Search Results (6,127)

In this study, we investigate the catalytic degradation of polystyrene (PS) in water at low temperature (90–110 ${}^{\circ }$C, 1 atm) using a multiphase carbide–alloy catalyst obtained by mechanosynthesis. X-ray diffraction and scanning electron microscopy confirm a mixture of Mo–W carbides and Fe/Ni alloys, consistent with multiple types of active sites. High-resolution mass spectrometry (MS) is used to assign products by oligomer-series spacing (styrene repeat mass, 104.15 Da) and the residual mass $\Delta m$ for end-group identification. At 90 ${}^{\circ }$C without catalyst, the spectrum shows PS fragments between $m/z=888$–4618, consistent with thermal depolymerization. With catalyst at 90 ${}^{\circ }$C, new lower-$m/z$ peaks emerge and long-chain signals diminish, indicating enhanced chain scission under mild conditions. Increasing the temperature to 100 and 110 ${}^{\circ }$C yields even lighter ions (e.g., $m/z=307.59$ and 247.88), confirming stronger cracking and a larger number of distinct products. End groups inferred from $\Delta m$ include alkenes (C${}_3$–C${}_7$), alkanes (C${}_4$, C${}_7$), cyclic C${}_6$–C${}_7$ fragments, and alcohols, which are consistent with protolytic C–C bond cleavage (Haag–Dessau), oxidative dehydrogenation, and subsequent hydrogenation/hydration on metal/carbide sites. Overall, the results show that water-activated carbide–alloy catalysts can drive PS deconstruction at low temperature, shifting products toward shorter chains with useful functional groups, while a simple MS-based rule set provides a transparent and reproducible approach to product assignment. Full article

Aramid Fiber Reinforced Plastic (AFRP) and aluminum alloy Al7075-T6 are widely used in the aerospace industry because they offer a high strength-to-weight ratio and reliable structural performance. However, drilling through stacked AFRP and Al7075-T6 materials in a single operation presents considerable challenges due to the differences in their mechanical and thermal properties. In this study, three types of customized twist drill bits were designed and fabricated to evaluate their effectiveness in single-shot drilling of these stacked materials. The drill geometries included the W-point design, the tapered web design, and the burnishing design. Each drill bit was tested using its own optimized drilling parameters to produce a total of one hundred holes. The aim was to determine which drill geometry provided the best overall performance in terms of tool wear and hole quality. After the drilling experiments, the tool tips were examined using a Scanning Electron Microscope (SEM) to observe wear characteristics and analyze elemental composition. The analysis revealed that aluminum adhered to the cutting lips of all drill bits. The percentage of adhesion layer, known as percentage of adhesion layer (PAL), was calculated to assess the severity of material adhesion. In addition, the morphology of the produced chips and dust was analyzed to support the PAL results. The findings showed that the drill bit with the lowest PAL value demonstrated superior wear resistance, a longer tool life, and the ability to produce holes of higher quality when drilling AFRP and Al7075-T6 stacked materials. Full article

The growing demand for reliable orthopedic implants has driven extensive research into biomaterials and metal alloys for the development of bone scaffolds. This review summarizes current progress in improving scaffold performance by optimizing mechanical strength, biocompatibility, and bone integration. Key studies on material choice, modeling methods, manufacturing techniques, and surface treatments are discussed, with a special focus on titanium-based alloys due to their favorable mechanical and biological properties. Computational tools, particularly finite element modeling, are increasingly used alongside experimental findings to illustrate mechanical behavior and to guide design of structures that more closely resemble natural bone. Both additive and traditional manufacturing routes are considered, emphasizing how porosity, geometry, and fabrication parameters affect mechanical stability and tissue response. Surface modification approaches, both physical and chemical can enhance cell attachment and antimicrobial function. Overall, this paper shows how combining materials science, mechanical analysis, and biological testing helps develop bone scaffolds that offer durable mechanical support and clinical outcomes. Full article

