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Article

Synthesis and Characterization of (pyNO−)2GaCl: A Redox-Active Gallium Complex

by
Jacob M. Kirsh
1,
Audra J. Woodside
1,
Brian C. Manor
2,
Patrick J. Carroll
2,
Paul R. Rablen
1 and
Christopher R. Graves
1,*
1
Department of Chemistry & Biochemistry, Swarthmore College, 500 College Avenue, Swarthmore, PA 19081, USA
2
Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, PA 19104, USA
*
Author to whom correspondence should be addressed.
Inorganics 2018, 6(2), 50; https://doi.org/10.3390/inorganics6020050
Submission received: 14 April 2018 / Revised: 11 May 2018 / Accepted: 15 May 2018 / Published: 21 May 2018
(This article belongs to the Special Issue Redox-Active Ligand in Coordination Chemistry)
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Abstract

:
We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide ligands. The (pyNO−)2GaCl complex was prepared in 85% yield via a salt metathesis route and was characterized by 1H and 13C NMR spectroscopies, X-ray diffraction, and theory. UV–Vis absorption spectroscopy and electrochemistry were used to access the optical and electrochemical properties of the complex, respectively. Our discussion focuses primarily on a comparison of the gallium complex to the corresponding aluminum derivative and shows that although the complexes are very similar, small differences in the electronic structure of the complexes can be correlated to the identity of the metal.

Graphical Abstract

1. Introduction

The synthesis of metal complexes of redox-active and non-innocent ligands is a research area that has been expanding in recent years and has resulted in new classes of complexes for metals from throughout the periodic table [1,2,3,4]. Of specific interest to us is the ability to modulate the reactivity of redox-active ligands through coordination of Lewis acids. We are specifically interested in how coordination of Lewis acids with different stabilizing effects change the electronic structure of a common redox-active ligand. In this vein, we have been interested in the development of aluminum complexes of redox active-ligands [5,6,7,8,9] and have recently reported the synthesis and characterization of a series of Al-nitroxide complexes [7,8]. The nitroxide functional group is well known to exist over three oxidation states: the reduced aminoxyl anion (R2N–O−), the neutral radical (R2N–O•), and the oxidized oxoammonium cation (R2N=O+) (Figure 1).
The Schelter group has reported the synthetic chemistry for a series of pyridyl-hydroxylamines (RpyNOH) and demonstrated their redox activities [10]. Metal complexes of these ligands have been prepared for several f-block [11,12,13,14,15] and transition [16,17,18] metals. Inspired by these compounds we prepared and fully characterized aluminum complexes of the type (RpyNO−)2AlCl (RpyNO− = N-tert-butyl-N-(2-(5-R-pyridyl))nitroxyl, R = H, CH3, CF3) [7] and {(μ-RpyNO−)Al(CH3)2}2 (R = H, CH3) [8] and explored their electrochemical behavior. The results of this study suggested that coordination to the Lewis-acidic aluminum ion affected the redox energetics of the ligand to stabilize the reduced pyNO− form. In their work with iminopyridine ligands, the Berben group demonstrated key differences in the electrochemical behavior of the aluminum versus gallium [(IP2−)2M]− anion (M = Al or Ga) which translated to different reaction profiles for the two complexes [19,20,21]. In light of these results, we have become interested in the preparation of redox-active ligand complexes of other group 13 metals, namely gallium and indium, to access how the identity of the metal translates to differences in the physical properties of the complexes. In this current contribution, we report the synthesis of the pyridyl-nitroxide gallium complex (pyNO−)2GaCl and present its characterization by various physical methods. We then discuss the results in the context of the corresponding aluminum complex.

