Cerium-Based Electrocatalysts for Oxygen Evolution/Reduction Reactions: Progress and Perspectives
Abstract
:1. Introduction
2. Ce-Based Materials Derived from MOFs
2.1. Design of Ce-Based MOFs
2.2. Direct Combination of MOFs and Cerium Oxides
2.3. Catalytic Performances of Ce-Based Materials Derived from MOFs
3. Ce-Based Materials with Various Structures
3.1. Low Dimension
3.1.1. 1D Nanomaterials
3.1.2. 2D Nanomaterials
3.2. Multidimension
3.2.1. Core-Shell Structure
3.2.2. Irregular Structure
3.3. Catalytic Performances of Ce-Based Materials with Various Structures
3.3.1. 1D Nanomaterials
3.3.2. 2D Nanomaterials
3.3.3. Core-Shell Structure
3.3.4. Irregular Structure
4. Multimetallic Element-Doped Ce-Based Materials
4.1. Pt/Pd-Doped Ce-Based Materials
4.2. Mn-Doped Ce-Based Materials
4.3. The Catalytic Performances of Multimetallic Element-Doped Ce-Based Materials
5. Summary and Outlook
- Synthesize MOF-based materials. Whether combining with ZIFs or constructing MOF-derived materials, both can provide enhanced electronic conductivity for Ce species and have a good inhibitory effect on the aggregation of Ce species. The introduction of heteroatoms and the formation of more pores augment the number of active sites on the catalyst surface. The introduction of MOFs has triggered many positive changes, which have played a vital role in improving the catalytic capacity of cathodic oxygen reduction/anodic oxygen evolution.
- Construct Ce-based materials with various structures. This report reviews 3D core-shell structures, one-dimensional, two-dimensional structures and special heterostructures. Different structures have unique physical and chemical properties: a 3D hierarchical structure can promote the transfer of electrons, O2 and electrolyte in the 3D direction, which ensures more sufficient contact between the reactants. 1D and 2D materials are currently studied in the ORR/OER field. The most unique feature is the good corrosion resistance and ability to stably maintain the morphology. The heterogeneous structures show unique characteristics in terms of their morphology, which is more of a physically improved surface area, porosity, etc., and the synergy between different substances is to promote the catalytic performance of the catalyst chemically.
- Dope with various metal elements. This article mainly summarizes Pt-, Pd- and Mn-Ce-based materials. In addition to Pt, Pd, and Mn, other metal elements with excellent properties can also be applied to Ce-based catalysts. On the one hand, the use of low-cost metals instead of precious metals can reduce the process costs; on the other hand, it can increase the active sites and form a synergy with Ce species to improve the overall catalytic activity. The introduction of one or more metal elements is also a very clever synthesis strategy.
- Load the Ce species on the conductive carrier. This is the most direct method of enhancing electronic conductivity, and it also has a beneficial effect on weakening the aggregation of Ce species. Common conductive carriers are mainly carbon substrates, such as rGO, g-C3N4, CNT and KB. A single carbon carrier cannot meet the current research demands, and composite carriers as newborn conductive carriers are more and more considered by researchers.
- Convert to CeCx/CeFx. Being analogous to the precious metal Pt, metal carbides also exhibit excellent catalytic performance, and they have low cost, high conductivity, strong chemical stability and strong methanol resistance, and they can be commonly used in ORR/OER electrochemistry [108,109,110]. As the most studied cerium compound, CeF3 also has rich Ce3+ and Ce4+ redox pairs, high electronic conductivity and structural stability, and exhibits satisfactory catalytic performance [94,111]. Therefore, the carbides and fluoride of Ce can replace precious metal-based materials, which are a novel type of promising ORR/OER electrocatalyst. In terms of Ce-based materials applied in ORR/OER catalysis, there is less research on CeCx/CeFx than CeO2, which may be due to the limited synthesis methods for carbides and fluoride. CeCx/CeFx also exhibits potent redox capacity, structural stability and oxygen adsorption capacity. Therefore, exploring new ways to develop CeCx/CeFx catalysts for the ORR/OER is a critical strategy.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Agarwal, S.; Yu, X.; Manthiram, A. A pair of metal organic framework (MOF)-derived oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts for zinc-air batteries. Mater. Today Energy 2020, 16, 100405. [Google Scholar]
