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Article

Spectrum of Sn5+ in the Region 500–1300 Å

Institute of Spectroscopy, Russian Academy of Sciences, Moscow 108840, Russia
*
Author to whom correspondence should be addressed.
Atoms 2017, 5(4), 47; https://doi.org/10.3390/atoms5040047
Submission received: 3 October 2017 / Revised: 7 November 2017 / Accepted: 8 November 2017 / Published: 18 November 2017

Abstract

:
The spectrum of tin, excited in a vacuum spark, was recorded in the region 500–1131 Å on a 6.65-m normal incidence spectrograph. The transitions between 4d85s, 4d86s, 4d85p and 4d85d excited configurations in Sn VI were studied. More than 500 lines of the 4d85p–4d85d and 4d85p–4d86s were identified with the aid of the Cowan code calculations. 67 energy levels (out of 70 possible levels of the 4d85d configuration) and all but two 4d86s levels were found. The wavelength of the 4d85s–4d85p transitions in the region 839–1131 Å were re-measured and supplemented by Sn VI lines in the region 1131–1300 Å measured previously by Srivastava et al. (1977) for optimisation of the energy level values. The SnVI line list in the region 500–1300 Å contains now 741 lines with calculated transition probabilities.

1. Introduction

The five times ionized tin has the ground state configuration 4d9. The resonance 4d9–4d85p transitions and the transitions between first excited configurations 4d85s and 4d85p were studied in [1,2]. All levels of these configurations were established. Later, 85 transitions from the 4d84f and 4d86p configurations to the ground 4d9 2D3/2,5/2 levels were identified [3]. In the 4d8(4f + 6p) configuration complex, 63 of the total 126 levels have been established. Recently, we reported the preliminary results of a study of the 4d85p–4d85d transitions in the region 680–850 Å [4]. In this article, we describe extensive analysis of the Sn5+ spectrum in the region 500–1131 Å resulting in identification of the 4d85p–4d85d and of the 4d85p–4d86s transitions and location of almost all levels of the 4d85d and 4d86s configurations.

2. Experimental Details

The spectrum of tin was recorded on the SWR plates using the 6.65-m normal incidence spectrograph of the Institute of Spectroscopy. With 1200 L/mm grating it has plate factor 1.25 Å/mm. The spectrum was excited in a vacuum spark discharge with electric parameters of the circuit: C = 7500 μF, U = 220 V and L = 8 and 25 μH. The plates were measured on an Epson Expression 10000XL scanner (Seiko Epson Corporation, Suwa, Japan). It was found [5], that a flatbed scanner, in their case Epson Expression XL11000, can have periodic errors with an amplitude up to 0.05 mm in the direction perpendicular to the linear detector in scanner (horizontally on the scanner bed) and almost no errors in the direction parallel to the detector. Therefore, our plates were scanned in a position vertically on the scanner bed.
The wavelengths were calculated using the impurity lines of aluminum, oxygen, silicon and carbon of different stages of the ionization [6] as the references. One standard deviation of the reference lines 0.006 Å was adopted as the measurement uncertainty for sharp unblended lines. Relative intensity of the lines is affected by wavelength dependence of the spectrograph effectivity and photoplate sensitivity, which were not taken into account. The saturation effects strongly influenced the intensities of strong lines. Thus, the measured intensities have mostly qualitative character.

3. Results

The analysis was guided by the Cowan code [7] calculations of the energy levels and transition probabilities. The matrices of the 4d9 + 4d8(5s–7s) + 4d8(5d–7d) + 4d75s2 and 4d85p + 4d86p + 4d84f + 4d85f + 4p5d10 configurations were used respectively for the even and odd levels. The energy parameters for the 4d85s and 4d85p configurations were obtained by a fitting of the calculated energy levels to the levels known from [2]. Initial energy parameters in the 4d85d and 4d86s configurations for the 4d–4d and 4d–6s interactions were obtained by a scaling of the corresponding ab initio Hartree–Fock integrals on the ratios of fitted to Hartree–Fock parameters (scaling factors) obtained for the Sn VI 4d85s configuration. The scaling factors for the 4d–5d interaction parameters were taken from In V [8]. The levels of the 4d84f + 4d86p configurations were predicted with the energy parameters from [3]. All parameters of the other unknown configurations were kept at the Hartree–Fock values. Thus, the predicted spectrum was used for the identification of the Sn VI lines with the aid of the IDEN code [9].
Identified lines of the 4d85p–4d85d and 4d85p–4d86s transitions in the region 510–1052 Å with calculated transition probabilities are presented in Table A1 (see Appendix A at the end of the document). It contains 518 newly identified lines, 24 of which are doubly identified. Previously identified lines of the 4d85s–4d85p transitions [2] falling in our region (up to 1131 Å) were re-measured and listed in Table A1 in comparison with previous measurements. They are supplemented by sixty lines from 1137 Å through 1276 Å from [2] for completeness of the 4d85s–4d85p transition array.
The energy levels of the 4d85d and 4d86s configurations found from the identified lines are given in Table A2. Kramida’s code LOPT [10] was used for the optimization of the level energies. In the optimization procedure, doubly classified, masked, blended, wide and weak lines were given a reduced weight. The uncertainties of the levels relative to each other given by LOPT are also listed. For consistency with our wavelength measurements, previously known 4d85s and 4d85p levels were also optimized and are given in Table A2 and Table A3. A difference with previous values for the 4d85p level energies is shown in Figure 1.
Although our wavelengths for the 4d85s–4d85p transitions generally agree with previous measurements [2] within mutual measurement uncertainties, linear systematic shift exists up to 0.015 Å in going from longer to shorter wavelengths. It is reflected in a trend of the difference for the level energies visible in Figure 1. The 311.827 Å line of the 4d9 2D5/2–4d85p (3F2)D5/2 transition [1] was used for a connection of the levels of the excited configurations to the ground level. With estimated 0.005 Å uncertainty of this line [1] it gives 5 cm−1 for the uncertainties of excited levels relative to the ground level.
As it is often the case for the ions with the 4dk ground state configuration, the designation of a level by the first component of its eigenvector is sometimes ambiguous (see, for example, 237,695.74 and 242,240.86 cm−1 levels having first component respectively 52% and 47% from the same 5s(3P)4P3/2 level). For this reason, the energy level value is given in Table A1 in addition to the designation by the first eigenvector component.
The configuration interaction within the low lying excited configurations included in the calculation is seen in the eigenvector composition limited to three components only for two levels. The 5d(1G)2H9/2 at 475,041.6 cm−1 has 25% contribution from the levels of the 4d75s2 configuration and the 6s(1D)2D5/2 level at 509,540.7 cm−1 is mixed with the 5d(1S)2D5/2 level.
The energy parameters and rms level deviations obtained after final fitting of the known levels are given in Table A4. As in preliminary calculations, the matrices of the 4d9 + 4d8(5s–7s) + 4d8(5d–7d) + 4d75s2 and 4d85p + 4d86p + 4d84f + 4d85f + 4p5d10 configurations were used. Only parameters of known configurations are listed in Table A4. The parameters of unknown 4d8nl configurations were tied at the Hartree–Fock ratios with the corresponding parameters of these configurations. Their average energies Eav were shifted with respect to the Hartree–Fockenergies on the values obtained for 4d85p and 4d86s configurations. Hartree–Fock average energies are defined such that the ground level energy of the 4d9 + 4d8(5s–7s) + 4d8(5d–7d) + 4d75s2 configurations is equal to zero. Ab initio Eav for the ground level configuration 4d9 in this case appears to be equal to 5338 cm−1. The average energy of the 4d75s2 configuration was taken lower by 6500 cm−1 than the one given by the ab initio calculation. This value was estimated from the shift of the 4d85s2 configuration in SnV [11] calculated with similar set of the configurations as in Sn VI. All configuration interaction parameters were fixed on values obtained with scaling by 0.85 of the Hartree–Fock integrals.
Good consistency of all relevant energy parameters for all studied configurations within the limit of their uncertainties should be noted. Due to extended set of interacting odd configurations rms deviation of the fitting for the 4d85p levels 61 cm−1 is 2.5 times smaller than in the one configuration approximation (151 cm−1) in the work by Srivastava et al. [2].