2. Results

2.1. Synthesis and Spectroscopic Characterization

Our synthetic strategy is outlined in Scheme 1: Reaction of N-tert-butyl-N-(2-pyridyl)hydroxylamine (pyNOH) with an equimolar amount of NaN(SiMe3)2 in tetrahydrofuran (THF) followed by addition of 0.5 equiv of GaCl3 gave the (pyNO−)2GaCl (1) complex in 85% yield. The compound was isolated as a yellow solid that is indefinitely stable in the solid state when stored in the freezer (−25 °C) under an N2 environment. We also attempted the synthesis of the corresponding indium complex under identical reaction conditions. However, unlike the aluminum and gallium systems which cleanly provide monometallic complexes, there is a ligand redistribution in the indium compound and after crystallization the zwitterionic [(pyNO−)2In][(pyNO−)2InCl2] (2) complex is isolated. Compound 2 was crystalized from slow diffusion of pentane into a concentrated THF solution at −25 °C, and it is not clear if the crystal sample obtained is representative of the bulk sample. In this work, we are primarily interested in comparing the analogous (pyNO−)2MCl complexes, and further characterization of complex 2 beyond X-ray was not carried out. A representation of the solid-state structure of 2 along with selected bonding metrics is provided in the Supplementary Materials.
The (pyNO−)2GaCl complex was readily characterized by 1H and 13C NMR spectroscopies, which support assignment of the structure as diamagnetic with a Ga3+ cation coordinated by fully reduced nitroxide ligands. As expected, the 1H NMR spectrum of the complex lacks the O–H signal of the ligand precursor but has all of the remaining ligand signatures that are readily assignable and in the expected chemical ranges. There is single resonance attributable to the t-Bu protons, which appears as a singlet which integrates to 18H, along with four unique aromatic resonances each of which integrates to 2H. All four of the aromatic signals exhibits a doublet-of-doublet-of-doublet coupling pattern indicative of coupling between all four of the protons within the aromatic ring. Site assignments for the pyridyl hydrogens are given in the Supporting Information. The 13C NMR spectra of 1 has characteristic signals for the t-Bu groups (resonances at 28.3 ppm (C(CH3)3) and 61.7 ppm (C(CH3)3) along with five aromatic signals. The single set of ligand-based resonances in both the 1H and 13C NMR spectra indicate symmetry equivalent pyNO− ligands in the complex.

2.2. Structural Characterization

Single crystals of the (pyNO−)2GaCl complex were grown from a concentrated solution of diethyl ether at −25 °C. The molecule crystallizes in the orthorhombic space group Pna21 and collected data refined to a final R1 value of 0.0226. A representation of the molecule is shown in Figure 2 and selected bonding metrics are provided in Table 1.
Complex 1 is five-coordinate at the gallium cation with a τ5 value [22] of 0.07 and is best described as slightly distorted square pyramidal. The two pyridyl nitroxide ligands are Npy,O-bound in a bidentate fashion and are arranged in the basal plane. The arrangement of the ligands results in the O–Al–O and N–Al–N atoms being in mutually trans arrangements, giving the complexes near C2 symmetry and supporting the equivalent ligands observed in the 1H and 13C NMR spectra. A chloride ligand completes the coordination sphere. The Ga–Cl bond is in the range of other non-bridging Ga–Cl bonds reported for structurally characterized five-coordinate gallium(III) complexes. For example, the bis(o-iminosemiquinonate) gallium(III) chloride complex reported by Piskunov et al. has a Ga–Cl of 2.1875(5) Å [23] and the gallium salen complex reported by the Dagorne group has a Ga–Cl distance of 2.2255(6) Å [24] The bis(β-ketoiminate) gallium(III) chloride complex prepared by the Carmalt group has a Ga–Cl bond length of distance 2.231(7) Å [25]. The Ga–Npy bond distances are also similar to other Ga–N distances reported for gallium complexes supporting pyridine ligands: The pyGaX3 (X = Cl and Br) complexes have an average Ga–N distance of 1.98 Å [26] while the {pyGaCl2H}2 dimer has Ga–N distances of 2.000(2) and 1.998(2) Å [27]. Several gallium complexes incorporating hydroxyl amine ligands have been structurally characterized, and the Ga–O and N–O distances observed for 1 compare well to their metrics. As representative examples, the Ga–O bond length in the (Me2GaONMe2)2 complex is 1.886(2) Å and the N–O distance was 1.435(3) Å [28] while the analogous distances in the GaH2(quinuclidine)(TEMPO) (TEMPO = tetramethylpiperidinyloxide) complex are 1.850(5) and 1.447(8) Å, respectively [29]. Finally, the series of bis(hydroxylamine) gallium complexes prepared by the Mitzel group have an average Ga–O distance of 1.91 Å and average N–O distance of 1.44 Å [30,31]. In all cases, the N–O bond distance in these complexes are longer than that observed for 1 (1.397(3) Å). However, the N–O bond distance in 1 does fit in the range of similar bonding parameters reported for metal complexes coordinated by the aminoxyl anion form of the pyridyl nitroxide ligand. For example, the cerium complexes {CeIII(μ-RpyNO−)(RpyNO−)2}2 and CeIV(RpyNO−)4 reported by the Schelter group have average N–O distances of 1.37 and 1.38 Å), respectively [12,13]. The [Cu2+(pyNO−)(pyNO•)]+ cation reported by the Ishida group has an N–O distance for the pyNO− ligand in the range of 1.4092(8)–1.423(2) Å [18]. This complex also has neutral, radical pyNO• ligands which have N–O distances in the range of 1.298(3)–1.303(2) Å. Similarly, the terbium complex (hfac)3Tb(pyNO•) (Hhfac = 1,1,1,5,5,5-hexafluoropentane-2,4-dione) has a N–O distance of 1.279(9) Å [11] which is significantly shorter than the analogous distance observed for 1. This supports the assignment of fully reduced pyNO− ligands in the gallium complex.

