Search Results (342)

Kumamoto is a city in Japan that relies completely on groundwater for drinking water. Groundwater in the Kumamoto region divided into shallow and deep aquifers. Around Lake Ezu, where one of Kumamoto City’s largest tap-water source wells are located, groundwater from both aquifers mixes, resulting in numerous springs. The aim of this study was to identify and quantify the relative contributions of the groundwater sources that discharge into Ezu Lake. River, lake, spring, and artesian well samples were collected every month between April 2021 and March 2022, and groundwater chemistry data for the shallow and deep aquifers were obtained from previous studies. The NO₃⁻ and SO₄²⁻ concentrations indicated three end-members: (A) high NO₃⁻ from anthropogenic sources, (B) high SO₄²⁻ from Shirakawa River water, and (C) low NO₃⁻ and SO₄²⁻ from denitrification or dilution. Mixing analysis show 60–70% from A, 17–22% from B, and 7–25% from C for the lake waters. Also, the result showed that springs in the Kami-Ezu area were dominated by shallow aquifer water, whereas artesian wells in the Shimo-Ezu area reflected deep aquifer water. This is the first time that the contributions of groundwater sources in this area have been quantified using a three-component mixing approach. Furthermore, it was estimated that Shirakawa River infiltration, including the artificial recharge project from rice paddy, contributed approximately 57% to groundwater discharge into Ezu Lake in 2020. These results provide new insights into the contribution of artificial recharge from agricultural land to groundwater. Full article

This article examines the effects of climate change on the 32 million inhabitants of the Megalopolis of Central Mexico (MCM), which is threatened by chaotic urbanization, land-use changes, the deforestation of the Forest of Water by organized crime, unsustainable agriculture, and biodiversity loss. Expensive hydraulic management extracting water from deep aquifers, long pipes exploiting water from neighboring states, and sewage discharged outside the endorheic basin result in expensive pumping costs and air pollution. This mismanagement has increased water scarcity. The overexploitation of aquifers and the pollution by toxic industrial and domestic sewage mixed with rainfall has increased the ground subsidence, damaging urban infrastructure and flooding marginal neighborhoods with toxic sewage. A system approach, satellite data, and participative research methodology were used to explore potential water scarcity and weakened water security for 32 million inhabitants. An alternative nature-based approach involves recovering the Forest of Water (FW) with IWRM, including the management of Natural Protected Areas, the rainfall recharge of aquifers, and cleaning domestic sewage inside the valley where the MCM is found. This involves recovering groundwater, reducing the overexploitation of aquifers, and limiting floods. Citizen participation in treating domestic wastewater with eco-techniques, rainfall collection, and purification filters improves water availability, while the greening of urban areas limits the risk of climate disasters. The government is repairing the broken drinking water supply and drainage systems affected by multiple earthquakes. Adaptation to water scarcity and climate risks requires the recognition of unpaid female domestic activities and the role of indigenous people in protecting the Forest of Water with the involvement of three state authorities. A digital platform for water security, urban planning, citizen audits against water authority corruption, and aquifer recharge through nature-based solutions provided by the System of Natural Protected Areas, Biological and Hydrological Corridors [SAMBA] are improving livelihoods for the MCM’s inhabitants and marginal neighborhoods, with greater equity and safety. Full article

This study investigates the transport of chloride, a conservative tracer and surrogate for contaminants, in the fractured Brunswick aquifer of northern New Jersey using a dual-porosity MODFLOW-MT3DMS model. Focusing on the First Watchung Mountain region—a microcosm of northern New Jersey’s hydrogeological environment encompassing Montclair State University and adjoining communities, the numerical model simulates groundwater flow and solute transport in a hydrogeologically complex, urbanized setting. Results indicate that chloride migrates through the fractured aquifer via both local flow systems (e.g., Third River) and regional flow systems (Passaic River) within decades. Chloride concentrations exceeded the EPA’s 250 mg/L threshold much faster in local discharge streams (5 years in the Third River) compared to regional base-level rivers (79 years in the Passaic River), demonstrating rapid fracture transport versus delayed matrix diffusion. Over 450 years, chlorides traveled approximately 7000 m, demonstrating potential for widespread salinization and contamination. The study also highlights “salting-out” effects, where elevated salinity enhances contaminant retention and complicates remediation efforts in fractured aquifers. These findings emphasize the need for integrated water management strategies, targeted deicing salt reduction, stormwater management, and recharge-zone protection, to mitigate long-term risks in fractured aquifers. By quantifying dual-domain dynamics previously unaddressed in the Brunswick aquifer, this work provides a framework for contaminant transport modeling and management in similar urbanized fractured systems. Full article

