Search Results (16)

Path integral Monte Carlo simulations and closure computations of quantum fluid triplet structures in the diffraction regime are presented. The principal aim is to shed some more light on the long-standing problem of quantum fluid triplet structures. This topic can be tackled via path integrals in an exact, though computationally demanding, way. The traditional approximate frameworks provided by triplet closures are complementary sources of information that (unexpectedly) may produce, at a much lower cost, useful results. To explore this topic further, the systems selected in this work are helium-3 under supercritical conditions and the quantum hard-sphere fluid on its crystallization line. The fourth-order propagator in the Jang-Jang-Voth’s form (for helium-3) and Cao–Berne’s pair action (for hard spheres) are employed in the corresponding path integral simulations; helium-3 interactions are described with Janzen–Aziz’s pair potential. The closures used are Kirkwood superposition, Jackson–Feenberg convolution, the intermediate AV3, and the symmetrized form of Denton–Ashcroft approximation. The centroid and instantaneous triplet structures, in the real and the Fourier spaces, are investigated by focusing on salient equilateral and isosceles features. To accomplish this goal, additional simulations and closure calculations at the structural pair level are also carried out. The basic theoretical and technical points are described in some detail, the obtained results complete the structural properties reported by this author elsewhere for the abovementioned systems, and a meaningful comparison between the path integral and the closure results is made. In particular, the results illustrate the very slow convergence of the path integral triplet calculations and the behaviors of certain salient Fourier components, such as the double-zero momentum transfers or the equilateral maxima, which may be associated with distinct fluid conditions (e.g., far and near quantum freezing). Closures are shown to yield valuable triplet information over a wide range of conditions, as ascertained from the analyzed centroid structures, which mimic those of fluids at densities higher than the actual ones; thus, closures should remain a part of quantum fluid triplet studies. Full article

This study reviews the integration of Brayton Cycle (BC) systems in nuclear power generation, emphasizing their potential to enhance thermal efficiency and operational flexibility over traditional Rankine Cycle (RC) systems. Key working fluids, such as helium (He), supercritical carbon dioxide (sCO₂), nitrogen (N₂), and air, are evaluated for their performance, efficiency, and compatibility with nuclear systems. He is recognized for its high thermal conductivity and inertness at elevated temperatures, while sCO₂ demonstrates advantages in compactness and efficiency in midrange temperatures. This article also highlights the importance of compressor designs in optimizing BC performance and reviews, available compressor technologies. Axial and centrifugal compressor designs enable efficient gas compression while managing the thermal and mechanical stresses associated with high-pressure operations in nuclear systems. Combined with variable geometry components and advanced materials, these technologies address the challenges posed by varying load conditions. Despite the promising features of BC systems, several challenges persist, including high leakage rates and material degradation under extreme conditions, which necessitate robust sealing technologies and thorough testing. The insights gained from operational experiences at facilities, such as the Oberhausen II plant and the High-Temperature He Test Facility (HHV), underscore the complexities involved in designing high-temperature gas turbines for nuclear applications. This review concludes that as the nuclear industry evolves, BC systems hold significant promise for contributing to a sustainable energy future, particularly in the context of small modular reactors (SMRs) and microreactors. Further exploration of combined cycle configurations that combine BCs with RCs may enhance overall efficiency and flexibility in power generation. Full article

The Polish Free-Electron Laser (PolFEL), which is currently under construction in the National Centre for Nuclear Research in Świerk near Warsaw, will comprise an electron gun and from four to six cryomodules, each accommodating two nine-cell TESLA RF superconducting resonant cavities. To cool the superconducting resonant cavities, the cryomodules will be supplied with superfluid helium at a temperature of 2 K. Other requirements regarding the cooling power of PolFEL result from the need to cool the power couplers for the accelerating cryomodules (5 K) and thermal shields, which limit the heat inleaks due to radiation (40–80 K). The machine will utilize several thermodynamic states of helium, including two-phase superfluid helium, supercritical helium, and low-pressure helium vapours. Supercritical helium will be supplied from a cryoplant by a cryogenic distribution system (CDS)—transfer line and valve boxes—where it will be thermodynamically transformed into a superfluid state. This article presents the architecture of the CDS, discusses several design solutions that could have been decided on with the use of second law analysis, and presents the design methodology of the chosen CDS elements. Full article