- D’Odorico, P.; Davis, K.F.; Rosa, L.; Carr, J.A.; Chiarelli, D.; Dell’Angelo, J.; Gephart, J.; MacDonald, G.K.; Seekell, D.A.; Suweis, S.; et al. The Global Food-Energy-Water Nexus. Rev. Geophys. 2018, 56, 456–531. [Google Scholar]
- Luo, X.; Ren, H.; Ma, H.; Yin, C.; Wang, Y.; Li, X.; Shen, Z.; Wang, Y.; Cui, L. In situ integration of Co5.47N and Co0.72Fe0.28 alloy nanoparticles into intertwined carbon network for efficient oxygen reduction. J. Colloid Interface Sci. 2020, 569, 267–276. [Google Scholar] [PubMed]
- Aurbach, D.; McCloskey, B.D.; Nazar, L.F.; Bruce, P.G. Advances in understanding mechanisms underpinning lithium–air batteries. Nat. Energy 2016, 1, 16128. [Google Scholar]
- Chai, L.; Zhang, L.; Wang, X.; Xu, L.; Han, C.; Li, T.-T.; Hu, Y.; Qian, J.; Huang, S. Bottom-up synthesis of MOF-derived hollow N-doped carbon materials for enhanced ORR performance. Carbon 2019, 146, 248–256. [Google Scholar]
- Wagner, F.; Lakshmanan, B.; Mathias, M. Electrons to Go: Electrochemistry and the Future of the Automobile. J. Phys. Chem. Lett. 2010, 1, 2204–2219. [Google Scholar]
- Gasteiger, H.A.; Kocha, S.S.; Sompalli, B.; Wagner, F.T. Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl. Catal. B Environ. 2005, 56, 9–35. [Google Scholar]
- Hu, X.; Min, Y.; Ma, L.-L.; Lu, J.-Y.; Li, H.-C.; Liu, W.-J.; Chen, J.-J.; Yu, H.-Q. Iron-nitrogen doped carbon with exclusive presence of FexN active sites as an efficient ORR electrocatalyst for Zn-air battery. Appl. Catal. B Environ. 2020, 268, 118405. [Google Scholar]
- Park, H.; Oh, S.; Lee, S.; Choi, S.; Oh, M. Cobalt- and nitrogen-codoped porous carbon catalyst made from core–shell type hybrid metal–organic framework (ZIF-L@ZIF-67) and its efficient oxygen reduction reaction (ORR) activity. Appl. Catal. B Environ. 2019, 246, 322–329. [Google Scholar]
- Jai, P. Kinetic Investigations of Oxygen Reduction and Evolution Reactions on Lead Ruthenate Catalysts. J. Electrochem. Soc. 1999, 146, 4145. [Google Scholar]
- Li, Y.; Mo, C.; Li, J.; Yu, D. Pyrazine–nitrogen–rich exfoliated C4N nanosheets as efficient metal–free polymeric catalysts for oxygen reduction reaction. J. Energy Chem. 2020, 49, 243–247. [Google Scholar]
- Faria, L.A.D.; Boodts, J.F.C.; Trasatti, S. Electrocatalytic properties of ternary oxide mixtures of composition Ru0.3Ti(0.7−x) CexO2: Oxygen evolution from acidic solution. J. Appl. Electrochem. 1996, 26, 1195–1199. [Google Scholar] [CrossRef]
- Weber, M.F.; Shanks, H.R. Electrocatalytic Activity and Surface Properties of Tungsten Bronzes; Iowa State University: Ames, IO, USA, 1977. [Google Scholar]
- Trasatti, S. Physical Electrochemistry of Ceramic Oxides. Electrochim. Acta 1991, 36, 225–241. [Google Scholar]
- Qin, X.; Huang, Y.; Wang, K.; Xu, T.; Wang, Y.; Liu, P.; Kang, Y.; Zhang, Y. Novel hierarchically porous Ti-MOFs/nitrogen-doped graphene nanocomposite served as high efficient oxygen reduction reaction catalyst for fuel cells application. Electrochim. Acta 2019, 297, 805–813. [Google Scholar]
- Qiao, M.; Wang, Y.; Wågberg, T.; Mamat, X.; Hu, X.; Zou, G.; Hu, G. Ni–Co bimetallic coordination effect for long lifetime rechargeable Zn–air battery. J. Energy Chem. 2020, 47, 146–154. [Google Scholar]
- Wang, Y.; Hao, J.; Yu, J.; Yu, H.; Wang, K.; Yang, X.; Li, J.; Li, W. Hierarchically porous N-doped carbon derived from biomass as oxygen reduction electrocatalyst for high-performance Al–air battery. J. Energy Chem. 2020, 45, 119–125. [Google Scholar]
- Song, D.; Wang, L.; Yao, M.; Sun, W.; Vajtai, R.; Ajayan, P.M.; Wang, Y. Rational Design of Ni-Based Electrocatalysts by Modulation of Iron Ions and Carbon Nanotubes for Enhanced Oxygen Evolution Reaction. Adv. Sustain. Syst. 2020, 4, 2000227. [Google Scholar]
- Yan, W.; Cao, X.; Wang, R.; Sha, Y.; Cui, P.; Cui, S. S, N co-doped rod-like porous carbon derived from S, N organic ligand assembled Ni-MOF as an efficient electrocatalyst for oxygen reduction reaction. J. Solid State Chem. 2019, 275, 167–173. [Google Scholar]
- Wang, Y.; Pan, Y.; Zhu, L.; Yu, H.; Duan, B.; Wang, R.; Zhang, Z.; Qiu, S. Solvent-free assembly of Co/Fe-containing MOFs derived N-doped mesoporous carbon nanosheets for ORR and HER. Carbon 2019, 146, 671–679. [Google Scholar]
