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Article

Statistical Characterization of the State-of-Health of Lithium-Ion Batteries with Weibull Distribution Function—A Consideration of Random Effect Model in Charge Capacity Decay Estimation

Engineering Product Development (EPD) Pillar, Singapore University of Technology and Design, Singapore 487372, Singapore
*
Authors to whom correspondence should be addressed.
Batteries 2017, 3(4), 32; https://doi.org/10.3390/batteries3040032
Submission received: 4 August 2017 / Revised: 19 September 2017 / Accepted: 9 October 2017 / Published: 16 October 2017
(This article belongs to the Special Issue Battery Management Systems)

Abstract

:
Effective prognosis of lithium-ion batteries involves the inclusion of the influences of uncertainties that can be incorporated through random effect parameters in a nonlinear mixed effect degradation model framework. This study is geared towards the estimation of the reliability of lithium-ion batteries, using parametric effects determination involving uncertainty, using a multiphase decay patterned sigmoidal model, experimental data and the Weibull distribution function. The random effect model, which uses Maximum Likelihood Estimation (MLE) and Stochastic Approximation Expectation Maximization (SAEM) algorithm to predict the parametric values, was found to estimate the remaining useful life (RUL) to an accuracy of more than 98%. The State-of-Health (SOH) of the batteries was estimated using the Weibull distribution function, which is found to be an appropriate formulation to use.

1. Introduction

Monitoring the State-of-Health (SOH) of lithium-ion batteries by means of remaining useful life (RUL) estimation and the measurement of other health indicators, such as the State-of-Charge (SOC), are vital for intelligent battery management systems [1]. This practice is especially important for monitoring systems on critical missions where the lithium-ion battery serves as the main power source, because the right information on the wear-out state and lifecycle of the battery will, in turn, ensure a higher probability of a successful mission. To this end, many researchers [1,2,3,4,5,6,7,8,9] have worked on the charge capacity decay modeling of lithium-ion batteries, in a bid to predict the degradation over time and to predict the SOH at different lifecycle phases [10]. Since total asset integrity management protocol entails the understanding of the performance and reliability of its components, sub-systems and systems, it is imperative that the trend of lithium-ion battery degradation is well understood, to forestall unplanned failures of facilities such as that of the plagued spacecrafts, which suffered fatal failures in the recent past due to power system failures [11].
Coincidentally, the practice of lithium-ion battery prognosis, which depends on the charge capacity degradation estimation over the period of use of the battery, has not yet resulted in an effective and standardized lifetime estimation procedure, predominantly due to the negligence of uncertainties that affect the charge capacity of these batteries. These uncertainties can come from numerous sources that include the manufacturing and assembly of the lithium-ion battery components, measurement errors associated with the reading of charge and discharge related values, operational environmental conditions of the battery, errors inherent in charge capacity decay modeling equations and uncertainties inherent in the electrochemical reactions in the battery system [5,12,13]. When considering the cumulative effects of these uncertainties that result in poor model development, since parametric values may not be precisely estimated, it is imperative that the influences of these uncertainties associated with the battery charge capacity be considered a priori in the model development stage. Inclusion of uncertainties as constituent terms in the degradation models will certainly account for the imbalances they create, thereby enhancing the predictability of the models. Moreover, since it is difficult to certify that the components in every lithium-ion battery are defect free, it is a safer option to construct charge capacity decay estimation models with uncertainties embedded in the framework. Another factor to consider is that of time-dependent uncertainties in the components of lithium-ion batteries that may originate and propagate during the operational life of the battery due to the unwarranted responses and the transient nature of the operating and environmental conditions. To this end, the best approach to predictive estimation of the RUL and SOH of lithium-ion batteries involves the consideration of uncertainties, through the random effect model framework [14,15]. Imperatively, the random effect model has the potential of incorporating uncertainties in prediction models, an attribute that many models used in literature for the estimation of battery retention life have not got. Random effect model also considers individual time changes amongst the covariates, while implementing a continuous time architecture, making it easier to estimate future behavioral patterns from the model. Due to the flexibility of the technique, variables that have repetitive values are easily captured in predictions and generic formulation of trends for non-normally distributed datasets are effortlessly achieved, because the covariances used for measurements are adaptable.