In this study, medium- and high-entropy carbide systems with compositions WC-TiC-TaC-HfC and WC-TiC-TaC-HfC-ZrC were successfully synthesized via a combination of mechanical activation (using high-energy ball milling, HEBM) and spark plasma sintering (SPS) at 1900 °C. Investigation of the SPS consolidation kinetics revealed that both systems undergo single-stage active densification via a solid-state sintering mechanism within the temperature range of 1316–1825 °C. The introduction of ZrC into the five-component system led to a 22% decrease in the maximum shrinkage rate (from 0.9 to 0.7 mm·min⁻¹), which is attributed to the manifestation of a sluggish diffusion effect, characteristic of high-entropy systems. X-ray diffraction analysis of the consolidated samples confirmed the formation of predominantly single-phase high-entropy solid solutions (W-Ti-Ta-Hf)C and (W-Ti-Ta-Hf-Zr)C with a NaCl-type cubic structure (space group Fm-3m) and lattice parameters of 4.4101 Å and 4.4604 Å, respectively. Energy-dispersive X-ray spectroscopy revealed a near-equimolar distribution of metallic components with deviations not exceeding ±1.9 at. %. The addition of ZrC increased the average crystallite size by 84.3% (from 83.6 to 153.1 nm). Both systems achieved comparable relative densities of ~91.75%; however, they exhibited differences in hardness distribution: the four-component system is characterized by a higher average microhardness (1860 HV), while the five-component system exhibits a higher macrohardness HV30 (2008.1). The established correlations between composition, phase formation, microstructure, and properties provide a fundamental basis for the targeted design of high-entropy carbide ceramics with tailored characteristics for high-temperature applications. Full article

Al–Si–Cu alloy is one of the aluminum die-cast alloys widely used in industry. Due to the presence of Si and Cu elements in the Al–Si–Cu alloy, the corrosion resistance of the Al–Si–Cu alloy is lowered. Thus, developing a corrosion-resistant film on the Al–Si–Cu alloy is necessary. A layered double hydroxide (LDH) film is recognized as a promising corrosion-resistant coating. LDHs exhibit a distinct structure where positively charged basic layers (metal hydroxides) are interleaved with intermediate layers that accommodate charge-compensating anions and hydration water. The positively charged layers allow for the exchange of anions as interlayers, enabling the incorporation of various anions into the interlayer. The difference in the anion species in the interlayer of the LDH films can affect corrosion-resistant performance. In this study, we aimed to prepare Mg–Al LDH films intercalated with different anions (NO₃⁻, MoO₄²⁻, VO₄³⁻, and PO₄³⁻) and investigate the corrosion resistance of the LDH films. The films were prepared on die-cast Al–Si–Cu alloys using steam coating and immersion processes. The prepared LDH films were characterized by XRD, SEM, FT-IR, and electrochemical measurements. The electrochemical measurements revealed that Mg–Al LDH films intercalated with MoO₄²⁻ showed the most superior corrosion resistance among all films prepared in this study. Full article

The objective of this study was to investigate the effect of surface disinfectant solutions against COVID-19 on the surface roughness, gloss, and color of removable denture materials. Fifty rectangular metallic specimens made of Co-Cr alloy and fifty disk-shaped specimens made of PMMA were prepared according to the manufacturers’ instructions. Fifty maxillary right central incisors were also included in the study. The above-mentioned specimens were equally divided into five groups (n = 10). Four disinfectant solutions were tested (0.1 wt% NaOCl, 0.5 wt% H₂O₂, 78 wt% ethanol, and 1 wt% Povidone Iodine), and freshly distilled water was used as the control. To simulate clinical practice, each specimen was immersed in the disinfectant solution 15 times. All specimens were marked, and surface roughness, gloss, and color were measured before and after immersion. All roughness parameters (Sa, Sq, Sz, Sc, and Sv) and gloss values before and after immersion were statistically compared. ΔE*ab values were statistically compared with perception and acceptability thresholds according to ISO/TR 28642. No significant differences were identified for surface roughness parameters for all groups tested. All materials demonstrated a significant increase in gloss after aging regime, while only the metallic specimens illustrated ΔE*ab values higher than the acceptability threshold after disinfection with H₂O₂. None of the surface properties deteriorated after exposure to tested disinfectants, and thus, all of them can be effectively implemented in everyday practice. Full article

Metallic mechanical metamaterials have attracted the attention of many industrial sectors due to their unique properties which enable them to outperform natural materials in unconventional ways. Metal metamaterials encompass multiple fields, including materials science, mechanics, and industrial technology, and they have become particularly popular following the implementation of reliable, high-resolution, efficient metal additive manufacturing processes. This review takes a joint approach, providing an in-depth analysis of the base materials and geometries that characterize metamaterials in order to understand their behavior in response to impacts at different load regimes and to offer readers a critical overview of the most suitable design choices for energy absorption systems. Furthermore, this review highlights advanced metamaterial optimization methods that are useful for increasing the mechanical energy absorbed avoiding peak impulse transfer to the people, instrumentation, or generic loads that mechanical metamaterials are designed to protect. Full article

