Influences and Isotherm Models on Phosphorus Removal from Wastewater by Using Fe3+-Type UBK10 Cation Exchange Resin as Absorbent
Abstract
:1. Introduction
2. Materials and Methods
2.1. Formulation of Fe3+-Type UBK 10
2.2. Adsorption of Phosphate Ions to the Fe3+-Type UBK 10 by the Batch Method
2.3. Molybdenum Blue Phosphorus Approach with a UV-Visible Spectrophotometer
2.4. Equilibrium Studies
2.4.1. The Langmuir Model
2.4.2. The Freundlich Model
2.4.3. The Temkin Model
3. Results and Discussions
3.1. Influence of Fe3+-Type UBK 10 Resin Quantity on Phosphate Ion Adsorption
3.2. Impact of Contact Time on Phosphate Ion Adsorption
3.3. Impact of NaCl Concentration on Rate of Phosphate Adsorption
3.4. Influence of pH on Phosphate Ion Adsorption
3.5. Isotherm Model
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Beaudry, J.W.; Sengupta, S. Phosphorus recovery from wastewater using pyridine-based ion-exchange resins: Role of impregnated iron oxide nanoparticles and preloaded Lewis acid (Cu2+). Water Environ. Res. 2021, 93, 774–786. [Google Scholar] [CrossRef]
- Bezzina, J.P.; Robshaw, T.J.; Canner, A.J.; Dawson, R.; Ogden, M.D. Adsorption studies of a multi-metal system within acetate media, with a view to sustainable phosphate recovery from sewage sludge. J. Environ. Manag. 2022, 324, 116279. [Google Scholar] [CrossRef] [PubMed]
- Khan, M.N.; Mohammad, F. Eutrophication: Challenges and Solutions. In Eutrophication: Causes, Consequences and Control; Ansari, A.A., Gill, S.S., Eds.; Springer: New York, NY, USA, 2014; pp. 1–15. [Google Scholar]
- Rose, J.; Manceau, A.; Masion, A.; Bottero, J.-Y. Structure and Mechanisms of Formation of FeOOH(NO3) Oligomers in the Early Stages of Hydrolysis. Langmuir 1997, 13, 3240–3246. [Google Scholar] [CrossRef]
- Liu, G.; Han, C.; Kong, M.; Abdelraheem, W.H.M.; Nadagouda, M.N.; Dionysiou, D.D. Nanoscale Zero-Valent Iron Confined in Anion Exchange Resins to Enhance Selective Adsorption of Phosphate from Wastewater. ACS ES&T Eng. 2022, 2, 1454–1464. [Google Scholar] [CrossRef]
- Wei, L.-L.; Wang, G.-Z.; Jiang, J.-Q.; Li, G.; Zhang, X.-L.; Zhao, Q.-L.; Cui, F.-Y. Co-removal of phosphorus and nitrogen with commercial 201 × 7 anion exchange resin during tertiary treatment of WWTP effluent and phosphate recovery. Desalination Water Treat. 2014, 56, 1633–1647. [Google Scholar] [CrossRef]
- Smil, V. Phosphorus in the environment: Natural flows and human interferences. Annu. Rev. Energy Environ. 2000, 25, 53–88. [Google Scholar] [CrossRef] [Green Version]
- Banu, H.T.; Meenakshi, S. One pot synthesis of chitosan grafted quaternized resin for the removal of nitrate and phosphate from aqueous solution. Int. J. Biol. Macromol. 2017, 104, 1517–1527. [Google Scholar] [CrossRef]
- Sun, Y.; Feng, X.; Zheng, W. Nanoscale Lanthanum Carbonate Hybridized with Polyacrylic Resin for Enhanced Phosphate Removal from Secondary Effluent. J. Chem. Eng. Data 2020, 65, 4512–4522. [Google Scholar] [CrossRef]
- Ding, L.; Wu, C.; Deng, H.; Zhang, X. Adsorptive characteristics of phosphate from aqueous solutions by MIEX resin. J. Colloid Interface Sci. 2012, 376, 224–232. [Google Scholar] [CrossRef]