- Xia, Z.; Zhu, Y.; Zhang, W.; Hu, T.; Chen, T.; Zhang, J.; Liu, Y.; Ma, H.; Fang, H.; Li, L. Cobalt ion intercalated MnO2/C as air cathode catalyst for rechargeable aluminum–air battery. J. Alloy. Compd. 2020, 824, 153950. [Google Scholar]
- Chen, D.; Zhu, J.; Mu, X.; Cheng, R.; Li, W.; Liu, S.; Pu, Z.; Lin, C.; Mu, S. Nitrogen-Doped carbon coupled FeNi3 intermetallic compound as advanced bifunctional electrocatalyst for OER, ORR and zn-air batteries. Appl. Catal. B Environ. 2020, 268, 118729. [Google Scholar]
- Kang, M.; Bae, Y.-S.; Lee, C.-H. Effect of heat treatment of activated carbon supports on the loading and activity of Pt catalyst. Carbon 2005, 43, 1512–1516. [Google Scholar] [CrossRef]
- Coloma, F.; Sepulveda, A.; Rodriguez, R.F. Heat-treated carbon -blacks as supports for platinum catalysts. J. Catal. 1995, 154, 299–305. [Google Scholar] [CrossRef]
- Hall, S.C.; Subramanian, V.; Teeter, G.; Rambabu, B. Influence of metal–support interaction in Pt/C on CO and methanol oxidation reactions. Solid State Ionics 2004, 175, 809–813. [Google Scholar] [CrossRef]
- Xu, X.; Pan, Y.; Ge, L.; Chen, Y.; Mao, X.; Guan, D.; Li, M.; Zhong, Y.; Hu, Z.; Peterson, V.; et al. High-Performance Perovskite Composite Electrocatalysts Enabled by Controllable Interface Engineering. Small 2021, 17, 2101573. [Google Scholar]
- Tang, J.; Xu, X.; Tang, T.; Zhong, Y.; Shao, Z. Perovskite-Based Electrocatalysts for Cost-Effective Ultrahigh-Current-Density Water Splitting in Anion Exchange Membrane Electrolyzer Cell. Small Methods 2022, 6, 2201099. [Google Scholar]
- Wu, G.; Zelenay, P. Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction. Acc. Chem. Res. 2013, 46, 1878–1889. [Google Scholar]
- Sun, T.; Wu, Q.; Che, R.; Bu, Y.; Jiang, Y.; Li, Y.; Yang, L.; Wang, X.; Hu, Z. Alloyed Co–Mo Nitride as High-Performance Electrocatalyst for Oxygen Reduction in Acidic Medium. ACS Catal. 2015, 5, 1857–1862. [Google Scholar]
- Poudel, M.; Kim, H. Confinement of Zn-Mg-Al-layered double hydroxide and α-Fe2O3 nanorods on hollow porous carbon nanofibers: A free-standing electrode for solid-state symmetric supercapacitors. Chem. Eng. J. 2022, 429, 132345. [Google Scholar]
- Poudel, M.; Logeshwaran, N.; Kim, A.; Karthikeyan, S.C.; Vijayapradeep, S.; Yoo, D. Integrated core-shell assembly of Ni3S2 nanowires and CoMoP nanosheets as highly efficient bifunctional electrocatalysts for overall water splitting. J. Alloy. Compd. 2023, 960, 170678. [Google Scholar]
- Lohani, P.; Tiwari, A.; Muthurasu, A.; Pathak, I.; Poudel, M.; Chhetri, K.; Dahal, B.; Acharya, D.; Ko, T.; Kim, H. Phytic acid empowered two nanos “Polypyrrole tunnels and transition Metal-(Oxy)hydroxide Sheets” in a single platform for unmitigated redox water splitting. Chem. Eng. J. 2023, 463, 142280. [Google Scholar]
- Park, S. Direct Oxidation of Hydrocarbons in a Solid Oxide Fuel Cell: I. Methane Oxidation. J. Electrochem. Soc. 1999, 146, 3603. [Google Scholar]
- Yu, X.; Kuai, L.; Geng, B. CeO2/rGO/Pt sandwich nanostructure: RGO-enhanced electron transmission between metal oxide and metal nanoparticles for anodic methanol oxidation of direct methanol fuel cells. Nanoscale 2012, 4, 5738–5743. [Google Scholar]
- Safiye, J.; Farnoush, F.; Parviz, N.; Amin Shiralizadeh, D.; Davood, A.; Fatemeh, M.; Mohammad, R. Detection of Aeromonas hydrophila DNA oligonucleotide Sequence using a Biosensor Design based on Ceria Nanoparticles Decorated Reduced Graphene Oxide and Fast Fourier Transform Square Wave Voltammetry. Anal. Chim. Acta 2015, 895, 80–88. [Google Scholar]
- Saravanan, T.; Shanmugam, M.; Anandan, P.; Azhagurajan, M.; Pazhanivel, K.; Arivanandhan, M.; Hayakawa, Y.; Jayavel, R. Facile synthesis of graphene-CeO2 nanocomposites with enhanced electrochemical properties for supercapacitors. Dalton Trans. Int. J. Inorg. Chem. 2015, 44, 9901–9908. [Google Scholar]
- Yang, Y.; Tian, C.; Sun, L.; Lü, R.; Zhou, W.; Shi, K.; Kan, K.; Wang, J.; Fu, H. Growth of small sized CeO2 particles in the interlayers of expanded graphite for high-performance room temperature NOx gas sensors. J. Mater. Chem. A 2013, 1, 12742–12749. [Google Scholar]
- Phokha, S.; Hunpratub, S.; Usher, B.; Pimsawat, A.; Chanlek, N.; Maensiri, S. Effects of CeO2 nanoparticles on electrochemical properties of carbon/CeO2 composites. Appl. Surf. Sci. 2018, 446, 36–46. [Google Scholar]
- Sun, C.; Li, H.; Chen, L. Nanostructured ceria-based materials: Synthesis, properties, and applications. Energy Environ. Sci. 2012, 5, 8475–8505. [Google Scholar]
