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26 pages, 28958 KB  
Article
Impact Assessment of Electric Bus Charging on a Real-Life Distribution Feeder Using GIS-Integrated Power Utility Data: A Case Study in Brazil
by Camila dos Anjos Fantin, Fillipe Matos de Vasconcelos, Carolina Gonçalves Pardini, Felipe Proença de Albuquerque, Marco Esteban Rivera Abarca and Jakson Paulo Bonaldo
World Electr. Veh. J. 2025, 16(11), 621; https://doi.org/10.3390/wevj16110621 (registering DOI) - 14 Nov 2025
Abstract
The electrification of public transport with battery electric buses (BEBs) poses technical, regulatory, and environmental challenges. This paper analyzes the impact of BEB charging on a Brazilian urban medium-voltage (MV) feeder using a novel methodology to convert utility GIS data into OpenDSS simulation [...] Read more.
The electrification of public transport with battery electric buses (BEBs) poses technical, regulatory, and environmental challenges. This paper analyzes the impact of BEB charging on a Brazilian urban medium-voltage (MV) feeder using a novel methodology to convert utility GIS data into OpenDSS simulation models. The study utilizes Geographic Database of the Distribution Company (BDGD) data from the Brazilian Electricity Regulatory Agency (ANEEL) and OpenDSS simulations. Motivated by Cuiabá’s proposal to electrify its public bus fleet, four realistic scenarios were simulated, incorporating distributed photovoltaic (PV) generation and vehicle-to-grid (V2G) operation. Results show that up to 118 BEBs can be charged simultaneously without voltage violations. However, thermal overload occurs beyond 56 units, requiring conductor upgrades or load redistribution. PV systems can supply up to 64% of the daily energy demand but introduce reverse power flows and overvoltages, indicating the need for dynamic control. V2G operation enables peak shaving but also leads to overvoltages when more than 33 buses inject power concurrently. The findings suggest that while the current infrastructure partially supports fleet electrification, future scalability depends on integrating smart grid features and reinforcing the system. Although focused on Cuiabá, the methodology offers a replicable approach for low-carbon urban mobility planning in similar developing regions. Full article
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17 pages, 2845 KB  
Article
Experimental Study on the Effects of Oxygen Concentration and Thermal Radiation on the Combustion Characteristics of Wood Plastic Composites at Low Pressure
by Wenbing Li, Xuhong Jia, Wanki Chow and Shupei Tang
Fire 2025, 8(11), 440; https://doi.org/10.3390/fire8110440 - 12 Nov 2025
Abstract
The use of artificial oxygenation to counteract the effects of hypoxia and improve living standards in high-altitude, low-oxygen settings is widespread. A recognized consequence of this intervention is that it elevates the risk of fire occurrence. In this study, we simulated a real [...] Read more.
