Search Results (1,530)

The decline in the injectivity of injection wells is a serious problem in geothermal systems. In this article, we analyse the mechanisms responsible for the reduction in permeability in Lower Jurassic sandstones during the injection of cooled formation brine. Flow experiments were conducted on rock cores using three types of brines with varying degrees of contamination. The studies included microscopic analysis, scanning electron microscopy (SEM) and mercury intrusion capillary pressure (MICP) before and after the experiments. The results showed that the main factor in the decrease in permeability is the formation of a filter cake from secondary iron minerals on the front surface of the core. Filter cake formation was observed in all samples, with ferrous sediment penetrating to a maximum depth of 1.5 cm from the core front. In addition, the mobilisation of clay particles was observed, which accumulate in pore constrictions, causing additional flow restriction. Mercury porosimetry revealed significant increases in hysteresis values in the front zone (from 16.5 to 42%), indicating complex pore connectivity changes without substantial porosity reduction. The rate of injectivity decline correlates strongly with the fluid flow velocity. The results of the study provide a scientific basis for optimising reinjection processes in geothermal systems and developing strategies to prevent formation damage. Full article

This study collected 820 topsoil samples from cultivated lands across Ningxia, covering the Yellow River irrigation area, the central arid zone, and the southern mountainous region. The ordinary kriging were spatially interpolated to analyze As, Hg, Cd, Cr, and Pb heavy-metal pollution spatial patterns. Pollution was evaluated using the Nemerow and geoaccumulation (I_(geo)) indices, and sources quantified via Pearson correlations, PCA (Principal Component Analysis), and PMF (Positive Matrix Factorization). The results indicated that Hg and Cd posed the highest ecological risks. The overall mean concentrations (mg.kg⁻¹) of Hg, Cd, As, Pb, and Cr were 0.04, 0.27, 9.91,23.81, and 57.34, respectively. Compared with the background values, they were 1.90, 2.41, 0.83, 1.14, 2.74 times higher, respectively. Geospatially, regions with higher pollution probabilities for Cd, Cr, Pb, Hg, and As were concentrated in the northern and central parts of Ningxia, whereas the southern region exhibited lower pollution probabilities. pH significantly influenced the accumulation and spatial distribution of heavy metals in soil. Source apportionment identified three primary contributors: transportation and natural parent materials (As, Pb, Cr), industrial activities (Hg), and agricultural practices (Cd). Hg and Cd were identified as the key risk elements requiring prioritized management. These results enhance understanding of the pollution levers of heavy metals in Ningxia cultivated soils, and also provide foundation for developing more scientific and precise soil risk control policies, offering significant practical value for environmental risk management. Full article

Atmospheric particulate matter (PM) pollution has escalated into a critical threat to urban public health and safety. Among urban functional zones, commercial districts—characterized by high human exposure—are simultaneously hotspots of pollutant accumulation. Consequently, PM mitigation in these areas has become an urgent challenge for sustainable urbanization. This study used Computational Fluid Dynamics (CFD) to simulate the diffusion process and vertical concentration distribution of particulate matter in commercial districts. The results showed that the concentration of PM2.5 decreased with increasing height, with the highest concentration in the respiratory zone (1.5 m) and basic diffusion above 50 m; There are significant differences in the concentration changes of pollutants under different combinations of architectural spaces. By establishing a 20 m block wind corridor, changing the relationship between the building and the street enclosure, and adjusting the form of the building podium and overhead design with building height multiples (6–12 m), strategies can effectively alleviate the accumulation of particulate matter in commercial blocks. These findings provide quantitative evidence for evidence-based retrofitting strategies aimed at reducing PM2.5 exposure in high-density commercial areas. Full article