To date, researchers have used several techniques to predict the RUL distribution and SOH for Li-ion batteries including particle filters, improved particle filters and Kalman filters [4,13,16,17,18,19]. Several machine learning approaches involving artificial neural networks, support vector machines, relevance vector machine, and Fuzzy K-means [6,20,21,22] have also been used in the recent past. Other approaches include the use of the Wiener process for RUL prediction with the maximum likelihood estimation and Bayesian updated expectation and maximization algorithm, which potentially gave a good fit for the experimental results for Li-ion battery charge decay [23]. Ng et al. [24] used the naïve Bayes model for different operating conditions of the Li-ion battery and concluded that the capacity fade is always higher at elevated temperatures. This capacity fade was further shown to be associated with the rise of impedance at the cathodes [25]. Similarly, after analyzing the failure cycles of the lithium ion battery, Harris et al. [26] concluded that the variation in failure times of the batteries was wide among the various cells. Despite the poor failure estimation results obtained by them using the three-parameter Weibull distribution function [26], they also obtained results that showed better fits to the experimental data with a two-parameter Weibull distribution as well as the normal distribution.
Although the work of numerous researchers on lithium-ion battery prognosis, RUL and SOH estimation as summarized above [2,3,4,8,17,22,27,28] have gained sufficient ground, our aim here is to add a new dimension to the study by accounting for uncertainty, using the random effect model, to enhance the predictability of RUL for lithium-ion batteries under real-life test. It is important to note that the prognostic studies on Li-ion batteries carried out by most of the reviewed papers here, did not account for uncertainties in the charge decay patterns and their impact on the prediction accuracy. This makes it imperative that the effects of uncertainties be considered in the right way, so as to understand the influences of these random factors on the RUL estimation. Negligence of uncertainties could be a fundamental source of faulty prognosis and unreliable RUL predictions. Since the uncertainties associated with the battery charge capacity decay such as manufacturing defects, environmental conditions, experimental measurement errors and physical and chemical characteristics of defects in materials etc. [17] are difficult to measure and can alter the health of the battery and the subsequent charging and discharging patterns, the use of the nonlinear mixed effect model (NLMEM) [14,15] will help to determine the influences of these random variables on the parametric values of the charge decay prediction model. NLMEM provides a methodology for estimating the influences of the uncertainties on the model parameters, thereby making it easier to understand the behavioral trend of the battery charge capacity decay. Also, the decay patterns of different Li-ion batteries, used for nonlinear mixed effect modeling, provide holistic information for better prognosis of similar batteries, since heterogeneous charge capacity decay information from different batteries with similar characteristics will help to develop better-fit generic prediction models for the RUL. This study will incorporate the uncertainties in the parametric values by using a multiphase decay sigmoidal model, to estimate the charge capacity decay trend of the batteries and use a two-parameter Weibull distribution function for fitting the RUL distribution, which has been shown to be robust for RUL estimation [29,30,31] to determine the characteristic life of the batteries at 70% end-of life (EOL) failure threshold. Since battery charge capacity decay is expected to be a non-reversible process (synonymous to wear-out failures), the use of the two-parameter Weibull function for estimating the expected characteristic life at a given EOL threshold will give an indication of the RUL and the SOH of the battery at a given cycle.

