Synthesis of Rice Husk-Based MCM-41 for Removal of Aflatoxin B1 from Peanut Oil
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of MCM-41
2.2. Effect of Adsorbent Dose
2.3. Adsorption Kinetics
2.4. Adsorption Isotherm
3. Conclusions
4. Materials and Methods
4.1. Materials and Reagents
4.2. Synthesis of MCM-41 from Rice Husk
4.3. Characterization of Rice Husk-Based MCM-41
4.4. Adsorption Experiments
4.4.1. Batch Adsorption Experiments
4.4.2. Determination of AFB1 Concentration
4.5. Adsorption Kinetics
4.6. Adsorption Isotherms
4.7. Data Analysis
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Adsorbents | Surface Area (m2/g) | Total Pore Volume (cm3/g) | Average Pore Diameter (nm) |
---|---|---|---|
MONT | 235 | 0.34 | 1.15 |
MCM-41 | 1246 | 1.75 | 3.11 |
CA | 453 | 0.52 | 1.87 |
Adsorbents | qe (exp) (ng/mg) | Pseudo-First-Order Model | Pseudo-Second-Order Model | ||||
---|---|---|---|---|---|---|---|
R2 | qe (cal) (ng/mg) | k1 (min−1) | R2 | qe (cal) (ng/mg) | k2 (mg/(ng·min)) | ||
MONT | 192.42 | 0.9940 | 166.00 | 0.00484 | 0.9960 | 197.58 | 2.596 × 10−5 |
MCM-41 | 217.22 | 0.9918 | 188.93 | 0.00487 | 0.9981 | 224.02 | 2.335 × 10−5 |
CA | 229.96 | 0.9898 | 199.67 | 0.00524 | 0.9974 | 234.95 | 2.441 × 10−5 |
Adsorbents | Langmuir Isotherm | Freundlich Isotherm | ||||
---|---|---|---|---|---|---|
R2 | qmax (ng/mg) | KL | R2 | KF | 1/n | |
MONT | 0.9978 | 199.41 | 0.0391 | 0.9106 | 31.475 | 0.324 |
MCM-41 | 0.9965 | 215.93 | 0.128 | 0.8638 | 58.807 | 0.247 |
CA | 0.9949 | 248.93 | 0.0701 | 0.8876 | 50.889 | 0.293 |
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Li, Y.; Wang, R.; Luo, X.; Chen, Z.; Wang, L.; Zhou, Y.; Liu, W.; Cheng, M.; Zhang, C. Synthesis of Rice Husk-Based MCM-41 for Removal of Aflatoxin B1 from Peanut Oil. Toxins 2022, 14, 87. https://doi.org/10.3390/toxins14020087
Li Y, Wang R, Luo X, Chen Z, Wang L, Zhou Y, Liu W, Cheng M, Zhang C. Synthesis of Rice Husk-Based MCM-41 for Removal of Aflatoxin B1 from Peanut Oil. Toxins. 2022; 14(2):87. https://doi.org/10.3390/toxins14020087
Chicago/Turabian StyleLi, Ya’nan, Ren Wang, Xiaohu Luo, Zhengxing Chen, Li Wang, Yunyu Zhou, Weizhi Liu, Miaomiao Cheng, and Chen Zhang. 2022. "Synthesis of Rice Husk-Based MCM-41 for Removal of Aflatoxin B1 from Peanut Oil" Toxins 14, no. 2: 87. https://doi.org/10.3390/toxins14020087