Mixing zones in carbonate coastal aquifers are dynamic interfaces where freshwater and seawater converge, triggering complex biogeochemical processes. This study investigates diagenetic barite (BaSO₄) precipitation within such a mixing zone in the dolomitic aquifer of the Sierra de Gádor (SE Spain). Three sectors were analyzed: two active mixing zones—one associated with submarine discharge and the other affected by marine intrusion—and an uplifted, fossilized Pleistocene mixing zone. Mineralogical, petrographic, and geochemical analyses reveal extensive dissolution of the dolomitic bedrock, forming polygonal voids and fracture-controlled porosity, frequently covered by Fe and Mn oxides. Barite crystals were identified exclusively in the Fe oxide precipitates at depths where 80% of seawater is reached. The saturation index for barite in groundwater suggests near-equilibrium conditions across the fresh–brackish–saline transition; however, barite precipitation is localized where Fe oxides act as a geochemical barrier, concentrating Ba and enabling nucleation. SEM imaging shows well-formed euhedral barite crystals up to 100 µm in size. This form of crystallization would be similar to the marine diagenetic barite formation models involving organic matter degradation and Ba remobilization, translated to a coastal aquifer setting in this study. Trace metal analyses show significant enrichment of Pb (up to 20 wt%) and other elements (Zn, Ni, and Co), suggesting potential for ore-forming processes if redox conditions shift. This work proposes a conceptual model for diagenetic barite formation in coastal aquifers, emphasizing the role of Fe and Mn oxides as reactive substrates in metal cycling at the land–sea interface. Full article

Managed aquifer recharge (MAR) can address challenges pertaining to water quality and security, land subsidence, and aquifer degradation. This study has been conducted in the irrigated plains of Indus River Basin (IRB) of Pakistan, where groundwater is being used for drinking, agriculture, industries, and other commercial purposes and where the Punjab Government is implementing the MAR project. The study aims to assess the existing level of heavy metals and trace elements contamination in the groundwater and to set baseline data for the suitability of the site for the MAR project. Groundwater samples from 20 tubewells were collected from an area of 1522 km² to investigate the level of heavy metals concentration in groundwater and to assess its suitability for irrigation and drinking. Samples were analyzed for Aluminum (Al), Arsenic (As), Barium (Ba), Cadmium (Cd), Cobalt (Co), Copper (Cu), Chromium (Cr), Lead (Pb), Manganese (Mn), Molybdenum (Mo), Nickel (Ni), Selenium (Se), Strontium (Sr), and Zinc (Zn). To elucidate the contamination trend of these metals, the Heavy Metal Pollution Index (HPI), Heavy Metal Index (HI), geostatistical description, Pearson correlation analysis, and geospatial mapping were employed. Results showed that groundwater in the study area is not suitable for drinking and may pose serious health risks. It should be, however, generally suitable for irrigation. This concludes that the site is suitable for the implementation of a MAR project where the intended use of groundwater is for irrigation. It has been recommended that the groundwater may not be used for direct human consumption in the study area. It has been recommended, too, that targeted monitoring of identified hotspots and assessment of soil and crop uptake are conducted so that industrial or wastewater discharge into irrigation supplies may be prevented and controlled. For policy decisions, distinguishing irrigation suitability from potable-water safety is essential. Full article

