Reprint

Solvatochromic Probes and Their Applications in Molecular Interaction Studies—a Themed Issue to Honor Professor Dr. Christian Reichardt

Edited by
May 2024
320 pages
  • ISBN978-3-7258-1038-3 (Hardback)
  • ISBN978-3-7258-1037-6 (PDF)

This book is a reprint of the Special Issue Solvatochromic Probes and Their Applications in Molecular Interaction Studies—a Themed Issue to Honor Professor Dr. Christian Reichardt that was published in

Chemistry & Materials Science
Physical Sciences
Summary

Solvent polarity and hydrogen-bonding character play important roles in determining the magnitude of the solute-solvent interactions that control chemical reaction rates and equilibrium concentrations of chemically special species dissolved in both water and organic mono-solvents, as well as in binary (and higher-order multicomponent) solvent systems and molecularly organized aqueous-surfactant mixtures. Spectroscopic methods employing solvatochromic probe molecules have provided valuable information in the form of empirical solvent polarity and hydrogen-bonding scales that can be used to understand and predict the effect of binary solvent composition on solute solubility, equilibrium constants, and chemical reaction rates, to investigate preferential solvation in binary solvent mixtures, and to examine interfacial regions of aqueous micelles formed by ionic surfactants.This Special Issue contains five very informative review articles as well as ten original research papers and communications that report the synthesis of new solvatochromic probe molecules, measurement of new spectroscopic data, and development of new computational methods. The large range of topics covered illustrates that solvatochromic probe studies have been and still continue to be a very important and active research area. This Special Issue will be a valuable resource for researchers conducting solvatochromic probe studies.

Format
  • Hardback
License and Copyright
© 2024 by the authors; CC BY-NC-ND license
Keywords
Reichardt’s dye; ET(30) solvent polarity parameter; hydrogen bonding; solvatochromism; Abraham model; predictive modeling; surfactant micelles; molecular dynamics modeling; solvatochromic Reichardt’s dyes; hydration; acid–base indicators; apparent dissociation constants; electrical surface potential; deep eutectic solvent; Reichardt’s betaine dye 33; Glyceline; Lithium chloride; pyrene; solvent polarity scales; ET(30) scale; condensed phases; binary mixtures; solvent structure; paracetamol; solubility prediction; Reichardt indicator; binary mixtures; binary solvent mixtures; solvatochromism; solvatochromic probes; solvation models; ester hydrolysis; biopolymer dissolution; water; solvent properties; hydrogen-bonds; solubility; physicochemical properties of aqueous solutions; fluorescence; solvatochromism; DFT; solvent parameters; polarity; polarizability; ET(30); Catalan SPP; computational chemistry; cycloimmonium ylids; solvatochromic study; nature and strength of molecular interactions; excited-state dipole moment; Reichardts dye; solvatochromism; solvent mixtures; refractive index; solvent composition; average molar concentration; solvent effect on the spectra of organic compounds; solvatochromism of diphenylpolyenes; on the polarizability of diphenylpolyenes in Cl4C and in Cl2CH2; ionic liquids; protic ionic liquids; KAT; molecular dynamics; solvation; rubbers; plasticizers; solvatochromic dyes; Nile Red dye; Reichardt’s dye ET(30); Reichardt’s dye ET(33); compatibility; solubility parameter; Reichardt polarity; Kamlet—Taft parameters; green chemistry; solvent substitution; pharmaceuticals