2.3. Electronic Strucutre of the (pyNO−)2GaCl Complex

2.3.1. Density Functional Theory (DFT) Studies

The full geometry of the (pyNO−)2GaCl complex was optimized using density functional theory with the molecule being constrained to C2 symmetry. A representation of the optimized structure and a table of xyz coordinates are provided in the Supporting Information. Overall, the computed bond distances were found to be in good agreement with those obtained in the X-ray data (Table 1). With the exception of the Ga–Cl distance, all of the computed bond distances centered around the gallium ion are within 0.05 Å. The Ga–Cl in the computed structure is slightly longer by ~0.07 Å. Similarly, all of the bond angles are also in good agreement, with the largest deviation being ~6° for the O–Ga–O and N–Ga–N angles. The charge distribution of the (pyNO−)2GaCl complex was studied by the natural bonding orbital (NBO) method, with selected data given in Table 2. The gallium cation has a positive charge while the bonding heteroatoms and chloride have negative charges.
We also examined the molecular orbitals of the (pyNO−)2GaCl complex. All of the frontier orbitals (Figure 3) are primarily localized on the pyNO− ligands. The HOMO and HOMO–1 are similar in structure and energy (energy difference of 0.163 eV) and have electron density delocalized across the N–O and pyridine groups of both pyNO− ligands, as well as some contribution from the chloride. The HOMO is antisymmetric with respect to C2 rotation about the Ga–Cl bond while the HOMO−1 is symmetric about the same rotation. The LUMO and LUMO+1 are also similar in structure and also have a relationship relative to C2 rotation about the Ga–Cl bond (the LUMO is symmetric to rotation and the LUMO + 1 is antisymmetric to rotation). The two virtual orbitals are degenerate (energy difference of 0.005 eV) and are localized primarily on the pyridine rings of the two pyNO− ligands with very little density on the N–O fragment and none on the chloride ligand.

2.3.2. Absorption Spectra

The absorption spectra of the (pyNO−)2GaCl complex was collected in methylene chloride (Figure 4). The spectrum has a dominant feature at 281 nm (ε ~ 2300 M−1·cm−1) and a smaller feature at 357 nm (ε ~ 550 M−1·cm−1). We propose that both features result from primarily ligand based π-to-π* transitions, as was determined for the corresponding aluminum complex.

