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39 Results Found

  • Article
  • Open Access
4,477 Views
12 Pages

Identification of Soluble Degradation Products in Lithium–Sulfur and Lithium-Metal Sulfide Batteries

  • Fabian Horsthemke,
  • Christoph Peschel,
  • Kristina Kösters,
  • Sascha Nowak,
  • Kentaro Kuratani,
  • Tomonari Takeuchi,
  • Hitoshi Mikuriya,
  • Florian Schmidt,
  • Hikari Sakaebe and
  • Stefan Kaskel
  • + 4 authors

Most commercially available lithium ion battery systems and some of their possible successors, such as lithium (metal)-sulfur batteries, rely on liquid organic electrolytes. Since the electrolyte is in contact with both the negative and the positive...

  • Feature Paper
  • Article
  • Open Access
31 Citations
7,474 Views
19 Pages

Recovery of Metals from Waste Lithium Ion Battery Leachates Using Biogenic Hydrogen Sulfide

  • Giles Calvert,
  • Anna H. Kaksonen,
  • Ka Yu Cheng,
  • Jonovan Van Yken,
  • Barbara Chang and
  • Naomi J. Boxall

17 September 2019

Lithium ion battery (LIB) waste is increasing globally and contains an abundance of valuable metals that can be recovered for re-use. This study aimed to evaluate the recovery of metals from LIB waste leachate using hydrogen sulfide generated by a co...

  • Review
  • Open Access
6 Citations
11,795 Views
18 Pages

Manufacturing High-Energy-Density Sulfidic Solid-State Batteries

  • Gang Li,
  • Shuo Wang,
  • Jipeng Fu,
  • Yuan Liu and
  • Zehua Chen

All-solid-state batteries (ASSBs) using sulfide solid electrolytes with high room-temperature ionic conductivity are expected as promising next-generation batteries, which might solve the safety issues and enable the utilization of lithium metal as t...

  • Article
  • Open Access
1,747 Views
14 Pages

Metal–Organic Framework-Derived Co9S8 Nanowall Array Embellished Polypropylene Separator for Dendrite-Free Lithium Metal Anodes

  • Deshi Feng,
  • Ruiling Zheng,
  • Li Qiao,
  • Shiteng Li,
  • Fengzhao Xu,
  • Chuangen Ye,
  • Jing Zhang and
  • Yong Li

5 July 2024

Developing a reasonable design of a lithiophilic artificial solid electrolyte interphase (SEI) to induce the uniform deposition of Li+ ions and improve the Coulombic efficiency and energy density of batteries is a key task for the development of high...

  • Article
  • Open Access
30 Citations
3,883 Views
12 Pages

Hydrometallurgical Synthesis of Nickel Nano-Sulfides from Spent Lithium-Ion Batteries

  • Esmaeel Darezereshki,
  • Ali Behrad Vakylabad,
  • Ahmad Hassanzadeh,
  • Tomasz Niedoba,
  • Agnieszka Surowiak and
  • Babak Koohestani

15 April 2021

By developing technologies, spent lithium-ion batteries (LIBs) are considered a great source of nickel-cobalt ions to fabricate metal sulfide nanoparticles. However, the presence of unnecessary ions such as manganese and lithium may hamper the format...

  • Article
  • Open Access
14 Citations
3,419 Views
14 Pages

29 November 2022

Ternary metal sulfides are projected as advanced lithium-ion battery (LIB) anodes due to their superior electronic conductivity and specific capacity compared to their respective oxide counterparts. Herein, a porous composite of cuboidal FeNi2S4 (FNS...

  • Article
  • Open Access
7 Citations
1,973 Views
15 Pages

19 April 2024

In this study, we synthesized a transition metal sulfide (TMS) with a spinel structure, i.e., MnIn2S4 (MIS), using a two-step hydrothermal and sintering process. In the context of lithium-ion battery (LIB) applications, ternary TMSs are being conside...

