Polymers

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14 pages, 1486 KiB

Open AccessArticle

Epoxidation of Fatty Acid Methyl Esters Derived from Algae Biomass to Develop Sustainable Bio-Based Epoxy Resins

by Pamela Hidalgo, Simona Álvarez, Renato Hunter and Alejandra Sánchez

Polymers 2020, 12(10), 2313; https://doi.org/10.3390/polym12102313 - 10 Oct 2020

Cited by 12 | Viewed by 4604

Abstract

The objective of this research was to investigate the development of epoxides from Chlorella vulgaris lipids to obtain a novel bio-based resin. The process involved the production of fatty acid methyl esters (FAMEs) by in situ transesterification of microalgal biomass, followed by epoxidation [...] Read more.

The objective of this research was to investigate the development of epoxides from Chlorella vulgaris lipids to obtain a novel bio-based resin. The process involved the production of fatty acid methyl esters (FAMEs) by in situ transesterification of microalgal biomass, followed by epoxidation of the FAMEs to obtain bioresin. During the FAME production process, an assessment was made of the main factors affecting the production of unsaturated fatty acid methyl esters (UFAMEs), such as catalyst dosage and methanol:hexane volume ratio. For step epoxidation, an evaluation of the catalyst concentration, temperature and formic acid:hydrogen peroxide ratio was made. From the results obtained, UFAME production was maximized using 20 wt% of catalyst dosage and a volume ratio of 1:2 (v/v, methanol:hexane). Then, in the epoxidation stage, a higher yield was obtained using 1 wt% of catalyst with a volume ratio of 1:1 and maintaining a temperature of 70 °C. The bioresin was blended with neat epoxy resin (DGEBA) and cured with tetraethylenepentamine (TEPA). Bio-based resin was characterized via Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA) to evaluate this material as an alternative source for oleochemistry. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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13 pages, 3115 KiB

Open AccessArticle

The Effect of Silica-Filler on Polyurethane Adhesives Based on Renewable Resource for Wood Bonding

by Mariusz Ł. Mamiński, Anna M. Więcław-Midor and Paweł G. Parzuchowski

Polymers 2020, 12(10), 2177; https://doi.org/10.3390/polym12102177 - 24 Sep 2020

Cited by 14 | Viewed by 3873

Abstract

The aim of the study was to evaluate the applicability and performance of polyglycerol- and sucrose-based polyols as components of a simplified formulation of polyurethane adhesives. Colloidal silica was used as a viscosity control and reinforcing agent. The adhesives were examined in terms [...] Read more.

The aim of the study was to evaluate the applicability and performance of polyglycerol- and sucrose-based polyols as components of a simplified formulation of polyurethane adhesives. Colloidal silica was used as a viscosity control and reinforcing agent. The adhesives were examined in terms of reactivity, thermal stability, viscosity, work of adhesion, wetting, surface energy, and bonding strength on wooden substrates. Silica was found to increase gelling time, but markedly improved bonding strength and adhesion with substrates. Bonded solid beech wood samples prepared at 80, 110, and 130 °C showed shear strengths between 7.1 MPa and 9.9 MPa with 100% wood failure. The renewable resource-based polyols were demonstrated to be useful in formulation of polyurethane adhesives for furniture industry—especially with silica as a filler. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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17 pages, 3014 KiB

Open AccessArticle

Utilization of Noxious Weed Water Hyacinth Biomass as a Potential Feedstock for Biopolymers Production: A Novel Approach

by Rijuta Ganesh Saratale, Si-Kyung Cho, Gajanan S. Ghodake, Han-Seung Shin, Ganesh Dattatraya Saratale, Yooheon Park, Hee-Seok Lee, Ram Naresh Bharagava and Dong-Su Kim

Polymers 2020, 12(8), 1704; https://doi.org/10.3390/polym12081704 - 29 Jul 2020

Cited by 41 | Viewed by 5478

Abstract

This study aims to utilize a noxious weed water hyacinth biomass (WH) for polyhydroxybutyrate (PHB) production. Alkaline and peracetic acid pretreatment was employed for the hydrolysis of WH and consequently enzymatic saccharification to produce fermentable sugars for PHB production. The pretreatment competence was [...] Read more.