Acknowledgments

The work was supported by the Russian Foundation for Basic Research, grant No. 16-02-00753a.

Author Contributions

All authors contributed equally to this work.

Conflicts of Interest

The authors declare no conflict of interest.

Appendix A

Table A1. Identified lines of the transitions between 4d85s, 4d86s, 4d85p and 4d85d configurations in the spectrum of Sn5+.
Table A1. Identified lines of the transitions between 4d85s, 4d86s, 4d85p and 4d85d configurations in the spectrum of Sn5+.
I agA, (107 s−1)λ (Å) bo–c, (Å) cλp (Å) dλ–λp, (Å)ν (cm−1)Lower LevelUpper Level
DesignationE (cm−1)DesignationE (cm−1)
1397510.301−0.017 195,962.85p(3F)4D7/2303,941.86s(3P)4P5/2499,898.2
1749526.120−0.002 190,070.95p(1D)2D3/2315,238.16s(3P)4P1/2505,308.4
8170530.922−0.006 188,351.75p(3F)4D3/2317,515.306s(3P)4P3/2505,864.7
10171540.276−0.008 185,090.55p(3F)4F7/2326,592.686s(1G)2G9/2511,680.3
32362548.289−0.008 182,385.65p(3F)4D3/2317,515.306s(3P)4P5/2499,898.2
29471550.079−0.006 181,792.05p(3P)4P1/2324,074.76s(3P)4P3/2505,864.7
21242550.541−0.001 181,639.45p(3F)4D5/2311,448.436s(3F)2F5/2493,087.6
13208550.851−0.007 181,537.25p(3P)4P3/2323,773.576s(3P)4P1/2505,308.4
25143553.679−0.002 180,610.25p(3P)4P5/2325,255.346s(3P)4P3/2505,864.7
1364555.6130.008 179,981.55p(3F)4F3/2330,063.756s(1D)2D3/2510,047.7
21201555.942−0.007 179,875.05p(3F)2D5/2320,690.136s(3P)2P3/2500,562.7
121926556.772−0.001 179,606.65p(3F)4D5/2311,448.436s(3F)4F7/2491,054.8
36427558.007−0.003 179,209.25p(3F)2D5/2320,690.136s(3P)4P5/2499,898.2
34251559.4230.001 178,755.65p(3P)4P5/2331,291.856s(1D)2D3/2510,047.7
3912652559.757−0.004 178,649.05p(3F)4D7/2303,941.86s(3F)4F9/2482,589.5
46346561.529−0.005 178,085.15p(3F)4G5/2315,004.026s(3F)2F5/2493,087.6
2653014561.9120.001 177,963.95p(1G)2H9/2333,754.86s(1G)2G7/2511,718.9
54655562.032−0.001 177,925.75p(1G)2H9/2333,754.86s(1G)2G9/2511,680.3
2401433562.275db−0.004 177,849.05p(1G)2F7/2333,832.66s(1G)2G9/2511,680.3
240851562.275db0.001 177,849.05p(1D)2D3/2315,238.16s(3F)2F5/2493,087.6
208846564.511db0.019 177,144.45p(3F)4G5/2315,004.026s(3F)4F3/2492,154.4
208894564.511db−0.008 177,144.45p(3F)4G7/2313,912.996s(3F)4F7/2491,054.8
1961441564.8680.002 177,032.55p(3F)4G7/2313,912.996s(3F)4F5/2490,946.0
44283565.2500.011 176,912.95p(1D)2D3/2315,238.16s(3F)4F3/2492,154.4
13112565.643−0.003 176,789.95p(3P)4P3/2323,773.576s(3P)2P3/2500,562.7
2852178566.2030.001 176,615.25p(3F)4G9/2307,476.06s(3F)2F7/2484,091.6
76611567.777−0.003 176,125.55p(3P)4P3/2323,773.576s(3P)4P5/2499,898.2
48390568.0220.004 176,049.55p(3F)4G5/2315,004.026s(3F)4F7/2491,054.8
76584568.369−0.001 175,942.25p(3F)4G5/2315,004.026s(3F)4F5/2490,946.0
18175568.8380.013 175,796.85p(3F)4F3/2330,063.756s(3P)4P3/2505,864.7
54240569.127db0.001 175,707.75p(1D)2D3/2315,238.16s(3F)4F5/2490,946.0
54174569.127db0.001 175,707.75p(1G)2F7/2333,832.66s(1D)2D5/2509,540.7
2781435571.054−0.004 175,114.75p(3F)4G9/2307,476.06s(3F)4F9/2482,589.5
79782571.2770.000 175,046.45p(3P)4D7/2336,634.026s(1G)2G9/2511,680.3
106191572.608db−0.002 174,639.65p(3F)4D3/2317,515.306s(3F)4F3/2492,154.4
106796572.608db0.011 174,639.65p(3P)4P5/2325,255.346s(3P)4P5/2499,898.2
959572.8330.006 174,570.95p(3P)4P5/2331,291.856s(3P)4P3/2505,864.7
43616573.245−0.001 174,445.45p(3P)2D5/2335,602.726s(1D)2D3/2510,047.7
104473574.904−0.013 173,941.95p(3P)2D5/2335,602.726s(1D)2D5/2509,540.7
109549576.6040.005 173,429.35p(3F)4D3/2317,515.306s(3F)4F5/2490,946.0
1195577.165−0.003 173,260.65p(3F)2F7/2319,827.766s(3F)2F5/2493,087.6
16208577.8220.002 173,063.85p(3F)2D3/2336,476.336s(1D)2D5/2509,540.7
68398578.8870.000 172,745.25p(3F)4D1/2319,409.186s(3F)4F3/2492,154.4
160707579.2310.001 172,642.85p(3F)4D5/2311,448.436s(3F)2F7/2484,091.6
46514581.568−0.003 171,949.05p(1D)2D5/2339,770.876s(1G)2G7/2511,718.9
16169582.1260.003 171,784.15p(1D)2P1/2334,079.86s(3P)4P3/2505,864.7
33431582.806−0.001 171,583.65p(3P)2P3/2334,281.536s(3P)4P3/2505,864.7
173646583.197db−0.015 171,468.85p(3F)2D5/2320,690.136s(3F)4F3/2492,154.4
173892583.197db0.018 171,468.85p(3F)2F5/2329,088.516s(3P)2P3/2500,562.7
53413584.3960.004 171,116.95p(3F)2F7/2319,827.766s(3F)4F5/2490,946.0
6104586.1160.000 170,614.65p(1D)2P3/2339,432.976s(1D)2D3/2510,047.7
10114586.510−0.004 170,500.15p(3F)4F3/2330,063.756s(3P)2P3/2500,562.7
50383586.9810.005 170,363.25p(3F)2D5/2320,690.136s(3F)4F7/2491,054.8
44341587.2840.005 170,275.45p(1D)2D5/2339,770.876s(1D)2D3/2510,047.7
22130587.341−0.010 170,258.85p(3F)2D5/2320,690.136s(3F)4F5/2490,946.0
85459587.6190.001 170,178.35p(3F)4G7/2313,912.996s(3F)2F7/2484,091.6
27283587.8640.001 170,107.45p(1D)2P3/2339,432.976s(1D)2D5/2509,540.7
23348588.389−0.004 169,955.65p(3P)4D1/2335,354.16s(3P)4P1/2505,308.4
