Emerging Hybrid Metal Halide Glasses for Sensing and Displays
Abstract
:1. Introduction
2. Principles of Glass Formation and Manufacturing Techniques
3. Glassy Hybrid Metal Halides and Derivates
3.1. Pb-Based Hybrid Metal Halide Glasses
3.2. Sn-Based Hybrid Metal Halide Glasses
3.3. Mn-Based Hybrid Metal Halide Glasses
3.4. Sb-Based Hybrid Metal Halide Glasses
3.5. Other Hybrid Metal Halide Systems
3.6. Crystalline–Amorphous Heterojunction
4. Emerging Applications
4.1. Lighting and Displays
4.2. Information Storage
4.3. X-ray Imaging
4.4. Optics and Sensing
5. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Materials | Organic Cations | Tx or Tg (°C) | Tm (°C) | Td (°C) | Ref. |
---|---|---|---|---|---|
(C4)2PbCl4 | 4-ammoniumbutyric acid | - | 144.64 | - | [17] |
(C5)2PbCl4 | 5-aminovaleric acid | - | 184.79 | - | [17] |
(C5)2PbBr4 | 5-aminovaleric acid | - | 157.35 | - | [17] |
(C6)2PbCl4 | 6-aminocaproic acid | - | 207.99 | - | [17] |
(C6)2PbBr4 | 6-aminocaproic acid | - | 211.39 | - | [17] |
Rac-NPB | racemic 1-(1-naphthyl)ethylammonium | - | 221 | 215 | [22] |
S-NPB | S-(−)-1-(1-naphthyl)ethylammonium | 67 a | 173 | 205 | [23] |
(4-F-PEA)2PbI4 | 4-fluorophenethylammonium | 244.3 | 258.9 | - | [58] |
(β-Me-PEA)2PbI4 | β-methylphenethylammonium | 170.7 | 207.0 | - | [58] |
(1-MeHa)2PbI4 | 1-methyl-hexylammonium | 111.1 | 172.3 | 228 | [63] |
(2-F-PEA)2PbI4 | 2-fluorophenethylammonium | 181.2 | 245.8 | - | [64] |
(4-MeO-PEA)2PbI4 | 4-methoxyphenethylammonium | 214.2 | 247.1 | - | [64] |
(PEA)2PbI4 | phenethylammonium | 199.2 | 252.9 | - | [64] |
(3-F-PEA)2PbI4 | 3-fluorophen-ethylammonium | 211.6 | 261.4 | - | [64] |
(DMIEA)3Pb2I7 | N,N-dimethyl iodoethylammonium | - | 173 | 235 | [62] |
(DMIPA)4Pb3I10 | N,N-dimethyl iodopropylammonium | - | 151 | 245 | [62] |
(DMBPA)4Pb3Br10 | N,N-dimethyl bromopropylammonium | - | 139 | 239 | [62] |
Materials | Organic Cations | Tg (°C) | Tm (°C) | Ref. |
---|---|---|---|---|
(HTPP)2MnBr4 | hexyltriphenylphosphonium | 38.6 | 169 | [15] |
(BuTP)2MnBr4 | butyltriphenylphosphonium | 46 | ~135 | [35] |
(1-EP)2MnBr4 | 1-ethylpyridine | - | ~105 | [35] |
(1-BuP)2MnBr4 | 1-butylpyridine | - | ~110 | [35] |
(BTP)2MnBr4 | benzyltriphenylphosphonium | 74 | ~220 | [35] |
(ETP)2MnCl4 | ethyltriphenylphosphonium | - | 204 | [35] |
(Bmmim)2MnCl4 | 1-butyl-2,3-dimethylimidazolium | - | 50 | [40] |
(Bmmim)2MnBr4 | 1-butyl-2,3-dimethylimidazolium | - | 60 | [40] |
(TPrA)[Mn(dca)3] | tetrapropylammonium | 218 | 271 | [79] |
(BTA)2MnBr4 | benzyltrimethylammonium | 175 | [80] | |
(ETP)2MnBr4 | ethyltriphenylphosphonium | 50 | 168 | [81] |
(BPTP)2MnBr4 | 3-bromopropyl)triphenylphosphonium | - | 220 | [82] |
(HTP)2MnBr4 | heptyl(triphenyl) phosphonium | - | 165 | [83] |
(TP)2MnBr4 | (triphenyl)phosphine | - | <220 | [83] |
(MTP)2MnBr4 | methyl(triphenyl)phosphonium | 55 | <220 | [83] |
(PTP)2MnBr4 | pentyl(triphenyl)phosphonium | - | <220 | [83] |
(TBuA)[Mn(dca)3] | tetrabutylammonium | 33 | 185 | [84] |
(TPnA)[Mn(dca)3] | tetrapentylammonium | 9 | 149 | [84] |
Materials | Organic Cations | Tg (°C) | Tm (°C) | Td (°C) | Ref. |
---|---|---|---|---|---|
(S-2-HMM)3SbCl6 | S-2-(hydroxymethyl)morpholine | 22 | 140 | 249 | [24] |
(Rac-2-HMM)2SbCl5 | rac-2-(hydroxymethyl)morpholine | 25 | 130 | - | [24] |
(Bmmim)2SbCl5 | 1-butyl-2,3-dimethylimidazolium | - | 140 | - | [40] |
(TMPZ)SbI5 | 1,1,4,4 tetramethylpiperazinium | - | 259 | - | [89] |
(S-MeTMPZ)SbI5 | (S)-1,1,2,4,4-pentamethylpiperazinium | - | 252 | - | [89] |
(MTP)2SbBr5 | methyltriphenylphosphonium | 65 | 178 | - | [90] |
(ETP)2SbCl5 | ethyltriphenylphosphine | 38 | 149 | - | [91] |
[Al(DMSO)6](SbCl6) | dimethyl sulfoxide | - | - | 175 | [92] |
[Ga(DMSO)6](SbCl6) | dimethyl sulfoxide | ~0 | 90 | - | [92] |
[Y(DMSO)6](SbCl6) | dimethyl sulfoxide | - | <100 | - | [92] |
[Zr(DMSO)6](SbCl6) | dimethyl sulfoxide | - | <100 | - | [92] |
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Tang, W.; Xing, G.; Xu, X.; Chen, B. Emerging Hybrid Metal Halide Glasses for Sensing and Displays. Sensors 2024, 24, 5258. https://doi.org/10.3390/s24165258
Tang W, Xing G, Xu X, Chen B. Emerging Hybrid Metal Halide Glasses for Sensing and Displays. Sensors. 2024; 24(16):5258. https://doi.org/10.3390/s24165258
Chicago/Turabian StyleTang, Wei, Guansheng Xing, Xiuwen Xu, and Bing Chen. 2024. "Emerging Hybrid Metal Halide Glasses for Sensing and Displays" Sensors 24, no. 16: 5258. https://doi.org/10.3390/s24165258