- Montini, T.; Melchionna, M.; Monai, M.; Fornasiero, P. Fundamentals and Catalytic Applications of CeO2-Based Materials. Chem. Rev. 2016, 116, 5987–6041. [Google Scholar]
- Ji, P.; Wang, L.; Chen, F.; Zhang, J. Ce3+-Centric Organic Pollutant Elimination by CeO2 in the Presence of H2O2. ChemCatChem 2010, 2, 1552–1554. [Google Scholar]
- Mullins, D.R.; Overbury, S.H.; Huntley, D.R. Electron spectroscopy of single crystal and polycrystalline cerium oxide surfaces. Surf. Sci. 1998, 409, 307–319. [Google Scholar]
- Mai, H.-X.; Sun, L.-D.; Zhang, Y.-W.; Si, R.; Feng, W.; Zhang, H.-P.; Liu, H.-C.; Yan, C.-H. Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods, and Nanocubes. J. Phys. Chem. B 2005, 109, 24380–24385. [Google Scholar] [PubMed]
- Liu, X.; Zhou, K.; Wang, L.; Wang, B.; Li, Y. Oxygen Vacancy Clusters Promoting Reducibility and Activity of Ceria Nanorods. J. Am. Chem. Soc. 2009, 131, 3140–3141. [Google Scholar] [CrossRef] [PubMed]
- Khalil, K.M.S.; Elkabee, L.A.; Murphy, B. Preparation and characterization of thermally stable porous ceria aggregates formed via a sol–gel process of ultrasonically dispersed cerium (IV) isopropoxide. Microporous Mesoporous Mater. 2005, 78, 83–89. [Google Scholar]
- Liu, Y.; Li, Y.; He, X. In situ synthesis of ceria nanoparticles in the ordered mesoporous carbon as a novel electrochemical sensor for the determination of hydrazine. Anal. Chim. Acta 2014, 819, 26–33. [Google Scholar]
- Yang, N.; Belianinov, A.; Strelcov, E.; Tebano, A.; Foglietti, V.; Castro, D.D.; Schlueter, C.; Lee, T.L.; Baddorf, A.P.; Balke, N. Effect of Doping on Surface Reactivity and Conduction Mechanism in Samarium-Doped Ceria Thin Films. ACS Nano 2014, 8, 12494–12501. [Google Scholar]
- Zhou, J.; Dou, Y.; Zhou, A.; Guo, R.-M.; Zhao, M.-J.; Li, J.-R. MOF Template-Directed Fabrication of Hierarchically Structured Electrocatalysts for Efficient Oxygen Evolution Reaction. Adv. Energy Mater. 2017, 7, 1602643. [Google Scholar]
- Pan, Y.; Sun, K.; Liu, S.; Cao, X.; Wu, K.; Cheong, W.-C.; Chen, Z.; Wang, Y.; Li, Y.; Liu, Y.; et al. Core–Shell ZIF-8@ZIF-67-Derived CoP Nanoparticle-Embedded N-Doped Carbon Nanotube Hollow Polyhedron for Efficient Overall Water Splitting. J. Am. Chem. Soc. 2018, 140, 2610–2618. [Google Scholar]
- Xu, X.; Sun, H.; Jiang, S.; Shao, Z. Modulating metal–organic frameworks for catalyzing acidic oxygen evolution for proton exchange membrane water electrolysis. SusMat 2021, 1, 460–481. [Google Scholar]
- Wang, H.; Chen, L.; Pang, H.; Kaskel, S.; Xu, Q. MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions. Chem. Soc. Rev. 2020, 49, 1414. [Google Scholar]
- Peng, L.; Wang, J.; Nie, Y.; Xiong, K.; Wang, Y.; Zhang, L.; Chen, K.; Ding, W.; Li, L.; Wei, Z. Dual-Ligand Synergistic Modulation: A Satisfactory Strategy for Simultaneously Improving the Activity and Stability of Oxygen Evolution Electrocatalyst. ACS Catal. 2017, 7, 8184–8191. [Google Scholar]
- Wang, Y.; Li, J.; Wei, Z. Transition-metal-oxide-based catalysts for the oxygen reduction reaction. J. Mater. Chem. A 2018, 6, 8194–8209. [Google Scholar]
- Ahmad Shah, S.S.; Najam, T.; Cheng, C.; Chen, S.; Xiang, R.; Peng, L.; Lu, L.; Ding, W.; Wei, Z. Design and synthesis of conductive carbon polyhedrons enriched with Mn-Oxide active-centres for oxygen reduction reaction. Electrochim. Acta 2018, 272, 169–175. [Google Scholar]
- Wang, W.; Kang, Y.; Li, J.; Wang, P.; Liu, X.; Lei, Z. Developing an advanced electrocatalyst derived from Ce(TTA)3Phen embedded polyaniline for oxygen reduction reaction. Appl. Surf. Sci. 2019, 465, 979–985. [Google Scholar]
- Kim, K.; Kim, Y.; Kim, J. Enhanced cathodic catalytic activity of an N-doped micropore structure obtained through the six-coordinate bond of an EDTA-Ce composite for the oxygen reduction reaction. Appl. Surf. Sci. 2020, 505, 144418. [Google Scholar]
- Luo, Y.; Calvillo, L.; Daiguebonne, C.; Daletou, M.K.; Granozzi, G.; Alonso-Vante, N. A highly efficient and stable oxygen reduction reaction on Pt/CeOx/C electrocatalyst obtained via a sacrificial precursor based on a metal-organic framework. Appl. Catal. B Environ. 2016, 189, 39–50. [Google Scholar]
- Sun, Z.; Cao, X.; Gonzalez Martinez, I.G.; Rümmeli, M.H.; Yang, R. Enhanced electrocatalytic activity of FeCo2O4 interfacing with CeO2 for oxygen reduction and evolution reactions. Electrochem. Commun. 2018, 93, 35–38. [Google Scholar]
