*Article* **Origin of Disseminated Gold-Sulfide Mineralization from Proximal Alteration in Orogenic Gold Deposits in the Central Sector of the Yana–Kolyma Metallogenic Belt, NE Russia**

**Valery Yurievich Fridovsky 1,\*, Lena Idenenovna Polufuntikova 1,2 and Maxim Vasilievich Kudrin <sup>1</sup>**


**\*** Correspondence: fridovsky@diamond.ysn.ru; Tel.: +7-4112-33-58-72

**Abstract:** The Yana–Kolyma metallogenic belt, NE Russia, is a world-class gold belt with resources numbering ~8300 tons of gold. The belt is localized in the central part of the Verkhoyansk–Kolyma orogen, formed by a collage of diverse terranes. The Tithonian-to-Early-Cretaceous orogenic gold deposits are hosted in a sequence of Permian–Triassic and Jurassic clastic rocks and altered Late Jurassic andesite, dacite, granodiorite, trachyandesite, and trachybasalt dykes. High-fineness gold (800–900‰) in quartz veins and invisible gold in disseminated arsenian pyrite-3 (Py3) and arsenopyrite-1 (Apy1) are present in ores. Here, we present new data about microtextures; the chemical composition and stable sulfur isotopes of auriferous pyrite-3 and arsenopyrite-1 from proximal alterations in sediment-hosted (Malo–Taryn, Badran, Khangalas); and intrusion-hosted (V'yun, Shumniy) orogenic Au deposits in the central sector of the Yana–Kolyma metallogenic belt to better constrain the ore-forming process and tracking their evolution. Detailed petrography defined the following generations of pyrite: syn-sedimentary/diagenetic Py1, metamorphic Py2 and hydrothermal Py3, and Apy1. Hydrothermal Py3 and Apy1 are localized in the proximal pyrite–arsenopyrite–sericite– carbonate–quartz alteration in ore zones and make a major contribution to the economic value of the veinlet-disseminated mineralization with "invisible" gold in the orogenic deposits of the Yana– Kolyma metallogenic belt. Electron microprobe analysis (EMPA) of Py3 in both types of deposits shows concentrations of As (up to 3.16 wt%), Co, Ni, Cu, Sb, and Pb. Py3 in intrusion-hosted orogenic gold deposits reveals elevated concentrations of Co (up to 0.87 wt%), Ni (up to 3.52 wt%), and Cu (up to 2.31 wt%). The identified negative correlation between S and As indicates an isomorphic substitution of sulfur by As1−. Py3 from igneous rocks is characterized by a high degree of correlation for the pairs Fe2+<sup>→</sup> Co2+ and Fe2+<sup>→</sup> Ni2+. For hydrothermal Apy1, Co (up to 0.27 wt%), Ni (up to 0.30 wt%), Cu (up to 0.04 wt%), and Sb (up to 0.76 wt%) are typomorphic. According to atomic absorption spectrometry, the concentration of Au in Py3 reaches 159.5 ppm; in Apy1, it reaches 168.5 ppm. The determination of the precise site of the invisible gold within Py3 and Apy1 showed the predominance of solid-solution Au<sup>+</sup> in the crystal lattice. The values of δ <sup>34</sup>S in Py3 and Apy1 (from <sup>−</sup>6.4 to +5.6‰, mean value of about +0.6‰), both from sediment-hosted and from intrusion-hosted deposits, display a relatively narrow range and are characteristic of the hydrothermal ore stage. Our analytical results showed no systematic differences between the chemical and stable sulfur isotope compositions of both auriferous pyrite-3 and arsenopyrite-1 from the proximal alteration in sediment-hosted (Malo–Taryn, Badran, Khangalas) and intrusion-hosted (V'yun, Shumniy) orogenic Au deposits, indicating that the primary source of sulfur, gold, and mineralizing fluids was likely from subcrustal and metamorphic systems in the Late-Jurassic-to-Early-Cretaceous Verkhoyansk–Kolyma orogen.

**Keywords:** disseminated Au-sulfide mineralization; orogenic gold deposits; Yana–Kolyma metallogenic belt; sulfide microtextures and mineralogy; stable sulfur isotopes; mineral chemistry; source of gold

**Citation:** Fridovsky, V.Y.; Polufuntikova, L.I.; Kudrin, M.V. Origin of Disseminated Gold-Sulfide Mineralization from Proximal Alteration in Orogenic Gold Deposits in the Central Sector of the Yana–Kolyma Metallogenic Belt, NE Russia. *Minerals* **2023**, *13*, 394. https://doi.org/10.3390/ min13030394

Academic Editor: David Banks

Received: 18 January 2023 Revised: 1 March 2023 Accepted: 7 March 2023 Published: 11 March 2023

**Copyright:** © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).

#### **1. Introduction**

Orogenic gold deposits (OGDs) are an economically important source of gold in the world. According to estimates [1], the relative significance of OGDs (including intrusionrelated OGDs) in past production and known reserves and resources is 32%. In addition, Goldfarb R.J. et al. [2] indicated that most (45%) of gold deposits worldwide containing more than 1 Moz of gold belong to orogenic gold deposits, much more than other types of deposits.

The Yana–Kolyma metallogenic belt (YKMB), NE Russia, is known for its large bulktonnage OGD at Natalka (1500 t Au), Degdekan (400 t Au), Pavlik (169 t Au), Drazhnoe (50 t Au), and other sites [3–6]. Similar Paleozoic-to-Mesozoic major deposits of this type are also known in Russia (Sukhoi Log), Uzbekistan (Muruntau), Kyrgyzstan (Kumtor), Australia (Bendigo, Ballarat), USA (Juneau, Treadwell), China (Jiaodong), and in other countries [5–8]. The endowment of the YKMB is ~8300 tons of gold [3,6]. However, the YKMB's main gold production came from placer deposits, sourced from OGDs.

Gold in the orogenic gold deposits of the Yana–Kolyma metallogenic belt is mainly found as "visible" gold grains in quartz veins/veinlets and rarely as inclusions in the pyrite and arsenopyrite of the proximal alteration envelopes in the host rock. In disseminated pyrite and arsenopyrite (up to 5–8%) in carbonaceous clastic rocks with pyrite–arsenopyrite– sericite–carbonate-quartz alterations, there is also "invisible" gold, which is in the form of a solid solution or nanoparticles [6,9–12]. Currently, the greatest economic value in the YKMB is Au-quartz veins and/or the Au-sulfide–quartz-veinlet-disseminated styles of mineralization. The reserves and resources of bulk YKMB deposits can be estimated in the Au-sulfide–quartz-veinlet-disseminated type of mineralization [4,13]. The geological, mineralogical, geochemical, and geochronological characteristics of the vein and veinlet mineralization in the YKMB are described in detail elsewhere (see [14–24] and references therein), but the study of disseminated mineralization and its contribution to the overall gold content of orogenic deposits in the central sector of the YKMB is in its infancy [11,12,25,26]. In addition, there are not many detailed investigations of the mineralization processes.

Fridovsky V.Y. et al. [11,26] and Kudrin M.V. et al. [12] showed that pyrite grew in clastic rocks in the central sector of the YKMB from sedimentation due to late metamorphism and finally formed together with arsenopyrite from hydrothermal fluids. Recent geochemical studies [11,12,26] revealed different concentrations of trace elements (As, Co, Ni, Cu, Pb, and Sb) in pyrite generations. However, the origin and sources of ore-forming fluids and metals in gold-bearing, disseminated mineralization from proximal alterations in sediment-hosted and intrusion-hosted OGDs in the YKMB remain unclear. Several genetic models of gold-bearing quartz veins and disseminated ores in the YKMB have been discussed: (a) magmatic–hydrothermal [17]; (b) formation from metamorphic fluids and boiling during uplift and decompression [22]; (c) and juvenile and metamorphic sources [23,27]. This creates serious difficulties in generating representative models and identifying potential targets.

The microtextures and mineral chemistry of pyrite and arsenopyrite are very useful for studying the processes of Au mineralization (e.g., [11,12,28–38]). These minerals can incorporate various metals and semi-metals (As, Co, Ni, Cu, Pb, Sb, etc.), showing the chemical evolution of gold ores [11,15,22,39–48] and many others. It is equally important that gold is either in solid solutions or micro- to nano-sized inclusions (e.g., [11,12,48,49]). Our understanding of the sources of ore-forming metals and fluids and the processes that form OGDs are also constrained by sulfur isotope analyses on sulfide minerals that are co-genetic with gold [11,15,20,21,23,26,39,43,50–56]. Additionally, sulfur isotope analyses allow us to assess the role of intrusions adjacent to hosting orogenic gold deposits in the providing metals (e.g., [43]).

Here, we present new data about microtextures and analyses of the chemical composition and stable sulfur isotopes of auriferous pyrite and arsenopyrite from proximal alterations in sediment-hosted and intrusion-hosted orogenic gold deposits in the central

sector of the YKMB. New characteristics and information about the origin and gold grade in disseminated mineralization from proximal alterations can contribute to the further development of prospecting programs and provide important data for the reassessment of known deposits and the discovery of new deposits in the central sector of the YKMB. Observations of microtextures using scanning electron microscopy (SEM) were combined with major and trace-element analyses performed using electron probe microanalysis (EPMA) and the sulfur isotope data of pyrite and arsenopyrite. This information was used to understand ore-forming events and to reinterpret the source of gold and the hydrothermal fluid-flow processes that formed the sediment-hosted and intrusion-hosted OGD orogenic Au systems in the YKMB.

#### **2. Geological and Metallogenic Background**

#### *2.1. Regional Geological Setting*

The Yana–Kolyma metallogenic belt is localized in the central part of the Verkhoyansk– Kolyma orogen, formed by a collage of diverse terranes [57]. Parfenov L.M. and Kuzmin M.I. [57], Parfenov L.M. [58], Parfenov L.M. et al. [59], Toro J. et al. [60], and Nokleberg W.J. et al. [61] provided detailed descriptions of terranes. The majority of OGDs in the YKMB are located in Upper Permian, Triassic, and Lower Jurassic clastic rocks and, less often, in Late Jurassic dykes of mafic, intermediate, and felsic composition, as well as granitoids of the small intrusions complexes in the Kular–Nera terrane, the adjacent Verkhoyansk fold-and-thrust belt, and the Polousny-Debin terrane [6,14,23,57,62] (Figure 1). Clastic rocks are represented by proximal and distal sediments in the eastern margin of the Siberian craton, metamorphosed under conditions no higher than the greenschist facies [57]. The rocks are deformed into the linear folds of the northwestern strike, fold-parallel faults, and transverse/oblique faults. The Adycha–Taryn and Charky–Indigirka faults are the longest faults, having an NW strike and limiting the terranes of the eastern margin of the Siberian craton. There are also cross-cutting faults in the NE and WE strikes.

Clastic rocks are intruded by granitoids from the main (Kolyma) batholitic belt (154–144 Ma, zircon, U-Pb SHRIMP-RG [63], SHRIMP-II [64]), volcanic rocks and intrusive rocks with intermediate and felsic compositions from the Tas–Kystabyt belt (151–148 Ma, zircon, U-Pb SHRIMP-II [64,65]), and Late-Jurassic-to-Early-Cretaceous granitoids from small massifs and dykes with basic-to-felsic compositions (151–143 Ma, zircon, U-Pb SHRIMP II [62,66]). Based on the geodynamic setting, structural geometry and control, host rocks, alterations, ore mineralogy, geochemistry, isotopes, and geochronological characteristics, the studied deposits have been classified as orogenic [5,6,21,23,67,68]. The morphological styles of the ore bodies are veins, breccias, and veinlet-disseminated. The deposits are localized mainly near the Adycha–Taryn and Charky–Indigirka thrusts and subsidiary faults.

As reviewed by [13,18,19,21,23,69], the ore formation of OGDs in the central sector of the YKMB occurred at pressures ranging from 1.2 to 0.25 kbar and temperatures ranging from 300 to 200 ◦C. Ore-forming fluids contained a dilute water–salt solution (salt concentration 0.5–9.3 wt% NaCl-eq.), carbon dioxide (8.5–15 mol%), and methane (up to 1 mol%). The hydrothermal fluid contained the following major micro-components: As, B, Sb, Zn, Fe, and Cu. The parameters and composition of the ore-forming fluids in the studied deposits are typical of Phanerozoic OGDs [43].

