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Keywords = heterogeneous gas hydrate model

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23 pages, 3512 KB  
Review
Advances in the Application of Fractal Theory to Oil and Gas Resource Assessment
by Baolei Liu, Xueling Zhang, Cunyou Zou, Lingfeng Zhao and Hong He
Fractal Fract. 2025, 9(10), 676; https://doi.org/10.3390/fractalfract9100676 - 20 Oct 2025
Viewed by 443
Abstract
In response to the growing complexity of global exploration targets, traditional Euclidean geometric and linear statistical methods reveal inherent theoretical limitations in characterizing hydrocarbon reservoirs as complex geological bodies that exhibit simultaneous local disorder and global order. Fractal theory, with its core parameter [...] Read more.
In response to the growing complexity of global exploration targets, traditional Euclidean geometric and linear statistical methods reveal inherent theoretical limitations in characterizing hydrocarbon reservoirs as complex geological bodies that exhibit simultaneous local disorder and global order. Fractal theory, with its core parameter systems such as fractal dimension and scaling exponents, provides an innovative mathematical–physics toolkit for quantifying spatial heterogeneity and resolving the multi-scale characteristics of reservoirs. This review systematically consolidates recent advancements in the application of fractal theory to oil and gas resource assessment, with the aim of elucidating its transition from a theoretical concept to a practical tool. We conclusively demonstrate that fractal theory has driven fundamental methodological progress across four critical dimensions: (1) In reservoir classification and evaluation, fractal dimension has emerged as a robust quantitative metric for heterogeneity and facies discrimination. (2) In pore structure characterization, the theory has successfully uncovered structural self-similarity across scales, from nanopores to macroscopic vugs, enabling precise modeling of complex pore networks. (3) In seepage behavior analysis, fractal-based models have significantly enhanced the predictive capacity for non-Darcy flow and preferential migration pathways. (4) In fracture network modeling, fractal geometry is proven pivotal for accurately characterizing the spatial distribution and connectivity of natural fractures. Despite significant progress, current research faces challenges, including insufficient correlation with dynamic geological processes and a scarcity of data for model validation. Future research should focus on the following directions: developing fractal parameter inversion methods integrated with artificial intelligence, constructing dynamic fractal–seepage coupling models based on digital twins, establishing a unified fractal theoretical framework from pore to basin scale, and expanding its application in low-carbon energy fields such as carbon dioxide sequestration and natural gas hydrate development. Through interdisciplinary integration and methodological innovation, fractal theory is expected to advance hydrocarbon resource assessment toward intelligent, precise, and systematic development, providing scientific support for the efficient exploitation of complex reservoirs and the transition to green, low-carbon energy. Full article
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22 pages, 4772 KB  
Article
Integrated Statistical Analysis and Spatial Modeling of Gas Hydrate-Bearing Sediments in the Shenhu Area, South China Sea
by Xin Feng and Lin Tan
Appl. Sci. 2025, 15(16), 8857; https://doi.org/10.3390/app15168857 - 11 Aug 2025
Viewed by 700
Abstract
Gas hydrate-bearing sediments in marine environments represent both a future energy source and a geohazard risk, prompting increasing international research attention. In the Shenhu area of the South China Sea, a large volume of drilling and laboratory data has been acquired in recent [...] Read more.
