First U-Pb (CA-ID-TIMS) Dating of the Uppermost Permian Coal Interval in the Minusinsk Coal Basin (Siberia, Russia) Using Zircon Grains from Volcanic Ashfalls
Abstract
:1. Introduction
2. Geological Background
3. Materials
4. Methods
5. Results
6. Discussion
7. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Mineral | Tonstein I-12 | Tonstein I-22 |
---|---|---|
Kaolinite | 42.6 | 56.2 |
Quartz | 35.0 | 22.9 |
K-feldspar (sanidine and microcline) | 9.8 | 12.5 |
Albite | 4.2 | 5.6 |
Apatite | 11.7 | 2.7 |
Total | 99.1 | 99.9 |
Major Element Oxides (Weight %) | Tonstein I-12 | Tonstein I-22 | UCC | NASC |
---|---|---|---|---|
SiO2 | 34.7 | 49.8 | 66.6 | 64.8 |
TiO2 | 0.59 | 0.65 | 0.64 | 0.70 |
Al2O3 | 16.4 | 27.8 | 15.4 | 16.9 |
Fe2O3 | 0.81 | 0.86 | 5.61 | 6.30 |
MnO | 0.011 | 0.006 | 0.10 | 0.06 |
CaO | 3.61 | 1.58 | 3.59 | 3.63 |
MgO | 0.20 | 0.31 | 2.48 | 2.86 |
K2O | 0.85 | 0.71 | 2.80 | 3.97 |
Na2O | 0.18 | 0.37 | 3.27 | 1.14 |
P2O5 | 2.16 | 0.88 | 0.15 | 0.13 |
Loss on Ignition (LOI, %) | 35.6 | 13.6 | - | - |
Total | 99.7 | 99.8 | 100.64 | 100.49 |
SiO2/Al2O3 | 2.12 | 1.79 | 4.3 | 3.8 |
TiO2/Al2O3 | 0.036 | 0.023 | 0.042 | 0.041 |
Element | Tonstein I-12 | Tonstein I-22 | Sedimentary Rocks 1 | Upper Continental Crust (UCC) 2 | Acid Volcanic Rocks 3 | Coal Ashes 4 |
---|---|---|---|---|---|---|
Li | 68.2 | 20.7 | 33 | 21 | 26 | 66 |
Be | 4.3 | 0.45 | 1.9 | 2.1 | 4 | 9.4 |
Sc | 11.4 | 6.9 | 9.6 | 14 | 4.2 | 23 |
V | 8.4 | 11.9 | 91 | 97 | 60 | 155 |
Cr | 2.4 | 3.4 | 58 | 92 | 8.5 | 100 |
Co | 1.3 | 1.7 | 14 | 17.3 | 4.8 | 32 |
Ni | 21.9 | 92.2 | 37 | 47 | 8 | 76 |
Cu | 68.6 | 57.5 | 31 | 28 | 15 | 92 |
Zn | 100.4 | 55.7 | 43 | 67 | 35 | 140 |
Ga | 20.8 | 36.2 | 12 | 17.5 | 26 | 33 |
Ge | 9.2 | 14.9 | 1.4 | – | 1 | 15 |
As | 14.9 | 10.8 | 7.6 | – | 4.3 | 47 |
Se | 6.4 | 8.1 | 0.27 | – | 0.093 | 8.8 |
Rb | 14.6 | 8.4 | 94 | 84 | 190 | 79 |
Sr | 236 | 218 | 270 | 320 | 240 | 740 |
Y | 81.2 | 39.2 | 29 | 21 | 24 | 51 |
Zr | 94.8 | 115.3 | 170 | 193 | 110 | 210 |
Nb | 7.1 | 4.6 | 7.6 | 12 | 26 | 20 |
Mo | 1.4 | 1.2 | 1.5 | – | 3.4 | 14 |
Cd | 0.3 | 0.2 | 0.8 | 0.09 | 0.3 | 1.2 |
Sn | 2.1 | 3.0 | 2.9 | 2.1 | 3.5 | 6.4 |
Sb | 0.1 | 0.70 | 1.2 | 0.4 | – | 6.3 |
