5/2]°34.8e+07D+F_ReTW
5088.9426(11)19644.972(4)5088.9421(5)0.000519000 4d(3/2)2[5/2]24f(3/2)2[5/2]°25.2e+07D+F_ReTW
5089.492(5)19642.851(21)5089.4972(7)−0.005330 sp(3F)3325d(5/2)2[3/2]1 R1c
5093.81535(17)19626.1799(7)5093.81536(14)−0.0000141000 4d(5/2)2[5/2]24f(5/2)2[5/2]°24.9e+07D+F_ReTW
5094.442(3)19623.766(11)5094.4408(7)0.001330 sp(3F)3325d(5/2)2[3/2]2 R1c
5095.7489(19)19618.733(7)5095.7478(3)0.00113100 4d(5/2)2[7/2]44f(5/2)2[7/2]°3 R1c
5100.0629(10)19602.138(4)5100.0650(3)−0.002112000 4d(5/2)2[5/2]24f(5/2)2[7/2]°3 F_Re
5100.9790(21)19598.618(8)5100.9762(5)0.00289900 4d(3/2)2[5/2]24f(3/2)2[5/2]°31.6e+07D+R1cTW
5103.283(3)19589.770(13)5103.2831(6)−0.000830 4d(3/2)2[5/2]34f(3/2)2[9/2]°4 R1c
5104.573(3)19584.818(11)5104.5755(3)−0.002830 4d(5/2)2[7/2]34f(5/2)2[3/2]°2 R1c
5108.3335(19)19570.402(7)5108.3328(4)0.00077300 4d(5/2)2[5/2]24f(5/2)2[3/2]°1 R1c
5109.825(3)19564.691(13)5109.8270(21)−0.002500 sp(1D)3315g(3/2)2[5/2]2 R1c
5109.880(6)19564.481(21)5109.8767(13)0.003330 4d(5/2)2[5/2]2sp(3P)352 R1c
5110.3417(19)19562.712(7)5110.3409(5)0.00081700 4d(5/2)2[7/2]44f(5/2)2[11/2]°5 R1c
5115.535(3)19542.852(13)5115.5386(11)−0.004170 sp(3F)3315d(5/2)2[1/2]0 R1c
5120.7535(4)19522.9360(15)5120.75319(19)0.000320000 4d(5/2)2[5/2]24f(5/2)2[3/2]°22.0e+07D+F_ReTW
5121.765(3)19519.080(13)5121.7672(7)−0.0021000 4d(3/2)2[5/2]34f(3/2)2[3/2]°2 R1c
5124.4745(7)19508.760(3)5124.4753(5)−0.000730000 4d(5/2)2[7/2]3sp(3F)134 F_Re
5127.682(3)19496.556(13)5127.7027(9)−0.020570 4d(3/2)2[5/2]24f(3/2)2[3/2]°1 R1c X
5127.7428(21)19496.326(8)5127.7327(8)0.0101630?4d(5/2)2[3/2]2sp(3P)331 R1c X
5130.583(3)19485.533(12)5130.5829(10)0.000920 4d(3/2)2[3/2]2sp(3P)312 R1c
5133.123(3)19475.890(11)5133.1211(4)0.002500 4d(5/2)2[5/2]24f(5/2)2[1/2]°1 R1c
5134.6720(24)19470.016(9)5134.6725(9)−0.0005170 4d(5/2)2[3/2]1sp(3P)331 R1c
5136.3939(19)19463.489(7)5136.3932(5)0.00071300 4d(5/2)2[7/2]4sp(3F)134 R1c
5138.613(4)19455.085(17)5138.6113(20)0.001340 4d(3/2)2[5/2]3sp(1G)334 R1c
5151.206(2)19407.522(9)5151.2073(8)−0.0012500 4d(5/2)2[7/2]3sp(3F)133 R1c
5157.255(4)19384.761(14)5157.2580(9)−0.003340 sp(3F)3336s(3/2)2[3/2]2 R1c
5158.0914(6)19381.6168(21)5158.0916(4)−0.000213000 4d(5/2)2[1/2]04f(5/2)2[3/2]°12.4e+07D+F_ReTW
5159.103(4)19377.817(17)5159.0971(13)0.0062300 sp(3F)3345d(5/2)2[7/2]4 R1c
5163.252(3)19362.244(11)5163.2501(8)0.002330 4d(5/2)2[7/2]4sp(3F)133 R1c
5167.6923(22)19345.609(8)5167.6825(8)0.009811000?4d(5/2)2[5/2]2sp(3F)133 R1c X
5171.644(3)19330.828(12)5171.6406(13)0.003570 4d(3/2)2[7/2]3sp(3F)133 R1c
5175.9651(23)19314.689(9)5175.9637(23)0.00141400*4d(3/2)2[3/2]1sp(3P)311 R1nc
5175.9651(23)19314.689(9)5175.9653(10)−0.00021400*4d(5/2)2[1/2]1sp(3P)332 R1c
5183.3664(7)19287.110(3)5183.3664(5)−0.000019000 4d(5/2)2[1/2]04f(5/2)2[1/2]°12.4e+07D+F_ReTW
5184.052(3)19284.561(11)5184.0520(11)−0.000340 4d(3/2)2[3/2]1sp(1G)332 R1nc
5192.638(6)19252.671(21)5192.6239(13)0.015240 sp(3F)3345d(5/2)2[5/2]3 R1c
5194.349(4)19246.331(16)5194.3399(17)0.009170 sp(3F)3526s(5/2)2[5/2]2 R1c
5205.112(4)19206.536(17)5205.1059(8)0.006500 sp(3F)3325d(5/2)2[1/2]1 R1c
5207.1357(22)19199.070(8)5207.1340(15)0.001829000 4d(3/2)2[7/2]4sp(1G)335 R1c
5229.518(3)19116.900(10)5229.5194(11)−0.0023200 4d(3/2)2[5/2]2sp(3P)312 R1c
5229.709(6)19116.201(21)5229.7107(10)−0.002170 sp(3F)3336s(3/2)2[3/2]2 R1c
5234.471(23)19098.81(8)5234.429(3)0.042170*sp(3P)3119s(3/2)2[3/2]2 R1nc
5234.471(23)19098.81(8)5234.4943(14)−0.023170*sp(3F)3345d(5/2)2[9/2]4 R1c
5239.5473(24)19080.307(9)5239.5490(8)−0.0017330 4d(5/2)2[9/2]4sp(3F)134 R1c
5245.340(3)19059.237(12)5245.3423(13)−0.00319000 sp(3F)3345d(5/2)2[9/2]5 R1c
5247.109(4)19052.811(16)5247.1155(9)−0.007160 4d(3/2)2[7/2]3sp(3F)132 R1c
5247.976(4)19049.661(16)5247.9750(7)0.001160 5p(5/2)2[3/2]°25d(3/2)2[5/2]2 R1c
5251.545(3)19036.718(9)5251.5445(8)0.000330 4d(5/2)2[3/2]2sp(3P)332 R1c
5254.2141(20)19027.046(7)5254.2139(6)0.0002350 5p(5/2)2[3/2]°25d(3/2)2[5/2]3 R1c
5258.8249(21)19010.364(8)5258.8237(8)0.0011580 4d(5/2)2[3/2]1sp(3P)332 R1c
5261.0461(22)19002.338(8)5261.0443(8)0.0018330 sp(3F)3315d(5/2)2[5/2]2 R1c
5269.9892(14)18970.091(5)5269.9904(6)−0.001223000 4p32s21D2 F_Re
5276.5244(15)18946.597(5)5276.5241(9)0.000316000 4d(3/2)2[7/2]3sp(1G)334 F_Re
5280.9533(23)18930.707(8)5280.9563(7)−0.0030480 sp(3F)3335d(5/2)2[5/2]2 R1c
5285.360(4)18914.923(13)5285.3600(13)0.000480 4d(3/2)2[3/2]2sp(3F)133 R1c
5289.1103(21)18901.512(8)5289.1096(6)0.0007800 sp(3F)3335d(5/2)2[7/2]4 R1c
5291.8196(20)18891.835(7)5291.8216(7)−0.00201600 sp(3F)3335d(5/2)2[7/2]3 R1c
5297.4020(23)18871.927(8)5297.4047(9)−0.0028480 4d(3/2)2[3/2]1sp(3F)132 R1c
5310.771(3)18824.421(11)5310.7694(24)0.001310 4f(5/2)2[1/2]°17g(5/2)2[3/2]2 R1c
5314.6020(22)18810.851(8)5314.6025(9)−0.0005480 4d(3/2)2[7/2]4sp(1G)334 R1c
5315.989(4)18805.942(15)5315.9868(7)0.003160 5p(5/2)2[3/2]°25d(3/2)2[3/2]1 R1c
5321.666(3)18785.883(12)5321.666(3)0.000310 4f(5/2)2[1/2]°07g(5/2)2[3/2]1 R1c
5321.840(3)18785.267(11)5321.8352(21)0.005310*4f(5/2)2[3/2]°27g(5/2)2[5/2]2 R1nc
5321.840(3)18785.267(11)5321.8386(23)0.002310*4f(5/2)2[3/2]°27g(5/2)2[5/2]3 R1c
5324.070(4)18777.398(13)5324.0734(24)−0.003310 4f(5/2)2[3/2]°27g(5/2)2[3/2]2 R1c
5324.3542(21)18776.397(7)5324.3531(6)0.00111500 sp(3F)3335d(5/2)2[5/2]3 R1c
5325.319(3)18772.994(12)5325.3132(19)0.006310 4f(5/2)2[11/2]°57g(5/2)2[11/2]5 R1c
5327.9841(23)18763.605(8) 920 4f(5/2)2[11/2]°67g(5/2)2[13/2]71.1e+07D+R1cTW
5328.8109(22)18760.694(8) 1600 4f(5/2)2[11/2]°57g(5/2)2[13/2]61.1e+07D+R1cTW
5328.963(4)18760.157(13) 460 4f(3/2)2[3/2]°27g(3/2)2[5/2]39.e+06D+R1cTW
5331.63(4)18750.78(14)5331.6093(19)0.02150*4f(5/2)2[7/2]°48d(5/2)2[7/2]4 R1nc X
5331.63(4)18750.78(14)5331.674(3)−0.05150*5s(3/2)2[3/2]2sp(1D)333 R1c X
5335.317(3)18737.818(12)5335.3169(21)−0.000300 4f(5/2)2[3/2]°17g(5/2)2[5/2]2 R2nc
5335.518(3)18737.112(12)5335.5179(6)−0.000300 4p32s23P1 R1c
5336.203(3)18734.707(12) 150 4f(3/2)2[3/2]°17g(3/2)2[5/2]2 R1c
5337.580(13)18729.87(5)5337.5664(20)0.013150*4f(5/2)2[3/2]°17g(5/2)2[3/2]2 R1c
5337.580(13)18729.87(5)5337.593(3)−0.013150*4f(5/2)2[3/2]°17g(5/2)2[3/2]1 R1c
5338.460(3)18726.784(10)5338.4584(6)0.002300 4d(3/2)2[1/2]14f(5/2)2[3/2]°1 R1c
5340.098(3)18721.041(11)5340.0973(8)0.0011300 4d(5/2)2[3/2]2sp(3P)331 R1c
5340.878(3)18718.305(12)5340.8750(20)0.003300 4f(5/2)2[7/2]°37g(5/2)2[9/2]4 R1c
5342.197(3)18713.684(12)5342.1987(24)−0.001150 4f(5/2)2[7/2]°37g(5/2)2[7/2]3 R1c
5344.316(4) m4f(3/2)2[9/2]°47g(3/2)2[9/2]4 R1nc
5344.366(4)18706.091(16)5344.3657(21)0.000150*4f(5/2)2[7/2]°37g(5/2)2[5/2]2 R1nc
5344.366(4)18706.091(16)5344.3692(24)−0.003150*4f(5/2)2[7/2]°37g(5/2)2[5/2]3 R1c
5345.160(3)18703.312(10)5345.154(3)0.006420*4f(3/2)2[9/2]°57g(3/2)2[11/2]5 R1c
5345.160(3)18703.312(10) 420*4f(3/2)2[9/2]°57g(3/2)2[11/2]61.1e+07D+R1ncTW
5345.576(2)18701.857(9)5345.5723(9)0.003300 sp(3F)3315d(5/2)2[3/2]1 R1c
5347.6243(22)18694.693(8)5347.6243(8)−0.00001500 4d(5/2)2[3/2]1sp(3P)331 R1c
5347.684(3)18694.484(11)5347.6891(8)−0.005750 4d(3/2)2[7/2]3sp(3F)133 R1c
5347.809(3)18694.047(12)5347.809(3)0.000420 4f(3/2)2[9/2]°47g(3/2)2[11/2]51.1e+07D+R1cTW
5349.076(4)18689.619(13)5349.0730(24)0.003150 4f(5/2)2[5/2]°27g(5/2)2[7/2]3 R1c
5351.245(4)18682.043(14)5351.2456(21)−0.000150*4f(5/2)2[5/2]°27g(5/2)2[5/2]2 R1nc
5351.245(4)18682.043(14)5351.2491(24)−0.004150*4f(5/2)2[5/2]°27g(5/2)2[5/2]3 R1c
5351.579(4)18680.878(12)5351.5804(12)−0.001300 4d(3/2)2[5/2]2sp(1G)332 R1nc
5352.0268(21)18679.315(7)5352.0245(5)0.00236000 4d(3/2)2[1/2]14f(5/2)2[3/2]°2 R1c
5353.863(4)18672.908(12)5353.8649(20)−0.002300 4f(5/2)2[5/2]°37g(5/2)2[9/2]4 R1c
5354.4850(20)18670.740(7)5354.4863(8)−0.00134500 4d(3/2)2[1/2]14f(5/2)2[1/2]°0 R1c
5355.186(3)18668.294(11)5355.1870(24)−0.001410 4f(5/2)2[5/2]°37g(5/2)2[7/2]47.4e+06D+R1cTW
5356.8109(21)18662.633(7)5356.8091(8)0.00182100 4d(5/2)2[5/2]3sp(3F)134 R1c
5357.374(4)18660.670(13)5357.3727(21)0.002300*4f(5/2)2[5/2]°37g(5/2)2[5/2]2 R1nc
5357.374(4)18660.670(13)5357.3761(24)−0.002300*4f(5/2)2[5/2]°37g(5/2)2[5/2]3 R1c
5361.907(4)18644.894(12)5361.914(4)−0.007150*4f(3/2)2[5/2]°37g(3/2)2[7/2]3 R1c
5361.907(4)18644.894(12) 150*4f(3/2)2[5/2]°37g(3/2)2[7/2]49.e+06D+R1ncTW
5365.5363(20)18632.284(7)5365.5363(6)−0.00005500 4d(3/2)2[1/2]14f(5/2)2[1/2]°1 R1c
5366.243(3)18629.831(11)5366.2476(7)−0.005440 sp(3F)3326s(3/2)2[3/2]2 R1c
5368.3825(21)18622.406(7)5368.3839(7)−0.00137400 sp(3F)3335d(5/2)2[9/2]4 R1c
5371.6264(21)18611.160(7)5371.6264(7)0.0001880 sp(3F)3335d(5/2)2[3/2]2 R1c
5375.276(4)18598.524(12)5375.276(4)0.000290 4f(3/2)2[5/2]°27g(3/2)2[7/2]38.1e+06D+R1cTW
5381.9479(23)18575.468(8)5381.9511(21)−0.0032430*4f(5/2)2[7/2]°47g(5/2)2[9/2]4 R1c
5381.9479(23)18575.468(8)5381.9485(20)−0.0006430*4f(5/2)2[7/2]°47g(5/2)2[9/2]58.2e+06D+R1ncTW
5382.329(4)18574.152(15)5382.3347(19)−0.006140 4f(5/2)2[7/2]°47g(5/2)2[11/2]5 R1c
5383.289(4)18570.842(12)5383.2871(24)0.001140 4f(5/2)2[7/2]°47g(5/2)2[7/2]4 R1c
5384.818(3)18565.569(11)5384.8222(16)−0.005430 4d(3/2)2[1/2]06p(3/2)2[1/2]°1 R1c
5386.435(4)18559.995(14)5386.437(4)−0.003420*4f(3/2)2[7/2]°47g(3/2)2[9/2]4 R1c
5386.435(4)18559.995(14) 420*4f(3/2)2[7/2]°47g(3/2)2[9/2]51.0e+07D+R1ncTW
5386.8405(22)18558.597(8)5386.8419(10)−0.0014720 4d(5/2)2[1/2]0sp(3P)331 R1c
5390.029(4)18547.619(13)5390.0296(21)−0.001140*4f(5/2)2[9/2]°57g(5/2)2[9/2]4 R1c
5390.029(4)18547.619(13)5390.0270(20)0.002140*4f(5/2)2[9/2]°57g(5/2)2[9/2]5 R1nc
5390.4163(22)18546.286(8)5390.4169(13)−0.00064800 4d(3/2)2[5/2]2sp(3F)133 R1c
5391.6966(22)18541.882(8)5391.6987(10)−0.00211700 4d(5/2)2[9/2]5sp(3F)135 R1c
5393.9372(21)18534.180(7)5393.9372(7)0.00012600 sp(3F)3326s(3/2)2[3/2]1 R1c
5397.2943(21)18522.652(7)5397.2952(5)−0.0008580 4d(3/2)2[7/2]34f(5/2)2[9/2]°4 R1c
5397.3718522.385397.3730(17) :sp(3F)1339s(5/2)2[5/2]3
5398.573(4)18518.266(12)5398.573(4)−0.000140 4f(3/2)2[7/2]°37g(3/2)2[9/2]49.e+06D+R1cTW
5403.714(4)18500.647(13)5403.7093(9)0.005140 5p(5/2)2[3/2]°25d(3/2)2[1/2]1 R1c
5405.652(3)18494.013(11)5405.6515(6)0.001280 4p32s23P2 R1c
5407.447(3)18487.877(11)5407.4452(23)0.001280 5s(3/2)2[3/2]2sp(1D)332 R1c
5408.383(4)18484.675(12)5408.3840(24)−0.001280 5s(3/2)2[3/2]1sp(1D)331 R1c
5422.002(4)18438.246(12)5422.0053(21)−0.003140 4f(5/2)2[9/2]°47g(5/2)2[9/2]4 R1c
5422.392(3)18436.920(11)5422.3947(19)−0.003270 4f(5/2)2[9/2]°47g(5/2)2[11/2]57.2e+06D+R1cTW
5428.274(3)18416.944(11)5428.2724(9)0.001140 4d(5/2)2[7/2]3sp(3F)134 R1c
5437.1438(21)18386.899(7)5437.1431(5)0.00062100 4d(3/2)2[7/2]44f(5/2)2[9/2]°4 R1c
5437.5787(23)18385.428(8)5437.5790(4)−0.00026700 4d(3/2)2[7/2]34f(5/2)2[7/2]°4 R1c
5441.6461(22)18371.686(7)5441.6471(9)−0.00112100 4d(5/2)2[7/2]4sp(3F)134 R1c
5448.1914(23)18349.615(8)5448.1938(9)−0.0024260 4d(5/2)2[7/2]3sp(3P)332 R1c
5449.409(4)18345.516(12)5449.4072(10)0.0022700 4d(5/2)2[3/2]2sp(3P)333 R1c
5458.0942(22)18316.323(7)5458.0941(9)0.0001390 4d(3/2)2[5/2]3sp(3F)132 R1c
5466.57(6)18287.94(20)5466.5527(5)0.011600*4d(3/2)2[7/2]34f(5/2)2[5/2]°3 R1c
5466.57(6)18287.94(20)5466.6267(9)−0.061600*4d(5/2)2[5/2]2sp(3P)332 R1c
5468.563(3)18281.260(9)5468.5633(19)−0.000510 5s(3/2)2[3/2]1sp(1D)332 R1c
5469.376(3)18278.541(10)5469.3734(8)0.0031300 4d(3/2)2[3/2]2sp(3F)133 R1c
5469.6826(21)18277.518(7)5469.6819(4)0.00064400 4d(3/2)2[7/2]44f(5/2)2[9/2]°5 R1c
5472.465(3)18268.225(11)5472.4631(10)0.002130 4d(3/2)2[5/2]2sp(3F)132 R1c
5472.9475(24)18266.614(8)5472.9467(5)0.0007740 4d(3/2)2[7/2]34f(5/2)2[5/2]°2 R1c
5473.0118266.425473.006(2) :sp(3F)1337g(5/2)2[9/2]4
5473.119(4)18266.040(12)5473.1211(8)−0.002920 5p(5/2)2[5/2]°25d(3/2)2[5/2]2 R1c
5473.1623(16) m4f(5/2)2[7/2]°39s(5/2)2[5/2]3 R1nc
5477.127(3)18252.676(11)5477.1275(13)−0.001130 4d(3/2)2[1/2]1sp(3P)330 R1c
5478.0268(23)18249.677(8)5478.0262(4)0.00063700 4d(3/2)2[7/2]44f(5/2)2[7/2]°4 R1c
5479.9089(22)18243.409(7)5479.9071(7)0.00183700 5p(5/2)2[5/2]°25d(3/2)2[5/2]3 R1c
5480.1613(24)18242.569(8)5480.1619(5)−0.00061900 4d(3/2)2[7/2]34f(5/2)2[7/2]°3 R1c
5482.524(3)18234.708(10)5482.5262(15)−0.002790 sp(3F)3346s(5/2)2[5/2]3 R1c
5486.205(3)18222.473(11)5486.2037(8)0.001120 5p(5/2)2[3/2]°15d(3/2)2[5/2]2 R1c
5493.5268(22)18198.186(7)5493.5289(6)−0.0021240 5p(5/2)2[7/2]°35d(3/2)2[7/2]4 R1c
5495.0454(23)18193.157(8)5495.0446(23)0.0008430 5s(3/2)2[3/2]2sp(1D)333 R1c
5496.868(3)18187.126(11)5496.8685(11)−0.001510 4d(5/2)2[3/2]2sp(3P)332 R1c
5504.021(4)18163.488(12)5504.0559(5)−0.035120?4d(3/2)2[7/2]34f(5/2)2[3/2]°2 R1c X
5504.844(3)18160.774(11)5504.8442(11)−0.000240 4d(5/2)2[3/2]1sp(3P)332 R1c
5507.428(4)18152.254(12)5507.4337(4)−0.006240 4d(3/2)2[7/2]44f(5/2)2[5/2]°3 R1c
5512.8649(22)18134.351(7)5512.8650(6)−0.0001240 5p(5/2)2[7/2]°35d(3/2)2[7/2]3 R1c
5521.249(3)18106.815(9)5521.2475(5)0.001230 4d(3/2)2[7/2]44f(5/2)2[7/2]°3 R1c
5521.729(3)18105.239(9)5521.7315(8)−0.0021100 5p(5/2)2[5/2]°25d(3/2)2[3/2]2 R1c
5525.438(3)18093.088(9)5525.4391(6)−0.001230 5p(5/2)2[7/2]°45d(3/2)2[7/2]4 R1c
5525.5318092.785525.532(6) :sp(3F)1328d(5/2)2[5/2]2
5527.1968(22)18087.330(7)5527.1993(7)−0.00252200 4d(3/2)2[7/2]3sp(3F)134 R1c
5527.6813(22)18085.744(7)5527.6804(5)0.0009690 4d(3/2)2[3/2]14f(5/2)2[5/2]°2 R1c
5534.668(3)18062.913(10)5534.6726(8)−0.004230 5p(5/2)2[5/2]°35d(3/2)2[5/2]2 R1c
5535.0494(22)18061.669(7)5535.0478(8)0.00164100 5p(5/2)2[3/2]°15d(3/2)2[3/2]2 R1c
5537.670(20)18053.12(7)5537.6662(21)0.004340 sp(3F)3145d(5/2)2[7/2]4 R1c
5538.3836(22)18050.796(7)5538.3835(6)0.0001880 4d(3/2)2[7/2]44f(5/2)2[11/2]°5 R1c
5541.6120(22)18040.280(7)5541.6123(6)−0.00031300 5p(5/2)2[5/2]°35d(3/2)2[5/2]3 R1c
5543.5368(22)18034.016(7)5543.5385(7)−0.00161900 sp(3F)3325d(5/2)2[5/2]2 R1c
5544.7815(22)18029.968(7)5544.7803(6)0.0012220 4d(3/2)2[3/2]14f(5/2)2[3/2]°1 R1c
5555.5122(22)17995.143(7)5555.5123(7)−0.00015500 sp(3F)3325d(5/2)2[7/2]3 R1c
5558.314(3)17986.072(11)5558.3108(10)0.003110 4d(3/2)2[7/2]3sp(3F)133 R1c
5559.417(4)17982.504(11)5559.4167(5)0.000110 4d(3/2)2[3/2]14f(5/2)2[3/2]°2 R1c
5560.5761(24)17978.755(8)5560.5739(8)0.0022610 5p(5/2)2[3/2]°15d(3/2)2[3/2]1 R1c
5562.074(3)17973.913(11)5562.0730(8)0.001110 4d(3/2)2[3/2]14f(5/2)2[1/2]°0 R1c
5562.6460(23)17972.065(7)5562.6478(9)−0.0018770 4d(5/2)2[5/2]2sp(3P)331 R1c
5567.002(3)17958.004(9)5567.0018(8)−0.000210 4d(3/2)2[5/2]3sp(3F)133 R1c
5569.670(3)17949.401(11)5569.6723(16)−0.002210 5d(5/2)2[9/2]57f(5/2)2[9/2]°5 R1c
5571.6406(24)17943.052(8)5571.6415(7)−0.0009210 5p(5/2)2[5/2]°25d(3/2)2[7/2]3 R1c
5578.4356(23)17921.196(7)5578.4337(17)0.0019520 5d(5/2)2[9/2]57f(5/2)2[11/2]°61.0e+07D+R1cTW
5579.431(4)17917.999(12)5579.4269(20)0.004210 5d(5/2)2[3/2]27f(5/2)2[5/2]°3 R1c
5581.9475(24)17909.921(8)5581.9507(9)−0.0032310 4d(3/2)2[5/2]2sp(3F)133 R1c
5582.173(4)17909.196(11)5582.1725(18)0.001100 5d(5/2)2[9/2]47f(5/2)2[9/2]°4 R1c
5583.864(3)17903.773(11)5583.8665(11)−0.002210 4d(3/2)2[1/2]1sp(3P)331 R1c
5584.346(3)17902.230(11)5584.3413(22)0.004480 5d(3/2)2[7/2]37f(3/2)2[9/2]°49.e+06D+R1cTW