The use of artificial oxygenation to counteract the effects of hypoxia and improve living standards in high-altitude, low-oxygen settings is widespread. A recognized consequence of this intervention is that it elevates the risk of fire occurrence. In this study, we simulated a real fire environment with low-pressure oxygen enrichment in a plateau area. A new multi-measuring apparatus was constructed by integrating an electronic control cone heater and a low-pressure oxygen enrichment combustion platform to enable the simultaneous measurement of multiple parameters. The combined effects of varying oxygen concentrations and thermal irradiance on the combustion behavior of wood plastic composites (WPCs) under specific low-pressure conditions were investigated, and alterations in crucial combustion parameters were examined and evaluated. Increasing the oxygen concentration and heat flux significantly reduced the ignition and combustion times. For instance, at 50 kW/m2, the ignition time decreased from 75 s to 16 s as the oxygen concentration increased from 21% to 35%. This effect was suppressed by higher heat fluxes. Compared with low oxygen concentrations and low thermal radiation environments, the ignition time of the material under high oxygen concentrations and high thermal radiation conditions was shortened by more than 78%, indicating that its flammability is enhanced under extreme conditions. Higher oxygen concentrations enhanced the heat feedback to the fuel surface, which accelerated pyrolysis and yielded a more compact flame with reduced dimensions and a color transition from blue-yellow to bright yellow. This intensified combustion was further manifested by an increased mass loss rate (MLR), elevated flame temperature, and a decline in residual mass percentage. The combustion of WPCs displayed distinct stage characteristics, exhibiting “double peak” features in both the MLR and flame temperature, which were attributed to the staged pyrolysis of its wood fiber and plastic components. Full article
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16 pages, 527 KB  
Article
Effect of Food Proteins on Wheat Starch Pasting and Thermal Properties
by Andrés Gustavo Teobaldi, Esteban Josué Carrillo Parra, Gabriela Noel Barrera and Pablo Daniel Ribotta
Foods 2025, 14(22), 3865; https://doi.org/10.3390/foods14223865 - 12 Nov 2025
Abstract
The objective of this study was to analyze the effect of different food proteins (wheat gluten, soy protein, whey protein, and ovalbumin), applied in different proportions, on the pasting and thermal properties of wheat starch using a Rapid Visco Analyzer (RVA) and Differential [...] Read more.
The objective of this study was to analyze the effect of different food proteins (wheat gluten, soy protein, whey protein, and ovalbumin), applied in different proportions, on the pasting and thermal properties of wheat starch using a Rapid Visco Analyzer (RVA) and Differential Scanning Calorimetry (DSC), enriching the RVA analysis with mathematical models for a deeper mechanistic understanding of the pasting behavior. Gluten and whey proteins significantly increased peak viscosity (up to +105% and +22%, respectively), while soy protein and ovalbumin decreased it (up to −16%). Conversely, the addition of all four proteins resulted in an increase in the starch pasting profile during the cooling period of the starch pastes (up to +95%). Additionally, the presence of all four proteins accelerated the starch paste formation process (0.2–0.9 min). Mathematical models showed that the addition of proteins accelerated both the viscosity decline phase (breakdown) immediately following the peak and the subsequent viscosity increase phase (setback), leading to the final viscosity. All proteins increased the gelatinization onset temperature, indicating restricted water availability for starch. Consequently, a decrease in gelatinization enthalpy was observed, most notably with ovalbumin (−28%) and whey protein (−24%). Conversely, the retrogradation characteristics showed no consistent pattern. These results offer valuable insights into managing the thermal stability of starch within diverse food applications (e.g., flour-based products) utilizing different protein sources. Full article
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14 pages, 9095 KB  
Article
Facile Preparation of Glass Fiber Wool/MTMS Aerogels with Improved Thermal Insulation and Safety
by Yong Ren, Huanlin Zhang, Xingwei Jiang, Miao Liu and Zhi Li
Gels 2025, 11(11), 906; https://doi.org/10.3390/gels11110906 - 12 Nov 2025
Abstract
With the continuous increase in global energy consumption and the escalating severity of climate change, the development of high-performance thermal insulation materials is crucial for reducing energy waste and carbon emissions. In this work, a facile method was proposed to prepare thermal-insulating glass [...] Read more.