- Zhang, X.; Ma, C.; Wen, K.; Han, R. Adsorption of phosphate from aqueous solution by lanthanum modified macroporous chelating resin. Korean J. Chem. Eng. 2020, 37, 766–775. [Google Scholar] [CrossRef]
- Xu, S.; Zhu, S.; Xiong, H. Phosphate Adsorption Removals by Five Synthesized Isomeric α-, β-, γ-FeOOH. Water Air Soil Pollut. 2022, 233, 454. [Google Scholar] [CrossRef]
- Nur, T.; Johir, M.; Loganathan, P.; Vigneswaran, S.; Kandasamy, J. Effectiveness of purolite A500PS and A520E ion exchange resins on the removal of nitrate and phosphate from synthetic water. Desalination Water Treat. 2012, 47, 50–58. [Google Scholar] [CrossRef]
- Sendrowski, A.; Boyer, T.H. Phosphate removal from urine using hybrid anion exchange resin. Desalination 2013, 322, 104–112. [Google Scholar] [CrossRef]
- Rafati, L.; Nabizadeh, R.; Mahvi, A.H.; Dehghani, M.H. Removal of phosphate from aqueous solutions by iron nano-particle resin Lewatit (FO36). Korean J. Chem. Eng. 2012, 29, 473–477. [Google Scholar] [CrossRef]
- Ren, J.; Li, N.; Zhao, L.; Ren, N. Enhanced adsorption of phosphate by loading nanosized ferric oxyhydroxide on anion resin. Front. Environ. Sci. Eng. 2014, 8, 531–538. [Google Scholar] [CrossRef]
- Das Gupta, M.; Loganathan, P.; Vigneswaran, S. Adsorptive Removal of Nitrate and Phosphate from Water by a Purolite Ion Exchange Resin and Hydrous Ferric Oxide Columns in Series. Sep. Sci. Technol. 2012, 47, 1785–1792. [Google Scholar] [CrossRef]
- Zhu, W.; Huang, X.; Zhang, Y.; Yin, Z.; Yang, Z.; Yang, W. Renewable molybdate complexes encapsulated in anion exchange resin for selective and durable removal of phosphate. Chin. Chem. Lett. 2021, 32, 3382–3386. [Google Scholar] [CrossRef]
- Bui, T.H.; Hong, S.P.; Kim, C.; Yoon, J. Performance analysis of hydrated Zr(IV) oxide nanoparticle-impregnated anion exchange resin for selective phosphate removal. J. Colloid Interface Sci. 2021, 586, 741–747. [Google Scholar] [CrossRef] [PubMed]
- Xu, H.; Zeng, W.; Li, S.; Wang, B.; Jia, Z.; Peng, Y. Hydrated zirconia-loaded resin for adsorptive removal of phosphate from wastewater. Colloids Surf. A Physicochem. Eng. Asp. 2020, 600, 124909. [Google Scholar] [CrossRef]
- Shen, Z.; Dong, X.; Shi, J.; Ma, Y.; Liu, D.; Fan, J. Simultaneous removal of nitrate/phosphate with bimetallic nanoparticles of Fe coupled with copper or nickel supported on chelating resin. Environ. Sci. Pollut. Res. 2019, 26, 16568–16576. [Google Scholar] [CrossRef] [PubMed]
- Machinsku, M.A. Fundamental Principles and Concepts of Ion Exchange: Environment Ion Exchange; CRC Press: Boca Raton, FL, USA, 2016; pp. 25–74. [Google Scholar]
- Xie, B.; Zuo, J.; Gan, L.; Liu, F.; Wang, K. Cation exchange resin supported nanoscale zero-valent iron for removal of phosphorus in rainwater runoff. Front. Environ. Sci. Eng. 2014, 8, 463–470. [Google Scholar] [CrossRef]
- Zhu, M.; Teng, Y.; Wu, D.; Zhu, J.; Zhang, Y.; Liu, Z. Development of Nanoscale Hydrated Titanium Oxides Support Anion Exchange Resin for Efficient Phosphate Removal from Water. Minerals 2022, 12, 1596. [Google Scholar] [CrossRef]