- Xia, W.; Li, J.; Wang, T.; Song, L.; Guo, H.; Gong, H.; Jiang, C.; Gao, B.; He, J. The synergistic effect of Ceria and Co in N-doped leaf-like carbon nanosheets derived from a 2D MOF and their enhanced performance in the oxygen reduction reaction. Chem. Commun. 2018, 54, 1623–1626. [Google Scholar]
- Xu, H.; Cao, J.; Shan, C.; Wang, B.; Xi, P.; Liu, W.; Tang, Y. MOF-Derived Hollow CoS Decorated with CeOx Nanoparticles for Boosting Oxygen Evolution Reaction Electrocatalysis. Angew. Chem. 2018, 57, 8654–8658. [Google Scholar] [CrossRef]
- Yu, Y.; Gao, L.; Liu, X.; Wang, Y.; Xing, S. Enhancing the Catalytic Activity of Zeolitic Imidazolate Framework-8-Derived N-Doped Carbon with Incorporated CeO2 Nanoparticles in the Oxygen Reduction Reaction. Chem. A Eur. J. 2017, 23, 10690–10697. [Google Scholar]
- Yu, Y.; Peng, X.; Ali, U.; Liu, X.; Xing, Y.; Xing, S. Facile route to achieve bifunctional electrocatalysts for oxygen reduction and evolution reactions derived from CeO2 encapsulated by the zeolitic imidazolate framework-67. Inorg. Chem. Front. 2019, 6, 3255–3263. [Google Scholar]
- Gao, L.; Chang, S.; Zhang, Z. High-Quality CoFeP Nanocrystal/N, P Dual-Doped Carbon Composite as a Novel Bifunctional Electrocatalyst for Rechargeable Zn−Air Battery. ACS Appl. Mater. Interfaces 2021, 13, 22282–22291. [Google Scholar] [PubMed]
- Wang, R.; Dong, X.; Du, J.; Zhao, J.; Zang, S. MOF-Derived Bifunctional Cu3P Nanoparticles Coated by a N,P-Codoped Carbon Shell for Hydrogen Evolution and Oxygen Reduction. Adv. Mater. 2018, 30, 1703711. [Google Scholar]
- Zeng, Z.; Xu, R.; Zhao, H.; Zhang, H.; Liu, L.; Xu, S.; Lei, Y. Exploration of nanowire- and nanotube-based electrocatalysts for oxygen reduction and oxygen evolution reaction. Mater. Today Nano 2018, 3, 54–68. [Google Scholar]
- Rawtani, D.; Sajan, T.; Twinkle, R.A.; Agrawal, Y.K. Emerging strategies for synthesis and manipulation of nanowires: A review. Rev. Adv. Mater. Sci. 2015, 40, 177–187. [Google Scholar]
- Xu, C.W.; Wang, H.; Shen, P.K.; Jiang, S.P. Highly Ordered Pd Nanowire Arrays as Effective Electrocatalysts for Ethanol Oxidation in Direct Alcohol Fuel Cells. Adv. Mater. 2007, 19, 4256–4259. [Google Scholar]
- Vilas Bôas, N.; Souza Junior, J.B.; Varanda, L.C.; Machado, S.A.S.; Calegaro, M.L. Bismuth and cerium doped cryptomelane-type manganese dioxide nanorods as bifunctional catalysts for rechargeable alkaline metal-air batteries. Appl. Catal. B Environ. 2019, 258, 118014. [Google Scholar]
- Zhang, Z.; Gao, D.; Xue, D.; Liu, Y.; Liu, P.; Zhang, J.; Qian, J. Co and CeO2 co-decorated N-doping carbon nanofibers for rechargeable Zn–air batteries. Nanotechnology 2019, 30, 395401. [Google Scholar]
- Sivanantham, A.; Ganesan, P.; Shanmugam, S. A synergistic effect of Co and CeO2 in nitrogen-doped carbon nanostructure for the enhanced oxygen electrode activity and stability. Appl. Catal. B Environ. 2018, 237, 1148–1159. [Google Scholar]
- Li, Y.; Zhang, X.; Wang, S.; Sun, G. Durable Platinum-Based Electrocatalyst Supported by Multiwall Carbon Nanotubes Modified with CeO2. ChemElectroChem 2018, 5, 2442–2448. [Google Scholar]
- Yu, Y.; He, B.; Liao, Y.; Yu, X.; Mu, Z.; Xing, Y.; Xing, S. Preparation of Hollow CeO2/CePO4 with Nitrogen and Phosphorus Co-Doped Carbon Shells for Enhanced Oxygen Reduction Reaction Catalytic Activity. ChemElectroChem 2018, 5, 793–798. [Google Scholar]
- Wang, W.; Dong, Y.; Yang, Y.; Chai, D.; Kang, Y.; Lei, Z. CeO2 overlapped with nitrogen-doped carbon layer anchoring Pt nanoparticles as an efficient electrocatalyst towards oxygen reduction reaction. Int. J. Hydrog. Energy 2018, 43, 12119–12128. [Google Scholar]
- Wang, W.; Xue, S.; Li, J.; Wang, F.; Kang, Y.; Lei, Z. Cerium carbide embedded in nitrogen-doped carbon as a highly active electrocatalyst for oxygen reduction reaction. J. Power Sources 2017, 359, 487–493. [Google Scholar]
- Xue, Y.; Huang, H.; Miao, H.; Sun, S.; Wang, Q.; Li, S.; Liu, Z. One-pot synthesis of La0.7Sr0.3MnO3 supported on flower-like CeO2 as electrocatalyst for oxygen reduction reaction in aluminum-air batteries. J. Power Sources 2017, 358, 50–60. [Google Scholar]
- Jing, W.; Wang, W.; Yang, Y.; Wang, Y.; Niu, X.; Lei, Z. Nitrogen-doped carbon layer coated CeNiOx as electrocatalyst for oxygen reduction reaction. J. Alloy. Compd. 2018, 761, 8–14. [Google Scholar]
