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Keywords = gamma titanium aluminide

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13 pages, 4388 KB  
Article
Robust γ-TiAl Dual Microstructure Concept by Advanced Electron Beam Powder Bed Fusion Technology
by Marcel Reith, Martin Franke and Carolin Körner
Crystals 2023, 13(9), 1348; https://doi.org/10.3390/cryst13091348 - 5 Sep 2023
Cited by 1 | Viewed by 2244
Abstract
The dual microstructure concept for gamma titanium aluminides (γ-TiAl) processed via electron beam–powder bed fusion (PBF-EB) provides a huge potential for more efficient jet turbine engines. While the concept is feasible and the mechanical properties are promising, there are still some challenges. For [...] Read more.
The dual microstructure concept for gamma titanium aluminides (γ-TiAl) processed via electron beam–powder bed fusion (PBF-EB) provides a huge potential for more efficient jet turbine engines. While the concept is feasible and the mechanical properties are promising, there are still some challenges. For an industrial application, the heat treatment window has to match the conditions in industrial furnaces. This study shows how the required heat treatment window can be achieved via advanced PBF-EB technology. Through using an electron beam with 150 kV acceleration voltage, the difference in aluminum between the designed aluminum-rich and aluminum-lean regions of the part is increased. Moreover, the aluminum content within each of these regions, respectively, is more homogenous compared to the 60 kV acceleration voltage. This combination provides a heat treatment window of 25 °C, enabling the industrial application of the dual microstructure concept for γ-TiAl. Full article
(This article belongs to the Special Issue Additive Manufacturing of Metallic Alloys)
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19 pages, 7200 KB  
Article
Insights on Niobium Micro-Alloyed Laser In Situ Synthesised Gamma Titanium Aluminide Alloys
by Monnamme Tlotleng, Sisa Pityana and Sibusisiwe Motha
Appl. Sci. 2023, 13(9), 5725; https://doi.org/10.3390/app13095725 - 6 May 2023
Cited by 4 | Viewed by 2200
Abstract
The effects of micro-alloying gamma titanium aluminide (γ-TiAl) with niobium (Nb) using a laser melt pool as a melting pot are reported. The Optomec LENS machine was used to carry out the laser in situ alloying experiments where Nb, ranging from 6 to [...] Read more.
The effects of micro-alloying gamma titanium aluminide (γ-TiAl) with niobium (Nb) using a laser melt pool as a melting pot are reported. The Optomec LENS machine was used to carry out the laser in situ alloying experiments where Nb, ranging from 6 to 10 (at. %), was added to the stable binary γ-TiAl alloy. The results of this study concluded that when a stable binary γ-TiAl alloy is micro-alloyed with Nb, there is a definite microstructural transformation, anneal twinning, promotion, and retardation of aluminium solubility in the dual and pure γ phases, respectively. Twinning in the as-built in situ alloyed ternary Ti–48Al–xNb was for the first time reported in this study. It was observed that 6 at. % Nb promoted twinning in the as-built sample, which inferred that the sample might have room temperature ductility. In fact, it was shown that the twins formed in the as-built sample dissipated with the addition of Nb. A heat treatment temperature of 1200 °C promoted anneal twinning only in the binary alloy, as confirmed by XRD data. Meanwhile, this twinning was absent in all the ternary alloys when they were heat treated to a temperature of 1200 °C. Anneal twinning was confirmed only for the alloy containing 8 Nb (at. %) at 1400 °C. Stalk faults, dislocations, and dislocation pile-ups were observed in the α2 phase of the alloys. Aluminium solubility was seen to increase in the α2 + γ (±49 at. %) phase alloy and sharply decrease in the pure γ (>49 at. %) phase alloys. Most importantly, this study determined that the laser in situ alloying process was highly exothermic. The heat gained by the reaction was found to increase with the increase in niobium content. Full article
(This article belongs to the Special Issue Heat Treatment of Metals and Alloys)
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14 pages, 5198 KB  
Review
Advancements and Prospects in Electro-Sinter-Forging
by Alessandro Fais
Metals 2022, 12(5), 748; https://doi.org/10.3390/met12050748 - 27 Apr 2022
Cited by 2 | Viewed by 3040
Abstract
A summary of the recent advancements, future prospects and open issues in the materials, methods and machines for the technology known as electro-sinter-forging is presented here. After a background introduction, the key characteristics of the procedure are explained. Metal systems that have been [...] Read more.