The first-principles method using density functional theory (DFT) reveals the mechanics, electronic structure, and magnetic properties of six Zr-based equiatomic quaternary Heusler compounds and their transformation under hydrostatic pressure. The results show that these compounds maintain mechanical stability under hydrostatic pressures of 0–100 GPa, and the ductility of all the alloys is improved except ZrCrFeGe. In the ground state structure, ZrVFeAl and ZrCrFeGe are half metals, ZrVCoAl and ZrCrFeAl are spin gapless semiconductors, while ZrCrMnAl and ZrMnFeAl are regarded as nearly half metals. ZrVFeAl, ZrVCoAl, ZrCrFeAl, and ZrCrFeGe have high spin polarization and satisfy the Slater–Pauling rule, and their spin-flip band gaps are 0.43 eV, 0.35 eV, 0.14 eV, and 0.11 eV, respectively. These half-metallic compounds maintain half-metallicity within a certain pressure range, while spin gapless semiconductors (SGS) complete the SGS~half-metal~near-half-metal transition under hydrostatic pressure. These half-metallic compounds and spin gapless semiconductors are ideal candidates for spintronic applications. Full article

Fluorinated polyurethanes (FPUs) and their composites are promising new barrier materials with a broad range of applications. In particular, they are widely used as effective hydrophobic coatings that perform well under prolonged environmental exposure. Despite their extensive use, the behavior of FPU coatings under specific climatic conditions remains insufficiently studied. In this paper, dynamic mechanical analysis (DMA) is employed to evaluate the structural, mechanical, and relaxation evidence of climatic aging for paint-and-varnish coatings, which protect the surfaces of metallic alloys and polymer composites. Special knowledge of structural and physical–mechanical properties—such as a glass transition temperature (T_g), elastic moduli (E′ and E″) in both glassy and elastic states, degree of crosslinking, and other features relevant to coatings designated for climatic impact prevention—can be reliably obtained by the DMA technique. Along with previously published data, the currently obtained results for FPU have been analyzed for a long time (three years) of exposure in a wide range of climatic regions in Russia. Full article

Hexafluoroethane and 1,1,1,3,3,3-hexafluoropropane (abbreviated as HFC-236fa and R-116, respectively, referred to as C₂F₆ and C₃H₂F₆ based on their molecular formulas) were selected as the object to study the corrosion effects of gas fire-extinguishing agents on different metal materials in the storage state. Typical metal materials used in storage containers including 304 stainless steel, Q235 carbon steel, 6061 aluminum alloy, H59 brass, and T2 copper were subjected to full-immersion corrosion experiments under simulated storage conditions with high-pressure and alternating high–low temperature cycles. High-definition cameras, a scanning electron microscope (SEM), high-precision electronic balances, an energy-dispersive spectrometer (EDS), and X-ray photoelectron spectroscopy (XPS) were used to explore the corrosion characteristics. The chemical reactions and mechanisms were analyzed. The results indicate the following: (1) A thin corrosion layer appears on the surface of the metal with varying degrees of severity but low prevalence. (2) The corrosion rates of C₂F₆ and C₃H₂F₆ were comparable and varied in the following order: 6061 aluminum alloy > Q235 carbon steel > H59 brass > 304 stainless steel > T2 copper. (3) C₃H₂F₆ is slightly higher than C₂F₆ in all corrosion rate values. (4) The corrosion of metal materials is mainly attributed to the reaction between metal elements and the F-containing groups produced by the cleavage of C₂F₆ and C₃H₂F₆. The generated metal halides in turn catalyze the cleavage of C₂F₆ and C₃H₂F₆. This catalytic effect may be positively correlated with the reactivity of the metal element. (5) The higher corrosive activity of C₃H₂F₆ compared to C₂F₆ is attributed to the ease of C–C bond cleavage, catalyzed by metal halogens. This study provides theoretical insights into the corrosion ability of halogenated alternatives as a replacement for halon-based fire extinguishers. Full article

Magnesium (Mg) alloys are the lightest metals used in engineering structures, making them highly valuable for lightweight designs in aerospace, automotives, and related industries. Their low density offers clear advantages for reducing product weight and improving energy efficiency–key priorities in modern manufacturing. However, their unique crystal structure leads to notable drawbacks: low plasticity at room temperature, uneven performance across different directions, and inconsistent strength under tension versus compression. These issues have severely limited their broader application beyond specialized use cases. Shear deformation methods address this challenge by creating high strain variations and complex stress conditions. This approach provides an effective way to regulate the internal structure of Mg alloys and enhance their overall performance, overcoming the inherent limitations of their crystal structure. This paper systematically summarizes current research on using shear deformation to process Mg alloys. It focuses on analyzing key structural changes induced by shear, including the formation and evolution of shear–related features, real–time grain reorganization, crystal twinning processes, the distribution of additional material phases, and reduced directional performance bias. The review also clarifies how these structural changes improve critical mechanical traits: strength, plasticity, formability, and the balance between tensile and compressive strength. Additionally, the paper introduces advanced shear–based processes and their derivative technologies, such as equal–channel angular extrusion, continuous shear extrusion, and ultrasonic vibration–assisted shearing. It also discusses strategies for constructing materials with gradient or mixed internal structures, which further expand the performance potential of Mg alloys. Finally, the review outlines future development directions to advance this field: developing shear processes that combine multiple physical fields, conducting real–time studies of microscale mechanisms, designing tailored shear paths for high–performance Mg alloys, and evaluating long–term service performance. These efforts aim to promote both theoretical innovation and industrial application of shear deformation technology for Mg alloys. Full article