2.3.3. Electrochemistry

The cyclic voltammogram of (pyNO−)2GaCl was collected in CH2Cl2 and exhibits two features which we attribute to two sequential one-electron oxidation processes corresponding to the N–O−/N–O• couples of each pyNO− ligand (Figure 5). We do not observe the other two oxidation processes corresponding to the N–O•/N=O+ couples in the electrochemical window. Coordination to the Ga3+ cation shifts the redox events to more positive potential relative to pyNOH [10], indicating that the Lewis acidic metal stabilizes the reduced aminoxyl anion pyNO−. For example, the first oxidation in 1 occurs at 0.24 V while the pyNOH/pyNO0 couple for free ligand comes at E½ = −0.39 V, for a shift in potential of 0.63 V. All values are referenced to the ferrocene/ferrocenium couple. This is in line with chemistry reported by the Hayton group, who demonstrated that coordination of the TEMPO radical (TEMPO = 2,2,6,6-tetramethylpiperidine-N-oxyl) to a Lewis acid significantly changes the reactivity of the molecule in the oxidation of various organic molecules.

3. Discussion

The (pyNO−)2GaCl complex presented herein was prepared using a salt metathesis route analogous to that employed for the synthesis of our previously reported (pyNO−)2AlCl complex. In both cases, complexes were isolated in high purity and yield. The gallium complex is significantly more soluble in hydrocarbon solvent relative to the aluminum complex, which reduced the recoverability of the former during recrystallization from hexane or pentane. The two complexes are isostructural, crystalizing as five-coordinate M3+ ions in distorted square pyramidal geometries. The gallium complex is closer to the idealized geometry as gauged by the τ5 geometry indices. Complex 1 has a τ5 value of 0.07 while the (pyNO−)2AlCl complex has a τ5 value of 0.30. The τ5 value for a square pyramid is 0 while that for a trigonal bipyramid is 1 [22]. Arrangement of the pyNO− ligands is also identical in the two complexes, with both ligands coordinating in the basal plane and with trans O–Al–O and N–Al–N geometries. The Ga–Cl, Ga–O, and Ga–N distances in 1 are all slightly longer than the corresponding distance in the aluminum complex, as is expected given the larger ionic radius [32] and relative decrease in Lewis acidity [33] of the Ga3+ ion relative to the Al3+ ion.
The electronic structure of the (pyNO−)2MCl complexes are also similar, with small differences being noted relative to the identity of the metal ion. The frontier molecular orbitals for the two complexes are essentially identical, although the HOMO–LUMO gap (∆E = 3.926 eV) is slightly smaller for 1 relative to that for the aluminum complex (∆E = 4.122 eV). The electronic transitions observed in the absorption spectra of the complexes are similar in shape, although there is a small red-shift (281 nm and 357 nm for 1 compared to 276 nm and 345 nm for (pyNO−)2AlCl) for both of the features in 1 relative to those of the aluminum complex. In both cases the transitions are primarily ligand based π-to-π*, and it follows that the smaller HOMO–LUMO gap for 1 would result in lower energy transitions. The redox process observed for the gallium complex are much more reversible than they were for the aluminum complex. Additionally, the processes are shifted to more negative potentials relative to those observed for the aluminum by ~0.1 V. We propose this shift is due to the decreased Lewis acidity of Ga3+ relative to Al3+.
In this work, we have demonstrated that pyridyl nitroxide ligands can be coordinated to gallium to provide a new class of redox-active gallium complexes. Characterization of the complex shows similar physical and electronic structure to the aluminum analog, although there are systematic differences commensurate with the difference in Lewis acidity of the two metal ions. Although subtle, these results demonstrate the ability to tune the electronic nature of the redox-active ligand through judicial choice of Lewis-acid. Our future work will involve investigating the reaction chemistry of the (pyNO−)2GaCl complex as well as the preparation of other gallium complexes supporting different classes of redox-active ligands.