32305589.032−0.001 169,770.15p(1D)2D5/2339,770.876s(1D)2D5/2509,540.7
46368590.7700.001 169,270.65p(3P)4P5/2331,291.856s(3P)2P3/2500,562.7
4443727591.2350.007 169,137.35p(1G)2H11/2342,540.96s(1G)2G9/2511,680.3
24228592.1010.003 168,890.25p(3P)4D5/2342,827.906s(1G)2G7/2511,718.9
29314592.301−0.003 168,833.05p(3F)2D3/2336,476.336s(3P)4P1/2505,308.4
43336593.1010.004 168,605.25p(3P)4P5/2331,291.856s(3P)4P5/2499,898.2
88796593.7300.001 168,426.85p(3P)2P3/2341,620.56s(1D)2D3/2510,047.7
59356593.8950.003 168,379.95p(3P)4P3/2323,773.576s(3F)4F3/2492,154.4
6403702597.5540.002 167,349.05p(3F)4G11/2315,239.916s(3F)4F9/2482,589.5
2942598.1880.004 167,171.45p(3P)4P3/2323,773.576s(3F)4F5/2490,946.0
6483051599.8880.001 166,697.95p(3F)4G9/2324,356.636s(3F)4F7/2491,054.8
48213601.8620.003 166,151.05p(3F)4F5/2324,902.966s(3F)4F7/2491,054.8
78484602.0720.002 166,093.25p(1D)2D5/2339,770.876s(3P)4P3/2505,864.7
198856602.1760.004 166,064.45p(1G)2F7/2333,832.66s(3P)4P5/2499,898.2
1871006602.253−0.001 166,043.35p(3F)4F5/2324,902.966s(3F)4F5/2490,946.0
21241602.4130.004 165,999.05p(1D)2F7/2345,680.166s(1G)2G9/2511,680.3
1177602.8650.003 165,874.55p(1D)2P3/2339,432.976s(3P)4P1/2505,308.4
3191949603.0190.003 165,832.35p(3F)2G7/2327,254.466s(3F)2F5/2493,087.6
1352603.130−0.008 165,801.65p(3P)4P5/2325,255.346s(3F)4F7/2491,054.8
88102603.5360.002 165,690.25p(3P)4P5/2325,255.346s(3F)4F5/2490,946.0
2801192604.4380.000 165,442.95p(3F)4F9/2318,648.66s(3F)2F7/2484,091.6
46336606.2120.005 164,958.75p(3P)2D5/2335,602.726s(3P)2P3/2500,562.7
163945606.9560.002 164,756.65p(1G)2F5/2346,961.726s(1G)2G7/2511,718.9
2921428608.0450.003 164,461.45p(3F)4F7/2326,592.686s(3F)4F7/2491,054.8
46146608.6610.001 164,295.15p(3P)2D5/2335,602.726s(3P)4P5/2499,898.2
4671787608.7810.004 164,262.85p(3F)2F7/2319,827.766s(3F)2F7/2484,091.6
51252609.4370.002 164,085.95p(3F)2D3/2336,476.336s(3P)2P3/2500,562.7
3061039610.2750.000 163,860.55p(1D)2F7/2345,680.166s(1D)2D5/2509,540.7
54121610.5040.005 163,799.15p(3F)2G7/2327,254.466s(3F)4F7/2491,054.8
84230611.9950.006 163,400.05p(3F)2D5/2320,690.136s(3F)2F7/2484,091.6
2321358612.5070.002 163,263.55p(3P)4D7/2336,634.026s(3P)4P5/2499,898.2
59467613.1780.005 163,084.75p(1G)2F5/2346,961.726s(1D)2D3/2510,047.7
61274613.2580.009 163,063.65p(3F)2F5/2329,088.516s(3F)4F3/2492,154.4
160988613.3610.003 163,036.15p(3P)4D5/2342,827.906s(3P)4P3/2505,864.7
61178613.4070.000 163,024.05p(3F)4F3/2330,063.756s(3F)2F5/2493,087.6
68118614.109−0.011 162,837.75p(3P)4S3/2347,213.076s(1D)2D3/2510,047.7
3365614.384−0.011 162,764.65p(3F)2F7/2319,827.766s(3F)4F9/2482,589.5
21184615.0860.000 162,579.05p(1G)2F5/2346,961.726s(1D)2D5/2509,540.7
29140616.0430.005 162,326.35p(3P)4S3/2347,213.076s(1D)2D5/2509,540.7
35300618.0660.003 161,794.95p(3P)4P5/2331,291.856s(3F)2F5/2493,087.6
50466620.6240.006 161,128.35p(1D)2P3/2339,432.976s(3P)2P3/2500,562.7
23103621.2460.011 160,966.75p(3P)2D3/2344,338.76s(3P)4P1/2505,308.4
30210621.5790.007 160,880.55p(3F)4F3/2330,063.756s(3F)4F5/2490,946.0
14102621.6500.001 160,862.25p(3P)4P5/2331,291.856s(3F)4F3/2492,154.4
2982258622.2790.003 160,699.55p(1G)2G7/2351,018.76s(1G)2G7/2511,718.9
1584623.1950.007 160,463.55p(1D)2P3/2339,432.976s(3P)4P5/2499,898.2
68562625.448−0.005 159,885.45p(1D)2P1/2350,163.56s(1D)2D3/2510,047.7
109445626.620−0.005 159,586.45p(1G)2G9/2352,133.86s(1G)2G7/2511,718.9
5422488626.775−0.001 159,546.85p(1G)2G9/2352,133.86s(1G)2G9/2511,680.3
197230628.183−0.002 159,189.25p(3F)4F5/2324,902.966s(3F)2F7/2484,091.6
2179629.154−0.005 158,943.55p(3P)2P3/2341,620.56s(3P)2P3/2500,562.7
117530629.577−0.002 158,836.75p(3P)4P5/2325,255.346s(3F)2F7/2484,091.6
68337630.303−0.009 158,654.05p(3P)4S3/2347,213.076s(3P)4P3/2505,864.7
56187633.415−0.006 157,874.35p(3P)2P3/2334,281.536s(3F)4F3/2492,154.4
123168634.630−0.004 157,572.15p(3F)4D7/2303,941.85d(3P)4F9/2461,513.0
48127635.073−0.004 157,462.25p(3F)4D5/2311,448.435d(1D)2F7/2468,909.5
2289636.035−0.008 157,224.15p(1G)2F7/2333,832.66s(3F)4F7/2491,054.8
24136636.652−0.006 157,071.85p(3P)4D5/2342,827.906s(3P)4P5/2499,898.2
48176637.742−0.012 156,803.25p(3P)4D1/2335,354.16s(3F)4F3/2492,154.4
3343641.0400.002 155,996.45p(3F)4F7/2326,592.686s(3F)4F9/2482,589.5
41124642.034−0.016 155,754.95p(3P)2S1/2344,811.66s(3P)2P3/2500,562.7
2515642.4450.000 155,655.35p(1D)2D3/2315,238.15d(3P)4P5/2470,893.4
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431481013.4840.0031013.494−0.01098,669.55s(3F)4F5/2226,585.525p(3P)4P5/2325,255.34
9899831015.2910.0041015.2760.01598,493.95s(1S)2S1/2283,847.95p(1S)2P3/2382,342.2
8196871017.1200.0061017.124−0.00498,316.85s(3F)4F5/2226,585.525p(3F)4F5/2324,902.96
74801017.624−0.0021017.636−0.01298,268.25s(3F)2F5/2237,334.765p(3P)2D5/2335,602.72