With the continuous increase in global energy consumption and the escalating severity of climate change, the development of high-performance thermal insulation materials is crucial for reducing energy waste and carbon emissions. In this work, a facile method was proposed to prepare thermal-insulating glass fiber wool/methyltrimethoxysilane aerogel (GFWA) composites through vacuum-assisted impregnation. The obtained results indicated that GFWA composites exhibited excellent thermal insulation and hydrophobic properties, with GFWA-30 containing 30 wt.% glass fiber wool having a thermal conductivity of 35.3 mW/m·K and a water contact angle of 125.8°. Additionally, the Young’s modulus of this composite was 21.2% higher than that of MTMS aerogel. In terms of thermal safety performance, compared to methyltrimethoxysilane aerogel, the GFWA-30 composite showed reductions of 21.6%, 18.8%, and 27.95% in peak heat release rate, total heat release, and gross calorific value, respectively. This study offers a simple and feasible approach to fabricating high-performance thermal insulation materials, which display huge potential for widespread application in the fields of building insulation and other fields with thermal insulation requirements. Full article
(This article belongs to the Special Issue Synthesis and Emerging Applications of Novel Aerogel Materials)
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15 pages, 3663 KB  
Article
Advancing Sustainable Refrigeration: In-Depth Analysis and Application of Air Cycle Technologies
by Lorenz Hammerschmidt, Zlatko Raonic and Michael Tielsch
Thermo 2025, 5(4), 52; https://doi.org/10.3390/thermo5040052 - 12 Nov 2025
Abstract
Air cycle systems, once largely replaced by vapour-compression technologies due to efficiency concerns, are now re-emerging as a viable and sustainable alternative for highly dynamic thermal applications and excel in ultra-low temperature. By using air as the working fluid, these systems eliminate the [...] Read more.
Air cycle systems, once largely replaced by vapour-compression technologies due to efficiency concerns, are now re-emerging as a viable and sustainable alternative for highly dynamic thermal applications and excel in ultra-low temperature. By using air as the working fluid, these systems eliminate the need for synthetic refrigerants and comply naturally with evolving environmental regulations. This study presents the conceptual design and simulation-based analysis of a novel air cycle machine developed for advanced automotive testing environments. The system is intended to replicate a wide range of climatic conditions—from deep winter to peak summer—through the use of fast-responding turbomachinery and a flexible control strategy. A central focus is placed on the radial turbine, which is designed and evaluated using a modular, open source framework that integrates geometry generation, off-design CFD simulation, and performance mapping. The study outlines a potential operating strategy based on these simulations and discusses a control architecture combining lookup tables with zone-specific PID tuning. While the results are theoretical, they demonstrate the feasibility and flexibility of the proposed approach, particularly the turbine’s role within the system. Full article
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25 pages, 6452 KB  
Article
Design Optimization of Direct Combustion Process in Regenerative Thermal Oxidizer at Low Concentration of Coal Mine Gas Using Advanced Computational Models
by Jida Zhang, Dong Wang, Zhongkuan Wei, Sheng Li, Junhui Yang, Shiyang Jia, Zhongcheng Ma, Chengmin Chen and Krishnaswamy Nandakumar
Fluids 2025, 10(11), 293; https://doi.org/10.3390/fluids10110293 - 12 Nov 2025
Abstract
Coal mine gas with methane concentrations below 8% cannot sustain stable self-combustion, posing significant challenges for safe utilization and greenhouse gas mitigation. To address this limitation, we developed a large-scale industrial square rotary regenerative thermal oxidizer (RTO) capable of high-efficiency oxidation under ultra-low [...] Read more.
