Search Results (62)

In high-sulfur environments, the failure risk of completion tubing increases due to the coupling effect of mechanical and electrochemical corrosion during the acidification production process. The corrosion behavior of P110SS tubing steel was investigated by an HTHP corrosion weight loss experiment and an electrochemical corrosion experiment. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) were used to analyze the surface morphology of the corrosion products. In addition, a prediction model for the remaining service life of completion tubing under the synergistic effect of corrosion and stress was established during the acidification production process. The results show that acidification operations have a significant impact on the subsequent service life of tubing; the corrosion rate of P110SS tubing in the full acidification production process is much higher than that after the produced gas field solution corrosion treatment alone. Obvious pitting marks, micropores, and microchannels are observed in the corrosion product film of P110SS steel after acidification treatment, and the corrosion product film structure of P110SS steel is loose and honeycomb-like after acidification production treatment. The corrosion products are mainly FexSy and FeCO₃ after acidification production corrosion treatment. The corrosion during the acidification production stage is controlled by cathodic polarization. The remaining service life of tubing after production corrosion treatment can reach up to 29 years, while the remaining service life of tubing after acidification production corrosion treatment is significantly reduced, with a maximum of only 8 years. The research results have guiding significance for the selection, optimization, and design of high-sulfur-gas well tubing. Full article

In polymer-based lithium batteries, polymer electrolytes (PEs) exhibit limited ionic conductivity at room temperature (25 °C). To address this issue, this paper describes a hexagonal-structure-based single-ion conducting gel polymer electrolyte (h-SICGPE) framework with a robust and efficient cross-linked polymer network, applicable to polymer-based batteries even at 25 °C. The proposed cross-linked polymer network backbone of the h-SICGPE, as a semisolid-state thin film type, has the homogeneous honeycomb structure incorporating anion receptor(s) inside each of its hexagonal closed cells and is obtained by cross-linking between trimethylolpropane tris(3-mercaptopropionate) and poly(ethylene glycol) diacrylate in a newly synthesized anion–receptor solution. The excellent structural capability of the h-SICGPE incorporating Li⁺/TFSI⁻ can enhance ionic conductivity and electrochemical stability by suppressing crystallinity and expanding free volume. Further, the anion receptor in its free volume helps to effectively increase the lithium-ion transference number by immobilizing counter-anions. Experimental results demonstrate dramatically superior performance at 25 °C, such as ionic conductivity (2.46 mS cm⁻¹), oxidative stability (4.9 V vs. Li/Li⁺), coulombic efficiency (97.65%), and capacity retention (88.3%). These results confirm the developed h-SICGPE as a promising polymer electrolyte for high-performance polymer-based lithium batteries operable at 25 °C. Full article

In this work, we have employed an advanced method of solvent vapor annealing to expose spin-cast thin films made from various lamellar and micellar block copolymers to generous amounts of different types of solvent vapors, with the final goal of stimulating the films’ self-assembly into (hierarchically) ordered structures. As revealed by atomic force microscopy measurements, periodic lamellar nanostructures of molecular dimensions based on poly(4-vinylpyridine)-b-polybutadiene and poly(2-vinylpyridine)-b-polybutadiene, as well as micellar structures further packed into either (parallel) stripe-like or honeycomb-resembling configurations based on poly(2-vinylpyridine)-b-poly(tert-butyl methacrylate)-b-poly(methacrylate cyclohexyl), were successfully produced through processing. Full article

An innovative design of a hydrophone based on a piezoelectric composite film of $AlN/S{c}_{0.2}A{l}_{0.8}N$ is presented. By designing a non-uniform composite sensitive layer, the dielectric loss and defect density are significantly reduced, while the high-voltage electrical characteristics of scandium-doped aluminum nitride are retained. X-ray diffraction analysis shows that the sensitive films have excellent crystal quality (FWHM is 0.34°). According to the standard underwater acoustic calibration test, the device exhibits full directivity with a minimum deviation of ±0.5 dB at 1 kHz frequency, sound pressure sensitivity of −162.9 dB (re: 1 V/$\mathsf{\mu }$Pa) and equivalent noise density of 46.1 dB (re: 1 $\mathsf{\mu }$Pa/√Hz). The experimental results show that the comprehensive performance of the piezoelectric heterostructure hydrophone meets the standard of commercial high-end hydrophones while maintaining mechanical stability, and provides a new solution for underwater acoustic sensing. Full article