A summary of the recent advancements, future prospects and open issues in the materials, methods and machines for the technology known as electro-sinter-forging is presented here. After a background introduction, the key characteristics of the procedure are explained. Metal systems that have been processed based on iron, copper and aluminium are discussed as single elements, and as alloys and composites. Intermetallic materials such as gamma titanium aluminide, Nd2Fe14B and Bi2Te3 are finally presented before discussing the experimental evidence of the atomic diffusion mechanisms involved, and a critical assessment of the limitations of the technique is performed. Full article
(This article belongs to the Special Issue Recent Advances in Field-Assisted Sintering Technologies)
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18 pages, 10439 KB  
Article
Optimization of the Dry Turning Process of Ti48Al2Cr2Nb Aluminide Based on the Cutting Tool Configuration
by Enrique García-Martínez, Valentín Miguel, Alberto Martínez-Martínez, Juana Coello, Jesús Andrés Naranjo and María Carmen Manjabacas
Materials 2022, 15(4), 1472; https://doi.org/10.3390/ma15041472 - 16 Feb 2022
Cited by 13 | Viewed by 2527
Abstract
Titanium aluminides are one of the most promising materials in aeronautical and automotive applications. However, their low machinability makes the processing of these alloys quite difficult under sustainability conditions, specially without lubrication. The current study focuses on the turning process of the Ti48Al2Cr2Nb [...] Read more.
Titanium aluminides are one of the most promising materials in aeronautical and automotive applications. However, their low machinability makes the processing of these alloys quite difficult under sustainability conditions, specially without lubrication. The current study focuses on the turning process of the Ti48Al2Cr2Nb gamma titanium aluminide under dry conditions. As far as we are aware, dry cutting is the most sustainable feature, although it has not been traditionally applied on titanium aluminides due to the accelerated tool wear that the material promotes. The main novelty of this work consists of providing a simple solution for reducing the tool wear based on the inclination of the cutting insert, what is evaluated in terms of tool wear and tool life, cutting forces, cutting temperature, surface integrity of the machined part, as well as its microhardness and microstructural effects. The results shown here clearly point out a better performance of the machining process. This fact could be understood if we take into consideration that an increment of the clearance angle from 6.3° to 11.6° and 15° increases the tool life by five and six times, respectively, using efficient cutting speeds, whose values have increased by 50% with respect to the original cutting conditions. This improvement is explained according to the reduction in the cutting temperature and friction forces in the flank face of the tool. In addition, the use of uncoated carbide inserts may lead to a better behaviour than the coated ones, considering the results obtained for a PVD TiAlN + AlCr2O3 coated insert herein researched. Full article
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18 pages, 7500 KB  
Article
A Novel Approach for Real-Time Quality Monitoring in Machining of Aerospace Alloy through Acoustic Emission Signal Transformation for DNN
by David Adeniji, Kyle Oligee and Julius Schoop
J. Manuf. Mater. Process. 2022, 6(1), 18; https://doi.org/10.3390/jmmp6010018 - 25 Jan 2022
Cited by 22 | Viewed by 4694
Abstract
Gamma titanium aluminide (γ-TiAl) is considered a high-performance, low-density replacement for nickel-based superalloys in the aerospace industry due to its high specific strength, which is retained at temperatures above 800 °C. However, low damage tolerance, i.e., brittle material behavior with a propensity to [...] Read more.