This study aims to utilize a noxious weed water hyacinth biomass (WH) for polyhydroxybutyrate (PHB) production. Alkaline and peracetic acid pretreatment was employed for the hydrolysis of WH and consequently enzymatic saccharification to produce fermentable sugars for PHB production. The pretreatment competence was determined using various operational parameters. By applying ambient conditions, alkaline pretreatment gave higher lignin removal of 65.0%, with 80.8% hydrolysis yield, and on enzyme hydrolysis (40 FPU/g of dry WH), produced total reducing sugar of about 523 mg/g of WH. The resulted WH enzymatic hydolysates were evaluated for the production of PHB by Ralstonia eutropha (ATCC 17699). The WH hydrolysates cultivation was compared to synthetic hydrolysates that contain a similar carbon composition in terms of bacterial growth and PHB synthesis. The effects of various supplements to enhance PHB production were estimated. Supplementation of corn steep liquor (CSL) as a cheap nitrogen source with WH hydrolysates favored a higher amount of PHB synthesis (73%), PHB titer of 7.30 g/L and PHB yield of 0.429 g/g of reducing sugar. Finally, using standard analytical tools, the physical and thermal characteristics of the extracted PHB were evaluated. The findings revealed WH was a promising and technically feasible option for transforming biomass into sustainable biopolymer conversion on a large scale. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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19 pages, 2786 KiB

Open AccessArticle

Experimental Investigation and Performance Evaluation of Modified Viscoelastic Surfactant (VES) as a New Thickening Fracturing Fluid

by Z. H. Chieng, Mysara Eissa Mohyaldinn, Anas. M. Hassan and Hans Bruining

Polymers 2020, 12(7), 1470; https://doi.org/10.3390/polym12071470 - 30 Jun 2020

Cited by 38 | Viewed by 4322

Abstract

In hydraulic fracturing, fracturing fluids are used to create fractures in a hydrocarbon reservoir throughout transported proppant into the fractures. The application of many fields proves that conventional fracturing fluid has the disadvantages of residue(s), which causes serious clogging of the reservoir’s formations [...] Read more.

In hydraulic fracturing, fracturing fluids are used to create fractures in a hydrocarbon reservoir throughout transported proppant into the fractures. The application of many fields proves that conventional fracturing fluid has the disadvantages of residue(s), which causes serious clogging of the reservoir’s formations and, thus, leads to reduce the permeability in these hydrocarbon reservoirs. The development of clean (and cost-effective) fracturing fluid is a main driver of the hydraulic fracturing process. Presently, viscoelastic surfactant (VES)-fluid is one of the most widely used fracturing fluids in the hydraulic fracturing development of unconventional reservoirs, due to its non-residue(s) characteristics. However, conventional single-chain VES-fluid has a low temperature and shear resistance. In this study, two modified VES-fluid are developed as new thickening fracturing fluids, which consist of more single-chain coupled by hydrotropes (i.e., ionic organic salts) through non-covalent interaction. This new development is achieved by the formulation of mixing long chain cationic surfactant cetyltrimethylammonium bromide (CTAB) with organic acids, which are citric acid (CA) and maleic acid (MA) at a molar ratio of (3:1) and (2:1), respectively. As an innovative approach CTAB and CA are combined to obtain a solution (i.e., CTAB-based VES-fluid) with optimal properties for fracturing and this behaviour of the CTAB-based VES-fluid is experimentally corroborated. A rheometer was used to evaluate the visco-elasticity and shear rate & temperature resistance, while sand-carrying suspension capability was investigated by measuring the settling velocity of the transported proppant in the fluid. Moreover, the gel breaking capability was investigated by determining the viscosity of broken VES-fluid after mixing with ethanol, and the degree of core damage (i.e., permeability performance) caused by VES-fluid was evaluated while using core-flooding test. The experimental results show that, at pH-value (