24301018.169−0.0011018.180−0.01198,215.55s(3P)2P1/2248,997.615p(3P)4S3/2347,213.07
119961018.480−0.0031018.492−0.01298,185.55s(3P)4P5/2231,878.535p(3F)4F3/2330,063.75
9148111019.816−0.0221019.847−0.03198,056.95s(1G)2G7/2248,906.985p(1G)2F5/2346,961.72
3112351021.376−0.0021021.388−0.01297,907.15s(3P)4P3/2237,695.745p(3P)2D5/2335,602.72
97610091021.6110.0001021.620−0.00897,884.65s(3F)4F7/2221,943.155p(3F)2F7/2319,827.76
37481022.161−0.0011022.172−0.01297,832.05s(3P)2P3/2249,381.165p(3P)4S3/2347,213.07
77801022.400−0.0021022.413−0.01397,809.05s(1D)2D5/2246,529.845p(3P)2D3/2344,338.7
2283441024.7960.0021024.803−0.00797,580.45s(3P)2P3/2249,381.165p(1G)2F5/2346,961.72
6905111025.324−0.0021025.333−0.00997,530.25s(3P)4P3/2242,240.865p(1D)2D5/2339,770.87
98729671027.041−0.0011027.043−0.00297,367.15s(3F)4F9/2217,872.985p(3F)4G11/2315,239.91
5443301028.694−0.0071028.709−0.01597,210.65s(3P)4P5/2231,878.535p(3F)2F5/2329,088.51
2061771028.8990.0091028.8940.00597,191.25s(3P)4P3/2242,240.865p(1D)2P3/2339,432.97
361251028.952db0.0191028.965−0.01397,186.35s(3F)4F5/2226,585.525p(3P)4P3/2323,773.57
361761028.952db−0.0131028.965 97,186.35s(3F)2F7/2230,069.485p(3F)2G7/2327,254.46
2141029.1420.0011029.153−0.01197,168.35s(3F)4F3/2228,086.865p(3P)4P5/2325,255.34
3661651031.1260.0001031.133−0.00796,981.45s(1G)2G9/2248,698.765p(1D)2F7/2345,680.16
26641031.492−0.0021031.504−0.01296,947.05s(3F)2F5/2237,334.765p(3P)2P3/2334,281.53
96491032.877−0.0091032.899−0.02296,816.95s(3F)4F3/2228,086.865p(3F)4F5/2324,902.96
63761033.339−0.0051033.354−0.01596,773.75s(1G)2G7/2248,906.985p(1D)2F7/2345,680.16
9827591034.0730.0051034.082−0.00996,705.05s(3F)4F7/2221,943.155p(3F)4F9/2318,648.6
98310291036.0240.0041036.027−0.00396,522.85s(3F)2F7/2230,069.485p(3F)4F7/2326,592.68
1651001037.505−0.0111037.512−0.00796,385.15s(3P)4P3/2237,695.745p(1D)2P1/2334,079.8
42491038.441−0.0021038.449−0.00896,298.25s(1D)2D5/2246,529.845p(3P)4D5/2342,827.90
1872321038.8250.0001038.832−0.00796,262.65s(3P)4P1/2240,213.795p(3F)2D3/2336,476.33
1261041.8010.0031041.803−0.00295,987.65s(3F)4F3/2228,086.865p(3P)4P1/2324,074.7
3033051043.6940.0051043.700−0.00695,813.55s(3P)2P1/2248,997.615p(3P)2S1/2344,811.6
7912821045.0780.0011045.086−0.00895,686.65s(3F)4F3/2228,086.865p(3P)4P3/2323,773.57
23401047.8870.0031047.895−0.00895,430.15s(3P)2P3/2249,381.165p(3P)2S1/2344,811.6
9738041048.480−0.0031048.485−0.00595,376.25s(3P)4P5/2231,878.535p(3F)2G7/2327,254.46
9805901048.855−0.0101048.860−0.00595,342.05s(3P)2P1/2248,997.615p(3P)2D3/2344,338.7
571891050.575−0.0011050.580−0.00595,186.05s(3F)2F7/2230,069.485p(3P)4P5/2325,255.34
3052131051.0830.0041051.089−0.00695,139.95s(3P)4P1/2240,213.795p(3P)4D1/2335,354.1
1281052.443−0.002 95,017.05p(1D)2F7/2345,680.165d(3F)4D5/2440,697.0
921051053.1020.0001053.105−0.00394,957.55s(3P)2P3/2249,381.165p(3P)2D3/2344,338.7
5733031054.477−0.0031054.483−0.00694,833.75s(3F)2F7/2230,069.485p(3F)4F5/2324,902.96
8672981055.8080.0001055.812−0.00494,714.25s(3P)4P5/2231,878.535p(3F)4F7/2326,592.68
98518331060.5910.0011060.593−0.00294,287.05s(3F)2F7/2230,069.485p(3F)4G9/2324,356.63
84741062.6480.0011062.6470.00194,104.65s(3F)4F5/2226,585.525p(3F)2D5/2320,690.13
12401063.060−0.0031063.065−0.00594,068.05s(3P)4P1/2240,213.795p(3P)2P3/2334,281.53
5674701064.313−0.0031064.3100.00393,957.35s(3F)2F5/2237,334.765p(3P)4P5/2331,291.85
1581661064.7280.0021064.729−0.00193,920.75s(1G)2G7/2248,906.985p(3P)4D5/2342,827.90
976351065.3630.0141065.354−0.01193,864.75s(3P)4P1/2240,213.795p(1D)2P1/2334,079.8
98127021065.618−0.0011065.6160.00293,842.25s(1G)2G9/2248,698.765p(1G)2H11/2342,540.9
3463061068.419−0.0021068.4180.00193,596.25s(3P)4P3/2237,695.745p(3P)4P5/2331,291.85
3894071070.128−0.0011070.130−0.00293,446.85s(3P)2P3/2249,381.165p(3P)4D5/2342,827.90
8064861070.929−0.0011070.931−0.00293,376.95s(3P)4P5/2231,878.535p(3P)4P5/2325,255.34
39341071.1030.0021071.1020.00193,361.75s(3P)4P3/2242,240.865p(3P)2D5/2335,602.72
6362021072.4780.0031072.483−0.00593,242.05s(3F)4F5/2226,585.525p(3F)2F7/2319,827.76
6362791072.478−0.0111072.483 93,242.05s(1D)2D5/2246,529.845p(1D)2D5/2339,770.87
25241073.958−0.0041073.966−0.00893,113.65s(3P)4P3/2242,240.865p(3P)4D1/2335,354.1
62271074.562−0.0031074.567−0.00593,061.15s(3F)4F7/2221,943.155p(3F)4G5/2315,004.02
2862101076.3920.0021076.3870.00592,903.05s(1D)2D5/2246,529.845p(1D)2P3/2339,432.97
3272091078.410−0.0011078.411−0.00192,729.15s(3F)2F5/2237,334.765p(3F)4F3/2330,063.75
8274621079.872−0.0041079.873−0.00192,603.65s(3F)4F3/2228,086.865p(3F)2D5/2320,690.13
3196501084.133−0.0031084.1320.00192,239.65s(3P)2P3/2249,381.165p(3P)2P3/2341,620.5
1132321086.4760.0001086.4740.00292,040.75s(3P)4P3/2242,240.865p(3P)2P3/2334,281.53
