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Inorganics, Volume 13, Issue 9

2025 September - 34 articles

Cover Story: Polyoxovanadates can interact with proteins, affecting their function and influencing many biochemical processes. Here, a mixed-valence pentadecavanadate, [Cl@VV7VIV8O36]6− (V15), inhibits Ca2+-ATPase activity, showing a mixed-type inhibition. V15 remains stable in enzymatic and cellular media for days. Electrostatic potential maps of V15 and other POMs were correlated with their enzyme inhibition activity. The breast cancer luminal MCF-7 and triple-negative MDA-MB-231 cell lines were vulnerable to V15. This POV reduced MDA-MB-231 cell migration and changed cell morphology from fusiform to epithelial-like shape, which is associated with less aggressive behavior. In the fight against breast cancer by V15, the mechanism of cell death in MDA-MB-231 may occur through necroptosis, which could trigger a better inflammatory response. View this paper
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Articles (34)

  • Article
  • Open Access
788 Views
10 Pages

22 September 2025

Motivated by the strategy developed by Hicks and Dresselhaus in a quantum wire corresponding to a single-chain model with k2-dispersion, we study a one-dimensional double-chain model with two carriers of electrons and holes, characterized by k4-dispe...

  • Article
  • Open Access
806 Views
10 Pages

Fibroblast Response to Cyclo- and Organic Phosphate Solutions: A Cytotoxicity Study

  • Leonardo Antônio de Morais,
  • Alberto Carlos Botazzo Delbem,
  • Caio Sampaio,
  • Vitória Bittencourt de Aguiar,
  • Luigi Pedrini Guisso,
  • Lucas Fernando Oliveira Tomáz Ferraresso,
  • Juliano Pelim Pessan and
  • Thayse Yumi Hosida

18 September 2025

Although the anticaries properties of phosphate-based compounds have been extensively investigated in recent years, their potential cytotoxic effects remain underexplored. This study evaluated the cytotoxicity of solutions containing sodium trimetaph...

  • Article
  • Open Access
1 Citations
1,056 Views
18 Pages

Upconversion and Downconversion Luminescence of CaLaLiTeO6:Mn4+/Er3+ Phosphors for Dual-Mode Optical Thermometry and Anti-Counterfeiting Application

  • Zheng-Rong Xia,
  • Rong-Qing Li,
  • Fang-Fang Liu,
  • Yue Tong,
  • Qing-Hua Zheng,
  • Zhao-Yan Ping,
  • Wang Zhao,
  • Wei-Wei Zhou and
  • Ming-Jun Song

13 September 2025

Multifunctional phosphors that integrate optical temperature measurement and counterfeit detection capabilities have garnered considerable interest owing to their diverse application potential. In this study, novel CaLaLiTeO6:Mn4+/Er3+ phosphors were...

  • Review
  • Open Access
890 Views
10 Pages

12 September 2025

The [2Fe-2S] transcription activator SoxR, a member of the MerR family, functions as a bacterial stress response sensor. The response governed by SoxR is activated by the oxidation of the [2Fe-2S]. In this review, I describe functional differences be...

  • Article
  • Open Access
2 Citations
1,370 Views
24 Pages

Mixed-Valence Pentadecavanadate with Ca2+-ATPase Inhibition Potential and Anti-Breast Cancer Activity

  • Bianca R. Brito,
  • Heloísa de S. Camilo,
  • Anderson F. da Cruz,
  • Ronny R. Ribeiro,
  • Eduardo L. de Sá,
  • Carolina Camargo de Oliveira,
  • Gil Fraqueza,
  • Giseli Klassen,
  • Manuel Aureliano and
  • Giovana G. Nunes

12 September 2025

Polyoxovanadates are a subclass of polyoxometalates (POMs) known to interact with proteins and to present anticancer, antimicrobial, and antiviral activities. Herein, we aimed to pursue the study of the breast anticancer activity of a mixed-valence p...