Gas hydrate-bearing sediments in marine environments represent both a future energy source and a geohazard risk, prompting increasing international research attention. In the Shenhu area of the South China Sea, a large volume of drilling and laboratory data has been acquired in recent years, yet a comprehensive framework for evaluating the characteristics of key reservoir parameters remains underdeveloped. This study presents a spatially integrated and statistically grounded framework that captures regional-scale heterogeneity using multi-source in situ datasets. It incorporates semi-variogram modeling to assess spatial variability and provides statistical reference values for geological and geotechnical properties across the Shenhu Area. By synthesizing core sampling results, acoustic logging, and triaxial testing data, representative probability distributions and variability scales of hydrate saturation, porosity, permeability, and mechanical strength are derived, which are essential for numerical simulations of gas production and slope stability. Our results support the development of site-specific reservoir models and improve the reliability of early-phase hydrate exploitation assessments. This work facilitates the rapid screening of hydrate reservoirs, contributing to the efficient selection of potential production zones in hydrate-rich continental margins. Full article
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28 pages, 9701 KB  
Article
Impact of Pore Structure and Hydrate Distribution on CO2-CH4 Replacement in CH4 Hydrate: A Pore-Scale Numerical Analysis
by Yingfei Wang, Xiangen Wu, Yujie Zhang, Chunlin Yin, Bo Dong and Weizhong Li
Energies 2025, 18(10), 2519; https://doi.org/10.3390/en18102519 - 13 May 2025
Viewed by 544
Abstract
The mining of CH4 hydrate through the CO2-CH4 replacement method mostly occurs within CH4 hydrate-bearing sediments. Therefore, it is crucial to investigate the replacement process on the pore scale. This study aims to explore the impacts of pore [...] Read more.
The mining of CH4 hydrate through the CO2-CH4 replacement method mostly occurs within CH4 hydrate-bearing sediments. Therefore, it is crucial to investigate the replacement process on the pore scale. This study aims to explore the impacts of pore microstructure and the CH4 hydrate non-uniform distribution on the replacement of CO2 for CH4. A two-dimensional numerical model has been adopted to investigate this issue. A pore-scale numerical simulation is conducted in a physical model of real porous media. Then, the replacement process in a comparative model, in which the pore microstructure and the non-uniform distribution of the CH4 hydrate are not considered, is simulated. The findings indicate that the CH4 hydrate dissociation and the CO2-CH4 mixed hydrate generation are affected by the effective throat length of pores. When the pore microstructure and CH4 hydrate heterogeneous distribution are ignored, the replacement rate and CO2 storage rate are underestimated. However, the effective throat length does not exert a significant impact on the pure CO2 hydrate generation, which is produced by the reaction of water with dissolved CO2. In addition, in terms of gas migration, ignoring the heterogeneous distribution of CH4 hydrate will underestimate the impact of initial water on the relative permeability of gas. Full article
(This article belongs to the Section B: Energy and Environment)
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21 pages, 42032 KB  
Article
3D Heterogeneous Geological Model of Natural Gas Hydrates in Shenhu Area, South China Sea
by Langfeng Mu, Dawang Liu, Yi Zhang, Hailong Lu and Shipeng Wei
J. Mar. Sci. Eng. 2025, 13(4), 705; https://doi.org/10.3390/jmse13040705 - 1 Apr 2025
Cited by 1 | Viewed by 947
Abstract
Natural gas hydrates, as a novel clean energy resource, have attracted widespread attention because of their highly complex reservoir properties, fluid distribution, and phase transitions. In particular, the fluid–solid interactions among hydrates, natural gas, water, and other multiphase components, along with phase state [...] Read more.
Natural gas hydrates, as a novel clean energy resource, have attracted widespread attention because of their highly complex reservoir properties, fluid distribution, and phase transitions. In particular, the fluid–solid interactions among hydrates, natural gas, water, and other multiphase components, along with phase state transitions influenced by temperature and pressure and the dynamic reservoir responses induced by hydrate decomposition and synthesis, make their study unique. Consequently, accurately predicting the structure and reservoir properties of natural gas hydrates remains a scientific challenge. In this study, high-resolution 3D seismic data, well logging, and core samples from the Shenhu test area in the South China Sea were utilized for stratigraphic correlation and classification. The hydrate, three-phase mixed, and free gas layers were identified as distinct geological bodies, and detailed stratigraphic subdivisions were performed based on hydrate distribution and physical properties. By integrating stochastic and deterministic modeling approaches, a comprehensive hydrate reservoir model, along with temperature and pressure field models, was established. For the first time, a three-dimensional heterogeneous geological model of the hydrate reservoir was developed for the test exploitation area. This model provides a robust geological foundation for hydrate reservoir studies, numerical simulations, and the formulation of efficient exploitation strategies, contributing to the advancement of natural gas hydrate exploration and production. Full article
(This article belongs to the Section Geological Oceanography)
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15 pages, 6453 KB  
Article
A Study on the Heterogeneity and Anisotropy of the Porous Grout Body Created in the Stabilization of a Methane Hydrate Reservoir through Grouting
by Yuchen Liu and Masanori Kurihara
Methane 2024, 3(2), 331-345; https://doi.org/10.3390/methane3020018 - 21 May 2024
Viewed by 1493
Abstract
To solve the sand problem during the depressurization of methane hydrate (MH), we proposed a method to build a porous grout body with sufficient permeability and strength around the wellbore through inhibitor pre-injection and grouting, and verified its effectiveness and potential in our [...] Read more.