9746211087.3130.0001087.3110.00291,969.95s(3F)4F7/2221,943.155p(3F)4G7/2313,912.99
118681088.2030.0041088.1960.00791,894.75s(3P)4P5/2231,878.535p(3P)4P3/2323,773.57
4532411088.857−0.0061088.8500.00791,839.45s(3P)4P3/2242,240.865p(1D)2P1/2334,079.8
1701361089.8820.0081089.8720.01091,753.15s(3F)2F5/2237,334.765p(3F)2F5/2329,088.51
6665471094.1860.0071094.1770.00991,392.25s(3P)4P3/2237,695.745p(3F)2F5/2329,088.51
8332661095.0250.0021095.0180.00791,322.15s(3F)4F3/2228,086.865p(3F)4D1/2319,409.18
9393241099.7490.0001099.7450.00590,929.85s(3F)4F5/2226,585.525p(3F)4D3/2317,515.30
3663341100.5520.0051100.5450.00790,863.55s(1G)2G7/2248,906.985p(1D)2D5/2339,770.87
8443481103.5030.0021103.4920.01290,620.55s(3F)2F7/2230,069.485p(3F)2D5/2320,690.13
38431105.759−0.0041105.7570.00290,435.75s(3P)2P1/2248,997.615p(1D)2P3/2339,432.97
1011105.915−0.004 90,422.85p(1G)2G9/2352,133.85d(3F)2H11/2442,556.3
88861106.3250.0041106.3220.00390,389.35s(3P)2P3/2249,381.165p(1D)2D5/2339,770.87
1882091111.7750.0031111.776−0.00189,946.35s(1D)2D5/2246,529.845p(3F)2D3/2336,476.33
6713121112.1070.0031112.107089,919.45s(3F)2F5/2237,334.765p(3F)2G7/2327,254.46
8633261114.100−0.0031114.0990.00189,758.55s(3F)2F7/2230,069.485p(3F)2F7/2319,827.76
9507501116.031−0.0031116.0270.00489,603.25s(3F)4F9/2217,872.985p(3F)4G9/2307,476.0
9437801117.252−0.0011117.2460.00589,505.45s(3F)4F7/2221,943.155p(3F)4D5/2311,448.43
4251061118.211−0.0021118.211089,428.65s(3F)4F3/2228,086.865p(3F)4D3/2317,515.30
259491120.3530.0041120.3520.00189,257.65s(3F)2F5/2237,334.765p(3F)4F7/2326,592.68
3623581120.889m2−0.0041120.897−0.00889,214.95s(1S)2S1/2283,847.95p(1S)2P1/2373,062.5
9274761122.669−0.0071122.673−0.00489,073.45s(1D)2D5/2246,529.845p(3P)2D5/2335,602.72
87551125.970−0.0091125.9680.00288,812.35s(3P)4P5/2231,878.535p(3F)2D5/2320,690.13
9672421127.996−0.0031127.9930.00388,652.85s(3F)4F5/2226,585.525p(1D)2D3/2315,238.1
5601621128.931−0.0031128.9280.00388,579.35s(3F)2F7/2230,069.485p(3F)4F9/2318,648.6
9633881130.983−0.0021130.9810.00288,418.65s(3F)4F5/2226,585.525p(3F)4G5/2315,004.02
7704131137.198−0.0021137.198 87,935.45s(1G)2G9/2248,698.765p(3P)4D7/2336,634.02
6301671137.382−0.0081137.382 87,921.25s(3F)2F5/2237,334.765p(3P)4P5/2325,255.34
8101471138.647−0.0081138.647 87,823.55s(3P)4P3/2242,240.865p(3F)4F3/2330,063.75
480731139.574−0.0051139.574 87,752.15s(1D)2D5/2246,529.845p(3P)2P3/2334,281.53
14091139.897−0.0021139.897 87,727.25s(1G)2G7/2248,906.985p(3P)4D7/2336,634.02
690871141.962−0.0051141.962 87,568.65s(3F)2F5/2237,334.765p(3F)4F5/2324,902.96
8051142.075−0.0041142.075 87,559.95s(3P)4P3/2237,695.745p(3P)4P5/2325,255.34
190141143.130−0.0051143.130 87,479.15s(3P)2P1/2248,997.615p(3F)2D3/2336,476.33
8606031145.109−0.0061145.109 87,327.95s(3F)4F5/2226,585.525p(3F)4G7/2313,912.99
7702221145.422−0.0171145.422 87,304.15s(1D)2D5/2246,529.845p(1G)2F7/2333,832.6
7301241147.425−0.0061147.425 87,151.75s(3F)4F3/2228,086.865p(1D)2D3/2315,238.1
4031148.166−0.0031148.166 87,095.45s(3P)2P3/2249,381.165p(3F)2D3/2336,476.33
7304081150.518−0.0031150.518 86,917.45s(3F)4F3/2228,086.865p(3F)4G5/2315,004.02
450681151.436−0.0061151.436 86,848.15s(3P)4P3/2242,240.865p(3F)2F5/2329,088.51
10061153.454−0.0051153.454 86,696.15s(1G)2G7/2248,906.985p(3P)2D5/2335,602.72
7802471156.881−0.0071156.881 86,439.35s(3F)2F5/2237,334.765p(3P)4P3/2323,773.57
7402201157.681−0.0081157.681 86,379.65s(3P)4P3/2237,695.745p(3P)4P1/2324,074.7
400341157.9930.0021157.993 86,356.35s(3P)2P1/2248,997.615p(3P)4D1/2335,354.1
6503021159.799−0.0041159.799 86,221.85s(3P)2P3/2249,381.165p(3P)2D5/2335,602.72
450241161.7420.0031161.742 86,077.65s(3P)4P3/2237,695.745p(3P)4P3/2323,773.57
94012391161.8670.0061161.867 86,068.45s(3F)4F9/2217,872.985p(3F)4D7/2303,941.8
11011163.148−0.0091163.148 85,973.65s(3P)2P3/2249,381.165p(3P)4D1/2335,354.1
7801441167.714−0.0091167.714 85,637.45s(3P)4P5/2231,878.535p(3F)4D3/2317,515.30
9408441169.1460.0051169.146 85,532.55s(3F)4F7/2221,943.155p(3F)4G9/2307,476.0
6901621172.5560.0021172.556 85,283.85s(3P)2P1/2248,997.615p(3P)2P3/2334,281.53
8506711174.6260.0051174.626 85,133.55s(1G)2G9/2248,698.765p(1G)2F7/2333,832.6
500401175.3520.0181175.352 85,080.95s(3P)2P1/2248,997.615p(1D)2P1/2334,079.8
7901551177.3810.0041177.381 84,934.35s(3F)2F7/2230,069.485p(3F)4G5/2315,004.02
280201177.500−0.0011177.500 84,925.75s(1G)2G7/2248,906.985p(1G)2F7/2333,832.6
200281177.8580.0071177.858 84,899.95s(3P)2P3/2249,381.165p(3P)2P3/2334,281.53
680201178.3710.0001178.371 84,862.95s(3F)4F5/2226,585.525p(3F)4D5/2311,448.43
86014021178.5810.0001178.581 84,847.85s(1G)2G7/2248,906.985p(1G)2H9/2333,754.8
740761179.7780.0041179.778 84,761.75s(1D)2D5/2246,529.845p(3P)4P5/2331,291.85
450191192.448−0.0031192.448 83,861.15s(3P)4P1/2240,213.795p(3P)4P1/2324,074.7
