Growth, and Structural Characterization of Self-Nucleated Nanowires

A special issue of Crystals (ISSN 2073-4352).

Deadline for manuscript submissions: closed (22 July 2018) | Viewed by 21633

Special Issue Editor


E-Mail Website
Guest Editor
Université Grenoble Alpes, Grenoble, France
Interests: nitride materials; molecular beam epitaxy; quantum dots; nanowires; light emitting diodes; nanowire physical characterization

Special Issue Information

Dear Colleagues,

Because of their unique structural and optical properties, semiconductor nanowires (II-VI materials, III-V arsenides, phosphides, antimonides and nitrides) have been a subject of sustained interest for a couple of decades. This is particularly true for III-nitride nanowires (NWs). With respect to bulk and layer material, the absence/drastic reduction of extended structural defects makes them particularly promising for a new generation of light emitting diodes (LEDs) or laser diodes (LDs) emitting in a wavelength range spanning from infrared to ultraviolet.

Commonly, NWs also exhibit specific electrical properties related to their morphology: Higher dopant solubility limit than in layers, assigned to an easy elastic strain relaxation in nanowires have been reported. Fermi level pinning effects related to surface proximity as well as depletion thicknesses extending to their whole volume in the case of thin enough nanowires have also been reported and are governing to a large extent the electrical transport properties of nanowires. Combined to their growth versatility on virtually any kind of substrates (Si, semiconductors, amorphous material, metal, graphene, etc.) these unique morphological, crystallographic, optical and electrical properties make nanowires fascinating for both basic  and device-oriented research.

In the well known catalyst-assisted case the growth of nanowires is triggered by the previous deposition of catalyst droplets on the substrate, acting as a reservoir of constituing species and promoting nanowire growth according to the well known VLS regime.

By contrast, the growth of self-nucleated nanowires, namely nanowires grown in absence of any catalyst is still a matter of controversy, especially as far as the very first stages of their nucleation is concerned. Such NWs, free by nature of catalyst contamination, are particularly attractive for device applications covering the fields of LEDs and LDs, biological sensors, single NW transistors and many more. In the particular case of nitrides, the huge piezoelectric constants make NWs of potential interest  for strain-sensitive sensors and energy harvesting.

Detrimental to most of these applications the morphology, chemical composition, doping fluctuations inherent to spontaneously nucleated NWs can be overcome by using patterned substrates to grow arrays of identical NWs  with a degree of in-plane ordering favorable to device processing. In this case, the nucleation process itself is not affected and still is of “non-catalytic” nature while growth is selectively performed on predefined sites. A further degree of freedom is provided by the patterning characteristics such as pitch and hole diameter, which combined to mask selectivity have been shown to affect growth kinetics.

We invite contributors to submit manuscripts on the growth mechanisms of self-nucleated semiconductor NWs and NW heterostructures, on the characterization of their morphological, microscopical, optical and electrical properties and on the realization of devices.

The potential topics include, but are not limited to:

  • Growth of self-nucleated NWs including the modelling of their nucleation and of steady-state growth regime
  • Selective area growth of self-nucleated NWs, including patterning-mediated engineering of physical properties
  • Nanowire heterostructures
  • Characterization of NW physical properties (microscopic, optical, electrical, etc.)
  • Applications of self-nucleated NWs to the realization of LEDs, LDs, sensors, piezoelectric devices
  • Flexible electronics and optoelectronics applications.

Prof. Dr. Bruno Daudin
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Crystals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Semiconductor nanowires
  • Self nucleation
  • Catalyst-free nucleation
  • Self-nucleation and growth theory
  • In-plane organized nanowire growth
  • Selective area growth
  • Nanowire physical properties (structural, optical, electrical)
  • light emitting diodes
  • laser diodes
  • Nanowire devices