  • Review
  • Open Access
2 Citations
2,252 Views
35 Pages

Advances in the Mechanism and Application of Nanoparticles in Concrete Property Modification

  • Huaming Li,
  • Yuhan Zhao,
  • Yan Zhao,
  • Min Zhang,
  • Yanan Niu and
  • Xi Cao

12 September 2025

Nanoparticles leverage their unique nanoscale effects to optimize concrete performance through synergistic multi-mechanism interactions. Core mechanisms include micro-filling effects (graded pore filling, optimized pore structure), nucleation (promot...

  • Article
  • Open Access
1,460 Views
23 Pages

11 September 2025

Precise remote temperature sensing at the micro- and nanoscale is a growing necessity in modern science and technology. We report a series of luminescent tris-acetylacetonate lanthanide complexes, Ln(acac)3(H2O)2 (Ln = Eu (1Eu), Tb (1Tb), Yb (1Yb));...

  • Article
  • Open Access
1 Citations
993 Views
21 Pages

Comparative Removal Properties of Sodium Magadiite and Its Protonic Form on Basic-Blue 41 from Contaminated Aqueous Solution

  • Thamer S. Alraddadi,
  • Mohd Gulfam Alam,
  • Rawan Al-Faze,
  • Saheed A. Popoola,
  • Souad Rakass,
  • Hicham Oudghiri Hassani and
  • Fethi Kooli

9 September 2025

Sodium magadiite (Na-Mgd) was hydrothermally prepared and converted to its protonic (H-Mgd) form by reaction with hydrochloric (HCl) solution. The obtained products were studied as adsorbents for basic blue 41 (BB-41) removal from polluted aqueous so...

  • Article
  • Open Access
1 Citations
1,520 Views
16 Pages

Prototypes of Highly Effective Stress Balancing AlN Interlayers in MOVPE GaN-on-Si (111)

  • Cai Liu,
  • Gaomin Li,
  • Hassanet Sodabanlu,
  • Masakazu Sugiyama and
  • Yoshiaki Nakano

7 September 2025

The GaN-on-Si virtual substrate is now an indispensable platform for the application of GaN in the fields of power devices, radio frequency, light-emitting devices, etc. Such applications are still in need of more effective stress balancing technique...

  • Article
  • Open Access
1 Citations
1,042 Views
16 Pages

5 September 2025

Mechanical energy is a plentiful, environmentally friendly, and sustainable energy source in the natural world. In this paper, ZnO tribocatalysts were synthesized using the hydrothermal and sol–gel methods. Under magnetic stirring, the catalyst...

  • Review
  • Open Access
1 Citations
2,160 Views
35 Pages

Research Progress on the Preparation, Modification, and Applications of g-C3N4 in Photocatalysis and Piezoelectric Photocatalysis

  • Mengyang Li,
  • Liuqing Yang,
  • Yizhe Song,
  • Hongru Hou,
  • Yujie Fang,
  • Yucheng Liu,
  • Lihao Xie and
  • Dingze Lu

5 September 2025

The metal-free polymeric semiconductor graphitic carbon nitride (g-C3N4) has emerged as a promising material for photocatalytic applications due to its responsiveness to visible light, adjustable electronic structure, and stability. This review syste...

  • Article
  • Open Access
1,243 Views
14 Pages

4 September 2025

The hydrogen sorption and electrochemical properties of the alloy Mg50Ni12.5Al12.5V12.5Fe12.5 synthesized by ball milling under the protected atmosphere of argon for 50 h in a planetary ball mill are investigated. The significantly fast rate of absor...

  • Review
  • Open Access
1 Citations
1,864 Views
28 Pages

Vanadium, a Promising Element for Cancer Treatment

  • Nelly López-Valdez,
  • Adriana Gonzalez-Villalva,
  • Marcela Rojas-Lemus,
  • Patricia Bizarro-Nevares,
  • Brenda Casarrubias-Tabarez,
  • María Eugenia Cervantes-Valencia,
  • Martha Ustarroz-Cano,
  • Gabriela Guerrero-Palomo,
  • Guadalupe Morales-Ricardes and
  • Teresa I. Fortoul
  • + 1 author

3 September 2025

In this century, cancer is one of the most important causes of death worldwide, and the need for the development of new treatment options is imperative. The use of metal-based compounds in cancer treatment has increased significantly due to certain p...