Gamma titanium aluminide (γ-TiAl) is considered a high-performance, low-density replacement for nickel-based superalloys in the aerospace industry due to its high specific strength, which is retained at temperatures above 800 °C. However, low damage tolerance, i.e., brittle material behavior with a propensity to rapid crack propagation, has limited the application of γ-TiAl. Any cracks introduced during manufacturing would dramatically lower the useful (fatigue) life of γ-TiAl components, making the workpiece surface’s quality from finish machining a critical component to product quality and performance. To address this issue and enable more widespread use of γ-TiAl, this research aims to develop a real-time non-destructive evaluation (NDE) quality monitoring technique based on acoustic emission (AE) signals, wavelet transform, and deep neural networks (DNN). Previous efforts have opted for traditional approaches to AE signal analysis, using statistical feature extraction and classification, which face challenges such as the extraction of good/relevant features and low classification accuracy. Hence, this work proposes a novel AI-enabled method that uses a convolutional neural network (CNN) to extract rich and relevant features from a two-dimensional image representation of 1D time-domain AE signals (known as scalograms), subsequently classifying the AE signature based on pedigreed experimental data and finally predicting the process-induced surface quality. The results of the present work show good classification accuracy of 80.83% using scalogram images, in-situ experimental data, and a VGG-19 pre-trained neural network, establishing the significant potential for real-time quality monitoring in manufacturing processes. Full article
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23 pages, 4627 KB  
Review
Microstructure Design and Its Effect on Mechanical Properties in Gamma Titanium Aluminides
by Xuqi Liu, Qia Lin, Wenjing Zhang, Constance Van Horne and Limei Cha
Metals 2021, 11(10), 1644; https://doi.org/10.3390/met11101644 - 16 Oct 2021
Cited by 18 | Viewed by 6959
Abstract
Intermetallic gamma titanium aluminides display attractive engineering properties at high temperatures of up to 750 °C. To date, they have been used in low-pressure turbine blades and turbocharger rotors in advanced aircraft and automotive engines. This review summarizes the fundamental information of the [...] Read more.
Intermetallic gamma titanium aluminides display attractive engineering properties at high temperatures of up to 750 °C. To date, they have been used in low-pressure turbine blades and turbocharger rotors in advanced aircraft and automotive engines. This review summarizes the fundamental information of the Ti–Al system. After providing the development of γ TiAl alloys, typical phases, microstructures and their characteristics in TiAl alloys, the paper focuses on the effects of alloying elements on the phase boundary shifting, stabilizing effects and strengthening mechanism. The relationships between chemical additions, microstructure evolution and mechanical properties of the alloy are discussed. In parallel, the processing technologies and the common heat treatment methods are described in detail, both of which are applied to optimize the mechanical properties via adjusting microstructures. On this basis, the effects from chemical composition, processing technologies and heat treatments on microstructure, which controls the mechanical properties, can be obtained. It has a certain guiding significance for tailoring the microstructures to gain desired mechanical properties. Full article
(This article belongs to the Special Issue Microstructure and Properties of High Temperature Intermetallic)
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19 pages, 5109 KB  
Article
Electron Beam Powder Bed Fusion of γ-Titanium Aluminide: Effect of Processing Parameters on Part Density, Surface Characteristics, and Aluminum Content
by Juliane Moritz, Mirko Teschke, Axel Marquardt, Lukas Stepien, Elena López, Frank Brückner, Marina Macias Barrientos, Frank Walther and Christoph Leyens
Metals 2021, 11(7), 1093; https://doi.org/10.3390/met11071093 - 9 Jul 2021
Cited by 15 | Viewed by 4203
Abstract
Gamma titanium aluminides are very interesting for their use in high-performance applications such as aircraft engines due to their low density, high stiffness and favorable high-temperature properties. However, the pronounced brittleness of these intermetallic alloys is a major challenge for their processing through [...] Read more.
Gamma titanium aluminides are very interesting for their use in high-performance applications such as aircraft engines due to their low density, high stiffness and favorable high-temperature properties. However, the pronounced brittleness of these intermetallic alloys is a major challenge for their processing through conventional fabrication methods. Additive manufacturing by means of electron beam powder bed fusion (EB-PBF) significantly improves the processability of titanium aluminides due to the high preheating temperatures and facilitates complex components. The objective of this study was to determine a suitable processing window for EB-PBF of the TNM-B1 alloy (Ti-43.5Al-4Nb-1Mo-0.1B), using an increased aluminum content in the powder raw material to compensate for evaporation losses during the process. Design of experiments was used to evaluate the effect of beam current, scan speed, focus offset, line offset and layer thickness on porosity. Top surface roughness was assessed through laser scanning confocal microscopy. Scanning electron microscopy, electron backscatter diffraction (EBSD) and energy-dispersive X-ray spectroscopy (EDX) were used for microstructural investigation and to analyze aluminum loss depending on the volumetric energy density used in EB-PBF. An optimized process parameter set for achieving part densities of 99.9% and smooth top surfaces was derived. The results regarding microstructures and aluminum evaporation suggest a solidification via the β-phase. Full article
(This article belongs to the Special Issue TiAl-Based Alloys and Their Applications)
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12 pages, 4119 KB  
Article
Influence of Shot Peening on the Isothermal Fatigue Behavior of the Gamma Titanium Aluminide Ti-48Al-2Cr-2Nb at 750 °C
by Christoph Breuner, Stefan Guth, Elias Gall, Radosław Swadźba, Jens Gibmeier and Martin Heilmaier
Metals 2021, 11(7), 1083; https://doi.org/10.3390/met11071083 - 6 Jul 2021
Cited by 10 | Viewed by 2848
Abstract
One possibility to improve the fatigue life and strength of metallic materials is shot peening. However, at elevated temperatures, the induced residual stresses may relax. To investigate the influence of shot peening on high-temperature fatigue behavior, isothermal fatigue tests were conducted on shot-peened [...] Read more.