Coal mine gas with methane concentrations below 8% cannot sustain stable self-combustion, posing significant challenges for safe utilization and greenhouse gas mitigation. To address this limitation, we developed a large-scale industrial square rotary regenerative thermal oxidizer (RTO) capable of high-efficiency oxidation under ultra-low methane conditions. This work integrates multi-scale computational fluid dynamics (CFD) modeling, laboratory and pilot-scale physical experiments, and multi-physics coupled simulations to capture the complex interactions of fluid flow, species transport, and thermal response in regenerative ceramics. Compared with conventional circular or three-bed RTOs, the proposed square rotating design achieves 13% higher heat storage utilization, 15% smaller floor area, and enhanced spatial uniformity of the temperature field. Multi-scale simulations reveal that increasing methane molar fraction (CH4) from 0.012 to 0.017 raises the peak temperature from 1280 K to 1350 K, reduces the burnout height from 1.18 m to 1.15 m, and, under constant oxygen supply, extends the high-temperature zone to 1450 K with a stabilized burnout position at 1.06 ± 0.01 m. Incorporating a 15° conical expansion combustion chamber increases local turbulent kinetic energy by 17.4%, accelerating oxidation while maintaining methane removal rates > 98% within an optimized bottom blowing time of 30–90 s. This study not only provides validated design thresholds for ultra-low concentration methane oxidation—such as temperature windows, buffer zones, and switching cycles—but also offers an engineering framework for scaling RTO systems to industrial coal mine applications. This advances both energy recovery efficiency and methane emission control, demonstrating clear advantages over existing RTO configurations. Full article
(This article belongs to the Special Issue Turbulence and Combustion)
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28 pages, 8862 KB  
Article
Experimental and Numerical Study on Fire Resistance and Residual Strength of Prefabricated Utility Tunnels
by Hongbo Li, Binlin Zhang, Zigen Li and Qi Yuan
Buildings 2025, 15(22), 4062; https://doi.org/10.3390/buildings15224062 - 11 Nov 2025
Abstract
Fire hazard presents a critical challenge to the structural reliability of underground modular infrastructure. This study examines the fire resistance performance of prefabricated monolithic utility tunnels featuring longitudinal threaded connections. A series of fire exposure tests was conducted on assembled utility tunnel specimens [...] Read more.
Fire hazard presents a critical challenge to the structural reliability of underground modular infrastructure. This study examines the fire resistance performance of prefabricated monolithic utility tunnels featuring longitudinal threaded connections. A series of fire exposure tests was conducted on assembled utility tunnel specimens using different bolt materials and thermal conditions, enabling evaluation of fire behavior, deformation behavior, and residual capacity. The observed thermal properties revealed significant temperature gradients across tunnel sections, with the peak internal–external differential reaching 536.8 °C. Post-fire mechanical degradation was evident in reduced stiffness and ductility, and the residual load-bearing capacity declined by up to 12.28% compared to unexposed specimens. Specimens using high-strength threaded bolts demonstrated superior performance compared to stainless steel bolt specimens, exhibiting a 4.67% higher residual capacity and 13.87% less residual deformation. A sequential thermal–mechanical finite element model was developed and calibrated based on experimental results, offering a reliable simulation framework for investigating fire-induced damage and residual strength in modular utility tunnel systems. These findings provide a quantitative basis for fire safety assessment. Full article
(This article belongs to the Special Issue Fire Science and Safety of Building Structure)
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16 pages, 2327 KB  
Article
Influence of Rail Temperature on Braking Efficiency in Railway Vehicles
by Diego Rivera-Reyes, Tania Elizabeth Sandoval-Valencia and Juan Carlos Jáuregui-Correa
Eng 2025, 6(11), 321; https://doi.org/10.3390/eng6110321 - 11 Nov 2025
Viewed by 42
Abstract
Railway braking efficiency hinges on the thermomechanical conditions at the wheel-rail interface. Frictional heating during operation causes significant temperature fluctuations, directly impacting braking performance in rail vehicles. Evaluating these effects is important for developing infrastructure and components adapted to environmental conditions. Several studies [...] Read more.
