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Review

Reviews of European Patents on Nickel/Metal Hydride Batteries

by
Shiuan Chang
1,2,
Kwo-Hsiung Young
2,3,* and
Yu-Ling Lien
4
1
Department of Mechanical Engineering, Wayne State University, Detroit, MI 48202, USA
2
BASF/Battery Materials—Ovonic, 2983 Waterview Drive, Rochester Hills, MI 48309, USA
3
Department of Chemical Engineering and Materials Science, Wayne State University, Detroit, MI 48202, USA
4
Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA
*
Author to whom correspondence should be addressed.
Batteries 2017, 3(3), 25; https://doi.org/10.3390/batteries3030025
Submission received: 22 June 2017 / Revised: 25 July 2017 / Accepted: 27 July 2017 / Published: 26 August 2017
(This article belongs to the Special Issue Nickel Metal Hydride Batteries 2017)
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Abstract

:
Patent applications in the field of nickel/metal hydride (Ni/MH) batteries are reviewed to provide a solid technology background and directions for future developments. As the fourth review article in the series of investigations into intellectual properties in this area, this article focuses on 126 patent applications filed by European companies at the European Patent Office, while the earlier articles dealt with those from USA, Japan, and China. The history and current status of the key companies in the Ni/MH battery business are briefly discussed. These companies are categorized by their main roles in the industry, i.e., battery manufacturer, metal hydride alloy supplier, separator supplier, and others. While some European companies are pioneers in bringing the Ni/MH product to customers, others have made significant contributions to the development of the technology, especially in the button cell, bipolar cell, and separator areas.

Graphical Abstract

1. Introduction

Nickel/metal hydride (Ni/MH) batteries are widely used in consumer electronics, stationary energy storage, and hybrid electric vehicles (HEV). Their advantages are in energy density (compared to the replaced NiCd), cycle stability at deep discharge (>3000), robust construction, ability to be quickly charged, environmental friendliness, and higher abuse tolerance (compared to the Li product) [1]. Two types of Ni/MH batteries are available: the small consumer type (usually cylindrical with a capacity <4 Ah) and the larger transportation type (usually prismatic with a capacity >6 Ah). Nowadays, most consumer type and HEV Ni/MH batteries are produced in China and Japan. Nevertheless, European companies still have a small portion of the market share (for example, about 10% in 2013 [2]) (Figure 1a). On the other hand, European countries are a large market for consumer type Ni/MH batteries. For instance, in 2013, Germany, the Netherlands, Belgium, and the UK accounted for a combined 8.3% of the Ni/MH batteries exported from China [2] (Figure 1b), and in February 2014 Europe received 32.7% of the Ni/MH batteries from Japanese manufacturers (mainly FDK, Tokyo, Japan) [2] (Figure 1c). European companies made great contributions to the debut of Ni/MH batteries in their early days. For example, Klaus-Dieter Beccu from Battelle Memorial Institute (Geneva, Switzerland) contributed to the earliest patent using MH alloy as the active material in the negative electrode to construct a Ni/MH battery in 1970 [3]; Annick Percheron-Guégen and her coworkers from the Agence Nationale de Valorisation de la Recherche (Neuilly sur Seine, France) filed the first patent of using LaNi5 modified with Ti, Ca, Ba, Cr, and/or Cu with improved capacity as negative electrode material in 1978 [4]; and Johannes Willems, Johann van Beek, and Buschow Kurt from Philips (Eindhoven, Netherlands) filed a USA patent adding Co and/or Cu in LaNi5 to reduce the lattice expansion during hydride process and consequently extend the cycle life in 1984 [5]. In the past, we have reviewed the Ni/MH-related patents (or patents applications) filed in the USA [6], Japan [7], and China [8]. In this review, we focus on patent applications to the European Patent Office submitted by European companies; these applicants are grouped as battery manufacturers, metal hydride (MH) alloy suppliers, separator suppliers, and others. The patent applications can be found online through the website of World Intellectual Property Organization (WIPO) [9]. In the case of a non-English description, a machine translation option supplied by WIPO is available free of charge. A brief introduction of European companies contributing to the European Patent Application (EPA) is included in Table 1.

2. Ni/MH Battery Manufacturer

Patent applications from five European battery/chemical companies related to the fabrication of Ni/MH batteries are reviewed in this section. There are two large European companies, Varta (Ellwangen, Germany) and SAFT (Bagnolet, France), that manufactured consumer-type Ni/MH batteries and submitted patent applications in related fields over the past two decades. In 2002, Varta microbattery spun off from Varta and focused on the button cell business. In 2013, SAFT sold its Small Nickel Battery division to Arts Energy (Nersac, France). Alcatel (later merged into Lucent Technology, Paris, France) made Ni/MH batteries for cell phones and was active in filing patent applications. Recently, Nilar (Täby, Sweden) began to offer bi-polar prismatic Ni/MH batteries for transportation applications. Hoppecke (Brilon-Hoppecke, Germany) made prismatic flooded-type Ni/MH batteries for transportation applications.

2.1. SAFT and Arts Energy

The Société des Accumulateurs Fixes et al Traction (SAFT) was founded in 1918 and manufactured batteries for the luggage carts and lighting in locomotives. In 2006, Saft and Johnson Controls (Milwaukee, WI, USA) formed a joint-venture pursuing batteries for electric vehicles (EV) and HEV. It was acquired by Total (Courbevoie, France) and delisted from the stock exchange in 2016. SAFT filed 24 and 19 European patent applications (EPAs) from 1990 to 2013 in the name of Accumulateurs Fixes and SAFT SA, respectively. In the positive electrode area, SAFT filed EPAs on the following subjects: a fabrication method of co-precipitated metal hydroxide [10], a description of characteristic of β-Ni(OH)2 [11], a fabrication method of pasted electrode [12,13], and uses of several additives including Celestine [14], CoO with a spinal structure [15], active carbon [16], Li(OH)2 [17], Ba(OH)2 and Sr(OH)2 [18], Nb2O5 [19], non-conductive fiber [20], and plastic binders [21,22,23]. Out of these inventions, those with additives and binders are particularly helpful in improving the performance of positive electrodes. In the negative electrode area, SAFT filed EPAs on the following subjects: active materials made from a single phase TiNi-based alloy [24], a Zr-based C14 AB2 alloy [25], a mixed-metal based AB5 alloy [26], superlattice alloys containing Y [27], Mg [28], or Zr (Ti) [29] and A2B7 [30] and A5B19 [31] phases, a catalytic substrate [32], a hydrophilic additive [33], and a paste process [34]. Among these EPAs, the superlattice alloy-related patents lead to a new direction of material research in MH alloy field. SAFT filed multiple EPAs on the subject of a foam substrate and associated current collector design [35,36,37,38,39,40,41] (Figure 2), which built a strong foundation for further research in the area. In the separator area, SAFT filed EPAs on microporous grafted membranes [42,43], a tri-layer composite [44], a double-layer with different orientations [45], and a N-retaining substrate [46]. SAFT also filed three EPAs on a charging algorithm [47,48,49] and one on a leak-tight box for holding battery modules [50].
Arts Energy filed two EPAs in the early days; one on the re-sealable safety valve [51] and the other one on a battery cooling module design [52]. Arts Energy continues to perform research and produce Ni/MH batteries after it was purchased from SAFT in 2013, but has not filed an EPA since then. Its products are mainly cylindrical NiCd and Ni/MH batteries (Figure 3).