- Kawamoto, D.; Yamanishi, Y.; Ohashi, H.; Yonezu, K.; Honma, T.; Sugiyama, T.; Kobayashi, Y.; Okaue, Y.; Miyazaki, A.; Yokoyama, T. A new and practical Se(IV) removal method using Fe3+ type cation exchange resin. J. Hazard. Mater. 2019, 378, 120593. [Google Scholar] [CrossRef] [PubMed]
- Amrane, A.; Zarrabi, M.; Soori, M.M.; Sepehr, M.N.; Borji, S.; Ghaffari, H.R. Removal of phosphorus by ion-exchange resins: Equilibrium, kinetic and thermodynamic studies. Environ. Eng. Manag. J. 2014, 13, 891–903. [Google Scholar] [CrossRef]
- Eletta, O.; Ajayi, O.; Ogunleye, O.; Akpan, I. Adsorption of cyanide from aqueous solution using calcinated eggshells: Equilibrium and optimisation studies. J. Environ. Chem. Eng. 2016, 4, 1367–1375. [Google Scholar] [CrossRef]
- Xu, X.; Gao, B.; Wang, W.; Yue, Q.; Wang, Y.; Ni, S. Adsorption of phosphate from aqueous solutions onto modified wheat residue: Characteristics, kinetic and column studies. Colloids Surf. B Biointerfaces 2006, 70, 46–52. [Google Scholar] [CrossRef] [PubMed]
- Chen, X. Modeling of Experimental Adsorption Isotherm Data. Information 2015, 6, 14–22. [Google Scholar] [CrossRef] [Green Version]
- Nur, T. Nitrate, Phosphate and Fluoride Removal from Water Using Adsorption Process. Ph.D. Dissertation, University of Technology Sydney, Ultimo, Australia, 2014. [Google Scholar]
- Zamri, M.F.M.A.; Kamaruddin, M.A.; Yusoff, M.S.; Aziz, H.A.; Foo, K.Y. Semi-aerobic stabilized landfill leachate treatment by ion exchange resin: Isotherm and kinetic study. Appl. Water Sci. 2017, 7, 581–590. [Google Scholar] [CrossRef] [Green Version]
- Khalil, A.K.A.; Dweiri, F.; Almanassra, I.W.; Chatla, A.; Atieh, M.A. Mg-Al Layered Double Hydroxide Doped Activated Carbon Composites for Phosphate Removal from Synthetic Water: Adsorption and Thermodynamics Studies. Sustainability 2022, 14, 6991. [Google Scholar] [CrossRef]
- Azizian, S.; Haerifar, M.; Basiri-Parsa, J. Extended geometric method: A simple approach to derive adsorption rate constants of Langmuir–Freundlich kinetics. Chemosphere 2007, 68, 2040–2046. [Google Scholar] [CrossRef]
- Febrianto, J.; Kosasih, A.N.; Sunarso, J.; Ju, Y.-H.; Indraswati, N.; Ismadji, S. Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: A summary of recent studies. J. Hazard. Mater. 2009, 162, 616–645. [Google Scholar] [CrossRef]
- Bektaş, T.E.; Uğurluoğlu, B.K.; Tan, B. Phosphate removal by Ion exchange in batch mode. Water Pract. Technol. 2021, 16, 1343. [Google Scholar] [CrossRef]
- Iftekhar, S.; Ramasamy, D.L.; Srivastava, V.; Asif, M.B.; Sillanpää, M. Understanding the factors affecting the adsorption of Lanthanum using different adsorbents: A critical review. Chemosphere 2018, 204, 413–430. [Google Scholar] [CrossRef]
- Nyuyen, H.T. Phosphate Removal from Wastewater Using Slag and ion Exchange Resins. Master’s Dissertation, School of Civil and Environmental Engineering Faculty of Engineering & Information Technology University of Technology Sydney, Ultimo, Australia, 2017. [Google Scholar]