Railway braking efficiency hinges on the thermomechanical conditions at the wheel-rail interface. Frictional heating during operation causes significant temperature fluctuations, directly impacting braking performance in rail vehicles. Evaluating these effects is important for developing infrastructure and components adapted to environmental conditions. Several studies have explored the influence of temperature on components such as the brake disc or the wheel; little attention has been paid to the thermal conditions of the rail itself. This paper examines the effect of rail temperature on the braking behavior and energy consumption of a railway vehicle. Using a 1:20 railway track, rail segments were subjected to four temperatures (28.5 °C, 40.0 °C, 49.9 °C, 71.0 °C) by heating with Nichrome wire, and tests were performed at three speeds (0.75, 1.00, and 1.30 m/s). The results show that higher rail temperatures improve wheel-rail adhesion up to an optimum point (40.0 °C), beyond which performance deteriorates. In contrast, tests at 71.0 °C showed reduced braking efficiency, despite lower electrical current peaks, indicating a non-linear thermal response. Full article
(This article belongs to the Special Issue Interdisciplinary Insights in Engineering Research)
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27 pages, 3118 KB  
Article
Native Collagen and Total Lipid Extract Obtained from Caranx hyppos By-Products: Characterization for Potential Use in the Biomedical and Nutraceutical Fields
by Sheyza Menéndez-Tasé, Evelin Gaeta-Leal, Darío Iker Téllez-Medina, Daniel Tapia-Maruri, Edgar Oliver López-Villegas, Georgina Calderón-Domínguez, Tzayhri Gallardo-Velázquez, Guillermo Osorio-Revilla, Mayuric Teresa Hernández-Botello and Diana Maylet Hernández-Martínez
Mar. Drugs 2025, 23(11), 432; https://doi.org/10.3390/md23110432 - 9 Nov 2025
Viewed by 235
Abstract
The processing of fishery products generates a substantial amount of by-products, which can be utilized to promote a circular economy. The objective of the present study was to extract and characterize native collagen and total lipid extract from the fish skin and bones [...] Read more.
The processing of fishery products generates a substantial amount of by-products, which can be utilized to promote a circular economy. The objective of the present study was to extract and characterize native collagen and total lipid extract from the fish skin and bones of crevalle jack (Caranx hippos). Physicochemical, structural, and morphological properties were evaluated for collagens. Chemical composition and functional properties were evaluated for lipid extracts. Native type I collagens were obtained by acid extraction, yielding approximately 2.64–6.16% (d.b.). The elemental chemical analysis showed its purity. The stability of the triple helix of collagen was verified through characteristic bands in the FTIR and UV spectra, the peaks at 2θ, around 7.5° and 19.5° obtained by XRD, and the bands of SDS-PAGE. Collagens show isoelectric points of 4.94 (skin) and 4.90 (bone), thermal stabilities of 53.40 °C (skin) and 46.88 °C (bone), and the percentage surface porosities of 41.28 (skin) and 38.84 (bone), all of which demonstrate their potential as a raw material in the biomedical field. The total lipids obtained were extracted using the Soxhlet and Folch methods. The extracts show EPA (1.26–3.16%) and DHA (3.94–9.78%) contents, with inhibition percentages of 32.7% (ABTS), 19.6% (DPPH), and 70.83% (β-carotene). These results highlight the potential of total lipid extract for nutraceutical and food applications. Full article
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12 pages, 2070 KB  
Article
Numerical Study on Optimization of Manifold Microchannel Heat Sink
by Jiajun Zhou, Jinfeng Chen, Qing Wang, Xianli Xie, Penghui Guan and Huai Zheng
Energies 2025, 18(22), 5883; https://doi.org/10.3390/en18225883 - 8 Nov 2025
Viewed by 216
Abstract
Integrated circuits have become indispensable in modern society owing to their formidable computational power and high integration, finding extensive applications in critical fields such as artificial intelligence and new energy vehicles. However, continued increases in integration density and reductions in physical size lead [...] Read more.