6.17

), 30 (mM) VES-fluid (i.e., CTAB-CA) possesses the highest visco-elasticity as the apparent viscosity at zero shear-rate reached nearly to 10

^{6}

(mPa·s). Moreover, the apparent viscosity of the 30 (mM) CTAB-CA VES-fluid remains 60 (mPa·s) at (90

^{\circ}

C) and 170 (s

^{- 1}

) after shearing for 2-h, indicating that CTAB-CA fluid has excellent temperature and shear resistance. Furthermore, excellent sand suspension and gel breaking ability of 30 (mM) CTAB-CA VES-fluid at 90 (

^{\circ}

C) was shown; as the sand suspension velocity is 1.67 (mm/s) and complete gel breaking was achieved within 2 h after mixing with the ethanol at the ratio of 10:1. The core flooding experiments indicate that the core damage rate caused by the CTAB-CA VES-fluid is (

7.99 %

), which indicate that it does not cause much damage. Based on the experimental results, it is expected that CTAB-CA VES-fluid under high-temperature will make the proposed new VES-fluid an attractive thickening fracturing fluid. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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15 pages, 3954 KiB

Open AccessArticle

Sustainable Aromatic Aliphatic Polyesters and Polyurethanes Prepared from Vanillin-Derived Diols via Green Catalysis

by Changbo Zhao, Caijuan Huang, Qin Chen, Ian D. V. Ingram, Xiankui Zeng, Tianhua Ren and Haibo Xie

Polymers 2020, 12(3), 586; https://doi.org/10.3390/polym12030586 - 5 Mar 2020

Cited by 18 | Viewed by 5486

Abstract

The design and preparation of polymers by using biobased chemicals is regarded as an important strategy towards a sustainable polymer chemistry. Herein, two aromatic diols, 4-(hydroxymethyl)-2-methoxyphenol and 2-(4-(hydroxymethyl)-2-methoxyphenoxy)ethanol, have been prepared in good yields through the direct reduction of vanillin and hydroxyethylated vanillin [...] Read more.

The design and preparation of polymers by using biobased chemicals is regarded as an important strategy towards a sustainable polymer chemistry. Herein, two aromatic diols, 4-(hydroxymethyl)-2-methoxyphenol and 2-(4-(hydroxymethyl)-2-methoxyphenoxy)ethanol, have been prepared in good yields through the direct reduction of vanillin and hydroxyethylated vanillin (4-(2-hydroxyethoxy)-3-methoxybenzaldehyde) using NaBH₄, respectively. The diols were submitted to traditional polycondensation and polyaddition with acyl chlorides and diisocyanatos, and serials of new polyesters and polyurethanes were prepared in high yields with moderate molecular weight ranging from 17,000 to 40,000 g mol⁻¹. Their structures were characterized by ¹H NMR, ¹³C NMR and FTIR, and their thermal properties were studied by TGA and differential scanning calorimetry (DSC), indicating that the as-prepared polyesters and polyurethanes have T_g in the range of 16.2 to 81.2 °C and 11.6 to 80.4 °C, respectively. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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15 pages, 4125 KiB

Open AccessArticle

A One-Pot Synthesis and Characterization of Antibacterial Silver Nanoparticle–Cellulose Film

by Qi-Yuan Chen, Sheng-Ling Xiao, Sheldon Q. Shi and Li-Ping Cai

Polymers 2020, 12(2), 440; https://doi.org/10.3390/polym12020440 - 13 Feb 2020

Cited by 27 | Viewed by 3875

Abstract

Using N,N-dimethylacetamide (DMAc) as a reducing agent in the presence of PVP-K30, the stable silver nanoparticles (Ag-NPs) solution was prepared by a convenient method for the in situ reduction of silver nitrate. The cellulose–Ag-NPs composite film (CANF) was cast in the same container [...] Read more.