2.2. Varta and Varta Microbattery

Varta (originally Vertrieb, Aufladung, Reparatur Transportabler Akkumulatoren) was founded in 1887 and produced the batteries that powered the first EV in Germany. For the production of Ni/MH batteries, Varta formed a joint-venture, 3C Alliance, with Toshiba (Tokyo, Japan) and Duracell (Bethel, CT, USA) in 1996. Varta filed 10 EPAs in 1994 and 1995, which cover an oxidation-resistant graphite additive in the positive electrode [54,55], a use of foam or felt electrode in the button cell [56], a multi-segment cylindrical cell design [57] (Figure 4a), a button cell design [58,59] (Figure 4b), Fe- [60], Ti(Zr)- [61] containing AB5 MH alloys, and metal recovery from spent batteries [62,63]. Out of these EPAs, those related to the new cell structure designs are important to extend the applicability of Ni/MH into various fields.
In 2002, Johnson Controls acquired the automotive battery division of Varta. Immediately before the sale, Varta Automotive GMGB filed an EPA on an electrolyte containing soluble Al-compound added in the positive electrode to improve high-temperature charge acceptance [65].
Varta Microbattery was a spin-off company from Varta in 2002 and is now owned by Montana Tech Components (Menziken, Switzerland). Their main products are button cells (Figure 5). Between 1998 and 2015, five EPAs were filed with Varta Microbattery as the assignee. They covered the areas of a charging device for Ni/MH battery [66,67], a hollow-cathode cylindrical cell design [64] (Figure 4c), and a battery/supercapacitor composite design [68,69]. The combination of rechargeable battery and supercapacitor increases the high-rate charging capability of Ni/MH battery and opens the door for some power-demanding applications.

2.3. Alcatel

Alcatel (originally short fir the Société Alsacienne de Constructions Atomiques, de Télécommunications et ďÉlectronique) was merged into CGE in 1966, which was later merged again with Lucent Technologies in 2006 and formed Alcatel-Lucent. It was finally merged into the Nokia Group in 2016. Alcatel made Ni/MH batteries for cell phones and cordless phone (Figure 6). Between 1994 and 2003, Alcatel filed 8 EPAs under the names of Alsthom CGE Alcatel and CIT Alcatel. They disclosed two designs for metal current collectors [71,72] (Figure 7), a minus ΔV cut-off charge control method [73], a C14 AB2 MH alloy [74], a coated, perforated metal substrate for a negative electrode [75], a double-layered separator [76], a cell design with a negative/positive ratio >1.15 [77], and a Ni(OH)2 coating on a MH alloy to improve low-temperature and cycle performance [78]. The last EPA is very important for the use of Ni/MH battery in areas with very harsh winter, Siberia, for example.

2.4. Nilar

Nilar was founded in Sweden in 2011. Before moving to Sweden, Nilar used to operate its research facility in Aurora, CO, USA. Nilar’s main product is a prismatic, bi-polar Ni/MH battery used in transportation applications (Figure 8). Nilar owns 14 USA Patents covering components, casing, assembly, module construction of a bi-polar design Ni/MH battery. Nilar filed 13 EPAs between 2002 and 2012, which included assembly of bipolar plates design [80] and manufacture [81], design [82] and manufacture [83,84,85,86] of a current collector, a case [87], a stacking arrangement [88], a pressure sensor [89], a powder reduction unit [90], a gasket design [91], and an energy managing system [92] for bipolar Ni/MH batteries. These bi-polar Ni/MH batteries are very important for large-scale transportation applications, which require both large capacity and high-rate drain capability. Recently, Prof. Dag Noréus filed an international Patent Cooperation Treaty (PCT) with Nilar regarding the addition of H2, O2, and/or H2O2 in sealed Ni/MH batteries to extend cycle life [93].

2.5. Hoppecke

Hoppecke was founded in 1927 to produce industrial batteries. It supplied lead-acid, Ni/MH (Figure 9), and Li-ion batteries to railway applications. Hoppecke filed two EPAs in 2011 disclosing a positive electrode manufacturing process [95] and a flooded design for a Ni/MH battery [96]. The latter is unusual and opens the way for stationary storage associated with alternative energies, such as solar and wind power.

3. MH Alloy Suppliers

GfE (Nuremberg, Germany) and Treibacher (Althofen, Austria) were previously the only two European companies producing MH materials used as active materials in the negative electrode of Ni/MH battery. Nowadays, all the Ni/MH battery manufacturers have switched to vendors from Japan and China.

3.1. GfE

GfE was founded in 1911 to produce metal products with electric furnaces. Today, it still offers an AB2-based MH alloy, mainly for the use of solid hydrogen storage [98]. GfE filed one EPS in 1999 regarding addition of a metal oxide (Cr2O3, for example) to hydrogen storage material (Mg, for example) as a catalyst [99].

3.2. Treibacher

Treibacher Industries AG was founded in 1898 to produce ferroalloy for the steel industry. Today, it still offers AB2 and AB5 MH alloys for hydrogen storage and battery applications, respectively [100]. Treibacher filed an EPA in 2001 to cover a Cr-containing AB5 MH alloy [101]. It also filed an international PCT on a two-chamber hydrogen storage canister [102].

4. Separator Suppliers

Scimat (Swindon, UK) and Freudenberg (Weinheim, Germany) were once two major separator companies making non-woven grafted polyethylene/polypropylene separators for Ni/MH battery producers worldwide. In 2006, Scimat was acquired by Freudenberg and, together, they still supply separators for high-performance Ni/MH batteries, especially in the HEV area. In 2015, Freudenberg also became the largest (75%) stockholder for Nippon Vilene—the top nonwoven producer in Japan.

4.1. Scimat

Scimat was founded in 1987, focusing on the production and development of automated controlled separator production process. It was acquired by its main competitor, Freudenberg, in 2006. Between 1985 and 1998, Scimat filed 7 EPSs on a grafting method preparing microporous particles [103], a halopolymer film [104,105], a double-layer (one porous, the other one partially blocking the pores) membrane [106], a grafted sheet composed of copolymer and polyolefin [107], an ultraviolet radiation process to increase the surface hydrophilicity of the separator [108], and a laminate composed of fiber and vinyl monomer on the surface [109]. The Scimat separator is very important in the HEV application.

4.2. Freudenberg

Freudenberg was founded in 1849 to make leather products. Combining the intellectual property and production capacity of past rivals Scimat and Nippon Vilene, Freudenberg became the only separator producer outside of China. Freudenberg filed 8 EPAs from 1993 to 2010, covering the subjects of a non-woven hydrophilic separator material [110], a grafting process making separator material from polymers [111], an addition of alkaline hydroxide or carbonate in the separator before use [112], a separator material containing a titrimetrically determined ammonia binding property [113], a chemically active separator material with an alkaline electrolyte [114], a bi-layer separator with different fiber diameters [115], a core-shell duel-component fiber as a separator [116], and a separator material with coating to enhance its puncturing resistance [117]. Together with Eveready Battery Company (St. Louis, MO, USA), Freudenberg filed an EPA on a cell design using a separator less than 0.15 mm thick in the dry state [118] (Figure 10).