- Hayes, K.F.; Papelis, C.; Leckie, J.O. Modeling ionic strength effects on anion adsorption at hydrous oxide/solution interfaces. J. Colloid Interface Sci. 1988, 125, 717–726. [Google Scholar] [CrossRef]
- Hyland, C.; Ketterings, Q.; Dewing, D.; Stockin, K.; Czymmek, K.; Albrecht, G.; Geohring, L. Phosphorus Basics-The Phosphorus Cycle; Cornell University Coorperative Extension: Ithaca, NY, USA, 2005. [Google Scholar]
- Borchert, K.B.L.; Steinbach, C.; Reis, B.; Gerlach, N.; Zimmermann, P.; Schwarz, S.; Schwarz, D. Mesoporous Poly(melamine-co-formaldehyde) Particles for Efficient and Selective Phosphate and Sulfate Removal. Molecules 2021, 26, 6615. [Google Scholar] [CrossRef] [PubMed]
- Chitrakar, R.; Tezuka, S.; Sonoda, A.; Sakane, K.; Ooi, K.; Hirotsu, T. Phosphate adsorption on synthetic goethite and akaganeite. J. Colloid Interface Sci. 2006, 298, 602–608. [Google Scholar] [CrossRef]
- Tran, L.B.; Nguyen, T.T.; Le, T.T.; Thi, Q.A.N.; Phan, P.T.; Padungthon, S.; Nguyen, N.H. Synthesis of hydrated ferric oxide on cation exchange resin for phosphate and hardness removal in water. IOP Conf. Ser. Earth Environ. Sci. 2022, 964, 012032. [Google Scholar] [CrossRef]
- Boukemara, L.; Boukhalfa, C. Phosphate removal from aqueous solution by hydrous iron oxide freshly prepared effects of ph, iron concentration and competitive ions. Procedia Eng. 2012, 33, 163–167. [Google Scholar] [CrossRef] [Green Version]
- Kamoru, B.A.; Dominic, O.O. Equilibrium studies and optimization of phosphate adsorption from synthetic effluent using acid modified bio-sorbent. Am. J. Eng. Appl. Sci. 2017, 10, 980–991. [Google Scholar] [CrossRef] [Green Version]
- Zhang, L.; Zeng, Y.; Cheng, Z. Removal of heavy metal ions using chitosan and modified chitosan: A review. J. Mol. Liq. 2016, 214, 175–191. [Google Scholar] [CrossRef]
Adsorption Process for the Langmuir Model | |
---|---|
Irreversible | |
Linear | |
Favorable | |
Unfavorable |
Adsorption Process for the Freundlich Model | |
---|---|
Irreversible | |
Linear | |
Favorable | |
Unfavorable |
Isotherm Models | Isotherm Parameters | Values | |
---|---|---|---|
Langmuir Model | qm | 2.854 | 0.99 |
b | 0.164 | ||
Freundlich Model | n | 4.053 | 0.92 |
kf | −1.736 | ||
Temkin Model | B1 | 16.645 | 0.88 |
kt | −5.948 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Juntarasakul, O.; Rawangphai, M.; Phengsaart, T.; Maneeintr, K. Influences and Isotherm Models on Phosphorus Removal from Wastewater by Using Fe3+-Type UBK10 Cation Exchange Resin as Absorbent. Metals 2023, 13, 1166. https://doi.org/10.3390/met13071166
Juntarasakul O, Rawangphai M, Phengsaart T, Maneeintr K. Influences and Isotherm Models on Phosphorus Removal from Wastewater by Using Fe3+-Type UBK10 Cation Exchange Resin as Absorbent. Metals. 2023; 13(7):1166. https://doi.org/10.3390/met13071166
Chicago/Turabian StyleJuntarasakul, Onchanok, Monthicha Rawangphai, Theerayut Phengsaart, and Kreangkrai Maneeintr. 2023. "Influences and Isotherm Models on Phosphorus Removal from Wastewater by Using Fe3+-Type UBK10 Cation Exchange Resin as Absorbent" Metals 13, no. 7: 1166. https://doi.org/10.3390/met13071166