Arid inland basins represent critical hotspots of intensified conflict among water resources, ecological integrity, and economic development on a global scale. The coevolution of groundwater systems and land use patterns plays a pivotal role in shaping regional sustainability trajectories. This study synthesizes multi-source data spanning 2000 to 2020 from the Wuwei Basin, located within the Shiyang River watershed in China, to elucidate the synergistic dynamics between hydrological and land use transformations. Key findings reveal: (1) Around 2010, a significant structural shift in land use occurred, transitioning from production-oriented expansion to ecologically driven priorities. This shift was characterized by a reduction in cultivated land, increased utilization of artificial surfaces, and accelerated ecological restoration efforts. These changes were jointly influenced by enhanced water governance frameworks and spatial planning policies. (2) Groundwater levels exhibit marked spatial variability. While stability is maintained in piedmont and discharge zones, persistent overdraft has led to pronounced declines in transitional and distal recharge areas. This heterogeneity is primarily governed by the interplay of hydrogeological factors—such as recharge capacity and aquifer permeability—and anthropogenic pressures, including the extent of cultivated land and intensity of groundwater extraction. Notably, these patterns cannot be explained solely by the proportion of cultivated land or total extraction volumes. (3) A positive feedback mechanism—termed the “gain-loss regime shift”—has been identified in the discharge zone, where simultaneous increases in groundwater extraction and water-level recovery are observed. However, human activities have disrupted the natural coupling between precipitation and groundwater recharge, resulting in a significant attenuation of recharge rates (exceeding 80%). These findings offer a robust scientific basis for implementing spatially differentiated water resource management strategies and optimizing land use in arid basin environments. The implications extend beyond regional contexts, contributing to broader efforts in harmonizing human–environment interactions globally. Full article

The sustainable use and management of groundwater resources is a challenging issue due to population growth and climate change. Accurate quantification of groundwater recharge is a basic requirement for effective groundwater resource management, yet it is still lacking in many areas around the world. The study was designed to estimate recharge to groundwater from natural rainfall in the Gilgel Gibe and Dhidhessa catchments in southwestern Ethiopia, employing the water table fluctuation (WTF) and chloride mass balance (CMB) techniques. These methods are being applied for the first time in the study area and have not previously been used in these catchments. Given the region’s data scarcity, a community-based data collection program was implemented and supplemented with additional field measurements and secondary data sources. Groundwater level, spring discharge, and rainfall were monitored over the 2022/2023 hydrological year. Groundwater level fluctuations were found to be influenced by topography and rainfall patterns, reaching 8.2 m in amplitude in the upstream part of the catchments. Chloride concentrations were determined in groundwater samples collected from hand-dug wells and springs, and rainwater was also collected. Rainwater exhibited a mean chloride concentration of 2.46 mg/L, while groundwater chloride concentrations ranged from 3 mg/L to 36.99 mg/L. The estimated recharge rates varied spatially, ranging from 170 to 850 mm/year using the CMB method (11% to 55% of annual rainfall, mean recharge rate of 454 mm/year) and from 76 to 796 mm/year using the WTF method (4% to 43% of annual rainfall, mean recharge rate of 439 mm/year). Notably, recharge estimates were lowest downstream in the lowland areas and highest upstream in the highland regions. Rainfall amount, local lithology, and topography were identified as major influences on groundwater recharge across the study area. Both CMB and WTF methods were deemed applicable in the volcanic aquifers, provided that all the respective assumptions are followed. This study significantly contributes to the groundwater dataset for the region, in addition to recharge estimation and the research conclusions, emphasizing the importance of long-term monitoring and time series analysis of chloride data to reduce uncertainties. The work serves as a valuable reference for researchers, policymakers, and regional water resource managers. Full article