Using hydrogen as a working fluid in cryocoolers can potentially benefit cryocooling technologies and hydrogen liquefaction. Moreover, in flow-through thermoacoustic systems, hydrogen can be efficiently cooled and undergo ortho-parahydrogen isomeric conversion, which is important for the efficient storage of cryogenic hydrogen. A traveling-wave regenerator is analyzed in this study, using the thermoacoustic theory with a superimposed mean flow and an empirical correlation for hydrogen isomer conversion. A regenerator with hydrogen fluid is shown to achieve higher performance in comparison with helium as the working fluid. However, the hydrogen system performance degrades at supercritical pressures and subcritical temperatures in compressed liquid states. In regenerators with mean flow, using hydrogen as the working fluid leads to higher cooling powers and efficiencies, but helium systems are able to achieve colder temperatures. Full article

For the large-scale fusion magnets of the International Thermonuclear Experimental Reactor (ITER) tokamak, wound with cable-in-conduit conductors, the application of sophisticated numerical models able to analyse the thermal–hydraulic behaviour during plasma scenarios is of paramount importance to guarantee an adequate stability margin during operating conditions. The SuperMagnet code has been developed by CryoSoft with the intent to simultaneously simulate the electrical, thermal and hydraulic phenomena occurring during the operation of superconducting coils. In this work, the SuperMagnet code is applied to analyse the thermal–hydraulic behaviour of the central solenoid of the ITER tokamak under the plasma scenario. The central solenoid (CS) is composed of six modules for a total amount of 240 pancakes. The software is able to tackle the complex structure of the CS and its cryogenic closed loop. In the present work, the circulation pump operation and the heat transfer to the helium bath are investigated. The results presented here show the temperature evolution of the magnet and of the supercritical helium during the plasma scenario, which allows the determination of the operation margin of the CS. Full article

The current developments in the theory of quantum static triplet correlations and their associated structures (real r-space and Fourier k-space) in monatomic fluids are reviewed. The main framework utilized is Feynman’s path integral formalism (PI), and the issues addressed cover quantum diffraction effects and zero-spin bosonic exchange. The structures are associated with the external weak fields that reveal their nature, and due attention is paid to the underlying pair-level structures. Without the pair, level one cannot fully grasp the triplet extensions in the hierarchical ladder of structures, as both the pair and the triplet structures are essential ingredients in the triplet response functions. Three general classes of PI structures do arise: centroid, total continuous linear response, and instantaneous. Use of functional differentiation techniques is widely made, and, as a bonus, this leads to the identification of an exact extension of the “classical isomorphism” when the centroid structures are considered. In this connection, the direct correlation functions, as borrowed from classical statistical mechanics, play a key role (either exact or approximate) in the corresponding quantum applications. Additionally, as an auxiliary framework, the traditional closure schemes for triplets are also discussed, owing to their potential usefulness for rationalizing PI triplet results. To illustrate some basic concepts, new numerical calculations (path integral Monte Carlo PIMC and closures) are reported. They are focused on the purely diffraction regime and deal with supercritical helium-3 and the quantum hard-sphere fluid. Full article

In recent years, fusion energy has assumed an important role in the energy scenario, being a sustainable, environmentally friendly, and practically inexhaustible energy source. Fusion energy could play a crucial role in fully decarbonized electricity production in the second half of this century, helping to meet the increasing energy demand. One of the studied reactors is ARC, a tokamak fusion device characterized by a compact and high-field design initially conceived by researchers at the Massachusetts Institute of Technology, which the Commonwealth Fusion System (CFS) plans to construct in the next decade. This paper is focused on the analysis and development of different configurations for the ARC Balance of Plant Power Conversion System, with the aim of improving the thermodynamic efficiency, which is one of the pillars of sustainability. Three cycles were studied by using the General Electric GateCycle^TM software: a supercritical steam Rankine cycle, a supercritical CO₂ Brayton cycle, and a supercritical helium Brayton cycle. The thermal efficiency of the three options was compared to select the most promising solution. The results showed that the supercritical steam cycle is the best configuration in terms of cycle efficiency for the ARC FNSF Pilot phase. Full article