Cs | 0.6 | 0.9 | 7.7 | 4.9 | 10 | 6.6 |
Ba | 445 | 231 | 410 | 628 | 480 | 940 |
La | 35.6 | 88.1 | 32 | 31 | 31 | 69 |
Ce | 76.9 | 169.8 | 52 | 63 | 58 | 130 |
Pr | 8.7 | 16.7 | 6.8 | 7.1 | 10 | 20 |
Nd | 35.5 | 62.0 | 24 | 27 | 27 | 67 |
Sm | 7.9 | 10.8 | 5.5 | 4.70 | 5.2 | 13 |
Eu | 1.8 | 1.6 | 0.94 | 1.0 | 1.5 | 2.5 |
Gd | 8.6 | 9.8 | 4 | 4.0 | 5 | 16 |
Tb | 1.3 | 1.4 | 0.69 | 0.70 | 0.82 | 2.1 |
Dy | 8.8 | 7.4 | 3.6 | 3.90 | 6 | 14 |
Ho | 2.1 | 1.4 | 0.92 | 0.83 | 1.7 | 4.0 |
Er | 7.3 | 3.4 | 1.7 | 2.30 | 3.6 | 5.5 |
Tm | 1.1 | 0.5 | 0.78 | 0.30 | 1 | 2.0 |
Yb | 8.0 | 3.0 | 2.0 | 1.96 | 2.5 | 6.2 |
Lu | 1.1 | 0.4 | 0.44 | 0.31 | 0.55 | 1.2 |
Hf | 3.9 | 5.2 | 3.9 | 5.3 | 4.1 | 8.3 |
Ta | 0.9 | 1.9 | 1.0 | 0.9 | 1.8 | 1.7 |
W | 0.5 | 0.3 | 2.0 | – | 1.4 | 6.9 |
Tl | 0.13 | 0.07 | 0.89 | 0.9 | 2.1 | 4.9 |
Pb | 19.7 | 30.0 | 12 | 17 | 23 | 47 |
Th | 12.3 | 31.9 | 7.7 | 10.5 | 13 | 21 |
U | 3.8 | 7.1 | 3.4 | 2.7 | 4.5 | 16 |
Th/U | 3.2 | 4.5 | 2.26 | 3.9 | 2.9 | 1.3 |
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Silantiev, V.V.; Arbuzov, S.I.; Tichomirowa, M.; Käßner, A.; Izmailova, A.K.; Ilenok, S.S.; Soktoev, B.R.; Nurgalieva, N.G.; Gutak, Y.M.; Felker, A.S.; et al. First U-Pb (CA-ID-TIMS) Dating of the Uppermost Permian Coal Interval in the Minusinsk Coal Basin (Siberia, Russia) Using Zircon Grains from Volcanic Ashfalls. Minerals 2024, 14, 982. https://doi.org/10.3390/min14100982
Silantiev VV, Arbuzov SI, Tichomirowa M, Käßner A, Izmailova AK, Ilenok SS, Soktoev BR, Nurgalieva NG, Gutak YM, Felker AS, et al. First U-Pb (CA-ID-TIMS) Dating of the Uppermost Permian Coal Interval in the Minusinsk Coal Basin (Siberia, Russia) Using Zircon Grains from Volcanic Ashfalls. Minerals. 2024; 14(10):982. https://doi.org/10.3390/min14100982
Chicago/Turabian StyleSilantiev, Vladimir V., Sergey I. Arbuzov, Marion Tichomirowa, Alexandra Käßner, Alsu Kh. Izmailova, Sergey S. Ilenok, Bulat R. Soktoev, Nouria G. Nurgalieva, Yaroslav M. Gutak, Anastasia S. Felker, and et al. 2024. "First U-Pb (CA-ID-TIMS) Dating of the Uppermost Permian Coal Interval in the Minusinsk Coal Basin (Siberia, Russia) Using Zircon Grains from Volcanic Ashfalls" Minerals 14, no. 10: 982. https://doi.org/10.3390/min14100982