- Soren, S.; Hota, I.; Debnath, A.K.; Aswal, D.K.; Varadwaj, K.S.K.; Parhi, P. Oxygen Reduction Reaction Activity of Microwave Mediated Solvothermal Synthesized CeO2/g-C3N4 Nanocomposite. Front. Chem. 2019, 7, 403. [Google Scholar]
- Sun, L.; Zhou, L.; Yang, C.; Yuan, Y. CeO2 nanoparticle-decorated reduced graphene oxide as an efficient bifunctional electrocatalyst for oxygen reduction and evolution reactions. Int. J. Hydrog. Energy 2017, 42, 15140–15148. [Google Scholar]
- Peng, W.; Zhao, L.; Zhang, C.; Yan, Y.; Xian, Y. Controlled growth cerium oxide nanoparticles on reduced graphene oxide for oxygen catalytic reduction. Electrochim. Acta 2016, 191, 669–676. [Google Scholar]
- Yu, Y.; Wang, X.; Gao, W.; Li, P.; Yan, W.; Wu, S.; Cui, Q.; Song, W.; Ding, K. Trivalent cerium-preponderant CeO2/graphene sandwich-structured nanocomposite with greatly enhanced catalytic activity for the oxygen reduction reaction. J. Mater. Chem. A 2017, 5, 6656–6663. [Google Scholar]
- Wei, H.; Su, X.; Liu, J.; Tian, J.; Wang, Z.; Sun, K.; Rui, Z.; Yang, W.; Zou, Z. A CeO2 modified phenylenediamine-based Fe/N/C with enhanced durability/stability as non-precious metal catalyst for oxygen reduction reaction. Electrochem. Commun. 2018, 88, 19–23. [Google Scholar]
- Dahal, B.; Chae, S.-H.; Muthurasu, A.; Mukhiya, T.; Gautam, J.; Chhetri, K.; Subedi, S.; Ojha, G.P.; Tiwari, A.P.; Lee, J.H.; et al. An innovative synthetic approach for core-shell multiscale hierarchically porous boron and nitrogen codoped carbon nanofibers for the oxygen reduction reaction. J. Power Sources 2020, 453, 227883. [Google Scholar]
- Sánchez-Padilla, N.M.; Morales-Acosta, D.; Morales-Acosta, M.D.; Montemayor, S.M.; Rodríguez-Varela, F.J. Catalytic activity and selectivity for the ORR of rapidly synthesized M@Pt (M = Pd, Fe3O4, Ru) core–shell nanostructures. Int. J. Hydrog. Energy 2014, 39, 16706–16714. [Google Scholar] [CrossRef]
- Lv, L.; Zha, D.; Ruan, Y.; Li, Z.; Ao, X.; Zheng, J.; Jiang, J.; Chen, H.M.; Chiang, W.H.; Chen, J.; et al. A Universal Method to Engineer Metal Oxide-Metal-Carbon Interface for Highly Efficient Oxygen Reduction. ACS Nano 2018, 12, 3042–3051. [Google Scholar] [PubMed]
- Yang, J.; Wang, J.; Zhu, L.; Gao, Q.; Zeng, W.; Wang, J.; Li, Y. Enhanced electrocatalytic activity of a hierarchical CeO2@MnO2 core-shell composite for oxygen reduction reaction. Ceram. Int. 2018, 44, 23073–23079. [Google Scholar]
- Gao, W.; Gou, W.; Ma, Y.; Wei, R.; Ho, J.C.; Qu, Y. Cerium Phosphate as a Novel Cocatalyst Promoting NiCo2O4 Nanowire Arrays for Efficient and Robust Electrocatalytic Oxygen Evolution. ACS Appl. Energy Mater. 2019, 2, 5769–5776. [Google Scholar]
- Li, X.; Liu, Z.; Song, L.; Wang, D.; Zhang, Z. Three-dimensional graphene network supported ultrathin CeO2 nanoflakes for oxygen reduction reaction and rechargeable metal-air batteries. Electrochim. Acta 2018, 263, 561–569. [Google Scholar]
- Cheng, F.; Zhang, T.; Zhang, Y.; Du, J.; Han, X.; Chen, J. Enhancing Electrocatalytic Oxygen Reduction on MnO2 with Vacancies. Angew. Chem. Int. Ed. 2013, 52, 2474–2477. [Google Scholar]
- Zheng, X.; Yu, L.; Lan, B.; Cheng, G.; Lin, T.; He, B.; Ye, W.; Sun, M.; Ye, F. Three-dimensional radial α-MnO2 synthesized from different redox potential for bifunctional oxygen electrocatalytic activities. J. Power Sources 2017, 362, 332–341. [Google Scholar]
- Yang, J.; Wang, J.; Zhu, L.; Zeng, W.; Wang, J. Multiple hollow CeO2 spheres decorated MnO2 microflower as an efficient catalyst for oxygen reduction reaction. Mater. Lett. 2019, 234, 331–334. [Google Scholar] [CrossRef]
- Sun, S.; Xue, Y.; Wang, Q.; Huang, H.; Miao, H.; Liu, Z. Cerium ion intercalated MnO2 nanospheres with high catalytic activity toward oxygen reduction reaction for aluminum-air batteries. Electrochim. Acta 2018, 263, 544–554. [Google Scholar]
- Hota, I.; Soren, S.; Mohapatra, B.D.; Debnath, A.K.; Muthe, K.P.; Varadwaj, K.S.K.; Parhi, P. Mn-doped ceria/reduced graphene oxide nanocomposite as an efficient oxygen reduction reaction catalyst. J. Electroanal. Chem. 2019, 851, 113480. [Google Scholar]
- Chen, J.; Zhou, N.; Wang, H.; Peng, Z.; Li, H.; Tang, Y.; Liu, K. Synergistically enhanced oxygen reduction activity of MnO(x)-CeO2/Ketjenblack composites. Chem. Commun. 2015, 51, 10123–10126. [Google Scholar]
- Bo, G.; Li, P.; Fan, Y.; Zhu, Q.; Xia, L.; Du, Y.; Dou, S.; Xu, X. Liquid-Metal-Mediated Electrocatalyst Support Engineering toward Enhanced Water Oxidation Reaction. Nanomaterials 2022, 12, 2153. [Google Scholar]