A newly produced silk fibroin (SF) aerogel particulate system using a supercritical carbon dioxide (scCO₂)-assisted drying technology is herein proposed for biomedical applications. Different concentrations of silk fibroin (3%, 5%, and 7% (w/v)) were explored to investigate the potential of this technology to produce size- and porosity-controlled particles. Laser diffraction, helium pycnometry, nitrogen adsorption–desorption analysis and Fourier Transform Infrared with Attenuated Total Reflectance (FTIR-ATR) spectroscopy were performed to characterize the physicochemical properties of the material. The enzymatic degradation profile of the SF aerogel particles was evaluated by immersion in protease XIV solution, and the biological properties by cell viability and cell proliferation assays. The obtained aerogel particles were mesoporous with high and concentration dependent specific surface area (203–326 m²/g). They displayed significant antioxidant activity and sustained degradation in the presence of protease XIV enzyme. The in vitro assessment using human dermal fibroblasts (HDF) confirm the particles’ biocompatibility, as well as the enhancement in cell viability and proliferation. Full article

A methodological study of triplet structures in quantum matter is presented. The focus is on helium-3 under supercritical conditions (4 < T/K < 9; 0.022 < ${\mathit{\rho }}_{\mathit{N}}/{Å}^{-3}$ < 0.028), for which strong quantum diffraction effects dominate the behavior. Computational results for the triplet instantaneous structures are reported. Path integral Monte Carlo (PIMC) and several closures are utilized to obtain structure information in the real and the Fourier spaces. PIMC involves the fourth-order propagator and the SAPT2 pair interaction potential. The main triplet closures are: AV3, built as the average of the Kirkwood superposition and the Jackson–Feenberg convolution, and the Barrat–Hansen–Pastore variational approach. The results illustrate the main characteristics of the procedures employed by concentrating on the salient equilateral and isosceles features of the computed structures. Finally, the valuable interpretive role of closures in the triplet context is highlighted. Full article

Supercritical carbon dioxide (SC-CO₂) fracturing has been used in developing low permeability and water-sensitive reservoirs in recent years, which is expected to become a new generation of unconventional reservoir fracturing fluid. However, the water-rock interaction characteristics of various lithology shales under SC-CO₂ circumstance and its influence on fracturing effect still need to be investigated. Two kinds of shale samples from C7 and S1 formations of the Ordos Basin were treated by SC-CO₂ with formation water. The aims of the research are to determine the processes taking place in shale reservoir when considering minerals components transformation, porosity/permeability variation, and micro pore-structure change during the SC-CO₂ fracturing. Static and dynamic SC-CO₂ immersed experiments were conducted and the scanning of electron microscopy (SEM) and X-ray diffraction (XRD) was employed to analyze the surface morphology and newly formed minerals. Helium porosimeter, the ultralow permeability meter, and the CT scanner are employed to record the alternation of physical parameters during SC-CO₂ dynamic injection. The experimental results show that the C7 samples are rich of chlorite and easily reacting with SC-CO₂ saturated formation water to form new minerals, but the S1 samples are insensitive to aqueous SC-CO₂. The minimum value of permeability and porosity of the C7 cores appear at 24h in the long-interval experiment, but in the short-interval dynamic experiment, the minimum values move ahead to 12h. The optimal flowback time for the C7 reservoir is before 12 h or after 24 h. The high-pressure SC-CO₂ flooding pushes the new forming minerals particles to migrate to the outlet side and block the pore throat. For the S1 core results, the porosity and permeability change little in both short and long interval experiments. There is no strict flow-back time requirement for S1 reservoir during SC-CO₂ fracturing. This study is significance for the efficient application of SC-CO₂ in the exploitation of shale oil reservoirs. Full article

Detailed thermodynamic, exergoeconomic, and multi-objective analysis are performed for a supercritical recompression Brayton cycle in which the advanced working medium mixture of nitrous oxide and helium (N₂O–He) is utilized for power generation. The thermodynamic and exergoeconomic models are propitious based on the standard components’ mass and energy conservation, exergy balance equation, and exergy cost calculation equation. An investigation of the sensitivity parametric is considered for judging the impact of crucial decision variable parameters on the performance of the proposed Brayton cycle. The proposed cycle’s performance is evaluated by systematic analysis of the thermal efficiency (η_th), exergy efficiency (η_ex), total cost rate ($\stackrel{.}{C}$_total), levelized cost of electricity (LCOE), and the total heat transfer area (A_total). Furthermore, multi-objective optimization is adopted from the viewpoint of the first and second laws of exergoeconomics to find the optimum operating parameters and to improve the circular’s exergoeconomic performance. The final results illustrate that the optimization calculation is based on the fact of the exergoeconomics method; the whole system produces electrical power of 0.277 MW with $\stackrel{.}{C}$_total of USD 18.37/h, while the η_th, η_ex, A_total, and LCOE are 49.14%, 67.29%, 165.55 m² and USD 0.0196/kWh, respectively. It is concluded that the work exergy destruction for the reactor and turbine is higher than that of other components; then, after the multi-objective optimization analysis, the η_th and η_ex improved by 2.08% and 5.07%, respectively, and the $\stackrel{.}{C}$_total, A_total, and LCOE decreased by 13.99%, 0.01%, and 5.13%, respectively. Full article