8001271192.695−0.0031192.695 83,843.75s(3F)2F7/2230,069.485p(3F)4G7/2313,912.99
7301011196.7530.0051196.753 83,559.45s(3P)4P1/2240,213.795p(3P)4P3/2323,773.57
530641197.1230.0041197.123 83,533.65s(1D)2D5/2246,529.845p(3F)4F3/2330,063.75
10002211199.631db0.0091199.631 83,359.05s(3P)4P5/2231,878.535p(1D)2D3/2315,238.1
1000201199.631db0.0371199.631 83,359.05s(3F)4F3/2228,086.865p(3F)4D5/2311,448.43
740631203.0030.0031203.003 83,125.35s(3P)4P5/2231,878.535p(3F)4G5/2315,004.02
770991204.6180.0091204.618 83,013.95s(3P)4P3/2242,240.865p(3P)4P5/2325,255.34
510281204.9020.0011204.902 82,994.35s(3P)4P3/2237,695.745p(3F)2D5/2320,690.13
120371209.7520.0081209.752 82,661.65s(3P)4P3/2242,240.865p(3F)4F5/2324,902.96
450441211.2710.0111211.271 82,557.95s(1D)2D5/2246,529.845p(3F)2F5/2329,088.51
420411213.8240.0091213.824 82,384.35s(1G)2G7/2248,906.985p(3P)4P5/2331,291.85
700601219.0040.0041219.004 82,034.25s(3P)4P5/2231,878.535p(3F)4G7/2313,912.99
250301219.514−0.0181219.514 81,999.95s(3F)4F7/2221,943.155p(3F)4D7/2303,941.8
860681220.8520.0101220.852 81,910.05s(3P)2P3/2249,381.165p(3P)4P5/2331,291.85
650741221.9920.0041221.992 81,833.65s(3P)4P3/2242,240.865p(3P)4P1/2324,074.7
510161223.7940.0051223.794 81,713.15s(3P)4P3/2237,695.745p(3F)4D1/2319,409.18
700941228.8200.0011228.820 81,378.95s(3F)2F7/2230,069.485p(3F)4D5/2311,448.43
630421247.1910.0061247.191 80,180.25s(3F)2F5/2237,334.765p(3F)4D3/2317,515.30
760761252.8300.0041252.830 79,819.35s(3P)4P3/2237,695.745p(3F)4D3/2317,515.30
7801051256.755−0.0021256.755 79,570.05s(3P)4P5/2231,878.535p(3F)4D5/2311,448.43
730771262.698−0.0021262.698 79,195.55s(3P)4P1/2240,213.795p(3F)4D1/2319,409.18
120121272.9840.0021272.984 78,555.65s(1G)2G9/2248,698.765p(3F)2G7/2327,254.46
270171274.699−0.0101274.699 78,449.95s(3P)4P3/2242,240.865p(3F)2D5/2320,690.13
290251275.9500.0021275.950 78,373.05s(1D)2D5/2246,529.845p(3F)4F5/2324,902.96
Notes: a Relative intensity; b Observed wavelengths: ?—questionable line; db—doubly identified; m—masked by close lying strong line; w—wide line; mR—masked by close lying strong line, calculated Ritz value is listed; m2—blended by second order line; m3 and m5—blended respectively by the Sn III [12] and Sn V [11] lines. Above1131 Å the measurements by Srivastava et al. [2] were used; c Difference between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength). A blank value indicates that the upper level is derived from that line only; d Previous measurements by Srivastava at al. [2].
Table A2. Level energies (in cm−1) of the 4d85s, 4d86s and 4d85d configurations of Sn VI.
Table A2. Level energies (in cm−1) of the 4d85s, 4d86s and 4d85d configurations of Sn VI.
E aUnc. bN co–c dJEigenvector Composition e
217,872.980.209219/299%5s(3F)4F1%5s(1G)2G
221,943.150.2117487/277%5s(3F)4F21%5s(3F)2F1%5s(1G)2G
226,585.520.1322−25/289%5s(3F)4F8%5s(1D)2D2%5s(3P)4P
228,086.860.1621413/275%5s(3F)4F22%5s(1D)2D2%5s(3P)2P
230,069.480.1319−437/277%5s(3F)2F22%5s(3F)4F1%5s(1G)2G
231,878.530.1422465/238%5s(3P)4P31%5s(1D)2D27%5s(3F)2F
237,334.760.1518−1055/253%5s(3F)2F43%5s(3P)4P3%5s(3F)4F
237,695.740.1417143/252%5s(3P)4P20%5s(1D)2D15%5s(3F)4F
240,213.790.1612−401/297%5s(3P)4P3%5s(1S)2S
242,240.860.1620113/247%5s(3P)4P28%5s(1D)2D18%5s(3P)2P
246,529.840.1717−595/260%5s(1D)2D18%5s(3F)2F17%5s(3P)4P
248,698.760.197−389/298%5s(1G)2G1%5s(3F)4F
248,906.980.1811387/297%5s(1G)2G2%5s(3F)2F
248,997.610.219441/298%5s(3P)2P2%5s(1S)2S
249,381.160.1814223/267%5s(3P)2P30%5s(1D)2D3%5s(3F)4F
283,847.90.4201/294%5s(1S)2S3%5s(3P)4P2%5s(3P)2P
440,371.70.65−1587/281%5d(3F)4D13%5d(3F)4F3%5d(3P)4D
440,697.00.36−355/244%5d(3F)4P44%5d(3F)4D4%5d(3F)4F
442,556.30.44−3211/246%5d(3F)2H42%5d(3F)4H10%5d(3F)4G
443,127.80.818413/298%5d(3F)4H2%5d(1G)2I
443,467.10.75−383/237%5d(3F)2P30%5d(3F)4D16%5d(3F)4P
443,675.50.65539/241%5d(3F)4F38%5d(3F)4G10%5d(3F)2G
444,550.50.92−111/276%5d(3F)4G22%5d(3F)2H1%5d(1G)2H
444,903.90.48307/253%5d(3F)2F19%5d(3F)4F13%5d(3F)4G
445,841.40.491109/241%5d(3F)2G38%5d(3F)4F9%5d(3F)4H
446,177.00.58585/247%5d(3F)4P18%5d(3F)4D8%5d(3F)2D
448,702.90.77−603/251%5d(3F)2P36%5d(3F)4D7%5d(3P)4D
449,182.90.53−1521/277%5d(3F)4D10%5d(3F)4P6%5d(3P)4D
450,402.30.47−59/264%5d(3F)4H20%5d(3F)2G12%5d(3F)2H
450,696.60.41197/243%5d(3F)4H31%5d(3F)4G13%5d(3F)2F
450,813.70.411−223/230%5d(3F)4P28%5d(1D)2D18%5d(3F)4F
451,154.40.411835/241%5d(3F)4F28%5d(3F)4G11%5d(3F)2F
451,241.30.81−19411/257%5d(3F)4H30%5d(3F)2H13%5d(3F)4G
451,702.70.56837/232%5d(3F)4F26%5d(3F)2F14%5d(3F)4H
451,729.50.64−345/232%5d(3F)2F20%5d(1D)2F17%5d(3F)4G
451,782.80.48−1823/246%5d(3F)4P22%5d(3F)4F11%5d(3F)4D
452,404.50.412−115/222%5d(3F)4F19%5d(3F)2D16%5d(3F)4G
452,562.50.74639/235%5d(3F)2H35%5d(3F)4G13%5d(3F)2G
