Confinement Effects on Chemical Equilibria: Pentacyano(Pyrazine)Ferrate(II) Stability Changes within Nanosized Droplets of Water
Abstract
:1. Introduction
2. Results and Discussion
2.1. Kinetic Measurements Using UV-Vis Spectroscopy
2.2. Thermodynamic Measurements using 1H-NMR Spectroscopy
3. Materials and Methods
3.1. General Materials and Methods
3.2. Preparation of Solutions
3.2.1. Metal Complex Solutions
3.2.2. Reverse Micelle (RM) Solutions for Spectroscopic Measurements
3.3. Methods
3.3.1. UV-Visible Spectroscopy
3.3.2. 1H-NMR Spectroscopy
3.3.3. Dynamic Light Scattering (DLS)
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Sample Availability: Compounds are readily available by synthesis from commercially available material according to literature procedures. |
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Borunda, T.; Myers, A.J.; Mary Fisher, J.; Crans, D.C.; Johnson, M.D. Confinement Effects on Chemical Equilibria: Pentacyano(Pyrazine)Ferrate(II) Stability Changes within Nanosized Droplets of Water. Molecules 2018, 23, 858. https://doi.org/10.3390/molecules23040858
Borunda T, Myers AJ, Mary Fisher J, Crans DC, Johnson MD. Confinement Effects on Chemical Equilibria: Pentacyano(Pyrazine)Ferrate(II) Stability Changes within Nanosized Droplets of Water. Molecules. 2018; 23(4):858. https://doi.org/10.3390/molecules23040858
Chicago/Turabian StyleBorunda, Teofilo, Alexander J. Myers, J. Mary Fisher, Debbie C. Crans, and Michael D. Johnson. 2018. "Confinement Effects on Chemical Equilibria: Pentacyano(Pyrazine)Ferrate(II) Stability Changes within Nanosized Droplets of Water" Molecules 23, no. 4: 858. https://doi.org/10.3390/molecules23040858