5. Other Companies

In addition to the companies mentioned above, which are (or were) involved directly with the manufacturing of Ni/MH batteries, there are other companies and universities in Europe that occasionally applied for EPAs in the Ni/MH battery field. In battery design, Deutsche Automobilgesellschaft (now a subsidiary of Daimler AG, Stuttgart, Germany) filed 3 EPAs on a prismatic cell [119] with the negative electrode covered by polytetrafluoroethylene (PTFE) threads [120], and a bi-polar design of electrode stacking [121].
In the Ni(OH)2 area, the University of Southampton (Southampton, UK) filed one EPA [122] and two PCTs [123,124] on the subject of a porous positive electrode active material with regularly spaced pores. In the MH alloy area, Höganäs AB (Höganäs, Sweden) filed two EPAs on an organically modified silicic acid coating for MH alloys [125], and MH alloys prepared by gas atomization with a unique dendritic microstructure [126]. Fraunhofer-Gesellschaft (Munich, Germany) also filed an EPA on an organically modified silicic acid polycondensated coating for MH alloys [127].
In the charging algorithm and devices, Peugeot (Paris, France) presented a method relating to inner pressure to the state-of-charge (SOC) [128]; Friwo Geräetebau (Ostbevern, Germany) patented a temperature sensor equipment charging device [129]; SGS Thomson Microelectronics (Geneva, Switzerland) disclosed a −ΔV cut-off method [130,131]; and Solarc Innovative Solarprodukte (Berlin, Germany) disclosed a solar-cell compatible battery charging unit [132].
EU countries are very concerned about battery recycling activities [133]. A special program, COLABATS, was initiated in Europe in 2013 to conduct the development of recycling technology for Ni/MH and Li-ion batteries [134]. In terms of battery recycling, Umicore (Brussels, Belgium) patented a smelting process to reclaim Ni and Co [135]; Montanuniversität Leoben (Leoben, Austria) disclosed a method of reclaiming rare earth metals by using a non-oxidizing acid [136]; Akkuser Ltd. (Nivala, Finland) has a Patent issued on the separation of spent batteries by chopping or crushing followed by a refining or smelting process [137]; CT Umwelttechnik AG (Winterthur, Switzerland) patented a recycling process for the mixture of various kind of batteries [138]; Titalyse S.A. (Croix-de-Rozon, Switzerland) patented an apparatus to sort spent batteries with different size and shape by an optical camera with imaging software [139]; Enviro EC AG (Zug, Switzerland) published a method of reclaiming MH from spent batteries by magnetic separation [140]; SNAM (Saint-Quentin-Fallavier, France) also reclaimed MH by spraying surfactant and later sedimentation [141]; and Eco Recycling SRL (Rome, Italy) reported a physical/chemical combinational method to reclaim Cu and plastic materials [142]. Additionally, French Alternative Energies and Atomic Energy Commission (Gif-sur-Yvette, France) filed a PCT on a process to reclaim rare earth elements, specifically Ni, Co, Mn, and Fe, by selective salt precipitation from a mixture of acid solution for spent Ni/MH battery [143]. Finally, only one EPA was found for the application of Ni/MH batteries, a low self-discharge battery used in soap dispensers filed by Vivian Blick [144].

6. Comparisons to Other Countries

The development of MH alloy and associated Ni/MH battery started from European companies, such as Battelle, Philips, Benz (Stuttgart, Germany) and followed by the successful commercialization by American and Japanese companies [145]. Now the Ni/MH batteries are mainly fabricated in China and Japan. Throughout the years, many important patents were filed in these four areas/countries, namely EU, USA, Japan, and China. The nature of these patent applications is compared in Table 2. Compared to other area/countries, European companies filed the fewest patents (application) in the Ni/MH field. However, their patents in areas such as button cells (owned by Varta Micronbattery), bi-polar design (owned by Nilar), and separators (owned by SciMat and now Freudenberg) are all very important. USA has the largest consumer market in the world and most of its patents related to Ni/MH batteries were filed by Japanese and European companies.

7. Conclusions

A total of 126 patent applications related to Ni/MH batteries and filed by European companies to the European Patent Office were reviewed. The scope covers metal hydride formulations and processing, nickel hydroxide preparation, electrode fabrication, cell design, charging method, and recycling. Together with reviews of patents (applications) in the Ni/MH field filed in the USA, Japan, and China, this work completes our studies on the intellectual properties in this field. Compared to companies (institutes) in other countries, European companies started the Ni/MH battery, but were not as active in the development of the production technology. They still made significant contributions in the separator and prismatic cell areas.

Author Contributions

Shiuan Chang collected the information. Kwo-Hsiung Young and Yu-Ling Lien prepared the manuscript.

Conflicts of Interest

The authors declare no conflict of interest.

Abbreviations

The following abbreviations are used in this manuscript:
Ni/MHNickel/metal hydride
HEVHybrid electric vehicle
MHMetal hydride
WIPOWorld Intellectual Property Organization
EPAEuropean Patent Application
EVElectric vehicle
PCTPatent Cooperation Treaty
PTFEPolytetrafluoroethylene
SOCState-of-charge