Hhighly efficient and reliable sealing technology is essential to improve the efficiency of precooled aeroengines. To explore the effects of large ambient temperature gradients on the sealing performance, the thermo-hydrodynamic characteristics of a supercritical helium spiral-grooved face seal were studied numerically, under low-temperature conditions. Considering the real gas effect of helium, the thermal deformations of the seal were analyzed numerically, under different temperature gradients. Additionally, the distributions of the pressure, temperature, and film thickness of the gas film were calculated, and the sealing performances of the seal under a wide range of working conditions were evaluated simultaneously. Results showed that a turning point occurred at the sealing pressure of 1.6 MPa in both the dynamic pressure effect and temperature rise of the gas film under the ambient-temperature gradient, leading to the transformation of the sealing gap, from convergent to divergent. The temperature gradient contributed to decreasing the thermal deformation and improving the sealing performance of the face seal. As the temperature gradient increased, although a mutational phenomenon existed near the sealing temperature of 250 K with both the dynamic pressure effect and the temperature rise, the variation of the opening force was within 120 N and the leakage was more than halved, indicating the broad application prospects of gas face seals in precooled aeroengine systems. Full article

Hybrid solar thermal power plants using the Brayton cycle are currently of great interest as they have proven to be technically feasible. This study evaluates mechanisms to reduce fuel consumption and increase the power generated, improving plant efficiency. An energy and exergy model for the hybrid solar plant is developed using an estimation model for the solar resource to determine the plant operation under specific environmental conditions. The effect of using different working fluids in the Brayton cycle, such as air, and helium in transcritical conditions and carbon dioxide in subcritical and supercritical conditions, is evaluated. Additionally, the plant’s exergy destruction and exergy efficiency are evaluated. In those, it can be highlighted that the helium cycle in the same operating conditions compared to other working fluids can increase the power by 160%, increasing fuel consumption by more than 390%. Full article

As an ideal pressurized gas, helium, especially supercritical helium, has been widely used in the pressurization system of various launch vehicles and spacecraft. This work mainly focuses on the natural convection of cryogenic supercritical helium in a spherical enclosure. Firstly, a three-dimensional numerical model is established and verified with experimental data. Then, the effects of inflation pressure and heating power on the flow and heat transfer characteristics are simulated. At the same time, the relationship between the Rayleigh number and Nusselt number is studied in detail. Finally, an improved natural convection heat transfer correlation modified by introducing the density ratio is obtained. The results show that the increase of the inflation pressure in the cavity is helpful to enhance the natural convection heat transfer of the cryogenic supercritical helium, and the temperature distribution in the cavity tends to be more uniform when the inflation pressure in the cavity increases. As to the improved natural convection heat transfer correlation, the average error between the simulation results and the calculated values is approximately 8%, which can better describe the natural convection heat transfer of cryogenic supercritical helium in the spherical enclosure. Full article

In this study, the nanoscale transformation of the polylactic-co-glycolic acid (PLGA) internal structure, before and after its supercritical carbon dioxide (sc-CO₂) swelling and plasticization, followed by foaming after a CO₂ pressure drop, was studied by small-angle X-ray scattering (SAXS) for the first time. A comparative analysis of the internal structure data and porosity measurements for PLGA scaffolds, produced by sc-CO₂ processing, on a scale ranging from 0.02 to 1000 μm, was performed by SAXS, helium pycnometry (HP), mercury intrusion porosimetry (MIP) and both “lab-source” and synchrotron X-ray microtomography (micro-CT). This approach opens up possibilities for the wide-scale evaluation, computer modeling, and prediction of the physical and mechanical properties of PLGA scaffolds, as well as their biodegradation behavior in the body. Hence, this study targets optimizing the process parameters of PLGA scaffold fabrication for specific biomedical applications. Full article