  • Article
  • Open Access
964 Views
13 Pages

Carbon Nanotubes-Doped Metal Oxides and Metal Sulfides Heterostructure Achieves 3D Morphology Deposition of Li2S and Stable Long-Cycle Lithium–Sulfur Batteries

  • Yu-Lin Luo,
  • Hai Huang,
  • Cheng-Wei Zhu,
  • Wen-Qi Lv,
  • Ye Zeng,
  • Gui-Fang Li,
  • Xiao-Hong Fan,
  • Ding-Rong Deng and
  • Qi-Hui Wu

The “shuttle effect” caused by the shuttling of soluble long-chain polysulfides between the anode and cathode electrodes has persistently hindered lithium–sulfur batteries (LSBs) from achieving stable and high-capacity performance....

  • Review
  • Open Access
83 Citations
18,223 Views
13 Pages

Electrolytes are key components in electrochemical storage systems, which provide an ion-transport mechanism between the cathode and anode of a cell. As battery technologies are in continuous development, there has been growing demand for more effici...

  • Review
  • Open Access
9 Citations
6,282 Views
17 Pages

Solid-state lithium metal batteries offer superior energy density, longer lifespan, and enhanced safety compared to traditional liquid-electrolyte batteries. Their development has the potential to revolutionize battery technology, including the creat...

  • Article
  • Open Access
9 Citations
2,432 Views
11 Pages

7 December 2022

In this study, we proposed a novel CoIn2S4/reduced graphene oxide (CoIn2S4/rGO) composite anode using a hydrothermal method. By introducing electronic-conductive reduced graphene oxide (rGO) to buffer the extreme volume expansion of CoIn2S4, we preve...

  • Article
  • Open Access
14 Citations
3,240 Views
17 Pages

Copper Zinc Sulfide (CuZnS) Quantum Dot-Decorated (NiCo)–S/Conductive Carbon Matrix as the Cathode for Li–S Batteries

  • Thanphisit Artchuea,
  • Assadawoot Srikhaow,
  • Chakrit Sriprachuabwong,
  • Adisorn Tuantranont,
  • I-Ming Tang and
  • Weeraphat Pon-On

14 July 2022

Sulfur composites consisting of electrochemical reactive catalysts/conductive materials are investigated for use in lithium–sulfur (Li–S) batteries (LSBs). In this paper, we report the synthesis, physicochemical and electrochemical proper...

  • Article
  • Open Access
6 Citations
2,389 Views
10 Pages

26 May 2023

Lithium-sulfur batteries are anticipated to be the next generation of energy storage devices because of their high theoretical specific capacity. However, the polysulfide shuttle effect of lithium-sulfur batteries restricts their commercial applicati...

  • Feature Paper
  • Review
  • Open Access
5 Citations
11,399 Views
31 Pages

A Comprehensive Review of Sulfide Solid-State Electrolytes: Properties, Synthesis, Applications, and Challenges

  • Bin Man,
  • Yulong Zeng,
  • Qingrui Liu,
  • Yinwen Chen,
  • Xin Li,
  • Wenjing Luo,
  • Zikang Zhang,
  • Changliang He,
  • Min Jie and
  • Sijie Liu

22 May 2025

Traditional lithium-ion batteries (LIBs) utilize liquid electrolytes, which pose significant safety risks. To address these concerns and enhance energy density, all-solid-state batteries (ASSBs) have emerged as a safer and more efficient alternative...

  • Feature Paper
  • Review
  • Open Access
8 Citations
4,368 Views
16 Pages

28 March 2024

The current commercially used anode material, graphite, has a theoretical capacity of only 372 mAh/g, leading to a relatively low energy density. Lithium (Li) metal is a promising candidate as an anode for enhancing energy density; however, challenge...

  • Article
  • Open Access
13 Citations
2,848 Views
13 Pages

18 March 2022

The combination of W2C and WS2 has emerged as a promising anode material for lithium-ion batteries. W2C possesses high conductivity but the W2C/WS2-alloy nanoflowers show unstable performance because of the lack of contact with the leaves of the nano...