Using N,N-dimethylacetamide (DMAc) as a reducing agent in the presence of PVP-K30, the stable silver nanoparticles (Ag-NPs) solution was prepared by a convenient method for the in situ reduction of silver nitrate. The cellulose–Ag-NPs composite film (CANF) was cast in the same container using lithium chloride (LiCl) giving the Ag-NPs-PVP/DMAc solution cellulose solubility as well as γ-mercaptopropyltrimethoxysilane (MPTS) to couple Ag-NPs and cellulose. The results showed that the Ag-NPs were uniformly dispersed in solution, and the solution had strong antibacterial activities. It was found that the one-pot synthesis allowed the growth of and cross-linking with cellulose processes of Ag-NPs conducted simultaneously. Approximately 61% of Ag-NPs was successfully loaded in CANF, and Ag-NPs were uniformly dispersed in the surface and internal of the composite film. The composite film exhibited good tensile properties (tensile strength could reach up to 86.4 MPa), transparency (light transmittance exceeds 70%), thermal stability, and remarkable antibacterial activities. The sterilization effect of CANF_0.04 against Staphylococcus aureus and Escherichia coli exceed 99.9%. Due to low residual LiCl/DMAc and low diffusion of Ag-NPs, the composite film may have potential for applications in food packaging and bacterial barrier. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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20 pages, 7594 KiB

Open AccessArticle

Modification of Poly(Ethylene 2,5-Furandicarboxylate) with Poly(Ethylene glycol) for Biodegradable Copolyesters with Good Mechanical Properties and Spinnability

by Peng Ji, Danping Lu, Shengming Zhang, Wanying Zhang, Chaosheng Wang and Huaping Wang

Polymers 2019, 11(12), 2105; https://doi.org/10.3390/polym11122105 - 14 Dec 2019

Cited by 21 | Viewed by 5202

Abstract

Using 2,5-furandicarboxylic acid, ethylene glycol, and poly(ethylene glycol) as raw materials and ethylene glycol antimony as a catalyst, poly(ethylene furandicarboxylate) (PEF) and polyethylene glycol (PEG) copolymers (PEGFs) were synthesized by transesterification by changing the molecular weight of PEG (from 600 to 10,000 g/mol) [...] Read more.

Using 2,5-furandicarboxylic acid, ethylene glycol, and poly(ethylene glycol) as raw materials and ethylene glycol antimony as a catalyst, poly(ethylene furandicarboxylate) (PEF) and polyethylene glycol (PEG) copolymers (PEGFs) were synthesized by transesterification by changing the molecular weight of PEG (from 600 to 10,000 g/mol) and the PEG content (from 10 to 60 wt %). The thermal, hydrophilic, degradation, and spinnility characteristics of these copolymers were then investigated. Thermogravimetric analysis shows that PEGF is thermally stable at 62 °C, much lower than the temperature for PEF. The intrinsic viscosity of the obtained copolyester was between 0.67 and 0.99 dL/g, which is higher than the viscosity value of PEF. The contact angle experiment shows that the hydrophilicity of PEGFs is improved (the surface contact angle is reduced from 91.9 to 63.3°), which gives PEGFs a certain degradability, and the maximum mass loss can reach approximately 15%. Melt spinning experiments show that the PEGF polymer has poor spinnability, but the mechanical properties of the polymer monofilament are better. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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15 pages, 3841 KiB

Open AccessArticle

Characterization of Starches Isolated from Colombian Native Potatoes and Their Application as Novel Edible Coatings for Wild Andean Blueberries (Vaccinium meridionale Swartz)

by Carolina Medina-Jaramillo, Santiago Estevez-Areco, Silvia Goyanes and Alex López-Córdoba

Polymers 2019, 11(12), 1937; https://doi.org/10.3390/polym11121937 - 25 Nov 2019

Cited by 10 | Viewed by 3944

Abstract

Andean blueberry is a promissory fruit native to South America. The current work aimed to characterize starches isolated from Colombian native potatoes and to evaluate the effect of the application of starch edible coatings on the changes in the physicochemical quality parameters of [...] Read more.