References

  1. Battery and Energy Technologies. Available online: http://www.mpoweruk.com/nimh.htm (accessed on 25 May 2017).
  2. Bai, W. The Current Status and Future Trends of Domestic and Foreign NiMH Battery Market. Available online: http://cbea.com/u/cms/www/201406/06163842rc0l.pdf (accessed on 25 May 2017).
  3. Beccu, K.-D. Electrical Accumulator with a Metal Hydride Serving as the Cathodic Reactive Material Arranged in Suspension in the Electrolyte. U.S. Patent 3,520,728, 14 July 1970. [Google Scholar]
  4. Percheron-Guégen, A.; Achard, J.C.; Loriers, J.; Bonnemay, M.; Bronoёl, G.; Sarradin, J.; Schlapbach, L. Electrode Materials Based on Lanthanum and Nickel, and Electrochemical Uses of Such Materials. U.S. Patent 4,107,405, 15 August 1978. [Google Scholar]
  5. Willems, J.J.G.S.A.; van Beek, J.R.G.C.M.; Buschow, K.H.J. Electrochemical cell comprising stable hydride-forming material. U.S. Patent 4,487,817, 11 December 1984. [Google Scholar]
  6. Chang, S.; Young, K.; Nei, J.; Fierro, C. Reviews on the U.S. Patents regarding nickel/metal hydride batteries. Batteries 2016, 2, 10. [Google Scholar] [CrossRef]
  7. Ouchi, T.; Young, K.; Moghe, D. Reviews on the Japanese Patent Applications regarding nickel/metal hydride batteries. Batteries 2016, 2, 21. [Google Scholar] [CrossRef]
  8. Young, K.; Cai, X.; Chang, S. Reviews on the Chinese Patent regarding Nickel/metal hydride battery. Batteries 2017, 3, 24. [Google Scholar] [CrossRef]
  9. World Intellectual Property Organization. Available online: https://patentscope.wipo.int/search/en/search.jsf (accessed on 23 May 2017).
  10. Blanchard, P.; Klein, J.P. Process for the Preparation of a Metal Hydride Powder and the Powder Obtained. Eur. Pat. Appl. 91401640, 18 June 1991. [Google Scholar]
  11. Bernard, P.; Audry, C.; Lecerf, A.; Senyarich, S. Nickel Electrode for Alcaline Accumulator. Eur. Pat. Appl. 96400423, 28 February 1996. [Google Scholar]
  12. Bernard, P.; Dennig, C.; Cocciantelli, J.-M.; Coco, I.; Alcorta, J. Non-Sintered Nickel Electrode. Eur. Pat. Appl. 99400049, 11 January 1999. [Google Scholar]
  13. Bernard, P.; Simonneau, O.; Bertrand, F. Pasted Nickel Electrode. Eur. Pat. Appl. 97401011, 5 May 1997. [Google Scholar]
  14. Bernard, P.; Goubault, L.; Guiader, O. Positive Electrode for an Electrochemical Generator with an Alkaline Electrolyte. Eur. Pat. Appl. 08290869, 16 September 2008. [Google Scholar]
  15. Bernard, P.; Audry, C. Conductive Material for Electrode of Secondary Battery with Alkali Electrolyte. Eur. Pat. Appl. 01401672, 25 June 2001. [Google Scholar]
  16. Chevalier, S.; Debdary, M.; Desprez, P. Negative Electrode for an Asymmetric Supercapacitor with Nickel Hydroxide Positive Electrode and Alkali Electrolyte and Method for Manufacturing Same. Eur. Pat. Appl. 12167763, 11 May 2012. [Google Scholar]
  17. Bernard, P.; Baudry, M.; Jan, O.; Audry, C. Non-Sintered Nickel Electrode for Secondary Battery with Alkali Electrolyte. Eur. Pat. Appl. 99403260, 23 December 1999. [Google Scholar]
  18. Bernard, P.; Goubault, L.; Hezeque, T. Electrochemical Alkaline Generator with Improved Service Life. Eur. Pat. Appl. 05291300, 17 June 2005. [Google Scholar]
  19. Bernard, P.; Goubault, L.; Gillot, S. Electrode for Alkaline Storage Battery. Eur. Pat. Appl. 12175342, 6 July 2012. [Google Scholar]
  20. Bernard, P. Positive Electrode for Alkaline Battery. Eur. Pat. Appl. 06291402, 5 September 2006. [Google Scholar]
  21. Coco, I.; Cocciantelli, J.-M.; Villenave, J.-J. Electrode of non Sintered Type for Accumulator with Alkaline Electrolyte. Eur. Pat. Appl. 97401723, 17 July 1997. [Google Scholar]
  22. Bernard, P.; Goubault, L. Plastified Electrode for Alkaline Battery. Eur. Pat. Appl. 07848215, 11 September 2007. [Google Scholar]
  23. Bernard, P.; Goubault, L.; Gillot, S.; Feugnet, T. Plastic-Coated Electrode for Alkaline Storage Battery. Eur. Pat. Appl. 10162920, 17 May 2010. [Google Scholar]
  24. Bouet, J.; Knosp, B.; Percheron-Guegan, A.; Jordy, C. Hydridable Material for a Nickel-Hydride Battery Negative Electrode and Process for Production. Eur. Pat. Appl. 93401399, 2 June 1993. [Google Scholar]
  25. Bouet, J.; Knosp, B.; Percheron-Guegan, A.; Canet, O. Hydridable Material for a Nickel-Hydride Battery Negative Electrode. Eur. Pat. Appl. 93402198, 9 September 1993. [Google Scholar]
  26. Bouet, J.; Knosp, B.; Percheron-Guegan, A.; Cocciantelli, J.-M. Hydridable Material for Nickel-Hydride Accumulator Negative Electrode. Eur. Pat. Appl. 0608646, 3 August 1994. [Google Scholar]
  27. Bernard, P.; Knosp, B.; Baudry, M. Composition for Negative Electrode of Accumulator with Alkaline Electrolyte. Eur. Pat. Appl. 07291035, 23 August 2007. [Google Scholar]
  28. Lavaud, C.; Dillay, V.; Bernard, P. Negative Active Material for Hydride metal Nickel Accumulator. Eur. Pat. Appl. 08012162, 4 July 2008. [Google Scholar]
  29. Bernard, P.; Knosp, B.; Latroche, M.; Zhang, J.; Serin, V.; Hytch, M. Active Material for a Negative Electrode of a Nickel-Metal Hydride Alkaline Accumulator. Eur. Pat. Appl. 11188182, 8 November 2011. [Google Scholar]
  30. Bernard, P.; Knosp, B.; Baudry, M. Active Material Composition and Alkaline Electrolyte Accumulator. Eur. Pat. Appl. 06290808, 18 May 2006. [Google Scholar]
  31. Bernard, P.; Knosp, B.; Latroche, M.; Ferey, A. Hydridable Alloy for Alkaline Storage Battery. Eur. Pat. Appl. 07290197, 16 February 2007. [Google Scholar]
  32. Senyarich, S.; Cocciantelli, J.-M. Hydrophylic Electrode for Alkaline Accumulator and Method of Preparation. Eur. Pat. Appl. 97402510, 23 October 1997. [Google Scholar]
  33. Sjövall, R.; Greis, M. Low Maintenance Alkaline Electrochemical Cell. Eur. Pat. Appl. 12190882, 31 October 2012. [Google Scholar]
  34. Coco, I.; Cocciantelli, J.-M.; Villenave, J.-J. Negative Electrode for Ni-Metal Hydride Accumulator. Eur. Pat. Appl. 96400850, 22 April 1996. [Google Scholar]
  35. Grange-Cossou, M.; Torregrossa, W. Process of Manufacturing an Electrode with Spongiform Support for Electrochemical Generator and Electrode Obtained Thereby. Eur. Pat. Appl. 90117834, 17 September 1990. [Google Scholar]
  36. Caillon, G.; Lebarbier, C. Method for Covering an Electrode with a Sponge like Support for Electrochemical Generator and Electrode Obtained by This Process. Eur. Pat. Appl. 90121037, 2 November 1990. [Google Scholar]
  37. Guerinault, J.-M.; Brunarie, J. Method for Joining a Metallic Current Collector to an Electrode Comprising a Spongeous Supporting Structure for Electrochemical Generator and Electrode Obtained Thereby. Eur. Pat. Appl. 91121081, 9 December 1991. [Google Scholar]