To solve the sand problem during the depressurization of methane hydrate (MH), we proposed a method to build a porous grout body with sufficient permeability and strength around the wellbore through inhibitor pre-injection and grouting, and verified its effectiveness and potential in our previous research using artificial cores created with silica sand and alternative hydrates such as TBAB- hydrate and iso-butane hydrate. However, all of the artificial cores mentioned above were created with high homogeneity, injected, cured, and had their physical properties measured in the vertical direction, which differs from real reservoir conditions. To investigate the effects of grouting in a more realistic fluid flow, we conducted further experiments using horizontal 1D cores, 1D cubic models, and a 2D cross-sectional model mimicking the near wellbore. These experiments revealed that (1) the generated gas somewhat suppressed the effects of grouting as in the case of previous experiments, and (2) grouted reservoirs would be heterogenous and anisotropic due to the fluid densities and the distribution of grout particles and turbidite sediments, but sufficient permeability and satisfactory strength could still be attained. The above series of experiments demonstrated that our method has the potential to effectively produce actual MH, preventing sand problems even in heterogeneous and anisotropic grouted reservoirs. Full article
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19 pages, 11581 KB  
Article
Effect of Mineral Grain and Hydrate Layered Distribution Characteristics on the Mechanical Properties of Hydrate-Bearing Sediments
by Zhenhua Han, Luqing Zhang, Jian Zhou, Zhejun Pan, Song Wang and Ruirui Li
Energies 2023, 16(21), 7366; https://doi.org/10.3390/en16217366 - 31 Oct 2023
Cited by 6 | Viewed by 1287
Abstract
The mechanical characteristics of gas hydrate-bearing sediments (HBS) are important for evaluating reservoir stability. The interbedded formation of HBS is common in target mining reservoirs. Existing studies on the triaxial mechanical properties of HBS are primarily based on homogeneous and isotropic samples. Therefore, [...] Read more.
The mechanical characteristics of gas hydrate-bearing sediments (HBS) are important for evaluating reservoir stability. The interbedded formation of HBS is common in target mining reservoirs. Existing studies on the triaxial mechanical properties of HBS are primarily based on homogeneous and isotropic samples. Therefore, the stress–strain law of the target mining reservoirs cannot be predicted accurately. In this study, a series of sediment models with interlayers of coarse and fine mineral grains were established based on the PFC3D code, and the influence of the layered distribution characteristics of sediment particles and hydrates on the macroscopic mechanical behaviour of the reservoir was comprehensively analysed. The triaxial compression simulation results indicate that the peak strength, deformation modulus, and cohesion of the layered HBS are significantly lower than those of the homogeneous model. The deformation modulus of the reservoir is mainly affected by the fine-grained layer without hydrates. When the coarse and fine grains correspond to different mineral components, the two minerals are heterogeneous in terms of their micromechanical parameters, which can further reduce the macroscopic mechanical parameters of the HBS. In addition, the layered distribution of hydrate results in significant anisotropy of the reservoir. This study constitutes a reference regarding the control mechanism of gas hydrate reservoir strength. Full article
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18 pages, 54426 KB  
Article
High-Resolution Resistivity Imaging of a Transversely Uneven Gas Hydrate Reservoir: A Case in the Qiongdongnan Basin, South China Sea
by Chenggong Liu, Jianen Jing, Qingxian Zhao, Xianhu Luo, Kai Chen, Meng Wang and Ming Deng
Remote Sens. 2023, 15(8), 2000; https://doi.org/10.3390/rs15082000 - 10 Apr 2023
Cited by 11 | Viewed by 2622
Abstract
Marine controlled-source electromagnetics (MCSEM) is an effective method to map the spatial distribution of gas hydrate and calculate gas hydrate saturation. An MCSEM survey is conducted in the Lingnan low uplift (LNLU), Qiongdongnan Basin (QDNB), South China Sea (SCS), and then the measured [...] Read more.
