*Review* **Utilization of CO2-Available Organocatalysts for Reactions with Industrially Important Epoxides**

**Tomáš Weidlich \* and Barbora Kamenická**

Chemical Technology Group, Institute of Environmental and Chemical Engineering, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic; barbora.kamenicka@student.upce.cz **\*** Correspondence: tomas.weidlich@upce.cz; Tel.: +420-46-603-8049

**Abstract:** Recent knowledge in chemistry has enabled the material utilization of greenhouse gas (CO2) for the production of organic carbonates using mild reaction conditions. Organic carbonates, especially cyclic carbonates, are applicable as green solvents, electrolytes in batteries, feedstock for fine chemicals and monomers for polycarbonate production. This review summarizes new developments in the ring opening of epoxides with subsequent CO2-based formation of cyclic carbonates. The review highlights recent and major developments for sustainable CO2 conversion from 2000 to the end of 2021 abstracted by Web of Science. The syntheses of epoxides, especially from bio-based raw materials, will be summarized, such as the types of raw material (vegetable oils or their esters) and the reaction conditions. The aim of this review is also to summarize and to compare the types of homogeneous non-metallic catalysts. The three reaction mechanisms for cyclic carbonate formation are presented, namely activation of the epoxide ring, CO2 activation and dual activation. Usually most effective catalysts described in the literature consist of powerful sources of nucleophile such as onium salt, of hydrogen bond donors and of tertiary amines used to combine epoxide activation for facile epoxide ring opening and CO2 activation for the subsequent smooth addition reaction and ring closure. The most active catalytic systems are capable of activating even internal epoxides such as epoxidized unsaturated fatty acid derivatives for the cycloaddition of CO2 under relatively mild conditions. In case of terminal epoxides such as epichlorohydrin, the effective utilization of diluted sources of CO2 such as flue gas is possible using the most active organocatalysts even at ambient pressure.

**Keywords:** cycloaddition; ionic liquid; deep eutectic solvents; onium salt; homogeneous catalysts