  • Article
  • Open Access
6 Citations
1,656 Views
10 Pages

14 November 2023

The high specific capacity of transition metal sulfides (TMSs) opens up a promising new development direction for lithium-ion batteries with high energy storage. However, the poor conductivity and serious volume expansion during charge and discharge...

  • Article
  • Open Access
1 Citations
1,583 Views
11 Pages

Nanostructured C@CuS Core–Shell Framework with High Lithium-Ion Storage Performance

  • Changqing Jin,
  • Zaidong Peng,
  • Yongxing Wei,
  • Ruihua Nan,
  • Zhong Yang,
  • Zengyun Jian and
  • Qingping Ding

21 September 2024

In this study, we have synthesized a nanostructured core–shell framework of carbon-coated copper sulfide (C@CuS) through a one-step precipitation technique. The carbon sphere template facilitated the nucleation of CuS nanostructures. The synthe...

  • Review
  • Open Access
2 Citations
1,852 Views
35 Pages

Recent Advances in Nanostructured Conversion-Type Cathodes: Fluorides and Sulfides

  • Mobinul Islam,
  • Md. Shahriar Ahmed,
  • Sua Yun,
  • Basit Ali,
  • Hae-Yong Kim and
  • Kyung-Wan Nam

This review paper explores the emerging field of conversion cathode materials, which hold significant promises for advancing the performance of lithium-ion (LIBs) and lithium–sulfur batteries (LSBs). Traditional cathode materials of LIBs, such...

  • Article
  • Open Access
8 Citations
3,435 Views
12 Pages

A Hierarchically Ordered Mesoporous-Carbon-Supported Iron Sulfide Anode for High-Rate Na-Ion Storage

  • Anupriya K. Haridas,
  • Natarajan Angulakshmi,
  • Arul Manuel Stephan,
  • Younki Lee and
  • Jou-Hyeon Ahn

18 July 2021

Sodium-ion batteries (SIBs) are promising alternatives to lithium-based energy storage devices for large-scale applications, but conventional lithium-ion battery anode materials do not provide adequate reversible Na-ion storage. In contrast, conversi...

  • Article
  • Open Access
5 Citations
2,454 Views
14 Pages

Synergistic Effect of Zn–Co Bimetallic Selenide Composites for Lithium–Sulfur Battery

  • Deng Li,
  • Huinan Pan,
  • Zhonghai Lin,
  • Xiulian Qiu,
  • Xinyu Zhao,
  • Wei Yang,
  • Wenzhi Zheng and
  • Fengming Ren

Compared with monometallic selenides, heterogeneous bimetallic selenides have rich phase boundaries and superior electrical conductivity. ZnSe/CoSe2 composites were prepared by introducing Zn metal and using ZIF-8/67 as the precursor through the syne...

  • Review
  • Open Access
103 Citations
51,291 Views
36 Pages

17 January 2024

The primary goal of this review is to provide a comprehensive overview of the state-of-the-art in solid-state batteries (SSBs), with a focus on recent advancements in solid electrolytes and anodes. The paper begins with a background on the evolution...

  • Article
  • Open Access
5 Citations
4,539 Views
14 Pages

A Layered Hybrid Oxide–Sulfide All-Solid-State Battery with Lithium Metal Anode

  • Juliane Hüttl,
  • Nicolas Zapp,
  • Saoto Tanikawa,
  • Kristian Nikolowski,
  • Alexander Michaelis and
  • Henry Auer

10 October 2023

Different classes of solid electrolytes for all-solid-state batteries (ASSB) are currently being investigated, with each of them suitable for a different ASSB concept. Their combination in hybrid battery cells enables the use of their individual bene...

