*Article* **Dyes of a Shadow Theatre: Investigating** *Tholu Bommalu* **Indian Puppets through a Highly Sensitive Multi-Spectroscopic Approach**

**Alessandro Ciccola 1, Ilaria Serafini 1,\*, Giulia D'Agostino 2, Belinda Giambra 3, Adele Bosi 1,4, Francesca Ripanti 5, Alessandro Nucara 5, Paolo Postorino 5, Roberta Curini <sup>1</sup> and Maurizio Bruno <sup>2</sup>**


**Abstract:** *Tholu Bommalu* are typical leather puppets of the traditional Indian shadow theatre. Two of these objects are part of a collection in the International Puppets Museum "Antonio Pasqualino" (Palermo, Sicily, Italy), which can count on one hundred-seventy-three of artifacts. These Indian puppets were investigated to obtain information related to the use of dyes for their manufacturing through a multi-technical approach exploiting the combination of highly sensitive spectroscopic techniques. Wet cotton stubbons were used to entrap small particles of dyes on the fibers from the art objects for the consequent analyses. Visible Light Micro-Reflectance spectroscopy was employed for the preliminary identification of the molecular class of dyes directly on the swabs, while Surface Enhanced Raman Scattering allowed the identification of the specific dye. Several synthetic dyes belonging to different typologies of coloring compounds were identified. The study resulted in an interesting overview of dyes used in recent *Tholu Bommalata* manufacturing through the combination of micro-invasive techniques directly on the sampling substrate.

**Keywords:** reflectance spectroscopy; SERS; synthetic dyes; *Tholu Bommalata*; puppets