The combined structural observations of the central sector of the Yana–Kolyma metallogenic belt [57,70], including deposit-scale observations [20,21,67–69,71], new Ar-Ar and Re-Os dating of minerals from ore veins [21,27], and the U-Pb dating of igneous rocks [62,66], allowed us to decipher the sequence of deformation events and their connection with OGDs [67,68]. A three-stage deformation history is proposed. D1 compression led to the formation of folds and faults in the northwest strike. When these progressive deformations were completed at the turn of the Late-Jurassic-to-Early-Cretaceous and at the beginning of the Early Cretaceous, the formation of OGDs in the YKMB took place during accretion–collision events on the eastern margin of the Siberian craton and

in the Verkhoyansk–Kolyma orogen. D2 sinistral strike-slip and D3 dextral strike-slip movements activated faults in the NW strike. The youngest events are a reflection of superimposed subduction–accretion processes at the rear of the active Cretaceous East Asian continental margin. Verkhoyansk–Kolyma orogen. D2 sinistral strike‐slip and D3 dextral strike‐slip move‐ ments activated faults in the NW strike. The youngest events are a reflection of superim‐ posed subduction–accretion processes at the rear of the active Cretaceous East Asian con‐ tinental margin.

during accretion–collision events on the eastern margin of the Siberian craton and in the

*Minerals* **2023**, *13*, x 4 of 41

**Figure 1.** Geology of the central part of the Verkhoyansk–Kolyma orogen with main tectonic units, Jurassic–Cretaceous magmatism, and studied deposits. Faults: AT—Adycha–Taryn, CI—Charky– Indigirka, D—Darpir, Ch—Chibagalakh. **Figure 1.** Geology of the central part of the Verkhoyansk–Kolyma orogen with main tectonic units, Jurassic–Cretaceous magmatism, and studied deposits. Faults: AT—Adycha–Taryn, CI—Charky– Indigirka, D—Darpir, Ch—Chibagalakh.

#### *2.2. Ore Deposit Geology 2.2. Ore Deposit Geology*

The studied sediment‐hosted (Malo–Taryn, Badran, Khangalas) and intrusion‐ hosted (V'yun, Shumnyi) gold deposits are typical OGDs with vein–veinlet quartz and disseminated mineralization with proximal pyrite–arsenopyrite–sericite–carbonate– quartz alterations controlled by faults [6,21,67,72,73]. Geological sketches of individual deposits are shown in Figures 2 and 3, and the common characteristics of the studied OGDs are presented in Table 1. Below is a brief geological description and information about the mineral composition of these ore deposits. The studied sediment-hosted (Malo–Taryn, Badran, Khangalas) and intrusion-hosted (V'yun, Shumnyi) gold deposits are typical OGDs with vein–veinlet quartz and disseminated mineralization with proximal pyrite–arsenopyrite–sericite–carbonate–quartz alterations controlled by faults [6,21,67,72,73]. Geological sketches of individual deposits are shown in Figures 2 and 3, and the common characteristics of the studied OGDs are presented in Table 1. Below is a brief geological description and information about the mineral composition of these ore deposits.


**Table 1.** General characteristics of the studied OGDs, central YKMB.

Qz—quartz, Ccp—chalcopyrite, Sp—sphalerite, Ab—albite, Ttr—tetrahedrite, Ser—sericite, Sbn—stibnite. \* Mineral associations: Au-Bi—gold–bismuth, Py-Apy-Qz metasomatic—pyrite–arsenopyrite–quartz metasomatic, Py-Apy-Qz vein—pyrite–arsenopyrite–quartz vein, Au-polysulfide-Qz—gold–polysulfide–quartz, Au-Sb gold–stibnite, sulfosalt–carbonate-Qz—sulfosalt–carbonate–quartz, Ag-Sb—silver–stibnite, Apy-Py-carbonate-Qz—arsenopyrite–pyrite–carbonate–quartz, Ccp-Sp-Ab-Qz—chalcopyrite–sphalerite–albite–quartz, Ttr-Ser-Qz tetrahedrite–sericite–quartz, Ag-Qz—silver–quartz, Sbn-carbonate-Qz—stibnite–carbonate–quartz, fahlore-Qz fahlore–quartz, Sbn-Qz—stibnite–quartz.

#### 2.2.1. Geology and Mineralization of the Sediment-Hosted Orogenic Gold Deposits

Information about the geology, magmatism, and mineral composition of the Malo– Taryn deposit is provided in [27,62,76,77,84,85,87,88]. The deposit is located on the left bank of the Malo–Taryn River, 100 km southeast of the settlement of Ust-Nera. Tectonically, the deposit is localized along the border of the Verkhoyansk fold-and-thrust belt and the Kular-Nera terrane, in the axial part of the Malo–Taryn branch of the Adycha–Taryn fault. The host clastic Upper Triassic rocks (Figure 2A) are deformed into folds of several generations. The early ones associate with the NW-trending thrusts, and the later ones associate with sinistral and dextral movements along the reactivated NW thrusts. In the Malo–Taryn fault zone, the stratified rocks dip at 30◦–55◦ to 60◦–70◦ , including overturned beddings. The Early Cretaceous Samyr (144.5–143 Ma, zircon, U-Pb SHRIMP-II [62]), and Kurdat (141–137 Ma, biotite, <sup>40</sup>Ar/39Ar [89]) granitoid massifs of the Tas–Kystabyt magmatic belt are located NW of the deposit at the intersection of the Malo–Taryn fault and the Kurdat transverse fault zone. Dykes of trachybasalts (145–160 Ma, Rb-Sr, rock [84,85]) are usually localized in the ore zones of the NW and NNW strikes. Their thickness is 0.1–2.0 m, and their lengths are up to the first tens of meters. The age of polychronous mineralization was constrained by different methods (40Ar/39Ar, K-Ar, Re-Os) at 148 to 126 Ma [21,27,87,90]. The ore bodies of the deposit occur along the faults of the NW and NS strikes with a dip to the SW and W at 30◦ to 85◦ . They are up to 40 m thick and can be traced 6 km along the strike.

The geological structure and mineral composition of the vein bodies and their localization at the Badran deposit have been studied in detail [74,91–94]. Underground gold mining at the deposit started in 1984. The deposit is located on the left bank of the Indigirka River, 130 km west of Ust-Nera in Upper Triassic clastic rocks (Figure 2B). The deposit is localized along the Badran–Egelyakh fault, up to 30 m wide, traceable for a distance of more than 5 km, and more than 1.2 km downdip. The northwestern and southeastern segments strike west–east and dip at 50◦–60◦ . In the central segment, the fault dips at 24◦–30◦ to the northeast. The quartz veins/veinlets and proximal pyrite–arsenopyrite–sericite–carbonate– quartz alteration are gold-bearing. The thickness of the quartz veins varies from tens of centimeters up to 4–5 m, with a length of up to 200 m. The gold content in altered rocks is at first grams per ton, reaching several kilograms per ton in the veins.

The structure and structural–tectonic setting of the formation and localization, as well as the mineralogical–geochemical and isotope–geochemical characteristics of the Khangalas deposit are described in [12,68,95–97]. The deposit is located on the left bank of the Nera River, 135 km southeast of the Ust-Nera settlement. Structurally, the deposit is confined to the Dvoinaya anticline (Figure 2C). The core of the anticline is composed mainly of Upper Permian sandstones; the limbs consist of Lower and Middle Triassic siltstones and mudstones. The Khangalas fault of the NW strike is the major ore-controlling fault. The ore bodies are represented by five extended (up to 1400 m) mineralized faults with quartz–carbonate veins/veinlets and pyrite–arsenopyrite-disseminated mineralization in the proximal alteration. The thickness of the faults is up to 32 m; their dip varies from SW to S and SE at 30◦–50◦ to 70◦–80◦ [67]. Re-Os data on the native gold from the quartz vein of the deposit showed that it was 137 million years old [27]. The gold content in the alteration is up to 5.29 ppm Au, with a mean of 0.73 ppm.

#### 2.2.2. Geology and Mineralization of the Intrusion-Hosted Orogenic Gold Deposits

Detailed geological, mineralogical, and geochemical characteristics for the *V'yun and Shumnyi deposits* are provided in [66,75,78,98]. Underground gold mining at the V'yun deposit started in 2020. The V'yun and Shumnyi deposits are located in the upper reaches of the Adycha River. The tectonic structure of the deposit is controlled by longitudinal NW fold-and-thrust structures and transverse NE faults activated by late strike-slip faults (Figures 4 and 5). The Upper Triassic clastic rocks are crumpled into linear isoclinal and compressed asymmetric folds in the northwest strike. Mineralization is localized in the Late Jurassic dykes of trachybasalts, andesites, trachyandesites, dacites, and granodiorites

(151–145 Ma, zircon, U–Pb SHRIMP-II [66]) and faults in the NE strike (Figure 4). Dykes are 2 to 8 m thick, extending for more than 2 km. The style of ore bodies is vein–stockwork and disseminated. In the veins and stockworks, the main minerals are quartz and carbonate made up of, at most, 1–3% sulfides, represented mostly by arsenopyrite. Rarer sulfides and sulfosalts are pyrite, galena, sphalerite, chalcopyrite, tetrahedrite, and argentotetrahedrite. There are insignificant quantities of bournonite and antimony. Gold in the veins is free and characterized by high grades of up to several hundred grams per tonne. The disseminated gold–sulfide mineralization is localized both in the fault zones up to several tens of meters thick and in dykes. The main ore minerals in them are auriferous pyrite and arsenopyrite. The host alteration is sericite–chlorite–quartz in composition. *Minerals* **2023**, *13*, x 7 of 41

**Figure 2.** Geologic map and simplified cross‐sections of the sediment‐hosted OGDs, central YKMB: (**A**) Malo–Taryn; (**B**) Badran; (**C**) Khangalas. **Figure 2.** Geologic map and simplified cross-sections of the sediment-hosted OGDs, central YKMB: (**A**) Malo–Taryn; (**B**) Badran; (**C**) Khangalas.

#### *2.3. Mineral Composition of the Deposits and Mineralization Types*

There are several types of mineralization at the Malo–Taryn, Badran, Khangalas, V'yun, and Shumnyi deposits: gold–quartz/gold–sulfide–quartz, stibnite, and silver– stibnite (Table 2) [23]. Gold–quartz mineralization developed in quartz veins and veinlets; gold is native here. Disseminated mineralization with "invisible" gold is localized in the proximal arsenopyrite–pyrite–sericite–carbonate–quartz alteration. Berthierite–stibnite and silver–stibnite mineralization is superimposed on OGDs sporadically.

*Gold–quartz/gold–sulfide–quartz-type* mineralization is characterized by a number of successively alternating paragenetic associations: arsenopyrite–pyrite–quartz alteration, pyritearsenopyrite–quartz veins, Au-polysulfide-quartz, and sulfosalt–carbonate [18–21,23]. The number of ore minerals takes up 1–3% or, less often, up to 5%. A detailed mineralogical– geochemical and isotopic characterization of the disseminated Py-Apy-Qz paragenesis is provided in Section 4 of this article.

The pyrite–arsenopyrite–quartz vein association is composed of coarse- and mediumgrained subhedral and anhedral milky-white quartz (85–95%), carbonate, chlorite, albite, and sericite. The texture of the veins is massive, banded (Figure 6A–C), and breccia-like

**Figure 3.** Ore bodies of (**A**,**D**,**G**,**J**) Malo–Taryn; (**B**,**E**,**H**,**K**) Badran; and (**C**,**F**,**I**,**L**) Khangalas orogenic gold deposits: (**A**–**C**) veins; (**D**–**F**) veinlets; (**G**–**J**,**I**,**L**) veinlet‐disseminated; (**K**) disseminated. Abbre‐

viations: Qz—quartz, Py—pyrite, Apy—arsenopyrite.

(Figure 6D,E); the structure is hypidiomorphoblastic (subhedral–blastic structure), and small veinlets are characterized by a comb structure. Pyrite4 and arsenopyrite2 occur in the form of individual crystals up to 1–2 mm in size; veinlets up to 1 mm in thickness; and nests up to 3–4 cm in size (Figure 6I) or, less often, 50–70 cm or more.

Pyrite4 and arsenopyrite2 form intergrowths and mutual inclusions (Figure 7A). The primary euhedral grains of early sulfides are cataclazed and corroded. Native gold, quartz, and sulfides from late mineral paragenesis occur in microcracks in arsenopyrite2 (Figure 7B,C) (Au-Qz-polysulfide and sulfosalt–carbonate). **Figure 2.** Geologic map and simplified cross‐sections of the sediment‐hosted OGDs, central YKMB: (**A**) Malo–Taryn; (**B**) Badran; (**C**) Khangalas.