  • Article
  • Open Access
1 Citations
1,118 Views
13 Pages

Electrical Resistivity Control for Non-Volatile-Memory Electrodes Induced by Femtosecond Laser Irradiation of LaNiO3 Thin Films Produced by Pulsed Laser Deposition

  • Leonélio Cichetto,
  • Carlos Doñate-Buendía,
  • María Teresa Flores-Arias,
  • Maria Aymerich,
  • João Paulo de Campos da Costa,
  • Eloísa Cordoncillo-Cordoncillo,
  • João Paulo Pereira do Carmo,
  • Oswaldo Hideo Ando,
  • Héctor Beltrán Mir and
  • Adenilson José Chiquito
  • + 2 authors

2 September 2025

In this work, we investigated how the electrical resistivity of LaNiO3 thin films deposited on SrLaAlO4 (100), LaAlO3 (100), and MgO (100) single-crystal substrates by the pulsed laser deposition (PLD) technique can be controlled by femtosecond laser...

  • Article
  • Open Access
1,567 Views
18 Pages

1 September 2025

This work develops a novel phosphate-functionalized extraction resin (HEHEHP + Cyanex272)/SiO2-P via the vacuum impregnation method for efficient separation of light rare earth element impurities from lanthanum (La3+) in nitric medium through synergi...

  • Article
  • Open Access
1 Citations
1,170 Views
12 Pages

1 September 2025

Regulating the crystallization dynamics of perovskite films is key to improving the efficiency and operational stability of (FA0.83MA0.17Cs0.05)Pb(I0.85Br0.15)3 perovskite solar cells (PSCs). However, precise regulation of the crystallization process...

  • Review
  • Open Access
3 Citations
2,100 Views
25 Pages

1 September 2025

Metal–organic frameworks (MOFs) and their derivatives have emerged as promising candidates for separator engineering in lithium–sulfur batteries (LSBs). This is attributed to their structural tunability, high porosity, and chemical versat...

  • Article
  • Open Access
1,656 Views
21 Pages

Implementation of a Particle Swarm Optimization Algorithm with a Hooke’s Potential, to Obtain Cluster Structures of Carbon Atoms, and of Tungsten and Oxygen in the Ground State

  • Jesús Núñez,
  • Gustavo Liendo-Polanco,
  • Jesús Lezama,
  • Diego Venegas-Yazigi,
  • José Rengel,
  • Ulises Guevara,
  • Pablo Díaz,
  • Eduardo Cisternas,
  • Tamara González-Vega and
  • David Laroze
  • + 1 author

Particle Swarm Optimization (PSO) is a metaheuristic optimization technique based on population behavior, inspired by the movement of a flock of birds or a school of fish. In this method, particles move in a search space to find the global minimum of...

  • Article
  • Open Access
1 Citations
1,105 Views
11 Pages

Binuclear Gold(I) Complexes with a Potentially Tetradentate S,N,N,S Ligand

  • Suelen Ferreira Sucena,
  • Adelheid Hagenbach,
  • Chien Thang Pham and
  • Ulrich Abram

The potentially tetradentate SNNS ligand N,N′-(ethane-1,2-diyl)bis(N″-(diethylcarbamothioyl)benzimidamide, H2L, was synthesized by the reaction of ethylenediamine with two equivalents of the corresponding benzimide chloride. H2L readily r...

  • Article
  • Open Access
1,182 Views
13 Pages

A Rare Thermochromic Zwitterionic Nickel (II) Complex of the Bulky Alpha Ligand 1,2-Bis-(di-tbutylphosphinomethyl)Benzene

  • Ian R. Butler,
  • Peter N. Horton,
  • Simon J. Coles,
  • William Clegg,
  • Kevin M. Fortune,
  • Michael G. B. Drew and
  • Kamil Suwada

The reaction of the bulky ligand 1,2-bis-(di-tert-butylphosphinomethyl)benzene, 1 with [Ni(DME)Cl2], 3, DME = 1,2-dimethoxyethane, at room temperature over extended periods, affords the new blue Zwitterionic complex [2-(C6H4-CH2P(H)tBu2-1-(CH2PtBu2Ni...

