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Solid-State High-Temperature Electrochemical Devices: Fabrication, Characterization, Operation

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "D: Energy Storage and Application".

Deadline for manuscript submissions: 31 July 2024 | Viewed by 811

Special Issue Editor


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Guest Editor
CTH2—Center for Hydrogen Technologies, Institute of Power Engineering, Augustówka 36, 02-981 Warsaw, Poland
Interests: solid oxide fuel cells (SOFC); mixed ionic and electronic conductors (MIEC); solid-state ionics; solid oxide electrolysis cells (SOEC); reversible solid oxide cells (rSOC)

Special Issue Information

Dear Colleagues, 

We are pleased to invite you to submit the results of your recent studies to the upcoming Special Issue of Energies entitled “Solid-State High-Temperature Electrochemical Devices: Fabrication, Characterization, Operation”.

Interest in electrochemical systems for the generation and accumulation of energy demonstrates a strong level of growth correlated with the development of “green” energy production. Being clean and potentially very cheap, solar and wind sources cannot ensure the stable operation of energy grids due to their dependence on weather conditions. The usage of high-temperature electrochemical devices provides an opportunity to mitigate this disadvantage in the production of hydrogen in steam electrolyzers (SOEC and PCEC). Specifically, when hydrogen is overproduced, it can be stored for consumption in fuel cells (SOFC and PCFC) for moments when weather conditions are unfavorable.

These options can be combined in one variety of electrochemical unit—a reversible solid oxide cell (rSOC). Other important opportunities, offered by solid oxide cells, are dedicated non-interruptible generators for data centers and other facilities. These require 24x365 access to a stable power source and SOECs, combined with catalytic reactors, so-called power-to-X systems, which might convert water and carbon dioxide into chemicals. A challenging direction of SOC development is in fuel-assisted electrolysis cells (SOFEC), devices which can consume low-grade gases fuel like refuse-derived fuel (RDF) to depolarize anodes. These practices allow researchers to decrease the costs of production for valuable products like hydrogen or hydrocarbon.

This Special Issue of Energies will focus on novel approaches to cell and stack designs of the various solid oxide cell, including both oxygen and high-temperature protonic conducting. Additionally, it will cover the characterization of the electrochemical units and issues, including those elements related to degradation.

  • Design of the cells, single repeating units and stacks.
  • Characterization of the electrochemical performance of the cells.
  • Electrochemical degradation of the cells in SOFC, PCFC, SOEC, PCEC, and SOFEC modes.
  • Characterization and degradation of the interfaces in single repeating unit, including anode and cathode electric contacts as well as possible impact of the sealing.
  • Novel and unusual application of solid oxide cells like electrocatalytic reactors, etc.

This Special Issue aims to publish the results, obtained on macro cells (with active surfaces of 10 cm2 or higher) in conditions approaching those expected in electrochemical devices.

Dr. Yevgeniy Naumovich
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Energies is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • SOFC
  • SOEC
  • reversible SOC
  • solid oxide fuel electrolysis cells (SOFEC)
  • protonic ceramic fuel cells (PCFC)
  • protonic ceramic electrolysis cells (PCEC)
  • degradation
  • interfaces
  • single repeating unit (SRU)
  • stack

Published Papers (1 paper)

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Research

16 pages, 20981 KiB  
Article
Impact of Sweep Gas on the Degradation of an La0.6Sr0.4Co0.8Fe0.8O3 Anode in a Solid Oxide Electrolysis Cell
by Michał Wierzbicki, Stanisław Jagielski, Yevgeniy Naumovich, Anna Niemczyk, Marek Skrzypkiewicz and Jakub Kupecki
Energies 2024, 17(5), 1144; https://doi.org/10.3390/en17051144 - 28 Feb 2024
Viewed by 571
Abstract
The degradation of solid oxide electrolysis (SOE) cells with different anode sweep gases was studied in 1000 h-long measurements in order to investigate the impact of sweep gas composition on cell performance. Cathode-supported electrolysis cells with an La0.6Sr0.4Co0.2 [...] Read more.
The degradation of solid oxide electrolysis (SOE) cells with different anode sweep gases was studied in 1000 h-long measurements in order to investigate the impact of sweep gas composition on cell performance. Cathode-supported electrolysis cells with an La0.6Sr0.4Co0.2Fe0.8O3 air electrode (active area of 4 × 4 cm2) were tested under a constant current (−0.25 A/cm2) in the electrolysis mode while supplying the cathode side with 70% H2O–30% H2 mixtures at 800 °C and using oxygen, nitrogen, and steam as sweep gases. It was demonstrated that the degradation of the anode in steam conditions resulted in more than a 2-fold increase in both, polarization and ohmic resistance (from 0.20–0.25 to 0.6–0.65 Ω cm2 compared to relatively stable values of 0.15–0.2 Ω cm2 for N2), as a consequence of the phase decomposition. Strontium played an important role in steam-induced degradation, migrating from the volume of the electrode layer to the surface of the electrolyte. As a result, the Sr-enriched layer demonstrated susceptibility to Cr poisoning. The cell purged with N2 demonstrated enhanced performance, while the use of oxygen led to degradation originating from the well-described delamination process. DRT analysis demonstrated some similarity of the spectra for steam and N2, namely the presence of a slow process at τ0.5 s, which might be associated with hindered oxygen transport due to point defect association in the perovskite structure. The results of this study showed that Sr-containing materials likely cannot be used as an SOE anode in high humidity conditions. Full article
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