Electrocatalytic water splitting for hydrogen production is a crucial technology in achieving carbon neutrality. The development of efficient and stable hydrogen evolution reaction (HER) electrocatalysts is a core challenge in this field. This review systematically summarizes the latest research advancements in nanoporous transition metal-based catalysts, covering metal alloys and compounds. Through strategies such as compositional optimization, crystal structure modulation, interface engineering, and nanoporous structure design, these non-precious metal catalysts exhibit outstanding performance comparable to commercial platinum-carbon catalysts across a wide pH range. This paper thoroughly discusses the catalytic mechanisms of different material systems, including electronic structure regulation, active site exposure, and mass transport optimization. Finally, the challenges faced in current research are summarized, and future directions are projected, including scalable fabrication processes and performance validation in real electrolysis cell environments. This review provides significant insights into designing next-generation efficient and stable non-precious metal electrocatalysts. Full article

The processing of bulk amorphous alloys is typically realized through superplastic deformation in the supercooled liquid region, and current research efforts predominantly focus on enhancing formability by optimizing processing parameters such as temperature and duration. However, excessive temperatures or prolonged exposure times can induce crystallization, which severely compromises the mechanical and functional properties of the alloy. This study presents the design of an ultrasonic vibration (UV)-assisted metal hot-forming apparatus that integrates an ultrasonic vibration field into the superplastic flow deformation of amorphous alloys. High-temperature compression experiments were conducted on Zr₅₅Cu₃₀Al₁₀Ni₅ amorphous alloy, and finite element simulations were performed to model the experimental process. Results show that ultrasonic vibration reduces the flow stress of the amorphous alloy, thereby enhancing its superplastic deformation capability. Simulation analysis reveals that surface effects arise from periodic interface separation between the pressure plate and the specimen caused by ultrasonic vibration, leading to a cyclic disappearance of friction forces, which manifest macroscopically as a reduction in effective friction. On the other hand, vibration introduces additional strain rates. Since the undercooled liquid of amorphous alloys exhibits non-Newtonian fluid behavior characterized by shear-thinning, ultrasonic vibration assistance can effectively reduce the apparent viscosity, thereby improving their filling capacity. Full article

The 2000 series aluminium alloys are an attractive option for lightweight structures, but solidification cracking in fusion welding remains an issue in additive manufacturing technologies. Al-Cu-Li alloys, in particular, have gained considerable attention due to their excellent strength-to-weight ratio and corrosion and fatigue resistance, making them highly suitable for aerospace components. Nevertheless, their narrow solidification range makes them highly susceptible to cracking, porosity formation, and elemental evaporation during fusion-based AM processes. These challenges underscore the necessity for advanced processing technologies and the development of suitable feedstock materials to ensure weld integrity and optimal performance. Although Al–Cu–Li alloys are highly valued in the aerospace sector, the application of wire arc additive manufacturing (WAAM) is currently limited by the lack of commercially available wire compositions. This study focuses on the use of powder metallurgy Al-Cu-Li wires in wire arc additive manufacturing, specifically using plasma metal deposition technology, to explore welding characteristics. This research demonstrates the development of an alternative wire using powder metallurgy for WAAM. Powder metallurgy wires were deposited on 5053 and 7075 aluminium substrates, and their microstructure, chemical composition, and mechanical properties were analysed. Key findings include significant elemental losses of Li and Cu during deposition—approximately 55% and 25%, respectively—as well as noticeable variations in microstructure, porosity, and grain morphology, depending on the substrate. Deposits on the 5083 aluminium exhibited more equiaxed grains and a higher chemical homogeneity compared to those on the 7075 substrate. This work establishes a link between material design and additive manufacturing by demonstrating that powder metallurgy Al–Cu–Li wires can be effectively processed by WAAM, achieving controlled elemental losses and a uniform microstructure that enhances weld integrity in aerospace components. Full article