Published Papers (3 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

Jump to: Review

14 pages, 7740 KiB  
Article
Selective Area Growth and Structural Characterization of GaN Nanostructures on Si(111) Substrates
by Alexana Roshko, Matt Brubaker, Paul Blanchard, Todd Harvey and Kris A. Bertness
Crystals 2018, 8(9), 366; https://doi.org/10.3390/cryst8090366 - 16 Sep 2018
Cited by 20 | Viewed by 5001
Abstract
Selective area growth (SAG) of GaN nanowires and nanowalls on Si(111) substrates with AlN and GaN buffer layers grown by plasma-assisted molecular beam epitaxy was studied. For N-polar samples filling of SAG features increased with decreasing lattice mismatch between the SAG and buffer. [...] Read more.
Selective area growth (SAG) of GaN nanowires and nanowalls on Si(111) substrates with AlN and GaN buffer layers grown by plasma-assisted molecular beam epitaxy was studied. For N-polar samples filling of SAG features increased with decreasing lattice mismatch between the SAG and buffer. Defects related to Al–Si eutectic formation were observed in all samples, irrespective of lattice mismatch and buffer layer polarity. Eutectic related defects in the Si surface caused voids in N-polar samples, but not in metal-polar samples. Likewise, inversion domains were present in N-polar, but not metal-polar samples. The morphology of Ga-polar GaN SAG on nitride buffered Si(111) was similar to that of homoepitaxial GaN SAG. Full article
(This article belongs to the Special Issue Growth, and Structural Characterization of Self-Nucleated Nanowires)
Show Figures

Figure 1

7 pages, 1338 KiB  
Article
Characterization of Sub-Monolayer Contaminants at the Regrowth Interface in GaN Nanowires Grown by Selective-Area Molecular Beam Epitaxy
by Paul Blanchard, Matt Brubaker, Todd Harvey, Alexana Roshko, Norman Sanford, Joel Weber and Kris A. Bertness
Crystals 2018, 8(4), 178; https://doi.org/10.3390/cryst8040178 - 19 Apr 2018
Cited by 10 | Viewed by 3734
Abstract
While GaN nanowires (NWs) offer an attractive architecture for a variety of nanoscale optical, electronic, and mechanical devices, defects such as crystal polarity inversion domains (IDs) can limit device performance. Moreover, the formation of such defects during NW growth is not fully understood. [...] Read more.
While GaN nanowires (NWs) offer an attractive architecture for a variety of nanoscale optical, electronic, and mechanical devices, defects such as crystal polarity inversion domains (IDs) can limit device performance. Moreover, the formation of such defects during NW growth is not fully understood. In this study, we use transmission electron microscopy (TEM) and atom probe tomography (APT) to investigate the effects of sub-monolayer contamination at the regrowth interface in GaN NWs grown by selective-area molecular beam epitaxy (MBE). TEM energy dispersive X-ray spectroscopy (EDS) and APT independently identified Al and O contamination localized at the regrowth interface in two of the three growth runs examined. The Al and O concentrations were each estimated to be on the order of 11% of an ideal c-plane monolayer in the most severely contaminated case. The amount of contamination correlated with the number of crystal polarity inversion domain defects (IDs) across the growth runs. A growth run in which the pre-regrowth HF vapor etch step was replaced by HCl immersion showed the smallest quantity of O and no measurable Al. In addition, many of the NWs examined from the HCl-treated growth run turned out to be free of IDs. These results suggest that sub-monolayer contamination introduced during processing contributes to defect formation in MBE-grown GaN NWs. Full article
(This article belongs to the Special Issue Growth, and Structural Characterization of Self-Nucleated Nanowires)
Show Figures

Figure 1

Review

Jump to: Research

25 pages, 5163 KiB  
Review
Nanowires for High-Efficiency, Low-Cost Solar Photovoltaics
by Yunyan Zhang and Huiyun Liu
Crystals 2019, 9(2), 87; https://doi.org/10.3390/cryst9020087 - 08 Feb 2019
Cited by 54 | Viewed by 12300
Abstract
Solar energy is abundant, clean, and renewable, making it an ideal energy source. Solar cells are a good option to harvest this energy. However, it is difficult to balance the cost and efficiency of traditional thin-film solar cells, whereas nanowires (NW) are far [...] Read more.
Solar energy is abundant, clean, and renewable, making it an ideal energy source. Solar cells are a good option to harvest this energy. However, it is difficult to balance the cost and efficiency of traditional thin-film solar cells, whereas nanowires (NW) are far superior in making high-efficiency low-cost solar cells. Therefore, the NW solar cell has attracted great attention in recent years and is developing rapidly. Here, we review the great advantages, recent breakthroughs, novel designs, and remaining challenges of NW solar cells. Special attention is given to (but not limited to) the popular semiconductor NWs for solar cells, in particular, Si, GaAs(P), and InP. Full article
(This article belongs to the Special Issue Growth, and Structural Characterization of Self-Nucleated Nanowires)
Show Figures

Figure 1

Back to TopTop