Chemical Modification of Poly(1-Trimethylsylil-1-Propyne) for the Creation of Highly Efficient CO2-Selective Membrane Materials
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of PTMSP on TaCl5–TIBA
2.3. Synthesis of Brominated PTMSP
2.4. Quaternization of N-Butylimidazole by the Brominated PTMSP
2.5. Physico-Chemical Characterization
3. Results and Discussions
3.1. Synthesis and Properties of PTMSP Containing Butylimidazole Bromide
3.2. Gas Transport Characteristics of PTMSP Containing Butylimidazole Salts
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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[Br]/[N-Butylimidazole] [mol/mol] | Content of N in the Polymer [wt%] | Content of Quaternized Units in the Polymer [mol%] |
---|---|---|
1:2 | 0.4 | 2.5 |
1:5 | 0.8 | 5.0 |
1:8 | 1.7 | 10.0 |
1:10 | 3.1 | 20.0 |
Content of Quaternized Units in the Polymer [mol%] | THF | CHCl3 | Toluene, Benzene | CCl4 | Cyclohexane | C5–C12 3 |
---|---|---|---|---|---|---|
0 2 | + | + | + | + | + | – |
2.5 | + | + | + | – | – | – |
5 | + | + | – | – | – | – |
10 | ± | ± | – | – | – | – |
20 | – | – | – | – | – | – |
Content of Quaternized Units in the Polymer [mol%] | 2θ [°], Basic Reflex | Δ1/2 [°] | Interplanar Distance d [Å] |
---|---|---|---|
0 1 | 9.8 | 3.2 | 9.0 |
0 2 | 9.3 | 3.0 | 9.5 |
5 | 9.6 | 3.7 | 9.3 |
20 | 9.3 | 3.4 | 9.5 |
Content of Quaternized Units in the Polymer [mol%] | P [Barrer] 1 | D × 107 [cm2/s] | S × 103 [cm3(STP)/ (cm3 × cmHg)] | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
O2 | N2 | CO2 | CH4 | O2 | N2 | CO2 | CH4 | O2 | N2 | CO2 | CH4 | |
0 2 | 2640 | 1400 | 12,500 | 2880 | 55 | 35 | 44 | 34 | 48 | 40 | 284 | 85 |
2.5 | 1200 | 406 | 5480 | 836 | 50 | 27 | 28 | 19 | 24 | 15 | 197 | 44 |
5 | 429 | 133 | 2410 | 336 | 39 | 19 | 13 | 16 | 11 | 7 | 185 | 21 |
Content of Quaternized Units in the Polymer [mol%] | O2/N2 | CO2/N2 | CO2/CH4 | ||||||
---|---|---|---|---|---|---|---|---|---|
αP | αD | αS | αP | αD | αS | αP | αD | αS | |
0 1 | 1.9 | 1.6 | 1.2 | 8.8 | 1.3 | 7.1 | 4.4 | 1.3 | 3.3 |
2.5 | 3.0 | 1.9 | 1.6 | 13.5 | 1.0 | 13.1 | 6.6 | 1.5 | 4.5 |
5 | 3.2 | 2.1 | 1.6 | 18.1 | 0.7 | 26.4 | 7.2 | 0.8 | 8.8 |
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Polevaya, V.; Geiger, V.; Bondarenko, G.; Shishatskiy, S.; Khotimskiy, V. Chemical Modification of Poly(1-Trimethylsylil-1-Propyne) for the Creation of Highly Efficient CO2-Selective Membrane Materials. Materials 2019, 12, 2763. https://doi.org/10.3390/ma12172763
Polevaya V, Geiger V, Bondarenko G, Shishatskiy S, Khotimskiy V. Chemical Modification of Poly(1-Trimethylsylil-1-Propyne) for the Creation of Highly Efficient CO2-Selective Membrane Materials. Materials. 2019; 12(17):2763. https://doi.org/10.3390/ma12172763
Chicago/Turabian StylePolevaya, Viktoriya, Viktoriya Geiger, Galina Bondarenko, Sergey Shishatskiy, and Valeriy Khotimskiy. 2019. "Chemical Modification of Poly(1-Trimethylsylil-1-Propyne) for the Creation of Highly Efficient CO2-Selective Membrane Materials" Materials 12, no. 17: 2763. https://doi.org/10.3390/ma12172763