4. Materials and Methods

4.1. Physical Measurements

The 1H and 13C NMR spectra were recorded at ambient temperature in C6D6 using a Bruker 400 MHz spectrometer (399.78 MHz for 1H, 100.52 MHz for 13C) (Bruker Corporation, Billerica, MA, USA). Chemical shifts were referenced to residual solvent. s = singlet, ad = apparent doublet, ddd = doublet of doublet of doublets. CHN analysis was performed on a crystalized sample of 1 at Midwest Microlab (Indianapolis, IN, USA). Electrochemical measurements were done in a glovebox under a dinitrogen environment using a CHI Potentiostat/Galvanostat (CH Instruments, Austin, TX, USA). A glassy carbon working electrode, a platinum wire auxiliary electrode, and a silver wire plated with AgCl as a quasi-reference electrode were utilized. Potentials were reported versus ferrocene, which was added as an internal standard for calibration at the end of each run. Solutions employed during these studies were ~3 mM in analyte and 100 mM in [n-Pr4N][BArF] (BArF− = B(3,5-CF3)2-C6H3)4−) in ~5 mL of CH2Cl2. All data were collected in a positive-feedback IR compensation mode at 500 mV/s. The absorbance spectrum was collected using an Agilent Cary Series UV–Vis spectrophotometer (Agilent, Santa Clara, CA, USA) in anhydrous methylene chloride at ambient temperature and pressure.

4.2. Preparation of Compounds

All reactions and manipulations were performed under an inert atmosphere (N2) using standard Schlenk techniques or in a Vacuum Atmospheres, Inc. NextGen drybox (Hawthorne, CA, USA) equipped with both oxygen and moisture purifier systems. Glassware was dried overnight at 150 °C before use. C6D6 was degassed and stored over 4 Å molecular sieves prior to use. All solvents were sparged for 20 min with dry argon and dried using a commercial two-column solvent purification system comprising two columns packed with neutral alumina (for tetrahydrofuran, diethyl ether, acetonitrile, and dichloromethane) or Q5 reactant then neutral alumina (for hexanes). The ligand precursor N-tert-butyl-N-(2-pyridyl)hydroxylamine was prepared as reported by the Schelter group [10]. [n-Pr4N][BArF] was prepared according to literature procedure [34]. All other reagents were purchased from commercial sources and used as received.
Synthesis of (pyNO−)2GaCl: N-tert-Butyl-N-(2-pyridyl)hydroxylamine (0.50 g, 3.0 mmol) was added to a flask equipped with a magnetic stirbar and was dissolved in THF (~25 mL). NaN(SiMe3)2 (0.62 g, 3.3 mmol) was added to the stirring solution in small portions over 0.5 h. The resulting reaction mixture was stirred at room temperature for 4 h after which gallium trichloride (0.26 g, 1.5 mmol) was added. The solution was stirred for 12 h at room temperature after which the reaction products were filtered over a Celite-padded frit and volatiles were removed from the filtrate. Crude product was dissolved in boiling hexanes (~25 mL) and filtered over a celite-padded frit. Solvents were removed from the filtrate to give (pyNO−)2GaCl as a yellow solid. Yield: 0.55 g, 1.3 mmol (85%). 1H NMR (C6D6): δ 8.19 (ddd, J = 5.8 Hz, J = 1.6 Hz, J = 0.9 Hz, 2H), 6.68 (ddd, J = 9.2 Hz, J = 6.8 Hz, J = 1.8 Hz, 2H), 6.46 (ad, J = 9.2 Hz, 2H), 5.98 (ddd, J = 6.8 Hz, J = 5.9 Hz, J = 0.7 Hz, 2H), 1.39 (s, 18H). 13C{1H} NMR (C6D6): δ 153.9, 142.8, 136.6, 110.0, 109.0, 61.7 (C(CH3)3), 28.3 (C(CH3)3. Anal. Calcd. for C18H26ClGaN4O2: C, 49.63; H, 6.02; N, 12.86. Found: C, 49.78; H, 5.77; N, 12.58.