The Puebla Metropolitan Area, one of the most industrialized regions in Mexico, shows severe contamination of both surface and groundwater. In this study a multi-tracer approach combining hydrochemistry with environmental isotopes (δ²H, δ¹⁸O, ³H) was applied to evaluate groundwater–surface water (GW–SW) interactions and their role in water quality degradation. Elevated concentrations of aluminum, iron, zinc, and lead were detected in the Alseseca and Atoyac Rivers, exceeding national standards, while arsenic, manganese, and lead in groundwater surpassed Mexican and WHO drinking water limits. The main sources of contamination include volcanic inputs from Popocatepetl activity (e.g., arsenic) and untreated discharges from industrial parks (e.g., lead), which together introduce significant loads of Potentially Toxic Elements (PTEs) into surface and groundwater. Isotopic analysis identified three sources for aquifer recharge: (1) recharge from high-altitude meteoric water, (2) mixed GW–SW water recharged at intermediate elevations with heavy metal presence, and (3) recharge from lower altitudes (evaporate water). Tritium confirmed both modern and old recharge, while isotope-based mixing models indicated surface water contributions to groundwater ranging from 18% to 72%. These interpretations were derived from the integrated analysis of hydrochemical and isotopic data, allowing the quantification of recharge sources, residence times, and mixing processes. The results demonstrate that hydraulic connectivity, enhanced by fractures and faults, facilitates contaminant transfer from polluted rivers into the aquifer. Full article

Although many studies have examined reaction zones in groundwater–seawater mixing areas, little attention has been given to how subsurface processes drive changes in iron (Fe) precipitation over time and space. This gap has limited our understanding of the “iron curtain” phenomenon in coastal aquifers. To address this, this study developed a reactive transport model to investigate how porosity evolves during the oxidative precipitation of Fe(II) in porous media. The model incorporates the dynamic effects of tortuosity, diffusivity, and surface area as minerals accumulate. Validation experiments, conducted with syringe tests that simulated Fe precipitation during freshwater–saltwater mixing, showed that precipitates formed mainly near the inlets, reflecting the development of a geochemical barrier at the groundwater–seawater interface. Scanning electron microscopy confirmed that Fe precipitates coated the surfaces of spherical particles. Numerical simulations further revealed that high Fe(II) concentrations drove pore clogging near the inlet, creating a dense precipitation zone akin to the iron curtain in coastal aquifers. At 10 mmol/L Fe(II), local clogging was observed, while at 100 mmol/L Fe(II), outflow rates (i.e., discharge) were substantially reduced. Together, the experiments and simulations highlight how hydrogeochemical processes influence hydraulic properties during the oxidative precipitation of Fe(II) in mixing zones. Full article

Karst aquifers are critical yet vulnerable water resources in semi-arid Mediterranean regions, where structural complexity, nonlinearity, and delayed hydrological responses pose significant modeling challenges under increasing climatic and anthropogenic pressures. This study examines the Jebel Zaghouan aquifer in northeastern Tunisia, aiming to simulate its natural discharge dynamics prior to intensive exploitation (1915–1944). Given the fragmented nature of historical datasets, meteorological inputs (rainfall, temperature, and pressure) were reconstructed using a data recovery process combining linear interpolation and statistical distribution fitting. The hyperparameters of the artificial neural network (ANN) model were optimized through a Bayesian search. Three deep learning architectures—Multi-Layer Perceptron (MLP), Convolutional Neural Network (CNN), and Long Short-Term Memory (LSTM)—were trained to model spring discharge. Model performance was evaluated using Kling–Gupta Efficiency (KGE′), Nash–Sutcliffe Efficiency (NSE), and R² metrics. Hydrodynamic characterization revealed moderate variability and delayed discharge response, while isotopic analyses (δ¹⁸O, δ²H, ³H, ¹⁴C) confirmed a dual recharge regime from both modern and older waters. LSTM outperformed other models at the weekly scale (KGE′ = 0.62; NSE = 0.48; R² = 0.68), effectively capturing memory effects. This study demonstrates the value of combining historical data rescue, ANN modeling, and hydrogeological insight to support sustainable groundwater management in data-scarce karst systems. Full article