Forest ecosystems are vital for climate mitigation, yet predicting their carbon (C) sequestration remains challenging, especially in urban-proximal regions. This study investigates the C storage dynamics across five major forest types in the Chang-Zhu-Tan Green Heart, a critical ecological buffer zone in China’s Yangtze River Mid-Reach urban agglomeration. We integrated field measurements with structural equation and random forest modeling to analyze vertical C distribution and its drivers. The results revealed that over 90% of vegetation C was stored in the tree layer, with soil C highest in evergreen broad-leaved forests (41.26 Mg C/ha). Biological factors (i.e., tree volume and biomass) primarily drove vegetation C (52–73% of variance), while non-biological factors (soil properties and micronutrients) predominantly regulated soil C. We identified distinct age-related trajectories: J-shaped accumulation in broad-leaved forests versus S-shaped patterns in coniferous and mixed forests. These findings provide a mechanistic framework for forest-type-specific management strategies to enhance C sequestration in urban-agglomeration buffer zones. Full article

Distinct paradigms, such as the “enzymic latch” and “iron gate” theories, have been proposed to elucidate SOC loss or accumulation, but their relative significance and whether they are mutually exclusive in permafrost peatlands remain unclear. To address this, we evaluated their relative importance and identified the dominant factors controlling SOC stability. Therefore, we employed a space-for-time substitution approach across a permafrost gradient (continuous, discontinuous, and isolated) by systematically quantifying extracellular enzyme activities, iron (Fe) phases, and iron-bound soil organic carbon (Fe-SOC) at various depths (0–10, 10–30, and 30–50 cm) in peatlands. Our results did not support the “enzymic latch” theory, with hydrolytic enzyme activities (β-glucosidase (BG), cellobiohydrolase (CBH), and β-N-acetylglucosaminidase (NAG)) showing positive correlations with phenolics but negative correlations with phenol oxidase (PHO) activity. However, ferrous iron (Fe(II)) was significantly positively correlated with PHO activity, and ferric iron (Fe(III)) stabilized SOC through co-precipitation with it to form Fe-SOC, supporting the “iron gate” theory. Moreover, Fe-SOC decreased from the continuous to the isolated permafrost zone, and with soil depth from 0–10 cm to 30–50 cm. Partial least squares path modeling (PLS-PM) analysis indicated that Fe(III) directly and indirectly (via Fe-SOC and phenolics) affected SOC. Our study demonstrated the primacy of the “iron gate” mechanism in controlling carbon stability in the Great Hing’an Mountains permafrost peatlands, providing new insights for projecting carbon-climate feedback. Full article

Understanding the microstructure–property relationship in aluminum extrusions is crucial to leverage their potential in automotive lightweighting. The sensitivity of the processing history to the microstructure and through-thickness variations poses a major challenge since it leads to strong directionality in plasticity and fracture. Reliable characterization of the mechanical response under relevant stress states is crucial for the development of modeling strategies and performance ranking in alloy design. To this end, tensile and 3-point bend tests were performed for an aluminum extrusion produced on a laboratory-scale extrusion press at Rio Tinto Aluminium. Direct measurements of surface strains during bending using stereoscopic digital image correlation revealed that a larger bend angle in the VDA238-100 test does not necessarily imply a higher fracture strain. The T4 sample tested in the extrusion direction sustained a bend angle of 104° compared to 68° in T6 for the same nominal bend severity (ratio of sheet thickness to punch radius), despite comparable major fracture strains of 0.60 and 0.58, respectively. It is proposed that the work-hardening behavior governs the strain distribution on the outer bend surface. The higher hardening rate in the T4 condition helped distribute deformation in the bend zone more uniformly. This delayed fracture to larger bend angles since strain is accumulated at a lower rate. To assess whether the effect of the hardening behavior is manifest at a microstructural lengthscale, microcomputed tomography (μ-CT) scans were conducted on interrupted bend samples. The distribution and severity of damage in the form of cracks on the outer bend surface were distinct to the temper and thus the hardening rate. Full article

