Reprint

POSS-Based Polymers

Edited by
December 2019
310 pages
  • ISBN978-3-03921-994-0 (Paperback)
  • ISBN978-3-03921-995-7 (PDF)

This book is a reprint of the Special Issue POSS-Based Polymers that was published in

Chemistry & Materials Science
Engineering
Summary

The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.

Format
  • Paperback
License
© 2020 by the authors; CC BY license
Keywords
direct synthesis; grafting synthesis; mercapto-modified; bridged silsesquioxane; polyhedral oligomeric silsesquioxanes; POSS; composites; thermal stability; fluorescent sensors; nitroaromatic explosives; polyhedral oligomeric silsesquioxane-based ionic liquids; self-assembly behaviors; thiol-ene ‘click’ reaction; siloxane-silsesquioxane resins; polypropylene; thermogravimetry; cone calorimeter tests; flame-retardant mechanism; POSS; filler; low refractive material; thermal stability; fluoropolymer; polyhedral oligomeric silsesquioxane (POSS); double-decker-shaped silsesquioxane (DDSQ); polyimide; thermal stability; dielectric constant; poly(ε-caprolactone) nanocomposite; POSS nanoparticles; dispersion; morphology; thermal properties; mechanical properties; surface properties; phthalonitrile polymers; phthalonitrile-polyhedral oligomeric silsesquioxane copolymers; cyanate ester; blends; thermal properties; POSS-based copolymer; graphene oxide; flame retardant; epoxy resin; giant surfactant; thiol–ene “click” reaction; polyhedral oligomeric silsesquioxane (POSS); poly(ε-caprolactone); aqueous self-assembly; POSS; ridgid polyurethane foams; mechanical properties; cellular structure; bi-functional POSS; hydrophobic modification; thermoplastic polyurethane; mechanical performance; silsesquioxanes; optoelectronics; OLEDs; Monomethacryloxy POSS; lauryl methacrylate; polymerization kinetics; anchor effect; octa-ammonium POSS; sodium alginate; hydrogels; temperature responsiveness; Octavinyl-POSS; organic-inorganic crosslinking; Si@C anode; lithium ion battery; mechanism analysis; monodisperse; nanocomposites; damping; POSS; liquefied; benzoxazine; POSS; organic-inorganic hybrids; epoxy resin; thermal properties; flame retardancy; n/a