*Minerals* **2023**, *13*, x 7 of 41

**Figure 3.** Ore bodies of (**A**,**D**,**G**,**J**) Malo–Taryn; (**B**,**E**,**H**,**K**) Badran; and (**C**,**F**,**I**,**L**) Khangalas orogenic gold deposits: (**A**–**C**) veins; (**D**–**F**) veinlets; (**G**–**J**,**I**,**L**) veinlet‐disseminated; (**K**) disseminated. Abbre‐ viations: Qz—quartz, Py—pyrite, Apy—arsenopyrite. **Figure 3.** Ore bodies of (**A**,**D**,**G**,**J**) Malo–Taryn; (**B**,**E**,**H**,**K**) Badran; and (**C**,**F**,**I**,**L**) Khangalas orogenic gold deposits: (**A**–**C**) veins; (**D**–**F**) veinlets; (**G**–**J**,**I**,**L**) veinlet-disseminated; (**K**) disseminated. Abbreviations: Qz—quartz, Py—pyrite, Apy—arsenopyrite.

2.2.2. Geology and Mineralization of the Intrusion‐Hosted Orogenic Gold Deposits

Detailed geological, mineralogical, and geochemical characteristics for the *V'yun and Shumnyi deposits* are provided in [66,75,78,98]. Underground gold mining at the V'yun deposit started in 2020. The V'yun and Shumnyi deposits are located in the upper reaches of the Adycha River. The tectonic structure of the deposit is controlled by longitudinal NW fold‐and‐thrust structures and transverse NE faults activated by late strike‐slip faults (Figures 4 and 5). The Upper Triassic clastic rocks are crumpled into linear isoclinal and compressed asymmetric folds in the northwest strike. Mineralization is localized in the Late Jurassic dykes of trachybasalts, andesites, trachyandesites, dacites, and granodiorites (151–145 Ma, zircon, U–Pb SHRIMP‐II [66]) and faults in the NE strike (Figure 4). Dykes are 2 to 8 m thick, extending for more than 2 km. The style of ore bodies is vein–stockwork and disseminated. In the veins and stockworks, the main minerals are quartz and car‐ bonate made up of, at most, 1–3% sulfides, represented mostly by arsenopyrite. Rarer sul‐ fides and sulfosalts are pyrite, galena, sphalerite, chalcopyrite, tetrahedrite, and argento‐ tetrahedrite. There are insignificant quantities of bournonite and antimony. Gold in the veins is free and characterized by high grades of up to several hundred grams per tonne. The disseminated gold–sulfide mineralization is localized both in the fault zones up to several tens of meters thick and in dykes. The main ore minerals in them are auriferous pyrite and arsenopyrite. The host alteration is sericite–chlorite–quartz in composition.

**Figure 4.** Geologic map and simplified cross‐sections of the intrusion‐hosted OGDs, central YKMB: (**A**) V'yun and (**B**) Shumnyi. **Figure 4.** Geologic map and simplified cross-sections of the intrusion-hosted OGDs, central YKMB: (**A**) V'yun and (**B**) Shumnyi. *Minerals* **2023**, *13*, x 9 of 41

**Figure 5.** Photographs of the ore bodies in the intrusion‐hosted OGDs, central YKMB: (**A**,**C**) V'yun; (**B**) Shumnyi; (**D**) stereogram of the veins, bedding, and dykes. Abbreviations: S0—bedding, Qz quartz vein, D—dyke. Structural data were plotted on the upper hemisphere of the Wulff stereo‐ graphic net. **Figure 5.** Photographs of the ore bodies in the intrusion-hosted OGDs, central YKMB: (**A**,**C**) V'yun; (**B**) Shumnyi; (**D**) stereogram of the veins, bedding, and dykes. Abbreviations: S0—bedding, Qz quartz vein, D—dyke. Structural data were plotted on the upper hemisphere of the Wulff stereographic net.

There are several types of mineralization at the Malo–Taryn, Badran, Khangalas, V'yun, and Shumnyi deposits: gold–quartz/gold–sulfide–quartz, stibnite, and silver–stib‐

*Gold–quartz/gold–sulfide–quartz‐type* mineralization is characterized by a number of successively alternating paragenetic associations: arsenopyrite–pyrite–quartz alteration, pyrite‐arsenopyrite–quartz veins, Au‐polysulfide‐quartz, and sulfosalt–carbonate [18– 21,23]. The number of ore minerals takes up 1–3% or, less often, up to 5%. A detailed min‐ eralogical–geochemical and isotopic characterization of the disseminated Py‐Apy‐Qz par‐

The pyrite–arsenopyrite–quartz vein association is composed of coarse‐ and me‐ dium‐grained subhedral and anhedral milky‐white quartz (85–95%), carbonate, chlorite, albite, and sericite. The texture of the veins is massive, banded (Figure 6A–C), and breccia‐ like (Figure 6D,E); the structure is hypidiomorphoblastic (subhedral–blastic structure), and small veinlets are characterized by a comb structure. Pyrite4 and arsenopyrite2 occur in the form of individual crystals up to 1–2 mm in size; veinlets up to 1 mm in thickness;

Pyrite4 and arsenopyrite2 form intergrowths and mutual inclusions (Figure 7A). The primary euhedral grains of early sulfides are cataclazed and corroded. Native gold, quartz, and sulfides from late mineral paragenesis occur in microcracks in arsenopyrite2

gold is native here. Disseminated mineralization with "invisible" gold is localized in the proximal arsenopyrite–pyrite–sericite–carbonate–quartz alteration. Berthierite–stibnite

and silver–stibnite mineralization is superimposed on OGDs sporadically.

and nests up to 3–4 cm in size (Figure 6I) or, less often, 50–70 cm or more.

(Figure 7B,C) (Au‐Qz‐polysulfide and sulfosalt–carbonate).

agenesis is provided in Section 4 of this article.

*2.3. Mineral Composition of the Deposits and Mineralization Types* 


*Minerals* **2023**, *13*, x 10 of 41

*Minerals* **2023**, *13*, x 10 of 41

clusters and fills cracks andvoids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

in the selvagesvein bodiesand near clay interlayers (Figure 6F), and itforms nest‐like clusters and fills cracks and voids in minerals in earlier associations(Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H).

The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

in the selvages of vein bodies and near clay interlayers(Figure 6F), and it forms nest‐likeclusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is acementing materialand forms comb structures (Figure 6H). The amount of carbonate in the veins varies from5 to 15%. Fahlores are represented by

in the selvagesof vein bodies and near clay interlayers (Figure 6F), and it forms nest‐like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and formscomb structures (Figure 6H).

in the selvages of vein bodies and near clay interlayers (Figure 6F), and it forms nest‐like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

clusters and fills cracksand voids inminerals inearlier associations (Figure6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure6H). The amount of carbonatein the veins varies from 5 to15%. Fahlores are represented by

in the selvages of vein bodies and near clay interlayers (Figure 6F), and it forms nest‐likeclusters and fills cracks and voids inminerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

In thesulfosalt–carbonateassociation, the leading mineral is carbonate. Itis localized in the selvages vein bodiesandnear clay interlayers (Figure 6F), andit forms nest‐like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the

In the sulfosalt–carbonate association, the leading mineral is carbonate. It is localized in the selvages of vein bodies and near clay interlayers (Figure 6F), and it forms nest‐like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H).

clusters and fills cracks and voids in minerals inearlier associations (Figure 6G).In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

In the sulfosalt–carbonate association, the leading mineralis carbonate. It is localized in the selvages of vein bodies and near clay interlayers(Figure6F), and itforms nest‐like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the

In the sulfosalt–carbonate association, theleading mineral is carbonate. It is localized in the selvages of vein bodies and near clay interlayers (Figure 6F), and it forms nest‐like

fineness of native gold is 800–900‰.

fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate inthe veins varies from 5 to 15%. Fahlores are represented by

clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

In the sulfosalt–carbonate association, the leading mineralis carbonate. It is localized in the selvages of vein bodies and near clay interlayers (Figure 6F), and it forms nest‐like

In the sulfosalt–carbonate association, the leading mineral is carbonate. It is localized

clusters and fills cracks and voids inminerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate inthe veins varies from 5 to 15%. Fahlores are represented by

in the selvages of veinbodies and near clay interlayers(Figure 6F), and it forms nest‐like clusters and fills cracks andvoids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H).

clusters and fills cracksand voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonateis a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

In the sulfosalt–carbonate association, the leading mineral is carbonate. It is localized in the selvages of vein bodies and near clay interlayers (Figure 6F), and it forms nest‐like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

Commonnative gold developed in interstitial quartzgrains or filled microcracks in earlier minerals. The shape of thegoldparticles is mainly elongated–lumpy (Figure 7G), lumpy– branched, and dendritic (Figure 7H), fractions of a millimeter to the first millimeter. The

clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fracturedareas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

in the selvages of veinbodies andnear clay interlayers (Figure 6F), and it forms nest‐like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fracturedareas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

clusters and fills cracks andvoids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonateis a cementing material and forms comb structures (Figure 6H). Theamount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by

In the sulfosalt–carbonate association, the leading mineral is carbonate. It is localized in the selvages of vein bodies and near clay interlayers (Figure 6F), and it forms nest-like clusters and fills cracks and voids in minerals in earlier associations (Figure 6G). In the fractured areas, carbonate is a cementing material and forms comb structures (Figure 6H). The amount of carbonate in the veins varies from 5 to 15%. Fahlores are represented by tetrahedrite (Figure 7I). They form anhedral grains in quartz veins in association with galena, sphalerite, and chalcopyrite. Carbonate minerals contain acicular crystals and microaggregates of boulangerite and jamesonite. At the Badran and V'yun deposits, bournonite is observed in intergrowths with galena (Figure 7J). *Minerals* **2023**, *13*, x 11 of 41 tetrahedrite (Figure 7I). They form anhedral grains in quartz veins in association with ga‐ lena, sphalerite, and chalcopyrite. Carbonate minerals contain acicular crystals and mi‐ croaggregates of boulangerite and jamesonite. At the Badran and V'yun deposits,

*Berthierite–stibnite-type* mineralization can be identified at the Malo–Taryn and Badran deposits [21,94]. Minerals occur in the form of individual aggregates and thin veinlets (up to 2–3 cm) in the gold–quartz veins. The superposition of late berthierite–stibnite mineralization on earlier gold–quartz/gold–sulfide–quartz mineralization leads to the development of corrosion (Figure 7K). The intensively cataclazed quartz experienced volumetric dissolution, and small (1–2 mm) euhedral crystals of regenerative quartz formed (Figure 7L) [20]. bournonite is observed in intergrowths with galena (Figure 7J). *Berthierite–stibnite‐type* mineralization can be identified at the Malo–Taryn and Badran deposits [21,94]. Minerals occurin the form of individual aggregates and thin vein‐ lets (up to 2–3 cm) in the gold–quartz veins. The superposition of late berthierite–stibnite mineralization on earlier gold–quartz/gold–sulfide–quartz mineralization leads to the de‐ velopment of corrosion (Figure 7K). The intensively cataclazed quartz experienced volu‐ metric dissolution, and small (1–2 mm) euhedral crystals of regenerative quartz formed (Figure 7L) [20].