2. Formulation of Charge Capacity Decay Model Considering Uncertainties

We analyzed the data of Li-ion battery charge capacity decay for four batteries—B0029, B0030, B0031, and B0032 that were experimentally tested under accelerated stress conditions from an initial charge capacity of 2.0 Ah at the NASA® AMES laboratory [32]. The charge capacities at the charging cycles and times were obtained for individual batteries through operations that involved charging, discharging and impedance measurements at a temperature of 43 °C. The charging was carried out via a constant current of 1.5 A to a voltage of 4.2 V, which was held constant until the battery capacity discharged to 20 mA. The discharge was carried out at a current of 4 A until the batteries B0029, B0030, B0031, and B0032 got to a voltage of 2.0 V, 2.2 V, 2.5 V, and 2.7 V respectively. The charge capacity decay trend of the lithium-ion batteries versus cycles of charge/discharge as obtained from the experiment are plotted in Figure 1.
The model for battery charge decay has been shown to follow a sigmoidal curve pattern [2,4,5] and can be ascribed to a multiphase decay pattern as per Equation (1).
Q ( t ) = P 1 exp ( r 1 t ) + P 2 exp ( r 2 t )
where Q(t) represents the charge capacity at time t, P1 and P2 represent the battery charge capacity baseline values that depend on the internal impedance of the battery, whereas r1 and r2 are charge capacity decay constants, which are related to the battery cell rechargeability and the electrolyte status of the battery. Incorporating the uncertainties in the modeling will result in the implementation of a nonlinear mixed effect model; hence, Equation (1) will be modeled with consideration of the fixed and random effects, to cater for the inherent uncertainties in the battery charge capacity decay.
To ensure a better fit to the dataset, stabilize the variance and ensure normally distributed variables, Equation (1) was reparametrized according to Equation (2).
Q ( t ) = P 1 exp ( λ 1 t ) + P 2 exp ( λ 2 t ) λ 1 = log ( r 1 )   λ 2 = log ( r 2 )  
By using the general form of the NLMEM that has response yij as the charge capacity decay and the covariate xij as the time of observation of capacity decay, the charge capacity at any time of observation with known and unknown parameters can be represented by Equation (3).
y i j = f ( x i j , ε i j ) + ε i j ,   1 i n , 1 j m i  
where εij is the error, which is assumed to be independent and identically distributed (iid) Gaussian random number with zero mean and unknown variance σ2N (0, σ2), n represents the number of covariates, mi is the number of observations of ith covariates, whereas f is a nonlinear function of the fixed and random effects, and εij represents a vector that combines the fixed and random effects according to Equation (4).
ε i j = A i j α + β i j b i   ;   b i = N ( 0 ,   σ 2 D )
Here, Aij denotes a matrix for combining the fixed effects, while βij is the matrix for combining the random effects, bi represents the random effect vector of the parameters and σ2D is a covariance matrix.
To determine the response vector, yi, for the ith individual, using the individual fixed and random effect εi, the relationship in Equation (5) was used [33].
y i = [ y i 1 y i 2 y i m i ] ;         ε i = [ ε i 1 ε i 2 ε i m i ] ;             η i ( ε i ) = [ f ( ε i , x i 1 ) f ( ε i , x i 1 ) f ( ε i , x i m i ) ] ;
Equation (5) can be further simplified to Equation (6).
y i = η i ( ε i ) + ε i   ;     ε i ~ N ( 0 , σ 2 Λ i )
where ηi is a function of the known and unknown variables and Λi is an identity matrix.
For n individual models, the response vector, y, the vector, ε, and the nonlinear function of the ε vector, η, can be expressed by Equation (7).
y = [ y 1 y 2 y n ] ;       ε = [ ε 1 ε 2 ε n ] ;         η ( ε ) = [ η 1 ( ε 1 ) η 1 ( ε 1 ) η n ( ε n ) ] ;  
If Ď = diag(D1, D2, , Dn) and Λ = diag(Λ1, Λ2, …, Λn), then the response variable y can be expressed by Equation (8).
y | ( α , b ) ~ N ( η ( σ 2 Λ ) ,   ε = A α + β b ,   b ~ ( 0 , σ 2 Ď ) )  
where B = diag(B1, B2, …, Bn), b = diag(b1, b2, …, bn)T and A = diag(A1, A2, …, An)T.

Estimation of Future Battery Charge Capacity

Estimation of the future battery charge capacity is a vital aspect of prognostics as this information will be essential to provide details of the RUL of the battery at a given time, for a predetermined failure threshold such as 70% of maximum retainable charge capacity. To determine the future charge capacity, the parametric values of the random effect model, which incorporates uncertainties was needed. The following steps were adopted for the prediction and computation of these parametric values:
  • Determine the maximum likelihood function value, L, of the battery charge capacity over time using the experimental data and apply Equation (9) that has P ( Q i j , ε i j ) , representing the probability density function of the nonlinear battery charge decay [34].
    L ( ε i j , Q i j ) = i = 1 n j = 1 m i P ( Q i j , ε i j )   = i = 1 n j = 1 m i P ( Q i j , b i , ε i j )   d b  
  • Estimate the maximum likelihood of the parameters in ε that will maximize L by following Equation (10) [35,36].
    log ( L ) b = 0
  • Apply stochastic approximation, expectation, and maximization technique that uses Markov Chain Monte Carlo (MCMC) simulation and Metropolis-Hasting algorithm to estimate the known and unknown parameters of the model, ε.
    • Simulation step: For kth iterative evaluation, determine the variable sk+1 such that the condition in Equation (11) is satisfied [37].
      s k + 1 = E [ log P ( Q , b , ε ) | Q , ε k ]
    • Stochastic approximation step: Update the value of sk+1 as per Equation (12).
      s k + 1 = s k + γ k [ log P ( Q , b ( k ) ; ε ) s k ]      
      where γ k   represents decreasing positive numbers that satisfy the conditions in Equation (13).
      { γ k = [ 0 , 1 ] k = 1 γ k = k = 1 γ k 2 <  
    • Maximization step: Update εk so as to maximize its value based on the relationship in Equation (14).
      ε k + 1 = argmax ε ( L ( s k + 1 , ε ) )
  • Determine the charge capacity of the batteries using the estimated parameters such that the charge capacity prediction (Qpred) is a function of the fixed effect parameters defined—P1, λ1, P2, λ2, and the random effects ψ11, ψ22, ψ33, and ψ44, which are the random effects on P1, λ1, P2, and λ2, respectively.
  • Estimate the residual (Res) of the random effect model estimated charge capacity from the measured charge capacity.
  • Predict the charge capacity of the lithium-ion batteries by incorporating the noise to Qpred to obtain the random effect modelled charge capacity decay (Qrnd), as per Equation (15).
    Q r n d = Q p r e d + n o r m r n d [ 0 ,   s t d ( R e s ) ]
  • Estimate the distribution of times of the battery discharge for a 70% End-of-Life (EOL) failure threshold, which is the time instant at which the battery retains 70% of the original charge capacity.