Understanding mineralogical transformations and elemental mobility during limestone weathering is critical for deciphering carbon cycling and critical zone evolution in karst terrains. This study investigates an in situ limestone weathering profile (12.6 m depth) in Shimen, Hunan Province, using integrated mineralogical (XRD, EPMA-EDS), elemental (XRF, ICP-MS), and Sr isotopic (MC-ICP-MS) analyses. Results reveal a two-stage pedogenic model: (1) Rapid dissolution of primary calcite (>95 wt% in bedrock to 1.1–48.5 wt% in soil) creates an abrupt bedrock–soil interface via volumetric collapse (>90%), accumulating acid-insoluble residues (quartz-dominated); (2) Subsequent weathering drives illitization of K-feldspar, trace element enrichment (e.g., Ni, Tl, Th τ up to 180) via illite adsorption, and radiogenic ⁸⁷Sr/⁸⁶Sr evolution (0.7076 in bedrock to 0.7292 in soil). Depth-dependent increases in chemical index of alteration (CIA: 6.79–79.96) and mass transfer coefficients confirm progressive weathering intensity. The profile acts as a net carbon source (58.5% depletion in soil inorganic carbon), highlighting significant CO₂ release during pedogenesis. These findings provide mechanistic insights into subtropical critical zone evolution and element cycling in carbonate-dominated systems. Full article

Laser processing of heterogeneous composites requires a clear understanding of coupled thermal and mechanical responses to ensure structural integrity and patterning precision. In this study, a thermal–mechanical coupling model based on the finite element method was developed to investigate laser–material interactions in Al–Tedlar–Kevlar composite films. The effects of key parameters—including pulse energy, spot size, pulse duration, and repetition frequency—on the evolution of temperature and stress fields were systematically examined. The simulations reveal that pulse energy leads to a linear rise in peak temperature, while pulse duration exerts a nonlinear influence on energy density and thermal uniformity. Increasing repetition frequency promotes thermal accumulation, enlarging the heat-affected zone. Coupled analyses further indicate significant stress concentrations at material interfaces, which may trigger delamination and compromise film reliability. Through comprehensive parameter evaluation, the optimal processing conditions were identified as 0.5 mJ pulse energy, 20 kHz repetition rate, 45 μm spot diameter, and 120 ns pulse duration. These findings clarify the governing mechanisms of thermal–mechanical interactions in multilayer composites and provide theoretical guidance for optimizing laser micropatterning processes while enhancing interfacial stability and manufacturing quality. Full article

The development of nuclear energy in Jordan necessitates a detailed understanding of local meteorological behavior, particularly during unfavorable weather conditions. This study uses the METEO mesoscale model to simulate wind fields, vertical motions, and surface–air temperature differences under unfavorable wind directions (15°, 105°, and 195°) and two wind speeds (1 m/s and 5 m/s), across cold season (January) and warm season (July), near the Samra Energy Power Plant (SEPP)—a proposed location for Jordan’s nuclear plant. Simulations reveal that low wind speeds create stable atmospheric layers with limited vertical motion (±0.1 m/s), enhancing the risk of pollutant accumulation in valleys. Higher wind speeds promote vertical mixing (up to ±0.15 m/s) and lower temperature gradients (within ±0.2 °C), dispersing pollutants more efficiently. These results suggest that specific wind thresholds could determine the spatial extent of emergency response zones, including “shelter-in-place” areas and evacuation perimeters. This study offers valuable insights for nuclear safety planning and environmental risk assessment in complex terrain. Full article

Huhehu Sag is a sag with high exploration degree in Hailar Basin. With large sedimentary thickness, complete stratigraphic development and excellent oil generation conditions, it is the main oil- and gas-producing sag in Hailar Basin. The primary source rocks are the Nantun Formation, with the Tongbomiao and Damoguaihe Formations as secondary sources. Hydrocarbon accumulation periods in the sag were comprehensively analyzed using methodologies including source rock hydrocarbon generation-expulsion history, authigenic illite dating of reservoirs, and fluid inclusion homogenization temperature analysis. Results reveal two major accumulation stages: Stage 1 (125–90 Ma), corresponding to the depositional period of the Yimin Formation, represented the peak paleo-geothermal regime and the primary hydrocarbon accumulation phase. Intensive hydrocarbon generation and expulsion, coupled with robust migration dynamics, facilitated large-scale oil and gas pooling. Stage 2(65 Ma-now), from the deposition of Qingyuangang Formation to the present, uplift and denudation reduce the burial depth of source rocks, the hydrocarbon generation intensity is weakened. This phase involved secondary adjustments of pre-existing reservoirs and continued charging of newly generated hydrocarbons. The Huhehu Sag is a typical half-graben structure. Fault-block and fault-lithologic reservoirs dominate, distributed zonally along gentle and steep slopes. Lithologic reservoirs primarily occur near or within the central hydrocarbon-generating sub-sags. The most favorable hydrocarbon accumulation zones are located in the sub-sag centers and adjacent areas with high-quality reservoirs. Full article