Marine controlled-source electromagnetics (MCSEM) is an effective method to map the spatial distribution of gas hydrate and calculate gas hydrate saturation. An MCSEM survey is conducted in the Lingnan low uplift (LNLU), Qiongdongnan Basin (QDNB), South China Sea (SCS), and then the measured data are processed to obtain the geoelectric structure. The estimated gas hydrate stability zone (GHSZ) ranges from 0 to 320 mbsf, and shallow high-conductive sediments serving as gas hydrate caps are at depths ranging from 0 to 100 mbsf (meters below the seafloor). The 2D resistivity model reveals multiple high-resistivity bodies at depths ranging from 100 to 320 mbsf, and BSRs are at depths of 240 mbsf to 280 mbsf, indicating a transversely uneven gas hydrate reservoir in the study area. Moreover, two high-resistivity bodies are detected beneath the GHSZ, implying the presence of potential gas transport pathways. The gas hydrate saturation with a variation of 0–68.4% is calculated using the MCSEM resistivity and Archie’s law. According to the resistivity model and geological data, the transversely uneven gas hydrate reservoir may be associated with multiple gas sources, including shallow biogenic gas and deep pyrolytic gas. The shallow biogenic gas is transported to the GHSZ via short-distance migration and free diffusion, and the deep pyrolytic gas is transported to the GHSZ via two microcracks. In addition, this case emphasizes that the dynamic accumulation of gas hydrate is an important factor causing reservoir heterogeneity. Full article
(This article belongs to the Section Remote Sensing in Geology, Geomorphology and Hydrology)
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19 pages, 8546 KB  
Article
Multi-Lateral Well Productivity Evaluation Based on Three-Dimensional Heterogeneous Model in Nankai Trough, Japan
by Xin Xin, Ying Shan, Tianfu Xu, Si Li, Huixing Zhu and Yilong Yuan
Energies 2023, 16(5), 2406; https://doi.org/10.3390/en16052406 - 2 Mar 2023
Cited by 4 | Viewed by 2073
Abstract
Widely employed in hydrate exploitation, the single well method is utilized to broaden the scope of hydrate decomposition. Optimizing the well structure and production strategy is necessary to enhance gas recovery efficiency. Complex wells represented by the multilateral wells have great application potential [...] Read more.