A deployable reflector antenna (DR-A) is a structure that can be stored in a large-diameter Synthetic Aperture Radar (SAR) antenna and be mounted onto a launch vehicle. Considering the performance of the launch vehicle, it is necessary to develop a lightweight, high-performance antenna structure. The solid-type deployable reflector antenna is composed of a number of unit main reflectors. To reduce the weight of the antenna, a lightweight main reflector must be developed. In this paper, following “Development of Deployable Reflector Antenna for the SAR Satellite (Part 1)”, the manufacturing and qualification of the main reflector using honeycomb sandwich composites are described. Four types of composite main reflectors were manufactured with variables in the manufacturing process. The manufacturing variables include the curing process of the structure, the application of an adhesive film between the sheet and the core, and the venting path inside of the sandwich core. After manufacturing the main reflector, we performed weight measurements, non-destructive testing (NDT), surface error measurement using a Coordinate Measurement Machine (CMM), and modal testing for each type of composite main reflector. Through the research and development process, we found that a perforated hole is necessary when excluding the adhesive film during bonding of an aramid core and a CFRP sheet, and a lightweight composite reflector could be developed through this process. We selected the main reflector with the best performance and developed a composite main reflector that can be applied to satellites. Full article

Developing efficient anti-microbials for thoroughly addressing Salmonella contamination is essential for the improvement of food safety. Phage-built materials have shown great potential for biocontrol in environments. Due to challenges in delivery and stability, their widespread use has remained unattainable. Here, we have developed a honeycomb film template-based method for the high-throughput preparation of phage microgels. The honeycomb film template can be simply fabricated in a humid chamber based on a well-established breath figure method. The bacteriophage microgels can be further manufactured by dropping a pre-gelation solution containing bacteriophages into a honeycomb film template. This method can produce over 210,000 phage microgels in every square centimeter template with each microgel containing 1.04 × 10⁷ phages. They can kill 99.90% of the contaminated S. typhimurium 14,028 on chicken samples. This simple, heat-free, and solvent-free method can maintain the strong anti-bacterial efficiency of phages, which can expand the wide application of phage-built microgels for food decontamination. Full article

This study investigates the process of using multi-walled carbon nanotube (MWCNT) coatings to enhance lamp heating temperatures for solar thermal absorption applications. The primary focus is studying the effects of the self-organized honeycomb structures of CNTs formed on silicon substrates on different cell area ratios (CARs). The drop-casting process was used to develop honeycomb-structured MWCNT-coated absorbers with varying CAR values ranging from ~60% to 17%. The optical properties were investigated within the visible (400–800 nm) and near-infrared (934–1651 nm) wavelength ranges. Although fully coated MWCNT absorbers showed the lowest reflectance, honeycomb structures with a ~17% CAR achieved high-temperature absorption. These structures maintained 8.4% reflectance at 550 nm, but their infrared reflection dramatically increased to 80.5% at 1321 nm. The solar thermal performance was assessed throughout a range of irradiance intensities, from 0.04 W/cm² to 0.39 W/cm². The honeycomb structure with a ~17% CAR value consistently performed better than the other structures by reaching the highest absorption temperatures (ranging from 52.5 °C to 285.5 °C) across all measured intensities. A direct correlation was observed between the reflection ratio (visible: 550 nm/infrared: 1321 nm) and the temperature absorption efficiency, where lower reflection ratios were associated with higher temperature absorption. This study highlights the significant potential for the large-scale production of cost-effective solar thermal absorbers through the application of optimized honeycomb-structured absorbers coated with MWCNTs. These contributions enhance solar energy efficiency for applications in water heating and purification, thereby promoting sustainable development. Full article

The co-integration of antennas with lighting sources appears as an effective way to distribute broadband networks closer to users, lowering interference and transmitted power, as well as to reduce energy consumption in future lighting systems. We here present an original contribution to the implementation of transparent and invisible antennas with OLED light sources. To validate the proposed approach, the honeycomb mesh technique was used, and an optical transparency of 75.4% was reached. The transparent mesh antenna was compared with the non-transparent full-metal antenna in terms of radio-electrical parameters. Our prototype was designed using copper films deposited on a glass substrate. The simulation results of the S-parameters and the radiation patterns were validated against measurements performed in an anechoic chamber. The directivity and gain obtained were $6.67$ dBi and $4.86$ dBi at $5.16$$\mathrm{G}$$\mathrm{Hz}$, respectively. To study the effect of antenna integration with OLEDs, optical and photometric characterizations with and without the antenna were measured, and the colorimetric parameters were then treated using the IES TM-30-18 standard. Full article