5591.382(3)17879.700(9)5591.3777(6)0.005210 sp(3F)3325d(5/2)2[5/2]3 R1c
5592.5298(24)17876.032(8)5592.5272(19)0.0026510 5d(5/2)2[9/2]47f(5/2)2[11/2]°59.e+06D+R1cTW
5593.7697(13)17872.070(4)5593.7708(4)−0.00115400 4d(3/2)2[3/2]24f(5/2)2[5/2]°3 F_Re
5600.4662(23)17850.701(7)5600.4661(5)0.0001500 4d(3/2)2[3/2]24f(5/2)2[5/2]°2 R1c
5600.581(4)17850.334(11)5600.5810(10)0.000300 4d(3/2)2[7/2]4sp(3F)133 R1c
5607.282(3)17829.001(9)5607.2823(22)0.000300 5d(3/2)2[7/2]47f(3/2)2[9/2]°58.e+06D+R1cTW
5608.027(3)17826.635(8)5608.0216(5)0.005200 4d(3/2)2[3/2]24f(5/2)2[7/2]°3 R1c
5615.2350(23)17803.751(7)5615.2379(6)−0.00305500 5p(5/2)2[5/2]°35d(3/2)2[7/2]4 R1c
5618.016(3)17794.938(11)5618.0200(6)−0.00498 4d(3/2)2[3/2]24f(5/2)2[3/2]°1 R1c
5619.885(7)17789.021(21)5619.8874(16)−0.003190 4d(3/2)2[3/2]2sp(3P)352 R1c
5620.7814(23)17786.183(7)5620.7805(5)0.0008850 4d(3/2)2[5/2]34f(5/2)2[9/2]°4 R1c
5621.7027(24)17783.268(8)5621.7019(10)0.0009530 4d(5/2)2[1/2]0sp(3P)331 R1c
5629.240(3)17759.456(11)5629.218(3)0.022190?5d(5/2)2[5/2]37f(5/2)2[7/2]°3 R1c X
5630.589(4)17755.202(11)5630.5900(18)−0.00195 5d(5/2)2[5/2]37f(5/2)2[9/2]°4 R1c
5631.153(3)17753.425(11)5631.1561(18)−0.003190 5d(5/2)2[5/2]37f(5/2)2[7/2]°4 R1c
5631.358(3)17752.777(11)5631.3600(20)−0.00295 5d(5/2)2[5/2]37f(5/2)2[5/2]°3 R1c
5633.0442(23)17747.464(7)5633.0461(5)−0.00203400 4d(3/2)2[3/2]24f(5/2)2[3/2]°2 R1c
5633.602(3)17745.707(10)5633.6032(12)−0.001950 4d(5/2)2[5/2]3sp(3P)332 R1c
5635.5118(23)17739.693(7)5635.5130(11)−0.00123000 4d(5/2)2[7/2]4sp(3F)135 R1c
5637.162(4)17734.501(13)5637.1546(21)0.007190 sp(3F)3145d(5/2)2[9/2]5 R1c
5637.468(3)17733.536(8)5637.4686(8)−0.0001100 sp(3F)3325d(5/2)2[3/2]1 R1c
5641.2645(23)17721.603(7)5641.2645(18)−0.00002300 5p(3/2)2[1/2]°15d(3/2)2[1/2]0 R1c
5643.5338(24)17714.477(8)5643.5346(7)−0.0008280 sp(3F)3325d(5/2)2[3/2]2 R1c
5648.0170(24)17700.416(8)5648.0161(6)0.0009430 4d(3/2)2[3/2]24f(5/2)2[1/2]°1 R1c
5651.708(4)17688.857(11)5651.7093(9)−0.001370 sp(3F)3316s(3/2)2[3/2]2 R1c
5656.632(3)17673.459(10)5656.6271(10)0.0057300 5p(5/2)2[3/2]°15d(3/2)2[1/2]1 R1c
5664.4833(23)17648.963(7)5664.4829(5)0.00042900 4d(3/2)2[5/2]34f(5/2)2[7/2]°4 R1c
5667.434(3)17639.775(11)5667.4344(19)−0.001180 5d(5/2)2[7/2]37f(5/2)2[9/2]°45.8e+06D+R1cTW
5668.007(3)17637.991(10)5668.0080(18)−0.001180 5d(5/2)2[7/2]37f(5/2)2[7/2]°4 R1c
5670.329(3)17630.769(10)5670.3245(16)0.004350 5d(5/2)2[7/2]47f(5/2)2[9/2]°57.4e+06D+R1cTW
5674.694(4)17617.207(12)5674.6947(7)−0.001180*sp(3F)3336s(3/2)2[3/2]2 R1c
5674.694(4)17617.207(12)5674.6968(9)−0.003180*sp(3F)3135d(3/2)2[5/2]2 R1nc
5676.005(3)17613.137(10)5676.0028(11)0.0021300 4d(5/2)2[7/2]4sp(3P)333 R1c
5678.556(3)17605.224(11)5678.554(3)0.00287 5d(5/2)2[5/2]27f(5/2)2[7/2]°3 R1c
5681.353(3)17596.559(11)5681.3597(11)−0.00787 4d(5/2)2[5/2]2sp(3P)333 R1c
5681.998(3)17594.559(9)5681.9923(7)0.006430 sp(3F)3135d(3/2)2[5/2]3 R1c
5682.433(3)17593.214(9)5682.4316(9)0.0012100 sp(3F)3316s(3/2)2[3/2]1 R1c
5689.83(4)17570.34(12)5689.8869(11)−0.06170 4d(3/2)2[3/2]2sp(3F)133 S36c
5694.526(3)17555.852(10)5694.5253(14)0.001170 4d(3/2)2[3/2]1sp(3P)330 R1c
5695.931(3)17551.521(10)5695.9321(5)−0.001340 4d(3/2)2[5/2]34f(5/2)2[5/2]°3 R1c
5706.012(4)17520.514(12)5706.0055(7)0.006450 4p13s23P2 R1c
5710.7111(24)17506.097(7)5710.7089(5)0.0022250 4d(3/2)2[5/2]34f(5/2)2[7/2]°3 R1c
5711.586(4)17503.416(11)5711.5823(5)0.003250 4d(3/2)2[5/2]24f(5/2)2[5/2]°3 R1c
5721.7840(24)17472.220(7)5721.7856(7)−0.00154100 4p31s21D2 R1c
5726.442(3)17458.009(11)5726.4406(6)0.001160 4d(3/2)2[5/2]24f(5/2)2[7/2]°3 R1c
5731.004(4)17444.110(12)5731.0007(11)0.004160 4d(3/2)2[1/2]1sp(3P)332 R1c
5736.659(4)17426.915(11)5736.6603(5)−0.001160 4d(3/2)2[5/2]34f(5/2)2[3/2]°2 R1c
5752.536(4)17378.819(11)5752.5355(6)0.000580 4d(3/2)2[5/2]24f(5/2)2[3/2]°2 R1c
5759.015(4)17359.266(11)5759.0170(20)−0.002150 sp(3F)1356g(5/2)2[11/2]6 R1c
5759.4219(24)17358.040(7)5759.4213(7)0.00056300 sp(3F)3135d(3/2)2[7/2]4 R1c
5761.220(3)17352.622(8)5761.2165(10)0.0042000 sp(3F)3336s(5/2)2[5/2]2 R1c
5761.8052(24)17350.860(7)5761.8056(7)−0.00032200 4d(3/2)2[5/2]3sp(3F)134 R1c
5768.143(4)17331.796(11)5768.1482(7)−0.005150 4d(3/2)2[5/2]24f(5/2)2[1/2]°1 R1c
5779.656(4)17297.270(12)5779.6592(8)−0.003360 sp(3F)3325d(5/2)2[1/2]1 R1c
5783.920(4)17284.519(11)5783.9194(20)0.0016400 5p(3/2)2[3/2]°15d(3/2)2[1/2]0 R1c
5801.130(7)17233.242(21)5801.116(3)0.014140 5s(5/2)2[5/2]3sp(3P)352 R1c
5805.989(3)17218.822(8)5805.9869(11)0.0024700 sp(3F)3336s(5/2)2[5/2]3 R1c
5825.823(2)17160.200(7)5825.8247(9)−0.0029100 sp(3F)3125d(3/2)2[5/2]21.1e+07D+R1cTW
5833.5146(24)17137.573(7)5833.5141(7)0.00056400 sp(3F)3125d(3/2)2[5/2]37.9e+06D+R1cTW
5836.619(4)17128.458(13)5836.6234(11)−0.004130 4d(3/2)2[1/2]1sp(3P)331 R1c
5842.495(3)17111.233(8)5842.4918(7)0.0031900 4p12s23P1 R1c
5851.787(4)17084.062(11)5851.7811(12)0.006930 sp(3F)3336s(5/2)2[5/2]2 R1c
5858.54(10)17064.4(3)5858.353(5)0.199100 sp(3F)1327g(3/2)2[7/2]3 S36cn X
5890.443(4)16971.949(11)5890.4592(12)−0.016120 4d(3/2)2[3/2]2sp(3P)331 R1c X
5897.971(3)16950.287(7)5897.9758(12)−0.00523000 sp(3F)3336s(5/2)2[5/2]3 R1c
5901.188(3)16941.047(10)5901.1910(8)−0.0031700 4p33s21D2 R1c
5909.753(3)16916.494(9)5909.7579(9)−0.0051500 sp(3F)3125d(3/2)2[3/2]1 R1c
5910.813(4)16913.460(11)5910.8150(20)−0.00257 sp(3F)1347d(5/2)2[9/2]5 R1c
5926.691(3)16868.147(8)5926.6916(6)−0.0001300 4p12s23P2 R1c
5929.634(3)16859.777(10)5929.6380(11)−0.004110 4d(3/2)2[7/2]4sp(3F)134 R1c
5937.576(2)16837.224(7)5937.5815(7)−0.0052000 sp(3F)3125d(3/2)2[7/2]31.0e+07D+R1cTW
5939.775(7)16830.992(21)5939.7773(20)−0.00254 sp(1G)3346g(3/2)2[11/2]5 R1c
5941.1951(4)16826.9685(10)5941.1951(3)−0.000131000 5p(5/2)2[3/2]°25d(5/2)2[5/2]33.6e+07D+F_ReTW
5941.826(4)16825.183(11)5941.8291(17)−0.0031600 4d(3/2)2[1/2]06p(5/2)2[3/2]°1 R1c
5979.015(3)16720.532(8)5979.0193(8)−0.0042800 sp(3F)3326s(3/2)2[3/2]2 R1c
5988.3141(17)16694.567(5)5988.3135(14)0.00067600 5p(5/2)2[3/2]°15d(5/2)2[1/2]09.e+07D+F_ReTW
5993.259(3)16680.793(7)5993.2605(8)−0.0013200 5p(5/2)2[3/2]°25d(5/2)2[3/2]1 R1c
5995.5902(19)16674.307(5)5995.5876(10)0.00264600 5p(3/2)2[1/2]°05d(3/2)2[3/2]13.0e+07D+F_ReTW
6000.1169(8)16661.7272(22)6000.1168(6)0.000138000 5p(5/2)2[3/2]°25d(5/2)2[3/2]27.5e+07D+F_ReTW
6002.304(4)16655.656(10)6002.305(3)−0.00098 6s(5/2)2[5/2]3sp(1D)112 R1c
6013.411(3)16624.893(7)6013.4138(8)−0.0033200 sp(3F)3326s(3/2)2[3/2]1 R1c
6018.369(5)16611.196(13)6018.3711(12)−0.002480 sp(3F)3125d(3/2)2[1/2]1 R1c
6023.263(3)16597.700(7)6023.2636(9)−0.0003900 sp(3F)3326s(5/2)2[5/2]2 R1c
6050.917(4)16521.845(11)6050.916(3)0.00191 6s(5/2)2[5/2]2sp(1D)112 R1c
6071.492(4)16465.858(10)6071.4896(22)0.002130 sp(3F)1336g(3/2)2[9/2]4 R1c
6072.217(3)16463.891(7)6072.2167(9)0.0014200 sp(3F)3326s(5/2)2[5/2]3 R1c
6080.3334(19)16441.915(5)6080.3370(7)−0.003611000 4p33s23P2 F_Re
6083.086(4)16434.475(10)6083.0848(22)0.001130 6p(5/2)2[7/2]°38d(5/2)2[9/2]46.9e+06D+R1cTW
6085.021(4)16429.250(11)6085.021(3)−0.00087 4d(5/2)2[1/2]1sp(3P)351 R1c
6097.328(3)16396.088(8)6097.3235(10)0.0044800 5p(3/2)2[5/2]°25d(3/2)2[5/2]21.9e+07D+R1cTW
6099.989(3)16388.936(7)6099.9896(7)−0.0013700 5p(5/2)2[7/2]°35d(5/2)2[5/2]2 R1c
6105.747(3)16373.480(7)6105.7469(8)0.0003600 5p(3/2)2[5/2]°25d(3/2)2[5/2]39.e+06D+R1cTW
6107.4055(21)16369.034(6)6107.4083(12)−0.00285100 5p(3/2)2[1/2]°05d(3/2)2[1/2]13.3e+07D+F_ReTW
6110.872(3)16359.748(7)6110.8706(7)0.0023700 5p(5/2)2[7/2]°35d(5/2)2[7/2]4 R1c
6114.4926(14)16350.061(4)6114.4911(7)0.001615000 5p(5/2)2[7/2]°35d(5/2)2[7/2]33.4e+07D+F_ReTW
6150.3818(9)16254.6548(23)6150.3813(6)0.000516000 5p(5/2)2[7/2]°45d(5/2)2[7/2]43.6e+07D+F_ReTW
6154.2215(8)16244.5134(21)6154.2211(7)0.000425000 5p(5/2)2[3/2]°25d(5/2)2[1/2]11.0e+08D+F_ReTW
6157.716(4)16235.296(10)6157.7151(10)0.0004700 5p(3/2)2[5/2]°25d(3/2)2[3/2]2 R1c
6157.956(8)16234.662(21)6157.9650(6)−0.009530 5p(5/2)2[7/2]°35d(5/2)2[5/2]3 R1c
6160.573(4)16227.765(11)6160.5707(14)0.003320 4d(3/2)2[7/2]4sp(3F)135 R1c
6172.033(3)16197.634(7)6172.0339(8)−0.00016000 5p(5/2)2[5/2]°25d(5/2)2[5/2]23.4e+07D+F_ReTW
6174.296(5)16191.698(12)6174.2920(12)0.004190 4d(3/2)2[5/2]3sp(3P)332 R1c
6186.8770(14)16158.772(4)6186.8803(8)−0.003318000 5p(5/2)2[5/2]°25d(5/2)2[7/2]33.6e+07D+F_ReTW
6188.6763(11)16154.075(3)6188.6761(7)0.000212000 5p(5/2)2[3/2]°15d(5/2)2[5/2]23.1e+07D+F_ReTW
6189.317(4)16152.402(11)6189.3237(10)−0.007760 5p(3/2)2[5/2]°25d(3/2)2[3/2]1 R1c
6192.684(4)16143.620(11)6192.6855(12)−0.00176 4d(3/2)2[5/2]2sp(3P)332 R1c
6198.091(3)16129.537(7)6198.0890(5)0.0025000 5p(5/2)2[7/2]°45d(5/2)2[5/2]39.e+06D+R1cTW
6199.751(3)16125.219(8)6199.7460(10)0.0051700 5p(3/2)2[5/2]°35d(3/2)2[5/2]2 R1c
6203.715(4)16114.915(11)6203.712(3)0.00437 6p(5/2)2[3/2]°28d(5/2)2[5/2]3 R1c
6204.2569(19)16113.507(5)6204.2577(10)−0.000811000 5p(3/2)2[1/2]°15d(3/2)2[3/2]24.9e+07D+F_ReTW
6208.4527(19)16102.618(5)6208.4549(8)−0.00229900 5p(3/2)2[5/2]°35d(3/2)2[5/2]32.9e+07D+F_ReTW
6208.988(4)16101.230(10)6208.9891(14)−0.00175 4d(3/2)2[7/2]4sp(3P)333 R1c
6214.542(4)16086.839(11) 150 6p(5/2)2[3/2]°28d(5/2)2[3/2]2 R1c
6216.9386(8)16080.6383(21)6216.9385(6)0.000139000 5p(5/2)2[7/2]°35d(5/2)2[9/2]49.4e+07C+F_ReTW
6219.8492(9)16073.1134(22)6219.8488(7)0.000524000 5p(3/2)2[5/2]°25d(3/2)2[7/2]39.4e+07C+F_ReTW
6221.288(4)16069.396(11)6221.2875(7)0.001740 5p(5/2)2[7/2]°35d(5/2)2[3/2]2 R1c
6231.396(3)16043.331(8)6231.3934(6)0.002290 5p(5/2)2[5/2]°25d(5/2)2[5/2]3 R1c
6236.344(3)16030.601(7)6236.3471(10)−0.0031200 5p(3/2)2[1/2]°15d(3/2)2[3/2]1 R1c
6250.417(3)15994.508(8)6250.4216(8)−0.005720 5p(5/2)2[5/2]°35d(5/2)2[5/2]2 R1c
6257.838(3)15975.542(7)6257.8373(7)0.0003400 5p(5/2)2[7/2]°45d(5/2)2[9/2]44.1e+06D+F_ReTW
6261.8477(13)15965.311(3)6261.8464(6)0.001319000 5p(5/2)2[5/2]°35d(5/2)2[7/2]43.7e+07D+F_ReTW
6265.650(3)15955.623(7)6265.6480(8)0.0022800 5p(5/2)2[5/2]°35d(5/2)2[7/2]3 R1c
6273.34762(8)15936.04484(21)6273.34763(8)−0.0000047000 5p(5/2)2[7/2]°45d(5/2)2[9/2]51.06e+08C+F_ReTW
6276.660(5)15927.636(14)6276.6713(19)−0.01214000 sp(3F)3346s(5/2)2[5/2]3 R1c
6288.695(3)15897.154(7)6288.6936(9)0.0016600 5p(5/2)2[5/2]°25d(5/2)2[3/2]11.7e+07D+R1cTW
6296.239(4)15878.107(11)6296.2430(8)−0.00434 5p(5/2)2[5/2]°25d(5/2)2[3/2]2 R1c
6299.864(5)15868.969(11)6299.810(3)0.05434?sp(3P)3126g(3/2)2[5/2]3 R1c X
6301.0135(8)15866.0749(21)6301.0137(7)−0.000127000 5p(3/2)2[5/2]°35d(3/2)2[7/2]41.0e+08C+F_ReTW
6305.9712(10)15853.601(3)6305.9718(8)−0.000612000 5p(5/2)2[3/2]°15d(5/2)2[3/2]15.7e+07D+F_ReTW
6311.3006(21)15840.214(5)6311.3059(5)−0.005318000 5p(5/2)2[5/2]°35d(5/2)2[5/2]33.5e+07D+F_ReTW
6312.491(3)15837.227(7)6312.4915(11)−0.00014000 5p(3/2)2[3/2]°15d(3/2)2[5/2]25.8e+07D+R1cTW
6313.564(3)15834.535(7)6313.5627(7)0.0011000 5p(5/2)2[3/2]°15d(5/2)2[3/2]2 R1c
6317.788(3)15823.950(7)6317.7831(12)0.0041300 4p31s23P0 R1c
6318.944(5)15821.053(13)6318.9422(15)0.00233 4d(3/2)2[3/2]2sp(3P)333 R1c
6326.465(3)15802.245(7)6326.4649(8)0.0002500 5p(3/2)2[5/2]°35d(3/2)2[7/2]35.0e+06D+R1cTW
6357.414(3)15725.318(7)6357.4193(13)−0.00516000 5p(3/2)2[1/2]°15d(3/2)2[1/2]15.5e+07D+F_ReTW
6363.566(5)15710.115(11)6363.568(4)−0.00132 6p(3/2)2[5/2]°39d(5/2)2[9/2]4 R1c
6373.267(3)15686.203(8)6373.2678(7)−0.0016900 5p(5/2)2[5/2]°35d(5/2)2[9/2]4 R1c
6377.248(7)15676.410(17)6377.2432(12)0.00513000 5p(3/2)2[3/2]°15d(3/2)2[3/2]2 R1c
6377.842(3)15674.951(7)6377.8383(7)0.00419000 5p(5/2)2[5/2]°35d(5/2)2[3/2]21.9e+07D+F_ReTW
6380.758(4)15667.788(9)6380.7645(7)−0.0071300 5p(5/2)2[3/2]°26s(3/2)2[3/2]2 R1c
6385.263(3)15656.734(7)6385.2618(10)0.0011200 sp(3F)3316s(5/2)2[5/2]2 R1c
6393.074(6)15637.604(15)6393.0792(20)−0.005130*sp(3F)1346g(5/2)2[9/2]4 R1c
6393.074(6)15637.604(15)6393.0735(21)0.001130*sp(3F)1346g(5/2)2[9/2]5 R1nc
6393.957(3)15635.446(8)6393.9587(13)−0.0022100 sp(3F)1346g(5/2)2[11/2]53.4e+06D+R1cTW
6403.384(3)15612.428(8)6403.3840(15)−0.0009600 4d(3/2)2[1/2]04f(3/2)2[3/2]°12.7e+07D+R1cTW
6411.142(4)15593.535(10)6411.1518(12)−0.01010000 5p(3/2)2[3/2]°15d(3/2)2[3/2]15.8e+07D+F_ReTW
6414.569(3)15585.204(7)6414.5612(11)0.00812000 5p(3/2)2[3/2]°25d(3/2)2[5/2]21.4e+07D+R1cTW
6414.625(3)15585.069(7)6414.6165(8)0.00816000 sp(3F)3336s(5/2)2[5/2]2 R1c
6418.160(4)15576.483(10)6418.1566(24)0.0042100 4f(5/2)2[1/2]°16g(5/2)2[3/2]21.5e+07D+R1cTW
6418.192(3) m4f(5/2)2[1/2]°16g(5/2)2[3/2]1 R1nc
6419.941(9)15572.162(21)6419.9515(7)−0.01062 5p(5/2)2[3/2]°26s(3/2)2[3/2]1 R1c
6423.8842(11)15562.604(3)6423.8846(8)−0.000319000 5p(3/2)2[3/2]°25d(3/2)2[5/2]35.6e+07C+F_ReTW
6427.416(9)15554.052(21)6427.411(3)0.00531 4f(5/2)2[3/2]°26g(5/2)2[7/2]3 R1c
6432.416(3)15541.962(7)6432.415(3)0.0015600 4f(5/2)2[3/2]°26g(5/2)2[5/2]31.5e+07D+R1cTW
6433.597(4)15539.109(10)6433.5944(22)0.003920 4f(5/2)2[11/2]°66g(5/2)2[11/2]62.7e+06D+R1cTW
6434.081(5)15537.941(12)6434.075(3)0.006610 4f(5/2)2[1/2]°06g(5/2)2[3/2]1 R1c
6434.799(3)15536.208(8)6434.7944(13)0.004610 4f(5/2)2[11/2]°56g(5/2)2[11/2]5 R1c
6437.596(3)15529.458(8)6437.5974(24)−0.002460 4f(5/2)2[3/2]°26g(5/2)2[3/2]26.7e+06D+R1cTW
6441.202(5)15520.764(12)6441.1920(9)0.0101200 4p32s21D2 R1c
6441.677(3)15519.618(8)6441.6790(8)−0.00213000 sp(3F)3135d(5/2)2[7/2]4 R1c
6441.7371(11)15519.474(3) 10000 4f(5/2)2[11/2]°66g(5/2)2[13/2]72.4e+07D+F_ReTW
6442.964(3)15516.519(7)6442.964(3)−0.0007600 4f(5/2)2[11/2]°56g(5/2)2[13/2]62.3e+07D+R1cTW
6443.587(3)15515.019(8)6443.587(3)0.0004900 4f(3/2)2[3/2]°26g(3/2)2[5/2]32.0e+07D+R1cTW
6445.692(20)15509.95(5)6445.673(3)0.0201400*6p(5/2)2[3/2]°29s(5/2)2[5/2]3 R1nc
6445.692(20)15509.95(5)6445.7022(9)−0.0101400*sp(3F)3135d(5/2)2[7/2]3 R1c
6447.627(5)15505.296(13)6447.632(3)−0.00561 sp(1G)3338d(5/2)2[9/2]4 R1c
6448.558(3)15503.059(8)6448.5593(8)−0.00220000 4p31s23P1 R1c
6449.63(3)15500.49(7)6449.6175(15)0.0130*4d(3/2)2[5/2]3sp(3P)333 R1c
6449.63(3)15500.49(7)6449.655(3)−0.0330*sp(3P)3526g(5/2)2[5/2]2 R1nc
6449.63(3)15500.49(7)6449.659(4)−0.0330*sp(3P)3526g(5/2)2[5/2]3 R1nc
6450.874(3)15497.493(8)6450.8738(17)−0.000610 4d(3/2)2[1/2]0sp(3F)131 R1c
6452.116(3)15494.508(7)6452.1161(24)0.0001300 4f(5/2)2[3/2]°16g(5/2)2[5/2]21.4e+07D+R1cTW
6454.161(3)15489.601(8) 910 4f(3/2)2[3/2]°16g(3/2)2[5/2]2 R1c
6454.894(9)15487.842(21)6454.895(3)−0.00130 6p(5/2)2[7/2]°48d(5/2)2[7/2]4 R1rc
6456.119(13)15484.90(3)6456.140(9)−0.02130 5s(3/2)2[3/2]1sp(3P)351 R1c
6457.187(3)15482.342(7)6457.1848(19)0.0022600 4f(5/2)2[7/2]°36g(5/2)2[9/2]4 R1c
6457.368(4)15481.908(10)6457.371(3)−0.0041600 4f(5/2)2[3/2]°16g(5/2)2[3/2]1 R1c
6458.263(9)15479.762(21)6458.259(3)0.00461 4f(3/2)2[9/2]°56g(3/2)2[9/2]5 R1c
6460.304(3)15474.870(8)6460.304(3)0.0011000 4f(5/2)2[7/2]°36g(5/2)2[7/2]3 R1c
6462.140(3)15470.475(8)6462.1413(20)−0.00260 4f(3/2)2[9/2]°46g(3/2)2[9/2]4 R1c
6462.70(10)15469.13(24)6462.6086(21)0.091000 4f(3/2)2[7/2]°37d(3/2)2[7/2]3 S36c
6465.342(15)15462.81(4)6465.3543(24)−0.01230*4f(5/2)2[7/2]°36g(5/2)2[5/2]2 R1c