Widely employed in hydrate exploitation, the single well method is utilized to broaden the scope of hydrate decomposition. Optimizing the well structure and production strategy is necessary to enhance gas recovery efficiency. Complex wells represented by the multilateral wells have great application potential in hydrate mining. This study focused on the impact of multilateral well production methods on productivity, taking the Nankai Trough in Japan as the study area. The spatial distribution of physical parameters such as porosity, permeability, and hydrate saturation in the Nankai Trough has significant heterogeneity. For model accuracy, the Sklearn machine learning and Kriging interpolation methods were used to construct a three-dimensional heterogeneous geological model to describe the structure and physical property parameters in the study area of the hydrate reservoir. The numerical simulation model was solved using the TOUGH + Hydrate program and fitted with the measured data of the trial production project to verify its reliability. Finally, we set the multilateral wells for hydrate high saturation area to predict the gas and water production of hydrate reservoir with different exploitation schemes. The main conclusions are as follows: ① The Sklearn machine learning and Kriging interpolation methods can be used to construct a three-dimensional heterogeneous geological model for limited site data, and the fitting effect of the heterogeneous numerical simulation model is better than that of the homogeneous numerical simulation model. ② The multilateral well method can effectively increase the gas production rate from the hydrate reservoir compared with the traditional single well method by approximately 8000 m3/day on average (approximately 51.8%). ③ In the high saturation area, the number of branches of the multilateral well were set to 2, 3, and 4, and the gas production rate was increased by approximately 51.8%, 52.5%, and 53.5%. Considering economic consumption, the number of branching wells should be set at 2–3 in the same layer. Full article
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22 pages, 10568 KB  
Article
Well-Logging Constraints on Gas Hydrate Saturation in Unconsolidated Fine-Grained Reservoirs in the Northern South China Sea
by Xiaoming Wan, Xueqing Zhou, Jinqiang Liang, Shiguo Wu, Jingan Lu, Chenglong Wei, Rui Wang and Bo Liu
Energies 2022, 15(23), 9215; https://doi.org/10.3390/en15239215 - 5 Dec 2022
Cited by 7 | Viewed by 2373
Abstract
Recently, drilling wells have encountered rich gas hydrates in fine-grained sediments in the northern South China Sea. Gas hydrate in fine-grained sediments is very heterogeneous, and its physical properties are different from those of oil and gas reservoirs. The reliability of the classical [...] Read more.
Recently, drilling wells have encountered rich gas hydrates in fine-grained sediments in the northern South China Sea. Gas hydrate in fine-grained sediments is very heterogeneous, and its physical properties are different from those of oil and gas reservoirs. The reliability of the classical logging saturation evaluation models established for diagenetic reservoirs is questionable. This study used four wells in GMGS3 and GMGS4 to evaluate the effects of the application of three typical methods for evaluating saturation with different principles in the unconsolidated fine-grained sediments: nuclear magnetic logging, sigma logging, and the Archie formula. It was found that the value of the lithologic capture cross-section in sigma logging and the rock’s electrical parameters in the Archie formula affect the accuracy of the model. Therefore, to obtain a reliable saturation value for fine-grained sediments, an innovative method for the calculation of resistivity and acoustic time is proposed to estimate gas hydrate saturation based on logging data, which is most consistent with the results of core analysis. The overall relative error of the verification well was 5.87%, whereas that of the density NMR logging method was 56%, showing that the accuracy of the newly proposed resistivity DT logging method’s saturation formula was significantly improved. Finally, a new model-based cross chart was developed, which can rapidly differentiate gas saturation during drilling. Full article
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17 pages, 6733 KB  
Article
Characterizing Gas Hydrate-Bearing Marine Sediments Using Elastic Properties—Part 2: Seismic Inversion Based on a Pore-Filling–Solid Matrix Decoupling Scheme
by Zhiqi Guo, Xiaoyu Lv, Cai Liu, Haifeng Chen and Lulu Mei
J. Mar. Sci. Eng. 2022, 10(10), 1497; https://doi.org/10.3390/jmse10101497 - 14 Oct 2022
Cited by 3 | Viewed by 1770
Abstract
Characterizing gas hydrate-bearing marine sediments using seismic methods is essential for locating potential hydrate resources. However, most existing pre-stack seismic inversion methods estimate the properties of sediments containing gas hydrates without considering specific characteristics associated with gas hydrate occurrences. In the present study, [...] Read more.