High-performance aeroengine design is an important component of modern industry, and advanced sealing technology is a key technology to meet the engine fuel consumption rate, thrust-to-weight ratio, pollutant emission, durability, and lifetime. Reducing the internal airflow leakage of the engine through a sealing technology can improve the performance and efficiency of the engine. In this paper, the typical sealing technology for an aeroengine is introduced in more detail, including the structural characteristics and use limitations of the labyrinth seal, brush seal, honeycomb seal, gas film face seal, and cylindrical gas film seal. It focuses on the development history, typical structure type, working principle, basic technology research method, steady-state performance, dynamic characteristics, multi-physical field coupling, structural deformation, experimental testing, processing technology. Finally, it summarizes the problems and future development trends of the current application of the cylindrical gas film seal in aeroengines, and points out that the seal performance test and evaluation based on advanced composite sensor technology and the innovative design of the seal based on new material, a new principle, and a new structure will be the new research direction. Full article

Recently, the icing disaster of transmission lines has been a serious threat to the safe operation of the power system. A superhydrophobic (SHP) anti-icing surface with a honeycomb nanopore structure was constructed using anodic oxidation technology combined with a vacuum infusion process. When the current density was 87.5 mA/cm², the honeycomb porous surface had the best superhydrophobic performance (excellent water mobility), lowest ice-adhesion strength (0.7 kPa) and best anti-frosting performance. Compared with other types of alumina surfaces, the ice-adhesion strength of the SHP surface (87.5 mA/cm²) was only 0.2% of that of the bare surface. The frosting time of the SHP surface (87.5 mA/cm²) was 150 min, which was much slower. The former is attributed to the air cushion within the porous structure and the stress concentration, and the latter is attributed to the self-transition of the droplets and low solid–liquid heat transfer area. After 100 icing or frosting cycles, the SHP surface (87.5 mA/cm²) maintained a low ice-adhesion strength and superhydrophobic performance. This is because the anodic oxidation process forms a hard porous film, and the nano porous structure with a high aspect ratio can store modifiers to realize self-healing. The results indicate that the SHP surface with a honeycomb nanopore structure presents excellent anti-icing performance and durability. Full article

Magnesium (Mg)/Polylactic acid (PLA) composites are promising materials for bone regeneration and tissue engineering applications. PLA is a biodegradable and biocompatible polymer that can be easily processed into various shapes and structures, such as scaffolds, films, and fibers, but has low biodegradability. Mg is a biocompatible metal that has been proven to have good biodegradability and osteoconductivity, which makes it suitable for bone tissue engineering. In this study, we prepared and characterized a Mg/PLA composite as a potential material for direct ink writing (DIW) in 3D printing. The results showed that the addition of Mg has a significant impact on PLA’s thermal and structural properties and has also significantly increased the degradation of PLA. XRD was used to determine the degree of crystallinity in the PLA/Mg composite, which provides insight into its thermal stability and degradation behavior. The crystallization temperature of PLA increased from 168 to 172 °C for a 15 wt% Mg incorporation, and the melting temperature reduced from 333 °C to 285 °C. The surface morphology and composition of these films were analyzed with SEM. The films with 5 wt% of Mg particles displayed the best-ordered honeycomb structure in their film form. Such structures are considered to affect the mechanical, biological and heat/mass transfer properties of the Mg/PLA composites and products. Finally, the composite ink was used as a feed for direct ink writing in 3D printing, and the preliminary 3D printing experiments were successful in resulting in dimensionally and structurally integral scaffold samples. The shape fidelity was not very good, and some research is needed to improve the rheological properties of the ink for DIW 3D printing. Full article

Flexible wearable strain sensors based on laser-induced graphene (LIG) have attracted significant interest due to their simple preparation process, three-dimensional porous structure, excellent electromechanical characteristics, and remarkable mechanical robustness. In this study, we demonstrated that LIG with various defects could be prepared on the surface of polyimide (PI) film, patterned in a single step by adjusting the scanning speed while maintaining a constant laser power of 12.4 W, and subjected to two repeated scans under ambient air conditions. The results indicated that LIG produced at a scanning speed of 70 mm/s exhibited an obvious stacked honeycomb micropore structure, and the flexible strain sensor fabricated with this material demonstrated stable resistance. The sensor exhibited high sensitivity within a low strain range of 0.4–8.0%, with the gauge factor (GF) reaching 107.8. The sensor demonstrated excellent stability and repeatable response at a strain of 2% after approximately 1000 repetitions. The flexible wearable LIG-based sensor with a serpentine bending structure could be used to detect various physiological signals, including pulse, finger bending, back of the hand relaxation and gripping, blinking eyes, smiling, drinking water, and speaking. The results of this study may serve as a reference for future applications in health monitoring, medical rehabilitation, and human–computer interactions. Full article