6465.342(15)15462.81(4)6465.359(3)−0.01730*4f(5/2)2[7/2]°36g(5/2)2[5/2]3 R1c
6466.245(3)15460.653(7) 5600 4f(3/2)2[9/2]°56g(3/2)2[11/2]62.3e+07D+R1cTW
6470.1386(19)15451.350(5)6470.1383(19)0.00038600 4f(3/2)2[9/2]°46g(3/2)2[11/2]52.3e+07D+F_ReTW
6470.160(3)15451.298(7)6470.1668(8)−0.00615000 sp(3F)3336s(5/2)2[5/2]3 F_Re
6475.426(4)15438.734(9)6475.4257(24)−0.0001000 4f(5/2)2[5/2]°26g(5/2)2[5/2]27.5e+06D+R1cTW
6476.184(4)15436.925(9)6476.1819(19)0.0031000 4f(5/2)2[5/2]°36g(5/2)2[9/2]4 R1c
6477.868(9)15432.912(21)6477.860(3)0.008120 6p(5/2)2[7/2]°48d(5/2)2[9/2]5 R1c
6479.316(3)15429.463(7)6479.3164(21)−0.0004100 4f(5/2)2[5/2]°36g(5/2)2[7/2]41.5e+07D+R1cTW
6481.436(3)15424.418(7)6481.4350(12)0.00115000 5p(3/2)2[3/2]°25d(3/2)2[3/2]23.4e+07D+R1cTW
6484.404(3) m4f(5/2)2[5/2]°36g(5/2)2[5/2]36.5e+06D+R1ncTW
6484.417(3)15417.326(8)6484.4174(9)−0.0007800 5p(5/2)2[3/2]°15d(5/2)2[1/2]11.4e+07D+F_ReTW
6488.816(3)15406.875(7)6488.814(3)0.0022700 4f(3/2)2[5/2]°36g(3/2)2[7/2]41.9e+07D+R1cTW
6494.029(3)15394.507(6)6494.0320(6)−0.00318000 sp(3F)3135d(5/2)2[5/2]3 F_Re
6497.040(9)15387.372(21)6497.041(3)−0.00189 4f(3/2)2[5/2]°36g(3/2)2[5/2]3 R1c
6508.401(3)15360.514(7)6508.400(3)0.0012700 4f(3/2)2[5/2]°26g(3/2)2[7/2]31.7e+07D+R1cTW
6516.458(3)15341.522(8)6516.4637(12)−0.0066600 5p(3/2)2[3/2]°25d(3/2)2[3/2]1 R1c
6517.316(3)15339.501(7)6517.3166(21)−0.0006600 4f(5/2)2[7/2]°46g(5/2)2[9/2]51.7e+07D+R1cTW
6518.236(4)15337.337(9)6518.2366(12)−0.001150 4f(5/2)2[7/2]°46g(5/2)2[11/2]5 R1c
6520.497(3)15332.019(8)6520.4970(21)−0.0001000 4f(5/2)2[7/2]°46g(5/2)2[7/2]45.7e+06D+R1cTW
6521.270(6)15330.200(13)6521.2756(14)−0.005480 4p11s23P0 R1c
6523.820(3)15324.209(7)6523.820(3)−0.0004500 4f(3/2)2[7/2]°46g(3/2)2[9/2]52.1e+07D+R1cTW
6525.641(9)15319.932(21)6525.650(3)−0.00829 4f(5/2)2[7/2]°46g(5/2)2[5/2]3 R1c
6526.646(6)15317.574(13)6526.655(3)−0.00988 4f(3/2)2[7/2]°46g(3/2)2[7/2]4 R1c
6529.167(3)15311.658(8)6529.1668(21)0.0011000 4f(5/2)2[9/2]°56g(5/2)2[9/2]54.6e+06D+R1cTW
6530.082(3)15309.514(7)6530.0829(22)−0.00113000 4f(5/2)2[9/2]°56g(5/2)2[11/2]62.0e+07D+R1cTW
6536.679(9)15294.062(21)6536.6969(17)−0.01729 4d(3/2)2[5/2]2sp(3P)332 R1c
6541.637(3)15282.471(7)6541.6369(20)0.0003400 4f(3/2)2[7/2]°36g(3/2)2[9/2]41.9e+07D+R1cTW
6544.485(6)15275.822(14)6544.480(3)0.00458*4f(3/2)2[7/2]°36g(3/2)2[7/2]4 R1nc
6544.485(6)15275.822(14)6544.489(3)−0.00458*4f(3/2)2[7/2]°36g(3/2)2[7/2]3 R1c
6550.304(5)15262.251(12)6550.3097(9)−0.006150 5p(3/2)2[3/2]°25d(3/2)2[7/2]3 R1c
6551.286(3)15259.964(8)6551.2873(8)−0.0021900 4p31s23P2 R1c
6554.791(6)15251.804(13)6554.7923(9)−0.0025100 4p32s23P1 R1c
6556.193(6)15248.542(14)6556.206(3)−0.013430 4d(5/2)2[1/2]1sp(1D)331 R1c
6559.657(4)15240.489(9)6559.6523(8)0.00513000 sp(3F)3135d(5/2)2[9/2]44.9e+06D+R1cTW
6564.492(3)15229.264(8)6564.4941(8)−0.00210000 sp(3F)3135d(5/2)2[3/2]2 R1c
6567.949(6)15221.249(13)6567.9621(7)−0.013290 5s(5/2)2[5/2]25p(3/2)2[3/2]°25.1e+05CR1cB00
6576.147(6)15202.273(13)6576.1510(20)−0.0041000 4f(5/2)2[9/2]°46g(5/2)2[9/2]44.3e+06D+R1cTW
6577.0812(15)15200.114(3)6577.0816(12)−0.00035700 4f(5/2)2[9/2]°46g(5/2)2[11/2]51.5e+07D+F_ReTW
6579.376(9)15194.812(21)6579.386(3)−0.01057 4f(5/2)2[9/2]°46g(5/2)2[7/2]3 R1c
6592.896(9)15163.652(21)6592.900(3)−0.004120 5s(3/2)2[3/2]1sp(3P)352 R1c
6602.096(9)15142.522(21)6602.094(3)0.00357 6p(5/2)2[5/2]°38d(5/2)2[7/2]4 R1c
6603.527(9)15139.242(21)6603.523(4)0.00329 6p(3/2)2[5/2]°39s(3/2)2[3/2]2 R1c
6612.087(9)15119.642(21)6612.086(3)0.00157 6p(5/2)2[5/2]°38d(5/2)2[5/2]3 R1c
6624.291(3)15091.787(7)6624.2890(9)0.0028200 sp(3F)3125d(5/2)2[5/2]22.2e+07D+R1cTW
6626.243(3)15087.341(8)6626.2420(20)0.001710 5d(5/2)2[1/2]18p(5/2)2[3/2]°1 R1c
6631.476(3)15075.436(7)6631.4733(7)0.0033300 5p(5/2)2[7/2]°36s(3/2)2[3/2]2 R1c
6635.173(7)15067.037(17)6635.1692(18)0.00385 5d(5/2)2[1/2]16f(5/2)2[5/2]°2 R1c
6641.395(3)15052.920(7)6641.3938(9)0.0028000 sp(3F)3125d(5/2)2[7/2]32.6e+07D+R1cTW
6647.796(4)15038.427(10)6647.7986(18)−0.003850 5d(5/2)2[1/2]16f(5/2)2[3/2]°2 R1c
6648.764(5)15036.237(11)6648.7717(14)−0.0087300 5p(3/2)2[3/2]°25d(3/2)2[1/2]11.1e+07D+R1cTW
6651.323(4)15030.453(10)6651.3254(21)−0.003700 sp(3F)1336g(5/2)2[9/2]43.8e+06D+R1cTW
6654.635(9)15022.972(21)6654.635(3)−0.00056 sp(3F)1336g(5/2)2[7/2]3 R1c
6660.961(3)15008.705(7)6660.9606(8)0.0009200 4p32s23P2 R1c
6663.950(9)15001.972(21)6663.9466(6)0.004560 5s(5/2)2[5/2]35p(3/2)2[5/2]°3 R1c
6692.710(6)14937.507(14)6692.7144(7)−0.005700 sp(3F)3125d(5/2)2[5/2]3 R1c
6711.983(6)14894.615(12)6711.980(3)0.00356 5d(3/2)2[1/2]16f(3/2)2[5/2]°2 R1c
6716.700(3)14884.155(7)6716.7062(8)−0.0071300 5p(5/2)2[5/2]°26s(3/2)2[3/2]2 R1c
6717.687(6)14881.968(12)6717.687(4)−0.001280 5s(3/2)2[3/2]2sp(3P)352 R1c
6725.481(10)14864.722(21)6725.490(4)−0.01028 5d(3/2)2[1/2]16f(3/2)2[3/2]°1 R2c
6725.834(10)14863.942(21)6725.850(8)−0.01628 5s(3/2)2[3/2]2sp(3P)353 R1nc
6736.397(5)14840.633(10)6736.4201(7)−0.0236300 5p(5/2)2[3/2]°16s(3/2)2[3/2]2 R1c X
6739.599(3)14833.582(7)6739.598(3)0.002140 5d(3/2)2[1/2]16f(3/2)2[3/2]°27.4e+06D+R1cTW
6743.740(7)14824.474(16)6743.737(3)0.00356 5d(5/2)2[1/2]16f(5/2)2[1/2]°1 R2nc
6758.855(4)14791.323(8)6758.8577(10)−0.0036300 sp(3F)3125d(5/2)2[3/2]11.0e+07D+R1cTW
6760.142(5)14788.506(11)6760.1422(8)0.00056 5p(5/2)2[5/2]°26s(3/2)2[3/2]1 R1c
6765.794(10)14776.152(21)6765.7884(19)0.00628 sp(1G)3346g(5/2)2[11/2]5 R1c
6767.561(7)14772.294(16)6767.5789(9)−0.01828 sp(3F)3125d(5/2)2[3/2]2 R1c
6770.361(3)14766.186(7)6770.3604(10)0.0003100 4p11s23P2 R1c
6779.440(7)14746.410(15)6779.4453(18)−0.00528 5p(3/2)2[1/2]°15d(5/2)2[1/2]0 R1c
6780.114(4)14744.945(9)6780.1122(7)0.0024900 5p(5/2)2[3/2]°16s(3/2)2[3/2]1 R1c
6786.482(5)14731.110(11)6786.4808(7)0.00184 5s(5/2)2[5/2]35p(3/2)2[5/2]°2 R1c
6802.138(3)14697.204(7)6802.1387(19)−0.001220 5d(5/2)2[9/2]56f(5/2)2[9/2]°53.5e+06D+R1cTW
6806.215(3)14688.401(7)6806.2136(9)0.0014100 sp(3F)3326s(5/2)2[5/2]2 R1c
6809.6453(23)14681.001(5)6809.6436(8)0.00165200 5p(5/2)2[5/2]°36s(3/2)2[3/2]2 F_Re
6814.690(14)14670.13(3)6814.6913(22)−0.00128 5d(5/2)2[3/2]28p(5/2)2[3/2]°1 R1c
6821.060(5)14656.434(11)6821.0571(19)0.002140 5d(5/2)2[9/2]46f(5/2)2[9/2]°43.2e+06D+R1cTW
6822.342(8)14653.679(17)6822.3460(19)−0.00428 5d(5/2)2[9/2]46f(5/2)2[7/2]°4 R1c
6823.201(3)14651.833(7)6823.2010(23)0.0006400 5d(5/2)2[9/2]56f(5/2)2[11/2]°61.8e+07D+R1cTW
6824.750(4)14648.508(8)6824.7493(19)0.001700 5d(5/2)2[3/2]26f(5/2)2[5/2]°37.2e+06D+R1cTW
6830.531(3)14636.112(7)6830.5296(22)0.0011300 5d(3/2)2[7/2]36f(3/2)2[9/2]°41.8e+07D+R1cTW
6833.026(4)14630.766(9)6833.0244(19)0.002560 5d(5/2)2[3/2]16f(5/2)2[5/2]°28.1e+06D+R1cTW
6837.491(4)14621.212(8)6837.4936(18)−0.002720 5d(5/2)2[3/2]26f(5/2)2[3/2]°29.e+06D+R1cTW
6844.156(3)14606.974(7)6844.1542(20)0.0023200 5d(5/2)2[9/2]46f(5/2)2[11/2]°51.8e+07D+R1cTW
6846.104(20)14602.82(4)6846.065(3)0.039880 sp(3F)3146s(5/2)2[5/2]3 R1c
6847.112(7)14600.669(14)6847.112(3)−0.000170 5d(5/2)2[3/2]16f(5/2)2[3/2]°1 R1c
6849.991(6)14594.532(13)6849.988(4)0.00356 4d(5/2)2[1/2]1sp(1D)330 R1c
6852.428(7)14589.342(14)6852.432(3)−0.00484 5d(3/2)2[3/2]16f(3/2)2[5/2]°2 R1c
6863.061(3)14566.739(7)6863.0599(23)0.0012100 5d(3/2)2[7/2]46f(3/2)2[9/2]°51.8e+07D+R1cTW
6867.88(20)14556.5(4)6868.184(4)−0.30470 4d(5/2)2[5/2]2sp(3P)352 S36c
6868.790(3)14554.589(7)6868.7864(9)0.0042900 sp(3F)3326s(5/2)2[5/2]3 R1c
6872.230(3)14547.303(7)6872.2293(10)0.0013200 4p13s21D2 R1c
6879.403(3)14532.136(7)6879.4043(7)−0.0012500 5s(5/2)2[5/2]25p(3/2)2[1/2]°15.5e+06CR1cB00
6893.496(6)14502.427(12)6893.4896(18)0.006220 5d(5/2)2[5/2]36f(5/2)2[9/2]°4 R1c
6894.810(4)14499.663(9)6894.8061(18)0.004700 5d(5/2)2[5/2]36f(5/2)2[7/2]°41.0e+07D+R1cTW
6902.617(4)14483.263(9)6902.6139(19)0.003560 5d(5/2)2[5/2]36f(5/2)2[5/2]°38.0e+06D+R1cTW
6915.653(10)14455.962(21)6915.6509(18)0.00256 5d(5/2)2[5/2]36f(5/2)2[3/2]°2 R1c
6928.602(6)14428.946(12)6928.592(3)0.009340 5d(3/2)2[3/2]26f(3/2)2[5/2]°31.1e+07D+R1cTW
6937.552(4)14410.331(8)6937.5472(7)0.0052100 5s(5/2)2[5/2]25p(3/2)2[5/2]°23.9e+06CR1cB00
6939.099(7)14407.119(14)6939.098(3)0.001280 5d(5/2)2[7/2]36f(5/2)2[7/2]°34.8e+06D+R1cTW
6948.795(7)14387.015(15)6948.7964(20)−0.0012000 5d(5/2)2[7/2]36f(5/2)2[9/2]°41.1e+07D+R1cTW
6950.139(6)14384.234(13)6950.1341(20)0.0051700 5d(5/2)2[7/2]36f(5/2)2[7/2]°43.1e+06D+R1cTW
6952.870(4)14378.583(7)6952.8664(20)0.0044200 5d(5/2)2[7/2]46f(5/2)2[9/2]°51.4e+07D+R1cTW
6953.480(10)14377.322(21)6953.4782(20)0.002110 5d(5/2)2[7/2]46f(5/2)2[9/2]°4 R1c
6953.930(6)14376.391(13)6953.914(3)0.0162100 5d(3/2)2[5/2]36f(3/2)2[7/2]°41.5e+07D+R1cTW
6954.820(10)14374.552(21)6954.8176(19)0.002230 5d(5/2)2[7/2]46f(5/2)2[7/2]°44.4e+06D+R1cTW
6957.884(10)14368.222(20)6957.869(3)0.0151800*5d(5/2)2[5/2]26f(5/2)2[7/2]°31.1e+07D+R1cTW
6957.884(10)14368.222(20)6957.876(4)0.0081800*sp(1G)3356g(5/2)2[13/2]6 R1c
6957.884(10)14368.222(20)6957.876(3)0.0081800*5d(3/2)2[5/2]36f(3/2)2[5/2]°2 R1c
6963.433(10)14356.772(21)6963.427(3)0.006230 5d(3/2)2[5/2]26f(3/2)2[7/2]°31.3e+07D+R1cTW
6968.846(10)14345.622(21)6968.847(3)−0.00257 5d(3/2)2[5/2]26f(3/2)2[5/2]°2 R1c
6976.305(10)14330.282(21)6976.2990(20)0.006230 5d(5/2)2[5/2]26f(5/2)2[5/2]°25.6e+06D+R1cTW
6977.571(4)14327.683(8)6977.5641(10)0.0074300 5p(3/2)2[5/2]°25d(5/2)2[5/2]2 R1c
6986.548(8)14309.273(17)6986.5269(20)0.0212100 5p(3/2)2[3/2]°15d(5/2)2[1/2]0 R1c
6996.556(5)14288.805(9)6996.5446(10)0.0121400 5p(3/2)2[5/2]°25d(5/2)2[7/2]3 R1c
7022.859(4)14235.289(7)7022.8519(9)0.0072800 sp(3F)3136s(3/2)2[3/2]2 R1c
7037.388(4)14205.899(8)7037.3853(10)0.0032900 5p(3/2)2[1/2]°15d(5/2)2[5/2]2 R1c
7083.772(6)14112.882(12)7083.7743(13)−0.003730 5p(3/2)2[1/2]°05d(5/2)2[1/2]1 R1c
7123.112(11)14034.939(21)7123.106(3)0.00659*6s(5/2)2[5/2]27p(5/2)2[5/2]°3 R1c
7123.112(11)14034.939(21)7123.1061(21)0.00659*sp(3F)1355g(3/2)2[11/2]6 R1c
7123.112(11)14034.939(21)7123.1212(21)−0.01059*sp(3F)1355g(3/2)2[11/2]5 R1c
7127.032(8)14027.218(15)7127.0305(11)0.002150 5p(3/2)2[5/2]°25d(5/2)2[3/2]1 R1c
7139.649(5)14002.431(10)7139.653(3)−0.0041500 6s(5/2)2[5/2]37p(5/2)2[7/2]°4 R1c
7157.757(5)13967.006(10)7157.7517(8)0.0061500 5s(5/2)2[5/2]3sp(3F)3125.2e+05CR1cB00
7182.106(7)13919.655(14)7182.104(5)0.00260 6s(5/2)2[5/2]27p(5/2)2[5/2]°2 R1c
7189.458(4)13905.422(7)7189.4534(12)0.0041300 5p(3/2)2[1/2]°15d(5/2)2[3/2]1 R1c
7194.900(3)13894.903(6)7194.8933(10)0.0076800 4p12s21D2 F_Re
7255.7937(20)13778.293(4)7255.7899(9)0.00386400 sp(3F)3126s(3/2)2[3/2]26.5e+06D+F_ReTW
7271.507(6)13748.519(11)7271.4991(10)0.008460 5p(3/2)2[5/2]°35d(5/2)2[9/2]4 R1c
7306.511(4)13682.653(7)7306.5042(9)0.0073700 sp(3F)3126s(3/2)2[3/2]1 R1c
7326.007(4)13646.242(7)7326.0039(8)0.0036900 5s(5/2)2[5/2]2sp(3F)3121.80e+07BR1cB00
7331.6940(19)13635.656(4)7331.6941(7)−0.00015100 5p(5/2)2[3/2]°26s(5/2)2[5/2]2 F_Re
7382.275(3)13542.229(6)7382.2720(14)0.0033500 4d(3/2)2[1/2]04f(5/2)2[3/2]°11.6e+07D+F_ReTW
7396.156(6)13516.815(11)7396.1523(12)0.0031900 5p(3/2)2[3/2]°25d(5/2)2[5/2]2 R1c
7399.8836(16)13510.005(3)7399.8787(7)0.004914000 5s(5/2)2[5/2]3sp(3F)3132.57e+07BF_ReB00
7404.3561(11)13501.8442(20)7404.3532(6)0.002955000 5p(5/2)2[3/2]°26s(5/2)2[5/2]32.0e+07D+F_ReTWL
7417.483(5)13477.950(9)7417.4819(12)0.0012400 5p(3/2)2[3/2]°25d(5/2)2[7/2]3 R1c
7420.556(4)13472.368(7)7420.5668(9)−0.0104100 5s(3/2)2[3/2]15p(3/2)2[3/2]°23.1e+06CR1cB00
7422.602(5)13468.656(9)7422.5904(11)0.011790 4p33s21D2 R1c
7434.155(4)13447.725(7)7434.1525(15)0.0023700 4d(3/2)2[1/2]04f(5/2)2[1/2]°11.3e+07D+R1cTW
7438.1504(13)13440.5007(24)7438.1505(10)−0.000111000 5p(3/2)2[1/2]°06s(3/2)2[3/2]11.0e+07D+F_ReTW
7481.554(8)13362.528(15)7481.5552(10)−0.001190 5p(3/2)2[3/2]°25d(5/2)2[5/2]3 R1c
7493.289(8)13341.602(14)7493.2883(20)0.000130 6p(5/2)2[7/2]°37d(5/2)2[7/2]33.0e+06D+R1cTW
7562.0141(17)13220.350(3)7562.0167(9)−0.002616000 5s(3/2)2[3/2]15p(3/2)2[3/2]°13.8e+07BF_ReB00
7564.324(8)13216.314(14)7564.3057(14)0.01864 5p(3/2)2[3/2]°25d(5/2)2[3/2]1 R1c
7575.242(7)13197.266(12)7575.2309(12)0.011220 5p(3/2)2[3/2]°25d(5/2)2[3/2]2 R1c
7579.023(3)13190.681(5)7579.0283(10)−0.00520000 5s(3/2)2[3/2]25p(3/2)2[3/2]°24.1e+07BF_ReB00
7579.850(5)13189.242(9)7579.8494(9)0.0018400 5s(5/2)2[5/2]2sp(3F)3131.15e+07BF_ReB00
7583.273(8)13183.289(13)7583.339(4)−0.06664?4d(5/2)2[1/2]0sp(1D)331 R1c X
7652.3326(7)13064.3147(12)7652.3337(5)−0.001126000 5s(5/2)2[5/2]35p(5/2)2[5/2]°32.35e+07BF_ReB00
7664.6451(12)13043.3283(20)7664.6465(7)−0.001452000 5p(5/2)2[7/2]°36s(5/2)2[5/2]23.5e+07D+F_ReTWL
7681.787(4)13014.223(7)7681.7968(10)−0.010570 5p(3/2)2[5/2]°26s(3/2)2[3/2]2 R1c
7712.418(6)12962.535(9)7712.421(3)−0.003640 6p(5/2)2[3/2]°27d(5/2)2[5/2]33.7e+06D+R1cTW
7726.637(4)12938.681(6)7726.6439(10)−0.0079000 5s(3/2)2[3/2]25p(3/2)2[3/2]°11.70e+07BF_ReB00
7738.6656(12)12918.5693(21)7738.6644(9)0.001230000 5p(3/2)2[5/2]°26s(3/2)2[3/2]14.5e+07D+F_ReTWL
7739.499(8)12917.179(14)7739.505(4)−0.0061600 6p(5/2)2[3/2]°27d(5/2)2[3/2]27.1e+06D+R1cTW
7744.0889(18)12909.522(3)7744.0905(8)−0.00167800 5p(5/2)2[7/2]°36s(5/2)2[5/2]3 F_Re
7754.3688(20)12892.408(3)7754.3653(10)0.003511000 5p(3/2)2[1/2]°16s(3/2)2[3/2]29.e+06D+F_ReTW
7766.516(9)12872.244(16)7766.511(7)0.00632 6p(3/2)2[1/2]°17d(3/2)2[1/2]0 R1c
7773.196(7)12861.182(12)7773.1992(9)−0.0033200 5s(5/2)2[5/2]35p(5/2)2[5/2]°21.08e+06CR1cB00
7778.7353(13)12852.0236(22)7778.7347(8)0.000625000 5p(5/2)2[5/2]°26s(5/2)2[5/2]21.3e+07D+F_ReTWL
7805.1886(13)12808.4659(21)7805.1878(7)0.000826000 5p(5/2)2[3/2]°16s(5/2)2[5/2]21.6e+07D+F_ReTWL
7807.6534(12)12804.4224(20)7807.6526(7)0.000782000 5p(5/2)2[7/2]°46s(5/2)2[5/2]33.6e+07C+F_ReTWL
7812.3182(19)12796.777(3)7812.3164(10)0.001810000 5p(3/2)2[1/2]°16s(3/2)2[3/2]11.2e+07D+F_ReTW
7820.577(4)12783.264(6)7820.5768(10)−0.0007300 5s(3/2)2[3/2]15p(3/2)2[1/2]°11.51e+07BF_ReB00
7825.6528(12)12774.9718(20)7825.6530(7)−0.000259000 5s(5/2)2[5/2]35p(5/2)2[7/2]°45.2e+07BF_ReB00L
7845.0792(12)12743.3378(20)7845.0795(9)−0.000324000 5p(3/2)2[5/2]°36s(3/2)2[3/2]23.8e+07D+F_ReTWL
7853.984(9)12728.890(15)7853.980(4)0.004190 6p(5/2)2[5/2]°27d(5/2)2[5/2]2 R1c
7860.576(5)12718.216(7)7860.5740(10)0.0025700 5p(5/2)2[5/2]°26s(5/2)2[5/2]3 R1c
7862.652(9)12714.857(14)7862.654(3)−0.002250 6p(5/2)2[5/2]°27d(5/2)2[7/2]32.9e+06D+R1cTW
7886.076(9)12677.091(15)7886.097(5)−0.02161 6p(3/2)2[1/2]°17d(3/2)2[1/2]1 R1c
7890.568(4)12669.874(6)7890.5666(8)0.0013500 5s(5/2)2[5/2]35p(5/2)2[7/2]°35.8e+06BF_ReB00
7895.8050(13)12661.4700(22)7895.8039(8)0.001121000 5s(3/2)2[3/2]15p(3/2)2[5/2]°24.3e+07BF_ReB00L
7902.5482(13)12650.6660(21)7902.5499(8)−0.001725000 5s(3/2)2[3/2]25p(3/2)2[5/2]°34.9e+07BF_ReB00L
7907.351(10)12642.983(16)7907.364(5)−0.01461 6p(5/2)2[5/2]°27d(5/2)2[3/2]1 R1c
7944.4368(6)12583.9633(10)7944.4365(5)0.000317000 5s(5/2)2[5/2]25p(5/2)2[3/2]°14.7e+07BF_ReB00L
7967.067(5)12548.220(8)7967.065(4)0.0022100 6p(3/2)2[5/2]°37d(3/2)2[7/2]41.0e+07D+R1cTW