Characterizing gas hydrate-bearing marine sediments using seismic methods is essential for locating potential hydrate resources. However, most existing pre-stack seismic inversion methods estimate the properties of sediments containing gas hydrates without considering specific characteristics associated with gas hydrate occurrences. In the present study, a pore-filling–solid matrix decoupling amplitude variation with offset (AVO) formula is proposed to represent seismic reflectivity in terms of properties associated with gas hydrates. Based on the rock physics relationships of solid substitution, the parameters introduced into the decoupling AVO equation estimate the concentration of gas hydrates with different occurrences, including pore fillings mixed with water and solid components forming part of the dry sediment frame. A theoretical model test indicates that seismic attributes obtained with the decoupling AVO inversion are superior to the conventional wave velocities-related properties in predicting gas hydrate saturations. A realistic model test further validates the applicability of the proposed method in characterizing a gas hydrate system with varying concentrations and layer thickness. By adjusting the tuning parameters, the configurations and concentrations of the gas hydrate system can be identified using the obtained attributes. Therefore, the presented method provides a useful tool for the characterization of gas hydrate-bearing sediments. Full article
(This article belongs to the Special Issue Properties of Gas Hydrate-Bearing Sediments)
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19 pages, 2719 KB  
Article
Mathematical Modeling of Gas Hydrates Dissociation in Porous Media with Water-Ice Phase Transformations Using Differential Constrains
by Natalia Alekseeva, Viktoriia Podryga, Parvin Rahimly, Richard Coffin and Ingo Pecher
Mathematics 2022, 10(19), 3470; https://doi.org/10.3390/math10193470 - 23 Sep 2022
Cited by 3 | Viewed by 1848
Abstract
2D numerical modeling algorithms of multi-component, multi-phase filtration processes of mass transfer in frost-susceptible rocks using nonlinear partial differential equations are a valuable tool for problems of subsurface hydrodynamics considering the presence of free gas, free water, gas hydrates, ice formation and phase [...] Read more.
2D numerical modeling algorithms of multi-component, multi-phase filtration processes of mass transfer in frost-susceptible rocks using nonlinear partial differential equations are a valuable tool for problems of subsurface hydrodynamics considering the presence of free gas, free water, gas hydrates, ice formation and phase transitions. In this work, a previously developed one-dimensional numerical modeling approach is modified and 2D algorithms are formulated through means of the support-operators method (SOM) and presented for the entire area of the process extension. The SOM is used to generalize the method of finite difference for spatially irregular grids case. The approach is useful for objects where a lithological heterogeneity of rocks has a big influence on formation and accumulation of gas hydrates and therefore it allows to achieve a sufficiently good spatial approximation for numerical modeling of objects related to gas hydrates dissociation in porous media. The modeling approach presented here consistently applies the method of physical process splitting which allows to split the system into dissipative equation and hyperbolic unit. The governing variables were determined in flow areas of the hydrate equilibrium zone by applying the Gibbs phase rule. The problem of interaction of a vertical fault and horizontal formation containing gas hydrates was investigated and test calculations were done for understanding of influence of thermal effect of the fault on the formation fluid dynamic. Full article
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21 pages, 11394 KB  
Article
Comparative Analysis on the Evolution of Seepage Parameters in Methane Hydrate Production under Depressurization of Clayey Silt Reservoir and Sandy Reservoir
by Yaobin Li, Xin Xin, Tianfu Xu, Huixing Zhu, Haibin Wang, Qiang Chen and Bo Yang
J. Mar. Sci. Eng. 2022, 10(5), 653; https://doi.org/10.3390/jmse10050653 - 11 May 2022
Cited by 13 | Viewed by 2420
Abstract
Gas hydrates are likely to become an important strategic resource with commercial development prospects. It is therefore of great significance to realize the long-term and efficient production of methane hydrate reservoirs. Previous studies have shown that the lithological characteristics of hydrate reservoirs have [...] Read more.