  38. Grange-Cossou, M.; Guerinault, J.-M.; Carteau, B.; Brunarie, J. Method for Joining a Metallic Collector to an Electrode Comprising a Spongeous Supporting Structure for Electrochemical Generator and Electrode Obtained Thereby. Eur. Pat. Appl. 92401446, 26 May 1992. [Google Scholar]
  39. Bouet, J.; Pichon, B. Process for Making a Foam-Type Support for an Electrode of a Secondary Battery. Eur. Pat. Appl. 92401861, 30 June 1992. [Google Scholar]
  40. Fradin, J. Cylindrical Electrochemical Generator with Spirally Wounded Electrodes. Eur. Pat. Appl. 97401780, 24 July 1997. [Google Scholar]
  41. Goubault, L.; Bernard, P.; Gillot, S. Plastic-Coated Electrode for Alkaline Storage Battery. Eur. Pat. Appl. 14170069, 27 May 2014. [Google Scholar]
  42. Gineste, J.-L.; Pourcelly, G.; Brunea, J.; Perton, F.; Broussely, M. Grafted Microporous Separator for Electrochemical Generator and Its Manufacturing Process. Eur. Pat. Appl. 93402037, 10 August 1993. [Google Scholar]
  43. Caillon, G.; Crochepierre, B. Alkaline Open Battery Comprising a Microporous Membrane. Eur. Pat. Appl. 06290869, 30 May 2006. [Google Scholar]
  44. Green, A.; Champalle, P.; Liska, J.-L. Separator for Alkaline Accumulator. Eur. Pat. Appl. 91402721, 11 October 1991. [Google Scholar]
  45. Senyarich, S.; Leblanc, P. Separator for Accumulator with Spirally Wounded Electrodes and Alkaline Electrolyte. Eur. Pat. Appl. 97401667, 10 July 1997. [Google Scholar]
  46. Senyarich, S.; Viaud, P. Alkaline Electrolyte Secondary Battery. Eur. Pat. Appl. 97402264, 29 September 1997. [Google Scholar]
  47. Berlureau, T.; Liska, J.-L. Method for Charging Maintenance-Free Nickel Metal Hydride Batteries. Eur. Pat. Appl. 98400455, 26 February 1998. [Google Scholar]
  48. Berlureau, T.; Bariand, M.; Liska, J.-L. Method for Controlling the Rapid Charging of an Alkaline Electrolyte Industrial Accumulator. Eur. Pat. Appl. 99401903, 26 July 1999. [Google Scholar]
  49. Gardes, F.; Juan, A.; Maloizel, S. Method for Managing the Charge of a Battery. Eur. Pat. Appl. 08291208, 18 December 2008. [Google Scholar]
  50. Vasti, P.; Tridon, X. Leaktight Box for Alkaline Batteries. Eur. Pat. Appl. 13773814, 9 October 2013. [Google Scholar]
  51. Payen, S.; Raymond, A. A Resealable Valve and Electrochemical Generator Comprising Said Valve. Eur. Pat. Appl. 01402994, 22 November 2001. [Google Scholar]
  52. Vigier, N.; Besse, S. Electrochemical Generator with Surface of Revolution. Eur. Pat. Appl. 03290969, 18 April 2003. [Google Scholar]
  53. Arts Energy. Available online: http://www.arts-energy.com/ (accessed on 25 May 2017).
  54. Lichtenberg, F.; Kleinsorgen, K.; Hofmann, G. Nickel/Metallic Hydride Secondary Cell. Eur. Pat. Appl. 94116439, 19 October 1994. [Google Scholar]
  55. Lichtenberg, F.; Kleinsorgen, K.; Hofmann, G. Electrical Nickel-Metal Hydride Accumulator with Electrode of Nickelhydroxide Comprising Graphite. Eur. Pat. Appl. 94115951, 10 October 1994. [Google Scholar]
  56. Klaus, C. Gastight Alkaline Button-Type Accumulator. Eur. Pat. Appl. 94116622, 21 October 1994. [Google Scholar]
  57. Klaus, C.; Simon, G.; Koehler, U.; Kannler, H. Gastight Nickel/Hydride-Accumulation of Round Cell Type. Eur. Pat. Appl. 95194924, 18 March 1995. [Google Scholar]
  58. Koehler, U.; Chen, G.; Lindner, J. Gastight Metaloxide-Metalhydride Accumulator. Eur. Pat. Appl. 95106832, 5 May 1995. [Google Scholar]
  59. Koehler, U.; Klaus, C.; Hofmann, G.; Lichtenberg, F. Alkaline Gastight Accumulator in the Shape of a Button Cell. Eur. Pat. Appl. 95106833, 5 May 1995. [Google Scholar]
  60. Lichtenberg, F.; Koehler, U.; Kleinsorgen, K.; Foelzer, A.; Bouvier, A. Alkaline Metal Oxide, Metal Hydride Battery. Eur. Pat. Appl. 96102419, 17 February 1996. [Google Scholar]
  61. Lichtenberg, F. Alloys for Use as Active Material for the Negative Electrode of an Alkaline, Rechargeable, Nickel Metal-Hybride Battery and Its Method of Preparation. Eur. Pat. Appl. 96110281, 26 June 1996. [Google Scholar]
  62. Kleinsorgen, K.; Koehler, U.; Bouvier, A.; Foelzer, A. Process for Recovery of Metals from Used Nickel-Metal Hydride Accumulators. Eur. Pat. Appl. 95940265, 1 December 1995. [Google Scholar]
  63. Kleinsorgen, K.; Koehler, U.; Bouvier, A.; Foelzer, A. Process for Recovery of Metals from Used Nickel-Metal Hydride Accumulators. Eur. Pat. Appl. 95941642, 1 December 1995. [Google Scholar]
  64. Brenner, R. Electrochemical Cell with a Positive Electrode in the Form of a Hollow Cylinder and a Negative Electrode Assembled Therein. Eur. Pat. Appl. 13178468, 30 July 2013. [Google Scholar]
  65. Baeuerlein, P. Nickel-Metal Hydride Secondary Battery. Eur. Pat. Appl. 01116524, 7 July 2001. [Google Scholar]
  66. Knop, I. Charging Device Adapted for Charging NiMeH Batteries. Eur. Pat. Appl. 98102036, 6 February 1998. [Google Scholar]
  67. Schein, H.; Kron, N.; Ilic, D. Mobile Charger for Charging Secondary Batteries from Secondary Batteries. Eur. Pat. Appl. 06776545, 2 August 2006. [Google Scholar]
  68. Schula, C.; Scholz, S.; Pytlik, E.; Ensling, D. Secondary Electrochemical Cell and Charging Method. Eur. Pat. Appl. 15735963, 9 July 2015. [Google Scholar]
  69. Schula, C.; Scholz, S.; Pytlik, E.; Ensling, D. Secondary Electrochemical Cell and Charging Method. Eur. Pat. Appl. 15735964, 9 July 2015. [Google Scholar]
  70. VARTA. Available online: http://www.varta-microbattery.com (accessed on 25 May 2017).
  71. Loustau, M.-T.; Verhoog, R.; Precigout, C. Method for Joining a Metallic Current Collector to an Electrode Comprising a Fibrous or a Spongeous Supporting Structure for Electrochemical Generator and Electrode Obtained Thereby. Eur. Pat. Appl. 94401155, 25 May 1994. [Google Scholar]
  72. Amiel, O.; Belkhir, I.; Freluche, J.-P.; Pineau, N.; Dupuy, C.; Babin, S. Non-Sintered Electrode with Tridimensional Support for Secondary Battery with Alcaline Electrolyte. Eur. Pat. Appl. 00403112, 9 November 2000. [Google Scholar]
  73. Cuesta, R.; Rouverand, C. Charge Control Method of a Sealed Nickel Storage Cell and Charger Therefor. Eur. Pat. Appl. 94401127, 20 May 1994. [Google Scholar]
  74. Knosp, B.; Mimoun, M.; Bouet, J.; Gicquel, D.; Jordy, C. Hydridable Material for Nickel-Hydride Accumulator Negative Electrode. Eur. Pat. Appl. 95400803, 10 April 1995. [Google Scholar]
  75. Cypel, L. Metal Hydride Negative Electrode Comprising a Coated Perforated Sheet. Eur. Pat. Appl. 98401150, 14 May 1998. [Google Scholar]