- Wang, Y.; Hao, S.; Liu, X.; Wang, Q.; Su, Z.; Lei, L.; Zhang, X. Ce-Doped IrO2 Electrocatalysts with Enhanced Performance for Water Oxidation in Acidic Media. ACS Appl. Mater. Interfaces 2020, 12, 37006–37012. [Google Scholar]
- Castegnaro, M.V.; Paschoalino, W.J.; Fernandes, M.R.; Balke, B.M.; Alves, M.C.; Ticianelli, E.A.; Morais, J. Pd–M/C (M = Pd, Cu, Pt) Electrocatalysts for Oxygen Reduction Reaction in Alkaline Medium: Correlating the Electronic Structure with Activity. Langmuir 2017, 33, 2734–2743. [Google Scholar] [CrossRef]
- Shen, P.K.; Xu, C. Alcohol oxidation on nanocrystalline oxide Pd/C promoted electrocatalysts. Electrochem. Commun. 2006, 8, 184–188. [Google Scholar]
- Meléndez-González, P.C.; Carrillo-Rodríguez, J.C.; Morales-Acosta, D.; Mukherjee, S.; Rodríguez-Varela, F.J. Significant promotion effect of Fe3O4 on the mass catalytic activity of Pd nanocatalyst for the formic acid oxidation reaction. Int. J. Hydrog. Energy 2017, 42, 30284–30290. [Google Scholar] [CrossRef]
- Amin, R.S.; Fetohi, A.E.; Hameed, R.M.A.; El-Khatib, K.M. Electrocatalytic activity of Pt-ZrO2 supported on different carbon materials for methanol oxidation in H2SO4 solution. Int. J. Hydrog. Energy 2016, 41, 1846–1858. [Google Scholar]
- Tan, Y.; Xu, C.; Chen, G.; Fang, X.; Zheng, N.; Xie, Q. Facile Synthesis of Manganese-Oxide-Containing Mesoporous Nitrogen-Doped Carbon for Efficient Oxygen Reduction. Adv. Funct. Mater. 2012, 22, 4584–4591. [Google Scholar]
- Kannan, R.; Jang, H.-R.; Yoo, E.-S.; Lee, H.-K.; Yoo, D.J. Facile green synthesis of palladium quantum dots@carbon on mixed valence cerium oxide/graphene hybrid nanostructured bifunctional catalyst for electrocatalysis of alcohol and water. RSC Adv. 2015, 5, 35993–36000. [Google Scholar]
- Carrillo-Rodríguez, J.C.; García-Mayagoitia, S.; Pérez-Hernández, R.; Ochoa-Lara, M.T.; Espinosa-Magaña, F.; Fernández-Luqueño, F.; Bartolo-Pérez, P.; Alonso-Lemus, I.L.; Rodríguez-Varela, F.J.; Carrillo-Rodríguez, J.C.; et al. Evaluation of the novel Pd CeO2-NR electrocatalyst supported on N-doped graphene for the Oxygen Reduction Reaction and its use in a Microbial Fuel Cell. J. Power Sources 2019, 414, 103–114. [Google Scholar]
- Xu, F.; Wang, D.; Sa, B.; Yu, Y.; Mu, S. One-pot synthesis of Pt/CeO2/C catalyst for improving the ORR activity and durability of PEMFC. Int. J. Hydrog. Energy 2017, 42, 13011–13019. [Google Scholar]
- Lee, K.H.; Kwon, K.; Roev, V.; Yoo, D.Y.; Chang, H.; Seung, D. Synthesis and characterization of nanostructured PtCo-CeOx/C for oxygen reduction reaction. J. Power Sources 2008, 185, 871–875. [Google Scholar]
- Cheng, F.; Su, Y.; Liang, J.; Tao, Z.; Chen, J. MnO2 Based Nanostructures as Catalysts for Electrochemical Oxygen Reduction in Alkaline Media. Chem. Mater. 2010, 22, 898–905. [Google Scholar]
- Zhu, H.; Sun, Z.; Chen, M.; Cao, H.; Li, K.; Cai, Y.; Wang, F. Highly porous composite based on tungsten carbide and N-doped carbon aerogels for electrocatalyzing oxygen reduction reaction in acidic and alkaline media. Electrochim. Acta 2017, 236, 154–160. [Google Scholar]
- Xiao, Y.; Jang-Yeon, H.; Sun, Y.-K. Transition metal carbide-based materials: Synthesis and applications in electrochemical energy storage. J. Mater. Chem. A 2016, 4, 10379–10393. [Google Scholar]
- Yang, H.; Liu, J.; Wang, J.; Poh, C.K.; Zhou, W.; Lin, J.; Shen, Z. Electrocatalytically Active Graphene supported MMo Carbides (M = Ni, Co) for Oxygen Reduction Reaction. Electrochim. Acta 2016, 216, 246–252. [Google Scholar]
- Deng, N.; Ju, J.; Yan, J.; Zhou, X.; Qin, Q.; Zhang, K.; Liang, Y.; Li, Q.; Kang, W.; Cheng, B. CeF3-Doped Porous Carbon Nanofibers as Sulfur Immobilizers in Cathode Material for High-Performance Lithium–Sulfur Batteries. ACS Appl. Mater. Interfaces 2018, 10, 12626–12638. [Google Scholar]
- Xiang, Y.; Cheng, B.-R.; Li, D.-F.; Zhou, B.-X.; Yang, T.-F.; Ding, S.-S.; Huang, G.-F.; Pan, A.; Huang, W.-Q. Facile one-step in-situ synthesis of type-II CeO2/CeF3 composite with tunable morphology and photocatalytic activity. Ceram. Int. 2016, 42, 16374–16381. [Google Scholar]
- Pavlov, V.V.; Rakhmatullin, R.M.; Morozov, O.A.; Korableva, S.L.; Kiiamov, A.G.; Naumov, A.K.; Semashko, V.V.; Evtugyn, V.G.; Osin, Y.N. CeO2/CeF3 composite nanoparticles: Fabrication by fluorination of CeO2 with tetrafluoromethane gas. Mater. Chem. Phys. 2018, 207, 542–546. [Google Scholar]
