Synthesis and Characterization of Mesoporous Silica Functionalized with Calix[4]arene Derivatives
Abstract
:1. Introduction
2. Results and Discussion
3. Experimental Section
3.1. Materials
3.2. Instrumentation
3.3. Synthesis Methods
3.3.1. Introduction of Diisocyanate Functional Groups into the Mesoporous Surfaces
3.3.2. Determination of Isocyanate Groups of the Reaction System
3.3.3. Grafting Modification of MCM-TDI with Calix[4]Arene Derivatives
4. Conclusions
Acknowledgments
References
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Sample | %C | %H | %N | %S |
---|---|---|---|---|
M-TDI | 18.64 | 3.04 | 5.93 | - |
MC4 | 42.64 | 3.05 | 1.06 | - |
MC4S | 33.31 | 4.16 | 3.97 | 4.04 |
MPC4 | 40.53 | 4.84 | 4.30 | - |
Sample | Region °C | Weight-loss % | Assignment |
---|---|---|---|
MC4 | 45–150 | 4.9 | Moisture |
150–280 | 8.4 | calix[4]arene | |
280–380 | 21.4 | Carbamate group and calix[4]arene | |
380–800 | 32.49 | calix[4]arene | |
MC4S | 45–150 | 4.7 | Moisture |
150–280 | 5.9 | Carbamate group | |
350–800 | 37.9 | calix[4]arene sulfonate | |
MPC4 | 45–150 | 2.4 | Moisture |
200–350 | 44.9 | Carbamate group and para tert butyl calix[4]arene | |
400–800 | 15.7 | para tert butyl calix[4]arene |
Sample | SBET (m2/g) | V (cm3/g) | D (nm) |
---|---|---|---|
MCM-41 | 993 | 0.86 | 2.9 |
MC4 | 733 | 0.67 | 3.6 |
MC4S | 452 | 0.43 | 3.8 |
MPC4 | 339 | 0.32 | 3.9 |
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Alahmadi, S.M.; Mohamad, S.; Maah, M.J. Synthesis and Characterization of Mesoporous Silica Functionalized with Calix[4]arene Derivatives. Int. J. Mol. Sci. 2012, 13, 13726-13736. https://doi.org/10.3390/ijms131013726
Alahmadi SM, Mohamad S, Maah MJ. Synthesis and Characterization of Mesoporous Silica Functionalized with Calix[4]arene Derivatives. International Journal of Molecular Sciences. 2012; 13(10):13726-13736. https://doi.org/10.3390/ijms131013726
Chicago/Turabian StyleAlahmadi, Sana M., Sharifah Mohamad, and Mohd Jamil Maah. 2012. "Synthesis and Characterization of Mesoporous Silica Functionalized with Calix[4]arene Derivatives" International Journal of Molecular Sciences 13, no. 10: 13726-13736. https://doi.org/10.3390/ijms131013726