*Proceeding Paper* **Physico-Chemical Modelling of Chloride Migration in Cement-Based Materials Considering Electrode Processes †**

**Zine-Eddine Kribes, Rachid Cherif \* and Abdelkarim Aït-Mokhtar**

**\*** Correspondence: rachid.cherif@univ-lr.fr

† Presented at the 10th MATBUD'2023 Scientific-Technical Conference "Building Materials Engineering and Innovative Sustainable Materials", Cracow, Poland, 19–21 April 2023.

**Abstract:** A multispecies model for chloride migration in cementitious materials was proposed. The model is applied to simulate chloride migration in the concrete submitted to the chloride migration test, considering the electrode processes. These processes are very rarely integrated into the literature, despite their impact on the chloride migration and the electroneutrality in the pore solution of the material. The generation of OH<sup>−</sup> in the cathode and H<sup>+</sup> in the anode allows for the monitoring of the electroneutrality. The modelling considers all the ions of the pore solution. Ion fluxes are calculated using Nernst–Planck equation. The Langmuir model is used to simulate the chloride isotherms. The thermodynamic equilibrium in the material is considered, which reflects the liquid– solid interactions during the migration. The ion profiles with and without considering the electrode processes are presented.

**Keywords:** durability; chloride migration; modelling; multispecies interactions; electrode processes