Gas hydrates are likely to become an important strategic resource with commercial development prospects. It is therefore of great significance to realize the long-term and efficient production of methane hydrate reservoirs. Previous studies have shown that the lithological characteristics of hydrate reservoirs have a significant impact on reservoir productivity by influencing the evolution of seepage parameters in the process of hydrate production. The porosity (Φ) and initial hydrate saturation (SH) affect the amount of hydrate decomposition and pressure transfer, and also indirectly affect the reservoir temperature field. The permeability (k) directly affects the rate of pressure-drop transmission and methane gas discharge. Due to the differences in seepage parameters caused by different reservoir lithology, a sandy hydrate reservoir (SHR) in Japan and a clayey silt hydrate reservoir (CHR) in China were found to have different gas production rates and the spatial evolution characteristics of the temperature and pressure fields varied in gas hydrate production tests. Therefore, to ensure the long-term and efficient production of the CHR in China, two models were established for a comparative analysis based on a numerical simulation. The two models were depressurizing models of the CHR of the W11 drilling site in the Shenhu Sea area of the South China Sea and the SHR of the AT1 drilling site in the Eastern Nankai Trough of Japan. Both models considered the heterogeneity of seepage parameters, and the TOUGH+HYDARATE (T+H) code was used in subsequent calculations. Four key results were obtained: (a) The order of the significance levels of the lithological parameters on productivity was k > SH > Φ in the CHR and SH > k > Φ in the SHR. (b) The heat conduction and heat convection in the CHR were weaker than in the SHR, which made it difficult to recover the low-temperature area caused by hydrate decomposition. (c) The exploitation of a high k hydrate reservoir should be given priority when the other initial conditions were the same in both the CHR and SHR. (d) The exploitation of both the CHR and SHR should not only rely on the hydrate content or seepage capacity to determine the reservoir exploitation potential, but the combined effect of the two parameters should be fully considered. Full article
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30 pages, 4811 KB  
Article
Small Alcohols as Surfactants and Hydrate Promotors
by Bjørn Kvamme
Fluids 2021, 6(10), 345; https://doi.org/10.3390/fluids6100345 - 30 Sep 2021
Cited by 13 | Viewed by 4181
Abstract
Many methods to produce hydrate reservoirs have been proposed in the last three decades. Thermal stimulation and injection of thermodynamic hydrate inhibitors are just two examples of methods which have seen reduced attention due to their high cost. However, different methods for producing [...] Read more.
Many methods to produce hydrate reservoirs have been proposed in the last three decades. Thermal stimulation and injection of thermodynamic hydrate inhibitors are just two examples of methods which have seen reduced attention due to their high cost. However, different methods for producing hydrates are not evaluated thermodynamically prior to planning expensive experiments or pilot tests. This can be due to lack of a thermodynamic toolbox for the purpose. Another challenge is the lack of focus on the limitations of the hydrate phase transition itself. The interface between hydrate and liquid water is a kinetic bottle neck. Reducing pressure does not address this problem. An injection of CO2 will lead to the formation of a new CO2 hydrate. This hydrate formation is an efficient heat source for dissociating hydrate since heating breaks the hydrogen bonds, directly addressing the problem of nano scale kinetic limitation. Adding limited amounts of N2 increases the permeability of the injection gas. The addition of surfactant increases gas/water interface dynamics and promotes heterogeneous hydrate formation. In this work we demonstrate a residual thermodynamic scheme that allows thermodynamic analysis of different routes for hydrate formation and dissociation. We demonstrate that 20 moles per N2 added to the CO2 is thermodynamically feasible for generating a new hydrate into the pores. When N2 is added, the available hydrate formation enthalpy is reduced as compared to pure CO2, but is still considered sufficient. Up to 3 mole percent ethanol in the free pore water is also thermodynamically feasible. The addition of alcohol will not greatly disturb the ability to form new hydrate from the injection gas. Homogeneous hydrate formation from dissolved CH4 and/or CO2 is limited in amount and not important. However, the hydrate stability limits related to concentration of hydrate former in surrounding water are important. Mineral surfaces can act as hydrate promotors through direct adsorption, or adsorption in water that is structured by mineral surface charges. These aspects will be quantified in a follow-up paper, along with kinetic modelling based on thermodynamic modelling in this work. Full article
(This article belongs to the Special Issue Fluids and Surfaces)
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24 pages, 5321 KB  
Article
Research into Dissociation Zones of Gas Hydrate Deposits with a Heterogeneous Structure in the Black Sea
by Oleg Bazaluk, Kateryna Sai, Vasyl Lozynskyi, Mykhailo Petlovanyi and Pavlo Saik
Energies 2021, 14(5), 1345; https://doi.org/10.3390/en14051345 - 2 Mar 2021
Cited by 33 | Viewed by 7225
Abstract
Ukraine is an energy-dependent country, with less that 50% of its energy consumption fulfilled by its own resources. Natural gas is of paramount importance, especially for industry and society. Therefore, there is an urgent need to search for alternative and potential energy sources, [...] Read more.