3. Results and Discussion

3.1. Battery Prognosis using Stochastic EM Algorithm

The summary of the parametric values of the lithium-ion batteries obtained with the stochastic approximation, expectation, and maximization (SAEM) technique is shown in Table 1.
The parametric values of the batteries in Table 1 were used for estimating the battery charge capacities over the time interval of the experiment, which is shown in Figure 2 with 95% and 99% confidence intervals and the measurement results.

3.2. Validation of Estimation Modeling Technique

To validate the random effect model, the Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), and Coefficient of Efficiency (COE), as shown in Equation (16) were used:
{ M A E = 1 m i = 1 m | Q e x p i Q r n d i |   M A P E = 1 m i = 1 m | Q e x p i Q r n d i Q e x p i | 100 C O E = 1 i = 1 m ( Q e x p i Q r n d i ) 2 i = 1 m ( Q e x p i Q m e a n ) 2  
where Qexp is the experimental result, Qrnd is the random effect model prediction results, m is the number of samples, and Qmean is the mean of the experimental result. The results of the MAE, MAPE, and COE are shown in Table 2 and Table 3.
The results in Table 2 showed that the percentage variation between the random effect model predicted battery charge capacity trend and the charge capacity determined experimentally is 0.71% and 1.45% at 95% confidence interval and between 0.70% and 1.69% for 99% confidence interval. Imperatively, the random effect model estimated charge capacity had predicted the experimental results to an error of <2%. The high values of the coefficient of efficiency (0.8731–0.9394) in Table 3 also confirmed the effectiveness of the random effect model used in this research to determine the lithium-ion battery charge decay. The error level obtained in this study is comparable to that obtained for the same battery using combinational Gaussian process functional regression [8], Gaussian Hermite particle filter [2], and improved particle and Kalman filters with particle swarm optimization [4].