One possibility to improve the fatigue life and strength of metallic materials is shot peening. However, at elevated temperatures, the induced residual stresses may relax. To investigate the influence of shot peening on high-temperature fatigue behavior, isothermal fatigue tests were conducted on shot-peened and untreated samples of gamma TiAl 48-2-2 at 750 °C in air. The shot-peened material was characterized using EBSD, microhardness, and residual stress analyses. Shot peening leads to a significant increase in surface hardness and high compressive residual stresses near the surface. Both effects may have a positive influence on lifetime. However, it also leads to surface notches and tensile residual stresses in the bulk material with a negative impact on cyclic lifetime. During fully reversed uniaxial tension-compression fatigue tests (R = −1) at a stress amplitude of 260 MPa, the positive effects dominate, and the fatigue lifetime increases. At a lower stress amplitude of 230 MPa, the negative effect of internal tensile residual stresses dominates, and the lifetime decreases. Shot peening leads to a transition from surface to volume crack initiation if the surface is not damaged by the shots. Full article
(This article belongs to the Special Issue TiAl-Based Alloys and Their Applications)
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10 pages, 4325 KB  
Article
Microstructure Evolution and Mechanical Properties of Spark Plasma Sintered Manganese Addition on Ti-48Al-2Cr-2Nb Alloys
by A. Raja Annamalai, Muthe Srikanth, Raunak Varshney, Mehta Yash Ashokkumar, Swarup Kumar Patro and Chun-Ping Jen
Metals 2020, 10(12), 1577; https://doi.org/10.3390/met10121577 - 25 Nov 2020
Cited by 7 | Viewed by 3573
Abstract
Titanium aluminide (TiAl) is one of the most promising materials for aerospace applications. It is a suitable replacement for nickel-based superalloys predominantly used in these applications. Titanium aluminide with superior processability is the main task in carrying out this work. A less brittle [...] Read more.
Titanium aluminide (TiAl) is one of the most promising materials for aerospace applications. It is a suitable replacement for nickel-based superalloys predominantly used in these applications. Titanium aluminide with superior processability is the main task in carrying out this work. A less brittle TiAl alloy was fabricated using spark plasma sintering by adding the nominal composition (2.5, 5, and 7.5 wt.%) of manganese (Mn) to Ti-48Al-2Cr-2Nb. The samples were sintered at 1150 °C using spark plasma sintering (SPS), which helped produce highly dense models with fine grain sizes at the high heating rate (here, 100 °C per minute). The effects produced by Mn additions on the densification, mechanical properties (yield strength, hardness, and % elongation), and microstructure of the Ti aluminide alloys are studied. Scanning electron microscopy (SEM) has been used to explore the sintered samples’ microstructures. The alloyed materials are entirely dissolved in the gamma matrix due to the manganese approaching its melting point. XRD and SEM analysis confirmed the new intermetallic related to Mn neither with titanium nor aluminum. The enhancement of % elongation at break is evident for the little improvement in the ductility of TiAl by the addition of Mn. The samples’ tensile fracture nature is also evidence for enhancement in the alloy’s % elongation. Full article
(This article belongs to the Special Issue Spark Plasma Sintering of Metals and Metal Matrix Nanocomposites)
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14 pages, 2682 KB  
Article
Sensitivity Analysis of Tool Wear in Drilling of Titanium Aluminides
by Aitor Beranoagirre, Gorka Urbikain, Raúl Marticorena, Andrés Bustillo and Luis Norberto López de Lacalle
Metals 2019, 9(3), 297; https://doi.org/10.3390/met9030297 - 6 Mar 2019
Cited by 14 | Viewed by 3494
Abstract
In the aerospace industry, a large number of holes need to be drilled to mechanically connect the components of aircraft engines. The working conditions for such components demand a good response of their mechanical properties at high temperatures. The new gamma TiAl are [...] Read more.