**Figure 6.** Photographs showing representative mineral assemblages and textures of the vein miner‐ als in the studied OGDs, central YKMB: (**A**) Milky‐white quartz with a massive texture; thread‐like interlayers of siltstone composition separate the bands of subhedral quartz from the anhedral quartz; (**B**) banded texture of quartz vein; (**C**) Alternation of banded and massive quartz; (**D**) brec‐ cia‐like texture of quartz vein, milky‐white quartz forms overgrowth textures around the rock frag‐ ments; (**E**) spherulitic and cryptogranular quartz cement vein quartz (Qz1); (**F**) Fe‐dolomite forms a rhythmically‐banded texture in a quartz vein; (**G**) veinlets and nests of intensely oxidized dolomite– ankerite; (**H**) quartz with siltstone xenoliths overgrown with combed dolomite–ankerite with Mg‐ siderite inclusions; (**I**) in milky‐white quartz, a nest of arsenopyrite with dendrite‐like gold in cracks. Abbreviations: Gn—galena, Sp—sphalerite, Apy—arsenopyrite, Dol—dolomite, Ank—ankerite, Sd—siderite. *Ag‐stibnite‐type* mineralization is represented by spherulitic, cryptogranular, or col‐ **Figure 6.** Photographs showing representative mineral assemblages and textures of the vein minerals in the studied OGDs, central YKMB: (**A**) Milky-white quartz with a massive texture; thread-like interlayers of siltstone composition separate the bands of subhedral quartz from the anhedral quartz; (**B**) banded texture of quartz vein; (**C**) Alternation of banded and massive quartz; (**D**) breccia-like texture of quartz vein, milky-white quartz forms overgrowth textures around the rock fragments; (**E**) spherulitic and cryptogranular quartz cement vein quartz (Qz1); (**F**) Fe-dolomite forms a rhythmically-banded texture in a quartz vein; (**G**) veinlets and nests of intensely oxidized dolomite–ankerite; (**H**) quartz with siltstone xenoliths overgrown with combed dolomite–ankerite with Mg-siderite inclusions; (**I**) in milky-white quartz, a nest of arsenopyrite with dendrite-like gold in cracks. Abbreviations: Gn—galena, Sp—sphalerite, Apy—arsenopyrite, Dol—dolomite, Ank—ankerite, Sd—siderite.

lomorphic–nodular quartz with a slight dissemination of fine‐grained pyrite with ele‐ vated concentrations of Au and Ag and individual crystals of arsenopyrite with an Sb admixture of up to 2–3%. Tetrahedrite, argentite, and acanthite are typomorphic minerals

*Ag-stibnite-type* mineralization is represented by spherulitic, cryptogranular, or collomorphic–nodular quartz with a slight dissemination of fine-grained pyrite with elevated concentrations of Au and Ag and individual crystals of arsenopyrite with an Sb admixture of up to 2–3%. Tetrahedrite, argentite, and acanthite are typomorphic minerals [21,94]. This epithermal mineralization is the latest in the YKMB [99]. It occurs at the Malo–Taryn, Badran, and Khangalas deposits. *Minerals* **2023**, *13*, x 12 of 41 [21,94]. This epithermal mineralization is the latest in the YKMB [99]. It occurs at the Malo– Taryn, Badran, and Khangalas deposits.

**Figure 7.** Photomicrographs showing the representative mineral assemblages and microtextures of the ore minerals of each vein‐type ((**A**)—backscattered electron images, (**B**–**L**)—reflected light) of the studied OGDs, central YKMB: (**A**) pyrite and arsenopyrite intergrowths in a quartz vein; (**B**) cataclase structures in arsenopyrite grains; cracks are healed with quartz in the Au‐polysulfide‐ quartz paragenesis; (**C**) in cataclazed arsenopyrite aggregate, native gold developed along cracks; (**D**) sphalerite–galena–chalcopyrite aggregate with an allotriomorphic blastic structure. Chalcopy‐ rite emulsions in sphalerite aggregates with a solid solution decomposition structure; (**E**) microtex‐ ture from corrosion and substitution of pyrite (Py) crystal caused by minerals of the Au‐polysulfide‐ quartz paragenesis; (**G**) native elongated lumpy gold in interstitial quartz grains; (**H**) lumpy‐ branched native gold in microcracks; (**I**) tetrahedrite aggregates intergrown with arsenopyrite; (**J**) intergrowths of burnonite with minerals from the Au‐polysulfide‐quartz paragenesis; (**K**) microtex‐ tures from berthierite corrosion due to pyrite crystals; (**L**) euhedral crystals made of regenerative quartz in stibnite aggregates. Abbreviations: Gn—galena, Sp—sphalerite, Ccp—chalcopyrite, Apy—arsenopyrite, Ttr—tetrahedrite, Bnn—burnonite, Brt—berthierite, Sbn—stibnite. **Figure 7.** Photomicrographs showing the representative mineral assemblages and microtextures of the ore minerals of each vein-type ((**A**)—backscattered electron images, (**B**–**L**)—reflected light) of the studied OGDs, central YKMB: (**A**) pyrite and arsenopyrite intergrowths in a quartz vein; (**B**) cataclase structures in arsenopyrite grains; cracks are healed with quartz in the Au-polysulfidequartz paragenesis; (**C**) in cataclazed arsenopyrite aggregate, native gold developed along cracks; (**D**) sphalerite–galena–chalcopyrite aggregate with an allotriomorphic blastic structure. Chalcopyrite emulsions in sphalerite aggregates with a solid solution decomposition structure; (**E**) microtexture from corrosion and substitution of pyrite (Py) crystal caused by minerals of the Au-polysulfide-quartz paragenesis; (**G**) native elongated lumpy gold in interstitial quartz grains; (**H**) lumpy-branched native gold in microcracks; (**I**) tetrahedrite aggregates intergrown with arsenopyrite; (**J**) intergrowths of burnonite with minerals from the Au-polysulfide-quartz paragenesis; (**K**) microtextures from berthierite corrosion due to pyrite crystals; (**L**) euhedral crystals made of regenerative quartz in stibnite aggregates. Abbreviations: Gn—galena, Sp—sphalerite, Ccp—chalcopyrite, Apy—arsenopyrite, Ttr—tetrahedrite, Bnn—burnonite, Brt—berthierite, Sbn—stibnite.

#### **3. Materials and Analytical Methods**

#### *3.1. Sample Preparation*

Samples for mineralogical–geochemical and isotope–geochemical studies were collected from natural outcrops and the walls and dumps of surfaces and underground workings; 62 thin sections and 36 polished mounts were prepared for mineralogical and microtextural studies. For mineralogical, microtextural, and geochemical studies of disseminated sulfide mineralization, thick polished sections (74 in total) and epoxy-mounted grains (100 sulfide grains in 10 mounts) were prepared.

The microtextural and paragenetic features of the sulfides were studied using a Karl Zeiss Axio M1 optical microscope (Carl Zeiss AG, Jena, Germany) at the Diamond and Precious Metal Geology Institute, Siberian Branch, Russian Academy of Sciences, Yakutsk, Russia. The qualitative chemical and mineral compositions of the samples were studied with the use of a JEOL JSM-6480LV scanning electron microscope (SEM analysis, JEOL Ltd., Tokyo, Japan) equipped with an Energy 350 Oxford energy dispersive spectrometer (20 kV, 1 nA, beam diameter 1 µm) at the Diamond and Precious Metal Geology Institute, Siberian Branch, Russian Academy of Sciences (Yakutsk, Russia).

#### *3.2. Electron Probe Micro-Analyzer (EPMA)*

The major element compositions of pyrite and arsenopyrite were determined with standard X-ray spectral analysis on a Camebax-Micro microanalyzer (Cameca, Courbevoie, France) at the Diamond and Precious Metal Geology Institute, Siberian Branch, Russian Academy of Sciences (Yakutsk, Russia). The analytical conditions were as follows: accelerating voltage of 20 kV; beam current of 25 nA; measurement time of 10 s; K series for Fe, Co, Ni, Cu, and S; M series for Au and Pb; L series for As and Sb.; and wavelength-dispersive spectrometer (WDS) with LiF, PET, and TAP crystals. The standards used were FeS<sup>2</sup> for Fe and S, FeAsS for As, Fe-Ni-Co alloy for Co, Ni, Au-Ag alloy for Au and Ag, CuSbS<sup>2</sup> for Sb, and PbS for Pb. The detection limit was 0.01%. In each grain, 3 measurements were made: core, midway between core and rim, and rim. In total, 422 analyses were used, of which 293 were used for the first time and 129 were taken from earlier studies [11,12].

### *3.3. Determination of Gold and Silver Content*

The Au and Ag contents were determined using powdery monomineral samples via atomic absorption spectrometry (AAS) with electrothermal atomization on a spectrometer MGA-1000 (LUMEX, St. Petersburg, Russia) at the Diamond and Precious Metal Geology Institute, Siberian Branch, Russian Academy of Sciences (Yakutsk, Russia). The detection limit for gold is 0.02 ppm. In total, 71 analyses were used, of which 34 were used for the first time and 37 taken were from earlier studies [11,12].

#### *3.4. S isotope Analysis*

The sulfur isotope composition was analyzed at the Laboratory of Stable Isotopes, Center for Collective Use, Far East Geological Institute, Far East Branch, Russian Academy of Sciences (Vladivostok, Russia). For sulfur isotope analysis of sulfides from the Malo– Taryn, Khangalas, V'yun, and Shumnyi deposits, we used pure sulfide fractions (54 samples) selected by hand and ground into powder. In total, 75 analyses were used, of which 30 were used for the first time and 45 were from earlier studies [11,12]. The analysis was performed using a Flash EA-1112 elemental analyzer (Thermo Scientific, Dreieich, Germany) in the S configuration according to the standard protocol for converting sulfur from sulfide to SO2. The sample preparation for mass spectrometric sulfur isotope analysis from the Badran deposit (20 samples) was carried out with the local laser method using an NWR Femto femtosecond laser ablation complex [100,101]. The <sup>34</sup>S/32S isotope ratios were measured on a MAT-253 mass spectrometer (Thermo Fisher Scientific, Germany) in continuous He flux mode. The measurements were performed against a standard laboratory gas, SO2, calibrated according to international standards IAEA-S-1, IAEA-S-2, IAEA-S-3, and NBS-

127. The results of the δ <sup>34</sup>S measurements are provided in reference to the international VCDT standard. Determination accuracy: δ <sup>34</sup><sup>S</sup> <sup>±</sup> 0.2‰ (1σ).

#### **4. Results**

#### *4.1. Pyrite and Arsenopyrite Types and Textures*

Our [12,26,78] and other works [10,102], beyond any known orebodies and in alteration of the OGDs in the central YKMB, have identified several generations of pyrite (Py1, Py2, Py3) and arsenopyrite (Apy1); a summary of the common textures and pyrite–arsenopyrite classifications for the central YKMB is shown in Table 3. Pyrite is the main and most common ore mineral in sedimentary strata, with diagenetic (Py1), metamorphic (Py2), and metasomatic (Py3) pyrites identified.

**Table 3.** Summary of common textures and pyrite–arsenopyrite classification OGDs Central YKMB.


#### 4.1.1. Syn-Sedimentary/Diagenetic Pyrite (Py1)

The earliest form of pyrite is observed in the Upper Paleozoic clastic sedimentary rocks (Figure 8). Pyrite1 is represented by dust-like and fine-grained spherical (framboidal) particles (Figure 8A) and nodular aggregates ranging in size from 10 to 100 microns (Figure 8B). They are composed of pyrite microcrystals with a zonal structure in a carboniferous–silicon matrix. Nodular aggregates often have a porous texture, which suggests the formation of minerals as a result of rapid crystallization [33]. In pyrite1, marcasite can be observed as anhedral-to-colloform grains. The location of Py1 follows the primary sedimentary texture of rocks (Figure 8C).

#### 4.1.2. Metamorphic Pyrite2

Pyrite2 can be most widely observed in the zones of regional faults (Adycha–Taryn, Charky–Indigirka, Chai–Yureya). It is represented by crystals with subhedral and euhedral shapes, ranging in size from 2–3 microns to 2–4 mm, which form dissemination (Figure 9A), intergrowths, nests (Figure 9B), and thin veinlets (Figure 9C). In individual crystals and aggregates, a xenomorphic porous central part can be observed, formed during diagenesis, surrounded by an idiomorphic shell of metamorphogenic Py2 (Figure 9).

*Minerals* **2023**, *13*, x 15 of 41

**Figure 8.** Microtexture of diagenetic Py1 (reflected light) OGDs, central YKMB: (**A**) framboids and zonal structure; (**B**) nodular aggregate pyrite and marcasite as anhedral‐to‐colloform grains; (**C**) lay‐ ered arrangement of Py1 crystals in siltstone. **Figure 8.** Microtexture of diagenetic Py1 (reflected light) OGDs, central YKMB: (**A**) framboids and zonal structure; (**B**) nodular aggregate pyrite and marcasite as anhedral-to-colloform grains; (**C**) layered arrangement of Py1 crystals in siltstone. ure 9A), intergrowths, nests (Figure 9B), and thin veinlets (Figure 9C). In individual crys‐ tals and aggregates, a xenomorphic porous central part can be observed, formed during diagenesis, surrounded by an idiomorphic shell of metamorphogenic Py2 (Figure 9).

**Figure 9.** Microtextures of metamorphic pyrite2 (reflected light) OGDs, central YKMB: (**A**) inter‐ growths of cubic pyrite; (**B**) accumulation of crystals and pyrite intergrowths. The central part of the individual grains is corroded; (**C**) micro‐veinlets of pyrite along cracks. **Figure 9.** Microtextures of metamorphic pyrite2 (reflected light) OGDs, central YKMB: (**A**) intergrowths of cubic pyrite; (**B**) accumulation of crystals and pyrite intergrowths. The central part of the individual grains is corroded; (**C**) micro-veinlets of pyrite along cracks.