Andean blueberry is a promissory fruit native to South America. The current work aimed to characterize starches isolated from Colombian native potatoes and to evaluate the effect of the application of starch edible coatings on the changes in the physicochemical quality parameters of the Andean blueberry during storage. Starches were isolated from three different potatoes varieties (pacha negra, mora, and alcarrosa) and characterized. Then, starch-based coatings were applied to Andean blueberries, and the changes in their quality parameters were monitored during 12 days of storage. Despite the phenotypical differences in the starch sources used, starches were similar in terms of their granule morphology, amylose content (~19%), crystallinity degree (~46%), and thermal properties. Coatings were able to reduce the gaseous exchange of the fruit, and, thus, the respiration rate of all coated blueberries was ~27% lower compared to the uncoated fruits (p < 0.05) at the end of the storage. While the application of starch coatings did not prevent water loss, all samples reached water loss of up 20%. Besides, the coated fruits showed soluble solids contents ~14% higher compared to the control one, as well as better bright and firmness. The new edible coatings can help add value to the Andean blueberry. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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13 pages, 3564 KiB

Open AccessArticle

Effects of Different Denaturants on Properties and Performance of Soy Protein-Based Adhesive

by Li Yue, Zhang Meng, Zhang Yi, Qiang Gao, An Mao and Jianzhang Li

Polymers 2019, 11(8), 1262; https://doi.org/10.3390/polym11081262 - 30 Jul 2019

Cited by 45 | Viewed by 4904

Abstract

Chemical modification of soy protein, via crosslinking, is the preferred method for creating non-toxic, renewable, environmentally friendly wood adhesives. The denaturing process of protein is important for the adhesive performance improvement. In order to investigate the effect of different denaturing agents on the [...] Read more.

Chemical modification of soy protein, via crosslinking, is the preferred method for creating non-toxic, renewable, environmentally friendly wood adhesives. The denaturing process of protein is important for the adhesive performance improvement. In order to investigate the effect of different denaturing agents on the performance of soy protein-based adhesives before and after crosslinking modification. In this study, three different denaturing agents—urea (U), sodium dodecyl sulfate (SDS), and sodium hydrogen sulfite (SHS) and an epoxide crosslinking agent—Triglycidylamine (CA) were used to prepare soy protein-based adhesives. The results showed: (1) The denaturing agent unfolded protein molecules and exposed more hydrophobic groups to prevent water intrusion, which was mainly a contribution for the water resistance and performance improvement of soy protein-based adhesives. The wet shear strength was improved up to 91.3% (denaturing by urea). (2) After modifying by the crosslinking agent, the properties and performance improvement was due to the fact that the active groups on soybean protein molecules reacted with the crosslinking agent to form a crosslinking structure, and there is no obvious correlation with the hydrophobic groups of the protein. (3) The unfolded soybean protein molecules also expose hydrophilic groups, which facilitates the reaction between the crosslinking agent and protein to form a denser crosslinking structure to improve the performance of the adhesive. Particularly, after denaturing with SHS, the wet shear strength of the plywood bonded by the SPI-SHS-CA adhesive increased by 217.24%. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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13 pages, 2289 KiB

Open AccessArticle

Opuntia Ficus-Indica L. Miller (Palma Forrageira) as an Alternative Source of Cellulose for Production of Pharmaceutical Dosage Forms and Biomaterials: Extraction and Characterization

by Amaro César Lima de Assis, Larissa Pereira Alves, João Paulo Tavares Malheiro, Alana Rafaela Albuquerque Barros, Edvânia Emannuelle Pinheiro-Santos, Eduardo Pereira de Azevedo, Harley da Silva Alves, João Augusto Oshiro-Junior and Bolívar Ponciano Goulart de Lima Damasceno

Polymers 2019, 11(7), 1124; https://doi.org/10.3390/polym11071124 - 2 Jul 2019

Cited by 15 | Viewed by 3934

Abstract

Cellulose is among the top 5 excipients used in the pharmaceutical industry. It has been considered one of the main diluents used in conventional and modern dosage forms. Therefore, different raw materials of plant origin have been evaluated as potential alternative sources of [...] Read more.