7972.031(5)12540.406(7)7972.0306(10)0.0007800 5s(5/2)2[5/2]25p(5/2)2[5/2]°22.9e+07BR1cB00
7981.574(9)12525.413(15)7981.4451(23)0.12859?4f(5/2)2[7/2]°36d(3/2)2[7/2]4 R1c X
7988.1598(13)12515.0857(20)7988.1620(7)−0.002247000 5p(5/2)2[5/2]°36s(5/2)2[5/2]31.7e+07D+F_ReTWL
7996.793(3)12501.575(5)7996.7854(10)0.0079000 5s(3/2)2[3/2]25p(3/2)2[1/2]°13.2e+07BF_ReB00
8006.515(5)12486.394(8)8006.525(4)−0.009440 6p(3/2)2[5/2]°27d(3/2)2[7/2]35.9e+06D+R2ncTW
8026.479(3)12455.338(5)8026.4828(12)−0.0047100 5p(3/2)2[3/2]°16s(3/2)2[3/2]28.2e+06D+F_ReTW
8042.489(7)12430.544(11)8042.494(4)−0.005230 6p(5/2)2[3/2]°17d(5/2)2[3/2]1 R1c
8053.200(6) m6p(3/2)2[5/2]°27d(3/2)2[1/2]1 R1c
8053.339(16)12413.796(24)8053.358(4)−0.019230 sp(1G)3337d(5/2)2[7/2]42.3e+06D+R1cTW
8054.227(7)12412.428(11)8054.239(3)−0.012110 sp(1G)3337d(5/2)2[7/2]3 R1c
8074.999(7)12380.498(11)8074.999(3)0.000420 6p(5/2)2[7/2]°38s(5/2)2[5/2]23.5e+06D+R1cTW
8075.456(7)12379.797(11)8075.4576(10)−0.0012300 5s(3/2)2[3/2]25p(3/2)2[5/2]°22.8e+05CR1cB00
8088.5846(15)12359.7038(23)8088.5888(11)−0.004213000 5p(3/2)2[3/2]°16s(3/2)2[3/2]11.6e+07D+F_ReTW
8095.5267(14)12349.1051(21)8095.5268(8)−0.000126000 5s(5/2)2[5/2]25p(5/2)2[7/2]°33.7e+07BF_ReB00
8098.519(7)12344.542(11)8098.5396(14)−0.020550 sp(3F)1345g(3/2)2[9/2]5 R1c
8100.868(7)12340.963(11)8100.883(3)−0.01583 6p(5/2)2[7/2]°38s(5/2)2[5/2]3 R1c
8103.352(7)12337.180(11)8103.353(4)−0.001550 sp(1G)3337d(5/2)2[9/2]42.7e+06D+R1cTW
8154.003(6)12260.545(9)8154.012(4)−0.0092000 6p(5/2)2[7/2]°47d(5/2)2[9/2]55.4e+06D+R1cTW
8192.221(6)12203.347(9)8192.2333(13)−0.01210700 5p(3/2)2[3/2]°26s(3/2)2[3/2]22.0e+07D+F_ReTW
8192.330(3)12203.185(4)8192.3279(10)0.0023300 sp(3F)3136s(5/2)2[5/2]25.9e+06D+F_ReTW
8201.898(7)12188.949(11)8201.908(4)−0.01052 6p(3/2)2[3/2]°27d(3/2)2[7/2]3 R1c
8235.272(4)12139.553(6)8235.2788(14)−0.0075600 5s(3/2)2[3/2]15p(3/2)2[1/2]°04.6e+07BF_ReB00
8256.944(6)12107.691(9)8256.9412(13)0.0023000 5p(3/2)2[3/2]°26s(3/2)2[3/2]1 F_Re
8277.5525(14)12077.5460(21)8277.5527(8)−0.000320000 5s(5/2)2[5/2]35p(5/2)2[3/2]°24.3e+07BF_ReB00
8283.1521(14)12069.3813(21)8283.1520(9)0.000023000 sp(3F)3136s(5/2)2[5/2]3 F_Re
8298.461(7)12047.116(11)8298.465(3)−0.00472 sp(3F)1327d(5/2)2[5/2]2 R1c
8306.475(5)12035.493(7)8306.4866(14)−0.011890 4p32s21D2 R1c
8308.148(7)12033.070(11)8308.150(3)−0.002120 sp(3F)1327d(5/2)2[7/2]3 R1c
8328.395(6)12003.817(8)8328.393(3)0.001470 6p(5/2)2[5/2]°37d(5/2)2[7/2]43.1e+06D+R1cTW
8333.074(7)11997.077(10)8333.072(4)0.001470 6p(5/2)2[3/2]°28s(5/2)2[5/2]32.3e+06D+R1cTW
8333.617(8)11996.294(12)8333.6418(20)−0.024580 sp(3F)1355g(5/2)2[9/2]5 R1c
8336.333(5)11992.386(8)8336.3323(20)0.0013500 sp(3F)1355g(5/2)2[11/2]61.4e+06D+R1cTW
8353.837(7)11967.259(10)8353.843(3)−0.006230 6p(5/2)2[5/2]°37d(5/2)2[5/2]33.1e+06D+R1cTW
8381.868(7)11927.237(11)8381.872(4)−0.00445 6p(5/2)2[5/2]°37d(5/2)2[9/2]4 R1c
8385.624(7)11921.895(11)8385.629(4)−0.00567 6p(5/2)2[5/2]°37d(5/2)2[3/2]2 R1c
8394.566(8)11909.195(11)8394.5745(12)−0.008110 4f(5/2)2[9/2]°45g(3/2)2[9/2]5 R1c
8402.897(7)11897.388(9)8402.9047(11)−0.0071600 5s(3/2)2[3/2]1sp(3F)3123.9e+06CR1cB00
8450.062(8)11830.982(11)8450.078(3)−0.01663 sp(3F)1326d(3/2)2[5/2]3 R1c
8477.298(5)11792.971(7)8477.3077(17)−0.0093900 4p11s21D2 R1c
8503.394(5)11756.780(7)8503.3976(9)−0.0043600 5s(5/2)2[5/2]25p(5/2)2[3/2]°21.6e+06CR1cB00
8511.0626(20)11746.187(3)8511.0647(10)−0.002111000 sp(3F)3126s(5/2)2[5/2]21.0e+07D+F_ReTW
8535.196(11)11712.975(15)8535.2020(23)−0.00677 sp(3P)3315g(5/2)2[5/2]2 R1c
8574.093(11)11659.838(15)8574.083(3)0.010110 sp(3F)1346d(5/2)2[9/2]5 R1c
8606.681(10)11615.690(13)8606.6732(12)0.008690 5s(3/2)2[3/2]2sp(3F)3127.9e+06BR1cB00
8609.132(5)11612.384(7)8609.1359(12)−0.0041100 sp(3F)3126s(5/2)2[5/2]3 R1c
8729.820(9)11451.845(12)8729.822(3)−0.002160 sp(1G)3345g(3/2)2[11/2]5 R1c
8730.233(7)11451.303(9)8730.232(3)0.002110 sp(1G)3338s(5/2)2[5/2]2 R1c
8797.094(7)11364.269(9)8797.0968(22)−0.002380 sp(3F)1345g(5/2)2[9/2]51.6e+06D+R1cTW
8800.120(8)11360.362(10)8800.122(3)−0.00274 sp(3F)1345g(5/2)2[11/2]5 R1c
8810.397(8)11347.110(10)8810.397(4)0.000290 6p(5/2)2[7/2]°48s(5/2)2[5/2]32.4e+06D+R1cTW
8937.241(8)11186.064(10)8937.281(3)−0.03913 5d(5/2)2[5/2]35f(3/2)2[7/2]°4 R1c X
8959.159(9)11158.698(11)8959.1604(12)−0.0011300 5s(3/2)2[3/2]2sp(3F)3131.6e+05CR1cB00
8967.150(9)11148.754(11)8967.143(4)0.007250 sp(1G)3326d(3/2)2[1/2]1 R1rc
8991.446(9)11118.629(11)8991.447(7)−0.00112 sp(3P)3116d(3/2)2[1/2]1 R2nc
9001.419(8)11106.311(9)9001.428(5)−0.00925 6p(3/2)2[3/2]°18s(3/2)2[3/2]2 R1c
9005.757(8)11100.961(9)9005.754(4)0.0034300 sp(3F)1335g(3/2)2[9/2]42.5e+06D+R1cTW
9015.187(9)11089.349(11)9015.144(4)0.043310 sp(3F)1335g(3/2)2[7/2]4 R1rc X
9029.347(8)11071.959(9)9029.343(4)0.003300 sp(3F)1328s(5/2)2[5/2]2 R1c
9036.147(8)11063.627(9)9036.132(4)0.015600 sp(1G)3355g(3/2)2[11/2]69.e+05D+R1rcTW
9067.974(8)11024.796(10)9067.9717(16)0.002180 5s(5/2)2[5/2]3sp(3F)3323.9e+05CR1cB00
9086.933(9)11001.793(11)9086.928(4)0.0051200 6p(5/2)2[5/2]°38s(5/2)2[5/2]31.7e+06D+R1cTW
9089.413(9)10998.792(11)9089.4094(24)0.00346 5d(5/2)2[7/2]35f(3/2)2[9/2]°4 R1c
9093.704(9)10993.602(11)9093.632(4)0.07212 sp(3P)3126d(3/2)2[5/2]2 R1c X
9096.064(9)10990.749(11)9096.054(6)0.01181 5d(5/2)2[1/2]17p(5/2)2[3/2]°2 R1c
9097.529(9)10988.980(11)9097.525(3)0.004460 sp(3P)3327s(5/2)2[5/2]3 R1c
9098.493(9)10987.815(11)9098.489(3)0.00569 5d(5/2)2[5/2]25f(3/2)2[5/2]°3 R1c
9101.459(12)10984.235(15)9101.4285(22)0.03023 5d(5/2)2[7/2]45f(3/2)2[9/2]°5 R1c
9103.234(6)10982.093(8)9103.2366(12)−0.0032600 5p(3/2)2[5/2]°26s(5/2)2[5/2]2 R1c
9107.895(9)10976.473(11)9107.878(6)0.016230 5s(5/2)2[5/2]3sp(3F)3149.1e+04CR1cB00
9115.700(9)10967.075(11)9115.643(10)0.05746?5f(5/2)2[11/2]°59d(5/2)2[9/2]4 R1c X
9125.941(9)10954.767(11)9125.932(4)0.009340 sp(1G)3325g(3/2)2[7/2]3 R2nc
9154.181(18)10920.973(21)9154.160(4)0.021170 sp(1G)3325g(3/2)2[5/2]3 R2c
9158.409(9)10915.931(11)9158.393(4)0.016450 sp(3P)3315g(5/2)2[3/2]1 R1c
9179.306(12)10891.081(14)9179.319(7)−0.014610 5d(3/2)2[1/2]17p(3/2)2[1/2]°1 R2nc
9205.3214(22)10860.301(3)9205.3242(12)−0.00285800 5p(3/2)2[1/2]°16s(5/2)2[5/2]2 F_Re
9219.491(10)10843.610(12)9219.466(5)0.02532 5d(5/2)2[5/2]37p(5/2)2[5/2]°3 R1c
9226.742(10)10835.088(12)9226.7371(12)0.005730 5s(3/2)2[3/2]15p(5/2)2[3/2]°11.3e+06CR1cB00
9230.567(11)10830.599(13)9230.577(3)−0.010370 sp(3P)3337s(5/2)2[5/2]3 R1c
9234.272(8)10826.253(10)9234.258(3)0.0141300 sp(3F)1336d(5/2)2[7/2]4 R1c
9277.399(12)10775.926(14)9277.400(9)−0.00011?5f(5/2)2[9/2]°58g(5/2)2[11/2]64.6e+06D+R1ncTW
9296.634(12)10753.631(14)9296.580(6)0.05421 sp(1D)3325d(3/2)2[5/2]3 R1c X
9312.387(13)10735.440(15)9312.450(9)−0.06421 5f(5/2)2[9/2]°57g(3/2)2[11/2]5 R1c X
9317.944(9)10729.037(10)9317.943(4)0.002260 sp(3F)1316d(3/2)2[5/2]2 R1c
9324.302(9)10721.722(10)9324.3128(20)−0.01121 sp(3F)1346d(5/2)2[7/2]3 R1c
9331.893(6)10713.000(7)9331.8965(12)−0.0042400 5s(3/2)2[3/2]25p(5/2)2[5/2]°31.2e+06CR1cB00
9339.711(8)10704.032(9)9339.7151(17)−0.004360 5s(5/2)2[5/2]2sp(3F)3326.8e+05CR1cB00
9364.118(14)10676.133(16)9364.046(7)0.07210 4d(3/2)2[7/2]4sp(1D)333 R1c X
9374.435(19)10664.383(21)9374.4412(23)−0.00610 4f(5/2)2[3/2]°26d(5/2)2[5/2]2 R1c
9391.049(12)10645.517(14)9390.9259(21)0.12321?4f(5/2)2[3/2]°26d(5/2)2[7/2]3 R1c X
9415.060(9)10618.368(10)9415.044(6)0.01621 4d(3/2)2[7/2]3sp(1D)332 R1c
9424.164(12)10608.110(14)9424.151(4)0.013100 sp(3F)1316d(3/2)2[3/2]1 R1c
9444.862(10)10584.863(11)9444.858(10)0.00510 4d(3/2)2[5/2]2sp(1D)333 R1c
9451.495(11)10577.435(12)9451.5130(13)−0.0181400 5p(3/2)2[5/2]°36s(5/2)2[5/2]3 R1c
9458.336(9)10569.785(10)9458.335(3)0.00072 4f(5/2)2[7/2]°36d(5/2)2[7/2]4 R1c
9459.889(10)10568.049(11)9459.895(4)−0.00531 sp(3F)1346d(5/2)2[9/2]5 R1c
9460.791(9)10567.042(10)9460.790(5)0.0011000 sp(3P)3305g(5/2)2[3/2]1 R1c
9461.294(10)10566.480(11)9461.3089(22)−0.01510 4f(5/2)2[7/2]°36d(5/2)2[7/2]3 R1c
9473.011(12)10553.411(13)9473.0050(12)0.0061300 5s(3/2)2[3/2]25p(5/2)2[3/2]°11.13e+06CR1cB00
9474.119(10)10552.176(11)9474.106(5)0.01310 5d(5/2)2[7/2]47p(5/2)2[7/2]°4 R1c
9485.256(10)10539.787(11)9485.2726(23)−0.01721 4f(5/2)2[5/2]°36d(5/2)2[5/2]2 R1c
9492.663(19)10531.563(21)9492.653(4)0.01010 4f(3/2)2[3/2]°16d(3/2)2[3/2]2 R1c
9493.808(21)10530.293(23)9493.987(16)−0.17910?sp(3P)3536s(3/2)2[3/2]2 R2c X
9500.248(10)10523.154(11)9500.262(3)−0.01452 sp(3P)3317s(5/2)2[5/2]2 R1c
9502.093(10)10521.111(11)9502.1498(21)−0.05710?4f(5/2)2[5/2]°36d(5/2)2[7/2]3 R1c X
9504.184(9)10518.796(10)9504.220(4)−0.035360 sp(3P)3125g(3/2)2[7/2]3 R1c X
9505.598(10)10517.232(11)9505.605(3)−0.00810 4f(5/2)2[3/2]°26d(5/2)2[3/2]1 R1c
9510.299(19)10512.033(21)9510.298(7)0.00142 sp(3P)3526s(3/2)2[3/2]2 R1c
9512.262(8)10509.864(9)9512.2653(15)−0.0042900 5s(3/2)2[3/2]25p(5/2)2[5/2]°21.3e+06CR1cB00
9515.588(11)10506.190(12)9515.595(3)−0.007210 4f(5/2)2[7/2]°36d(5/2)2[5/2]3 R1c
9527.379(10)10493.188(11)9527.376(4)0.00331 4f(3/2)2[3/2]°16d(3/2)2[3/2]1 R1c
9530.897(10)10489.315(11)9530.905(3)−0.008160 4f(5/2)2[11/2]°56d(5/2)2[9/2]4 R1c
9546.928(10)10471.701(11)9546.928(3)−0.000210 4f(5/2)2[11/2]°66d(5/2)2[9/2]5 R1c
9548.691(10)10469.768(11)9548.702(3)−0.01121 4f(5/2)2[3/2]°16d(5/2)2[3/2]1 R1c
9565.600(10)10451.261(11)9565.623(4)−0.02453 4f(3/2)2[9/2]°56d(3/2)2[7/2]4 R1c
9585.611(10)10429.442(11)9585.628(3)−0.01732 4f(3/2)2[5/2]°36d(3/2)2[3/2]2 R1c
9597.666(20)10416.343(21)9597.614(7)0.05211 sp(3P)3526s(3/2)2[3/2]1 R1c
9599.817(10)10414.009(11)9599.843(3)−0.02611 4f(5/2)2[5/2]°26d(5/2)2[3/2]1 R1c
9602.377(10)10411.232(11)9602.374(3)0.00322 4f(3/2)2[7/2]°46d(3/2)2[5/2]3 R1c
9605.15(9)10408.22(10)9605.075(6)0.0854*5d(5/2)2[5/2]37p(5/2)2[3/2]°2 R1c
9605.15(9)10408.22(10)9605.193(4)−0.0454*4f(3/2)2[9/2]°46d(3/2)2[7/2]3 R1c
9610.896(10)10402.004(11)9610.884(5)0.012430 5d(5/2)2[1/2]05f(3/2)2[3/2]°15.9e+06D+R1cTW
9613.596(20)10399.083(21)9613.594(3)0.00265 4f(5/2)2[9/2]°56d(5/2)2[7/2]4 R1c
9630.420(10)10380.916(11)9630.428(3)−0.00911 4f(3/2)2[7/2]°36d(3/2)2[5/2]2 R1c
9630.969(11)10380.324(11)9631.023(3)−0.05411 4f(5/2)2[5/2]°36d(5/2)2[3/2]2 R1c X
9637.149(11)10373.668(12)9637.148(3)0.0001100 sp(3F)1335g(5/2)2[9/2]4 R1c
9646.751(10)10363.342(11)9646.770(3)−0.01922 4f(5/2)2[7/2]°46d(5/2)2[5/2]3 R1c
9649.361(10)10360.539(11)9649.378(3)−0.017110*sp(3F)1335g(5/2)2[7/2]4 R1c X
9649.361(10)10360.539(11)9649.399(3)−0.038110*sp(3F)1335g(5/2)2[7/2]3 R1nc X
9651.107(10)10358.665(11)9651.115(4)−0.00822 4f(3/2)2[3/2]°26d(3/2)2[1/2]1 R1c
9657.363(11)10351.954(11)9657.369(4)−0.00522 4f(5/2)2[1/2]°16d(5/2)2[1/2]1 R1c
9664.119(10)10344.717(11)9664.140(3)−0.02011 4f(3/2)2[5/2]°26d(3/2)2[3/2]1 R1c
9670.167(10)10338.248(11)9670.172(8)−0.00611 6d(5/2)2[9/2]48f(5/2)2[11/2]°53.5e+06D+R1cTW
9688.602(8)10318.577(8)9688.6189(13)−0.0171600 5s(3/2)2[3/2]25p(5/2)2[7/2]°32.5e+05CR1cB00
9715.855(20)10289.633(21)9715.789(3)0.06612 4f(5/2)2[9/2]°46d(5/2)2[7/2]4 R1c X
9718.927(10)10286.381(11)9718.9263(24)0.00023 4f(5/2)2[9/2]°46d(5/2)2[7/2]3 R1c
9732.121(21)10272.435(22)9732.1007(17)0.0211100*sp(3F)1345g(5/2)2[9/2]5 R1nc
9732.148(13)10272.407(13)9732.1264(21)0.0221100*sp(3F)1345g(5/2)2[9/2]42.1e+06D+F_ReTW
9734.473(10)10269.953(11)9734.488(3)−0.01524 4f(5/2)2[7/2]°46d(5/2)2[9/2]5 R1c
9735.802(4)10268.551(4)9735.8031(20)−0.0016700 sp(3F)1345g(5/2)2[11/2]59.e+06D+F_ReTW
9781.688(5) msp(3F)1315g(3/2)2[5/2]2 R1c
9781.844(13)10220.219(13)9781.880(4)−0.037120 4f(3/2)2[7/2]°36d(3/2)2[7/2]3 R1c X
9792.465(10)10209.134(11)9792.4709(19)−0.00650 4f(5/2)2[1/2]°15g(5/2)2[5/2]2 R1c
9794.085(10)10207.445(10)9794.067(3)0.01838 sp(3P)3327s(5/2)2[5/2]2 R1c
9813.2038(22)10187.5583(23)9813.2047(20)−0.00098600 4f(5/2)2[1/2]°15g(5/2)2[3/2]24.1e+07C+F_ReTW
9813.334(8)10187.423(8)9813.325(4)0.0092600 4f(5/2)2[1/2]°15g(5/2)2[3/2]11.7e+07D+R1cTW
9817.398(9)10183.206(9)9817.3974(12)0.001240 4f(5/2)2[3/2]°25g(5/2)2[7/2]31.8e+06D+R1cTW
9824.237(10)10176.117(11)9824.2394(9)−0.002100 4f(5/2)2[11/2]°65g(5/2)2[9/2]5 R1c
9827.041(12)10173.213(12)9827.0477(21)−0.00678 4f(5/2)2[11/2]°55g(5/2)2[9/2]4 R1c
9827.982(4)10172.240(4)9827.9787(7)0.0033200 4f(5/2)2[11/2]°65g(5/2)2[11/2]67.5e+06D+F_ReTW
9828.973(10)10171.214(10)9828.9743(16)−0.001710 5p(3/2)2[3/2]°26s(5/2)2[5/2]2 R1c
9830.795(4)10169.329(4)9830.7965(20)−0.0012700 4f(5/2)2[11/2]°55g(5/2)2[11/2]57.7e+06D+F_ReTW
9835.299(10)10164.672(11)9835.299(3)−0.001100 4f(3/2)2[3/2]°25g(3/2)2[7/2]3 R1c
9837.8361(21)10162.0505(22)9837.8372(17)−0.001110000 4f(5/2)2[3/2]°25g(5/2)2[5/2]34.4e+07C+F_ReTW
9850.495(5)10148.991(6)9850.504(4)−0.0102400 4f(5/2)2[1/2]°05g(5/2)2[3/2]12.8e+07D+F_ReTW
9858.723(7)10140.521(8)9858.7254(24)−0.0022500 4f(5/2)2[3/2]°25g(5/2)2[3/2]21.9e+07D+R1cTW
9861.28027(17)10137.89135(18) 21000 4f(5/2)2[11/2]°65g(5/2)2[13/2]76.7e+07BF_ReTW
9864.13643(18)10134.95593(19) 19000 4f(5/2)2[11/2]°55g(5/2)2[13/2]66.6e+07BF_ReTW
9868.0934(21)10130.8920(22)9868.0940(21)−0.00069100 4f(3/2)2[3/2]°25g(3/2)2[5/2]35.6e+07C+F_ReTW
9870.816(16)10128.098(17)9870.8012(20)0.01497 5s(5/2)2[5/2]3sp(3F)3335.4e+05CR1cB00
9878.465(8)10120.255(9)9878.193(5)0.273280?sp(3P)3525g(5/2)2[5/2]2 R1c X
9881.464(3)10117.184(3)9881.4639(15)0.0008400 4f(5/2)2[7/2]°35g(5/2)2[9/2]42.1e+07DF_ReTW
9883.730(9)10114.864(9)9883.7091(24)0.021560 4f(3/2)2[9/2]°55g(3/2)2[9/2]55.4e+06D+R1cTW
9883.9672(10)10114.6216(10)9883.9674(10)−0.00015100 4f(5/2)2[3/2]°15g(5/2)2[5/2]23.9e+07C+F_ReTW
9884.996(11)10113.569(11)9884.989(4)0.00728 6p(5/2)2[7/2]°36d(3/2)2[7/2]4 R1c
9892.939(4)10105.448(4)9892.940(4)−0.0004800 4f(3/2)2[3/2]°15g(3/2)2[5/2]23.1e+07DF_ReTW
9894.337(7)10104.021(7)9894.3443(14)−0.0075300 4f(5/2)2[7/2]°35g(5/2)2[7/2]31.0e+07D+R1cTW
9899.567(11)10098.683(11)9899.414(6)0.15357?sp(3P)3525g(5/2)2[3/2]1 R1c X
9905.136(23)10093.005(24)9905.091(3)0.0451800*4f(5/2)2[3/2]°15g(5/2)2[3/2]23.7e+06D+F_ReTW
9905.18(8)10092.97(8)9905.214(4)−0.041800*4f(5/2)2[3/2]°15g(5/2)2[3/2]11.5e+07D+R1cTW
9911.988(12)10086.028(12)9911.986(3)0.00258 sp(3F)1327s(3/2)2[3/2]1 R1c
9915.090(21)10082.873(22)9915.0672(18)0.022630*4f(5/2)2[7/2]°35g(5/2)2[5/2]2 R1c
9915.090(21)10082.873(22)9915.1061(20)−0.017630*4f(5/2)2[7/2]°35g(5/2)2[5/2]3 R1c
9916.4171(3)10081.5233(3)9916.4172(3)−0.000115000 4f(3/2)2[9/2]°55g(3/2)2[11/2]66.6e+07BF_ReTW
9917.9509(10)10079.9642(10)9917.9510(10)−0.00019800 4f(5/2)2[5/2]°25g(5/2)2[7/2]33.8e+07C+F_ReTW
9925.5883(4)10072.2080(4)9925.5883(4)−0.000013000 4f(3/2)2[9/2]°45g(3/2)2[11/2]56.5e+07BF_ReTW
9926.0209(15)10071.7690(16)9926.0211(13)−0.00024900 4f(5/2)2[5/2]°35g(5/2)2[9/2]4 F_Re
9938.775(4)10058.844(4)9938.7730(16)0.0025300 4f(5/2)2[5/2]°25g(5/2)2[5/2]22.1e+07C+F_ReTW
9938.9960(6)10058.6207(6)9938.9960(6)0.000011000 4f(5/2)2[5/2]°35g(5/2)2[7/2]44.4e+07C+F_ReTW
9948.895(11)10048.612(11)9948.8880(21)0.00761 4f(3/2)2[5/2]°35g(3/2)2[9/2]4 R1c
9959.970(3)10037.439(3)9959.9679(18)0.0025800 4f(5/2)2[5/2]°35g(5/2)2[5/2]31.9e+07C+F_ReTW
