Non Edible Oil-Based Epoxy Resins from Jatropha Oil and Their Shape Memory Behaviors
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Epoxidized Jatropha Oil
2.3. Preparation of EJO/MHPA
2.4. Characterization
2.4.1. Oxirane Oxygen Content
2.4.2. Fourier Transform Infrared Spectroscopy
2.4.3. Nuclear Magnetic Resonance Spectroscopy
2.4.4. Thermal Analysis
2.4.5. Investigation of the Shape Memory Recovery Behavior of EJO/MHPA Polymer
3. Results
3.1. Oxirane Oxygen Content
3.2. FTIR Analysis
3.3. Thermal Analysis
3.4. Shape Memory-Recovery Behaviours
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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EJO/MHPA Ratio | Ti (°C) | Td at Different wt. Losses (°C) | Tdmax (°C) | Wt. Residue at 600 °C (%) | ||
---|---|---|---|---|---|---|
T5% | T25% | T50% | ||||
0.6 | 163 | 252 | 334 | 369 | 382 | 3.69 |
0.8 | 147 | 249 | 335 | 371 | 381 | 3.44 |
1.0 | 168 | 283 | 347 | 375 | 383 | 2.64 |
1.2 | 150 | 273 | 343 | 372 | 376 | 1.00 |
1.4 | 151 | 254 | 338 | 368 | 373 | 1.75 |
EJO/MHPA Ratio | Tg1 (°C) | Tg2 (°C) | ΔH (J/g) |
---|---|---|---|
0.6 | 9.8 | 135 | −3.76 |
0.8 | 10.8 | 140 | −1.07 |
1.0 | 9.6 | 144 | −2.86 |
1.2 | 7.8 | −0.76 | |
1.4 | 11.3 | −2.00 |
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Taung Mai, L.L.; Aung, M.M.; Muhamad Saidi, S.A.; H’ng, P.S.; Rayung, M.; Jaafar, A.M. Non Edible Oil-Based Epoxy Resins from Jatropha Oil and Their Shape Memory Behaviors. Polymers 2021, 13, 2177. https://doi.org/10.3390/polym13132177
Taung Mai LL, Aung MM, Muhamad Saidi SA, H’ng PS, Rayung M, Jaafar AM. Non Edible Oil-Based Epoxy Resins from Jatropha Oil and Their Shape Memory Behaviors. Polymers. 2021; 13(13):2177. https://doi.org/10.3390/polym13132177
Chicago/Turabian StyleTaung Mai, Lu Lu, Min Min Aung, Sarah Anis Muhamad Saidi, Paik San H’ng, Marwah Rayung, and Adila Mohamad Jaafar. 2021. "Non Edible Oil-Based Epoxy Resins from Jatropha Oil and Their Shape Memory Behaviors" Polymers 13, no. 13: 2177. https://doi.org/10.3390/polym13132177