Cellulose is among the top 5 excipients used in the pharmaceutical industry. It has been considered one of the main diluents used in conventional and modern dosage forms. Therefore, different raw materials of plant origin have been evaluated as potential alternative sources of cellulose. In this context, Opuntia ficus-indica L. Miller (palma forrageira), a plant of the cactus family that has physiological mechanisms that provide greater productivity with reduced water requirements, is an interesting and unexplored alternative for extracting cellulose. By using this source, we aim to decrease the extraction stages and increase the yields, which might result in a decreased cost for the industry and consequently for the consumer. The aim of this work was to investigate the use of Opuntia ficus-indica L. Miller as a new source for cellulose extraction, therefore providing an efficient, straight forward and low-cost method of cellulose II production. The extraction method is based on the oxidation of the lignins. The obtained cellulose was identified and characterized by spectroscopic methods (FTIR and NMR), X-ray diffraction, thermal analysis (TGA-DTG and DSC) and scanning electron microscopy. The results confirmed the identity of cellulose and its fibrous nature, which are promising characteristics for its use in the industry and a reasonable substrate for chemical modifications for the synthesis of cellulose II derivatives with different physicochemical properties that might be used in the production of drug delivery systems and biomaterials. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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17 pages, 8742 KiB

Open AccessEditor’s ChoiceArticle

Influence of Starch Composition and Molecular Weight on Physicochemical Properties of Biodegradable Films

by Daniel Domene-López, Juan Carlos García-Quesada, Ignacio Martin-Gullon and Mercedes G. Montalbán

Polymers 2019, 11(7), 1084; https://doi.org/10.3390/polym11071084 - 26 Jun 2019

Cited by 168 | Viewed by 14837

Abstract

Thermoplastic starch (TPS) films are considered one of the most promising alternatives for replacing synthetic polymers in the packaging field due to the starch biodegradability, low cost, and abundant availability. However, starch granule composition, expressed in terms of amylose content and phosphate monoesters, [...] Read more.

Thermoplastic starch (TPS) films are considered one of the most promising alternatives for replacing synthetic polymers in the packaging field due to the starch biodegradability, low cost, and abundant availability. However, starch granule composition, expressed in terms of amylose content and phosphate monoesters, and molecular weight of starch clearly affects some film properties. In this contribution, biodegradable TPS films made from potato, corn, wheat, and rice starch were prepared using the casting technique. The effect of the grain structure of each starch on microstructure, transparency, hydration properties, crystallinity, and mechanical properties of the films, was evaluated. Potato starch films were the most transparent and corn starch films the most opaque. All the films had homogeneous internal structures—highly amorphous and with no pores, both of which point to a good starch gelatinization process. The maximum tensile strength (4.48–8.14 MPa), elongation at break (35.41–100.34%), and Young’s modulus (116.42–294.98 MPa) of the TPS films were clearly influenced by the amylose content, molecular weight, and crystallinity of the film. In this respect, wheat and corn starch films, are the most resistant and least stretchable, while rice starch films are the most extensible but least resistant. These findings show that all the studied starches can be considered suitable for manufacturing resistant and flexible films with similar properties to those of synthetic low-density polyethylene (LDPE), by a simple and environmentally-friendly process. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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12 pages, 2321 KiB

Open AccessArticle

Development of a High-Performance Adhesive with a Microphase, Separation Crosslinking Structure Using Wheat Flour and a Hydroxymethyl Melamine Prepolymer

by Jieyu Zhang, Yi Zhang, Jianzhang Li and Qiang Gao

Polymers 2019, 11(5), 893; https://doi.org/10.3390/polym11050893 - 15 May 2019

Cited by 14 | Viewed by 3938

Abstract

The objective of this study is to use wheat flour (WF) and hydroxymethyl melamine prepolymer (HMP) to develop a low cost, highly water-resistant, starch-based bio-adhesive for plywood fabrication. Three-layer plywood was fabricated using the resultant adhesive, and the wet shear strength of the [...] Read more.