- Kashinath, L.; Byrappa, K. Ceria Boosting on In Situ Nitrogen-Doped Graphene Oxide for Efficient Bifunctional ORR/OER. Activity. Front. Chem. 2022, 10, 889579. [Google Scholar]
- Sim, Y.; Kim, S.J.; Janani, J.; Chae, Y.; Surendran, S.; Kim, H.; Yoo, S.; Seok, D.C.; Jung, Y.H.; Jeon, C.; et al. The synergistic effect of nitrogen and fluorine co-doping in graphene quantum dot catalysts for full water splitting and supercapacitor. Applied Surface Science 2020, 507, 145157. [Google Scholar]
Category | Catalyst | Synthesis | Reaction | Electrolyte | E1/2(V)/EJ=10 (V) | Tafel slope | Ref. |
---|---|---|---|---|---|---|---|
Ce-based materials derived from MOFs | CeOx/CoS | In situ generation | OER | 1 M KOH | 0.269 V | 50 mV dec−1 | [54] |
CeO2@N-C | ORR | 0.1 M KOH/0.1 M HClO4 | 0.908 V/ 0.670 V | - | [60] | ||
CeO2/Co@N-C | ORR/OER | 0.1 M KOH | 0.934 V/ 1.704 V | - | [61] | ||
CENC | Chemical oxidative polymerization method | ORR | 0.1 M KOH | −0.114 V | 63.4 mV dec−1 | [62] | |
CNMCs | Stand at RT | ORR | 0.1 M KOH | −0.1031 V | - | [59] | |
SMOFs | Carbonyl chemical route | ORR | 0.1 M HClO4 | - | −52 mV dec−1 | [55] | |
FeCo2O4/CeO2 | Stand at RT | ORR/OER | 0.1 M KOH/1 M KOH | 0.713 V/1.722 V | 69.3 mV dec−1/63.0 mV dec−1 | [56] | |
Ce–HPCNs | Stand at RT | ORR | 0.1 M KOH | 0.831 V | 91 mV dec−1 | [57] | |
CeO2@MnO2 | Two-step hydrothermal process | ORR | 0.1 M KOH | 0.89 V | - | [66] | |
CeO2/CePO4@N, P-C | Polymerization | ORR | 0.1 M KOH | 0.822 V | - | [67] | |
CeO2−Co−NC | Sacrificial templates | ORR | 0.1 M KOH | 0.797 V | 60 mV dec−1 | [68] | |
Pt-CeO2@CN | Polyol method | ORR | 0.1 M KOH | 0.79 V | 70 mV dec−1 | [69] | |
CePO4/NiCo2O4 | Hydrothermal | OER | 1 M KOH | 0.281V (EJ = 20) | 74 mV dec−1 | [70] | |
LSM-CeO2 | One-pot method | ORR | 0.1 M KOH | 0.666 V | 71 mV dec−1 | [71] | |
UCNFs@3DG | Freeze-drying | ORR | 0.1 M KOH | - | - | [76] | |
Ce-based materials with various structures | CeOMS-2 | Cation exchange | ORR/OER | 1 M KOH | 1.78V/0.76 V | - | [80] |
Co–CeO2–N–C | Electro-spun | ORR/OER | 0.1 M KOH/1 M KOH | 0.89V/0.326 V | - | [81] | |
CeO2/MWNT | Precipitation | ORR | 0.1 M HClO4 | - | - | [74] | |
Co–CeO2/N-CNR | Electro-spun | ORR/OER | 0.1 M KOH | 0.82V/0.410 V | 58.4 mV dec−1/90 mV dec−1 | [82] | |
PdQD@C–CeOx/RGO | In situ generation | ORR/OER | 1 M KOH | +1.0V/+0.12 V | - | [85] | |
Pd-CeO2-NR/G | RT stir | ORR | 0.5 M KOH | Eonset = 0.98 V | - | [86] | |
Pt/CeO2/C | Reflux | ORR | 1 M HClO4 | 0.86 V | - | [75] | |
PtCo-CeOx/C | Colloid method | ORR | 0.5 M H3PO4 | - | - | [87] | |
Pd/MnOx-CeO2-C | Three-step reaction | ORR | 0.1 M HClO4 | - | - | [96] | |
CeO2/MnO2 | Two-step hydrothermal approach | ORR | 0.1 M KOH | 0.75 V | - | [102] | |
Ce-MnO2/C | Redox synthesis | ORR | 0.1 M KOH | 0.783 V | −90 mV dec−1 | [103] | |
Mn-CeO2/rGO | Microwave mediated solvothermal method | ORR | 0.1 M KOH | −0.336 V | - | [104] | |
MnOx–CeO2/KB | A two-step strategy | ORR | 0.1 M KOH | 0.81 V | 94.4 mV dec−1 | [105] | |
CeNiOx@CN-n | In situ polymerization | ORR | 0.1 M KOH | - | - | [88] | |
CeO2/g-C3N4 | Microwave-mediated solvothermal method | ORR | 0.1 M KOH | −0.383 V | - | [89] | |
CeO2/rGO | Sonochemical method | ORR/OER | 0.1 M KOH | −0.05 V/0.35V (onset) | 138 mV/dec | [90] | |
CeO2-rGO750 | In situ growth | ORR | 0.1 M KOH | - | - | [91] | |
CeGS | solvothermal method | ORR | 0.1 M KOH | 0.81 V | 111 mV dec−1 | [92] | |
CeLa2Cx-NC | Pyrolysis | ORR | 0.1 M KOH | - | - | [92] | |
PpPD-Fe-ZnO-CeO2 | Hydrothermal method | ORR | 0.1M HClO4 | - | - | [93] | |
CeF3-Fe/N/C | Bottom-up synthetic method | ORR | 0.5 M H2SO4 | 0.78 V | - | [94] |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Zhang, H.; Wang, Y.; Song, D.; Wang, L.; Zhang, Y.; Wang, Y. Cerium-Based Electrocatalysts for Oxygen Evolution/Reduction Reactions: Progress and Perspectives. Nanomaterials 2023, 13, 1921. https://doi.org/10.3390/nano13131921
Zhang H, Wang Y, Song D, Wang L, Zhang Y, Wang Y. Cerium-Based Electrocatalysts for Oxygen Evolution/Reduction Reactions: Progress and Perspectives. Nanomaterials. 2023; 13(13):1921. https://doi.org/10.3390/nano13131921
Chicago/Turabian StyleZhang, Huiyi, Yan Wang, Daqi Song, Liang Wang, Yifan Zhang, and Yong Wang. 2023. "Cerium-Based Electrocatalysts for Oxygen Evolution/Reduction Reactions: Progress and Perspectives" Nanomaterials 13, no. 13: 1921. https://doi.org/10.3390/nano13131921