9960.3485(8)10037.0575(8)9960.3485(8)−0.000011000 4f(3/2)2[5/2]°35g(3/2)2[7/2]45.6e+07BF_ReTW
9981.399(12)10015.890(12)9981.379(3)0.020130 4f(5/2)2[5/2]°35g(5/2)2[3/2]21.9e+06D+R1cTW
9994.027(11)10003.234(11)9994.019(3)0.008900 4f(3/2)2[5/2]°35g(3/2)2[5/2]39.e+06D+R1cTW
10006.588(3)9990.678(3)10006.5881(24)−0.0018400 4f(3/2)2[5/2]°25g(3/2)2[7/2]34.9e+07C+F_ReTW
10022.9672(3)9974.3510(3)10022.9672(3)−0.000020000 4f(5/2)2[7/2]°45g(5/2)2[9/2]54.9e+07BF_ReTW
10026.894(4)9970.445(4)10026.8943(17)−0.0011500 4f(5/2)2[7/2]°45g(5/2)2[11/2]5 F_Re
10036.224(3)9961.176(3)10036.2243(9)−0.0005700 4f(5/2)2[7/2]°45g(5/2)2[7/2]41.64e+07C+F_ReTW
10038.0920(5)9959.3223(5)10038.0919(5)0.000114000 4f(3/2)2[7/2]°45g(3/2)2[9/2]56.0e+07BF_ReTW
10040.499(13)9956.935(13)10040.481(5)0.017560 4f(3/2)2[5/2]°25g(3/2)2[5/2]29.e+06D+R1cTW
10049.773(12)9947.746(12)10049.7881(19)−0.0151200 4f(3/2)2[7/2]°45g(3/2)2[7/2]49.e+06D+R1cTW
10051.0231(20)9946.5092(20)10051.0218(6)0.00145100 4f(5/2)2[9/2]°55g(5/2)2[9/2]51.32e+07C+F_ReTW
10054.93572(22)9942.63880(21)10054.93573(22)−0.0000124000 4f(5/2)2[9/2]°55g(5/2)2[11/2]65.8e+07BF_ReTW
10057.609(11)9939.996(11)10057.6090(20)−0.000180 4f(5/2)2[7/2]°45g(5/2)2[5/2]31.7e+06D+R1cTW
10080.3499(10)9917.5719(10)10080.3499(10)−0.000011000 4f(3/2)2[7/2]°35g(3/2)2[9/2]45.5e+07BF_ReTW
10092.14(3)9905.99(3)10092.1155(21)0.02990*4f(3/2)2[7/2]°35g(3/2)2[7/2]41.4e+06D+R1ncTW
10092.14(3)9905.99(3)10092.151(3)−0.01990*4f(3/2)2[7/2]°35g(3/2)2[7/2]37.3e+06D+R1cTW
10162.808(8)9837.103(8)10162.8099(18)−0.0013800 4f(5/2)2[9/2]°45g(5/2)2[9/2]41.25e+07C+F_ReTW
10166.8202(21)9833.2217(20)10166.8192(16)0.001018000 4f(5/2)2[9/2]°45g(5/2)2[11/2]54.4e+07BF_ReTW
10176.433(12)9823.933(11)10176.4346(17)−0.0021700 4f(5/2)2[9/2]°45g(5/2)2[7/2]31.4e+06D+R1cTW
10193.660(10)9807.331(10)10193.6484(21)0.0121100 5s(5/2)2[5/2]2sp(3F)333 R1c
10225.073(10)9777.201(10)10225.077(4)−0.0031700 6p(5/2)2[7/2]°35g(3/2)2[9/2]4 R1c
10237.22(3)9765.60(3)10237.183(4)0.03120*6p(5/2)2[7/2]°35g(3/2)2[7/2]4 R1nc
10237.22(3)9765.60(3)10237.219(4)−0.00120*6p(5/2)2[7/2]°35g(3/2)2[7/2]3 R1c
10247.043(10)9756.239(9)10247.038(4)0.0051300 sp(3F)1326d(5/2)2[7/2]31.9e+06D+R1cTW
10278.686(16)9726.204(15)10278.6604(14)0.026540 5s(3/2)2[3/2]25p(5/2)2[3/2]°2 R1c
10297.40(3)9708.53(3)10297.147(5)0.2556?sp(1G)3346d(5/2)2[9/2]5 R1c X
10343.469(10)9665.287(9)10343.472(3)−0.0036100 sp(3F)1335g(5/2)2[9/2]41.17e+07C+R1cTW
10357.603(10)9652.098(9)10357.586(3)0.017780 sp(3F)1335g(5/2)2[7/2]34.8e+06D+R1cTW
10380.323(21)9630.972(20)10380.297(3)0.026130*sp(3F)1335g(5/2)2[5/2]2 R1nc
10380.323(21)9630.972(20)10380.340(3)−0.016130*sp(3F)1335g(5/2)2[5/2]3 R1c
10424.302(8)9590.341(7)10424.309(3)−0.0073700 5d(5/2)2[1/2]15f(5/2)2[3/2]°21.2e+07D+F_ReTW
10453.012(7)9564.000(7)10453.004(4)0.0084800 5d(5/2)2[1/2]15f(5/2)2[1/2]°12.7e+07D+F_ReTW
10465.664(10)9552.438(10)10465.665(4)−0.0023800 5d(5/2)2[1/2]15f(5/2)2[1/2]°03.6e+07D+F_ReTW
10575.703(11)9453.046(10)10575.690(6)0.013180 6p(5/2)2[5/2]°26d(3/2)2[7/2]33.0e+06D+R1cTW
10609.294(11)9423.116(10)10609.300(5)−0.006240 5d(3/2)2[1/2]15f(3/2)2[3/2]°11.0e+07D+R1cTW
10624.895(12)9409.280(11)10624.901(4)−0.00796 sp(1G)3345g(5/2)2[11/2]5 R1c
10641.797(11)9394.335(9)10641.822(5)−0.0253600 5d(3/2)2[1/2]15f(3/2)2[3/2]°23.0e+07D+F_ReTW
10742.332(8)9306.416(7)10742.3392(23)−0.0074800 5d(5/2)2[9/2]55f(5/2)2[9/2]°57.7e+06D+F_ReTW
10745.703(12)9303.497(11)10745.703(3)−0.001110 5d(5/2)2[9/2]55f(5/2)2[9/2]°4 R1c
10752.044(14)9298.010(12)10752.046(3)−0.00253 5d(5/2)2[9/2]55f(5/2)2[7/2]°4 R1c
10768.359(14)9283.923(12)10768.360(4)−0.001210 5d(3/2)2[7/2]35f(3/2)2[7/2]°35.7e+06D+R1cTW
10787.828(10)9267.168(9)10787.827(3)0.001210 5d(5/2)2[3/2]25f(5/2)2[7/2]°31.9e+06D+R1cTW
10791.529(10)9263.990(9)10791.519(3)0.0101400 5d(5/2)2[9/2]45f(5/2)2[9/2]°47.e+06D+R1cTW
10797.923(12)9258.504(11)10797.915(3)0.008160 5d(5/2)2[9/2]45f(5/2)2[7/2]°4 R1c
10800.96(3)9255.90(3)10800.929(3)0.03110*5d(5/2)2[9/2]45f(5/2)2[7/2]°3 R1c
10800.985(12)9255.879(10)10800.972(7)0.014110*sp(3F)3534d(3/2)2[5/2]2 F_Re
10836.3452(6)9225.6765(5)10836.3453(6)−0.00018300 5d(5/2)2[9/2]55f(5/2)2[11/2]°64.2e+07D+F_ReTW
10849.473(3)9214.514(3)10849.477(3)−0.0046300 5d(3/2)2[7/2]35f(3/2)2[9/2]°44.1e+07D+F_ReTW
10852.407(10)9212.022(9)10852.401(4)0.0072100 5d(5/2)2[3/2]15f(5/2)2[5/2]°21.8e+07D+R1cTW
10865.050(17)9201.303(15)10865.010(5)0.039100 5d(5/2)2[3/2]25f(5/2)2[3/2]°1 R1c
10885.074(16)9184.376(14)10885.066(5)0.008200*sp(1G)3336d(3/2)2[7/2]42.1e+06D+R1cTW
10885.074(16)9184.376(14)10885.064(8)0.010200*sp(3F)1316d(5/2)2[1/2]0 R1c
10889.9718(12)9180.2457(11)10889.9720(12)−0.00036800 5d(5/2)2[9/2]45f(5/2)2[11/2]°54.2e+07D+F_ReTW
10904.886(9)9167.691(7)10904.902(5)−0.0162600 5d(3/2)2[3/2]15f(3/2)2[5/2]°22.8e+07D+F_ReTW
10925.167(13)9150.672(11)10925.155(4)0.01297 5d(3/2)2[7/2]45f(3/2)2[9/2]°41.3e+06D+R1cTW
10929.791(10)9146.800(9)10929.799(4)−0.008480 5d(5/2)2[3/2]25f(5/2)2[1/2]°11.2e+07D+R1cTW
10930.9327(21)9145.8452(17)10930.9342(19)−0.00155300 5d(3/2)2[7/2]45f(3/2)2[9/2]°54.2e+07D+F_ReTW
10959.809(11)9121.748(9)10959.819(5)−0.0104600 5d(3/2)2[3/2]25f(3/2)2[7/2]°33.0e+06D+R1cTW
10964.502(11)9117.844(9)10964.527(5)−0.0253200 5d(3/2)2[3/2]15f(3/2)2[3/2]°11.0e+07D+R1cTW
10966.532(11)9116.156(9)10966.524(5)0.008900 5d(5/2)2[3/2]15f(5/2)2[1/2]°07.e+06D+R1cTW
10973.938(5)9110.004(4)10973.944(3)−0.0063100 5d(5/2)2[5/2]35f(5/2)2[9/2]°45.5e+06D+F_ReTW
10980.553(5)9104.516(4)10980.559(3)−0.0064700 5d(5/2)2[5/2]35f(5/2)2[7/2]°42.0e+07D+F_ReTW
10983.677(10)9101.926(8)10983.675(3)0.0021600 5d(5/2)2[5/2]35f(5/2)2[7/2]°33.9e+06D+R1cTW
11008.410(12)9081.477(10)11008.408(4)0.0023300 sp(3F)1337s(5/2)2[5/2]3 R1c
11009.932(6)9080.221(5)11009.932(4)−0.0003200 5d(3/2)2[3/2]25f(3/2)2[5/2]°32.9e+07D+F_ReTW
11027.380(13)9065.854(11)11027.388(3)−0.008190 5d(5/2)2[5/2]35f(5/2)2[5/2]°21.6e+06D+R1cTW
11035.977(10)9058.792(8)11035.978(4)−0.0022700 5d(5/2)2[5/2]35f(5/2)2[5/2]°31.6e+07D+R1cTW
11098.345(11)9007.885(9)11098.352(3)−0.006150 5d(5/2)2[5/2]35f(5/2)2[3/2]°24.5e+06D+R1cTW
11100.523(11)9006.118(9)11100.529(5)−0.006150 5d(3/2)2[3/2]25f(3/2)2[3/2]°21.1e+07D+R1cTW
11114.771(5)8994.573(4)11114.773(3)−0.0012500 5d(5/2)2[7/2]35f(5/2)2[9/2]°42.4e+07D+F_ReTW
11121.559(10)8989.083(8)11121.558(3)0.0013300 5d(5/2)2[7/2]35f(5/2)2[7/2]°49.e+06ER1cTW
11123.1488(20)8987.7987(16)11123.1487(18)0.00016400 5d(5/2)2[7/2]45f(5/2)2[9/2]°53.3e+07D+F_ReTW
11124.761(11)8986.496(9)11124.755(4)0.0062400 5d(5/2)2[7/2]35f(5/2)2[7/2]°31.2e+07D+R1cTW
11125.451(5)8985.939(4)11125.454(4)−0.0033400 5d(3/2)2[5/2]35f(3/2)2[7/2]°43.5e+07D+F_ReTW
11126.754(11)8984.886(9)11126.756(3)−0.0012100 5d(5/2)2[7/2]45f(5/2)2[9/2]°44.5e+06D+R1cTW
11133.556(12)8979.397(9)11133.556(3)0.0002300 5d(5/2)2[7/2]45f(5/2)2[7/2]°49.e+06D+R1cTW
11141.872(21)8972.695(17)11141.845(5)0.027490 sp(3F)1317s(3/2)2[3/2]1 R1c
11156.494(10)8960.935(8)11156.492(5)0.0023400 5d(3/2)2[5/2]25f(3/2)2[7/2]°33.2e+07D+R1cTW
11173.078(11)8947.635(8)11173.081(4)−0.0032200 5d(5/2)2[5/2]25f(5/2)2[7/2]°32.2e+07D+F_ReTW
11180.070(13)8942.039(11)11180.072(4)−0.002800 5d(3/2)2[5/2]35f(3/2)2[5/2]°31.0e+07D+R1cTW
11190.552(13)8933.663(11)11190.534(4)0.01894 5d(5/2)2[7/2]45f(5/2)2[5/2]°32.0e+06D+R1cTW
11202.751(12)8923.935(9)11202.717(5)0.034350 5d(3/2)2[5/2]25f(3/2)2[5/2]°21.1e+07D+R1cTW
11208.490(13)8919.366(11)11208.425(5)0.06584 5d(3/2)2[5/2]25f(3/2)2[5/2]°31.2e+06D+R1cTWX
11218.324(11)8911.547(9)11218.317(4)0.0071200 5d(5/2)2[5/2]25f(5/2)2[5/2]°21.6e+07D+R1cTW
11227.209(11)8904.495(9)11227.208(4)0.0001100 5d(5/2)2[5/2]25f(5/2)2[5/2]°35.4e+06D+R1cTW
23063.74335.8223063.701(9) :4s3D34s1D22.0e−01C+ TW,G64M1
29261.73417.4329261.733(10) :4s3D24s1D21.55e−02C+ TW,G64M1
44127.22266.1844127.15(3) :4s3D14s1D22.7e−02C+ TW,G64M1
48317.62069.63948317.60(4) :4s3D34s3D19.e−08E TWE2
86861.81151.25486861.79(7) :4s3D24s3D15.6e−02C+ TW,G64M1
108887918.385108886.80(16) :4s3D34s3D21.8e−02C+ TW,G64M1
a Observed wavelength between 2000 Å and 20000 Å is given in standard air; outside of this region, it is in vacuum. The standard uncertainty in the last decimal place is given in parentheses after the value. Conversion from air to vacuum was made using the five-parameter formula from Peck and Reeder [38];
b Observed wavenumber in vacuum;
c Ritz wavelength and its uncertainty were obtained in the least-squares level optimization procedure using the LOPT code [39]. For lines that alone determine one of the energy levels of the transition, this column is blank;
d Observed intensities from different experiments have been normalized to a uniform scale (see text). They are proportional to the energy flux under the line profile and have uncertainties of a factor of three on average. Intensities of parity-forbidden transitions are given on a different scale, since most of them were observed only in nebulas;
e Line character code: bl—blended line; p—perturbed by a close line; *—the given intensity value is shared by two or more transitions; m—masked by another strong line (no wavelength measurement available);—the value given in the observed wavelength column is a rounded Ritz wavelength (no wavelength measurement available); ?—questionable identification;
f Transition probability accuracy code: A+—transition probability uncertainty is likely ≤2%; B+—≤7%; B—≤7%; C+—≤18%; C—≤25%; D—≤50%; E—>50%;
g Key to observed wavelength and transition probability references: A73—Aller et al. [4]; A08—Andersson et al. [40]; B00—Biémont et al. [41]; B09—Brown et al. [42]; C84—Cederquist et al. [43]; C94—Crespo López-Urrutia et al. [44]; D05—Dong and Fritzsche [45]; G64—Garstang [46]; H71—Hefferlin et al. [47]; K66—Kaufman and Ward [15]; K82—Kono and Hattori [48]; M97—McKenna et al. [5]; N88—Neger and Jäger [49]; O07—Ortiz et al. [50]; P84—Prior [37]; P97—Pinnington et al. [51]; R1—Ross [2]; R2—Ross [16]; S36—Shenstone [1]; T53—Thackeray [3]; W93—Wagatsuma and Hirokawa [36]; F—this work, FTS measurements with Cu/Ge/Pt/Ar hollow cathode; F_Re—this work, measurements with Cu/Re/Ar hollow cathode; TW—this work, grating measurements. Lower-case letters after the reference have the following meaning: c—corrected in this work; n—new identification; r—revised identification; cal—calculated A-value; se—A-value was semiempirically adjusted by ratio of observed and calculated lifetime;
h Notes: X—excluded from level-optimization procedure; L—lasing line; M1—magnetic-dipole transition; E2—electric-quadrupole transition; HF—hyperfine-induced transition
Table A2. Energy levels of Cu II.
Table A2. Energy levels of Cu II.
Label aConfigurationTermJLevel b, cm−1Unc. c, cm−1Landé g dLeading Percentages eNote fNlines g
d101S3d101S00.0000.017 97% + 2% 4d 1S 15
4s3D3d94s3D321928.73260.00141.3298% 59
4s3D3d94s3D222847.11761.1689% + 9% 4s 1D 77
4s3D3d94s3D123998.37180.00090.4898% 48
4s1D3d94s1D226264.55020.00121.0089% + 9% 4s 3D 64
4p33d94p3266418.68490.00141.4996% + 2% 4p 3 31
4p33d94p3167916.55720.00111.4995% + 2% 4p 1 42
4p33d94p3368447.73490.00131.0662% + 34% 4p 1 32
4p33d94p3468730.88760.00171.2398% 23
4p33d94p3068850.26280.0014 98% 12
s23F3d84s23F469704.70150.0019 95% + 4% p2 (3F)1S 3F 32
4p33d94p3269867.98490.00110.6788% + 6% 4p 3 37
4p13d94p1370841.46690.0014 49% + 31% 4p 3D° + 17% 4p 3 40
4p13d94p1271493.85480.00071.0854% + 35% 4p 3D° + 9% 4p 3 36
s23F3d84s23F371531.5420.003 95% + 4% p2 (3F)1S 3F 57
4p33d94p3371920.09610.0008 64% + 19% 4p 3F° + 15% 4p 1 36
s23F3d84s23F272723.8170.004 94% + 4% p2 (3F)1S 3F 52
4p33d94p3173102.04080.00070.4792% + 3% 4p 1 31
4p33d94p3273353.29570.00080.9954% + 41% 4p 1 39
4p13d94p1173595.81430.00181.0493% + 4% 4p 3 36
s21D3d84s21D285388.7720.003 73% + 21% s2 3P 49
s23P3d84s23P288362.0010.003 74% + 21% s2 1D 44
s23P3d84s23P188605.0960.004 95% + 4% p2 (3P)1S 3P 38
s23P3d84s23P088926.0020.003 95% + 4% p2 (3P)1S 3P 17
s21G3d84s21G495565.6190.0030.9895% + 4% p2 (1G)1S 1G 18
sp(3F)353d8(3F)4s4p(3P°)54107942.7950.010 93% + 4% sp (3P)35 2
5s(5/2)2[5/2]3d9(2D5/2)5s2[5/2]3108014.83720.0012 100% 48
5s(5/2)2[5/2]3d9(2D5/2)5s2[5/2]2108335.60780.0012 98% + 2% 5s (3/2)2[3/2] 48
sp(3F)353d8(3F)4s4p(3P°)53109276.0150.006 91% + 4% sp (3P)35 8
5s(3/2)2[3/2]3d9(2D3/2)5s2[3/2]1110084.47730.0011 100% 34
sp(3F)353d8(3F)4s4p(3P°)52110363.7250.008 91% + 5% sp (3P)35 4
5s(3/2)2[3/2]3d9(2D3/2)5s2[3/2]2110366.15420.0011 98% + 2% 5s (5/2)2[5/2] 47
sp(3F)353d8(3F)4s4p(3P°)55110631.1960.009 82% + 13% sp (3F)35 1
sp(3F)353d8(3F)4s4p(3P°)51111124.390.14 93% + 5% sp (3P)35 1
sp(3F)353d8(3F)4s4p(3P°)54111218.7050.008 83% + 10% sp (3F)35F° + 5% sp (3F)33 2
sp(3F)353d8(3F)4s4p(3P°)53111876.4120.008 89% + 7% sp (3F)35 3
sp(3F)353d8(3F)4s4p(3P°)55112401.6320.022 86% + 12% sp (3F)35 1
sp(3F)353d8(3F)4s4p(3P°)52112424.6790.023 95% + 3% sp (3F)35 2
sp(3F)353d8(3F)4s4p(3P°)54113302.8230.006 84% + 9% sp (3F)35 5
sp(3F)353d8(3F)4s4p(3P°)53114000.4520.007 86% + 7% sp (3F)35 5
sp(3F)353d8(3F)4s4p(3P°)52114481.6740.006 92% + 3% sp (3F)35 6
4d(5/2)2[1/2]3d9(2D5/2)4d2[1/2]1114511.23860.0012 91% + 7% 4d (3/2)2[1/2] + 1% 4d2 39
sp(3F)353d8(3F)4s4p(3P°)51114755.9530.011 97% 3
sp(3F)333d8(3F)4s4p(3P°)34115359.5320.005 71% + 20% sp (3F)31G° + 6% sp (3F)35 7
sp(3F)333d8(3F)4s4p(3P°)35115546.1140.011 93% + 6% sp (3F)35 1
4d(5/2)2[9/2]3d9(2D5/2)4d2[9/2]5115568.994970.0012 99% 22
4d(5/2)2[3/2]3d9(2D5/2)4d2[3/2]2115638.80360.0011 93% + 4% 4d (5/2)2[5/2] + 2% 4d (3/2)2[3/2] 42
4d(5/2)2[9/2]3d9(2D5/2)4d2[9/2]4115662.56220.0014 97% + 1% 4d (5/2)2[7/2] 32
4d(5/2)2[3/2]3d9(2D5/2)4d2[3/2]1115665.15390.0011 97% + 1% 4d (3/2)2[1/2] + 1% 4d (3/2)2[3/2] 30
4d(5/2)2[5/2]3d9(2D5/2)4d2[5/2]3116080.22370.0010 97% + 1% 4d (5/2)2[7/2] + 1% 4d (3/2)2[5/2] 35
4d(5/2)2[7/2]3d9(2D5/2)4d2[7/2]3116325.91480.0011 93% + 4% 4d (3/2)2[7/2] + 1% 4d (5/2)2[5/2] 37
4d(5/2)2[7/2]3d9(2D5/2)4d2[7/2]4116371.180400.0011 95% + 2% 4d (3/2)2[7/2] + 1% 4d (5/2)2[9/2] 35
sp(3F)333d8(3F)4s4p(3P°)33116375.4060.003 44% + 35% sp (3F)33G° + 13% sp (3F)33 17
4d(5/2)2[5/2]3d9(2D5/2)4d2[5/2]2116387.78730.0010 92% + 3% 4d (3/2)2[3/2] + 3% 4d (5/2)2[3/2] 43
4d(5/2)2[1/2]3d9(2D5/2)4d2[1/2]0116576.57580.0018 53% + 45% 4d (3/2)2[1/2] 16
sp(3F)333d8(3F)4s4p(3P°)33116643.9600.003 57% + 36% sp (3F)33 17
sp(3F)333d8(3F)4s4p(3P°)32117130.3400.003 75% + 10% sp (3F)33 27
4d(3/2)2[1/2]3d9(2D3/2)4d2[1/2]1117231.40140.0019 91% + 7% 4d (5/2)2[1/2] 28
sp(3F)333d8(3F)4s4p(3P°)34117666.6260.005 88% + 3% sp (3F)35 15
4d(3/2)2[7/2]3d9(2D3/2)4d2[7/2]3117747.35040.0015 95% + 4% 4d (5/2)2[7/2] 37
4d(3/2)2[7/2]3d9(2D3/2)4d2[7/2]4117883.09850.0013 96% + 2% 4d (5/2)2[7/2] 35
4d(3/2)2[3/2]3d9(2D3/2)4d2[3/2]1117928.21970.0018 98% 31
sp(3F)333d8(3F)4s4p(3P°)31118071.3020.003 87% + 6% sp (1D)33 22
sp(3F)333d8(3F)4s4p(3P°)33118142.9500.003 63% + 14% sp (3F)31F° + 10% sp (3F)33 32
4d(3/2)2[3/2]3d9(2D3/2)4d2[3/2]2118163.26630.0015 82% + 12% 4d (3/2)2[5/2] + 2% 4d (5/2)2[5/2] 42