4.3. X-ray Structure Determination

X-ray diffraction data were collected either on a Bruker APEXII [35] CCD area detector (for 2) or a Bruker APEXIII [36] D8QUEST CMOS area detector (for 1) (Bruker Corporation, Billerica, MA, USA), both employing graphite-monochromated Mo-Kα radiation (λ = 0.71073Å) at a temperature of 100 K. Rotation frames were integrated using SAINT [37], producing a listing of unaveraged F2 and σ(F2) values. The intensity data were corrected for Lorentz and polarization effects and for absorption using SADABS [38]. The structures were solved by direct methods (SHELXT [39]) and refined by full-matrix least squares based on F2 using SHELXL-2014 [40]. All non-hydrogen atoms were refined anisotropically and hydrogen atoms were refined using a riding model. CCDC 1833920-1833921 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44-1223-336033.
(pyNO−)2GaCl: Refinement converged to R1 = 0.0226 and wR2 = 0.0481 for 4230 observed reflections for which F > 4σ(F) and R1 = 0.0260 and wR2 = 0.0491 and GOF = 1.091 for all 4528 unique, non-zero reflections and 241 variables.
(pyNO−)2In(pyNO−)2InCl2: Refinement converged to R1 = 0.0253 and wR2 = 0.0574 for 9724 observed reflections for which F > 4σ(F) and R1 = 0.0290 and wR2 = 0.0600 and GOF = 1.094 for all 10,557 unique, non-zero reflections and 576 variables.

4.4. Computational Details

The structure optimization of (pyNO−)2GaCl was performed with the Gaussian ’09, Revision D.01 program using the B3LYP hybrid DFT method [41] and the LanL2DZ basis set [42,43,44]. Geometry optimization was performed using the crystal structure geometry as the initial starting point. Molecular orbitals are rendered at an isovalue of ±0.03 a.u. NBO analyses were performed using the NBO6 package [45].

Supplementary Materials

The following are available online at https://www.mdpi.com/2304-6740/6/2/50/s1. Figures S1 and S2: 1H NMR and 13C NMR spectrum of (pyNO−)2GaCl (1), Figure S3: Solid state structure of {(pyNO−)2In}{(pyNO−)2InCl2} (2), Tables S1 and S2: Summary of Structure Determination of (pyNO−)2GaCl (1) and {(pyNO−)2In}{(pyNO−)2InCl2} (2), Table S3: Optimized coordinates of (pyNO−)2GaCl (1); Full Gaussian ’09 Reference.

Author Contributions

C.R.G. conceived and designed the experiments; J.M.K. and A.J.W. performed the experiments; J.M.K. and P.R.R. performed the DFT calculations; B.C.M. and P.J.C. performed the X-ray diffraction and solved the crystal structure data; C.R.G., J.M.K., and A.J.W. analyzed the data; C.R.G. wrote the paper.

Acknowledgments

C.R.G. thanks Swarthmore College, the Research Corporation for Scientific Advancement (CCSA 23329), and the National Science Foundation (CHE-1664902) for financial support of this work. A.J.W. was supported through a James H. Scheuer Summer Internship in Environmental Studies. We thank the NSF (CHE-1337494) for funding toward the NMR spectrometer used in this work. We thank Bren E. Cole (University of Pennsylvania) for assistance collecting the X-ray diffraction data for complexes 1 and 2.

Conflicts of Interest

The authors declare no conflict of interest.