#### 4.1.3. Hydrothermal Pyrite3 and Arsenopyrite1 from Proximal Alteration 4.1.3. Hydrothermal Pyrite3 and Arsenopyrite1 from Proximal Alteration

**Figure 9.** Microtextures of metamorphic pyrite2 (reflected light) OGDs, central YKMB: (**A**) inter‐ growths of cubic pyrite; (**B**) accumulation of crystals and pyrite intergrowths. The central part of the individual grains is corroded; (**C**) micro‐veinlets of pyrite along cracks. 4.1.3. Hydrothermal Pyrite3 and Arsenopyrite1 from Proximal Alteration Sulfides (Py3 and Apy1) are localized in the proximal sericite‐carbonate–quartz al‐ teration and make a major contribution to the economic value of the veinlet‐disseminated mineralization containing "invisible" gold. A proximal alteration is characterized by var‐ ious types of transformation in rocks. Sericitization, carbonation, and silicification devel‐ oped in the clastic rocks (sandstones, siltstones). Carbonation, chloritization, and argilli‐ zation manifested in the dykes of basic, intermediate, and felsic composition. The hydro‐ thermal alteration of both clastic and intrusive rocks involves pyrite–arsenopyrite sulfi‐ dation. Py3 is cubic and pentagondodecahedral in shape and often has a zonal structure (Figure 10). The second typomorphic mineral of the association is arsenopyrite (Apy1) with a short‐prismatic and pseudopyramidal form (Figure 10A). The size of Apy1 crystals ranges from fractions up to 1–1.5 mm or, less often, up to 2–3 mm. Microinclusions in the minerals of the Au‐polysulfide‐quartz and sulfosalt–carbonate associations can be noted Sulfides (Py3 and Apy1) are localized in the proximal sericite‐carbonate–quartz al‐ teration and make a major contribution to the economic value of the veinlet‐disseminated mineralization containing "invisible" gold. A proximal alteration is characterized by var‐ ious types of transformation in rocks. Sericitization, carbonation, and silicification devel‐ oped in the clastic rocks (sandstones, siltstones). Carbonation, chloritization, and argilli‐ zation manifested in the dykes of basic, intermediate, and felsic composition. The hydro‐ thermal alteration of both clastic and intrusive rocks involves pyrite–arsenopyrite sulfi‐ dation. Py3 is cubic and pentagondodecahedral in shape and often has a zonal structure (Figure 10).The second typomorphic mineral of the association is arsenopyrite (Apy1) with a short‐prismatic and pseudopyramidal form (Figure 10A). The size of Apy1 crystals ranges from fractions up to 1–1.5 mm or, less often, up to 2–3 mm. Microinclusions in the minerals of the Au‐polysulfide‐quartz and sulfosalt–carbonate associations can be noted in Py3 and Apy1 crystals (Figure 10B). These minerals are confined to pores, voids, and microcracks, as well as the growth zones of pyrite and arsenopyrite crystals. A rod‐like quartz–carbonate rim is often formed at the edges of sulfide crystals (Figure 10C). The content of disseminated sulfide mineralization in proximal alteration can be up to 6–8%. Sulfides (Py3 and Apy1) are localized in the proximal sericite-carbonate–quartz alteration and make a major contribution to the economic value of the veinlet-disseminated mineralization containing "invisible" gold. A proximal alteration is characterized by various types of transformation in rocks. Sericitization, carbonation, and silicification developed in the clastic rocks (sandstones, siltstones). Carbonation, chloritization, and argillization manifested in the dykes of basic, intermediate, and felsic composition. The hydrothermal alteration of both clastic and intrusive rocks involves pyrite–arsenopyrite sulfidation. Py3 is cubic and pentagondodecahedral in shape and often has a zonal structure (Figure 10). The second typomorphic mineral of the association is arsenopyrite (Apy1) with a short-prismatic and pseudopyramidal form (Figure 10A). The size of Apy1 crystals ranges from fractions up to 1–1.5 mm or, less often, up to 2–3 mm. Microinclusions in the minerals of the Au-polysulfide-quartz and sulfosalt–carbonate associations can be noted in Py3 and Apy1 crystals (Figure 10B). These minerals are confined to pores, voids, and microcracks, as well as the growth zones of pyrite and arsenopyrite crystals. A rod-like quartz–carbonate rim is often formed at the edges of sulfide crystals (Figure 10C). The content of disseminated sulfide mineralization in proximal alteration can be up to 6–8%. Usually, pyrite prevails at a distance from quartz veins/veinlets, and arsenopyrite prevails near them.

#### in Py3 and Apy1 crystals (Figure 10B). These minerals are confined to pores, voids, and Usually, pyrite prevails at a distance from quartz veins/veinlets, and arsenopyrite prevails near them. *4.2. Chemical Composition of Pyrite and Arsenopyrite*

near them.

microcracks, as well as the growth zones of pyrite and arsenopyrite crystals. A rod‐like quartz–carbonate rim is often formed at the edges of sulfide crystals (Figure 10C). The content of disseminated sulfide mineralization in proximal alteration can be up to 6–8%. The EPMA analyses revealed distinct trace-element abundances in the various generations of pyrite and arsenopyrite (for the full dataset, see Supplementary Tables S1 and S2).

Usually, pyrite prevails at a distance from quartz veins/veinlets, and arsenopyrite prevails

**Figure 10.** Microtextures of alteration pyrite3 and arsenopyrite1 from proximal alteration rock sed‐ iment‐hosted OGDs (**A**–**C**) and from proximal alteration rock intrusion‐hosted OGDs (**D**) ((**A**,**C**,**D**) reflected light and (**B**) backscattered electron images), central YKMB. (**A**) Dissemination of Py3 and Apy1: pentagondodecahedral shape and zoning are characteristic of individual large pyrite crystals; (**B**) microinclusions of galena (gn), chalcopyrite (Ccp), and sphalerite (Sp) in pores, voids, and mi‐ crocracks of pyrite crystals; (**C**) rod‐like rims of quartz–carbonate composition; (**D**) dissemination of the alteration Py3 and Apy1 in a dyke. **Figure 10.** Microtextures of alteration pyrite3 and arsenopyrite1 from proximal alteration rock sediment-hosted OGDs (**A**–**C**) and from proximal alteration rock intrusion-hosted OGDs (**D**) ((**A**,**C**,**D**) reflected light and (**B**) backscattered electron images), central YKMB. (**A**) Dissemination of Py3 and Apy1: pentagondodecahedral shape and zoning are characteristic of individual large pyrite crystals; (**B**) microinclusions of galena (gn), chalcopyrite (Ccp), and sphalerite (Sp) in pores, voids, and microcracks of pyrite crystals; (**C**) rod-like rims of quartz–carbonate composition; (**D**) dissemination of the alteration Py3 and Apy1 in a dyke.

#### 4.2.1. Chemical Composition of Pyrite in Sediment-Hosted Orogenic Gold Deposits

*4.2. Chemical Composition of Pyrite and Arsenopyrite* The EPMA analyses revealed distinct trace‐element abundances in the various gen‐ erations of pyrite and arsenopyrite (for the full dataset, see Supplementary Tables S1 and S2). Most of the analyzed pyrites of the sediment-hosted orogenic gold deposits have a nonstoichiometric composition (in 63% of analyses, Fe/(S + As) 6= 0.5) and the trace elements As, Co, Ni, Cu, and Sb, as well as, less often, Pb (Supplementary Table S1). Pyrite is characterized by a deficit of sulfur (in 75–95% of analyses, S/Fe < 2.0 at Cs = 51.16–53.82 wt%). Concentrations of trace elements vary within wide limits; the values of the coefficients of variation indicate the heterogeneity of the sample (Vσ from 38% to 138%).

4.2.1. Chemical Composition of Pyrite in Sediment‐Hosted Orogenic Gold Deposits Most of the analyzed pyrites of the sediment‐hosted orogenic gold deposits have a nonstoichiometric composition (in 63% of analyses, Fe/(S + As) ≠ 0.5) and the trace ele‐ Arsenian Py is an indicator. In the metamorphic Py2, CAs ≤ 0.32 wt%. In alteration Py3, the main trace element is As (from 0.31 to 3.16 wt%) (Figure 11A). For the majority (70%) of the analyzed grains, CAs < 1.5 wt%. The zonal distribution of As in pyrite crystals is typical. Core (CAs to 3.08 wt%), intermediate (CAs < 2.0 wt%), and rim (CAs to 2.20 wt%) zones were found.

ments As, Co, Ni, Cu, and Sb, as well as, less often, Pb (Supplementary Table S1). Pyrite is characterized by a deficit of sulfur (in 75–95% of analyses, S/Fe < 2.0 at Cs = 51.16–53.82 wt%). Concentrations of trace elements vary within wide limits; the values of the coeffi‐ cients of variation indicate the heterogeneity of the sample (Vσ from 38% to 138%). Arsenian Py is an indicator. In the metamorphic Py2, CAs ≤ 0.32 wt%. In alteration Py3, the main trace element is As (from 0.31 to 3.16 wt%) (Figure 11A). For the majority (70%) of the analyzed grains, CAs < 1.5 wt%. The zonal distribution of As in pyrite crystals is typical. Core (CAs to 3.08 wt%), intermediate (CAs < 2.0 wt%), and rim (CAs to 2.20 wt%) zones were found. Cobalt, Ni, Cu, Sb, and Pb are typomorphic trace elements in Py3 (Supplementary Table S1). Other elements are present in quantities below the detection limit of EPMA analyses. The total trace-element content varies from 0.01 to 0.55 wt%; the entire spectrum of elements can be found in 20% of crystals. Py3 Σ (Co, Ni, Cu, Sb, Pb) < 0.15 wt% prevails (Figure 11B). There is a decrease in the amount of trace-element content in Py3 compared with Py1 and Py2 (Figure 11B). The pyrites of the Badran deposits are characterized by an increase in the concentration of Sb, and at the Malo–Taryn deposit, the Sb is below the detection limit (Figure 12E). In Py3, the common trace element is Co (from 0.01 to 0.22 wt%; in 90% of analyses, CCo < 0.1 wt%). In zonal crystals, the maximum concentration of Co is characteristic of core Py3. Ni and Cu are present in 50% of the analyzed grains in quantities exceeding the detection limit. Ni (up to 0.46 wt%) can be observed in the rim Py3. There is

Cobalt, Ni, Cu, Sb, and Pb are typomorphic trace elements in Py3 (Supplementary

of elements can be found in 20% of crystals. Py3 Σ (Co, Ni, Cu, Sb, Pb) < 0.15 wt% prevails (Figure 11B). There is a decrease in the amount of trace‐element content in Py3 compared with Py1 and Py2 (Figure 11B). The pyrites of the Badran deposits are characterized by an increase in the concentration of Sb, and at the Malo–Taryn deposit, the Sb is below the detection limit (Figure 12E). In Py3, the common trace element is Co (from 0.01 to 0.22 wt%; in 90% of analyses, CCo < 0.1 wt%). In zonal crystals, the maximum concentration of Co is characteristic of core Py3. Ni and Cu are present in 50% of the analyzed grains in quantities exceeding the detection limit. Ni (up to 0.46 wt%) can be observed in the rim no zoning in the distribution of Cu. The Py3 of the Khangalas deposit is characterized by Pb (to 0.11 wt%) in the core zone. The general formula of pyrite in the sediment-hosted orogenic gold deposit alteration (Py3) pyrite is Fe0.98–1.08(Ni0.0–0.01Co0.0–0.01)S1.95–2.00As0.01–0.05. Py3. There is no zoning in the distribution of Cu. The Py3 of the Khangalas deposit is characterized by Pb (to 0.11 wt%) in the core zone. The general formula of pyrite in the sediment‐hosted orogenic gold deposit alteration (Py3) pyrite is Fe0.98–1.08(Ni0.0–0.01Co0.0– 0.01)S1.95–2.00As0.01–0.05.

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**Figure 11.** Distribution of trace elements in pyrites of different generations in the studied OGDs, central YKMB: (**A**) ternary diagram As–Co+Ni–Sb for Py2 and Py3; (**B**) content of Σ (Co, Ni, Cu, Sb, Pb). **Figure 11.** Distribution of trace elements in pyrites of different generations in the studied OGDs, central YKMB: (**A**) ternary diagram As–Co+Ni–Sb for Py2 and Py3; (**B**) content of Σ (Co, Ni, Cu, Sb, Pb).

