*Article* **Migration of Natural Hydrogen the**

**São**

**Frédéric-Victor Donzé 1,\*, Laurent Truche 1, Parisa Shekari Namin 1, Nicolas Lefeuvre 1 and Elena F. Bazarkina 2,3**

**Francisco**

1 University Grenoble Alpes, University Savoie Mont Blanc, CNRS, IRD, IFSTTAR, ISTerre, 38000 Grenoble, France; laurent.truche@univ-grenoble-alpes.fr (L.T.); parisa.shekari@gmail.com (P.S.N.); nicolas.lefeuvre@univ-grenoble-alpes.fr (N.L.)

**from**

**Brazil**

**Basin,**


Received: 22 July 2020; Accepted: 28 August 2020; Published: 2 September 2020

**Abstract:** Hydrogen gas is seeping from the sedimentary basin of São Franciso, Brazil. The seepages of H2 are accompanied by helium, whose isotopes reveal a strong crustal signature. Geophysical data indicates that this intra-cratonic basin is characterized by (i) a relatively high geothermal gradient, (ii) deep faults delineating a horst and graben structure and affecting the entire sedimentary sequence, (iii) archean to paleoproterozoïc basements enriched in radiogenic elements and displaying mafic and ultramafic units, and (iv) a possible karstic reservoir located 400 m below the surface. The high geothermal gradient could be due to a thin lithosphere enriched in radiogenic elements, which can also contribute to a massive radiolysis process of water at depth, releasing a significant amount of H2. Alternatively, ultramafic rocks that may have generated H2 during their serpentinization are also documented in the basement. The seismic profiles show that the faults seen at the surface are deeply rooted in the basement, and can drain deep fluids to shallow depths in a short time scale. The carbonate reservoirs within the Bambuí group which forms the main part of the sedimentary layers, are crossed by the fault system and represent good candidates for temporary H2 accumulation zones. The formation by chemical dissolution of sinkholes located at 400 m depth might explain the presence of sub-circular depressions seen at the surface. These sinkholes might control the migration of gas from temporary storage reservoirs in the upper layer of the Bambuí formation to the surface. The fluxes of H2 escaping out of these structures, which have been recently documented, are discussed in light of the newly developed H2 production model in the Precambrian continental crust.

**Keywords:** native hydrogen; H2 exploration; gas seeps; H2 venting; radiolysis; serpentinization; draining faults; intra-cratonic basin