The construction of underground infrastructure in urban environments can significantly alter groundwater flow dynamics, particularly in karst settings, which are characterized by high permeability, rapid groundwater flow, and strong spatial variability in recharge and discharge processes. Tunneling in a karst system can severely deplete an aquifer and undermine the sustainability of water resources over the long term. These impacts pose significant challenges for regional water resources management, highlighting the urgent need for strategies that support both sustainable development and the protection of these complex hydrogeological systems. One of the most critical consequences of such construction activities can be tunnel drainage, which can modify the hydrogeological balance of karst aquifers. For this reason, an accurate estimation of groundwater recharge remains a major challenge, yet it is essential for effective groundwater management, particularly in regions that rely heavily on karst groundwater resources. This paper proposes a GIS-based methodological framework to assess the active recharge of the karst aquifer feeding the Mazzoccolo Spring, located in the urban area of Formia (southern Latium Region, Central Italy), which is potentially affected by a planned underground infrastructure. The study focuses on delineating the recharge area and evaluating the potential impacts of tunneling on this complex and sensitive hydrogeological system. Full article

The precise and accurate use of aquifer hydraulic parameters for assessing local and regional recharge potential for enhancing groundwater allocation planning is vital for many hydrogeological studies. The conventional approach for allocating groundwater presents a challenging scenario, as it remains uncertain whether the applied recharge estimate is local or regional recharge. The approach does not account for the extent of the aquifer recharge in terms of local and regional scale; instead, it assumes that recharge is distributed across the catchment. This study aimed to demonstrate the use of aquifer hydraulic parameters (transmissivity and storativity) to explain areas of potential recharge (local and regional) for enhancing groundwater allocation planning with a specific case study of De Aar, Northern Cape, South Africa. It argues that not integrating local and regional recharge potentials in planning for groundwater allocations can result in over- or under-allocation of groundwater resources to users. A constant discharge pumping test and recovery test matching the duration of pumping were conducted for data collection. The Flow Characteristics method was used as a diagnostic tool to understand the different aquifer flow regimes in the study area. To develop an integrated understanding of the groundwater system, a hydrogeological conceptual model was used to visualize areas with higher or lower recharge potential across local and regional scales. Results showed significant variability in transmissivity, ranging from 213 to 596 m²/d, and storativity, ranging from 0.0000297 to 0.000185. The transmissivity values suggest that groundwater moves faster; meanwhile, the storativity values suggest that the aquifer system has high water storage capacity. These results will assist water resource planners in making informed decisions on how to allocate groundwater to users. This study demonstrated that aquifer hydraulic parameters are a valuable tool for improving groundwater allocations, thereby highlighting the importance of considering areas for potential recharge, both local and regional, in planning groundwater allocation. Full article

Understanding groundwater quality in karst environments is essential, particularly in semi-arid regions where water resources are highly vulnerable to both climatic variability and anthropogenic pressures. The Ghar Boumaaza karst aquifer, located in the semi-arid Tlemcen Mountains of Algeria, represents a critical yet understudied water resource increasingly threatened by climate change and human activity. This study integrates hydrochemical analysis, multivariate statistical techniques, and predictive modeling to assess groundwater quality and characterize the relationship between total dissolved solids (TDSs) and discharge (Q). An analysis of 66 water samples revealed that 96.97% belonged to a Ca²⁺–HCO₃⁻ facies, reflecting carbonate rock dissolution, while 3% exhibited a Cl⁻–HCO₃⁻ facies associated with agricultural contamination. A principal component analysis identified carbonate weathering (40.35%) and agricultural leaching (18.67%) as the dominant drivers of mineralization. A third-degree polynomial regression model (R² = 0.953) effectively captured the nonlinear relationship between TDSs and flow, demonstrating strong predictive capacity. Independent validation (R² = 0.954) confirmed the model’s robustness and reliability. This study provides the first integrated hydrogeochemical assessment of the Ghar Boumaaza system in decades and offers a transferable methodological framework for managing vulnerable karst aquifers under similar climatic and anthropogenic conditions. Full article

