Halide-Enhanced Catalytic Activity of Palladium Nanoparticles Comes at the Expense of Catalyst Recovery
Abstract
:1. Introduction
1.1. The Oxidative Homocoupling Reaction of Arylboronic Acids
1.2. Nanoparticle Catalysis
1.3. The Suzuki-Miyaura cross Coupling Reaction and the Oxidative Homocoupling Reaction or Arylboronic Acids Catalyzed by Pd NPs
1.4. The Mechanism of Catalysis by Nanoparticles—On the Surface or in Solution?
1.5. Catalysis in Aqueous Solutions
1.6. Aims
2. Results and Discussion
2.1. Reaction Parameters
2.2. Effect of Added Halide on the Catalytic Activity of Pd-PPy-PS Nanocomposites
2.3. Effect of Added Halide on the Recovery of Catalytic Activity
2.4. Proposed Mechanism for Enhanced Catalysis and Increased Loss of Activity
3. Materials and Methods
3.1. Chemicals
3.2. Kinetic Experiments
3.3. Catalyst Recovery
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Bouleghlimat, A.; Othman, M.A.; Lagrave, L.V.; Matsuzawa, S.; Nakamura, Y.; Fujii, S.; Buurma, N.J. Halide-Enhanced Catalytic Activity of Palladium Nanoparticles Comes at the Expense of Catalyst Recovery. Catalysts 2017, 7, 280. https://doi.org/10.3390/catal7090280
Bouleghlimat A, Othman MA, Lagrave LV, Matsuzawa S, Nakamura Y, Fujii S, Buurma NJ. Halide-Enhanced Catalytic Activity of Palladium Nanoparticles Comes at the Expense of Catalyst Recovery. Catalysts. 2017; 7(9):280. https://doi.org/10.3390/catal7090280
Chicago/Turabian StyleBouleghlimat, Azzedine, Mazin A. Othman, Louis V. Lagrave, Soichiro Matsuzawa, Yoshinobu Nakamura, Syuji Fujii, and Niklaas J. Buurma. 2017. "Halide-Enhanced Catalytic Activity of Palladium Nanoparticles Comes at the Expense of Catalyst Recovery" Catalysts 7, no. 9: 280. https://doi.org/10.3390/catal7090280