*Article* **Hydrochemical Characteristics of Arsenic in Shallow Groundwater in Various Unconsolided Sediment Aquifers: A Case Study in Hetao Basin in Inner Mongolia, China**

**Zizhao Cai 1,2, Lingxia Liu 2,3,\*, Wei Xu <sup>4</sup> , Ping Wu <sup>5</sup> and Chuan Lu <sup>2</sup>**


**Abstract:** This study focused on the entire Hetao Basin, which can fall into four hydrogeological units, the Houtao Plain, Sanhuhe Plain, Hubao Plain, and South Bank Plain of the Yellow River, all of which are under different geological and environmental conditions. To systematically investigate the hydrochemical characteristics and spatial distribution of high-As groundwater (As > 10 µg/L), 974 samples were collected from shallow groundwater. As indicated from the results, high-As groundwater had an extensive distribution, and its spatial distribution in the four hydrogeological units exhibited significant variability. Three concentrated distribution areas were reported with high-As groundwater, which were all in the discharge areas of groundwater, and the arsenic contents in the groundwater were found to exceed 50 µg/L. The hydrochemical types of high-As groundwater in the HT Plain and the SHH Plain consisted of HCO<sup>3</sup> SO<sup>4</sup> ·Cl for anions and Na for cations, while those in the other two plains included HCO<sup>3</sup> for anions as well as Na·Mg·Ca for cations. According to the pH values, the groundwater was weakly alkaline in the areas with high-As groundwater, and arsenic primarily existed as arsenite. Furthermore, high-As groundwater in the Hetao Basin was characterized by high contents of Fe (mean value of 2.77 mg/L) and HCO<sup>3</sup> − (mean value of 460 mg/L) and a low relative concentration of SO<sup>4</sup> <sup>2</sup><sup>−</sup> (average value of 310 mg/L). This study did not identify any significant correlation between groundwater arsenic and other ions (e.g., Fe2+, Fe3+, HCO3−, SO<sup>4</sup> <sup>2</sup>−, NO<sup>2</sup> − and NO<sup>3</sup> −) in the entire Hetao Basin over a wide range of hydrogeological units. The results remained unchanged after the four hydrogeological units were analyzed. The special sedimentary environment evolution of the Hetao Basin was found as the prerequisite for the formation of higharsenic groundwater. Furthermore, groundwater runoff conditions and hydrogeochemical processes in the basin were indicated as the factors controlling the formation of high-arsenic groundwater.

**Keywords:** high-As groundwater; shallow groundwater; geological environment; geochemistry; correlation; Hetao Basin