Integrated circuits have become indispensable in modern society owing to their formidable computational power and high integration, finding extensive applications in critical fields such as artificial intelligence and new energy vehicles. However, continued increases in integration density and reductions in physical size lead to a significantly higher heat flux density, thereby posing major challenges for thermal management and overall chip reliability. To address these thermal challenges, this study introduces an optimized manifold microchannel design. A three-dimensional conjugate heat transfer model was developed, and computational fluid dynamics simulations were performed to analyze the thermal–hydraulic performance. To mitigate temperature non-uniformity, several strategies were implemented: adjusting channel widths, employing uneven inlet gaps, and incorporating micro-fins. Results demonstrate that the optimized configuration achieves a maximum temperature reduction of 7.7 K, with peak thermal stress decreasing from 55.29 MPa to 47 MPa, effectively improving temperature uniformity. This study confirms that the proposed optimized design significantly enhances overall thermal performance, thereby offering a reliable and effective strategy for advanced chip thermal management. Full article
(This article belongs to the Special Issue The Future of Renewable Energy: 2nd Edition)
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14 pages, 2402 KB  
Article
Characteristics of Nanosecond Bipolar Pulsed Water Electrode Dielectric Barrier Discharge for Ozone Generation
by Weitian Wu, Chenyang Jin, Yifan Wu, Xianyang Zeng, Linsheng Wei, Zhongqian Ling and Lijian Wang
Processes 2025, 13(11), 3619; https://doi.org/10.3390/pr13113619 - 8 Nov 2025
Viewed by 215
Abstract
This study investigates the ozone generation characteristics of a nanosecond bipolar pulse-excited single-water electrode (dielectric barrier discharge) DBD reactor, with a particular focus on the effects of pulse width (Tp) on discharge behavior, plasma parameters, and ozone generation efficiency. The [...] Read more.
This study investigates the ozone generation characteristics of a nanosecond bipolar pulse-excited single-water electrode (dielectric barrier discharge) DBD reactor, with a particular focus on the effects of pulse width (Tp) on discharge behavior, plasma parameters, and ozone generation efficiency. The results indicate that the bipolar pulse voltage displays a symmetric alternating waveform, and the reactor demonstrates excellent thermal stability. Rotation temperature (Trot) remains stable between 307 and 310 K (close to room temperature, which effectively suppresses O3 thermal decomposition), while vibrational temperature (Tvib) stabilizes at 3120 ± 50 K (sufficient to ensure the electron energy required for O2 dissociation). Electron excitation temperature (Texc) increases with both the specific input energy (SIE) and Tp. At SIE = 200 J/L, extending Tp from 200 ns to 1000 ns results in an increase in Texc from 2633 K to 2724 K. The ozone generation efficiency exhibits a “rise-then-decline” trend with increasing Tp. The optimal Tp is 500–600 ns, at which the maximum efficiency reaches 102 g/kWh (corresponding to SIE = 35.95 J/L), which is slightly higher than the peak efficiency of the unipolar pulse-driven water electrode reactor (99.64 ± 0.87 g/kWh, corresponding to SIE = 33.60 ± 1.53 J/L). This work innovatively applies nanosecond bipolar pulse excitation to a single-water electrode DBD reactor for ozone generation, an understudied configuration that integrates the discharge stability advantage of bipolar pulses and the superior cooling advantages of water electrodes. This study offers significant insights into the pulse power excitation of ozone generation. Full article
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19 pages, 13626 KB  
Article
Advanced Thermal Protection Systems Enabled by Additive Manufacturing of Hybrid Thermoplastic Composites
by Teodor Adrian Badea, Alexa-Andreea Crisan and Lucia Raluca Maier
Polymers 2025, 17(22), 2974; https://doi.org/10.3390/polym17222974 - 7 Nov 2025
Viewed by 282
Abstract
This study investigates seven advanced hybrid composite thermal protection system (TPS) prototypes, featuring an innovative internal air chamber design that reduces heat conduction and enhances overall thermal protection performance. Specimens were manufactured by fused deposition modeling (FDM), an additive manufacturing technique, using a [...] Read more.
