1. Introduction
Chaos refers to irregular, random non-linear phenomena in a certainty system. In reality, it has an inherent regularity, which is a unity of order and disorder. In the natural world, chaotic phenomena are everywhere. To solve actual problems in the natural world, we often build corresponding physical models to find solutions. Integer order differential transformation has been widely applied to soil spectrum-signal processing [
1,
2,
3,
4]. However, the physical model it describes is just approximation processing, and needs to use a fractional order differential equation to increase accuracy as the complexity and diversity of the descriptive system increases. Fractional calculus is a generalized form for orders in classic calculus. Compared to traditional calculus, its greatest advantage lies in its memory and inheritance. This makes describing certain physical phenomenons with fractional order differential equation more accurate and effective. Studies have already proven that the fractional order system conforms better to natural law and engineering physical phenomena [
5,
6,
7,
8,
9,
10] and has a more complex dynamic behavior. The development of fractional calculus facilitated fractional order chaotic system research, such as Chua’s circuit, Lorenz system, and the Chen system. When orders become fractional orders, the system still exhibited chaotic phenomenon. In recent years, fractional order chaotic system studies have become popular, and the system has been applied widely to various fields [
11,
12] such as physics, computer science, ecology, management, biology and medicine.
Soil salinization is the main cause of soil desertification in arid areas. Natural environment and human activities affect the accumulation of soluble salts on the surface, forming different levels of salinization [
13,
14,
15,
16,
17]. Xinjiang has become an important food and cotton production base for China, as well as being the safety reserve base for food and cotton. Soil salinization seriously threatens agricultural safety in Xinjiang [
18,
19]. Xinjiang’s arid/desert areas have high evaporation levels and low rainfall. High levels of human activities also have special effects on the moisture and salt status in desert areas. Previously, scholars used soil’s salt spatial and temporal distribution, field measured water/salt migration laws, salt/water content organic physical properties, and image spectrum data to monitor and draw maps in soil salinization studies [
20,
21,
22,
23,
24]. Nurmemet et al. [
25] used salinization areas in the Keriya River Basin in Xinjiang as test areas and used a support vector machine (SVM) to classify soil coverage types in the salinization areas. The cross-validation method was used to ensure optimal classification parameters and a decision tree (DT) solution was applied to increase the accuracy of saline soil estimation. The result showed that an integration of passive reflectance and active microwave remote sensing is an effective way to measure salinization. The DT solution is even more effective and has an accuracy rate of 93.01%. Overall, the study area had a saline soil content of 41.43%. Sarani et al. [
26] used the soil in the Sistan plain, Iran, as the research subject. They measured the soil’s physical and chemical properties, then used the data to find the changes in exchangeable sodium percentage (ESP) and sodium adsorption ratio (SAR) in the soil. The result shows that the multilayer perceptron (MLP) is the best neural network prediction model and can accurately estimate ESP and SAR quantity. Vermeulen et al. [
27] used extremely high resolution WorldView-2 image to draw soil salt accumulation in South Africa’s Vaalharts region. The result shows that extremely high-resolution images can be used to great effect to detect salt accumulation. Salinity indices threshold based on normalized differences has the best classification effect and has an accuracy of 80%. Xia et al. [
28] used a Fourier infrared spectrometer to field measure Xinjiang saline soil. They found that 8000–13,000 nm soil thermal infrared emissivity decreased as the salt content increased and that emissivity spectrum is the most sensitive to salt content at 8000–9500 nm. However, there are insufficient numbers of studies on soil salt content changes and distribution pattern in areas with different levels of human interference. Changes in soil salt content are affected by the natural environment and human activities. To obtain a better classification of salinization level, we need to explore the temporal and spatial change laws in salinization status. Soil salinization exhibits greater temporal and spatial changes, which present a challenge for salinization identification and diagnostic.