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Inorganics 06 00050 g001 550
Figure 1. The nitroxide functional group across three oxidation states.
Figure 1. The nitroxide functional group across three oxidation states.
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Scheme 1. Synthesis of the gallium pyridyl nitroxide complex (pyNO−)2GaCl (1) and the indium dimer [(pyNO−)2In][(pyNO−)2InCl2] (2).
Scheme 1. Synthesis of the gallium pyridyl nitroxide complex (pyNO−)2GaCl (1) and the indium dimer [(pyNO−)2In][(pyNO−)2InCl2] (2).
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Figure 2. Solid state structure of (pyNO−)2GaCl (1). Ellipsoids are projected at 30% probability and H atoms are omitted for clarity.
Figure 2. Solid state structure of (pyNO−)2GaCl (1). Ellipsoids are projected at 30% probability and H atoms are omitted for clarity.
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Figure 3. The frontier molecular orbitals of the (pyNO−)2GaCl complex. The orbitals are visualized looking down the Ga–Cl bond.
Figure 3. The frontier molecular orbitals of the (pyNO−)2GaCl complex. The orbitals are visualized looking down the Ga–Cl bond.
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Figure 4. UV−Vis spectra of a 3.0 × 10−4 M solution of 1 in CH2Cl2.
Figure 4. UV−Vis spectra of a 3.0 × 10−4 M solution of 1 in CH2Cl2.
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Figure 5. Cyclic voltammogram of 1 recorded in 0.1 M [n-Pr4N][BArF] CH2Cl2 solution.
Figure 5. Cyclic voltammogram of 1 recorded in 0.1 M [n-Pr4N][BArF] CH2Cl2 solution.
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Table
Table 1. Selected bond distances (Å) and angles (°) the (pyNO−)2GaCl complex obtained from the solid-state structure and theoretical analysis.
Table 1. Selected bond distances (Å) and angles (°) the (pyNO−)2GaCl complex obtained from the solid-state structure and theoretical analysis.
Solid-StateTheoretical
Ga(1)–Cl(1)2.2215(7)2.2918
Ga(1)–O(1)
Ga(1)–O(2)		1.8890(18)
1.9011(18)		1.8936
Ga(1)–N(1)
Ga(1)–N(3)		1.991(2)
2.006(2)		2.0028
N(2)–O(1)
N(4)–O(2)		1.397(3)
1.397(3)		1.4265
O(1)–Ga(1)–N(1)
O(1)–Ga(1)–N(3)
O(2)–Ga(1)–N(1)
O(2)–Ga(1)–N(3)		81.00(8)
91.61(8)
88.87(8)
80.28(8)		81.22
90.12
O(1)–Ga(1)–O(2)145.14(8)138.53
N(1)–Ga(1)–N(3)149.25(9)155.45
O(1)–Ga(1)–Cl(1)
O(2)–Ga(1)–Cl(1)		108.00(6)
106.86(6)		110.74
N(1)–Ga(1)–Cl(1)
N(3)–Ga(1)–Cl(1)		106.23(6)
104.44(6)		102.28
Table
Table 2. Charge Distribution of the (pyNO−)2GaCl Complex.
Table 2. Charge Distribution of the (pyNO−)2GaCl Complex.
Ga(1)1.124Cl(1)−0.418
N(1)/N(3)−0.470N(2)/N(4)−0.076
O(1)/O(2)−0.565--

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Kirsh, J.M.; Woodside, A.J.; Manor, B.C.; Carroll, P.J.; Rablen, P.R.; Graves, C.R. Synthesis and Characterization of (pyNO−)2GaCl: A Redox-Active Gallium Complex. Inorganics 2018, 6, 50. https://doi.org/10.3390/inorganics6020050

AMA Style

Kirsh JM, Woodside AJ, Manor BC, Carroll PJ, Rablen PR, Graves CR. Synthesis and Characterization of (pyNO−)2GaCl: A Redox-Active Gallium Complex. Inorganics. 2018; 6(2):50. https://doi.org/10.3390/inorganics6020050

Chicago/Turabian Style

Kirsh, Jacob M., Audra J. Woodside, Brian C. Manor, Patrick J. Carroll, Paul R. Rablen, and Christopher R. Graves. 2018. "Synthesis and Characterization of (pyNO−)2GaCl: A Redox-Active Gallium Complex" Inorganics 6, no. 2: 50. https://doi.org/10.3390/inorganics6020050

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