  76. Senyarich, S.; Viaud, P. Alkaline Electrolyte Secondary Battery, Particularly of the Type nickel-Cadmium or Nickel Metal Hydride. Eur. Pat. Appl. 98402291, 17 September 1998. [Google Scholar]
  77. Berlureau, T.; Liska, J.-L. Sealed Nickel-Metal Hydride Storage Battery. Eur. Pat. Appl. 00402019, 13 July 2000. [Google Scholar]
  78. Bernard, P.; Goubault, L.; Le, G.L. Electrochemically Active Material for Negative Electrode of an Alkaline Electrolyte Secondary Battery. Eur. Pat. Appl. 03290119, 17 January 2003. [Google Scholar]
  79. Alcatel-Lucent. Available online: https://en.wikipedia.org/wiki/Alcatel-Lucent (accessed on 29 July 2017).
  80. Fredriksson, L.; Puester, N. A Method for Manufacturing a Biplate Assembly, a Biplate Assembly and a Bipolar Battery. Eur. Pat. Appl. 02746283, 8 July 2002. [Google Scholar]
  81. Hug, L.; Puester, N.H.; Fredriksson, L. An Apparatus for Manufacturing an Electrode. Eur. Pat. Appl. 03770206, 7 November 2003. [Google Scholar]
  82. Fredriksson, L.; Puester, N. A Bipolar Battery and a Biplate assembly. Eur. Pat. Appl. 02798876, 13 September 2002. [Google Scholar]
  83. Fredriksson, L.; Puester, N. A Bipolar Battery, a Method for Manufacturing a Bipolar Battery and a Biplate Assembly. Eur. Pat. Appl. 02798875, 13 September 2002. [Google Scholar]
  84. Fredriksson, L.; Puester, N.H. An Electrode, a Method for Manufacturing an Electrode and a Bipolar Battery. Eur. Pat. Appl. 03810729, 7 November 2003. [Google Scholar]
  85. Fredriksson, L.; Puester, N.H. A Bipolar Battery and a Method for Manufacturing a Bipolar Battery. Eur. Pat. Appl. 03812398, 7 November 2003. [Google Scholar]
  86. Hock, D.; Puester, N.; Fredriksson, L. A Method for Manufacturing a Bipolar Battery with a Gasket. Eur. Pat. Appl. 04800257, 3 November 2004. [Google Scholar]
  87. Jensen, K.; Puester, N.; Hock, D. A Casing for a Sealed Battery. Eur. Pat. Appl. 06717032, 20 March 2006. [Google Scholar]
  88. Fredriksson, L.; Puester, N.H.; Howlett, R. A Battery Stack Arrangement. Eur. Pat. Appl. 07703860, 15 January 2007. [Google Scholar]
  89. Fredriksson, L.; Howlett, R. A Bipolar Battery Including a Pressure Sensor. Eur. Pat. Appl. 07712225, 15 February 2007. [Google Scholar]
  90. Fredriksson, L.; Puester, N.H. A System for Reducing the Power in a Battery Stack Arrangement. Eur. Pat. Appl. 07852114, 17 December 2007. [Google Scholar]
  91. Hock, D.; Fredriksson, L.; Puester, N.H. A Gasket, a Bipolar Battery and a Method for Manufacturing a Gasket. Eur. Pat. Appl. 08712719, 18 February 2008. [Google Scholar]
  92. Howlett, R. An Energy Management System. Eur. Pat. Appl. 12738289, 28 June 2012. [Google Scholar]
  93. Noréus, D. A Metal Hydride Battery with Added Hydrogen Gas, Oxygen Gas or Hydrogen Peroxide. International Application No. PCT/SE2016/051020, 27 April 2017. [Google Scholar]
  94. Nilar. Available online: http://www.nilar.com (accessed on 25 May 2017).
  95. Schaffrath, U.; Ohms, D.; Benczur-Uermoessy, G.; Markolf, R.; Schmelter, K. Method for Producing a Positive Nickel-Hydroxide Electrode for a Nickel-Metal Hydrid or Nickel-Cadmium Battery. Eur. Pat. Appl. 11007464, 14 September 2011. [Google Scholar]
  96. Ohms, D.; Schaedlich, G.R.N.; Kleinschnittger, B.D.-I.; Markolf, R.; Schmelter, K. Nickel-Metal Hydrid Battery. Eur. Pat. Appl. 11007465, 14 September 2011. [Google Scholar]
  97. Hoppecke Power from Innovation. Available online: https://www.hoppecke.com/ (accessed on 25 May 2017).
  98. Master Alloys. Available online: http://www.gfe.com/fileadmin/user_upload/pdfs/Produktspezifikationen_Alloys/HYDRALLOY_C_2004732_2005169_2019929_V4.pdf (accessed on 25 May 2017).
  99. Klassen, T.; Bormann, R.; Oelerich, W.; Guether, V.; Otto, A. Metalliferous Storage Material for Hydrogen and Method for Producing Same. Eur. Pat. Appl. 99955727, 17 September 1999. [Google Scholar]
  100. Non-Ferrous Metal Alloys. Available online: https://www.treibacher.com/en/products/non-ferrous-metal-alloys.html (accessed on 25 May 2017).
  101. Knosp, B.; Arnaud, O.; Hezeque, T.; Barbic, P.; Bouvier, A. Hydridable Alloy. Eur. Pat. Appl. 01402059, 30 July 2001. [Google Scholar]
  102. Hebenstreit, G.; Barbic, P. Metal Hydride Reservoir. International Application No. PCT/AT2006/000241, 28 December 2006. [Google Scholar]
  103. Dubrow, R.S.; Froix, M.F. Method of Making a Microporous Article. Eur. Pat. Appl. 85902861, 20 May 1985. [Google Scholar]
  104. Park, G.B.; Cook, J.A. Microporous Films. Eur. Pat. Appl. 90112666, 18 December 1985. [Google Scholar]
  105. Dorling, M.G.L.; Barker, D.J.; Mcloughlin, R.H. Microporous Films. Eur. Pat. Appl. 89906800, 13 June 1989. [Google Scholar]
  106. Singleton, R.W.; Cook, J.A.; Gargan, K. Polymer Membrane. Eur. Pat. Appl. 91916836, 19 September 1991. [Google Scholar]
  107. Gargan, K.; Singleton, R.W.; Cook, J.A. Polymeric Sheet. Eur. Pat. Appl. 92914965, 9 July 1992. [Google Scholar]
  108. Mcloughlin, R.H.; Gentilcore, G.; Cook, J.A. Non-Woven Fabric Treatment. Eur. Pat. Appl. 98925861, 8 June 1998. [Google Scholar]
  109. Gentilcore, G.; Lancaster, I.M. Non-Woven Fabric Laminate. Eur. Pat. Appl. 98925860, 8 June 1998. [Google Scholar]
  110. Hoffmann, H.; Schwoebel, R. Nonwoven Hydrophilic Material for Electrochemical Battery Separator and Method of Manufacturing. Eur. Pat. Appl. 93109577, 16 June 1993. [Google Scholar]
  111. Wenneis, W.; Hoffmann, H.; Severich, B.; Keul, H.R.N. Alkaline Cell or Battery. Eur. Pat. Appl. 02009348, 3 May 2002. [Google Scholar]
  112. Kritzer, P.; Trautmann, C. Hydrophylized Separator Material. Eur. Pat. Appl. 02023842, 24 October 2002. [Google Scholar]
  113. Kritzer, P.; Schwoebel, R.-P. Method for the Production of a Separator Material for Alkaline Batteries. Eur. Pat. Appl. 03003011, 12 February 2003. [Google Scholar]
  114. Kritzer, P.; Feistner, H.-J.; Schilling, H.; Kalbe, M. Nonwoven Fabric, Fiber and Electrochemical Cell. Eur. Pat. Appl. 05023520, 27 October 2005. [Google Scholar]
  115. Kritzer, P. Separator for Housing in Batteries and Battery. Eur. Pat. Appl. 07006211, 27 March 2007. [Google Scholar]
  116. Kritzer, P.; Schilling, H. Layer with Insulated Fibres and Electrochemical Cell. Eur. Pat. Appl. 07020102, 15 October 2007. [Google Scholar]
  117. Roth, M.; Weber, C.; Berg, M.; Geiger, S.; Hirn, K.; Waschinski, C.; Falusi, S.; Kasai, M. Separator with Increased Puncture Resistance. Eur. Pat. Appl. 10749599, 11 August 2010. [Google Scholar]