4d(3/2)2[5/2]3d9(2D3/2)4d2[5/2]3118483.81350.0015 98% + 1% 4d (5/2)2[5/2] 37
4d(3/2)2[5/2]3d9(2D3/2)4d2[5/2]2118531.90580.0016 86% + 12% 4d (3/2)2[3/2] + 1% 4d (5/2)2[3/2] 35
sp(3F)313d8(3F)4s4p(3P°)14118991.3300.007 75% + 20% sp (3F)33 9
sp(3F)333d8(3F)4s4p(3P°)32119039.63550.0019 82% + 8% sp (3F)33 34
5p(5/2)2[3/2]°3d9(2D5/2)5p2[3/2]°2120092.38280.0012 96% + 2% sp + 1% 5p (3/2)2[3/2]° 40
5p(5/2)2[7/2]°3d9(2D5/2)5p2[7/2]°3120684.71280.0013 86% + 13% sp 33
5p(5/2)2[7/2]°3d9(2D5/2)5p2[7/2]°4120789.808650.0013 95% + 4% sp 20
5p(5/2)2[5/2]°3d9(2D5/2)5p2[5/2]°2120876.01410.0015 51% + 41% sp + 3% 5p (3/2)2[3/2]° 41
5p(5/2)2[3/2]°3d9(2D5/2)5p2[3/2]°1120919.57150.0012 83% + 15% 5p (3/2)2[1/2]° + 1% sp 43
5p(5/2)2[5/2]°3d9(2D5/2)5p2[5/2]°3121079.15010.0012 54% + 35% sp + 3% 5p (3/2)2[5/2]° 45
sp(3F)313d8(3F)4s4p(3P°)13121524.85090.0014 39% + 43% 5p 3D° + 6% sp (3F)33cd37
sp(3F)313d8(3F)4s4p(3P°)12121981.85460.0015 36% + 32% 5p 3D° + 22% 5p 3 44
5p(3/2)2[1/2]°3d9(2D3/2)5p2[1/2]°0122224.01990.0020 99% 13
4d(3/2)2[1/2]3d9(2D3/2)4d2[1/2]0122415.9570.003 45% + 34% 4d (5/2)2[1/2] + 10% 5d (5/2)2[1/2] 12
5p(3/2)2[5/2]°3d9(2D3/2)5p2[5/2]°2122745.94910.0013 85% + 4% 5p (3/2)2[3/2]° + 4% 5p (5/2)2[5/2]° 39
5p(3/2)2[1/2]°3d9(2D3/2)5p2[1/2]°1122867.74070.0015 75% + 14% 5p (5/2)2[3/2]° + 9% 5p (3/2)2[3/2]° 39
5p(3/2)2[5/2]°3d9(2D3/2)5p2[5/2]°3123016.81750.0014 91% + 7% sp + 1% 5p (5/2)2[7/2]° 27
5p(3/2)2[3/2]°3d9(2D3/2)5p2[3/2]°1123304.8230.003 86% + 9% 5p (3/2)2[1/2]° + 4% sp 27
5p(3/2)2[3/2]°3d9(2D3/2)5p2[3/2]°2123556.82610.0016 76% + 13% sp + 3% 5p (5/2)2[5/2]° 43
sp(3P)353d8(3P)4s4p(3P°)53125230.0610.017 88% + 8% sp (1D)33 6
sp(3P)353d8(3P)4s4p(3P°)52125248.1210.008 88% + 3% sp (1D)33 11
sp(3P)353d8(3P)4s4p(3P°)51125569.330.04 94% + 2% sp (1D)33 5
sp(1D)333d8(1D)4s4p(3P°)32128365.7360.006 69% + 15% sp (1D)33 10
sp(1D)333d8(1D)4s4p(3P°)33128559.3140.008 68% + 11% sp (3P)35D° + 9% sp (1D)33 6
sp(1D)333d8(1D)4s4p(3P°)31128569.1500.008 66% + 9% sp (1D)33P° + 9% sp (3P)33 7
sp(1D)333d8(1D)4s4p(3P°)34128778.0370.017 64% + 28% sp (3P)35 2
sp(1D)333d8(1D)4s4p(3P°)32128854.0360.008 59% + 19% sp (1D)33 8
s21S3d84s21S0128910.030.06 94% + 5% p2 (1S)1S 1SN1
sp(1D)333d8(1D)4s4p(3P°)30129105.7780.009 63% + 32% sp (3P)33 3
sp(1D)333d8(1D)4s4p(3P°)33129116.7740.011 69% + 10% sp (1D)33F° + 7% sp (3P)35 6
sp(1D)333d8(1D)4s4p(3P°)31129759.7500.006 56% + 19% sp (1D)33D° + 18% sp (3P)33 9
sp(1D)333d8(1D)4s4p(3P°)32130386.4040.016 74% + 12% sp (3P)33P° + 8% sp (1D)33 8
sp(3P)353d8(3P)4s4p(3P°)51130940.4880.008 91% + 5% sp (3F)35 8
sp(3P)353d8(3P)4s4p(3P°)52130943.6610.009 88% + 5% sp (3F)35 9
sp(3P)353d8(3P)4s4p(3P°)50130953.5580.016 91% + 6% sp (3F)35N2
sp(3P)353d8(3P)4s4p(3P°)53131044.3100.008 81% + 11% sp (1D)33 10
sp(3P)353d8(3P)4s4p(3P°)54131312.4260.013 66% + 25% sp (1D)33F° + 5% sp (1G)33 5
6s(5/2)2[5/2]3d9(2D5/2)6s2[5/2]3133594.23230.0013 100% 27
6s(5/2)2[5/2]3d9(2D5/2)6s2[5/2]2133728.03870.0013 100% 29
sp(3P)333d8(3P)4s4p(3P°)32133825.9270.004 55% + 22% sp (3P)33D° + 9% sp (1D)33 13
sp(3P)333d8(3P)4s4p(3P°)33133984.3250.004 47% + 31% sp (3F)13D° + 6% sp (1D)33 14
sp(3F)133d8(3F)4s4p(1P°)35134110.8700.004 93% + 2% 4f 3 9
sp(3P)333d8(3P)4s4p(3P°)31134359.8470.003 52% + 24% sp (3P)33P° + 10% sp (1D)33 16
sp(3P)333d8(3P)4s4p(3P°)32134675.5220.003 50% + 22% sp (3P)33P° + 7% sp (3F)13 18
sp(3F)133d8(3F)4s4p(1P°)34134742.8630.003 50% + 31% sp (3F)13G° + 7% sp (1G)33cd13
sp(3P)333d8(3P)4s4p(3P°)31135135.1680.003 38% + 32% sp (3P)33D° + 14% sp (1D)33 10
sp(3P)333d8(3P)4s4p(3P°)30135484.0750.004 60% + 31% sp (1D)33P° + 5% 4f 3 6
6s(3/2)2[3/2]3d9(2D3/2)6s2[3/2]1135664.52040.0015 100% 21
sp(3F)133d8(3F)4s4p(1P°)33135733.4330.003 26% sp (3P)33D° + 14% sp (3F)13F° + 13% sp (3F)13 20
6s(3/2)2[3/2]3d9(2D3/2)6s2[3/2]2135760.15480.0016 99% 27
sp(3F)133d8(3F)4s4p(1P°)34135834.67200.0019 49% + 22% sp (3F)13F° + 9% 4f 3 17
4f(5/2)2[1/2]°3d9(2D5/2)4f2[1/2]°1135863.68570.0016 97% + 2% sp + 1% 4f (5/2)2[3/2]° 19
4f(5/2)2[1/2]°3d9(2D5/2)4f2[1/2]°0135902.13650.0023 94% + 4% sp 8
4f(5/2)2[3/2]°3d9(2D5/2)4f2[3/2]°2135910.72450.0011 94% + 4% 4f (5/2)2[5/2]° + 2% sp 23
4f(5/2)2[11/2]°3d9(2D5/2)4f2[11/2]°6135931.014120.0012 99% + 1% sp 5
4f(5/2)2[11/2]°3d9(2D5/2)4f2[11/2]°5135933.894990.0019 98% + 1% sp 11
sp(3P)353d8(3P)4s4p(3P°)52135952.2790.005 83% + 4% 4f 1 12
4f(5/2)2[3/2]°3d9(2D5/2)4f2[3/2]°1135958.19190.0016 97% + 2% sp + 1% 4f (5/2)2[1/2]° 20
4f(5/2)2[7/2]°3d9(2D5/2)4f2[7/2]°3135989.91760.0012 41% + 37% sp + 11% 4f (5/2)2[5/2]° 33
4f(5/2)2[5/2]°3d9(2D5/2)4f2[5/2]°2136013.96710.0011 84% + 9% sp + 5% 4f (5/2)2[3/2]° 17
4f(5/2)2[5/2]°3d9(2D5/2)4f2[5/2]°3136035.33280.0010 86% + 11% 4f (5/2)2[7/2]° + 3% sp 28
4f(5/2)2[7/2]°3d9(2D5/2)4f2[7/2]°4136132.777810.0010 88% + 8% 4f (5/2)2[9/2]° + 3% sp 26
4f(5/2)2[9/2]°3d9(2D5/2)4f2[9/2]°5136160.618250.0011 98% + 2% sp 14
4f(5/2)2[9/2]°3d9(2D5/2)4f2[9/2]°4136269.99960.0014 75% + 14% sp + 9% 4f (5/2)2[7/2]° 20
5d(5/2)2[1/2]3d9(2D5/2)5d2[1/2]1136336.89710.0020 98% + 1% 5d (3/2)2[1/2] 17
sp(3F)133d8(3F)4s4p(1P°)33136441.8170.003 25% + 25% sp (3F)13G° + 11% sp (1G)33 21
sp(1G)333d8(1G)4s4p(3P°)34136693.9480.003 97% 10
5d(5/2)2[9/2]3d9(2D5/2)5d2[9/2]5136725.853490.0013 100% 14
5d(5/2)2[3/2]3d9(2D5/2)5d2[3/2]2136754.11040.0018 97% + 2% 5d (5/2)2[5/2] 25
5d(5/2)2[9/2]3d9(2D5/2)5d2[9/2]4136765.35140.0018 99% 20
5d(5/2)2[3/2]3d9(2D5/2)5d2[3/2]1136773.17130.0021 99% 19
sp(3F)133d8(3F)4s4p(1P°)32136800.1370.003 41% + 18% sp (3P)31D° + 14% 6p 14
5d(5/2)2[5/2]3d9(2D5/2)5d2[5/2]3136919.35110.0014 99% + 1% 5d (5/2)2[7/2] 36
5d(5/2)2[7/2]3d9(2D5/2)5d2[7/2]3137034.7780.003 99% + 1% 5d (5/2)2[5/2] + 1% 5d (3/2)2[7/2] 23
5d(5/2)2[7/2]3d9(2D5/2)5d2[7/2]4137044.46470.0017 99% 22
5d(5/2)2[5/2]3d9(2D5/2)5d2[5/2]2137073.64650.0019 97% + 2% 5d (5/2)2[3/2] 24
sp(3F)133d8(3F)4s4p(1P°)33137078.1900.005 52% + 19% sp (3F)13F° + 14% sp (1G)33 7
sp(1G)333d8(1G)4s4p(3P°)35137082.1750.005 96% + 2% 4f 1H° 6
sp(1G)333d8(1G)4s4p(3P°)32137212.7790.004 36% + 36% sp (3F)13F° + 14% sp (3P)31RJ12
sp(3P)313d8(3P)4s4p(3P°)11137242.9140.008 82% + 5% sp (3P)33N6
5d(5/2)2[1/2]3d9(2D5/2)5d2[1/2]0137614.1400.004 60% + 37% 5d (3/2)2[1/2] + 1% 6d (5/2)2[1/2] 7
sp(3P)313d8(3P)4s4p(3P°)12137648.8000.004 50% + 9% sp (3P)33D° + 9% sp (3F)13 15
sp(3F)133d8(3F)4s4p(1P°)31137913.4500.004 28% + 16% 4f 3D° + 16% 4f 13
sp(1G)333d8(1G)4s4p(3P°)34137938.9040.007 49% + 39% 6p 3F° + 5% sp (3F)13cd6
4f(3/2)2[3/2]°3d9(2D3/2)4f2[3/2]°2138002.88560.0023 94% + 3% sp + 2% 4f (3/2)2[5/2]° 10
4f(3/2)2[3/2]°3d9(2D3/2)4f2[3/2]°1138028.3840.003 59% + 26% sp + 10% 6p 14
4f(3/2)2[9/2]°3d9(2D3/2)4f2[9/2]°5138064.29710.0021 99% + 1% sp 10
4f(3/2)2[9/2]°3d9(2D3/2)4f2[9/2]°4138073.58260.0022 98% + 1% sp 10
4f(3/2)2[5/2]°3d9(2D3/2)4f2[5/2]°3138130.53450.0015 97% + 1% 4f (3/2)2[7/2]° 17
4f(3/2)2[5/2]°3d9(2D3/2)4f2[5/2]°2138176.87970.0018 89% + 7% sp + 1% 4f (3/2)2[3/2]° 17
4f(3/2)2[7/2]°3d9(2D3/2)4f2[7/2]°4138219.86050.0015 98% 12
4f(3/2)2[7/2]°3d9(2D3/2)4f2[7/2]°3138261.58220.0017 93% + 1% sp + 1% 4f (3/2)2[5/2]° 19
6p(5/2)2[7/2]°3d9(2D5/2)6p2[7/2]°3138401.9560.003 62% + 29% sp + 2% 6p (5/2)2[5/2]° 21
sp(3P)333d8(3P)4s4p(3P°)31138516.490.03 97%N5
5d(3/2)2[1/2]3d9(2D3/2)5d2[1/2]1138593.0460.003 98% + 1% 5d (5/2)2[1/2] 17
6p(5/2)2[3/2]°3d9(2D5/2)6p2[3/2]°2138745.8170.005 91% + 4% sp + 3% 6p (5/2)2[5/2]° 14
5d(3/2)2[7/2]3d9(2D3/2)5d2[7/2]3138819.06370.0019 99% + 1% 5d (5/2)2[7/2] 15
5d(3/2)2[7/2]3d9(2D3/2)5d2[7/2]4138882.89210.0019 99% 15
5d(3/2)2[3/2]3d9(2D3/2)5d2[3/2]1138898.3340.003 99% 18
5d(3/2)2[3/2]3d9(2D3/2)5d2[3/2]2138981.2460.003 97% + 2% 5d (3/2)2[5/2] + 1% 5d (5/2)2[3/2] 19
6p(5/2)2[5/2]°3d9(2D5/2)6p2[5/2]°2139028.7050.005 41% + 40% sp + 11% 6p (3/2)2[5/2]° 11
5d(3/2)2[5/2]3d9(2D3/2)5d2[5/2]3139119.42950.0020 100% 18
5d(3/2)2[5/2]3d9(2D3/2)5d2[5/2]2139142.0490.003 97% + 2% 5d (3/2)2[3/2] 24
6p(5/2)2[3/2]°3d9(2D5/2)6p2[3/2]°1139241.1300.005 73% + 7% 6p (3/2)2[3/2]° + 4% 6p (3/2)2[1/2]° 13
sp(1G)333d8(1G)4s4p(3P°)33139331.1490.003 21% + 46% 6p 1F° + 15% 6p 3cd21
6p(5/2)2[7/2]°3d9(2D5/2)6p2[7/2]°4139395.7860.004 59% + 37% sp 11
sp(3F)133d8(3F)4s4p(1P°)32139710.4910.004 19% + 42% 6p 1D° + 15% sp (1G)33 15
6p(5/2)2[5/2]°3d9(2D5/2)6p2[5/2]°3139741.0970.003 59% + 31% sp + 4% 6p (5/2)2[7/2]° 18
5d(3/2)2[1/2]3d9(2D3/2)5d2[1/2]0140589.3440.006 47% + 20% 6d (5/2)2[1/2] + 17% 5d (5/2)2[1/2] 4
6p(3/2)2[1/2]°3d9(2D3/2)6p2[1/2]°1140981.5100.005 94% + 3% 6p (5/2)2[3/2]° + 2% sp 8
6p(3/2)2[5/2]°3d9(2D3/2)6p2[5/2]°3141202.6280.006 89% + 8% sp 12
6p(3/2)2[5/2]°3d9(2D3/2)6p2[5/2]°2141244.5560.006 62% + 22% sp + 13% 6p (3/2)2[3/2]°ci9
6p(3/2)2[3/2]°3d9(2D3/2)6p2[3/2]°2141542.0010.005 73% + 13% 6p (3/2)2[5/2]° + 10% sp 13
6p(3/2)2[3/2]°3d9(2D3/2)6p2[3/2]°1141734.1750.005 79% + 16% sp + 1% 5pci10
sp(1G)333d8(1G)4s4p(3P°)33143423.3190.020 99%N4
7s(5/2)2[5/2]3d9(2D5/2)7s2[5/2]3144814.91180.0014 100% 26
7s(5/2)2[5/2]3d9(2D5/2)7s2[5/2]2144882.98590.0016 100% 26
5f(5/2)2[1/2]°3d9(2D5/2)5f2[1/2]°0145889.3340.004 100% 6
5f(5/2)2[1/2]°3d9(2D5/2)5f2[1/2]°1145900.9040.003 84% + 16% 5f (5/2)2[3/2]° 10
5f(5/2)2[3/2]°3d9(2D5/2)5f2[3/2]°2145927.2310.003 100% 13
5f(5/2)2[11/2]°3d9(2D5/2)5f2[11/2]°5145945.59690.0019 100% 5
5f(5/2)2[11/2]°3d9(2D5/2)5f2[11/2]°6145951.52990.0014 100% 2
5f(5/2)2[3/2]°3d9(2D5/2)5f2[3/2]°1145955.4470.004 84% + 16% 5f (5/2)2[1/2]° 10
5f(5/2)2[5/2]°3d9(2D5/2)5f2[5/2]°3145978.1420.003 98% + 2% 5f (5/2)2[7/2]° 12
5f(5/2)2[5/2]°3d9(2D5/2)5f2[5/2]°2145985.1990.003 100% 12
5f(5/2)2[7/2]°3d9(2D5/2)5f2[7/2]°3146021.2790.003 98% + 2% 5f (5/2)2[5/2]° 13
5f(5/2)2[7/2]°3d9(2D5/2)5f2[7/2]°4146023.8620.003 86% + 14% 5f (5/2)2[9/2]° 13
5f(5/2)2[9/2]°3d9(2D5/2)5f2[9/2]°4146029.3500.003 86% + 14% 5f (5/2)2[7/2]° 13
5f(5/2)2[9/2]°3d9(2D5/2)5f2[9/2]°5146032.26350.0021 100% 7
5g(5/2)2[3/2]3d9(2D5/2)5g2[3/2]1146051.1180.004 100% 5
5g(5/2)2[3/2]3d9(2D5/2)5g2[3/2]2146051.24310.003 100% 4
5g(5/2)2[13/2]3d9(2D5/2)5g2[13/2]6146068.850920.0019 100% 1
5g(5/2)2[13/2]3d9(2D5/2)5g2[13/2]7146068.905470.0012 100% 1
5g(5/2)2[5/2]3d9(2D5/2)5g2[5/2]3146072.77390.0020 100% 5
5g(5/2)2[5/2]3d9(2D5/2)5g2[5/2]2146072.81340.0018 100% 6
5g(5/2)2[7/2]3d9(2D5/2)5g2[7/2]3146093.93120.0014 100% 5
5g(5/2)2[7/2]3d9(2D5/2)5g2[7/2]4146093.95350.0012 100% 2
5g(5/2)2[11/2]3d9(2D5/2)5g2[11/2]5146103.22230.0018 100% 7
5g(5/2)2[11/2]3d9(2D5/2)5g2[11/2]6146103.257040.0011 100% 3
5g(5/2)2[9/2]3d9(2D5/2)5g2[9/2]4146107.10160.0016 100% 7
5g(5/2)2[9/2]3d9(2D5/2)5g2[9/2]5146107.12880.0010 100% 6
6d(5/2)2[1/2]3d9(2D5/2)6d2[1/2]1146215.6340.004 98% + 1% 6d (5/2)2[3/2] 7
6d(5/2)2[9/2]3d9(2D5/2)6d2[9/2]5146402.7150.004 100% 8
6d(5/2)2[3/2]3d9(2D5/2)6d2[3/2]2146415.5990.004 97% + 2% 6d (5/2)2[5/2] 12
6d(5/2)2[9/2]3d9(2D5/2)6d2[9/2]4146423.2010.003 100% 10
6d(5/2)2[3/2]3d9(2D5/2)6d2[3/2]1146427.9480.003 99% + 1% 6d (5/2)2[1/2] 12
6d(5/2)2[5/2]3d9(2D5/2)6d2[5/2]3146496.1000.003 99% + 1% 6d (5/2)2[7/2] 16
6d(5/2)2[7/2]3d9(2D5/2)6d2[7/2]3146556.3810.003 99% + 1% 6d (5/2)2[5/2] 19
6d(5/2)2[7/2]3d9(2D5/2)6d2[7/2]4146559.7030.003 100% 14
6d(5/2)2[5/2]3d9(2D5/2)6d2[5/2]2146575.1010.003 97% + 2% 6d (5/2)2[3/2] + 1% 7s (3/2)2[3/2] 23
7s(3/2)2[3/2]3d9(2D3/2)7s2[3/2]1146886.16670.0021 100% 20
7s(3/2)2[3/2]3d9(2D3/2)7s2[3/2]2146936.31800.0018 99% 24
6d(5/2)2[1/2]3d9(2D5/2)6d2[1/2]0147097.8350.005 60% + 29% 6d (3/2)2[1/2] + 4% 7d (5/2)2[1/2] 6
7p(5/2)2[3/2]°3d9(2D5/2)7p2[3/2]°2147327.6590.007 94% + 4% sp + 1% 7p (5/2)2[5/2]° 10
7p(5/2)2[7/2]°3d9(2D5/2)7p2[7/2]°3147525.930.06 98% + 1% spR3
7p(5/2)2[3/2]°3d9(2D5/2)7p2[3/2]°1147562.6720.006 94% + 3% sp + 1% 5f (3/2)2[3/2]° 8
7p(5/2)2[7/2]°3d9(2D5/2)7p2[7/2]°4147596.6550.006 100% 4
7p(5/2)2[5/2]°3d9(2D5/2)7p2[5/2]°2147647.6990.009 94% + 3% sp + 2% 7p (5/2)2[3/2]° 7
7p(5/2)2[5/2]°3d9(2D5/2)7p2[5/2]°3147762.9900.005 98% 9
5f(3/2)2[3/2]°3d9(2D3/2)5f2[3/2]°2147987.3590.004 99% 8
5f(3/2)2[3/2]°3d9(2D3/2)5f2[3/2]°1148016.1570.004 99% + 1% 7p (5/2)2[3/2]° 11
5f(3/2)2[9/2]°3d9(2D3/2)5f2[9/2]°5148028.73600.0023 100% 5
5f(3/2)2[9/2]°3d9(2D3/2)5f2[9/2]°4148033.5740.003 100% 6
5f(3/2)2[5/2]°3d9(2D3/2)5f2[5/2]°3148061.4670.003 97% + 2% 5f (3/2)2[7/2]° 9
5f(3/2)2[5/2]°3d9(2D3/2)5f2[5/2]°2148066.0110.003 99% 11
5f(3/2)2[7/2]°3d9(2D3/2)5f2[7/2]°3148102.9860.003 97% + 3% 5f (3/2)2[5/2]° 9
5f(3/2)2[7/2]°3d9(2D3/2)5f2[7/2]°4148105.3660.003 100% 5
5g(3/2)2[5/2]3d9(2D3/2)5g2[5/2]3148133.7770.003 100% 3
5g(3/2)2[5/2]3d9(2D3/2)5g2[5/2]2148133.8320.005 100% 3
5g(3/2)2[11/2]3d9(2D3/2)5g2[11/2]5148145.79060.0022 100% 3
5g(3/2)2[11/2]3d9(2D3/2)5g2[11/2]6148145.82030.0021 100% 3
5g(3/2)2[7/2]3d9(2D3/2)5g2[7/2]3148167.5570.003 100% 5
5g(3/2)2[7/2]3d9(2D3/2)5g2[7/2]4148167.59200.0017 100% 4
5g(3/2)2[9/2]3d9(2D3/2)5g2[9/2]4148179.15410.0019 100% 4
5g(3/2)2[9/2]3d9(2D3/2)5g2[9/2]5148179.18290.0016 100% 4
6d(3/2)2[1/2]3d9(2D3/2)6d2[1/2]1148361.5420.004 99% 10
6d(3/2)2[7/2]3d9(2D3/2)6d2[7/2]3148481.7630.003 100% 11
6d(3/2)2[7/2]3d9(2D3/2)6d2[7/2]4148515.5320.004 100% 9
6d(3/2)2[3/2]3d9(2D3/2)6d2[3/2]1148521.5750.003 100% 12
6d(3/2)2[3/2]3d9(2D3/2)6d2[3/2]2148559.9580.003 99% + 1% 6d (3/2)2[5/2] 15
6d(3/2)2[5/2]3d9(2D3/2)6d2[5/2]3148631.0960.003 100% 13
6d(3/2)2[5/2]3d9(2D3/2)6d2[5/2]2148642.4890.003 99% + 1% 6d (3/2)2[3/2] 13
6d(3/2)2[1/2]3d9(2D3/2)6d2[1/2]0149202.6070.007 51% + 28% 7d (5/2)2[1/2] + 6% 6d (5/2)2[1/2] 3
7p(3/2)2[1/2]°3d9(2D3/2)7p2[1/2]°0149371.080.08 94% + 5% spN2
7p(3/2)2[1/2]°3d9(2D3/2)7p2[1/2]°1149484.1110.008 95% + 4% sp + 1% 7p (5/2)2[3/2]°N5
7p(3/2)2[5/2]°3d9(2D3/2)7p2[5/2]°2149525.970.05 64% + 26% 7p (3/2)2[3/2]° + 8% spN4
7p(3/2)2[5/2]°3d9(2D3/2)7p2[5/2]°3149624.470.05 92% + 6% spN2
7p(3/2)2[3/2]°3d9(2D3/2)7p2[3/2]°2149726.690.05 63% + 33% 7p (3/2)2[5/2]° + 3% spN3
7p(3/2)2[3/2]°3d9(2D3/2)7p2[3/2]°1149765.880.05 95% + 4% spN4
sp(1D)113d8(1D)4s4p(1P°)12150249.8870.008 38% + 28% sp (3P)13P° + 11% 7p 1 8
8s(5/2)2[5/2]3d9(2D5/2)8s2[5/2]3150742.8960.003 100% 13
8s(5/2)2[5/2]3d9(2D5/2)8s2[5/2]2150782.4540.003 100% 13
6f(5/2)2[1/2]°3d9(2D5/2)6f2[1/2]°1151161.3790.007 63% + 21% sp + 5% 8p (5/2)2[3/2]°N6
6f(5/2)2[1/2]°3d9(2D5/2)6f2[1/2]°0151327.2620.008 98% + 1% sp 2
6f(5/2)2[11/2]°3d9(2D5/2)6f2[11/2]°5151372.3300.004 100% 4
6f(5/2)2[3/2]°3d9(2D5/2)6f2[3/2]°1151373.8400.006 96% + 3% 6f (5/2)2[1/2]° 5
6f(5/2)2[3/2]°3d9(2D5/2)6f2[3/2]°2151375.3180.004 52% + 46% 6f (5/2)2[5/2]° 7
6f(5/2)2[11/2]°3d9(2D5/2)6f2[11/2]°6151377.6880.005 100% 2
6f(5/2)2[5/2]°3d9(2D5/2)6f2[5/2]°3151402.6210.004 71% + 28% 6f (5/2)2[7/2]° 7
6f(5/2)2[5/2]°3d9(2D5/2)6f2[5/2]°2151403.9420.004 53% + 44% 6f (5/2)2[3/2]° 8
6f(5/2)2[7/2]°3d9(2D5/2)6f2[7/2]°4151419.0220.004 90% + 10% 6f (5/2)2[9/2]° 8
6f(5/2)2[9/2]°3d9(2D5/2)6f2[9/2]°4151421.7910.004 90% + 10% 6f (5/2)2[7/2]° 9
6f(5/2)2[9/2]°3d9(2D5/2)6f2[9/2]°5151423.0560.004 100% 4
8p(5/2)2[3/2]°3d9(2D5/2)8p2[3/2]°1151424.2410.004 33% 6f (5/2)2[1/2]° + 36% sp + 20% 8p (5/2)2[3/2]° 8