In the aerospace industry, a large number of holes need to be drilled to mechanically connect the components of aircraft engines. The working conditions for such components demand a good response of their mechanical properties at high temperatures. The new gamma TiAl are in the transition between the 2nd and 3rd generation, and several applications are proposed for that sector. Thus, NASA is proposing the use of the alloys in the Revolutionary Turbine Accelerator/Turbine-Based Combined Cycle (RTA/TBCC) Program for the next-generation launch vehicle, with gamma TiAl as a potential compressor and structural material. However, the information and datasets available regarding cutting performance in titanium aluminides are relatively scarce. So, a considerable part of the current research efforts in this field is dedicated to process optimization of cutting parameters and tool geometries. The present work is framed in the study of wear when machining holes in these difficult-to-cut alloys. In particular, the work presents the results from drilling tests on three types of gamma TiAl alloys, extruded MoCuSi, ingot MoCuSi, and TNB type, to define an optimal set of cutting parameters. Maintaining uniform, gradual wear is key to avoiding tool breakage and enabling good hole dimensional accuracy. So, this paper proposes a model based on ANOVA analysis to identify the relationships between cutting conditions and resulting wear and estimate tool life. The best cutting parameters were found at vc = 10–15 m/min and fn = 0.025 mm/rev. Full article
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13 pages, 2161 KB  
Article
Drilling Process in γ-TiAl Intermetallic Alloys
by Aitor Beranoagirre, Gorka Urbikain, Amaia Calleja and Luis Norberto López de Lacalle
Materials 2018, 11(12), 2379; https://doi.org/10.3390/ma11122379 - 26 Nov 2018
Cited by 17 | Viewed by 4184
Abstract
Gamma titanium aluminides (γ-TiAl) present an excellent behavior under high temperature conditions, being a feasible alternative to nickel-based superalloy components in the aeroengine sector. However, considered as a difficult to cut material, process cutting parameters require special study to guarantee component quality. In [...] Read more.
Gamma titanium aluminides (γ-TiAl) present an excellent behavior under high temperature conditions, being a feasible alternative to nickel-based superalloy components in the aeroengine sector. However, considered as a difficult to cut material, process cutting parameters require special study to guarantee component quality. In this work, a developed drilling mechanistic model is a useful tool in order to predict drilling force (Fz) and torque (Tc) for optimal drilling conditions. The model is a helping tool to select operational parameters for the material to cut by providing the programmer predicted drilling forces (Fz) and torque (Tc) values. This will allow the avoidance of operational parameters that will cause excessively high force and torque values that could damage quality. The model is validated for three types of Gamma-TiAl alloys. Integral hard metal end-drilling tools and different cutting parameters (feeds and cutting speeds) are tested for three different sized holes for each alloy. Full article
(This article belongs to the Special Issue Machining—Recent Advances, Applications and Challenges)
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16 pages, 1107 KB  
Article
A Model for Creep and Creep Damage in the γ-Titanium Aluminide Ti-45Al-2Mn-2Nb
by William Harrison, Zakaria Abdallah and Mark Whittaker
Materials 2014, 7(3), 2194-2209; https://doi.org/10.3390/ma7032194 - 14 Mar 2014
Cited by 25 | Viewed by 11695
Abstract
Gamma titanium aluminides (γ-TiAl) display significantly improved high temperature mechanical properties over conventional titanium alloys. Due to their low densities, these alloys are increasingly becoming strong candidates to replace nickel-base superalloys in future gas turbine aeroengine components. To determine the safe operating life [...] Read more.
Gamma titanium aluminides (γ-TiAl) display significantly improved high temperature mechanical properties over conventional titanium alloys. Due to their low densities, these alloys are increasingly becoming strong candidates to replace nickel-base superalloys in future gas turbine aeroengine components. To determine the safe operating life of such components, a good understanding of their creep properties is essential. Of particular importance to gas turbine component design is the ability to accurately predict the rate of accumulation of creep strain to ensure that excessive deformation does not occur during the component’s service life and to quantify the effects of creep on fatigue life. The theta (θ) projection technique is an illustrative example of a creep curve method which has, in this paper, been utilised to accurately represent the creep behaviour of the γ-TiAl alloy Ti -45Al-2Mn-2Nb. Furthermore, a continuum damage approach based on the θ-projection method has also been used to represent tertiary creep damage and accurately predict creep rupture. Full article
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