**Cannabigerobutol (CBGB, 15):**

Compound **15** was prepared as described for 1**4** using compound **11** (250 mg, 1.50 mmol) and geraniol (416 mg, 2.7 mmol) to give compound **15** in 18% yield. 1H NMR (500 MHz, CD3OD): δ 6.16 (d, 2H, aromatic), 5.26 (t, 1H, CH, J = 7.0 Hz), 5.09 (t, 1H, CH, J = 7.0 Hz), 3.27 (d, 2H, J = 7.5 Hz, Ph-CH2), 2.50–2.35 (m, 2H, Ph-CH2), 2.10–1.90 (m, 4H), 1.77 (s, 3H, CH3), 1.67 (S, 3H, CH3), 1.58 (s, 3H, CH3), 1.40–1.30 (m, 4H), 0.92 (t, 3H, CH3, J = 6.5 Hz); HRMS calculated for C20H30O2 + H: 303.2326; the observed value was 303.1941.

#### **Cannabigerophorbol (CBGP, 16):**

Compound **16** was prepared as described for **14** using compound **12** (208 mg, 1.0 mmol) and geraniol (278 mg, 1.8 mmol) to give compound **16** in 26% yield [33]. 1H NMR (500 MHz, CDCl3): δ 6.27 (S, 2H, aromatic), 5.30 (t, 1H, CH, J = 7.0 Hz), 5.08 (t, 1H, CH, J = 6.0 Hz), 5.02 (bs, 2H, OH), 3.42 (d, 2H, Ph-CH2, J = 7.0 Hz), 2.48 (t, 2H, Ph-CH2, J = 8.0 Hz), 2.19–2.10 (m, 4H), 1.84 (s, 3H, CH3), 1.70 (S, 3H, CH3), 1.62–1.57 (m and S, 5H, CH2 and CH3), 1.33–1.24 (m, 10H), 0.91 (t, 3H, CH3, J = 7.0 Hz); HRMS calculated for C23H36O2 + H: 344.2715; the observed value was 344.2657.

#### **Cannabigerononol (CBGN, 17):**

Compound **17** was prepared as described for **14** using compound **13** (307 mg, 1.5 mmol) and geraniol (417 mg, 2.7 mmol) to give compound **17** in 29% yield. 1H NMR (500 MHz, CDCl3): δ 6.27 (S, 2H, aromatic), 5.30 (t, 1H, CH, J = 7.0 Hz), 5.08 (t, 1H, CH, J = 6.5 Hz), 5.00 (bs, 2H, OH), 3.42 (d, 2H, Ph-CH2, J = 7.0 Hz), 2.48 (t, 2H, Ph-CH2, J = 7.5 Hz), 2.15–2.10 (m, 4H), 1.84 (s, 3H, CH3), 1.70 (S, 3H, CH3), 1.62 (s, 3H, CH3), 1.62–1.57 (m, 2H), 1.33–1.24 (m, 12H), 0.91 (t, 3H, CH3, J = 7.0 Hz); HRMS calculated for C25H40O2 + H: 373.3108; the observed value was 373.3089.