4.2.2. Chemical Composition of Pyrite in Intrusion‐Hosted Orogenic Gold Deposits 4.2.2. Chemical Composition of Pyrite in Intrusion-Hosted Orogenic Gold Deposits

Pyrite in the intrusion‐hosted orogenic gold deposits is analyzed both in the host clastic rocks and in dykes of intermediate composition. Most of the pyrite analyzed had a nonstoichiometric composition (in 57% of analyses, Fe/S + As ≠ 0.5) and they showed a deficit of sulfur (in 75–95% of analyses, S/Fe < 2.0 at CS = 51.01–54.08 wt%) (Supplementary Table S1). The concentrations of trace elements vary within a large range; the values of the coefficient of variation indicate the heterogeneity of the samples (Vσ from 42 to 227%). The distributions of trace‐element concentrations in Py3 from clastic rocks and from dykes are comparable, but a number of features can be observed. Pyrite in the intrusion-hosted orogenic gold deposits is analyzed both in the host clastic rocks and in dykes of intermediate composition. Most of the pyrite analyzed had a nonstoichiometric composition (in 57% of analyses, Fe/S + As 6= 0.5) and they showed a deficit of sulfur (in 75–95% of analyses, S/Fe < 2.0 at C<sup>S</sup> = 51.01–54.08 wt%) (Supplementary Table S1). The concentrations of trace elements vary within a large range; the values of the coefficient of variation indicate the heterogeneity of the samples (V<sup>σ</sup> from 42 to 227%). Thedistributions of trace-element concentrations in Py3 from clastic rocks and from dykes are comparable, but a number of features can be observed.

In the alteration Py3 of the clastic rocks, As is the main trace element (from 0.30 to 3.16 wt%) (Figure 12A). Concentrations of CAs < 0.5 wt% are only in 14% of grains, for 60% CAs >1.0 wt%. High As contents are recorded in individual Py3 grains from dykes (CAs = 0.57–2.02 wt%); 34% of Py3 have CAs = 0.01–1.00 wt%, and 44% have non‐arsenian varieties (Supplementary Table S1). In the alteration Py3 of the clastic rocks, As is the main trace element (from 0.30 to 3.16 wt%) (Figure 12A). Concentrations of CAs < 0.5 wt% are only in 14% of grains, for 60% CAs >1.0 wt%. High As contents are recorded in individual Py3 grains from dykes (CAs = 0.57–2.02 wt%); 34% of Py3 have CAs = 0.01–1.00 wt%, and 44% have non-arsenian varieties (Supplementary Table S1).

Cobalt, Ni, Cu, and Sb are typomorphic trace elements in Py3 from clastic rocks (Fig‐ ure 12). The remaining trace elements are present in quantities below the detection limit of the EPMA analysis. The total content of these elements varies from 0.01 to 0.42 wt%, but the whole spectrum of elements is fixed in single crystals. Py3 grains of Σ (Co, Ni, Cu, Sb) < 0.15 wt% prevail (Figure 11B). Co, Ni, and Cu are typomorphic trace elements in Py3 from dykes. Antimony is determined in Py3 from some dykes; it is characterized by in‐ creased concentrations (to 0.10 wt%,) (Figure 12E). The total content of these elements varies widely from 0.003 to 3.97 wt%, but the whole spectrum of elements is fixed in single crystals. Elevated concentrations of Ni and Co can be observed in individual crystals (CNi = 3.52 wt%; CCu = to 2.31 wt%) (Supplementary Table S1). The remaining trace elements are present in quantities below the detection limit of EPMA analyses. Cobalt, Ni, Cu, and Sb are typomorphic trace elements in Py3 from clastic rocks (Figure 12). The remaining trace elements are present in quantities below the detection limit of the EPMA analysis. The total content of these elements varies from 0.01 to 0.42 wt%, but the whole spectrum of elements is fixed in single crystals. Py3 grains of Σ (Co, Ni, Cu, Sb) < 0.15 wt% prevail (Figure 11B). Co, Ni, and Cu are typomorphic trace elements in Py3 from dykes. Antimony is determined in Py3 from some dykes; it is characterized by increased concentrations (to 0.10 wt%,) (Figure 12E). The total content of these elements varies widely from 0.003 to 3.97 wt%, but the whole spectrum of elements is fixed in single crystals. Elevated concentrations of Ni and Co can be observed in individual crystals (CNi = 3.52 wt%; CCu = to 2.31 wt%) (Supplementary Table S1). The remaining trace elements are present in quantities below the detection limit of EPMA analyses.

**Figure 12.** Boxplots showing the compositional difference in Py1‐2 and Py3 acquired using an EPMA analysis of the studied OGDs, central YKMB. The lower border of the line shows the mini‐ mum value; the upper shows the maximum value. Horizontal lines in the boxes denote the median, the X marks in the boxes denote the mean, and the bottom and top of each box denote the first and third quartiles, respectively. Concentrations are on a logarithmic scale. **Figure 12.** Boxplots showing the compositional difference in Py1-2 and Py3 acquired using an EPMA analysis of the studied OGDs, central YKMB. The lower border of the line shows the minimum value; the upper shows the maximum value. Horizontal lines in the boxes denote the median, the X marks in the boxes denote the mean, and the bottom and top of each box denote the first and third quartiles, respectively. Concentrations are on a logarithmic scale. **Figure 12.** Boxplots showing the compositional difference in Py1‐2 and Py3 acquired using an EPMA analysis of the studied OGDs, central YKMB. The lower border of the line shows the mini‐ mum value; the upper shows the maximum value. Horizontal lines in the boxes denote the median, the X marks in the boxes denote the mean, and the bottom and top of each box denote the first and third quartiles, respectively. Concentrations are on a logarithmic scale.

#### 4.2.3. Chemical Composition of Arsenopyrite in Sediment‐Hosted Orogenic Gold Depos‐ its 4.2.3. Chemical Composition of Arsenopyrite in Sediment-Hosted Orogenic Gold Deposits 4.2.3. Chemical Composition of Arsenopyrite in Sediment‐Hosted Orogenic Gold Depos‐ its

Most of the analyzed Apy1 has a nonstoichiometric composition (in 72% of analyses, Fe/(S + As) ≠ 0.5) and is rich in sulfur (As/S from 0.77 tо 0.99). In some cases, the ratio is As/S > 1.0. For Apy1, the trace elements Co, Ni, Cu, and Sb are typomorphic (Supplemen‐ tary Table S2, Figure 13). Other elements are present in quantities below the detection limit of EPMA analyses. Most of the analyzed Apy1 has a nonstoichiometric composition (in 72% of analyses, Fe/(S + As) 6= 0.5) and is rich in sulfur (As/S from 0.77 to 0.99). In some cases, the ratio is As/S > 1.0. For Apy1, the trace elements Co, Ni, Cu, and Sb are typomorphic (Supplementary Table S2, Figure 13). Other elements are present in quantities below the detection limit of EPMA analyses. Most of the analyzed Apy1 has a nonstoichiometric composition (in 72% of analyses, Fe/(S + As) ≠ 0.5) and is rich in sulfur (As/S from 0.77 tо 0.99). In some cases, the ratio is As/S > 1.0. For Apy1, the trace elements Co, Ni, Cu, and Sb are typomorphic (Supplemen‐ tary Table S2, Figure 13). Other elements are present in quantities below the detection limit of EPMA analyses.

The concentrations of typomorphic elements vary significantly, and in most of the analyzed grains, Σ (Co, Ni, Cu, Sb) is no more than 0.15 wt% (Figure 13A, Figure 14). The ratios of trace elements are individual for different deposits (Figure 13B). Thus, at the Malo–Taryn deposit, Sb accounts for 60% of the trace elements, and at the Khangalas de‐ posit, 45% is Co. Antimony is found in all the analyzed grains; its content is not stable (Vσ up to 124%), but this is the main trace element in Apy1. The concentrations of typomorphic elements vary significantly, and in most of the analyzed grains, Σ (Co, Ni, Cu, Sb) is no more than 0.15 wt% (Figures 13A and 14). The ratios of trace elements are individual for different deposits (Figure 13B). Thus, at the Malo– Taryn deposit, Sb accounts for 60% of the trace elements, and at the Khangalas deposit, 45% is Co. Antimony is found in all the analyzed grains; its content is not stable (Vσ up to 124%), but this is the main trace element in Apy1. The concentrations of typomorphic elements vary significantly, and in most of the analyzed grains, Σ (Co, Ni, Cu, Sb) is no more than 0.15 wt% (Figure 13A, Figure 14). The ratios of trace elements are individual for different deposits (Figure 13B). Thus, at the Malo–Taryn deposit, Sb accounts for 60% of the trace elements, and at the Khangalas de‐ posit, 45% is Co. Antimony is found in all the analyzed grains; its content is not stable (Vσ up to 124%), but this is the main trace element in Apy1.

**Figure 13.** Distribution of trace elements in arsenopyrite1 of the studied OGDs, central YKMB: (**A**) content of Σ (Co, Ni, Cu, Sb); (**B**) the ratio of individual trace elements in the studied deposits. **Figure 13.** Distribution of trace elements in arsenopyrite1 of the studied OGDs, central YKMB: (**A**) content of Σ (Co, Ni, Cu, Sb); (**B**) the ratio of individual trace elements in the studied deposits. **Figure 13.** Distribution of trace elements in arsenopyrite1 of the studied OGDs, central YKMB: (**A**) content of Σ (Co, Ni, Cu, Sb); (**B**) the ratio of individual trace elements in the studied deposits.

Alteration rock after sandstones

Alteration rock after sandstones and silt‐ stones

Deposits

#### 4.2.4. Chemical Composition of Arsenopyrite in the Intrusion-Hosted Orogenic Gold Deposits Arsenopyrite1 in intrusion‐hosted orogenic gold deposits is rare. Most of the ana‐ lyzed arsenopyrites from the dykes of the V'yun deposit have a nonstoichiometric com‐

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Arsenopyrite1 in intrusion-hosted orogenic gold deposits is rare. Most of the analyzed arsenopyrites from the dykes of the V'yun deposit have a nonstoichiometric composition (in 67% of analyses, Fe/(S + As) 6= 0.5) and are rich in sulfur (As/S from 0.75 to 0.94). For Apy1 intrusion-hosted orogenic gold deposits, the typomorphic element is Sb (Supplementary Table S2), averaging 85% of the total volume of the trace elements. In some samples, the Sb content reaches 1.03–1.8 wt%. Ni and Cu were determined in 65% of the analyzed grains; Co in the Apy1 of the dykes is present within CCo = 0.01–0.07 wt% and in clastic rocks in quantities below the detection limit of EPMA analyses. position (in 67% of analyses, Fe/(S + As) ≠ 0.5) and are rich in sulfur (As/S from 0.75 to 0.94). For Apy1 intrusion‐hosted orogenic gold deposits, the typomorphic element is Sb (Supplementary Table S2), averaging 85% of the total volume of the trace elements. In some samples, the Sb content reaches 1.03–1.8 wt%. Ni and Cu were determined in 65% of the analyzed grains; Co in the Apy1 of the dykes is present within CCo = 0.01–0.07 wt% and in clastic rocks in quantities below the detection limit of EPMA analyses.

**Figure 14.** Boxplots showing the compositional difference in the arsenopyrite1 of the studied OGDs, central YKMB, in this study acquired by EPMA. The lower border of the line shows the minimum value; the upper one shows the maximum value. Horizontal lines in the boxes denote the median, the X marks in the boxes denote the mean, and the bottom and top of each box denote the first and third quartiles, respectively. Concentrations are on a logarithmic scale. **Figure 14.** Boxplots showing the compositional difference in the arsenopyrite1 of the studied OGDs, central YKMB, in this study acquired by EPMA. The lower border of the line shows the minimum value; the upper one shows the maximum value. Horizontal lines in the boxes denote the median, the X marks in the boxes denote the mean, and the bottom and top of each box denote the first and third quartiles, respectively. Concentrations are on a logarithmic scale.

### *4.3. Gold and Silver Content of Sulfides from Proximal Alteration according to AAS Data*

55.7/15.1

1.2 െ 83.4 17.0/9.9

9.5 െ 42.6 21.8/17.5

0.5 െ 10.9 2.6/1.8

*4.3. Gold and Silver Content of Sulfides from Proximal Alteration according to AAS Data* Data on the gold and silver content in pyrites and arsenopyrites from the proximal Data on the gold and silver content in pyrites and arsenopyrites from the proximal alteration are shown in Table 4 and illustrated in Figure 15.


Arsenopyrite 4

Pyrite 12

4.2/3.3

1.2 െ 16.9 6.0/3.6

1.3 െ 12.6 4.9/2.9

1.1 െ 17.4 6.2/6.1

Arsenopyrite 9

Khangalas deposit

Badran deposit

17.1/17.8

13.7 െ 155.5 57.5/41.1

34.8 െ 168.5 66.9/54.6

> 0.8 െ 39.3 11.2/7.4

alteration are shown in Table 4 and illustrated in Figure 15. **Table 4.** Results of atomic absorption atomic spectrometry (ppm) of sulfides from the proximal al‐ **Table 4.** Results of atomic absorption atomic spectrometry (ppm) of sulfides from the proximal alteration of the studied OGDs, central YKMB.