3.3. Weibull Distribution Function Estimation of the Battery State-of-Health (SOH)

To estimate the battery State-of-Health (SOH) at the failure threshold, which corresponds to 70% End-of-Life (EOL), the random effect model was used to estimate the charge capacities, and times to reach the EOL at 1.4 Ah (Figure 3).
The charging cycles corresponding to the charge capacities of the battery from the initial charge cycle to the EOL charge cycle at 70% EOL failure threshold were used for computation of the cycles (equivalent time) to failure and the state-of-health of the batteries, based on the probability density function (w(t)) and cumulative density function (W(t)) of Weibull distribution, as per Equation (17). Note here that t refers to the time equivalent of the number of “remaining” cycles to failure of the battery unit.
{ w ( t ) = ( ρ μ ) ( t μ ) ρ 1 e x p ( ( t μ ) ρ )   ρ , μ > 0   W ( t ) = 1 e x p ( ( t μ ) ρ )   ρ , μ > 0 0   o t h e r w i s e
The values of ρ and μ, which represent the shape parameter and characteristic life (scale parameter) can be obtained by using double logarithmic transformation of the cumulative density function as per Equation (18). Since Equation (18) is a linear function, using median ranking, mean ranking, or symmetrical cumulative density function, we may extract the parametric values of the Weibull distribution, which is a very standard textbook exercise [36].
log [ log [ 1 W ( t ) ] ] = ρ log ( t ) ρ log ( μ )
The goodness of fit of the Weibull distribution was estimated using the coefficient of determination (R2), which was obtained for all the four battery data sets. The value of R2 ranged from 0.9846–0.9852 indicated a good correlation between the random effect model data (battery charging times to 70% EOL—Figure 3) and the Weibull distribution function fitting. Figure 4 plots the “cycles to failure” data of one of the batteries investigated (B0029). The other Weibull plots were omitted here for redundancy sake.
The parametric values of the Weibull distribution function were used for the SOH estimation, according to Equation (19), which is basically the reliability function for the Weibull distribution.
S O H = e x p ( ( t μ ) ρ )
The SOH of the batteries at 70% EOL threshold, as shown in Figure 5 for the four batteries, indicates the characteristic life of the batteries i.e., the time that they will take to lose 63.2% of the lifecycle for EOL failure threshold of 70%. The fact that the shape parameters of the batteries are all larger than unity (ρ > 1) is an indication of a charge decay related failure that generally increases in occurrence probability with time of usage of the battery, which is a “wear-out” condition that is common for Li-ion batteries, as also shown by other researchers [38,39]. The information in this figure is a vital tool for estimating the remaining useful life of the battery at any given time during its lifecycle for effective prior planning and decision making on the utilization of assets powered by these charging units.
The probability density function plots (Figure 6) show that the variance of the batteries with shorter lifecycle durations is smaller than those with longer lifecycle durations. It can also be deduced from the figure that the rate of charge capacity decay is expected to be higher as the age of the battery increases [11,39], due to problems associated with lithium corrosion, surface area degradation of the electrodes and local lithium plating that results in a faded power output [38]. This could be a plausible physical explanation to the observed variances where wider tails are evident at higher exposure times.

4. Conclusions of the Study

Understanding the influence of uncertainties in lithium-ion battery charge decay is vital for prognosis and remaining useful life estimation. This study used the random effect model that comprised of fixed and random effect parametric values of lithium-ion batteries, to estimate the future battery lifecycle and predict the State-of-Health (SOH) at 70% End-of-Life (EOL) failure threshold. After determining the parameters of this nonlinear mixed effect degradation model using the Maximum Likelihood Estimation (MLE) and Stochastic Approximation Expectation and Maximization (SAEM) algorithm, the predicted results were compared with NASA’s experimental results on four chosen lithium-ion batteries that were tested at 43 °C using charging, discharging, and impedance profiles.
The results of the predicted battery charge capacity were found to vary from the experimental results by less than 2% on average. The State-of-Health (SOH) of the batteries were also estimated considering the Weibull distribution function, which showed good predictive power, assuming 70% of EOL as the user defined failure threshold. The findings revealed that the battery charge capacity decay rate tends to increase with aging of the batteries due to problems that can be attributed to retarded electrode functionalities, lithium corrosion, and reduced reaction surface area, which impairs the functionalities of the electrodes and the electrolytes and impedes Li-ion diffusion through the electrolytes. Hence, there is a clear need to incorporate uncertainties in battery charge capacity decay modeling to enhance the robustness of prognostic estimates of remaining useful life in the future for mission critical applications.

Acknowledgments

This work is jointly funded by the SUTD-ZJU Collaboration Research Grant No. ZJURP1500103, Temasek Seed Grant No. IGDSS1604021 and the SUTD Start-Up Research Grant No. SREP15108.

Author Contributions

The original idea was conceived by Ossai, C.I, Nagarajan Raghavan helped to modify the ideas, and the preparation of the paper was done by both authors.

Conflicts of Interest

The authors do not have any conflict of interest.