Ukraine is an energy-dependent country, with less that 50% of its energy consumption fulfilled by its own resources. Natural gas is of paramount importance, especially for industry and society. Therefore, there is an urgent need to search for alternative and potential energy sources, such as gas hydrate deposits in the Black Sea, which can reduce the consumption of imported gas. It is necessary to refine the process parameters of the dissociation of gas hydrate deposits with a heterogeneous structure. The analyzed known geological–geophysical data devoted to the study of the offshore area and the seabed give grounds to assert the existence of a significant amount of hydrate deposits in the Black Sea. An integrated methodological approach is applied, which consists of the development of algorithms for analytical and laboratory studies of gas volumes obtained during the dissociation of deposits with a heterogeneous structure. These data are used for the computer modelling of the dissociation zone in the Surfer-8.0 software package based on the data interpolation method, which uses three methods for calculating the volumes of modelling bodies. A 3D grid-visualization of the studied part of the gas hydrate deposit has been developed. The dissociation zone parameters of gas hydrate deposits with different shares of rock intercalation, that is, the minimum and maximum diameters, have been determined, and the potentially recoverable gas volumes have been assessed. The effective time of the process of gas hydrate deposit dissociation has been substantiated. The obtained research results of the dissociation process of gas hydrate deposits can be used in the development of new technological schemes for gas recovery from the deep-water Black Sea area. Full article
(This article belongs to the Special Issue Energy Resource Potential of Gas Hydrates)
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23 pages, 3557 KB  
Article
A Quantitative Assessment of Methane-Derived Carbon Cycling at the Cold Seeps in the Northwestern South China Sea
by Junxi Feng, Niu Li, Min Luo, Jinqiang Liang, Shengxiong Yang, Hongbin Wang and Duofu Chen
Minerals 2020, 10(3), 256; https://doi.org/10.3390/min10030256 - 12 Mar 2020
Cited by 22 | Viewed by 5388
Abstract
Widespread cold seeps along continental margins are significant sources of dissolved carbon to the ocean water. However, little is known about the methane turnovers and possible impact of seepage on the bottom seawater at the cold seeps in the South China Sea (SCS). [...] Read more.
Widespread cold seeps along continental margins are significant sources of dissolved carbon to the ocean water. However, little is known about the methane turnovers and possible impact of seepage on the bottom seawater at the cold seeps in the South China Sea (SCS). We present seafloor observation and porewater data of six push cores, one piston core and three boreholes as well as fifteen bottom-water samples collected from four cold seep areas in the northwestern SCS. The depths of the sulfate–methane transition zone (SMTZ) are generally shallow, ranging from ~7 to <0.5 mbsf (meters below seafloor). Reaction-transport modelling results show that methane dynamics were highly variable due to the transport and dissolution of ascending gas. Dissolved methane is predominantly consumed by anaerobic oxidation of methane (AOM) at the SMTZ and trapped by gas hydrate formation below it, with depth-integrated AOM rates ranging from 59.0 and 591 mmol m−2 yr−1. The δ13C and Δ14C values of bottom-water dissolved inorganic carbon (DIC) suggest discharge of 13C- and 14C-depleted fossil carbon to the bottom water at the cold seep areas. Based on a two-endmember estimate, cold seeps fluids likely contribute 16–26% of the bottom seawater DIC and may have an impact on the long-term deep-sea carbon cycle. Our results reveal the methane-related carbon inventories are highly heterogeneous in the cold seep systems, which are probably dependent on the distances of the sampling sites to the seepage center. To our knowledge, this is the first quantitative study on the contribution of cold seep fluids to the bottom-water carbon reservoir of the SCS, and might help to understand the dynamics and the environmental impact of hydrocarbon seep in the SCS. Full article
(This article belongs to the Special Issue Marine Geology and Minerals)
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