[11]

and [12]

Pyrite <sup>13</sup> This study,

Alteration rock after sandstones and siltstones


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Arsenopyrite 3

0.4 − 11.8 6.5/7.2

1.4 − 28.6 11.1/3.3

12.3 − 23.8 17.5/16.4

#### **Table 4.** *Cont.*

\* Minimum−Maximum Mean/Median . \* ୧୬୧୫୳୫ିୟ୶୧୫୳୫ ୣୟ୬/ୣୢ୧ୟ୬ .

**Figure 15.** The gold and silver content in sulfides from the alteration of the studied OGDs, central YKMB: (**A**) Malo–Taryn; (**B**) Badran; (**C**) Khangalas; (**D**) V'yun; (**E**) Shumnyi; (**F**) comparative diagrams between the maximum, mean, and median values of the gold and silver content in sulfides from the alteration. **Figure 15.** The gold and silver content in sulfides from the alteration of the studied OGDs, central YKMB: (**A**) Malo–Taryn; (**B**) Badran; (**C**) Khangalas; (**D**) V'yun; (**E**) Shumnyi; (**F**) comparative diagrams between the maximum, mean, and median values of the gold and silver content in sulfides from the alteration.

#### *4.4. Sulfur Isotopic Composition of Sulfides*

The δ <sup>34</sup>S isotopic composition of pyrite and arsenopyrite from the Malo–Taryn, Badran, and Khangalas proximal alterations in the sediment-hosted deposits and the V'yun and Shumnyi proximal alterations in the intrusion-hosted deposit of the central YKMB is shown in Table 5.

**Table 5.** Sulfur isotope data of pyrite and arsenopyrite from proximal alteration rock sediment-hosted deposits and intrusion-hosted deposits of the studied OGDs, central YKMB.



#### **Table 5.** *Cont.*

\* The values of the S isotopic composition of pyrite and arsenopyrite for the Badran deposit were determined using local measurement methods at the periphery (denominator) and center (numerator).

#### 4.4.1. Sediment-Hosted Orogenic Gold Deposits

In three analyses of Py grains from the alteration of the Malo–Taryn deposit, δ <sup>34</sup>S has a range from −5.5 to +1.4‰; two analyses of Apy grains provided a restricted δ <sup>34</sup>S range— −1.6 and −1.4‰. The δ <sup>34</sup>S values of Py and Apy from the alteration sampled at various depths (from 587 to 916 m) of the Badran deposit have a narrow range of values, from −1.1 to +1.9‰. The highest variations of δ <sup>34</sup>S are determined in 26 analyses of Py (from −0.7 to +1.9‰, mean +0.8‰, median +1.0‰), and 16 analyses yielded a δ <sup>34</sup>S Apy range of −1.1 to +0.1‰ (mean −0.4‰, median −0.3‰). The sulfur δ <sup>34</sup>S isotopic composition of sulfides from the alteration of the Khangalas deposit is characterized by a narrow range of negative δ <sup>34</sup>S values, from <sup>−</sup>2.1 to <sup>−</sup>0.6‰, according to seven analyses of Py (from <sup>−</sup>1.9

to −0.6‰, mean −1.2‰, median −1.3‰) and four analyses of Apy (from −2.1 to −1.1‰, mean −1.5‰, median −1.3‰).

#### 4.4.2. Intrusion-Hosted Orogenic Gold Deposits

At the V'yun deposit, there is a heterogeneous δ <sup>34</sup>S in the sulfides. The highest variations in six analyses of δ <sup>34</sup>S are determined in Py from dykes (from <sup>−</sup>6.4 to +3.1‰, mean −1.9‰, median −3.3‰). The highest δ <sup>34</sup>S values are determined in Py (from +2.3 to +5.6‰, mean +4.0‰, median +4.1‰) and Apy (+4.4‰) from clastic rocks. Seven analyses of δ <sup>34</sup>S in Py from the alteration of the Shumnyi deposit yielded positive values from +2.1 to +5.1‰. There are no evident isotopic variations between δ <sup>34</sup>S in Py from sandstones (from +4.3 to +5.0‰) or from dykes (from +2.1 to +5.1‰, mean +3.4‰, median +2.5‰).

#### **5. Discussion**

#### *5.1. Composition of Pyrite3 and Arsenopyrite1*

#### 5.1.1. Incorporation of Metals and Metalloids in Pyrite3

Microelements in pyrite can be in the form of isomorphic trace elements and in the form of micro- and nanoinclusions. Concentrations of trace elements and their correlations with the major elements indicate the form and conditions of their accumulation in pyrite, as well as the evolution of the ore formation conditions.

Arsenic is the most informative in the composition of pyrite. A number of researchers, analyzing changes in the shape and concentration of As in pyrite from gold deposits of various types, suggest using As to explain the evolution of the hydrothermal system [103]. The chemical zoning of As in pyrites may be the result of physicochemical changes in the composition of the ore-forming fluid [104–108] and the effects of magmatic fluids (magmatic vapor plumes) [105].

It was mentioned in Section 4.2 that the Py3 from sediment-hosted (Malo–Taryn, Badran, Khangalas) and intrusion-hosted (V'yun, Shumnyi) gold deposits are characterized by nonstoichiometric compositions. The S/Fe ratio varies in individual deposits within sufficiently large ranges (V'yun, S/Fe = 1.87–2.04; Badran, S/Fe = 1.88–2.09). According to the obtained results from the EPMA analysis, Py3 differs from the calculated values (Fe = 46.55 wt% and S = 53.45 wt%) (Figure 16) and indicates the presence of vacant positions in the structure of pyrite, which are occupied by trace elements. The As-Fe-S ternary diagram demonstrates the possible variants of the occurrence of microelements in the composition of pyrite (Figure 16) [104]. Mainly, As isomorphically replaces S (As1−) (Figure 16), but it can replace Fe in the crystal lattice Fe (As2+ and As3+) [109,110] or may occur in the form of nanoinclusions (As<sup>0</sup> ) [104]. The isomorphic substitution of Fe is the main mechanism for the inclusion of Co, Ni, Cu, Sb, and Pb (Me2+) in the composition of pyrite [33].

The negative trend between concentrations of elements also confirms the isomorphic substitutions. This is most clearly manifested for the S-As pair (Figure 17A): elevated As contents are characteristic of pyrites with a deficit of sulfur; for the entire sample population, rS-As = −0.68, and it increases in individual objects (Malo–Taryn, rS-As = −0.77; Vyun dykes, rS-As = −0.80). The correlations between Fe, S, and other trace elements are variable and are better expressed in individual objects (Malo–Taryn, rS-Cu = −0.54; Shumnyi, rFe-Cu = −0.65) (Figure 17). Pyrites from igneous rocks are characterized by a negative correlation for the pairs Fe2+<sup>→</sup> Co2+ and Fe2+<sup>→</sup> Ni2+(r = <sup>−</sup>0.7–−0.9) (Figure 17C,D). The similar incorporation of metals and metalloids in pyrite3 from sediment-hosted (Malo–Taryn, Badran, Khangalas) and intrusion-hosted (V'yun, Shumnyi) gold deposits indicates their unified nature.

[33].

nature.

It was mentioned in Section 4.2 that the Py3 from sediment‐hosted (Malo–Taryn,

The negative trend between concentrations of elements also confirms the isomorphic

substitutions. This is most clearly manifested for the S‐As pair (Figure 17A): elevated As contents are characteristic of pyrites with a deficit of sulfur; for the entire sample popula‐ tion, rS‐As = −0.68, and it increases in individual objects (Malo–Taryn, rS‐As = −0.77; Vyun dykes, rS‐As = −0.80). The correlations between Fe, S, and other trace elements are variable and are better expressed in individual objects (Malo–Taryn, rS‐Cu = −0.54; Shumnyi, rFe‐Cu = −0.65) (Figure 17). Pyrites from igneous rocks are characterized by a negative correlation for the pairs Fe2+→ Co2+ and Fe2+→ Ni2+(r = −0.7–−0.9) (Figure 17C,D). The similar incorpo‐ ration of metals and metalloids in pyrite3 from sediment‐hosted (Malo–Taryn, Badran, Khangalas) and intrusion‐hosted (V'yun, Shumnyi) gold deposits indicates their unified

Badran, Khangalas) and intrusion‐hosted (V'yun, Shumnyi) gold deposits are character‐ ized by nonstoichiometric compositions. The S/Fe ratio varies in individual deposits within sufficiently large ranges (V'yun, S/Fe = 1.87–2.04; Badran, S/Fe = 1.88–2.09). Accord‐ ing to the obtained results from the EPMA analysis, Py3 differs from the calculated values (Fe = 46.55 wt% and S = 53.45 wt%) (Figure 16) and indicates the presence of vacant posi‐ tions in the structure of pyrite, which are occupied by trace elements. The As‐Fe‐S ternary diagram demonstrates the possible variants of the occurrence of microelements in the composition of pyrite (Figure 16) [104]. Mainly, As isomorphically replaces S (As1−) (Fig‐ ure 16), but it can replace Fe in the crystal lattice Fe (As2+ and As3+) [109,110] or may occur in the form of nanoinclusions (As0) [104]. The isomorphic substitution of Fe is the main mechanism for the inclusion of Co, Ni, Cu, Sb, and Pb (Me2+) in the composition of pyrite

**Figure 16.** Ternary diagram showing the As‐Fe‐S composition of pyrite in the studied OGDs, cen‐ **Figure 16.** Ternary diagram showing the As-Fe-S composition of pyrite in the studied OGDs, central YKMB. The demarcated fields are after [104].

#### 5.1.2. Incorporation of Metals and Metalloids in Arsenopyrite1

tral YKMB. The demarcated fields are after [104].

5.1.2. Incorporation of Metals and Metalloids in Arsenopyrite1 Arsenopyrite is a three‐component system and the main isomorphic substitutions occur according to the scheme S1<sup>−</sup> As1<sup>−</sup> (r = 0.92–0.99) (Figure 18A) and Fe2+(Fe3+) As2+(As3+) (Figure 18B) (r = 0.65–0.89). In the studied Apy1 grains, Fe is characterized by small variations in the content; in 75% of the analyzed grains, CApy = 33.8–34.8 wt%, which, in the mean, corresponds to stoichiometry. The sulfur content in all grains exceeds the Arsenopyrite is a three-component system and the main isomorphic substitutions occur according to the scheme S1<sup>−</sup> <sup>→</sup> As1<sup>−</sup> (r = 0.92–0.99) (Figure 18A) and Fe2+(Fe3+)<sup>→</sup> As2+(As3+) (Figure 18B) (r = 0.65–0.89). In the studied Apy1 grains, Fe is characterized by small variations in the content; in 75% of the analyzed grains, CApy = 33.8–34.8 wt%, which, in the mean, corresponds to stoichiometry. The sulfur content in all grains exceeds the stoichiometric composition (19.7 wt%), which varies between 19–24 wt%, with a mean content of C<sup>S</sup> = 21.3 wt%. The As content is less than the stoichiometric content (46.0 wt% with a mean content). Variations in the concentration of S and As are different in the individual deposits (Figure 18C). Arsenopyrite of the Malo–Taryn deposit is closest to the stoichiometric composition (Figure 18 C,D).

stoichiometric composition (19.7 wt%), which varies between 19–24 wt%, with a mean content of CS = 21.3 wt%. The As content is less than the stoichiometric content (46.0 wt% with a mean content). Variations in the concentration of S and As are different in the in‐ dividual deposits (Figure 18C). Arsenopyrite of the Malo–Taryn deposit is closest to the stoichiometric composition (Figure 18 C,D). A diagram of S/As and (S+As)/Fe [111] clearly reflects both the nonstoichiometry and variability of the compositions, as well as the increased sulfur content of Apy3 in the studied deposits (Figure 18). The deficit of Fe and As is compensated by the trace elements (Co, Ni, Cu, Sb). They can occupy both anionic and cationic vacant positions in the crystal structure, and their distribution in arsenopyrite is less ordered than in pyrite. Slight and moderate negative correlations prevail between the main elements and trace elements (Figure 19). The connection between As and Sb is most clearly manifested (r = −0.45–−0.61) (Figure 19L). For alteration arsenopyrites with nonstoichiometric composition and a predominance (excess) of S, many researchers [39,112,113] specify the increased concentrations of Au. The following trend can also be observed in the deposits studied by us (Figure 18D). Significant variations in the S, As, and Fe and trace-element content in the arsenopyrite also indicate the crystallization of the mineral in an inhomogeneous temperature field [111]. This is reflected in the zonal distribution of both trace elements and the gold content of Apy3.

