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Advanced Materials for Smart and Functional Windows

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Smart Materials".

Deadline for manuscript submissions: closed (31 December 2019) | Viewed by 6090

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Department of Electrical and Computer Engineering, University of Delaware, 202 Evans Hall Newark, Newark, DE 19716-3130, USA
Interests: distrubuted sensors; optical integration; non-intrusive monitoring
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

There is a great interest in variable or switchable transparency large-area panels, for a variety of reasons, including switchable transparency windows for selected privacy, as well as adjusting solar load, climate-adaptive building shells, including variable reflectivity roofing and more exotic applications, such as variable camouflage. In general, this includes intelligent Smart Glass, which will automatically varies transparency in response to temperature or other parameters, and active Smart Glass, which will vary or switch transparency in response to an electrical control signal. As such, active Smart Glass can be considered a form of optical modulator, or device that varies optical transmission vs. voltage. The most commercial forms of optical modulator are Lithium Niobate electrooptic modulators and Liquid Crystal Displays. The former varies optical transmission via an electrooptic change of refractive index, has picosecond response time, and is used to encode communication data on optical fiber. The latter varies optical transmission via a movement of liquid crystal molecules, has a microsecond response time, and is used in displays. One can see that the form of optical physics used is adapted to the application.

For smart windows or other types of such large panel devices, the most common technology used is Electrochromic. Electrochromic Smart Glass consists of layers of material, for which when voltage causes ions to move from one layer to another, optical transmission varies. The Electrochromic effect illustrates a further distinction of smart glass technologies: it causes a variation from transparency to absorption, rather than transparency to reflection. As such the Electrochromic effect is ideal for applications such as shading, as in varying the reflection of automobile rear-view mirrors. For applications such as adjusting solar transmission through building windows, it should be considered that Electrochromic shading will cause absorption and heating of the windows.

The next common technologies for smart windows are Suspended Particle Devices3 and Polymer Dispersed Liquid Crystal. Both of these technologies have suspended particles or liquid crystal droplets, respectively, which are randomly oriented in the zero-voltage state. For the former, the random orientation results in forward-scattering and absorption in the particles, like Electrochromic, the non-transparency state is absorptive. When voltage is applied, the particles align, lowering the scattering and raising the transparency. For the latter, the droplets result in scattering, and so illustrate a further distinction of optical effect, reflective scattering in the non-transparent state. When a voltage is applied, the droplets align and closely match the refractive index of the matrix, raising transmission. For both of these technologies, there is current in the transparent state, resulting in power consumption on the order of 5–20 W/m2.

The aim of this Special Issue is not to disparage any particular technology in favor of another, as clearly, each has its benefits and drawbacks. Rather, it is to explore the technologies that may result in the desired optical effect, and thus develop a range of technologies with different costs and performance. Existing commercial technologies are complex, and thus their widespread application may be limited. Lower complexity should result in lower cost and increase adoption, and thus should be explored even if engineering problems are pushed into ancillary systems. In considering different effects that may result in optical modulation or switching, it should be appreciated that something must move. The simplest example is a shutter, and a reasonable example here are double-pane windows with motorized built-in blinds. In electrochromic or particle technologies, ions, molecules, or particles move. In optofluidics, a fluid moves. This call for articles encourages workers in the field to think both inside and outside the box, finding ways to decrease costs and increase performance for both standard and exploratory smart window technologies.