Soil salinization is an extremely complex evolution process that is affected by numerous mutually interacting factors. This process exhibits a strong non-linear characteristic [
29,
30,
31]. Temporal and spatial changes in saline soil spectrum are random and uncertain. Traditional mathematical methods have a difficult time accurately describing and analyzing this system change process. Because the conversion function between saline soil spectrum reflectance and soil parameter is a complex non-linear relationship, non-linear science based on chaos theory can explore and analyze this type of non-linear problem [
32,
33]. However, there are currently few studies on the use of chaotic system to analyze the soil spectrum features of soil with different levels of salinization.
At present, Tian (2019) has proposed the use of fractional-order chaotic system and PNN (probability neural network, PNN) to classify the degree of soil salinization. The classification accuracy is better than the traditional SVM and KNN (K-nearest neighbor, KNN) methods [
34], and the simulation results prove that the hyperspectral signals processed by the fractional-order chaotic system are easier to identify, which is beneficial to classification. However, the calculation of PNN is more complicated, the execution rate is slower, and the promotion in practical applications is limited. Because the extension method is simpler than PNN, it is easier to popularize and use.
Therefore, this paper uses the fractional-order chaotic system to map the soil hyperspectral signal as a chaotic attractor, and the soil salinization classification model is established by using the plane coordinate method and extension theory. The simulation results show that the classification accuracy of the proposed classification method in Area A and B is 90% and 100%, respectively. Compared with other traditional classification methods, the proposed method has shorter calculation time and higher classification accuracy. The expectation is to uncover saline soil change laws for areas with different levels of human interference as well as to provide new thinking for accurately classifying saline soil spectrum data.
3. Sample Collection
3.1. Overview of the Study Area
The research area is located in Xinjiang’s Fukang City. The area’s geographical coordinate is 87°44′ to 88°46′ E and 43°29′ to 45°45′ N, located in the northern foothill of Tarim Basin and the southern edge of the Gurbantünggüt Desert. Fukang is 57 km west of Urumqi and located in the northern foothill of the Tarim Basin economic development belt. Fukang has an agricultural development, industry, and travel industry advantages. The area has temperate continental desert climate with clear seasonal changes. The winter is cold, the summer is hot, and there is very little rainfall (averaging 200 nm annually). The annual air temperature is 6.6 °C and the area is very abundant in thermal energy (average annual sunshine of 2931.3 h).
3.2. Soil Sample Collection
Collection of soil samples, gathering of sampling area-related data, and ensuring reasonable sample collection time and route must be prepared ahead of time. A field survey showed that the research area has a giant canal that is 24 m wide at the top, 6 m wide at the bottom, and that is 15.30 km long. This giant canal is used as the boundary to divide the research area into Area A and Area B sampling areas. Area A is located on the right side of the canal and is further away from human activity. This means that the area is less affected by human activities and that the soil has maintained its natural ecological form. Area B is located on the left side of the canal and is closer to Xinjiang’s 102 Production and Construction Army Corp, and is often affected by human interference. This area has been developed into farmland and seedling plantation area. During the soil sample collection process we chose a flat area with no surface vegetation. The choice of sampling points emphasized representativeness and uniformity. This ensures that the samples are representative of the research area’s soil status. The soil samples were field collected in May 2017. The quincunx sampling method was used to collect 0–10 cm of surface soil. Twenty-five points were collected from Area A and 30 points were collected from Area B. The samples were mixed evenly and 1 kg was placed into a sample bag and labeled. Before conducting the field soil sample collection work, a handheld GPS was used to mark the longitude and latitude of each sampling point. After collecting the soil samples the sample was placed in a dry and ventilated laboratory. After natural air drying, the sample was grounded and screened to remove materials other than soil. The soil sample was sent to the Xinjiang Institute of Ecology and Geography where chemical analysis was used to measure the soil salt content. Soil-sampling points are as shown in
Figure 5.