The objective of this study is to use wheat flour (WF) and hydroxymethyl melamine prepolymer (HMP) to develop a low cost, highly water-resistant, starch-based bio-adhesive for plywood fabrication. Three-layer plywood was fabricated using the resultant adhesive, and the wet shear strength of the plywood samples was measured under various conditions. After determining that water resistance was significantly improved with the addition of HMP, we evaluated the physical characteristics of the starch-based adhesive and functional groups and analyzed the thermal stability and fracture surface of the cured adhesive samples. Results showed that by adding 20 wt.% HMP into WF adhesive, the sedimentation volume in the resultant adhesive decreased by 11.3%, indicating that the increase of crosslinking in the structure of the adhesives increased the bond strength, and the wet shear strength of the resultant plywood in 63 °C water improved by 375% when compared with the WF adhesive. After increasing the addition of HMP to 40 wt.%, the wet shear strength of the resultant plywood in 100 °C water changed from 0 MPa to 0.71 MPa, which meets the exterior use plywood requirement. This water resistance and bond strength improvement resulted from (1) HMP reacting with functions in WF and forming a crosslinking structure to prevent moisture intrusion; and (2) HMP self-crosslinking and combining with crosslinked WF to form a microphase separation crosslinking structure, which improved both the crosslinking density and the toughness of the adhesive, and subsequently, the adhesive’s bond performance. In addition, the microphase separation crosslinking structure had better thermostability and created a compact ductile fracture surface, which further improved the bond performance of the adhesive. Thus, using a prepolymer to form a microphase separation crosslinking structure within the adhesive improves the rigidity, toughness, and water resistance of the material in a practical and cost-effective manner. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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Review

Jump to: Research

36 pages, 3726 KiB

Open AccessReview

Application of Polysaccharide Biopolymer in Petroleum Recovery

by Shunxiang Xia, Laibao Zhang, Artur Davletshin, Zhuoran Li, Jiahui You and Siyuan Tan

Polymers 2020, 12(9), 1860; https://doi.org/10.3390/polym12091860 - 19 Aug 2020

Cited by 81 | Viewed by 9408

Abstract

Polysaccharide biopolymers are biomacromolecules derived from renewable resources with versatile functions including thickening, crosslinking, adsorption, etc. Possessing high efficiency and low cost, they have brought wide applications in all phases of petroleum recovery, from well drilling to wastewater treatment. The biopolymers are generally [...] Read more.

Polysaccharide biopolymers are biomacromolecules derived from renewable resources with versatile functions including thickening, crosslinking, adsorption, etc. Possessing high efficiency and low cost, they have brought wide applications in all phases of petroleum recovery, from well drilling to wastewater treatment. The biopolymers are generally utilized as additives of fluids or plugging agents, to correct the fluid properties that affect the performance and cost of petroleum recovery. This review focuses on both the characteristics of biopolymers and their utilization in the petroleum recovery process. Research on the synthesis and characterization of polymers, as well as controlling their structures through modification, aims to develop novel recipes of biopolymer treatment with new application realms. The influences of biopolymer in many petroleum recovery cases were also evaluated to permit establishing the correlations between their physicochemical properties and performances. As their performance is heavily affected by the local environment, screening and testing polymers under controlled conditions is the necessary step to guarantee the efficiency and safety of biopolymer treatments. Full article

(This article belongs to the Special Issue Synthesis and Characterization of Bio-Based Polymers)

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