6g(5/2)2[3/2]3d9(2D5/2)6g2[3/2]1151440.0910.008 100% 2
6g(5/2)2[3/2]3d9(2D5/2)6g2[3/2]2151440.1780.006 100% 2
6f(5/2)2[7/2]°3d9(2D5/2)6f2[7/2]°3151441.8990.006 70% + 27% 6f (5/2)2[5/2]° + 2% sp 7
6g(5/2)2[13/2]3d9(2D5/2)6g2[13/2]6151450.4140.007 100% 2
6g(5/2)2[13/2]3d9(2D5/2)6g2[13/2]7151450.4880.003 100% 1
6g(5/2)2[5/2]3d9(2D5/2)6g2[5/2]3151452.6900.007 100% 4
6g(5/2)2[5/2]3d9(2D5/2)6g2[5/2]2151452.7010.006 100% 4
6h(5/2)2[5/2]°3d9(2D5/2)6h2[5/2]°2[151458.3]6 100%pf0
6h(5/2)2[5/2]°3d9(2D5/2)6h2[5/2]°3[151458.4]6 100%pf0
6h(5/2)2[15/2]°3d9(2D5/2)6h2[15/2]°7[151461.7]6 100%pf0
6h(5/2)2[15/2]°3d9(2D5/2)6h2[15/2]°8[151461.8]6 100%pf0
6h(5/2)2[7/2]°3d9(2D5/2)6h2[7/2]°3[151463.9]6 100%pf0
6h(5/2)2[7/2]°3d9(2D5/2)6h2[7/2]°4[151464.0]6 100%pf0
6g(5/2)2[7/2]3d9(2D5/2)6g2[7/2]3151464.7890.006 100% 4
6g(5/2)2[7/2]3d9(2D5/2)6g2[7/2]4151464.7960.005 100% 2
6h(5/2)2[9/2]°3d9(2D5/2)6h2[9/2]°4[151468.8]6 100%pf0
6h(5/2)2[9/2]°3d9(2D5/2)6h2[9/2]°5[151468.9]6 100%pf0
6h(5/2)2[13/2]°3d9(2D5/2)6h2[13/2]°6[151469.8]6 100%pf0
6h(5/2)2[13/2]°3d9(2D5/2)6h2[13/2]°7[151470.0]6 100%pf0
6g(5/2)2[11/2]3d9(2D5/2)6g2[11/2]5151470.1130.003 100% 5
6g(5/2)2[11/2]3d9(2D5/2)6g2[11/2]6151470.1300.005 100% 3
6h(5/2)2[11/2]°3d9(2D5/2)6h2[11/2]°5[151471.4]6 100%pf0
6h(5/2)2[11/2]°3d9(2D5/2)6h2[11/2]°6[151471.5]6 100%pf0
6g(5/2)2[9/2]3d9(2D5/2)6g2[9/2]4151472.2640.005 100% 5
6g(5/2)2[9/2]3d9(2D5/2)6g2[9/2]5151472.2780.005 100% 3
7d(5/2)2[1/2]3d9(2D5/2)7d2[1/2]1151552.1910.007 98% + 1% 7d (5/2)2[3/2] 2
7d(5/2)2[9/2]3d9(2D5/2)7d2[9/2]5151656.3170.005 100% 5
7d(5/2)2[3/2]3d9(2D5/2)7d2[3/2]2151662.9850.005 96% + 4% 7d (5/2)2[5/2] 6
7d(5/2)2[9/2]3d9(2D5/2)7d2[9/2]4151668.3280.005 99% 7
7d(5/2)2[3/2]3d9(2D5/2)7d2[3/2]1151671.6660.006 99% + 1% 7d (5/2)2[1/2] 4
7d(5/2)2[5/2]3d9(2D5/2)7d2[5/2]3151708.3470.004 99% + 1% 7d (5/2)2[7/2] 8
7d(5/2)2[7/2]3d9(2D5/2)7d2[7/2]3151743.5580.003 99% + 1% 7d (5/2)2[5/2] 13
7d(5/2)2[7/2]3d9(2D5/2)7d2[7/2]4151744.9160.005 99% 8
7d(5/2)2[5/2]3d9(2D5/2)7d2[5/2]2151757.6010.004 96% + 4% 7d (5/2)2[3/2] 8
8p(5/2)2[3/2]°3d9(2D5/2)8p2[3/2]°2152054.780.03 53% + 21% 8p (5/2)2[5/2]° + 20% spN5
7d(5/2)2[1/2]3d9(2D5/2)7d2[1/2]0152179.0510.007 52% + 28% 7d (3/2)2[1/2] + 9% 8d (5/2)2[1/2] 2
8p(5/2)2[5/2]°3d9(2D5/2)8p2[5/2]°2152580.190.05 65% + 27% 8p (5/2)2[3/2]° + 7% spN2
sp(3P)133d8(3P)4s4p(1P°)30152783.410.05 77% + 9% 8p 3P° + 5% 7p 3N2
8s(3/2)2[3/2]3d9(2D3/2)8s2[3/2]1152814.0320.007 100% 4
8s(3/2)2[3/2]3d9(2D3/2)8s2[3/2]2152840.4750.005 100% 6
sp(3P)133d8(3P)4s4p(1P°)32152944.110.05 39% + 19% sp (1D)11D° + 16% 8p 3N4
sp(1D)113d8(1D)4s4p(1P°)11153165.240.04 22% + 18% 6f 3D° + 17% 6f 1N5
6f(3/2)2[5/2]°3d9(2D3/2)6f2[5/2]°3153410.2120.006 89% + 8% sp + 1% 6f (3/2)2[7/2]° 5
6f(3/2)2[3/2]°3d9(2D3/2)6f2[3/2]°2153426.6320.006 52% + 42% 6f (3/2)2[5/2]° + 5% sp 7
6f(3/2)2[9/2]°3d9(2D3/2)6f2[9/2]°5153449.6330.005 100% 2
6f(3/2)2[9/2]°3d9(2D3/2)6f2[9/2]°4153455.1780.005 100% 4
6f(3/2)2[3/2]°3d9(2D3/2)6f2[3/2]°1153457.7470.009 55% + 23% sp + 15% 8p (3/2)2[1/2]° 6
6f(3/2)2[5/2]°3d9(2D3/2)6f2[5/2]°2153487.6680.005 56% + 37% 6f (3/2)2[3/2]° + 5% sp 8
6f(3/2)2[7/2]°3d9(2D3/2)6f2[7/2]°4153495.8540.006 100% 3
6f(3/2)2[7/2]°3d9(2D3/2)6f2[7/2]°3153498.8340.006 98% + 2% 6f (3/2)2[5/2]° 3
6g(3/2)2[5/2]3d9(2D3/2)6g2[5/2]3153517.9050.007 100% 2
6g(3/2)2[5/2]3d9(2D3/2)6g2[5/2]2153517.9850.008 100% 1
6g(3/2)2[11/2]3d9(2D3/2)6g2[11/2]5153524.9330.005 100% 2
6g(3/2)2[11/2]3d9(2D3/2)6g2[11/2]6153524.9500.007 100% 1
6g(3/2)2[7/2]3d9(2D3/2)6g2[7/2]3153537.3950.007 100% 2
6g(3/2)2[7/2]3d9(2D3/2)6g2[7/2]4153537.4140.006 100% 3
6h(3/2)2[7/2]°3d9(2D3/2)6h2[7/2]°3[153543.7]6 100%pf0
6h(3/2)2[7/2]°3d9(2D3/2)6h2[7/2]°4[153543.8]6 100%pf0
6g(3/2)2[9/2]3d9(2D3/2)6g2[9/2]4153544.0540.005 100% 3
6g(3/2)2[9/2]3d9(2D3/2)6g2[9/2]5153544.0690.007 100% 2
6h(3/2)2[13/2]°3d9(2D3/2)6h2[13/2]°6[153546.0]6 100%pf0
6h(3/2)2[13/2]°3d9(2D3/2)6h2[13/2]°7[153546.2]6 100%pf0
6h(3/2)2[9/2]°3d9(2D3/2)6h2[9/2]°4[153552.0]6 100%pf0
6h(3/2)2[9/2]°3d9(2D3/2)6h2[9/2]°5[153552.1]6 100%pf0
6h(3/2)2[11/2]°3d9(2D3/2)6h2[11/2]°5[153554.3]6 100%pf0
6h(3/2)2[11/2]°3d9(2D3/2)6h2[11/2]°6[153554.4]6 100%pf0
7d(3/2)2[1/2]3d9(2D3/2)7d2[1/2]1153658.5670.006 99% 5
7d(3/2)2[7/2]3d9(2D3/2)7d2[7/2]3153730.9350.005 100% 5
7d(3/2)2[7/2]3d9(2D3/2)7d2[7/2]4153750.8510.005 100% 3
7d(3/2)2[3/2]3d9(2D3/2)7d2[3/2]1153753.7380.007 100% 2
7d(3/2)2[3/2]3d9(2D3/2)7d2[3/2]2153773.8840.006 97% + 3% 7d (3/2)2[5/2] 5
7d(3/2)2[5/2]3d9(2D3/2)7d2[5/2]3153815.6440.006 100% 5
7d(3/2)2[5/2]3d9(2D3/2)7d2[5/2]2153821.9370.006 97% + 3% 7d (3/2)2[3/2] 4
sp(3P)133d8(3P)4s4p(1P°)33153850.180.04 62% + 9% sp (1D)11F° + 8% 8p 3N2
7d(3/2)2[1/2]3d9(2D3/2)7d2[1/2]0153853.7630.011 49% + 44% 8d (5/2)2[1/2] + 2% 8d (3/2)2[1/2] 2
8p(3/2)2[3/2]°3d9(2D3/2)8p2[3/2]°1154225.210.04 38% + 44% sp + 6% 7f (5/2)2[3/2]°N2
9s(5/2)2[5/2]3d9(2D5/2)9s2[5/2]3154255.8150.005 100% 4
9s(5/2)2[5/2]3d9(2D5/2)9s2[5/2]2154281.2510.008 100% 4
7f(5/2)2[11/2]°3d9(2D5/2)7f2[11/2]°5154641.3920.006 99% 2
7f(5/2)2[11/2]°3d9(2D5/2)7f2[11/2]°6154647.0560.005 100% 2
7f(5/2)2[3/2]°3d9(2D5/2)7f2[3/2]°1154653.77?0.07 51% + 25% 8p (3/2)2[3/2]° + 12% 8p (3/2)2[1/2]°N2
7f(5/2)2[5/2]°3d9(2D5/2)7f2[5/2]°3154672.1230.006 62% + 37% 7f (5/2)2[7/2]° 4
7f(5/2)2[7/2]°3d9(2D5/2)7f2[7/2]°4154672.7660.006 91% + 9% 7f (5/2)2[9/2]° 5
7f(5/2)2[9/2]°3d9(2D5/2)7f2[9/2]°4154674.5510.006 91% + 9% 7f (5/2)2[7/2]° 4
7f(5/2)2[9/2]°3d9(2D5/2)7f2[9/2]°5154675.2470.005 100% 4
7f(5/2)2[7/2]°3d9(2D5/2)7f2[7/2]°3154678.8770.008 62% + 36% 7f (5/2)2[5/2]° + 1% sp 3
7g(5/2)2[3/2]3d9(2D5/2)7g2[3/2]1154688.0200.011 100% 2
7g(5/2)2[3/2]3d9(2D5/2)7g2[3/2]2154688.1120.009 100% 3
7g(5/2)2[13/2]3d9(2D5/2)7g2[13/2]6154694.5890.008 100% 1
7g(5/2)2[13/2]3d9(2D5/2)7g2[13/2]7154694.6190.008 100% 1
7g(5/2)2[5/2]3d9(2D5/2)7g2[5/2]3154695.9970.008 100% 4
7g(5/2)2[5/2]3d9(2D5/2)7g2[5/2]2154696.0090.007 100%N5
7f(5/2)2[5/2]°3d9(2D5/2)7f2[5/2]°2154698.2880.020 39% + 28% 8p (3/2)2[3/2]° + 15% 7f (5/2)2[3/2]°N3
7h(5/2)2[5/2]°3d9(2D5/2)7h2[5/2]°2[154702.4]2.0 100%pf0
7h(5/2)2[5/2]°3d9(2D5/2)7h2[5/2]°3[154702.5]2.0 100%pf0
7g(5/2)2[7/2]3d9(2D5/2)7g2[7/2]3154703.5970.008 100% 2
7g(5/2)2[7/2]3d9(2D5/2)7g2[7/2]4154703.6250.008 100% 2
7h(5/2)2[15/2]°3d9(2D5/2)7h2[15/2]°7[154704.6]2.0 100%pf0
7h(5/2)2[15/2]°3d9(2D5/2)7h2[15/2]°8[154704.6]2.0 100%pf0
7h(5/2)2[7/2]°3d9(2D5/2)7h2[7/2]°3[154706.0]2.0 100%pf0
7h(5/2)2[7/2]°3d9(2D5/2)7h2[7/2]°4[154706.1]2.0 100%pf0
7g(5/2)2[11/2]3d9(2D5/2)7g2[11/2]5154706.9110.007 100% 3
7g(5/2)2[9/2]3d9(2D5/2)7g2[9/2]4154708.2350.007 100% 5
7g(5/2)2[9/2]3d9(2D5/2)7g2[9/2]5154708.2440.007 100%N2
7h(5/2)2[9/2]°3d9(2D5/2)7h2[9/2]°4[154709.1]2.0 100%pf0
7h(5/2)2[9/2]°3d9(2D5/2)7h2[9/2]°5[154709.1]2.0 100%pf0
7h(5/2)2[13/2]°3d9(2D5/2)7h2[13/2]°6[154709.7]2.0 100%pf0
7h(5/2)2[13/2]°3d9(2D5/2)7h2[13/2]°7[154709.8]2.0 100%pf0
7h(5/2)2[11/2]°3d9(2D5/2)7h2[11/2]°5[154710.7]2.0 100%pf0
7h(5/2)2[11/2]°3d9(2D5/2)7h2[11/2]°6[154710.8]2.0 100%pf0
8p(3/2)2[1/2]°3d9(2D3/2)8p2[1/2]°1154719.090.03 29% + 32% 8p (3/2)2[3/2]° + 19% spN3
8d(5/2)2[1/2]3d9(2D5/2)8d2[1/2]1154766.0340.022 98% + 1% 8d (5/2)2[3/2] 1
8d(5/2)2[9/2]3d9(2D5/2)8d2[9/2]5154828.7180.008 100% 2
8d(5/2)2[3/2]3d9(2D5/2)8d2[3/2]2154832.6570.011 95% + 5% 8d (5/2)2[5/2] 1
8d(5/2)2[9/2]3d9(2D5/2)8d2[9/2]4154836.4340.006 100% 4
8d(5/2)2[3/2]3d9(2D5/2)8d2[3/2]1154838.973?0.013 98% + 1% 8d (5/2)2[1/2] 2
8d(5/2)2[5/2]3d9(2D5/2)8d2[5/2]3154860.7410.006 98% + 1% 8d (5/2)2[7/2] 5
8d(5/2)2[7/2]3d9(2D5/2)8d2[7/2]3154883.1040.009 98% + 1% 8d (5/2)2[5/2] 2
8d(5/2)2[7/2]3d9(2D5/2)8d2[7/2]4154883.6250.007 100% 6
8d(5/2)2[5/2]3d9(2D5/2)8d2[5/2]2154892.9160.020 95% + 5% 8d (5/2)2[3/2] 2
8d(5/2)2[1/2]3d9(2D5/2)8d2[1/2]0155244.842?0.021 32% + 29% 9d (5/2)2[1/2] + 20% 8d (3/2)2[1/2] 1
9s(3/2)2[3/2]3d9(2D3/2)9s2[3/2]1156326.9130.018 100% 4
9s(3/2)2[3/2]3d9(2D3/2)9s2[3/2]2156341.8780.009 99% + 1% 10s (5/2)2[5/2] 5
10s(5/2)2[5/2]3d9(2D5/2)10s2[5/2]3156508.5010.022 100% 1
10s(5/2)2[5/2]3d9(2D5/2)10s2[5/2]2156526.4360.015 99% + 1% 9s (3/2)2[3/2] 2
7f(3/2)2[9/2]°3d9(2D3/2)7f2[9/2]°5156711.8940.007 91% + 6% 8f (5/2)2[11/2]° + 3% 8f (5/2)2[9/2]° 2
7f(3/2)2[9/2]°3d9(2D3/2)7f2[9/2]°4156721.3080.007 97% + 3% 8f (5/2)2[9/2]° 2
7f(3/2)2[7/2]°3d9(2D3/2)7f2[7/2]°4[156754.9]7 99% + 1% 8f (5/2)2[7/2]°sf0
8f(5/2)2[11/2]°3d9(2D5/2)8f2[11/2]°5156761.4430.008 94% + 6% 7f (3/2)2[9/2]° 3
7g(3/2)2[5/2]3d9(2D3/2)7g2[5/2]3156763.0440.014 99% + 1% 8g (5/2)2[5/2] 1
7g(3/2)2[5/2]3d9(2D3/2)7g2[5/2]2156763.0900.011 99% + 1% 8g (5/2)2[5/2] 1
8f(5/2)2[11/2]°3d9(2D5/2)8f2[11/2]°6156767.0660.016 100% 2
7g(3/2)2[11/2]3d9(2D3/2)7g2[11/2]6156767.6090.011 99% + 1% 8g (5/2)2[11/2]N1
7g(3/2)2[11/2]3d9(2D3/2)7g2[11/2]5156767.6300.011 99% + 1% 8g (5/2)2[11/2] 2
7g(3/2)2[7/2]3d9(2D3/2)7g2[7/2]3156775.4050.014 99% + 1% 8g (5/2)2[7/2] 2
7g(3/2)2[7/2]3d9(2D3/2)7g2[7/2]4156775.4300.014 99% + 1% 8g (5/2)2[7/2]N1
8f(5/2)2[7/2]°3d9(2D5/2)8f2[7/2]°4[156779.7]7 94% + 5% 8f (5/2)2[9/2]° + 1% 7f (3/2)2[7/2]°sf0
7g(3/2)2[9/2]3d9(2D3/2)7g2[9/2]4156779.8470.014 100% 2
7g(3/2)2[9/2]3d9(2D3/2)7g2[9/2]5156779.8550.014 100%N1
8f(5/2)2[9/2]°3d9(2D5/2)8f2[9/2]°4[156781.7]7 92% + 5% 8f (5/2)2[7/2]° + 2% 7f (3/2)2[9/2]°sf0
8f(5/2)2[9/2]°3d9(2D5/2)8f2[9/2]°5[156782.4]7 97% + 3% 7f (3/2)2[9/2]°sf0
8g(5/2)2[3/2]3d9(2D5/2)8g2[3/2]2[156797.3]2.0 100%pf0
8g(5/2)2[7/2]3d9(2D5/2)8g2[7/2]3[156805.7]2.0 99% + 1% 7g (3/2)2[7/2]pf0
8g(5/2)2[9/2]3d9(2D5/2)8g2[9/2]5[156807.8]2.0 100%pf0
8g(5/2)2[11/2]3d9(2D5/2)8g2[11/2]6156808.189?0.010 99% + 1% 7g (3/2)2[11/2]N2
9d(5/2)2[9/2]3d9(2D5/2)9d2[9/2]5[156888.5]2.0 100%sf0
9d(5/2)2[9/2]3d9(2D5/2)9d2[9/2]4156912.7400.011 51% + 44% 8d (3/2)2[7/2] + 5% 9d (5/2)2[7/2] 2
8d(3/2)2[5/2]3d9(2D3/2)8d2[5/2]2156958.11?0.06 42% + 38% 9d (5/2)2[5/2] + 16% 8d (3/2)2[3/2] 1
9g(5/2)2[3/2]3d9(2D5/2)9g2[3/2]2[158241.1]2.0 100%pf0
9g(5/2)2[7/2]3d9(2D5/2)9g2[7/2]3[158246.8]2.0 100%pf0
10d(5/2)2[1/2]3d9(2D5/2)10d2[1/2]1[158285.3]4 98% + 2% 10d (5/2)2[3/2]sf0
10d(5/2)2[3/2]3d9(2D5/2)10d2[3/2]2[158306.0]5 95% + 4% 10d (5/2)2[5/2]sf0
10d(5/2)2[9/2]3d9(2D5/2)10d2[9/2]5[158306.9]2.0 100%sf0
10d(5/2)2[9/2]3d9(2D5/2)10d2[9/2]4[158308.9]2.0 100%sf0
10d(5/2)2[3/2]3d9(2D5/2)10d2[3/2]1[158310.4]4 98% + 2% 10d (5/2)2[1/2]sf0
10d(5/2)2[5/2]3d9(2D5/2)10d2[5/2]3[158323.3]4 98% + 2% 10d (5/2)2[7/2]sf0
10d(5/2)2[5/2]3d9(2D5/2)10d2[5/2]2[158333.4]5 95% + 4% 10d (5/2)2[3/2]sf0
10d(5/2)2[7/2]3d9(2D5/2)10d2[7/2]3[158334.1]4 98% + 2% 10d (5/2)2[5/2]sf0
10d(5/2)2[7/2]3d9(2D5/2)10d2[7/2]4[158334.2]2.0 100%sf0
10s(3/2)2[3/2]3d9(2D3/2)10s2[3/2]1158579.330.14 100%N1
8f(3/2)2[9/2]°3d9(2D3/2)8f2[9/2]°4[158851.1]8 100%sf0
8f(3/2)2[7/2]°3d9(2D3/2)8f2[7/2]°4[158864.4]8 100%sf0
8g(3/2)2[5/2]3d9(2D3/2)8g2[5/2]3[158869.3]2.0 100%pf0
8g(3/2)2[11/2]3d9(2D3/2)8g2[11/2]6[158871.7]2.0 100%pf0
8g(3/2)2[7/2]3d9(2D3/2)8g2[7/2]4[158875.8]2.0 100%pf0
8h(3/2)2[7/2]°3d9(2D3/2)8h2[7/2]°3[158876.9]2.0 100%pf0
8h(3/2)2[7/2]°3d9(2D3/2)8h2[7/2]°4[158877.0]2.0 100%pf0
8h(3/2)2[13/2]°3d9(2D3/2)8h2[13/2]°6[158877.9]2.0 100%pf0
8g(3/2)2[9/2]3d9(2D3/2)8g2[9/2]5[158878.0]2.0 100%pf0
8h(3/2)2[13/2]°3d9(2D3/2)8h2[13/2]°7[158878.0]2.0 100%pf0
8h(3/2)2[9/2]°3d9(2D3/2)8h2[9/2]°4[158880.4]2.0 100%pf0
8h(3/2)2[9/2]°3d9(2D3/2)8h2[9/2]°5[158880.5]2.0 100%pf0
8h(3/2)2[11/2]°3d9(2D3/2)8h2[11/2]°5[158881.4]2.0 100%pf0
8h(3/2)2[11/2]°3d9(2D3/2)8h2[11/2]°6[158881.5]2.0 100%pf0
9d(3/2)2[1/2]3d9(2D3/2)9d2[1/2]1[158935.9]4 99%sf0
9d(3/2)2[7/2]3d9(2D3/2)9d2[7/2]3[158961.1]2.0 100%sf0
9d(3/2)2[7/2]3d9(2D3/2)9d2[7/2]4[158966.7]2.0 100%sf0
9d(3/2)2[3/2]3d9(2D3/2)9d2[3/2]1[158970.8]2.0 100%sf0
9d(3/2)2[3/2]3d9(2D3/2)9d2[3/2]2[158977.0]5 96% + 4% 9d (3/2)2[5/2]sf0
9d(3/2)2[5/2]3d9(2D3/2)9d2[5/2]3[158999.4]2.0 100%sf0
9d(3/2)2[5/2]3d9(2D3/2)9d2[5/2]2[159000.4]5 96% + 4% 9d (3/2)2[3/2]sf0
10g(5/2)2[3/2]3d9(2D5/2)10g2[3/2]2[159273.3]2.0 100%pf0
10g(5/2)2[7/2]3d9(2D5/2)10g2[7/2]3[159277.4]2.0 100%pf0
9g(3/2)2[5/2]3d9(2D3/2)9g2[5/2]3[160312.5]2.0 100%pf0
9g(3/2)2[11/2]3d9(2D3/2)9g2[11/2]6[160314.1]2.0 100%pf0
9g(3/2)2[7/2]3d9(2D3/2)9g2[7/2]4[160317.0]2.0 100%pf0
9g(3/2)2[9/2]3d9(2D3/2)9g2[9/2]5[160318.5]2.0 100%pf0
10d(3/2)2[1/2]3d9(2D3/2)10d2[1/2]1[160361.5]4 99%sf0
10d(3/2)2[7/2]3d9(2D3/2)10d2[7/2]3[160378.4]2.0 100%sf0
10d(3/2)2[7/2]3d9(2D3/2)10d2[7/2]4[160382.2]2.0 100%sf0
10d(3/2)2[3/2]3d9(2D3/2)10d2[3/2]1[160385.0]2.0 100%sf0
10d(3/2)2[3/2]3d9(2D3/2)10d2[3/2]2[160388.7]5 96% + 3% 10d (3/2)2[5/2]sf0
10d(3/2)2[5/2]3d9(2D3/2)10d2[5/2]3[160404.5]2.0 100%sf0
10d(3/2)2[5/2]3d9(2D3/2)10d2[5/2]2[160405.1]5 96% + 3% 10d (3/2)2[3/2]sf0
10g(3/2)2[5/2]3d9(2D3/2)10g2[5/2]3[161344.3]2.0 100%pf0
10g(3/2)2[11/2]3d9(2D3/2)10g2[11/2]6[161345.4]2.0 100%pf0
10g(3/2)2[7/2]3d9(2D3/2)10g2[7/2]4[161347.6]2.0 100%pf0
10g(3/2)2[9/2]3d9(2D3/2)10g2[9/2]5[161348.6]2.0 100%pf0
Cu III (3d9 2D5/2)Limit 163669.20.5
a Label used in the column of Leading Percentages;
b Level values were obtained in the least-squares optimization procedure using the LOPT code [39] (see text), except the following: (1) Values in square brackets were obtained using extrapolations along level series (see column “Notes”); (2) The ionization limit is quoted from Ross [2] (see text). A question mark after the value indicates an uncertain identification;
c Uncertainties (one standard deviation) are specified for separations from the 3d94s 3D2 level (at 22847.1176 cm−1). To determine uncertainties relative to the ground level, the given values should be combined in quadrature with the uncertainty of the ground level, 0.017 cm−1;
d Experimental Landé g-factors are quoted from Sugar and Musgrove [17];
e The three leading contributions to the eigenvector are given, if their rounded value is ≥1%. The first percentage refers to the configuration and term given in the second and third columns, unless otherwise specified after the percentage value. For the 3d9nl levels designated in the J1l (a.k.a. JK) coupling scheme, the percentage value of the 3d84s4p configuration is the sum of percentage contributions of all terms of this configuration;
f Key to the notes: N—newly identified level; R—revised level value (new identification); RJ—revised J value (was 1 in Sugar and Musgrove [17] and Ross [2]); ci—the two previously known levels, for which the identifications have been interchanged; cd—previously known levels, for which the configuration and/or term designations have been revised; sf, pf—level values found by extrapolation using the Ritz quantum-defect or polarization formulas, respectively (see text in Section 4), in combination with the least-squares parametric fitting (see text);
g Number of connecting lines included in the level optimization procedure for this level.
Table A3. Least-squares fitting parameters for Cu II.
Table A3. Least-squares fitting parameters for Cu II.