This study investigates seven advanced hybrid composite thermal protection system (TPS) prototypes, featuring an innovative internal air chamber design that reduces heat conduction and enhances overall thermal protection performance. Specimens were manufactured by fused deposition modeling (FDM), an additive manufacturing technique, using a fire-retardant thermoplastic. Selected configurations were reinforced with continuous carbon or glass fibers, coated with ceramic surface layer, or hybridized with carbon fiber reinforced polymer (CFRP) layers or a CFRP laminate disk. To validate performance, a harsh oxy-acetylene torch (OAT) protocol was implemented, deliberately designed to exceed the severity of most reported typical ablative assessments. The exposed surface of each specimen was subjected to direct flame at a 50 mm distance, recording peak temperatures of 1600 ± 50 °C. Two samples of each configuration were tested under 60 and 90 s exposures. Back-face thermal readings at potential payload sites consistently remained below 85 °C, well under the 200 °C maximum standard threshold for TPS applications. Several configurations preserved structural integrity despite the extreme environment. Prototypes 4.1 and 4.2 demonstrate the most favorable performance, maintaining structural integrity and low back-face temperatures despite substantial thickness loss. By contrast, specimen 6.2 exhibited rapid degradation following 60 s of exposure, which served as a rigorous and selective early-stage screening tool for evaluating polymer-based ablative TPS architectures. Full article
(This article belongs to the Special Issue Polymeric Composites: Manufacturing, Processing and Applications)
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39 pages, 2886 KB  
Review
Sand-Based Thermal Storage System for Human-Powered Energy Generation: A Review
by Qirui Ding, Lili Zeng, Ying Zeng, Changhui Song, Liang Lei and Weicheng Cui
Energies 2025, 18(22), 5869; https://doi.org/10.3390/en18225869 - 7 Nov 2025
Viewed by 290
Abstract
Sand-based thermal energy storage systems represent a paradigm shift in sustainable energy solutions, leveraging Earth’s most abundant mineral resource through advanced nanocomposite engineering. This review examines sand-based phase change materials (PCM) systems with emphasis on integration with human-powered energy generation (HPEG). Silicon-based hierarchical [...] Read more.
Sand-based thermal energy storage systems represent a paradigm shift in sustainable energy solutions, leveraging Earth’s most abundant mineral resource through advanced nanocomposite engineering. This review examines sand-based phase change materials (PCM) systems with emphasis on integration with human-powered energy generation (HPEG). Silicon-based hierarchical pore structures provide multiscale thermal conduction pathways while achieving PCM loading capacities exceeding 90%. Carbon-based nanomaterial doping enhances thermal conductivity by up to 269%, reaching 3.1 W/m·K while maintaining phase change enthalpies above 130 J/g. This demonstrated cycling stability exceeds 1000 thermal cycles with <8% capacity degradation. Thermal energy storage costs reach ~$20 kWh−1—60% lower than lithium-ion systems when normalized by usable heat capacity. Integration with triboelectric nanogenerators achieves 55% peak mechanical-to-electrical conversion efficiency for direct pathways, while thermal-buffered systems provide 8–12% end-to-end efficiency with temporal decoupling between intermittent human power input and stable electrical output. Miniaturized systems target off-grid communities, offering 5–10× cost advantages over conventional batteries for resource-constrained deployments. Levelized storage costs remain competitive despite efficiency penalties versus lithium-ion alternatives. Critical challenges, including thermal cycling degradation, energy-power density trade-offs, and environmental adaptability, are systematically analyzed. Future directions explore biomimetic multi-level pore designs, intelligent responsive systems, and distributed microgrid implementations. Full article
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29 pages, 15539 KB  
Article
Multifunctional Performance of Bacterial Cellulose Membranes in Saline and Oily Emulsion Filtration
by Alexandre D’Lamare Maia de Medeiros, Cláudio José Galdino da Silva Junior, Yasmim de Farias Cavalcanti, Matheus Henrique Castanha Cavalcanti, Maryana Rogéria dos Santos, Ana Helena Mendonça Resende, Ivison Amaro da Silva, Julia Didier Pedrosa de Amorim, Andréa Fernanda de Santana Costa and Leonie Asfora Sarubbo
Fermentation 2025, 11(11), 635; https://doi.org/10.3390/fermentation11110635 - 7 Nov 2025
Viewed by 346
Abstract
The separation of oil-in-water emulsions from industrial wastewater remains a significant challenge, particularly under saline conditions. This study evaluated bacterial cellulose (BC) membranes from Komagataeibacter hansenii for filtering synthetic effluents with high oil content (ES1) and saline oil-in-water emulsions (ES2). FTIR confirmed the [...] Read more.