  118. Audebert, J.-F.; Feistner, H.-J.; Frey, G.; Farer, R.; Thrasher, G.L.; Weiss, M. Nonwoven Separator for Electrochemical Cell. Eur. Pat. Appl. 02789528, 8 November 2002. [Google Scholar]
  119. Benczur-Uermoessy, G. Gastight Prismatic Nickel-Metal Hydride cell. Eur. Pat. Appl. 00942051, 10 June 2000. [Google Scholar]
  120. Benczur-Uermoessy, G.; Ohms, D.; Waidelich, D. Electrode Capable of Storing Hydrogen and a Method for the Production of the Same. Eur. Pat. Appl. 00942050, 10 June 2000. [Google Scholar]
  121. Benczur-Uermoessy, G.; Gensierich, M.; Ohms, D.; Wiesener, K. Battery in Bipolar Stacked Configuration and Method for the Production Thereof. Eur. Pat. Appl. 00927157, 6 May 2000. [Google Scholar]
  122. Bartlett, P.N.; Owen, J.R.; Nelson, P.A. Electrochemical Cell. Eur. Pat. Appl. 03767996, 12 December 2003. [Google Scholar]
  123. Bartlett, P.N.; Owen, J.R.; Nelson, P.A. Electrochemical Cell. International Application No. PCT/GB2003/005441, 28 October 2004. [Google Scholar]
  124. Bartlett, P.N.; Owen, J.R.; Nelson, P.A. Electrochemical Cell Suitable for Use in Electronic Device. International Application No. PCT/GB2003/005442, 24 July 2004. [Google Scholar]
  125. Bruchmann, B.; Klok, H.; Scholl, M.T. Preparation and Use of Modified Polylysines. Eur. Pat. Appl. 10152919, 15 November 2006. [Google Scholar]
  126. Arvidsson, J.; Carlström, R.; Hallen, H.; Löfgren, S. Powder Composition and Process for the Preparation Thereof. Eur. Pat. Appl. 98928768, 5 June 1998. [Google Scholar]
  127. Popall, M.; Olsowski, B.; Cochet, S. Particles Coated with an Organically Modified (Hetero) Silicic Acid Polycondensate and Containing a Metal Core Suited for Storing Hydrogen, Batteries Produced Therewith and Method for the Production Thereof Using the Particles. Eur. Pat. Appl. 10726978, 29 June 2010. [Google Scholar]
  128. Maugy, C.; Porcellato, D.; Tarascon, J.-M.; Sainton, P. Method and System for Charging a Battery Wherein the Internal Pressure Varies Depending on State of Charge and Temperature. Eur. Pat. Appl. 04292653, 9 November 2004. [Google Scholar]
  129. Bothe, M.; Schröder, G.B.R.; Breuch, G. Battery Charger with State of Charge Determination on the Primary Side. Eur. Pat. Appl. 05012135, 6 June 2005. [Google Scholar]
  130. Nicolai, J. Quick Charge Method for Battery and Integrated Circuit for Performing the Method. Eur. Pat. Appl. 94400575, 16 March 1994. [Google Scholar]
  131. Yuen, T.K. Battery Charger. Eur. Pat. Appl. 94300655, 28 January 1994. [Google Scholar]
  132. Lang, O. Method for Regulating Charging of Nickel Cadmium and Nickel Metal Hydride Batteries, and Power Supply Unit. Eur. Pat. Appl. 06762920, 26 July 2006. [Google Scholar]
  133. Umicore. Battery Recycling in the EU. Presented in the NaatBatt Battery Recycling Workshop, Ann Arbor, MI, USA. 30 November 2016. Available online: http://naatbatt.org/wp-content/uploads/2016/12/What%E2%80%99s-the-Rest-of-the-World-Doing_Caffarey_A.pdf (accessed on 24 July 2017).
  134. About the Colabats Project. Available online: http://www.colabats.eu/about-the-colabats-project (accessed on 27 July 2017).
  135. Cheret, D.; Santén, S. Battery Recycling. Eur. Pat. Appl. 05075736, 30 March 2005. [Google Scholar]
  136. Luidold, S.; Antrekowitsch, H. Recovery of Rare Earth Metals from Waste Material by Leaching in Non-Oxidizing Acid and by Precipitation Using Sulphates. Eur. Pat. Appl. 10188264, 20 October 2010. [Google Scholar]
  137. Pudas, J.; Erkkila, A.; Viljamaa, J. Battery Recycling Method. Eur. Pat. Appl. 11708474, 16 March 2011. [Google Scholar]
  138. Hanulik, J. Battery Recycling Process, in Particular for Dry Batteries. Eur. Pat. Appl. 95920722, 16 June 1995. [Google Scholar]
  139. Wiaux, J.; Lazouni, A.; Indaco, A. Used Battery and Cell Sorting Method and Apparatus. Eur. Pat. Appl. 94906358, 24 February 1994. [Google Scholar]
  140. Alavi, K.; Salami, B. Method of Treating Nickel-Cadmium of Nickel-Hydride Cells. Eur. Pat. Appl. 93113054, 14 August 1993. [Google Scholar]
  141. Traverse, J.-P.; Bressolles, J.-C.; Archier, P. Method for Processing Scrap Containing One or More Alloys that React to Form Hydrides, to Enable Recycling Thereof. Eur. Pat. Appl. 96926454, 24 July 1996. [Google Scholar]
  142. Toro, L.; Veglio, F.; Beolchini, F.; Pagnanelli, F.; Furlani, G.; Granata, G.; Moscardini, E. Plant and Process for the Treatment of Exhausted Accumulators and Batteries. Eur. Pat. Appl. 11185532, 18 October 2011. [Google Scholar]
  143. Laucournet, R.; Billy, E. Method for Recovering Metals Contained in an Ni-MH Battery. International Application No. PCT/IB2014/066008, 21 May 2015. [Google Scholar]
  144. Black, V. Soap Dispenser Conversion Kit. Eur. Pat. Appl. 15156912, 27 February 2015. [Google Scholar]
  145. Young, K. Metal Hydride. In Reference Module in Chemistry, Molecular Science and Chemical Engineering; Reedijk, J., Ed.; Elsevier: Waltham, MA, USA, 2013. [Google Scholar] [CrossRef]
Batteries 03 00025 g001 550
Figure 1. Consumer Ni/MH battery market shares for (a) Sources in 2013, (b) Exports from China in 2013, and (c) Exports from Japan in February 2014. Data originate from [2].
Figure 1. Consumer Ni/MH battery market shares for (a) Sources in 2013, (b) Exports from China in 2013, and (c) Exports from Japan in February 2014. Data originate from [2].
Batteries 03 00025 g001
Batteries 03 00025 g002 550
Figure 2. Schematics of three difference designs of current collectors by SAFT. The parts are 1: metal plate, 2: plug, 3: indent, 4: electrode [37]; 5: expanded metal or perorated metal strip [38]; 6: threaded holes, 7: terminal assembly, 8: conducting strip, and 9: shoulder [40].
Figure 2. Schematics of three difference designs of current collectors by SAFT. The parts are 1: metal plate, 2: plug, 3: indent, 4: electrode [37]; 5: expanded metal or perorated metal strip [38]; 6: threaded holes, 7: terminal assembly, 8: conducting strip, and 9: shoulder [40].
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Figure 3. Cylindrical cells from Arts Energy [53].
Figure 3. Cylindrical cells from Arts Energy [53].