  • Article
  • Open Access
1,091 Views
13 Pages

Fe Species Intercalation Confined by the Interlayer Environment of V2CTx MXene for Lithium-Ion Storage

  • Jiaxin Li,
  • Miao Liu,
  • Jiaming Li,
  • Wenjuan Han,
  • Shichong Xu,
  • Haibo Li and
  • Ming Lu

This work successfully achieved pre-intercalation of Fe species in V2CTx MXene through an annealing method. The crystallographic structure, microscopic morphology, and functional groups of the samples before and after pre-intercalation were analyzed...

  • Article
  • Open Access
1,525 Views
15 Pages

Tantalum nitride (TaN) is a typical transition metal nitride characterized by a wide range of tunable resistivity. Low-resistance TaN even exhibits a resistivity similar to that of metals. Given that electrical resistance influences secondary electro...

  • Article
  • Open Access
1,327 Views
18 Pages

Structural Water Accommodation in Co3O4: A Combined Neutron and Synchrotron Radiation Diffraction and DFT Study

  • Mariangela Longhi,
  • Mauro Coduri,
  • Paolo Ghigna,
  • Davide Ceresoli and
  • Marco Scavini

Spinels like Co3O4 have acquired relevance because of their photocatalytic, electrocatalytic, optical and magnetic properties. In this context, we investigated the defect structure evolution of compounds synthetized using the nitrate precursor method...

  • Article
  • Open Access
2 Citations
1,910 Views
19 Pages

Mixed-Ligand Copper(II) Complexes Derived from Pyridinecarbonitrile Precursors: Structural Features and Thermal Behavior

  • Amalija Golobič,
  • Matjaž Kristl,
  • Tinkara Marija Podnar,
  • Zvonko Jagličić and
  • Brina Dojer

Pyridinecarbonitriles (pyCN), also referred to as cyanopyridines, are promising ligands for the formation of pyridine-based coordination compounds due to their two different N-donor atoms, which enable versatile coordination modes. Copper(II) complex...

  • Review
  • Open Access
1 Citations
3,186 Views
48 Pages

Recent Advances in Carbon Dots-Based Photocatalysts for Water Treatment Applications

  • Adamantia Zourou,
  • Afrodite Ntziouni,
  • Alexandra Karagianni,
  • Niyaz Alizadeh,
  • Nikolaos Argirusis,
  • Maria Antoniadou,
  • Georgia Sourkouni,
  • Konstantinos V. Kordatos and
  • Christos Argirusis

Carbon dots (CDs), a rapidly emerging class of zero-dimensional (0-D) nanomaterials with small particle sizes (<10 nm), have garnered significant scientific interest owing to their exceptional physicochemical properties, non-toxicity, low-cost syn...

  • Article
  • Open Access
1 Citations
1,053 Views
15 Pages

A γ-Al2O3 and MgO/MgAl2O4 Fabricated via a Facile Pathway as Excellent Dye Eliminators from Water

  • Salah H. Elhory,
  • Mohamed R. Elamin,
  • Tarig G. Ibrahim,
  • Mutaz Salih,
  • Faisal K. Algethami,
  • Mohamed S. Eltoum and
  • Babiker Y. Abdulkhair

This study has successfully developed a practical and straightforward approach for synthesizing nanocomposites with excellent dye removal potential. The SEM inspection of γ-Al2O3 (γ-Al) and MgO/MgAl2O4 (Mg/MgAl) nanocomposite showed a mea...

  • Article
  • Open Access
1 Citations
1,473 Views
18 Pages

Structure and Electrochemical Performance of Glasses in the Li2O-B2O3-V2O5-MoO3 System

  • Margarita Milanova,
  • Xinhao Yang,
  • Pamela Vargas,
  • Nataly Carolina Rosero-Navarro,
  • Ruzha Harizanova,
  • Bojidar Jivov,
  • Lyubomir Aleksandrov,
  • Reni Iordanova,
  • Maya Shopska and
  • Savina Koleva

Applying the melt quenching method (cooling rate 101–102 K/s), new multicomponent vanadate glasses were synthesized, containing different amounts of MoO3 at the expense of B2O3 with the composition 20Li2O:(30 − x)B2O3:50V2O5:xMoO3, x = 10...