452,941.90.67877/234%5d(3F)4G17%5d(3F)4F16%5d(3F)4H
453,052.00.571921/244%5d(3F)4P28%5d(3F)2P14%5d(1D)2P
453,692.10.85311/246%5d(3F)2P28%5d(3F)4P20%5d(1D)2S
453,935.80.37677/254%5d(3F)2G23%5d(1D)2F12%5d(3P)4D
454,139.1?0.81259/226%5d(3F)2H24%5d(1D)2G18%5d(3F)4G
455,917.50.311293/239%5d(3F)4F18%5d(3F)2D14%5d(1D)2P
457,356.80.48−935/228%5d(3P)4D24%5d(3F)2D19%5d(3F)4G
458,526.71.04581/258%5d(3P)4D19%5d(1D)2P11%5d(3F)2P
459,319.40.59−995/229%5d(3F)2F16%5d(3P)4D12%5d(3F)4D
459,793.50.77707/253%5d(3P)4D24%5d(3F)2G8%5d(3F)4G
459,851.50.51053/257%5d(3P)4D10%5d(3P)4P9%5d(1G)2D
460,950.80.46−337/234%5d(3P)2F23%5d(1D)2G19%5d(3F)4H
461,161.00.58613/240%5d(3P)2D12%5d(3F)2D11%5d(1D)2P
461,513.00.86−499/255%5d(3P)4F16%5d(1D)2G15%5d(3F)2H
461,838.90.411155/236%5d(3P)2D22%5d(1G)2D16%5d(3P)4D
462,676.00.6701/241%5d(3P)4P26%5d(1D)2S13%5d(3P)2P
466,052.90.56−81/230%5d(3P)2P29%5d(3P)4D18%5d(1D)2P
466,132.90.68−373/249%5d(3P)4F12%5d(1G)2D11%5d(3P)4D
466,390.20.612−215/251%5d(3P)4F13%5d(3P)4D6%5d(1D)2F
466,991.10.93−173/244%5d(3P)4P17%5d(3P)2D11%5d(3P)4D
467,183.60.510−45/222%5d(3P)4P20%5d(1D)2D17%5d(3P)2F
467,575.70.9557/239%5d(3P)4F17%5d(3P)4D12%5d(3P)2F
468,085.20.551105/237%5d(1D)2F25%5d(3P)4F7%5d(3P)2F
468,560.60.525311/297%5d(1G)2I1%5d(3F)2H1%5d(3F)4H
468,909.50.5101417/234%5d(1D)2F29%5d(3P)4F12%5d(1D)2G
468,947.50.710343/224%5d(3P)4F23%5d(1G)2D22%5d(3P)2P
469,675.020.81−6513/298%5d(1G)2I2%5d(3F)4H
469,722.20.67−605/254%5d(3P)2F28%5d(3P)4P7%5d(3P)4F
470,284.20.4767/244%5d(3P)2F29%5d(1D)2G11%5d(1D)2F
470,339.20.72−699/246%5d(1D)2G28%5d(3P)4F11%5d(1G)2G
470,893.40.412925/235%5d(3P)4P32%5d(1D)2D8%5d(1G)2D
471,219.30.47653/248%5d(3P)2P14%5d(1G)2D13%5d(1D)2D
471,270.90.64−561/238%5d(3P)4P28%5d(1D)2P23%5d(1D)2S
472,326.00.781173/246%5d(1D)2P23%5d(3P)4P17%5d(3P)2P
472,651.20.55507/285%5d(1G)2F5%5d(1D)2F2%5d(1D)2G
473,251.70.67855/278%5d(1G)2F6%5d(1D)2F6%5d(3P)2F
473,931.20.72−651/246%5d(3P)2P27%5d(1D)2S17%5d(1D)2P
475,041.60.57−79/260%5d(1G)2H25%4d75s210%5d(1G)2G
475,955.30.57−6711/297%5d(1G)2H1%5d(3F)4G
476,018.01.12−1357/286%5d(1G)2G6%5d(1D)2G3%5d(1G)2F
476,324.70.54−1499/276%5d(1G)2G12%5d(1G)2H7%5d(1D)2G
482,589.51.06−489/298%6s(3F)4F2%6s(1G)2G
484,091.60.510187/262%6s(3F)2F36%6s(3F)4F2%6s(1G)2G
487,660 * 5/235%5d(1G)2D25%5d(3P)2D23%5d(3F)2D
490,946.00.612−245/282%6s(3F)4F12%6s(3F)2F4%6s(1D)2D
491,054.80.610−137/263%6s(3F)4F37%6s(3F)2F
492,154.40.910−83/265%6s(3F)4F29%6s(1D)2D5%6s(3P)2P
493,087.60.77255/258%6s(3F)2F29%6s(1D)2D11%6s(3P)4P
493,303.71.11−53/229%5d(3F)2D24%5d(1G)2D17%5d(1D)2D
499,898.20.712−375/260%6s(3P)4P22%6s(3F)2F11%6s(3F)4F
500,562.70.710313/241%6s(3P)2P26%6s(3F)4F17%6s(1D)2D
505,308.41.06−361/296%6s(3P)4P3%6s(1S)2S
505,864.70.810313/280%6s(3P)4P17%6s(3P)2P2%6s(1D)2D
507,492 * 1/298%6s(3P)2P2%6s(1S)2S
509,084 * 3/286%5d(1S)2D4%5d(3P)2D2%5d(3P)4F
509,540.70.791105/252%6s(1D)2D25%6s(3P)4P9%5d(1S)2D
509,843 * 5/269%5d(1S)2D11%4d75s27%5d(1D)2D
510,047.70.79553/252%6s(1D)2D36%6s(3P)2P8%6s(3F)4F
511,680.30.87−519/298%6s(1G)2G2%6s(3F)4F
511,718.90.76−387/298%6s(1G)2G1%6s(3F)2F
Notes: a The star * indicates a calculated value for the level. Tentative value of the level is listed with the question mark; b The energy uncertainty relative to any other level of the 4d85s, 4d85s and 4d85s configurations. The energy uncertainty relative to ground level 4d9 2D5/2 is 5 cm−1; c The number of spectral lines used for the determination of each level energy; d The difference between the observed and the calculated energies; e For the eigenvector composition, up to three components with the largest percentages in the LS—coupling scheme are listed.
Table A3. Level energies (in cm−1) of the 4d85p configuration of Sn VI.
Table A3. Level energies (in cm−1) of the 4d85p configuration of Sn VI.
EUnc. aN bo–c cJEigenvector Composition d
303,941.80.514−637/274%5p(3F)4D12%5p(3F)4F5%5p(3F)2F
307,476.00.39−59/240%5p(3F)4G37%5p(3F)2G22%5p(3F)4F
311,448.430.1720−415/265%5p(3F)4D12%5p(3P)4D11%5p(3F)4F
313,912.990.211877/266%5p(3F)4G14%5p(3F)2G14%5p(3F)4F
315,004.020.1821−345/250%5p(3F)4G15%5p(1D)2F14%5p(3F)4F
315,238.10.2521911/298%5p(3F)4G2%5p(1G)2H
315,239.910.505−663/224%5p(1D)2D20%5p(3F)4F15%5p(3F)2D
317,515.300.1925−363/256%5p(3F)4D25%5p(3P)4D9%5p(3P)4P
318,648.60.31119/271%5p(3F)4F26%5p(3F)2G1%5p(3F)4G
319,409.180.23921/256%5p(3F)4D28%5p(3P)4D9%5p(1D)2P
319,827.760.2419607/258%5p(3F)2F19%5p(3F)4F12%5p(3F)4D
320,690.130.2027365/234%5p(3F)2D28%5p(3F)4G12%5p(3F)4F
323,773.570.1928873/246%5p(3P)4P22%5p(3F)4F9%5p(3F)2D
324,074.70.314−751/286%5p(3P)4P4%5p(3P)2P4%5p(1D)2P
324,356.630.276−89/258%5p(3F)4G35%5p(3F)2G6%5p(3F)4F
324,902.960.2023−15/233%5p(3F)4F22%5p(3F)2F14%5p(3F)2D
325,255.340.1928595/239%5p(3P)4P28%5p(3F)2D10%5p(3F)4D