The separation of oil-in-water emulsions from industrial wastewater remains a significant challenge, particularly under saline conditions. This study evaluated bacterial cellulose (BC) membranes from Komagataeibacter hansenii for filtering synthetic effluents with high oil content (ES1) and saline oil-in-water emulsions (ES2). FTIR confirmed the incorporation of lipophilic compounds into the BC matrix. Crystallinity decreased from 78.8% to 40% following ES1 filtration, while a new peak at 2θ ≈ 31.8° appeared in ES2, indicating salt deposition. TGA revealed increased mass loss in the oil-saturated membrane (BCO), whereas the saline-exposed membrane (BCOS) exhibited higher thermal stability. SEM showed fiber compaction and localized deposition of oil and salt, corroborated by EDS, which identified Na, Cl, Ca, and elevated oxygen levels. Mechanical testing indicated that oil acted as a plasticizer, increasing the elongation at break of BCO, while salt crystallization enhanced BCOS stiffness. The membranes removed up to 98% of organic load (BOD and COD), 69% of oils and greases, and reduced turbidity and apparent color by 92%. Partial salt retention (~23%) and a significant decrease in dissolved oxygen were also observed. These results demonstrate the potential of BC membranes as an effective and sustainable solution for the treatment of complex oily and saline wastewater. Full article
(This article belongs to the Section Industrial Fermentation)
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18 pages, 2486 KB  
Article
Spatiotemporal Variations and Future Trends of Sucralose Contamination in Major Rivers of Zhejiang, China: An Emerging Concern and Sustainability Challenge
by Wen Zhang, Shiyuan Ni, Zike Huang, Zhequan Wang and Zhiwei Liu
Sustainability 2025, 17(22), 9935; https://doi.org/10.3390/su17229935 - 7 Nov 2025
Viewed by 184
Abstract
The environmental persistence of sucralose (SUC), a recalcitrant artificial sweetener, has raised significant ecological concerns owing to its notable resistance to both thermal and biological degradation. This study focused on the eight major river basins in Zhejiang Province and used the LC-MS/MS external [...] Read more.
The environmental persistence of sucralose (SUC), a recalcitrant artificial sweetener, has raised significant ecological concerns owing to its notable resistance to both thermal and biological degradation. This study focused on the eight major river basins in Zhejiang Province and used the LC-MS/MS external standard method to systematically detect the environmental occurrence of SUC. Significant spatial variations were observed. The highest concentration recorded in the river was 6.60 μg/L in the Beijing-Hangzhou Grand Canal. In contrast, the Ou River showed almost no detectable concentration. Higher contamination levels were consistently found in urban-adjacent areas, particularly near Hangzhou metropolitan region. Distinct seasonal patterns were also identified, with peak concentrations occurring during summer months. Through the application of the seasonal Kendall trend analysis, an increasing trend was projected for seven of the eight river systems studied, with the Ou River being the sole exception. Furthermore, the accuracy of the model’s prediction results was verified by comparing the data from the 2024 experimental tests with the model’s predicted results. By comparing the data from the experimental tests in 2024 with the model’s predictions, the results showed that, except for the Beijing-Hangzhou Grand Canal, the relative deviations of the other rivers were all less than 5.00%. This indicates that the model had a high accuracy in predicting the changing trend of concentrations. This study provided fundamental data for understanding sucralose’s environmental behavior in the Yangtze River Delta watersheds, serving as a critical baseline data for ecological risk assessments and contributing to water resource sustainability. And the ecological or toxicological implications of SUC pollution require further study. Furthermore, this study developed a transferable methodological framework for monitoring artificial sweetener contamination across diverse aquatic ecosystems. Full article
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