3.3. Field Spectrum Measurements
While field collecting the soil samples, we also collected field soil spectrums. To field measure the soil spectrums, we used an American ASD FieldSpec3 spectrometer with spectrum wavelength range of 350–2500 nm. For the 350–1050 nm range, an interval of 1.4 nm was used and for the 1000–2500 nm range an interval of 2 nm was used. Resampling interval was 1nm. There were a total of 2151 wavebands. The field spectrum testings were done in the afternoon of clear days. Before each spectrum is measured, the spectrometer undergoes a standard calibration with a standard reference table to reach a nearly 100% baseline. The spectrometer is then pointed towards the ground target to obtain the measure. To make the data representative, five locations around each sampling point is used to collect the spectrum. Each location is measured 10 times. Thus, each soil sample requires 50 measured spectrum curves. The mean of the spectrum reflectance is used as the final result. This can limit the impact on spectrum reflectance caused by soil surface roughness (as a result of soil granules) and ensure spectrum data accuracy.
3.4. Spectrum Signal Pre-Processing
Soil spectrum collection is inevitably affected by soil viscosity, particle size, and the environment. Appropriate spectrum pre-treatment can reduce the impact of background noise on the soil spectrum curve. Pre-processing can also increase the correlation between the spectrum and soil content, which can help build a reliable predictive model. The edge bands with lower signal noise (350–399 nm and 2401–2500 nm) and wave bands around the moisture absorption belt (1355–1410 nm and 1820–1942 nm) is removed from the measured spectrum data. Savitzky-Golay convolution smoothing method is used to smooth the remaining spectrum reflectance curves and further remove high-frequency noise interference from the spectrum signal, thereby, increasing the signal–noise ratio.
3.5. Soil Salinization-Level Determination Standard
The spectrum reflectance curve of the 55 sampling points in the research area is shown in
Figure 6.
Figure 6 shows that there is a large quantity of soil spectrum data with a high number of wave band dimensions. As a result, there is an excessively high number of spectrum reflectance information overlap. This is especially true when there are too many soil-sampling points; the spectrum reflectance curve of the sampling points displayed severe overlapping. This makes it difficult to distinguish the salt content of the sampling points and its spectrum reflectance relationship. The soil salinization is classified according to the standard in
Table 1 [
45]. Six sampling points were selected in Area A, numbered A1 to A6. Six sampling points were selected for Area B, numbered B1 to B6.
Figure 7 shows the spectrum reflectance of sampling points with different salinization levels.
Figure 7 clearly shows that the higher the soil salt content the greater the spectrum reflectance, and the more severe the salinization level. Conversely, soil with low salt content has low spectrum reflectance.
In addition, the descriptive statistics of Na
+ and Cl
− ion contents are shown in
Table 2. The maximum, minimum and mean of Na
+ ion in Area A is 4.890, 0.640 and 1.590 respectively, and it is 8.299, 0.622 and 2.148 in Area B. The maximum, minimum and mean of Cl
− ion in Area A is 9.882, 0.077 and 1.167 respectively, and it is 15.646, 0.077 and 3.081in Area B. So that the Na
+ and Cl
− ion contents in Area B are higher than Area A.
5. Conclusions
The soil spectrum feature is a highly complex non-linear system and its spectrum change is affected by topography, parent material, salt content, mineral content, moisture content, organic content, and human activities. Chaos is a unique movement pattern in non-linear dynamic systems. In this study we introduced chaotic techniques to analyze this type of non-linear question. We proposed a classification and prediction method for salinization level in arid area soil based on Chua’s circuit combined with a fractional order Sprott chaotic system. The chaotic dynamic error, chaotic attractor, and the extension matter-element model are used as the classification basis for salinization level. A fractional order chaotic principle and extension theory were combined to build a salinization-level classification model based on a fractional order compound master/slave chaotic system. This model can accurately classify salinization level. In an area with no human interference this model achieved 90% identification accuracy rate. In area with human interference, this model achieved 100% identification accuracy rate. Thus, we were able to achieve smart classification of saline soil spectrum’s non-linear system. This study produced a brand new method for rapidly and accurately testing the soil salinization level in a test area.