  • Article
  • Open Access
1 Citations
1,277 Views
13 Pages

A new series of luminescent Zn(II) complexes based on mono- and bis-imidazo[1,5-a]pyridine ligands was synthesized to investigate the correlation between structural modifications and photophysical behaviour. Systematic variations in substituent group...

  • Editorial
  • Open Access
1,279 Views
7 Pages

Metal-Based Compounds: Relevance for the Biomedical Field

  • Tamara Liana Topală,
  • Andreea Elena Bodoki and
  • Luminița Simona Oprean

In the field of drug design and the continuous search for new targeted and safe therapeutic options, metal complexes remain one of the most intensely studied classes of compounds, especially as potential antitumor and antibacterial agents [...]

  • Review
  • Open Access
1,454 Views
20 Pages

Design, Deposition, Performance Evaluation, and Modulation Analysis of Nanocoatings for Cutting Tools: A Review

  • Qi Xi,
  • Siqi Huang,
  • Jiang Chang,
  • Dong Wang,
  • Xiangdong Liu,
  • Nuan Wen,
  • Xi Cao and
  • Yuguang Lv

With the rapid development of advanced machining technologies such as high-speed cutting, dry cutting, and ultra-precision cutting, as well as the widespread application of various difficult-to-machine materials, the surface degradation problems such...

  • Article
  • Open Access
2 Citations
1,378 Views
11 Pages

Humans are being exposed to a variety of potentially toxic metal compounds through the diet and/or the intravenous administration of metal-containing medicinal drugs. The organomercurial thimerosal (THI) is a bactericidal that is present in vaccines,...

  • Article
  • Open Access
983 Views
12 Pages

Aqueous Singlet Oxygen Sensitization of Porphyrin-Embedded Silica Particles with Long-Term Stability

  • Pengcheng Zhu,
  • Zilong Guo,
  • Yulin Sha,
  • Yonghang Li,
  • Xiaoyu Zhang,
  • Yandong Han,
  • Wensheng Yang and
  • Xiaonan Ma

Aqueous singlet oxygen (1O2) sensitization is of high interest due to its wide application in bio-imaging and photodynamic therapy. For organic photosensitizers like porphyrin derivatives, surfactant-assisted micelles have been intensively explored f...

  • Review
  • Open Access
3 Citations
2,555 Views
25 Pages

Lithium Niobate Crystal Preparation, Properties, and Its Application in Electro-Optical Devices

  • Yan Zhang,
  • Xuefeng Xiao,
  • Jiayi Chen,
  • Han Zhang,
  • Yan Huang,
  • Jiashun Si,
  • Shuaijie Liang,
  • Qingyan Xu,
  • Huan Zhang and
  • Xuefeng Zhang
  • + 2 authors

Lithium Niobate (LiNbO3, LN) crystals are multifunctional optical materials with excellent electro-optical, acousto-optical, and nonlinear optical properties, and their broad spectral transparency makes them widely used in electro-optical modulators,...

  • Article
  • Open Access
2 Citations
1,091 Views
19 Pages

Bismuth-Doped Indium Oxide as a Promising Thermoelectric Material

  • Haitao Zhang,
  • Bo Feng,
  • Tongqiang Xiong,
  • Wenzheng Li,
  • Tong Tang,
  • Ruolin Ruan,
  • Peng Jin,
  • Guopeng Zhou,
  • Yang Zhang and
  • Xiaoqiong Zuo
  • + 3 authors

Bismuth (Bi)-doped indium oxide (In2O3) has emerged as a promising thermoelectric material due to its tunable electrical and thermal properties. This study investigates the effects of Bi-doping on the thermoelectric performance of In2O3, focusing on...

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Inorganics - ISSN 2304-6740