ConfigurationParameter aLSF bSTD cGroup dHFR eLSF/HF
Even parity
3d10Eav5775.852 0.0
3d94sEav26843.521 9367.02.8658
ζ(3d)819.92.01814.71.0064
G2(3d,4s)8519.513229945.50.8566
3d94dEav119071.812 98893.71.2040
ζ(3d)827.02.01821.71.0064
ζ(4d)13.7fixed 13.71.0000
F2(3d,4d)3237.596 4085.10.7925
F4(3d,4d)1109.0fixed 1386.30.8000
G0(3d,4d)1426.847 1440.00.9908
G2(3d,4d)705.6152 1276.50.5528
G4(3d,4d)538.0228 890.60.6041
3d95sEav109078.520 92286.11.1820
ζ(3d)826.42.01821.11.0064
G2(3d,5s)1537.12421794.40.8566
3d95dEav137813.110 120253.41.1460
ζ(3d)827.62.01822.31.0064
ζ(5d)6.1fixed 6.11.0000
F2(3d,5d)1905.27351567.91.2152
F4(3d,5d)463.5fixed 579.40.8000
G0(3d,5d)455.2208616.80.7380
G2(3d,5d)412.6188559.00.7380
G4(3d,5d)290.1138393.00.7380
3d95gEav146914.99 129486.81.1346
ζ(3d)828.02.01822.71.0064
F2(3d,5g)133.4fixed 166.70.8000
F4(3d,5g)5.2fixed 6.50.8000
3d96sEav134521.020 117385.51.1460
ζ(3d)827.42.01822.11.0064
G2(3d,6s)564.892659.40.8566
3d96dEav147347.910 129891.51.1344
ζ(3d)827.82.01822.51.0064
ζ(6d)3.2fixed 3.21.0000
F2(3d,6d)952.5365783.91.2152
F4(3d,6d)240.4fixed 300.50.8000
G0(3d,6d)182.2179320.80.5680
G2(3d,6d)166.8159293.60.5680
G4(3d,6d)117.6119207.00.5680
3d96gEav152289.19 134856.31.1293
ζ(3d)828.02.01822.71.0064
F2(3d,6g)77.6fixed 97.00.8000
F4(3d,6g)3.9fixed 4.90.8000
3d97sEav145697.120 128417.01.1346
ζ(3d)827.72.01822.41.0064
G2(3d,7s)273.242318.90.8566
3d97dEav152539.110 135114.41.1290
ζ(3d)827.92.01822.61.0064
ζ(7d)1.9fixed 1.91.0000
F2(3d,7d)546.1215449.41.2152
F4(3d,7d)140.5fixed 175.60.8000
G0(3d,7d)149.8fixed 187.20.8000
G2(3d,7d)166.8fixed 172.40.8000
G4(3d,7d)117.6fixed 121.80.8000
3d97gEav155529.510 138096.91.1262
ζ(3d)828.02.01822.71.0064
F2(3d,7g)49.0fixed 61.30.8000
F4(3d,7g)2.7fixed 3.40.8000
3d98sEav151604.120 134260.11.1292
ζ(3d)827.82.01822.51.0064
G2(3d,8s)153.22.02178.90.8566
3d98dEav155694.014 138268.41.1260
ζ(3d)827.92.01822.61.0064
ζ(8d)1.2fixed 1.21.0000
F2(3d,8d)342.5135281.91.2152
F4(3d,8d)89.1fixed 111.40.8000
G0(3d,8d)95.0fixed 118.80.8000
G2(3d,8d)87.7fixed 109.60.8000
G4(3d,8d)62.0fixed 77.50.8000
3d98gEav157632.217 140200.61.1243
ζ(3d)828.02.01822.71.0064
F2(3d,8g)32.9fixed 41.10.8000
F4(3d,8g)2.0fixed 2.50.8000
3d99sEav155106.120 137730.51.1262
ζ(3d)827.92.01822.61.0064
G2(3d,9s)94.71.02110.50.8566
3d99dEav157752.114 140319.61.1242
ζ(3d)828.02.01822.71.0064
ζ(9d)0.8fixed 0.81.0000
F2(3d,9d)229.195188.51.2152
F4(3d,9d)60.0fixed 75.00.8000
G0(3d,9d)64.0fixed 80.00.8000
G2(3d,9d)59.2fixed 74.00.8000
G4(3d,9d)41.8fixed 52.20.8000
3d99gEav159073.917 141643.11.1231
ζ(3d)828.02.01822.71.0064
F2(3d,9g)23.1fixed 28.90.8000
F4(3d,9g)1.4fixed 1.70.8000
3d910sEav157351.823 139959.41.1243
ζ(3d)827.92.01822.61.0064
G2(3d,10s)62.51.0273.00.8566
3d910dEav159159.710 141729.31.1230
ζ(3d)828.02.01822.71.0064
ζ(10d)0.6fixed 0.61.0000
F2(3d,10d)160.765132.31.2152
F4(3d,10d)42.3fixed 52.90.8000
G0(3d,10d)45.1fixed 56.40.8000
G2(3d,10d)41.8fixed 52.20.8000
G4(3d,10d)29.5fixed 36.90.8000
3d910gEav160104.817 142674.41.1222
ζ(3d)828.02.01822.71.0064
F2(3d,10g)16.8fixed 21.00.8000
F4(3d,10g)1.1fixed 1.40.8000
3d84s2Eav88372.416 62522.01.4135
F2(3d,3d)91560.31143109696.00.8347
F4(3d,3d)58255.9103468373.10.8520
α(3d)93.8370.0
ζ(3d)892.231886.51.0064
3d84p2Eav188427.0fixed 162579.71.1590
F2(3d,3d)92340.01153110630.10.8347
F4(3d,3d)58793.9104469004.60.8520
α(3d)93.8370.0
F2(4p,4p)28518.8fixed 35648.50.8000
ζ(3d)898.531892.81.0064
ζ(4p)619.0fixed 619.01.0000
F2(3d,4p)12983.5fixed 16229.40.8000
G1(3d,4p)4628.9fixed 5786.10.8000
G3(3d,4p)3922.3fixed 4902.90.8000
3d84s4dEav186352.1fixed 160504.81.1610
F2(3d,3d)92375.31153110672.40.8347
F4(3d,3d)58816.8104469031.50.8520
α(3d)93.8370.0
ζ(3d)898.631892.91.0064
F2(3d,4d)5461.620854494.51.2152
G2(3d,4s)9256.3144210805.60.8566
3d84s5sEav178348.4fixed 152501.11.1695
F2(3d,3d)92277.51153110555.20.8347
F4(3d,3d)58748.9104468951.70.8520
α(3d)93.8370.0
ζ(3d)897.831892.11.0064
G2(3d,4s)9552.4148211151.30.8566
G2(3d,5s)1270.32021482.90.8566
3d84d2Eav307518.0fixed 281670.71.0918
F2(3d,3d)93279.61163111755.90.8347
F4(3d,3d)59441.2105469764.20.8520
α(3d)93.8370.0
ζ(3d)906.031900.21.0064
F2(3d,4d)7552.128856214.91.2152
3d84s5dEav209861.7fixed 184014.41.1405
F2(3d,3d)92407.31153110710.80.8347
F4(3d,3d)58838.5104469056.90.8520
α(3d)93.8370.0
ζ(3d)899.031893.31.0064
F2(3d,5d)1997.47651643.71.2152
G2(3d,4s)9429.0147211007.30.8566
Configuration interaction
3d94d-3d95dRd0(3d4d,3d5d)147.876135.31.0921
Rd2(3d4d,3d5d)2400.910862198.41.0921
Rd4(3d4d,3d5d)959.9436879.01.0921
Re0(3d4d,3d5d)1028.7466942.01.0921
Re2(3d4d,3d5d)921.6416843.91.0921
Re4(3d4d,3d5d)645.4296591.01.0921
3d94d-3d96dRd0(3d4d,3d6d)106.65697.61.0921
Rd2(3d4d,3d6d)1631.17361493.61.0921
Rd4(3d4d,3d6d)684.3316626.61.0921
Re0(3d4d,3d6d)741.5336679.01.0921
Re2(3d4d,3d6d)667.2306610.91.0921
Re4(3d4d,3d6d)467.9216428.41.0921
3d94d-3d97dRd0(3d4d,3d7d)81.54674.61.0921
Rd2(3d4d,3d7d)1212.25461110.01.0921
Rd4(3d4d,3d7d)520.2236476.31.0921
Re0(3d4d,3d7d)566.5256518.71.0921
Re2(3d4d,3d7d)510.8236467.71.0921
Re4(3d4d,3d7d)358.5166328.31.0921
3d94d-3d98dRd0(3d4d,3d8d)64.93659.41.0921
Rd2(3d4d,3d8d)950.0436869.91.0921
Rd4(3d4d,3d8d)412.8186378.01.0921
Re0(3d4d,3d8d)451.0206413.01.0921
Re2(3d4d,3d8d)407.2186372.91.0921
Re4(3d4d,3d8d)286.0136261.91.0921
3d94d-3d99dRd0(3d4d,3d9d)53.22.0648.71.0921
Rd2(3d4d,3d9d)771.9356706.81.0921
Rd4(3d4d,3d9d)338.0156309.51.0921
Re0(3d4d,3d9d)370.1176338.91.0921
Re2(3d4d,3d9d)334.4156306.21.0921
Re4(3d4d,3d9d)234.9116215.11.0921
3d94d-3d910dRd0(3d4d,3d10d)44.82.0641.01.0921
Rd2(3d4d,3d10d)643.8296589.51.0921
Rd4(3d4d,3d10d)283.4136259.51.0921
Re0(3d4d,3d10d)310.7146284.51.0921
Re2(3d4d,3d10d)281.0136257.31.0921
Re4(3d4d,3d10d)197.596180.81.0921
3d95d-3d96dRd2(3d5d,3d6d)1147.05161050.31.0921
Rd4(3d5d,3d6d)454.3206416.01.0921
Re0(3d5d,3d6d)485.8226444.81.0921
Re2(3d5d,3d6d)442.4206405.11.0921
Re4(3d5d,3d6d)311.5146285.21.0921
3d95d-3d97dRd2(3d5d,3d7d)850.8386779.11.0921
Rd4(3d5d,3d7d)346.3166317.11.0921
Re0(3d5d,3d7d)371.2176339.91.0921
Re2(3d5d,3d7d)339.0156310.41.0921
Re4(3d5d,3d7d)238.7116218.61.0921
3d95d-3d98dRd2(3d5d,3d8d)666.6306610.41.0921
Rd4(3d5d,3d8d)275.3126252.11.0921
Re0(3d5d,3d8d)295.5136270.61.0921
Re2(3d5d,3d8d)270.3126247.51.0921
Re4(3d5d,3d8d)190.696174.51.0921
3d95d-3d99dRd2(3d5d,3d9d)541.3246495.71.0921
Rd4(3d5d,3d9d)225.8106206.81.0921
Re0(3d5d,3d9d)242.4116222.01.0921
Re2(3d5d,3d9d)222.0106203.31.0921
Re4(3d5d,3d9d)156.676143.41.0921
3d95d-3d910dRd2(3d5d,3d10d)451.6206413.51.0921
Rd4(3d5d,3d10d)189.486173.41.0921
Re0(3d5d,3d10d)203.796186.51.0921
Re2(3d5d,3d10d)186.486170.71.0921
Re4(3d5d,3d10d)131.666120.51.0921
3d96d-3d97dRd2(3d6d,3d7d)631.0286577.81.0921
Rd4(3d6d,3d7d)250.7116229.61.0921
Re0(3d6d,3d7d)267.7126245.11.0921
Re2(3d6d,3d7d)245.7116225.01.0921
Re4(3d6d,3d7d)173.486158.81.0921
3d96d-3d98dRd2(3d6d,3d8d)494.0226452.31.0921
Rd4(3d6d,3d8d)199.696182.81.0921
Re0(3d6d,3d8d)213.3106195.31.0921
Re2(3d6d,3d8d)196.096179.51.0921
Re4(3d6d,3d8d)138.566126.81.0921
3d96d-3d99dRd2(3d6d,3d9d)401.0186367.21.0921
Rd4(3d6d,3d9d)163.776149.91.0921
Re0(3d6d,3d9d)175.186160.31.0921
Re2(3d6d,3d9d)161.076147.41.0921
Re4(3d6d,3d9d)113.756104.11.0921
3d96d-3d910dRd2(3d6d,3d10d)334.6156306.41.0921
Rd4(3d6d,3d10d)137.366125.71.0921
Re0(3d6d,3d10d)146.976134.51.0921
Re2(3d6d,3d10d)135.366123.91.0921
Re4(3d6d,3d10d)95.64687.51.0921
3d97d-3d98dRd2(3d7d,3d8d)382.7176350.41.0921
Rd4(3d7d,3d8d)152.876139.91.0921
Re0(3d7d,3d8d)163.076149.31.0921
Re2(3d7d,3d8d)150.276137.51.0921
Re4(3d7d,3d8d)106.05697.11.0921
3d97d-3d99dRd2(3d7d,3d9d)310.7146284.51.0921
Rd4(3d7d,3d9d)125.466114.81.0921
Re0(3d7d,3d9d)133.766122.41.0921
Re2(3d7d,3d9d)123.466113.01.0921
Re4(3d7d,3d9d)87.34679.91.0921
3d97d-3d910dRd2(3d7d,3d10d)259.2126237.31.0921
Rd4(3d7d,3d10d)105.35696.41.0921
Re0(3d7d,3d10d)112.356102.81.0921
Re2(3d7d,3d10d)103.65694.91.0921
Re4(3d7d,3d10d)73.33667.11.0921
3d98d-3d99dRd2(3d8d,3d9d)249.3116228.31.0921
Rd4(3d8d,3d9d)99.94691.51.0921
Re0(3d8d,3d9d)106.55697.51.0921
Re2(3d8d,3d9d)98.44690.11.0921
Re4(3d8d,3d9d)69.63663.71.0921
3d98d-3d910dRd2(3d8d,3d10d)207.896190.31.0921
Rd4(3d8d,3d10d)83.94676.81.0921
Re0(3d8d,3d10d)89.44681.91.0921
Re2(3d8d,3d10d)82.84675.81.0921
Re4(3d8d,3d10d)58.53653.61.0921
3d99d-3d910dRd2(3d9d,3d10d)171.386156.91.0921
Rd4(3d9d,3d10d)68.83663.01.0921
Re0(3d9d,3d10d)73.33667.11.0921
Re2(3d9d,3d10d)67.93662.21.0921
Re4(3d9d,3d10d)48.12.0644.01.0921
Odd parity
3d94pEav73281.022 53995.61.3572
ζ(3d)828.851818.31.0128
ζ(4p)538.0209444.21.2112
F2(3d,4p)13098.9152 13901.70.9423
G1(3d,4p)4368.565 5338.70.8183
G3(3d,4p)3615.9363 4299.10.8411
3d94fEav136895.617 119289.71.1476
ζ(3d)833.251822.71.0128
3d95pEav121911.624 104871.21.1625
ζ(3d)832.051821.51.0128
ζ(5p)159.869131.91.2112
F2(3d,5p)3512.52123548.40.9899
G1(3d,5p)1262.19431287.60.9802
G3(3d,5p)1174.4306101102.41.0653
3d95fEav146833.416 129308.61.1355
ζ(3d)833.251822.71.0128
3d96pEav139748.829 122652.31.1394
ζ(3d)832.751822.21.0128
ζ(6p)69.93957.71.2112
F2(3d,6p)1443.6921458.40.9899
G1(3d,6p)521.8393532.40.9802
G3(3d,6p)493.412910463.11.0653
3d96fEav152224.417 134753.41.1297
ζ(3d)833.251822.71.0128
3d96hEav152299.516 134875.81.1292
ζ(3d)833.251822.71.0128
3d97pEav148438.822 131122.81.1321
ζ(3d)833.051822.51.0128
ζ(7p)36.81.0930.41.2112
F2(3d,7p)738.742746.30.9899
G1(3d,7p)268.6203274.00.9802
G3(3d,7p)255.86710240.11.0653
3d97fEav155498.822 138032.91.1265
ζ(3d)833.251822.71.0128
3d97hEav155540.721 138110.81.1262
ζ(3d)833.251822.71.0128
3d98pEav153145.354 135833.11.1275
ζ(3d)833.151822.61.0128
ζ(8p)21.81.0918.01.2112
F2(3d,8p)429.632434.00.9899
G1(3d,8p)156.8123160.00.9802
G3(3d,8p)150.03910140.81.0653
3d98fEav157610.428 140157.81.1245
ζ(3d)833.251822.71.0128
3d98hEav157629.526 140210.61.1242
ζ(3d)833.251822.71.0128
3d84s4pEav132837.312 104548.61.2706
F2(3d,3d)92783.81194110131.50.8425
F4(3d,3d)59745.4207568667.50.8701
α(3d)84.8380.0
ζ(3d)900.851889.41.0128
ζ(4p)732.4279604.71.2112
F2(3d,4p)15857.794216019.70.9899
G2(3d,4s)8059.3145710125.00.7960
G1(3d,4p)5532.782115751.70.9619
G3(3d,4p)4703.6208124854.40.9689
G1(4s,4p)37321.352647726.60.7820
3d84s4fEav211778.8fixed 183501.61.1541
F2(3d,3d)93301.41194110745.90.8425
F4(3d,3d)60104.6208569080.20.8701
α(3d)84.8380.0
ζ(3d)905.051893.61.0128
G2(3d,4s)8816.3158711076.00.7960
3d84p4dEav244758.6fixed 216481.41.1306
F2(3d,3d)93638.61204111146.10.8425
F4(3d,3d)60341.3209569352.40.8701
α(3d)84.8380.0
ζ(3d)907.551896.11.0128
ζ(4p)873.4339721.11.2112
F2(3d,4p)17746.3105217927.60.9899
G1(3d,4p)6222.892116469.10.9619
G3(3d,4p)5367.4237125539.40.9689
3d84s5pEav195045.6fixed 166768.41.1696
F2(3d,3d)93179.21194110600.70.8425
F4(3d,3d)60019.6208568982.60.8701
α(3d)84.8380.0
ζ(3d)903.951892.51.0128
ζ(5p)182.979151.01.2112
F2(3d,5p)3559.62123596.00.9899
G2(3d,4s)8773.2158711021.90.7960
G1(3d,5p)1184.88931208.80.9802
G3(3d,5p)1145.1298101074.91.0653
G1(4s,5p)4181.2665346.90.7820
3d84s5fEav222119.6fixed 193842.41.1459
F2(3d,3d)93300.71194110745.00.8425
F4(3d,3d)60104.1208569079.80.8701
α(3d)84.8380.0
ζ(3d)905.051893.61.0128
G2(3d,4s)8827.6159711090.30.7960
a All omitted single-configuration parameters were fixed at HFR values scaled by a factor of 0.80 for the direct and exchange electrostatic parameters Fk and Gk, and 1.0 for spin-orbit parameters ζ. All omitted configuration-interaction parameters were fixed at HFR values scaled by a factor of 0.94 in both parities;
b Parameter values determined in the least-squares fitting procedure (see Section 3);
c Standard deviation of the least-squares fitting;
d Parameters within each numbered group were linked together in the LSF procedure, so that the ratios to ab initio HFR values were the same for each parameter in the group;
e The ab initio Hartree-Fock-Relativistic parameter values as computed by Cowan’s codes [52]. In this calculation, we included both relativistic and Breit corrections (in Cowan’s codes, the latter affect only the average energies of configurations) and used the scaling factor of 1.0 for the exchange contribution.

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Figure 1. Profile of the Cu II line at 12852 cm−1 (7778.7 Å) as measured in our Fourier transform spectrometers (FTS) spectrum. This line has a partially resolved hyperfine structure (HFS). The vertical line indicates the center of gravity.
Figure 1. Profile of the Cu II line at 12852 cm−1 (7778.7 Å) as measured in our Fourier transform spectrometers (FTS) spectrum. This line has a partially resolved hyperfine structure (HFS). The vertical line indicates the center of gravity.
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Figure 2. Dependence of calibration factor for interferometric measurements of Ross [2] on wavenumber. The error bars are measurement uncertainties of Ross [2] and our FTS data, combined in quadrature. The solid line is a weighted fit with two cubic polynomials stitched together at about 45000 cm−1. The dashed lines are 68% confidence intervals (±1 standard deviation) of the fit.
Figure 2. Dependence of calibration factor for interferometric measurements of Ross [2] on wavenumber. The error bars are measurement uncertainties of Ross [2] and our FTS data, combined in quadrature. The solid line is a weighted fit with two cubic polynomials stitched together at about 45000 cm−1. The dashed lines are 68% confidence intervals (±1 standard deviation) of the fit.
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Figure 3. Deviations of vacuum ultraviolet (VUV) wavelengths measured by Shenstone [1] from Ritz values from Ross [2]. The solid line is a 2nd degree polynomial fit.
Figure 3. Deviations of vacuum ultraviolet (VUV) wavelengths measured by Shenstone [1] from Ritz values from Ross [2]. The solid line is a 2nd degree polynomial fit.
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Figure 4. Boltzmann plots for relative intensities of observed lines: (a) Measurements of Hefferlin et al. [47] (H71); (b) Measurements of Neger and Jäger [49] (N88). The A-values used in these plots are the final adopted values given in Table A1. The error bars are combined uncertainties of A-values and relative intensities (see text).
Figure 4. Boltzmann plots for relative intensities of observed lines: (a) Measurements of Hefferlin et al. [47] (H71); (b) Measurements of Neger and Jäger [49] (N88). The A-values used in these plots are the final adopted values given in Table A1. The error bars are combined uncertainties of A-values and relative intensities (see text).
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Figure 5. Comparison of adjusted A-values deduced from the line ratios reported by Hefferlin et al. [47] (H71) and by Neger and Jäger [49] (N88). The error bars are combined uncertainties of the measured line ratios and adopted reference A-values.
Figure 5. Comparison of adjusted A-values deduced from the line ratios reported by Hefferlin et al. [47] (H71) and by Neger and Jäger [49] (N88). The error bars are combined uncertainties of the measured line ratios and adopted reference A-values.
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Figure 6. Comparison of transition probabilities calculated in this work (ATW) with reference values (Aref, see text). Natural logarithm of the ratio ATW/Aref is plotted against our calculated line strength, STW (in atomic units).
Figure 6. Comparison of transition probabilities calculated in this work (ATW) with reference values (Aref, see text). Natural logarithm of the ratio ATW/Aref is plotted against our calculated line strength, STW (in atomic units).
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Table 1. Spectrograms used in the present measurements.
Table 1. Spectrograms used in the present measurements.
ExposureTrackRegion (Å)Hollow Cathode UsedImpuritiesEquip. aWavelength Standards bTrack LabelDateFit Poly cSt. Dev. d
11636–827Cu/He/Ar/Ne NIVSAr II (11), Ne I (1), Cu II (TW-1) e4184/3/197420.0009
22822–1000Cu/Ge/Si/He/ArH, C, ONIVSH I (2), O I (9), O II (1), Ar II (2), Ge II (3)419_tr424/4/197420.0013
6977–1166 H, C, N, ONIVSC I (2), C II (1), N I (2), O I (7), Ar I (2), Si II (2), Ge II (3)419_tr424/4/197420.0013
35824–1020Cu/HeH, ONIVSH I (1), O I (5), Cu II (KW66-4, TW-10) f 12/17/196920.0012
471181–1360Cu/Ge/Si/He/ArH, C, N, ONIVS, LiFC I (6), N I (3), Si II (6), Ge II (1), Cu II (KW66-6, TW-1) gX431_tr2710/24/197420.0024
81339–1527 NIVS, LiFC I (4), O I (1), Cu II (KW66-48)X431_tr2710/24/19742, 3 k0.0021
591399–1590Cu/He/ArC, NNIVSC I (1), Cu II (KW66-62, TW-4) h 12/16/19692, 2 l0.0010
6101398–1584Cu/Si/He/NeC, NNIVSC I (3), Si II (1), Cu II (KW66-44, TW-1) i 1/15/197020.0012
171920–2106 NIVSC I (1), Cu II (R69-20) 1/15/197020.0021
7111399–1587Cu/Ge/Si/HeC, NNIVSC I (3), N I (1), Si II (2), Ge II (2), Cu II (KW66-66)X434_tr5211/11/197430.0014
141560–1743 NIVSC I (5), N I (1), Ge II (3), Cu II (KW66-21)X434_tr5211/11/197430.0016
8121394–1584Cu/Ge/Si/HeC, NNIVSC I (3), Si II (2), Ge II (3), Cu II (KW66-52)X434_tr2711/11/197420.0016
131559–1743 NIVSC I (1), Si I (3), Ge II (1), Cu I (1), Cu II (KW66-14)X434_tr2711/11/197420.0019
151751–1939 NIVSSi I (7), Si II (1), Cu I (1), Cu II (KW66-5)X434_tr2711/11/197420.0017
9161790–1980Cu/Si/HeCNIVSC I (1), Cu I (1), Cu II (KW66-4, R69-1, TW-2) j 11/10/196940.0012
10181977–2162Cu/Ge/Si/HeH, C, ONIVSSi I (2), Ge I (6), Ge II (2), Cu I (I), Cu II (R69-11)X433_tr2711/7/197420.0016
202139–2315 NIVSSi I (4), Ge I (1), Cu I (4), Cu II (R69-26)X433_tr2711/7/197450.0021
212336–2517 NIVSSi I (3), Cu I (1), Cu II (R69-13)X433_tr2711/7/197430.0017
222490–2682 NIVSO I (3), Si I (7), Ge I (3), Ge II (1), Cu II (KW66-2, R69-5)X433_tr2711/7/197420.0011
11192117–2310Cu/Ge/Si/He NIVSSi I (2), Ge I (1), Cu I (4), Cu II (R69-20)E16-36/3/196920.0019
121792–3324Cu/Ge/Pt/Fe/Ne FTSGe I-II (37) 200211.7 × 10−8
131825–3324Cu/Ge/Pt/Fe/Ne FTSGe I-II (37) 200212.0 × 10−8
142769–11733Cu/Re/Ar/He FTSAr II (68) 200912.0 × 10−9
a Equipment used: NIVS = Normal Incidence Vacuum Spectrograph (NIST, 10.7 m grating, reciprocal linear dispersion 0.78 Å); FTS = Fourier Transform Spectrometer (NIST, FT700 0.2 m vacuum FTS for spectra 12 and 13, and a 2 m vacuum FTS for spectrum 14); LiF = a LiF window was used to remove higher diffraction orders;
b The number of spectral lines of each spectrum used as standards is given in parentheses. Unless otherwise indicated, the standard wavelengths used in grating measurements were the Ritz wavelengths taken from the ASD database [19]. For Cu II lines used as standards, the references are as follows: KW66—Kaufman and Ward [15]; R69—Ross [2]; TW—this work. Standards used in the FTS measurements are described in the text;
c Power of the polynomial used to fit standard lines;
d For grating spectra (exposures 1–11), standard deviation of the measured wavenumbers of the standard lines from the fitted polynomial (Å); For FTS spectra (exposures 12–14), standard deviation of the correction factor from the linear fit (dimensionless);
e Cu II line at 826.9946 Å measured in 1st order on track 2 was used as standard on track 1;
f Ten Cu II lines measured in 1st order on track 2 were used as standards on track 5;
g Cu II line at 1275.5713 Å measured in 2nd order on track 22 was used as standard on track 7;
h Four Cu II lines measured in 1st order on tracks 10–12 were used as standards on track 9;
i Cu II line at 1407.1688 Å measured in 1st order on tracks 8, 11, and 12 was used as standard on track 10;
j Two Cu II lines measured in 1st order on track 15 were used as standards on track 16;
k Long-wavelength end of track 8 was fitted separately with a cubic polynomial;
l Short-wavelength end of track 9 was fitted separately with a 2nd degree polynomial.

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Kramida, A.; Nave, G.; Reader, J. The Cu II Spectrum. Atoms 2017, 5, 9. https://doi.org/10.3390/atoms5010009

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Kramida A, Nave G, Reader J. The Cu II Spectrum. Atoms. 2017; 5(1):9. https://doi.org/10.3390/atoms5010009

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Kramida, Alexander, Gillian Nave, and Joseph Reader. 2017. "The Cu II Spectrum" Atoms 5, no. 1: 9. https://doi.org/10.3390/atoms5010009

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