  • Feature Paper
  • Article
  • Open Access
15 Citations
5,378 Views
25 Pages

Worth from Waste: Utilizing a Graphite-Rich Fraction from Spent Lithium-Ion Batteries as Alternative Reductant in Nickel Slag Cleaning

  • Anna Dańczak,
  • Ronja Ruismäki,
  • Tommi Rinne,
  • Lassi Klemettinen,
  • Hugh O’Brien,
  • Pekka Taskinen,
  • Ari Jokilaakso and
  • Rodrigo Serna-Guerrero

19 July 2021

One possible way of recovering metals from spent lithium-ion batteries is to integrate the recycling with already existing metallurgical processes. This study continues our effort on integrating froth flotation and nickel-slag cleaning process for me...

  • Article
  • Open Access
24 Citations
4,004 Views
10 Pages

V3S4 Nanosheets Anchored on N, S Co-Doped Graphene with Pseudocapacitive Effect for Fast and Durable Lithium Storage

  • Naiteng Wu,
  • Di Miao,
  • Xinliang Zhou,
  • Lilei Zhang,
  • Guilong Liu,
  • Donglei Guo and
  • Xianming Liu

18 November 2019

Construction of a suitable hybrid structure has been considered an important approach to address the defects of metal sulfide anode materials. V3S4 nanosheets anchored on an N, S co-coped graphene (VS/NSG) aerogel were successfully fabricated by an e...

  • Article
  • Open Access
1 Citations
982 Views
15 Pages

Nickel-Rich Cathodes for Solid-State Lithium Batteries: Comparative Study Between PVA and PIB Binders

  • José M. Pinheiro,
  • Beatriz Moura Gomes,
  • Manuela C. Baptista and
  • M. Helena Braga

15 July 2025

The growing demand for high-energy, safe, and sustainable lithium-ion batteries has increased interest in nickel-rich cathode materials and solid-state electrolytes. This study presents a scalable wet-processing method for fabricating composite catho...

  • Article
  • Open Access
26 Citations
5,884 Views
13 Pages

The Stabilizing of 1T-MoS2 for All-Solid-State Lithium-Ion Batteries

  • Peidian Chong,
  • Ziwang Zhou,
  • Kaihong Wang,
  • Wenhao Zhai,
  • Yafeng Li,
  • Jianbiao Wang and
  • Mingdeng Wei

29 December 2022

All-solid-state batteries (SSBs) are prospective candidates for a range of energy accumulation systems, delivering higher energy densities compared to batteries which use liquid electrolytes. Amongst the numerous solid-state electrolytes (SEs), sulfi...

  • Review
  • Open Access
14 Citations
8,018 Views
48 Pages

10 September 2024

Renewable and non-renewable energy harvesting and its storage are important components of our everyday economic processes. Lithium-ion batteries (LIBs), with their rechargeable features, high open-circuit voltage, and potential large energy capacitie...

  • Review
  • Open Access
62 Citations
11,799 Views
53 Pages

5 August 2020

Sodium-ion batteries (SIBs) were investigated as recently as in the seventies. However, they have been overshadowed for decades, due to the success of lithium-ion batteries that demonstrated higher energy densities and longer cycle lives. Since then,...

  • Article
  • Open Access
34 Citations
5,086 Views
10 Pages

MOF-Derived FeS/C Nanosheets for High Performance Lithium Ion Batteries

  • Jianguo Zhao,
  • Zhuan Hu,
  • Dezhu Sun,
  • Hong Jia and
  • Xianming Liu

30 March 2019

In recent years, transitional metal sulfides have received much attention as lithium ion batteries (LIBs) anode. In this paper, FeS/C nanosheets are prepared through Fe-based metal organic frameworks (Fe-MOFs) as a precursor. The electrochemical perf...