Meeting the growing demand for vegetable oil while promoting agricultural sustainability in Northeast China requires developing high-yield, high-oil-content soybean varieties. We present the comprehensive development and evaluation of Heinong 551, an innovative soybean variety created through an integrated approach of conventional breeding methods and radiation-induced mutation techniques. The breeding program began with hybridization between Heinong 44 (the maternal parent) and Hefeng 47 (the paternal parent), followed by targeted exposure to ⁶⁰Co gamma radiation at 130 Gy to induce beneficial mutations. Using systematic selection protocols over five generations from 2012 to 2016, we identified superior lines that underwent rigorous multi-location testing across seven sites in Heilongjiang Province during 2020–2021. Field evaluation results showed consistent performance, with Heinong 551 achieving average yields of 2901 kg/ha and 3142 kg/ha in those years, representing significant gains of 10. 6% and 11.0. 0% compared to standard control varieties. The cultivar maintained stable phenological traits with a reliable 120-day maturation period and demonstrated strong environmental adaptability across different growing conditions. Biochemical analysis revealed excellent nutritional value, with 39.45% crude protein and 21.69% crude fat, reaching a combined protein–fat percentage of 61.14%. Quality tests confirmed superior seed integrity, with sound seed rates over 97% and minimal pest or disease damage. Disease resistance assessments showed moderate tolerance to gray leaf spot while maintaining excellent overall plant health, with no signs of viral infections or nematode infestations during testing. Heinong 551 has received official approval for cultivation in Heilongjiang Province’ s second accumulated temperature zone, characterized by thermal units ≥2550 °C above a 10 °C threshold. This represents significant progress in high-oil soybean variety development, illustrating the success of combining traditional breeding methods with modern mutation technology. Full article

This study systematically investigates the influence of laser pulse duration on cutting efficiency, heat-affected-zone (HAZ) formation, and mechanical integrity during carbon fiber-reinforced polymer (CFRP) laser cutting. Three distinct pulse-width lasers—picosecond, nanosecond, and quasi-continuous-wave (QCW)—are compared. Results show that pulse duration governs material removal mechanisms and HAZ extent: the nanosecond laser achieves the smallest HAZ and minimal porosity; the picosecond laser exhibits limited thermal accumulation due to low average power; and the QCW laser induces the largest HAZ (11.6 times that of the nanosecond laser) and significant porosity. Cutting efficiency scales inversely with pulse width, with single-hole processing times of 480.4 s for picosecond-laser cutting, 76.8 s for nanosecond-laser cutting, and 4.028 s for QCW-laser cutting, reflecting a transition from thermal ablation to mechanical spallation. Mechanical testing reveals that while tensile and flexural strengths vary by less than 5% across laser types, damage morphology and failure modes differ significantly. In situ digital image correlation (DIC) and 3D CT imaging show that longitudinal plies fail via fiber pull-out, whereas transverse plies fail via interfacial debonding. QCW-laser-cut specimens exhibit more uniform strain distribution and higher damage tolerance. An optimized process parameter is proposed: nanosecond-laser cutting at 200 W and 20 kHz achieves a HAZ of less than 50 µm and a cutting time of less than 80 s, offering the best balance between efficiency and quality. Full article