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Figure 4. Schematics of (a) A multi-segment cylindrical cell, (b) A button cell, and (c) A hollow-cathode cylindrical cell from Varta. The parts are 1: terminal, 2: conducting pin, 3: positive electrode, 4: negative electrode, 5: separator, 6: central hole [57]; 7: pressure spring, 8: current collector plate, 9: cover, 10: gasket, 11: negative electrode, 12: electrolyte-saturated separator, 13: positive electrode, 14: case [58]; 15: head, 16: disc shape lid with radial profile, 17: rim (bent radially inward), 18: seal, 19: separator, 20: cylindrical wall, 21: shank, 22:thread, 23: negative electrode, 24: can, 25: flat circular bottom, 26: one positive electrode, 27: positive electrode assembly, 28: another segment of positive electrode, 29: cavity, 30: screw shape current collector [64].
Figure 4. Schematics of (a) A multi-segment cylindrical cell, (b) A button cell, and (c) A hollow-cathode cylindrical cell from Varta. The parts are 1: terminal, 2: conducting pin, 3: positive electrode, 4: negative electrode, 5: separator, 6: central hole [57]; 7: pressure spring, 8: current collector plate, 9: cover, 10: gasket, 11: negative electrode, 12: electrolyte-saturated separator, 13: positive electrode, 14: case [58]; 15: head, 16: disc shape lid with radial profile, 17: rim (bent radially inward), 18: seal, 19: separator, 20: cylindrical wall, 21: shank, 22:thread, 23: negative electrode, 24: can, 25: flat circular bottom, 26: one positive electrode, 27: positive electrode assembly, 28: another segment of positive electrode, 29: cavity, 30: screw shape current collector [64].
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Batteries 03 00025 g005 550
Figure 5. Button cells from Varta Microbattery [70].
Figure 5. Button cells from Varta Microbattery [70].
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Figure 6. Alcatel One Touch 535 with Ni/MH battery [79].
Figure 6. Alcatel One Touch 535 with Ni/MH battery [79].
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Figure 7. Schematics of (a) A metal-foam connection and (b) A cylindrical cell design from Alcatel. The parts are 1: metal strip, 2: foam without Ni(OH)2, 3: auxiliary foam, 4: main foam, 5: slot formed by compression [71]; 6: folded part of can, 7: metal tab, 8: negative electrode, 9: separator, 10: positive electrode, 11: can, 12: a piece of nickel plated steel disc, 13: adhesive tape, 14: lug, and 15: cover [72].
Figure 7. Schematics of (a) A metal-foam connection and (b) A cylindrical cell design from Alcatel. The parts are 1: metal strip, 2: foam without Ni(OH)2, 3: auxiliary foam, 4: main foam, 5: slot formed by compression [71]; 6: folded part of can, 7: metal tab, 8: negative electrode, 9: separator, 10: positive electrode, 11: can, 12: a piece of nickel plated steel disc, 13: adhesive tape, 14: lug, and 15: cover [72].
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Figure 8. (a) Nilar’s bipolar prismatic Ni/MH batteries and (b) A ferry powered by them [94].
Figure 8. (a) Nilar’s bipolar prismatic Ni/MH batteries and (b) A ferry powered by them [94].
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Figure 9. Prismatic flooded Ni/MH batteries from Hoppecke [97].
Figure 9. Prismatic flooded Ni/MH batteries from Hoppecke [97].
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Batteries 03 00025 g010 550
Figure 10. Schematic of a cylindrical cell design from Eveready/Freudenberg. The parts are 1: negative current collector, 2: negative terminal, 3: metal plate, 4: polymer seal, 5: metalized plastic film, 6: steel can, 7: tubular positive electrode, 8: separator, 9: negative electrode, 10: bottom of negative electrode, 11: bottom of folding cylinder, 12: positive terminal, and 13: folding can [118].
Figure 10. Schematic of a cylindrical cell design from Eveready/Freudenberg. The parts are 1: negative current collector, 2: negative terminal, 3: metal plate, 4: polymer seal, 5: metalized plastic film, 6: steel can, 7: tubular positive electrode, 8: separator, 9: negative electrode, 10: bottom of negative electrode, 11: bottom of folding cylinder, 12: positive terminal, and 13: folding can [118].
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Table
Table 1. European companies related to Ni/MH battery manufacturing included in this review, in order of their presence.
Table 1. European companies related to Ni/MH battery manufacturing included in this review, in order of their presence.
Company NameHeadquarterProducts Related to Ni/MHTrademarkWebsite
SaftBagnolet, FranceC, D, F-size cells Batteries 03 00025 i001http://saftbatteries.com/
Arts EnergyNersac, FranceC, D, F-size cells Batteries 03 00025 i002http://www.arts-energy.com
VartaEllwangen, GermanyAAA to FA, button cell Batteries 03 00025 i003http://www.varta-microbattery.be/
NilarTäby, SwedenPrismatic, bipolar cell Batteries 03 00025 i004http://www.nilar.com/
AlcatelParis, FranceCell phone battery Batteries 03 00025 i005http://www5.alcatel-lucent.com
HoppeckeBrilon-Hoppecke, GermanyPrismatic cell Batteries 03 00025 i006https://www.hoppecke.com/
GfENuremberg, GermanyMH alloy powder Batteries 03 00025 i007http://www.gfe.com
TreibacherAlthofen, AustriaMH alloy powder Batteries 03 00025 i008https://www.treibacher.com
SciMatSwindon, UKSeparator Batteries 03 00025 i009Not available now
FreudenbergWeinheim, GermanySeparator Batteries 03 00025 i010http://www.freudenberg.com
Table
Table 2. Comparison of numbers of patents (applications) filed in EU, USA, Japan, and China and number of associated companies (institutes). * The number of companies used in USA only counts for American companies (institutes).
Table 2. Comparison of numbers of patents (applications) filed in EU, USA, Japan, and China and number of associated companies (institutes). * The number of companies used in USA only counts for American companies (institutes).
CountryEUUSAJapanChina
Number of patents (application) related to Ni/MH126371275692
Number of patents in negative electrode2258128136
Number of patents in positive electrode18542783
Number of patents in manufacturing technology103328104
Number of companies (institutes) filed patents2918 *4699

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Chang, S.; Young, K.-H.; Lien, Y.-L. Reviews of European Patents on Nickel/Metal Hydride Batteries. Batteries 2017, 3, 25. https://doi.org/10.3390/batteries3030025

AMA Style

Chang S, Young K-H, Lien Y-L. Reviews of European Patents on Nickel/Metal Hydride Batteries. Batteries. 2017; 3(3):25. https://doi.org/10.3390/batteries3030025

Chicago/Turabian Style

Chang, Shiuan, Kwo-Hsiung Young, and Yu-Ling Lien. 2017. "Reviews of European Patents on Nickel/Metal Hydride Batteries" Batteries 3, no. 3: 25. https://doi.org/10.3390/batteries3030025

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