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Amorphous and Nanocrystalline Materials for Electrochemical Energy Storage

A special issue of Materials (ISSN 1996-1944).

Deadline for manuscript submissions: closed (20 September 2016) | Viewed by 12101

Special Issue Editor


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Guest Editor
Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria
Interests: ion transport (Li, Na, F) in nanocrystalline and amorphous solids; battery materials; all-solid-state batteries; solid electrolytes; extremely fast ion dynamics; ultraslow-motions; dimensionality and nanosize effects; NMR; conductivity spectroscopy
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Special Issue Information

Dear Colleagues,

Today, more than ever before, the development of suitable electrochemical systems to store electricity generated from renewable sources has a vital role to play in shaping the future of our societies. New and powerful materials are urgently needed to realize advanced rechargeable batteries; they will help us to cut our dependency on fossil fuels and, thus, to reduce CO2 emissions. To increase the energy density and lifetime of the batteries materials, scientists are currently seeking to develop and characterize new materials, as well as to understand the associated interfacial phenomena the different components in a battery are subject to.

Amorphous and nanocrystalline materials offer various advantages over materials with crystallites having mean diameters in the µm range. In particular, they provide short diffusion lengths for both ions and electrons assisting in fast charging and discharging processes. This Special Issue aims to present latest findings in next-generation electrochemical energy storage systems benefiting from structurally disordered solids or nanocrystalline materials putting special emphasis on nanostructured ceramics.

Manuscripts presenting studies of the following topics are highly welcome: (i) new synthesis methods of both active materials and solid electrolytes, (ii) electrochemical performance, (iii) interfacial phenomena, or (iv) ion transport properties of the main charge carriers, covering both ions and electrons. In detail, the manuscripts can be, on the one hand, devoted to active materials for Li-ion, Na-ion, Mg-ion, or even F-ion batteries, and, on the other hand, also to novel solid electrolytes, such as highly ion conducting sulfides, oxides, fluorides, or hydrides. In regard to solid electrolytes, focus is put on bulk ion dynamics vs. transport across grain boundaries, chemical and electrochemical stability, bulk-type, and thin film all-solid-state batteries equipped with nanocrystalline electrolytes.

It is my pleasure to invite you to submit a manuscript (full papers, communications, or reviews) for the Special Issue, “Amorphous and Nanocrystalline Materials for Electrochemical Energy Storage”.

Prof. Dr. Martin Wilkening
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • nanomaterials for next-generation batteries
  • Li-ion and Na-ion cells
  • novel synthesis methods
  • solid electrolytes, ceramics
  • electrochemical properties
  • interfacial effects
  • ion transport

Published Papers (2 papers)

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Research

2757 KiB  
Article
Nature of the Electrochemical Properties of Sulphur Substituted LiMn2O4 Spinel Cathode Material Studied by Electrochemical Impedance Spectroscopy
by Monika Bakierska, Michał Świętosławski, Roman Dziembaj and Marcin Molenda
Materials 2016, 9(8), 696; https://doi.org/10.3390/ma9080696 - 16 Aug 2016
Cited by 13 | Viewed by 6489
Abstract
In this work, nanostructured LiMn2O4 (LMO) and LiMn2O3.99S0.01 (LMOS1) spinel cathode materials were comprehensively investigated in terms of electrochemical properties. For this purpose, electrochemical impedance spectroscopy (EIS) measurements as a function of state of charge [...] Read more.
In this work, nanostructured LiMn2O4 (LMO) and LiMn2O3.99S0.01 (LMOS1) spinel cathode materials were comprehensively investigated in terms of electrochemical properties. For this purpose, electrochemical impedance spectroscopy (EIS) measurements as a function of state of charge (SOC) were conducted on a representative charge and discharge cycle. The changes in the electrochemical performance of the stoichiometric and sulphur-substituted lithium manganese oxide spinels were examined, and suggested explanations for the observed dependencies were given. A strong influence of sulphur introduction into the spinel structure on the chemical stability and electrochemical characteristic was observed. It was demonstrated that the significant improvement in coulombic efficiency and capacity retention of lithium cell with LMOS1 active material arises from a more stable solid electrolyte interphase (SEI) layer. Based on EIS studies, the Li ion diffusion coefficients in the cathodes were estimated, and the influence of sulphur on Li+ diffusivity in the spinel structure was established. The obtained results support the assumption that sulphur substitution is an effective way to promote chemical stability and the electrochemical performance of LiMn2O4 cathode material. Full article
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2867 KiB  
Article
Nano-Crystalline Li1.2Mn0.6Ni0.2O2 Prepared via Amorphous Complex Precursor and Its Electrochemical Performances as Cathode Material for Lithium-Ion Batteries
by Xiangming He, Jixian Wang, Li Wang and Jianjun Li
Materials 2016, 9(8), 661; https://doi.org/10.3390/ma9080661 - 05 Aug 2016
Cited by 18 | Viewed by 5082
Abstract
An amorphous complex precursor with uniform Mn/Ni cation distribution is attempted for preparing a nano-structured layered Li-rich oxide (Li1.2Mn0.6Ni0.2O2)cathode material, using diethylenetriaminepentaacetic acid (DTPA) as a chelating agent. The materials are characterized by powder X-ray [...] Read more.
An amorphous complex precursor with uniform Mn/Ni cation distribution is attempted for preparing a nano-structured layered Li-rich oxide (Li1.2Mn0.6Ni0.2O2)cathode material, using diethylenetriaminepentaacetic acid (DTPA) as a chelating agent. The materials are characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical tests. The crystal structure of Li-rich materials is found to be closely related to synthesis temperature. As-obtained nano materials sintered at 850 °C for 10 h show an average size of 200 nm with a single crystal phase and good crystallinity. At a current density of 20 mA·g−1, the specific discharge capacity reaches 221 mAh·g−1 for the first cycle and the capacity retention is 81% over 50 cycles. Even at a current density of 1000 mA·g−1, the capacity is as high as 118 mAh·g−1. The enhanced rate capability can be ascribed to the nano-sized morphology and good crystal structure. Full article
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