The evaluation of bioavailable forms of heavy metals in zones of anthropogenic pollution is the basis of ecological risk assessment. The characterization of the consequences of the operation of the Pechenganikel smelting plant was carried out using AAS and two methods of soil bioavailable forms of heavy metal extraction (3% nitric acid and ammonium acetate buffer with pH 4.8) along three directions from the plant, corresponding to the wind prevalence. Buffer extraction provided more significant correlations between Ni, Co, Cu, Pb, and Zn, compared to nitric acid application, indicating a negative correlation between soil Cu, Co, and the distance from the plant, while no significant correlations were recorded for nitric acid extracts. A higher significant correlation number arose between soil elements in buffer extracts along the N-E direction than the S-W one. In the former direction, the number of the mentioned correlations decreased according to the following sequence: Zn (6) > Cu (5) > Se and Co (4) > Ni and Fe (3); in nitric acid extract, only significant correlations of Cu, Zn, and Se with Co and Ni were recorded. Biocrust formation was revealed only along the N-E direction, characterized by unexpected high Se concentrations and intensive correlation between Zn and all the elements extracted by the buffer. Biocrust accumulated high levels of all the elements tested and showed antioxidant activity and polyphenol content significantly correlated with soil organic matter. The biocrust mineral content demonstrated a complex relationship with soil Fe, Cu (buffer extract), and Se, as well as Co and Zn (nitric acid extract). Application of linear mixed-effects modelling and transfer factor analysis indicate that biocrusts may serve as effective bioindicators of both absolute metal contamination and its bioavailable fractions. The results indicate the expediency of using both methods of soil extraction for assessing the ecological risk and soil–biocrust relationships. Full article

The escalating pressure on water resources in agricultural regions has become a catalyst for water conflicts. The adoption of innovative approaches to estimate actual evapotranspiration (ETa) offers potential solutions to mitigate conflicts related to water usage. This research presents the application of a remote sensing-based methodology for estimating actual evapotranspiration (ETa) based on a two-source energy balance model (TSEB) for riparian vegetation in Nebraska, US using the Spatial EvapoTranspiration Modeling Interface (SETMI). Estimated results through SETMI and field data using the eddy covariance system (EC) considering the period 2008–2013 were used to validate the energy balance components and ETa. Modeled energy balance components showed a strong correlation to the ground data from EC, with ET presenting R2 equal to 0.96 and RMSE of 0.73 mm.d⁻¹. In 2012, the lowest adjusted crop coefficient (Kcadj) values were observed across all land covers, with a mean value of 0.49. The years 2013 and 2012, due to the dry conditions, recorded the highest accumulated ETa values (706 mm and 664 mm, respectively). Soybeans and corn exhibited the highest ETa values, recording 699 mm and 773 mm, respectively. Corn and soybeans, together accounting for a substantial portion of the land cover at 15% and 3%, respectively, play a significant role. Given that most fields cultivating these crops are irrigated, both pumped groundwater and surface water directly impact the water source of the Republican River. The SETMI model has generated appropriate estimated daily ETa values, thereby affirming the model’s utility as a tool for assisting water management and decision-makers in riparian zones. Full article

This study focuses on the high-precision microhole machining of 304 stainless steel and explores a backwater-assisted picosecond laser trepanning technique. The laser used is a 30 W green picosecond laser with a wavelength of 532 nm, a repetition rate of 1000 kHz, and a pulse width of less than 15 ps. Experiments were conducted under both water-based and non-water-based laser processing environments to systematically investigate the effects of laser power and scanning cycles on hole roundness, taper, and overall hole quality. The experimental results further confirm the advantages of the backwater-assisted technique in reducing slag accumulation, minimizing roundness variation, and improving hole uniformity. In addition, thermal effects during the machining process were analyzed, showing that the water-based environment effectively suppresses the expansion of the heat-affected zone and mitigates recast layer formation, thereby enhancing hole wall quality. Compared with conventional non-water-based methods, the backwater-assisted approach demonstrates superior processing stability, better hole morphology, and more efficient thermal management. This work provides a reliable technical route and theoretical foundation for precision microhole machining of stainless steel and exhibits strong potential for engineering applications. Full article