Rapid socio-economic development and the impact of human activities have exerted tremendous pressure on the groundwater system of the Dawen River Basin (DRB), the largest tributary in the middle and lower reaches of the Yellow River. Hydrochemical studies on the DRB have largely centered on the upstream Muwen River catchment and downstream Dongping Lake, with some focusing solely on karst groundwater. Basin-wide evaluations suggest good overall groundwater quality, but moderate to severe contamination is confined to the lower Dongping Lake area. The hydrogeologically complex mid-reach, where the Muwen and Chaiwen rivers merge, warrants specific focus. This region, adjacent to populous areas and industrial/agricultural zones, features diverse aquifer systems, necessitating a thorough analysis of its hydrochemistry and origins. This study presents an integrated hydrochemical, isotopic investigation and EWQI evaluation of groundwater quality and formation mechanisms within the multiple groundwater types of the central DRB. Central DRB groundwater has a pH of 7.5–8.2 (avg. 7.8) and TDSs at 450–2420 mg/L (avg. 1075.4 mg/L) and is mainly brackish, with Ca²⁺ as the primary cation (68.3% of total cations) and SO₄²⁻ (33.6%) and NO₃⁻ (28.4%) as key anions. The Piper diagram reveals complex hydrochemical types, primarily HCO₃·SO₄-Ca and SO₄·Cl-Ca. Isotopic analysis (δ²H, δ¹⁸O) confirms atmospheric precipitation as the principal recharge source, with pore water showing evaporative enrichment due to shallow depths. The Gibbs diagram and ion ratios demonstrate that hydrochemistry is primarily controlled by silicate and carbonate weathering (especially calcite dissolution), active cation exchange, and anthropogenic influences. EWQI assessment (avg. 156.2) indicates generally “good” overall quality but significant spatial variability. Pore water exhibits the highest exceedance rates (50% > Class III), driven by nitrate pollution from intensive vegetable cultivation in eastern areas (Xiyangzhuang–Liangzhuang) and sulfate contamination from gypsum mining (Guojialou–Nanxiyao). Karst water (26.7% > Class III) shows localized pollution belts (Huafeng–Dongzhuang) linked to coal mining and industrial discharges. Compared to basin-wide studies suggesting good quality in mid-upper reaches, this intensive mid-reach sampling identifies critical localized pollution zones within an overall low-EWQI background. The findings highlight the necessity for aquifer-specific and land-use-targeted groundwater protection strategies in this hydrogeologically complex region. Full article

The global shift towards the use of renewable energy is essential to ensure sustainable development, and geothermal energy stands out as a suitable option that can support various cascading projects. Spent geothermal water (SGW) requires proper treatment to ensure that it does not become an environmental burden. Typically, companies often face the dilemma of choosing between discharging spent geothermal water (SGW) into surface waters or injecting it into rock masses, and the economic and environmental impacts of the decision made determines the feasibility of geothermal plant development. In this study, we aimed to comprehensively assess the technical, economic, and environmental feasibility of SGW injection into rock masses. To this end, we employed a comprehensive analytical approach using the Chochołów GT-1 geothermal injection borehole in Poland as a reference case. We also performed drilling and hydrogeological testing, characterized rock samples in the laboratory, and corrected hydrodynamic parameters for thermal lift effects to ensure accurate aquifer characterization. The results obtained highlight the importance of correcting hydrogeological parameters for thermal effects, which if neglected can lead to a significant overestimation of the calculated hydrogeological parameters. Based on our analysis, we developed a framework for assessing SGW injection feasibility that integrates detailed hydrogeological and geotechnical analyses with environmental risk assessment to ensure sustainable geothermal resource exploitation. This framework should be mandatory for planning new geothermal power plants or complexes worldwide. Our results also emphasize the need for adequate SGW management so as to ensure that the benefits of using a renewable and zero-emission resource, such as geothermal energy, are not compromised by the low absorption capacity of rock masses or adverse environmental effects. Full article