  • Article
  • Open Access
1,458 Views
11 Pages

Two-Dimensional ABS4 (A and B = Zr, Hf, and Ti) as Promising Anode for Li and Na-Ion Batteries

  • Shehzad Ahmed,
  • Imran Muhammad,
  • Awais Ghani,
  • Iltaf Muhammad,
  • Naeem Ullah,
  • Nadeem Raza,
  • Yong Wang,
  • Xiaoqing Tian,
  • Honglei Wu and
  • Danish Khan

4 November 2024

Metal ion intercalation into van der Waals gaps of layered materials is vital for large-scale electrochemical energy storage. Transition-metal sulfides, ABS4 (where A and B represent Zr, Hf, and Ti as monolayers as anodes), are examined as lithium an...

  • Review
  • Open Access
59 Citations
16,261 Views
20 Pages

Perovskite Solid-State Electrolytes for Lithium Metal Batteries

  • Shuo Yan,
  • Chae-Ho Yim,
  • Vladimir Pankov,
  • Mackenzie Bauer,
  • Elena Baranova,
  • Arnaud Weck,
  • Ali Merati and
  • Yaser Abu-Lebdeh

7 November 2021

Solid-state lithium metal batteries (LMBs) have become increasingly important in recent years due to their potential to offer higher energy density and enhanced safety compared to conventional liquid electrolyte-based lithium-ion batteries (LIBs). Ho...

  • Article
  • Open Access
2 Citations
1,272 Views
10 Pages

18 November 2024

As an important component of LIBs, the electrode material plays a crucial role in determining the lithium (Li) storage performance in LIBs. In this study, MoS2 nano-flowers were synthesized using a one-pot hydrothermal method. The resulting MoS2 nano...

  • Review
  • Open Access
7,368 Views
35 Pages

Solid-state lithium batteries (SSLBs) have emerged as a promising alternative to conventional lithium-ion systems due to their superior safety profile, higher energy density, and potential compatibility with lithium metal anodes. However, a major cha...

  • Review
  • Open Access
2,249 Views
31 Pages

Laser material processing is emerging as a critical manufacturing technology in the advancement of solid-state lithium batteries (SSLBs), offering numerous advantages in precision, efficiency, and versatility. This mini-review explores the applicatio...

  • Article
  • Open Access
35 Citations
6,564 Views
10 Pages

Chemical Dealloying Synthesis of CuS Nanowire-on-Nanoplate Network as Anode Materials for Li-Ion Batteries

  • Zhifeng Wang,
  • Xiaomin Zhang,
  • Yongguang Zhang,
  • Man Li,
  • Chunling Qin and
  • Zhumabay Bakenov

9 April 2018

CuS is a metal sulfide anode material used in constructing lithium ion batteries (LIBs) with great promise. However, its practical application is limited by rapid capacity decline, poor cycling, and rate performance. In this work, the CuS nanowire-on...

  • Review
  • Open Access
22 Citations
13,842 Views
30 Pages

This review focuses on the promising technology of solid-state batteries (SSBs) that utilize lithium metal and solid electrolytes. SSBs offer significant advantages in terms of high energy density and enhanced safety. This review categorizes solid el...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,051 Views
12 Pages

19 January 2023

The promised prospects of Li–S technology, especially within the energy situation of the 21st century, have sparked a renewed interest from the scientific community in the 2000s. In this context, we present our new vision for the fabrication of...

  • Article
  • Open Access
35 Citations
5,395 Views
15 Pages

MoO3@MoS2 Core-Shell Structured Hybrid Anode Materials for Lithium-Ion Batteries

  • Muhammad Faizan,
  • Sajjad Hussain,
  • Mobinul Islam,
  • Ji-Young Kim,
  • Daseul Han,
  • Jee-Hwan Bae,
  • Dhanasekaran Vikraman,
  • Basit Ali,
  • Saleem Abbas and
  • Hyun-Seok Kim
  • + 3 authors

10 June 2022

We explore a phase engineering strategy to improve the electrochemical performance of transition metal sulfides (TMSs) in anode materials for lithium-ion batteries (LIBs). A one-pot hydrothermal approach has been employed to synthesize MoS2 nanostruc...