Prof. Keith Goossen
Guest Editor

Manuscript Submission Information

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Keywords

  • Smart glass
  • smart windows
  • climate adaptive building shells
  • electrochromic
  • photochromic
  • thermochromic
  • suspended-particle
  • polymer-dispersed liquid-crystal
  • nanocyrstal smart glass
  • micro-blinds
  • optofluidics

Published Papers (2 papers)

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Research

10 pages, 1404 KiB  
Article
Damage Adaptive Titanium Alloy by In-Situ Elastic Gradual Mechanism
by Siqian Zhang, Jing Liu, Haoyu Zhang, Jie Sun and Lijia Chen
Materials 2020, 13(2), 406; https://doi.org/10.3390/ma13020406 - 15 Jan 2020
Viewed by 1547
Abstract
Natural materials are generally damage adaptive through their multilevel architectures, with the characteristics of compositional and mechanical gradients. This study demonstrated that the desired elastic gradient can be in-situ stress-induced in a titanium alloy, and that the alloy showed extreme fatigue-damage tolerance through [...] Read more.
Natural materials are generally damage adaptive through their multilevel architectures, with the characteristics of compositional and mechanical gradients. This study demonstrated that the desired elastic gradient can be in-situ stress-induced in a titanium alloy, and that the alloy showed extreme fatigue-damage tolerance through the crack deflection and branch due to the formation of a three-dimensional elastically graded zone surrounding the crack tip. This looks like a perceptive and adaptive mechanism to retard the crack: the higher stress concentrated at the tip and the larger elastic gradient to be induced. The retardation is so strong that a gradient nano-grained layer with a thickness of less than 2 μm formed at the crack tip due to the highly localized and accumulated plasticity. Furthermore, the ultrafine-grained alloy with the nano-sized precipitation also exhibited good damage tolerance. Full article
(This article belongs to the Special Issue Advanced Materials for Smart and Functional Windows)
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20 pages, 5237 KiB  
Article
Thermoresponsive Bentonite for Water-Based Drilling Fluids
by Wenxin Dong, Xiaolin Pu, Yanjun Ren, Yufen Zhai, Feng Gao and Wei Xie
Materials 2019, 12(13), 2115; https://doi.org/10.3390/ma12132115 - 30 Jun 2019
Cited by 26 | Viewed by 4207
Abstract
As an important industrial material, bentonite has been widely applied in water-based drilling fluids to create mud cakes to protect boreholes. However, the common mud cake is porous, and it is difficult to reduce the filtration of a drilling fluid at high temperature. [...] Read more.
As an important industrial material, bentonite has been widely applied in water-based drilling fluids to create mud cakes to protect boreholes. However, the common mud cake is porous, and it is difficult to reduce the filtration of a drilling fluid at high temperature. Therefore, this paper endowed bentonite with a thermo response via the insertion of N-isopropylacrylamide (NIPAM) monomers. The interaction between NIPAM monomers and bentonite was investigated via Fourier infrared spectroscopy (FTIR), isothermal adsorption, and X-ray diffraction (XRD) at various temperatures. The results demonstrate that chemical adsorption is involved in the adsorption process of NIPAM monomers on bentonite, and the adsorption of NIPAM monomers accords with the D–R model. With increasing temperature, more adsorption water was squeezed out of the composite when the temperature of the composite exceeded 70 °C. Based on the composite of NIPAM and bentonite, a mud cake was prepared using low-viscosity polyanionic cellulose (Lv-PAC) and initiator potassium peroxydisulfate (KPS). The change in the plugging of the mud cake was investigated via environmental scanning electron microscopy (ESEM), contact angle testing, filtration experiments, and linear expansion of the shale at various temperatures. In the plugging of the mud cake, a self-recovery behavior was observed with increasing temperature, and resistance was observed at 110 °C. The rheology of the drilling fluid was stable in the alterative temperature zone (70–110 °C). Based on the high resistance of the basic drilling fluid, a high-density drilling fluid (ρ = 2.0 g/cm3) was prepared with weighting materials with the objective of drilling high-temperature formations. By using a high-density drilling fluid, the hydration expansion of shale was reduced by half at 110 °C in comparison with common bentonite drilling fluid. In addition, the rheology of the high-density drilling fluid tended to be stable, and a self-recovery behavior was observed. Full article
(This article belongs to the Special Issue Advanced Materials for Smart and Functional Windows)
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