Metallic and Metal Oxide Nanoparticles: Novel Approaches

A special issue of Metals (ISSN 2075-4701).

Deadline for manuscript submissions: closed (30 November 2016) | Viewed by 31979

Special Issue Editor

Department of Science and Engineereing of Oxide Materials and Nanomaterials, Faculty of Applied Chemistry and Materials Science, Politehnica University of Bucharest, RO-011061 Bucharest, Romania
Interests: synthesis and characterization of nanobiomaterials; polymers; pharmaceutical nanotechnology; drug delivery; anti-biofilm surfaces; nanomodified surfaces; natural products
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

In the last few decades, nanosized structures, usually ranging from 1–100 nm, were organized in four main categories: 0D, 1D, 2D, and 3D. These structures attracted the attention of scientific communities, which developed applications and implemented them in research areas, such as food sector, medical sector, environmental, and also socio-economical sector. The main purpose of this Special Issue is to highlight the current progress and the impact of metallic and metal oxide nanoparticles in the above mentioned research areas. This Special Issue aims to present novel approaches related to fabrication, characterization methods, properties, and applications of such nanostructures. Considering the fact that health-related applications are mostly investigated, this Special Issue will highlight the novel approaches related to the utility of metallic nanoparticles and metal oxide nanoparticles in drug delivery, drug targeting, cancer therapy, medical imaging, tissue engineering, cosmetics, dentistry, food preservation, water treatment and purification, nutrient delivery, food packaging, nanosensors, new pesticides, and other environmental applications.

Dr. Alexandru Mihai Grumezescu
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Metals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • gold
  • silver
  • magnetite
  • zinc oxide
  • quantum dots
  • nanobiomaterials
  • thin coatings
  • cancer therapy
  • antimicrobials
  • drug delivery and targeting
  • water purification
  • food packaging
  • nanosensors

Published Papers (5 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

Jump to: Review

28143 KiB  
Article
Preparation and Properties of Microarc Oxidation Self-Lubricating Composite Coatings on Aluminum Alloy
by Zhenwei Li and Shichun Di
Metals 2017, 7(4), 127; https://doi.org/10.3390/met7040127 - 05 Apr 2017
Cited by 9 | Viewed by 5166
Abstract
Microarc oxidation (MAO) coatings were prepared on 2024-T4 aluminum alloy using pulsed bipolar power supply at different cathode current densities. The MAO ceramic coatings contained many crater-like micropores and a small number of microcracks. After the MAO coatings were formed, the coated samples [...] Read more.
Microarc oxidation (MAO) coatings were prepared on 2024-T4 aluminum alloy using pulsed bipolar power supply at different cathode current densities. The MAO ceramic coatings contained many crater-like micropores and a small number of microcracks. After the MAO coatings were formed, the coated samples were immersed into a water-based Polytetrafluoroethylene (PTFE) dispersion. The micropores and microcracks on the surface of the MAO coatings were filled with PTFE dispersion for preparing MAO self-lubricating composite coatings. The microstructure and properties of MAO coatings and the wear resistance of microarc oxidation self-lubricating composite coatings were analyzed by SEM, laser confocal microscope, X-ray diffractometry (XRD), Vickers hardness test, scratch test and ball-on-disc abrasive tests, respectively. The results revealed that the wear rates of the MAO coatings decreased significantly with an increase in cathode current density. Compared to the MAO coatings, the microarc oxidation self-lubricating composite coatings exhibited a lower friction coefficient and lower wear rates. Full article
(This article belongs to the Special Issue Metallic and Metal Oxide Nanoparticles: Novel Approaches)
Show Figures

Figure 1

4009 KiB  
Article
Synthesis, Characterization, and Toxicity Evaluation of Dextran-Coated Iron Oxide Nanoparticles
by Mihaela Balas, Carmen Steluta Ciobanu, Carmen Burtea, Miruna Silvia Stan, Eugenia Bezirtzoglou, Daniela Predoi and Anca Dinischiotu
Metals 2017, 7(2), 63; https://doi.org/10.3390/met7020063 - 21 Feb 2017
Cited by 24 | Viewed by 6599
Abstract
We report the synthesis of dextran-coated iron oxide magnetic nanoparticles (DIO-NPs) with spherical shape and uniform size distribution as well as their accumulation and toxic effects on Jurkat cells up to 72 h. The characterization of dextran-coated maghemite nanoparticles was done by X-ray [...] Read more.
We report the synthesis of dextran-coated iron oxide magnetic nanoparticles (DIO-NPs) with spherical shape and uniform size distribution as well as their accumulation and toxic effects on Jurkat cells up to 72 h. The characterization of dextran-coated maghemite nanoparticles was done by X-ray diffraction and dynamic light scattering analyses, transmission electron microscopy imaging, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, magnetic hysteresis, and relaxometry measurements. The quantification of DIO-NPs intracellular uptake showed a progressive accumulation of iron as a function of time and dose accompanied by additional lysosome formation and an increasing darkening exhibited by a magnetic resonance imaging (MRI) scanner. The cytotoxicity assays revealed a decrease of cell viability and a loss of membrane integrity in a time- and dose-dependent manner. Exposure to DIO-NPs determined an increase in reactive oxygen species level up to 72 h. In the first two days of exposure, the level of reduced glutathione decreased and the amount of malondyaldehyde increased, but at the end of the experiment, their concentrations returned to control values. These nanoparticles could be used as contrast agents for MRI but several parameters concerning their interaction with the cells should be taken into consideration for a safe utilization. Full article
(This article belongs to the Special Issue Metallic and Metal Oxide Nanoparticles: Novel Approaches)
Show Figures