Based on the new high-modulus carbon fiber CCM40J-6k, which is the critical raw material of a solar panel, the molding process of a mesh face sheet combined with epoxy resin, the overall mechanical performance of a mesh face sheet combined with aluminum honeycomb, the compatibility with polyimide insulation film + solar cell circuit, and the space environment adaptability must pass a test verification and assessment as the premise for large-scale orbit applications. Therefore, based on the traditional carbon fiber M40JB-6k as a reference, a systematic verification project was conducted to apply the CCM40J-6k carbon fiber composite at the process, component, and assembly levels. Six aspects of testing and verifying items were conducted, including mechanical properties under room temperature and thermal shock conditions, bonding force of mesh nodes, comparison of the adaptability of domestic and imported carbon fiber substrates to high–low temperature alternation, the ability of domestic carbon fiber substrates to adapt to the thermal environment after laying solar cell circuits, and in-orbit lifespan of solar panels. Based on the verification results, the mechanical properties of the substrate are the same as those of the imported M40JB-6k, and the actual molding process for M40JB-6k can be utilized. Sample pieces of the substrates can withstand the thermal shock and thermal cycling tests. The bending stiffness of the sample pieces before and after the tests is 3.5%~9.6% higher, and the bending strength is 4.2%~7.2% lower. The tensile strength of mesh nodes made of domestic carbon fiber is 18.9% higher than that of mesh nodes made of imported carbon fiber. The CCM40J-6k substrate is similar to triple-junction GaAs solar cells. The change rates of the open-circuit voltage and the short-circuit current of solar panels based on domestic carbon fiber after fatigue thermal cycling with 2070 cycles are 0.55% and 0.24%, respectively. The above results indicate that the comprehensive performance of the domestic carbon fiber CCM40J-6k meets the requirements and can be applied to solar panels for solar arrays. Full article

In this study, according to the acquired polydopamine deposition rates, polydopamine films with equal thickness were prepared under different conditions on SiO₂ substrates. Subsequently, we investigated the influence of dopamine solution pH and concentration on the formation of surface aggregates of the deposited polydopamine films. Assumptions were made to explain how pH and concentration execute their effects. Based on the optimized parameters, a continuous and smooth polydopamine film with a thickness of about 14 nm and a roughness of 1.76 nm was fabricated on a silicon dioxide substrate, through the deposition for 20 minutes in a dopamine solution with a concentration of 1.5 mg/mL and a pH of 8.2. The prepared polydopamine film was then employed as a precursor and subjected to a high-temperature process for the carbonization and graphitization of the film. Raman spectroscopy analysis indicated that the resulting graphene-like film had fewer structural defects in comparison with previous works and the results of XPS indicated that most of the carbon atoms were bound into the cross-linked honeycomb lattice structure. The prepared graphene-like material also exhibited high electrical conductivity and satisfying mechanical elasticity. Full article

Volatile organic compounds (VOCs) in indoor environments have typical features of multiple components, high concentration, and long duration. The development of gas sensors with high sensitivity to multiple VOCs is of great significance to protect human health. Herein, we proposed a sensitive ZnO/WO₃ composite chemi-resistive sensor facilely fabricated via a sacrificial template approach. Based on the transferable properties of self-assembled monolayer colloidal crystal (MCC) templates, two-dimensional honeycomb-like ordered porous ZnO/WO₃ sensing matrixes were constructed in situ on commercial ceramic tube substrates with curved and rough surfaces. The nanocomposite thin films are about 250 nm in thickness with large-scale structural consistency and integrity, which facilitates characteristic responses with highly sensitivity and reliability. Furthermore, the nanocomposite sensor shows simultaneous responses to multiple VOCs that commonly exist in daily life with an obvious suppression sensing for traditional flammable gases. Particularly, a detection limit of 0.1 ppm with a second-level response/recovery time can be achieved, which is beneficial for real-time air quality assessments. We proposed a heterojunction-induced sensing enhancement mechanism for the ZnO/WO₃ nanocomposite film in which the formation of abundant heterojunctions between ZnO and WO₃ NPs significantly increases the thickness of the electron depletion layer in the bulk film and improves the formation of active oxygen species on the surface, which is conducive to enhanced responses for reducing VOC gases. This work not only provides a simple approach for the fabrication of high-performance gas sensors but also opens an achievable avenue for air quality assessment based on VOC concentration detection. Full article