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Figure 1. Degradation trend of charge capacity for lithium-ion batteries—B0029, B0030, B0031, and B0032 as a function of various operational cycles.
Figure 1. Degradation trend of charge capacity for lithium-ion batteries—B0029, B0030, B0031, and B0032 as a function of various operational cycles.
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Figure 2. Comparison of the measured data with the random effect model estimated lithium-ion battery charge decay for the four batteries assessed in this study at 95% and 99.5% confidence intervals—(a) B0029, (b) B0030, (c) B0031 and (d) B0032.
Figure 2. Comparison of the measured data with the random effect model estimated lithium-ion battery charge decay for the four batteries assessed in this study at 95% and 99.5% confidence intervals—(a) B0029, (b) B0030, (c) B0031 and (d) B0032.
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Figure 3. Experimental data of the lithium-ion batteries and estimated future charge capacity decay to 70% End-of-Life (EOL) failure threshold- Battery No. (a) B0029, (b) B0030, (c) B0031 and (d) B0032.
Figure 3. Experimental data of the lithium-ion batteries and estimated future charge capacity decay to 70% End-of-Life (EOL) failure threshold- Battery No. (a) B0029, (b) B0030, (c) B0031 and (d) B0032.
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Figure 4. Goodness of fit test of Weibull distribution function fit to the remaining cycles to failure data for lithium-ion battery (B0029) considering the charge capacity decay threshold of 70% EOL. F(t) is a function that represents the median ranking of the age of the battery at various charge capacities.
Figure 4. Goodness of fit test of Weibull distribution function fit to the remaining cycles to failure data for lithium-ion battery (B0029) considering the charge capacity decay threshold of 70% EOL. F(t) is a function that represents the median ranking of the age of the battery at various charge capacities.
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Figure 5. State-of-Health of the four lithium-ion batteries at 70% EOL failure threshold where µ represents the characteristic life and ρ represents the shape factor of the batteries.
Figure 5. State-of-Health of the four lithium-ion batteries at 70% EOL failure threshold where µ represents the characteristic life and ρ represents the shape factor of the batteries.
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Figure 6. Probability density function plot for the four lithium-ion battery data sets with a failure threshold of 70% of maximum charge capacity.
Figure 6. Probability density function plot for the four lithium-ion battery data sets with a failure threshold of 70% of maximum charge capacity.
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Table 1. Summary of the parametric values of the Lithium-ion battery charge decay model using the stochastic approximation expectation and maximization algorithm.
Table 1. Summary of the parametric values of the Lithium-ion battery charge decay model using the stochastic approximation expectation and maximization algorithm.
ParametersB0029B0030B0031B0032
P11.84451.77291.82321.8812
λ1−6.6079−6.6265−7.0221−6.5622
P2−2.4236−2.4666−2.4418−2.4521
λ20.35420.44020.33300.2969
Table 2. Mean Absolute Error (MAE) and Mean Absolute Percentage Error (MAPE) of the Lithium-ion batteries obtained at 95% and 99% confidence intervals.
Table 2. Mean Absolute Error (MAE) and Mean Absolute Percentage Error (MAPE) of the Lithium-ion batteries obtained at 95% and 99% confidence intervals.
Error Measure TechniqueMean Absolute Error (MAE)Mean Absolute Percentage Error (MAPE)
Lithium ion batteryMean valueLower valueUpper valueMean valueLower valueUpper value
95% Confidence Interval
B00290.01380.02460.0204 0.80351.42421.1832
B00300.01680.02000.02371.01161.19331.4323
B00310.01240.01680.01730.70960.95930.9915
B00320.01660.0248 0.02540.94401.41051.4524
99% confidence interval
B00290.01210.02530.02710.70441.46011.5751
B00300.01480.02530.02760.88931.52111.6652
B00310.01240.01910.02020.70941.08741.1638
B00320.01600.02980.02880.90661.69091.6473
Table 3. Coefficient of Efficiency (COE) for the lithium-ion battery estimation at 95% and 99% confidence intervals.
Table 3. Coefficient of Efficiency (COE) for the lithium-ion battery estimation at 95% and 99% confidence intervals.
BatteryB0029B0030B0031B0032
95%0.91960.89000.87310.8948
99%0.93940.90440.88480.9069

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Ossai, C.I.; Raghavan, N. Statistical Characterization of the State-of-Health of Lithium-Ion Batteries with Weibull Distribution Function—A Consideration of Random Effect Model in Charge Capacity Decay Estimation. Batteries 2017, 3, 32. https://doi.org/10.3390/batteries3040032

AMA Style

Ossai CI, Raghavan N. Statistical Characterization of the State-of-Health of Lithium-Ion Batteries with Weibull Distribution Function—A Consideration of Random Effect Model in Charge Capacity Decay Estimation. Batteries. 2017; 3(4):32. https://doi.org/10.3390/batteries3040032

Chicago/Turabian Style

Ossai, Chinedu I., and Nagarajan Raghavan. 2017. "Statistical Characterization of the State-of-Health of Lithium-Ion Batteries with Weibull Distribution Function—A Consideration of Random Effect Model in Charge Capacity Decay Estimation" Batteries 3, no. 4: 32. https://doi.org/10.3390/batteries3040032

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