Figure 1

3373 KiB  
Article
Dissolution Behavior of Alumina-Based Inclusions in CaF2-Al2O3-CaO-MgO-SiO2 Slag Used for the Electroslag Metallurgy Process
by Yanwu Dong, Zhouhua Jiang and Ang Yu
Metals 2016, 6(11), 273; https://doi.org/10.3390/met6110273 - 09 Nov 2016
Cited by 10 | Viewed by 6253
Abstract
Removal of non-metallic inclusions to CaF2-based slag is one of the most important functions of electroslag remelting. In this work, the dissolution behavior for alumina-based inclusions in CaF2-Al2O3-CaO-MgO-SiO2 slag has been investigated. Results indicate [...] Read more.
Removal of non-metallic inclusions to CaF2-based slag is one of the most important functions of electroslag remelting. In this work, the dissolution behavior for alumina-based inclusions in CaF2-Al2O3-CaO-MgO-SiO2 slag has been investigated. Results indicate that the diffusion or permeability capacity of slag components into alumina particles is F, Ca2+, Si4+, Mg2+, from strongest to weakest, for CaF2-Al2O3-CaO-MgO-SiO2 slag. Alumina inclusions react with F in liquid slag at first and then react with CaO to form xCaO-yAl2O3 system. Subsequently, MgO substitutes for CaO to form a MgO-Al2O3 system layer surrounding the other product and reactant, and then enters the liquid slag. CaF2 can improve the dissolution capacity of slag to alumina inclusions. A complex region was formed between alumina-based particles and the slag, with different areas dominated by CaF2, CaO-Al2O3, CaO-SiO2 and MgO-Al2O3. The dissolution process of alumina particles in slag is different from the formation of compound inclusions originated from the Al-O deoxidization reaction. Full article
(This article belongs to the Special Issue Metallic and Metal Oxide Nanoparticles: Novel Approaches)
Show Figures

Figure 1

17646 KiB  
Article
Antimicrobial Nanostructured Bioactive Coating Based on Fe3O4 and Patchouli Oil for Wound Dressing
by Marius Rădulescu, Ecaterina Andronescu, Alina Maria Holban, Bogdan Stefan Vasile, Florin Iordache, Laurențiu Mogoantă, George Dan Mogoșanu, Alexandru Mihai Grumezescu, Mihaela Georgescu and Mariana Carmen Chifiriuc
Metals 2016, 6(5), 103; https://doi.org/10.3390/met6050103 - 30 Apr 2016
Cited by 25 | Viewed by 6030
Abstract
The aim of this study was to develop a biocompatible coating for wound dressings, containing iron oxide nanoparticles functionalized with patchouli essential oil in order to obtain improved antimicrobial properties able to prevent biofilm development and consecutive associated infections. The bioactive coating was [...] Read more.
The aim of this study was to develop a biocompatible coating for wound dressings, containing iron oxide nanoparticles functionalized with patchouli essential oil in order to obtain improved antimicrobial properties able to prevent biofilm development and consecutive associated infections. The bioactive coating was prepared by the co-precipitation of a precursor in an alkaline solution of patchouli oil. The prepared surface was characterized by XRD (X ray diffraction), TEM (transmission electron microscopy), SAED (selected area diffraction), SEM (scanning electron microscopy) and FT-IR (Fourier transform infrared spectroscopy). The bioevaluation of the obtained coating consisted in antimicrobial, as well as in vitro and in vivo biocompatibility and biodistribution assays. The obtained coating revealed a strong anti-biofilm activity maintained up to 72 h, as well as a low cytotoxicity on mammalian cells and a good biodistribution after intraperitoneal injection in mice. These results demonstrate the promising potential of the respective coatings for the management of wound infections and for the development of soft materials with improved resistance to microbial colonization. Full article
(This article belongs to the Special Issue Metallic and Metal Oxide Nanoparticles: Novel Approaches)
Show Figures

Graphical abstract

Review

Jump to: Research

537 KiB  
Review
Collagen-Nanoparticles Composites for Wound Healing and Infection Control
by Mădălina Elena Grigore, Alexandru Mihai Grumezescu, Alina Maria Holban, George Dan Mogoşanu and Ecaterina Andronescu
Metals 2017, 7(12), 516; https://doi.org/10.3390/met7120516 - 23 Nov 2017
Cited by 20 | Viewed by 7011
Abstract
Nowadays, the world is facing a serious crisis represented by the rapid emergence of resistant bacteria, which jeopardizes the efficacy of antibiotics. This crisis has been attributed to the overuse and misuse of antibiotics, as well as the cessation of new drug production [...] Read more.
Nowadays, the world is facing a serious crisis represented by the rapid emergence of resistant bacteria, which jeopardizes the efficacy of antibiotics. This crisis has been attributed to the overuse and misuse of antibiotics, as well as the cessation of new drug production by the pharmaceutical industry. Therefore, bacterial strains with resistance to multiple antibiotic classes have appeared, such as Staphylococcus aureus, Acinetobacter spp. and Pseudomonas aeruginosa. This review aims to provide an updated summary of the current approach to the treatment of infections due to resistant microorganisms, with a focus on the application of the antimicrobial effects of inorganic nanoparticles in combination with collagen to promote wound healing. In addition, the paper describes the current approaches in the field of functionalized collagen hydrogels capable of wound healing and inhibiting microbial biofilm production. Full article
(This article belongs to the Special Issue Metallic and Metal Oxide Nanoparticles: Novel Approaches)
Show Figures

Figure 1

Back to TopTop