326,592.680.1922−227/245%5p(3F)4F25%5p(3F)2G21%5p(3F)2F
327,254.460.1815−297/231%5p(3F)2G30%5p(1D)2F16%5p(3F)4G
329,088.510.2423−285/229%5p(3F)2F25%5p(1D)2F18%5p(3P)2D
330,063.750.2223123/247%5p(3F)4F18%5p(3F)2D13%5p(3P)4P
331,291.850.1833135/221%5p(3P)4P16%5p(3F)4F14%5p(3F)4G
333,754.80.38687/243%5p(1G)2F20%5p(3F)2G13%5p(1D)2F
333,832.60.324−299/291%5p(1G)2H7%5p(1G)2G1%5p(3F)2G
334,079.80.313971/238%5p(1D)2P33%5p(3P)2P8%5p(3P)4P
334,281.530.1920653/231%5p(3P)2P23%5p(3P)4D16%5p(3F)2D
335,354.10.2516881/253%5p(3P)4D29%5p(3F)4D8%5p(3P)2P
335,602.720.1727−125/226%5p(3P)2D22%5p(3F)2F17%5p(1D)2D
336,476.330.1719203/232%5p(3F)2D24%5p(3P)4D14%5p(1D)2D
336,634.020.2026−337/253%5p(3P)4D28%5p(1G)2F6%5p(3F)2F
339,432.970.2223633/252%5p(1D)2P13%5p(3P)2D11%5p(1D)2D
339,770.870.2319915/228%5p(1D)2D27%5p(1G)2F15%5p(3P)4D
341,620.50.316343/251%5p(3P)2P24%5p(1D)2D8%5p(3P)4D
342,540.90.452811/298%5p(1G)2H2%5p(3F)4G
342,827.900.212305/240%5p(3P)4D39%5p(3P)2D12%5p(1G)2F
344,338.70.310−663/266%5p(3P)2D13%5p(3P)4D5%5p(1D)2P
344,811.60.39−61/271%5p(3P)2S14%5p(3P)2P6%5p(3P)4D
345,680.160.2416−137/250%5p(1D)2F26%5p(3P)4D6%5p(1G)2F
346,961.720.2519−1325/249%5p(1G)2F13%5p(1D)2D13%5p(1D)2F
347,213.070.2421−393/284%5p(3P)4S4%5p(1D)2P3%5p(3P)2P
350,163.50.76−1261/241%5p(1D)2P35%5p(3P)2P16%5p(3P)2S
351,018.70.38267/285%5p(1G)2G12%5p(1G)2F2%5p(1D)2F
352,133.80.311−69/292%5p(1G)2G7%5p(1G)2H1%5p(3F)4F
373,062.50.52311/290%5p(1S)2P4%5p(1D)2P3%5p(3P)4D
382,342.20.77−283/292%5p(1S)2P2%5p(1D)2P2%5p(3P)2D
Notes: a The energy uncertainty relative to any other level of the 4d85p, 4d85s and 4d85s configuration. The energy uncertainty relative to ground level 4d9 2D5/2 is 5 cm−1; b The number of spectral lines used for the determination of each level energy; c The difference between the observed and the calculated energies; d For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed.
Table A4. Fitted (FIT) with their uncertainties (Unc.) and Hartree–Fock (HF) energy parameters in cm−1 of the 4d85s, 4d86s, 4d85p and 4d85d configurations in Sn VI calculated with the Cowan code.
Table A4. Fitted (FIT) with their uncertainties (Unc.) and Hartree–Fock (HF) energy parameters in cm−1 of the 4d85s, 4d86s, 4d85p and 4d85d configurations in Sn VI calculated with the Cowan code.
ParameterHF aFITUnc. bLSF/HF c
Even levels
Eav(4d85s)240,747236,92121−3826
F2(4d,4d)99,99683,4821870.835
F4(4d,4d)66,52058,6773290.882
α 567
β −658116
ζ(4d)35163668181.043
G2(4d,5s)16,61914,4311260.868
Eav(4d85d)460,364460,88812524
F2(4d,4d)100,66684,1421570.836
F4(4d,4d)67,02659,1552740.883
α 56f
β −658f
ζ(4d)35503651131.028
ζ(5d)477563131.179
F1(4d,5d) 19381
F2(4d,5d)21,74419,4881200.896
F4(4d,5d)97978780540.896
G0(4d,5d)52544606130.877 d
G2(4d,5d)64455650160.877 d
G4(4d,5d)53144658130.877 d
Eav(4d86s)499,343499,50923166
F2(4d,4d)100,72484,3532690.837
F4(4d,4d)67,06859,7564450.891
α 56f
β −658f
ζ(4d)35533663181.031
G2(4d,6s)40343404300.844
σ79
Odd levels
Eav(4d85p)332,959330,80910−2150
F2(4d,4d)100,23283,6291120.834
F4(4d,4d)66,69859,2441640.888
α 444
β −45862
ζ(4d)35283626141.028
ζ(5p)61016831211.120
F2(4d,5p)34,43629,734880.863
G1(4d,5p)11,0149929500.901
G3(4d,5p)10,41788432180.849
σ61
Notes: a Hartree–Fock average energy for the ground level configuration 4d9 is 5338 cm−1 (see text); b f-parameters are fixed on the values obtained for the 4d85s configuration; c For Eav the difference between fitted and ab initio values is given. Parameters F2(4d,5p) and F4(4d,5p) as well as G0(4d,5p), G2(4d,5p) and G4(4d,5p) are tied together at their Hartree–Fock ratios; d Parameters are linked at their Hartree–Fock ratios.

References

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Figure 1. Difference between the level energies of the 4d85p configuration measured in this work (ETW) and the energies ESr published by Srivastava at al. [2].
Figure 1. Difference between the level energies of the 4d85p configuration measured in this work (ETW) and the energies ESr published by Srivastava at al. [2].
Atoms 05 00047 g001

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Ryabtsev, A.; Kildiyarova, R.; Kononov, E. Spectrum of Sn5+ in the Region 500–1300 Å. Atoms 2017, 5, 47. https://doi.org/10.3390/atoms5040047

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Ryabtsev A, Kildiyarova R, Kononov E. Spectrum of Sn5+ in the Region 500–1300 Å. Atoms. 2017; 5(4):47. https://doi.org/10.3390/atoms5040047

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Ryabtsev, Alexander, Rimma Kildiyarova, and Edward Kononov. 2017. "Spectrum of Sn5+ in the Region 500–1300 Å" Atoms 5, no. 4: 47. https://doi.org/10.3390/atoms5040047

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