**Figure 17.** Diagrams of the ratios of concentrations of Fe, S, and trace elements in Py3 in the studied OGDs, central YKMB. (**A**) S vs. As; (**B**) Fe vs. As; (**C**) Fe vs. Co; (**D**) Fe vs. Ni; (**E**) S vs. Co; (**F**) Fe vs. Ni; (**G**) Fe vs. Cu; (**H**) S vs. Cu; (**I**) Fe vs. Co; (**J**) S vs. Cu; (**K**) Fe vs. Pb; (**L**) S vs. Pb. Negative corre‐ lation indicates isomorphic substitution. The lines Fe = 46.547 wt% and S = 53.453 wt% correspond to the stoichiometric composition of pyrite. See symbols in Figure 16. **Figure 17.** Diagrams of the ratios of concentrations of Fe, S, and trace elements in Py3 in the studied OGDs, central YKMB. (**A**) S vs. As; (**B**) Fe vs. As; (**C**) Fe vs. Co; (**D**) Fe vs. Ni; (**E**) S vs. Co; (**F**) Fe vs. Ni; (**G**) Fe vs. Cu; (**H**) S vs. Cu; (**I**) Fe vs. Co; (**J**) S vs. Cu; (**K**) Fe vs. Pb; (**L**) S vs. Pb. Negative correlation indicates isomorphic substitution. The lines Fe = 46.547 wt% and S = 53.453 wt% correspond to the stoichiometric composition of pyrite. See symbols in Figure 16.

#### 5.1.3. Gold–Cobalt–Nickel Relationships in Pyrite3

The analysis of the Co and Ni content and the ratios of these elements is important for determining the conditions of the formation and genesis of pyrite [29,33,106,114–116]. Py3 is characterized by S/Fe 6= 2.00 (Figure 20A). In most analyses, pyrites are depleted in sulfur, the deficit of which is compensated by As. Co and Ni in the pyrite structure occur mainly as isomorphic replacements of the types Fe2+ <sup>→</sup> Co2+ and Fe2+ <sup>→</sup> Ni2+ [117]. Elevated concentrations of Co and Ni are characteristic of pyrites with Fe content of <46.547 wt%, which corresponds to the stoichiometric composition (Figure 17C,D). The deficit of Fe indicates the presence of cationic vacant positions in the pyrite structure, which are filled with Co and Ni [118]. In grains with high iron content, Co and Ni are part of the pyrite structure and are incorporated there via emplacement isomorphism. *Minerals* **2023**, *13*, x 26 of 41

**Figure 18.** Diagrams of the ratios of concentrations of Fe, S, and As in Apy1 of the studied OGDs, central YKMB. (**A**) As vs. S. (**B**) As vs. Fe. (**C**) Variations in the S and As content in the studied deposits; (**D**) diagrams of the ratios S/As and (S + As)/Fe. The intersection of the lines S/As = 1 and (S + As)/Fe = 2 corresponds to chemical stoichiometry. See symbols in Figure 16. **Figure 18.** Diagrams of the ratios of concentrations of Fe, S, and As in Apy1 of the studied OGDs, central YKMB. (**A**) As vs. S. (**B**) As vs. Fe. (**C**) Variations in the S and As content in the studied deposits; (**D**) diagrams of the ratios S/As and (S + As)/Fe. The intersection of the lines S/As = 1 and (S + As)/Fe = 2 corresponds to chemical stoichiometry. See symbols in Figure 16.

structure, and their distribution in arsenopyrite is less ordered than in pyrite. Slight and moderate negative correlations prevail between the main elements and trace elements (Figure 19). The connection between As and Sb is most clearly manifested (r = −0.45–−0.61) (Figure 19L). For alteration arsenopyrites with nonstoichiometric composition and a predominance (excess) of S, many researchers [39,112,113] specify the increased concentrations of Au. The following trend can also be observed in the deposits studied by us (Figure 18D). Significant variations in the S, As, and Fe and trace‐element content in the arsenopyrite also indicate the crystallization of the mineral in an inhomogeneous temperature field [111]. This is reflected in the zonal distribution of both trace elements

A diagram of S/As and (S+As)/Fe [111] clearly reflects both the nonstoichiometry and variability of the compositions, as well as the increased sulfur content of Apy3 in the studied deposits (Figure 18). The deficit of Fe and As is compensated by the trace elements

and the gold content of Apy3.

**Figure 19.** Diagrams of the ratios of concentrations of Fe, S, As, and trace elements in Apy1 of the studied OGDs, central YKMB. (**A**) Fe vs. Co; (**B**) S vs. Co; (**C**) As vs. Co; (**D**) Fe vs. Ni; (**E**) S vs. Ni; (**F**) As vs. Ni; (**G**) Fe vs. Cu; (**H**) S vs. Cu; (**I**) As vs. Cu; (**J**) Fe vs. Sb; (**K**) S vs. Sb; (**L**) As vs. Sb. The lines Fe = 34.30 wt%, S = 19.69 wt%, and As = 46.01 wt% correspond to the stoichiometric composi‐ tion of pyrite. See symbols in Figure 16. **Figure 19.** Diagrams of the ratios of concentrations of Fe, S, As, and trace elements in Apy1 of the studied OGDs, central YKMB. (**A**) Fe vs. Co; (**B**) S vs. Co; (**C**) As vs. Co; (**D**) Fe vs. Ni; (**E**) S vs. Ni; (**F**) As vs. Ni; (**G**) Fe vs. Cu; (**H**) S vs. Cu; (**I**) As vs. Cu; (**J**) Fe vs. Sb; (**K**) S vs. Sb; (**L**) As vs. Sb. The lines Fe = 34.30 wt%, S = 19.69 wt%, and As = 46.01 wt% correspond to the stoichiometric composition of pyrite. See symbols in Figure 16.

21B).

5.1.3. Gold–Cobalt–Nickel Relationships in Pyrite3

pyrite structure and are incorporated there via emplacement isomorphism.

The analysis of the Co and Ni content and the ratios of these elements is important for determining the conditions of the formation and genesis of pyrite [29,33,106,114–116]. Py3 is characterized by S/Fe ≠ 2.00 (Figure 20A). In most analyses, pyrites are depleted in sulfur, the deficit of which is compensated by As. Co and Ni in the pyrite structure occur mainly as isomorphic replacements of the types Fe2+ → Co2+ and Fe2+ → Ni2+ [117]. Ele‐ vated concentrations of Co and Ni are characteristic of pyrites with Fe content of <46.547 wt%, which corresponds to the stoichiometric composition (Figure 17C,D). The deficit of Fe indicates the presence of cationic vacant positions in the pyrite structure, which are

**Figure 20.** Distribution of the total impurity Co+Ni in Py3 relative to the indicator S/Fe (**A**) of the studied OGDs, central YKMB. (**B**) Diagram of concentration ratios Ni and Co in Py3 of the studied deposits. The demarcated fields are after [115]. See symbols in Figure 16. **Figure 20.** Distribution of the total impurity Co+Ni in Py3 relative to the indicator S/Fe (**A**) of the studied OGDs, central YKMB. (**B**) Diagram of concentration ratios Ni and Co in Py3 of the studied deposits. The demarcated fields are after [115]. See symbols in Figure 16.

Co concentrations vary markedly in the volume of a single grain. Elevated concen‐ trations are characteristic of the central part of the zonal Py3, which can be formed before the formation of mineralization. There is an inverse correlation between Co and Au (r = Co concentrations vary markedly in the volume of a single grain. Elevated concentrations are characteristic of the central part of the zonal Py3, which can be formed before the formation of mineralization. There is an inverse correlation between Co and Au (r = −0.6) (Figure 21A), which, perhaps, is a temperature effect [119] and indicates the formation of gold-bearing pyrite in low-temperature conditions.

−0.6) (Figure 21A), which, perhaps, is a temperature effect [119] and indicates the for‐ mation of gold‐bearing pyrite in low‐temperature conditions. The Co/Ni ratio in Py3 of the studied deposits varies widely (0.1–28.0), but in most analyses, CCo > CNi, and in 90% of analyses, 10.0 > Co/Ni > 0.1, which is typical for hydro‐ thermal pyrite (Figure 20B) [33,102]. High concentrations of Ni in sulfides may indicate [120] the participation of basic and ultrabasic components supplied into hydrothermal fluids and involved in the deposition of sulfides. The Ni/Co ratio can indirectly character‐ The Co/Ni ratio in Py3 of the studied deposits varies widely (0.1–28.0), but in most analyses, CCo > CNi, and in 90% of analyses, 10.0 > Co/Ni > 0.1, which is typical for hydrothermal pyrite (Figure 20B) [33,102]. High concentrations of Ni in sulfides may indicate [120] the participation of basic and ultrabasic components supplied into hydrothermal fluids and involved in the deposition of sulfides. The Ni/Co ratio can indirectly characterize the gold content of pyrite [119]. Gold is predominantly isomorphic in pyrite with conductivity (Ni/Co > 0.1), and cobalt-rich pyrite (Ni/Co < 0.1) is not gold-bearing (Figure 21B). *Minerals* **2023**, *13*, x 29 of 41

**Figure 21.** (**A**) Graph showing the relationship between the concentration of Co and Au in Py3 of the studied deposits; (**B**) graph showing the relationship between the concentration of Au and the Ni/Co indicator of the studied deposits. **Figure 21.** (**A**) Graph showing the relationship between the concentration of Co and Au in Py3 of the studied deposits; (**B**) graph showing the relationship between the concentration of Au and the Ni/Co indicator of the studied deposits.

Data on the gold content in pyrite and arsenopyrite from the alteration of the studied

In general, for all the studied deposits, gold contents in sulfides from proximal alter‐ ations were determined from fractions to be 168.5 ppm (Badran deposit, Apy). The highest gold content is found in Py, with 159.5 ppm (V'yun deposit) (Figure 15). Our results are comparable with data on the gold content in sulfides from alterations in many gold de‐ posits in NE Russia, but they are noticeably lower compared with some large deposits with disseminated ores (Natalka—140–482.6 ppm Au, Mayskoe—300–1975 ppm Au [121], Nezhdaninskoe—up to 1400 ppm [28,112], Kyuchus—11.5–440 ppm Au [122]). Neverthe‐ less, these results show the high economic potential of the disseminated mineralization in the studied deposits. For example, for the Khangalas deposit, it was shown that with a minimum gold content in alterations of 0.5 ppm, a length of 1.4 km, a thickness of 50 m,

Gold in sulfides can occur in an isomorphic structurally bound form and in the form of native nano‐ and microinclusions [31,119,123–125]. The problem of invisible gold has been studied in the most detail in pyrite, which is related to the discovery of a large Carlin deposit in Nevada, where gold is closely associated with arsenian pyrite [126]. However, it is known that pyrite and arsenopyrite with invisible gold occur in deposits of various types (e.g., orogenic, epithermal, intrusion‐related, porphyry‐Cu, iron‐oxide copper‐gold, etc.) [32,119]. Over the past 15–20 years, with the advent of new analytical techniques and technologies, a lot of information has been obtained about invisible gold and its form of occurrence in sulfides [31,32,124,127]. It was shown that invisible gold is mainly concen‐ trated in pyrite with a high solid‐solution As content—arsenian pyrite [128]. Arsenic can

Au were obtained for Py grains from the Malo–Taryn deposit (Au—5.1 ppm); the maxi‐ mum mean values of Au are determined for arsenopyrite from the Badran deposit (66.9 ppm Au). For the proximal alteration of the V'yun and Shumnyi intrusion‐hosted depos‐ its, there are obvious differences between the gold contents in sulfides from clastic rocks compared with dykes. In alteration rocks from dykes in the V'yun deposit, the mean value of Au is 5.0 ppm, whereas, in Py from alterations in clastic rocks, the mean value of Au is 35.6 ppm. In two Apy samples from alterations in sandstones, the following values were obtained: 28.9 and 58.4 ppm Au. The Shumnyi deposit is characterized by the inverse value of variations in the Au content in Py. Thus, in Py from dykes, the mean value of Au

5.2.1. Gold Concentration

5.2.2. Gold in Pyrite3

*5.2. Gold Occurrence and Concentration in Sulfides from Proximal Alteration*

is 28.8 ppm, and in Py from sandstones, the mean value of Au is 13.2 ppm.

and a depth of 100 m for ore zones, reserves can be increased by 9.1 t Au [12].
